7.1 MSDS Complete.pdf

MATERIAL SAFETY DATA SHEET

PRODUCT NALCO® EC6080A EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

1.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME :

NALCO® EC6080A

APPLICATION :

SCALE INHIBITOR

COMPANY IDENTIFICATION :

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, The Netherlands

EMERGENCY TELEPHONE NUMBER(S) :

See section 16, for Emergency Telephone Numbers.

Date issued : Version Number :

03.04.2007 1.12

COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. NALCO AB (SE) NALCO ANADOLU KIMYA (TR) NALCO APPLIED SERVICES OF EUROPE BV NALCO BELGIUM N.V./S.A. (B) NALCO DANMARK A/S NALCO DEUTSCHLAND GmbH (D) NALCO ESPAÑOLA S.A. (E) NALCO FINLAND OY (FI)

+31 71 5241 100 +46 (0)8-50074000 +90 216 5743464 +31 (0)73 6456980

NALCO NORGE AS (NO) NALCO POLSKA Sp.z.o.o. (PL) NALCO PORTUGUESA LDA. (P) NTD S.r.l (IT)

+47 51 96 36 00 +48 (0)32-3262750 +351 214130996 +39 (0) 313351325

+32 (0)3-450 69 10 +45-48195800 +49 (0)69-79340 +34 93-4095555 +358 (0)9 2517 4700

+41 (0)56 4606260 +41 (0)41 760 2220 +41 (0)52 235 38 38 +7 (0)495 980 72 80 + 43(0)1 27026350

NALCO FRANCE SAS

+33 (0)3 20 11 70 00

NALCO HELLAS S.A. (GR)

+30 210 238 9620

NALCO ITALIANA S.R.L.(I)

+39 06-542971

NALCO LIMITED

+44 (0)1606 74488

CHEMIA BRUGG AG (CH) OEKOPHIL AG (CH) WYSS WASSERTECHNIK AG (CH) ZAO Nalco (RU) NALCO ÖSTERREICH Ges.m.b.H. (A) local support: Nalco Czechia s.r.o. (CZ) Local Support: Nalco Hungary Kft. (HU) Local Support: Nalco Österreich Ges.m.b.H., Representation Office Predstavnistvo Zagreb (HR) Local Support: Nalco Österreich Ges.m.b.H. Representation Office ROMANIA (RO)

NALCO NETHERLANDS B.V.

+31 (0)13-5952200

2.

+420 (0)2 679 123 50 +36 (0)1 471 91 81 +385 (0)1 377 95 21 +40 (0) 21 224 17 93

COMPOSITION/INFORMATION ON INGREDIENTS

This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC. Any disclosed substance(s) are present below hazardous concentration levels for the product classification. Hazardous Substance(s) Ethylene Glycol Sodium Phosphate, Tribasic

EINECS / ELINCS NO 203-473-3 231-509-8

CAS NO

SYMBOL

107-21-1 7601-54-9

Xn Xi

R-PHRASES / NOTAS R22 R36/38

% (w/w) 1- 5 10 - 30

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

3.

HAZARDS IDENTIFICATION

HAZARD CLASSIFICATION :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100

For additional copies of an MSDS visit www.nalco.com and request access 1 / 10



This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC. Any disclosed substance(s) are present below hazardous concentration levels for the product classification.

HUMAN HEALTH HAZARDS - ACUTE : INHALATION : Repeated or prolonged exposure may irritate the respiratory tract. SKIN CONTACT : May cause irritation with prolonged contact. Can be absorbed through the skin. EYE CONTACT : May cause irritation with prolonged contact. INGESTION : Not a likely route of exposure. No adverse effects expected.

4.

FIRST AID MEASURES

INHALATION : Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. SKIN CONTACT : Flush affected area with water. If symptoms develop, seek medical advice. EYE CONTACT : Flush affected area with water. If symptoms develop, seek medical advice. INGESTION : Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If reflexive vomiting occurs, rinse mouth and repeat administration of water. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5.

FIRE FIGHTING MEASURES

FLASH POINT :

105 °C TCC

EXTINGUISHING MEDIA : This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARD : May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100




6.

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water.

7.

