TUGAS KELOMPOK TEKNOLOGI PROSES KIMIA - SULFONASI KELAS A NAMA: 1. NUR APRIL APRILIAN IANII (121 (12111 11012 0128) 8) 2. RIZKIA RIZKIA AYUNANI YUNANI P. P. (12111 (121110136) 0136) 3. FARID FARID ROBIT ROBITO O !. (1211 (1211100 1000") 0") #. $ISNU $ISNU DAR DARMA MA S. (121 (12111 110020 0020)) ". ADIB ADIB SYU SYUADA ADA L. (1211 (1211101 1012%) 2%)
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/' Dodecene
/*',,'
4*4*, Dodecyl Benzene. Benzene. K*4/'
Dodecyl Benzene 5' *;'/ /'4'7,' /*' <+* <+*4 4 4*7'+,' Dodecyl Benzene Sulfonic Acid . Dodecyl Benzene Sulfonic Acid 5' *;'/ ,*4/' ,*4/' /*'+,' /*' *'4'7' N'O *7 *7 ' ' 4*7'+,' Sodium Dodecyl Benzene Sulfonate '' /***.
1.2 P*4+7' K''' P', M*' ,*7' ',' /*** / I/<*' *4', 4*,' (+7' '*+ 1.1)9 4',' *+ '+*' , 4*4, */ *7' /7'',' ,*7' ',' /*** (Sodium ( Sodium Dodecyl Benzene Sulfonate) Sulfonate) ','**7. ','**7.
D'' 4< /*** /' '7 2001 7' 200" /'' /+7' /'+'4 '*+ *, : T'*+ 1.1 I4< /*** (Sodium Dodecyl Benzene Sulfonate ) ,* I/<*' N<
T'7
!4+'7 (T< * '7)
1
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2002
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2003 2004 2005
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> #86%96= @ 2010 - %=3%%2%98# > #8106986 < D' 7'+ *7'9 4',' /*,',' ,*7' Sodium Dodecyl Benzene
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Dodecyl
Benzene
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,*7'
Sodium
Dodecyl
Benzene
Sulfonate '/' '7 2010
/*,',' 4*'' #".000 <'7 (+7' '*+ 1.1). 2. K***/'' '7' ', B'7' ', Sodium Dodecyl Benzene Sulfonate 5' Benzene /' Dodecene *;'4.
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1.3 P*4+7' L<,' P', P**' +<,' ', /', +*' /' '*,-'*, *,<<4 /' *,. P'/' 5' /+7 '5' , 5' *44 4, /' / 7'+ 5' , 4/'7. P*4+7' +<,' ', //'',' '/' ',< '4' /' ',< ,7 (P** /' T44*7'9 1%%1: %1) 5':
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/*' PT. B''7*49 *'' /< '7'
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A+,+' &66 C &122#
-
& "&122"
S+<' &6"&122" C 2SO#
-
A + &+3 → 6
&122"&6#SO3 C 2O
→
N*'+' &122"&6#SO3 C N'O
→
&122"&6#SO3 N' C 2O
Dodecene /' Benzene /<4' ,* /'+'4 *',< *7' *;'/ *', '+,+' 5' *,*;' *'' ,<5 '/' 7 11#98 F (#6 &) /' °
°
*,'' 1 '4 4*4*, +'' Dodecyl Benzene. '+ /' *',< /+';,' 4*; *',< +<' 5' *,*;' *'' ,<5
'/'
7 11#98 F (#6 &) 4*4*, +'' Dodecyl Benzene Sulfonic Acid . °
°
'+ +<' / /'+'4 *',< /*,' 4*;
*'+*
'
4**'+,' ' ''4 /' *',<. L'' Dodecyl Benzene Sulfonic Acid 5' *;'/ *'+*
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*' +5.. '+5' ,*4/' /,*,' / /'+'4 "!ay d!ye! , 4*4*<+*7 , , /***9
5' Sodium Dodecyl Benzene
Sulfonate. 2. P<* +<' Dodecyl Benzene /*' "ulfonatin$ a$ent oleum (2SO#SO3). R*', '/'+'7 *'' *,: -
A+,+' &66 C &122#
-
A + &+3 → 6
& "&122"
S+<' &6"&122" C 2SO#.SO3
-
&122"&6#SO3 C 2SO#
→
N*'+' &122"&6#CSO3C3N'O→ &122"&6#SO3 N'CN'2SO#C 2O
3. P<* +<' Dodecyl Benzene /*' "ulfonatin$ a$ent "ulfu! t!io%ide (SO3) -
S+<' &122"&6" C SO3
-
& 2"&6#SO3
→ 12
N*'+' &122"&6#CSO3C3N'O→ &122"&6#SO3 N'CN'2SO#C
Dodecyl
Benzene
/*',
/*'
20
<+*4
2O
/'+'4 +<'<
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°
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/*' *'4'7' N'O 20. P**'+' 4*7'+,'
Sodium
Dodecyl Benzene Sulfonate9 Sodium +'* /' 2O. Sodium Dodecyl Benzene Sulfonate 5' *' +59 ,*4/' /,*,' / /'+'4 "!ay d!ye!
, 4*4*<+*7 , , /***9 5' Sodium
Dodecyl Benzene Sulfonate.
1.#.2 K*'' , D*** (Sodium Dodecyl Benzene Sulfonate )
''' +'
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:
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Benzene
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: 19833 4L E*
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: 09360 $4.K *'
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2N2SO2O C &O2
→
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N'2SO# C 2O
→
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N'2SO# C 2&+
→
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C
← →
-
3O C 2SO#
/. S4 7/<,/' S' R4 4<+*,+
: N'O
B*' 4<+*,+
: 3%9%%8
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: 318 &
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SO3 N'
R4 4<+*,+
: &122"&6#SO3 N'
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: B'9 , '' 7 7' ,
B*' 4<+*,+
: 3#8
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('+*59 1%81: %3%-%#0)
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"ulfonate
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*.
S+<'
Dodecyl
Benzene
/'' /+',,' *''
'7 '' <<. -. Batc' !oce"" P'/' <* 9 +<' *;'+' '/' 7 %0-11#98 F (32°
#6 &) /' *,'' 1 '4 /*' 4*4',' 20 <+*4 /' ''4 /*' °
'< 1.02 (' ''4 100 2SO#). S*+'4' *'4'7' ''4 *', 7'5' %0 ( Dodecyl Benzene Sulfonic Acid ) *'' ,
49
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/*' ,*4' %8E.
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N'O 20 '4' 8. ,*4/'
,
/*'
/4','
4*; /5* , /,*,'. *. Continue !oce"" P'/' <* 9 *'4' <* A+,+' / /'+'4 *',< 5' *;'/ *',
'+,+' Benzene.
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/'+'4
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,*4/'
,
/4',' 4*; /5* , /,*,'. (F'7 K*5*9 1%6")
T!iyanti D ()) )*)