HANDLING AND STORAGE

HANDLING : Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. STORAGE CONDITIONS : Store in suitable labeled containers. Store the containers tightly closed. SUITABLE CONSTRUCTION MATERIAL : Stainless Steel 304, Stainless Steel 316L, EPDM, HDPE (high density polyethylene), Viton, Neoprene, Nitrile, Perfluoroelastomer, PTFE, MDPE UNSUITABLE CONSTRUCTION MATERIAL : Carbon steel SPECIFIC USE(S) : SCALE INHIBITOR For specific dosages and customized applications please contact your representative.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source AUSTRIA __

Substance(s) Ethylene Glycol

Category: MAK MAK CEIL Skin*

BELGIUM

Ethylene Glycol (Aerosol.)

TWA

ppm 10 20

mg/m3 26 52

20

52





DENMARK

Ethylene Glycol Ethylene Glycol (Aerosol.) Ethylene Glycol

STEL Skin*

40

104

GV GV Skin* GV Skin*

10

26 10

10

FINLAND

Ethylene Glycol

HTP 8H HTP 15MIN Skin*

20 40

50 100

FRANCE

Ethylene Glycol (Vapour.)

VME STEL Skin*

20 40

52 104

GERMANY

Ethylene Glycol

MAK Skin*

10

26

IRELAND

Ethylene Glycol (Vapour.) Ethylene Glycol (Particulate.) Ethylene Glycol (Vapour.)

TWA TWA STEL Skin*

20 40

52 10 104

ITALY

Ethylene Glycol

TWA STEL Skin*

20 40

52 104

NETHERLANDS

Ethylene Glycol (Mist.) Ethylene Glycol (Vapour.)

MAC MAC MAC-TGG 15 Skin*

20 40

10 52 104

Ethylene Glycol (Dust) Ethylene Glycol (Vapour.)

ADM. NORM CEIL Skin* Skin*

NORWAY

Ethylene Glycol (Dust)

10 25

SPAIN

Ethylene Glycol

VLA-ED VLA-EC Skin*

20 40

52 104

SWEDEN

Ethylene Glycol

NGV KTV Skin*

10 20

25 50

SWITZERLAND

Ethylene Glycol

TWA STEL Skin*

10 20

26 52

UNITED KINGDOM

Ethylene Glycol (Particulate.) Ethylene Glycol (Vapour.)

TWA TWA STEL Skin* Skin*

20 40

10 52 104

Ethylene Glycol (Particulate.) Ethylene Glycol (Vapour.) POLAND

Ethylene Glycol

MAC-NDS MACNDSCh

HUNGARY

Ethylene Glycol

ÁK CK Skin*

52 104

CZECH REPUBLIC

Ethylene Glycol

PEL

50



15 50



NPK-P Skin*

100

CROATIA

Ethylene Glycol

MDK

50

125

ROMANIA

Ethylene Glycol

TWA STEL Skin*

SLOVAKIA

Ethylene Glycol

TWA CEILING Skin*

20

52 104

SLOVENIA

Ethylene Glycol

TWA Skin*

20

52

52 104

* A skin notation refers to the potential si gnificant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes.

MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant Ethylene Glycol US NIOSH: 5523 Gas chromatography XAD-7 / Glass fibre filter OVS tube ENGINEERING MEASURES : The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : Wear standard protective clothing. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100




EYE PROTECTION : Wear chemical splash goggles. Wear safety glasses with side-shields. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.

9.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

Liquid

APPEARANCE

Amber

ODOR

Mild

FLASH POINT : SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER pH (100 %) VISCOSITY VISCOSITY VAPOR PRESSURE

105 °C TCC 1.42 (20 °C) 1.4 g/cm3 Complete 3.8 250 cst (20 °C) 360 SUS (15.5 °C) 3.2 kPa (25 °C)

Note: These physical properties are typical values for this product and are subject to change.

10.

STABILITY AND REACTIVITY

STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID : Freezing temperatures. MATERIALS TO AVOID : Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of nitrogen, Oxides of phosphorus

11.

TOXICOLOGICAL INFORMATION

No toxicity studies have been conducted on this product.





SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence, or a different pattern of tumors when compared to untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce chromosomal breakage or mutagenic effects. For additional information on the hazard of the preparation, please consult section 3 and 12.

12.

ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS : No toxicity studies have been conducted on this product. ACUTE FISH RESULTS : Species Exposure Bluegill Sunfish 96 hrs Rainbow Trout 96 hrs Rainbow Trout 96 hrs

LC50 > 1,000 mg/l > 1,000 mg/l > 1,800 mg/l

ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 Daphnia magna 48 hrs

NOEC 1,000 mg/l 1,000 mg/l 1,800 mg/l

Method

Test Descriptor Product Product Product

EC50 > 2,000 mg/l

Method

Test Descriptor Product

MOBILITY : The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air <5%

Water 30 - 50%

Soil/Sediment 50 - 70%

The portion in water is expected to be soluble or dispersible. PERSISTENCY AND DEGRADATION : The organic portion of this preparation is expected to be inherently biodegradable. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100




13.

DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product will generate an ash if burned. It can be burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code. NATIONAL REGULATIONS AUSTRIA : Waste Code :52725 NATIONAL REGULATIONS FRANCE : Waste Code :Relevant.

14.

TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT Proper Shipping Name : AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name :

15.

PRODUCT IS NOT REGULATED DURING TRANSPORTATION PRODUCT IS NOT REGULATED DURING TRANSPORTATION PRODUCT IS NOT REGULATED DURING TRANSPORTATION

REGULATORY INFORMATION

CLASSIFICATION AND LABELLING : This preparation is not regulated, however, we recommend the following safety precautions:





SAFETY PHRASES S24/25 - Avoid contact with skin and eyes. S37/39 - Wear suitable gloves and eye/face protection. NATIONAL REGULATIONS AUSTRIA Danger classification according to VbF: Not Regulated NATIONAL REGULATIONS DENMARK MAL CODE Yes FIRE CLASS Non-regulated. ORGANIC SOLVENTS/VOCS Yes SUSPECT CARCINOGENS No NATIONAL REGULATIONS FRANCE Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Not-applicable. Dangerous or Poisonous Substances and Preparations: Not-applicable. Special medical supervision - Decree of 11 July 1977: Not-applicable. Work Restrictions: Fair labor standards act, Article R234-9 and 10 (women): Not-applicable. Fair labor standards act, Article R234-16, 20 and 21 (young workers): Not-applicable. Fair labor standards act, Decree of the 8/10/90 (temporary work and contract last given): Not-applicable. Classified Industrial Sites (ICPE): Not-applicable. Water Discharge: Relevant. PRODUCT REGISTRATION NUMBER Denmark 1235347 Norway 019853

INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals (REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment. Should you require any further information on Nalco's REACH programme please contact us at [email protected] or visit our website. UNITED STATES The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

16.

OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 2 NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100




R22 - Harmful if swallowed. R36/38 - Irritating to eyes and skin. - REVISED INFORMATION: section(s): -3 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. EMERGENCY TELEPHONE NUMBER(S) Trans-European

+32-(0)3-575-5555

Belgium / Luxembourg Czech Republic Denmark Finland France / French Switzerland Germany / Austria / German Switzerland Hungary Italy / Italian Switzerland The Netherlands Norway Poland Portugal Russia / Belarus Saudi Arabia Slovak Republic Spain Sweden UAE UK and Republic of Ireland Nalfleet International

+32-(0)3-575-0330 +420-602-669421 +47-22-33-69-99 +358-(0)9-4711 +33-(0)6-11-07-32-81 +49-(0)6232-130128 +36-30-9-506-447 +39-333-210-7947 +32-(0)3-575-0330 +47-22-33-69-99 +48-(0)601-66-2626 +351-91-911-1399 +7-812-449-0474 +966-(3)847-1515 +421-(0)905-585-938 +34-977-551577 +47-22-33-69-99 +44-(0)7071-223-738 +44-(0)7071-223-738 +32-(0)3-575-5555

POISON CONTROL CENTER TELEPHONE NUMBERS Belgium Czech Republic France Slovak Republic

+32-70-245245 +420 224 91 92 93 +33-(0)145-42-59-59 ORFILA +421 (0)2 5477 4166

Prepared By : SHE Department Date issued : 03.04.2007 Version Number : 1.12 Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth




PRODUCT NALCO® 780-A EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone N umbers.

1.


PRODUCT NAME :

NALCO® 780-A

APPLICATION :

OXYGEN SCAVENGER






15.06.2006 1.9

COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. NALCO AB (SE) NALCO ANADOLU KIMYA (TR) NALCO APPLIED SERVICES OF EUROPE BV NALCO BELGIUM N.V./S.A. (B) NALCO DANMARK A/S NALCO DEUTSCHLAND GmbH (D)

+32 (0)3-450 69 10 +45-48195800 +49 (0)69-79340

NALCO ESPAÑOLA S.A. (E) NALCO FINLAND OY (FI) NALCO FRANCE SAS

+34 93-4095555 +358 (0)9 2517 4700 +33 (0)3 20 11 70 00

2.

+31 71 5241 100 +46 (0)8-50074000 +90 216 5743464 +31 (0)73 6456980

NALCO ITALIANA S.R.L.(I) NALCO Kft. (HU) NALCO LIMITED

+39 06-542971 +36 (0)1 471 91 81 +44 (0)1606 74488

NALCO NETHERLANDS B.V. NALCO NORGE AS (NO) NALCO ÖSTERREICH Ges.m.b.H. (A) NALCO POLSKA Sp.z.o.o. (PL) NALCO PORTUGUESA LDA. (P) WYSS WASSERTECHNIK AG (CH)

+31 (0)13-5952200 +47 51 96 36 00 + 43(0)1 27026350 +48 (0)32-3262750 +351 214130996 +41 (0)52 235 38 38


This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Hazardous Substance(s) Sodium Bisulfite

EINECS / ELINCS NO 231-548-0

SYMBOL Xn

R-PHRASES / NOTAS R22, R31

% (w/w) 30 - 60


3.


HAZARD CLASSIFICATION : This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Harmful if swallowed. Contact with acids liberates toxic gas. HUMAN HEALTH HAZARDS - ACUTE : INHALATION : Not a likely route of exposure. Contains Sulfite. Causes asthmatic signs and symptoms in hyper-reactive individuals.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • 0031 71 5241100

1 / 11


PRODUCT NALCO® 780-A



SKIN CONTACT : May cause irritation with prolonged contact. EYE CONTACT : May cause irritation with prolonged contact. INGESTION : There may be irritation to the gastro-intestinal tract. Harmful if swallowed. May cause asthmatic-like attack. HUMAN HEALTH HAZARDS - CHRONIC : Ingestion of sulfite can cause a severe allergic reaction in asthmatics and some sulfite sensitive individuals. The resulting symptoms can include difficulty in breathing, flushed skin and a rash. Chronic exposure to sulfites may cause symptoms of upper respiratory disease and affect sense of taste and smell.

4.

FIRST AID MEASURES

INHALATION : Remove to fresh air, treat symptomatically. If breathing is difficult, administer oxygen. Get medical attention. SKIN CONTACT : Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician. EYE CONTACT : Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush with plenty of water for at least 15 minutes. INGESTION : Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5.


FLASH POINT :

None

EXTINGUISHING MEDIA : This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Keep containers cool by spraying with water. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARD : May evolve oxides of sulfur (SOx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.


2 / 11





6.


PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ensure adequate ventilation. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water.

7.


HANDLING : Avoid eye and skin contact. Do not take internally. Do not get in eyes, on skin, on clothing. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Keep the containers closed when not in use. Use with adequate ventilation. STORAGE CONDITIONS : Store separately from oxidizers. Store the containers tightly closed. Store in suitable labeled containers. Amine and sulphite products should not be stored within close proximity or resulting vapors may form visible airborne particles. SPECIFIC USE(S) : OXYGEN SCAVENGER For specific dosages and customized applications please contact your representative.

8.


OCCUPATIONAL EXPOSURE LIMITS Exposure limits are listed for sulfur dioxide (SO 2) since this product evolves SO2 when open to the atmosphere. Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source ____ AUSTRIA

Substance(s) Sulfur Dioxide

Category: MAK MAK CEIL

BELGIUM

Sodium Bisulfite

TWA

Sulfur Dioxide

TWA STEL

Sodium Bisulfite

GV

DENMARK

ppm 2 4

5 2 5


3 / 11



mg/m3 5 10

5.3 13 5



Sulfur Dioxide

GV

FINLAND

Sulfur Dioxide

HTP 8H HTP 15MIN

FRANCE

Sodium Bisulfite

VME

Sulfur Dioxide

VME VLE

2 5

5 10

GERMANY

Sulfur Dioxide

MAK MAK MAK

2 1 0.5

5 2.5 1.3

IRELAND

Sodium Bisulfite

TWA

Sulfur Dioxide

TWA STEL

Sodium Bisulfite

TWA

Sulfur Dioxide

TWA STEL

Sodium Bisulfite

MAC TGG

Sulfur Dioxide

MAC TGG

Sodium Bisulfite

ADM. NORM

Sulfur Dioxide

ADM. NORM

Sodium Bisulfite

VLA-ED

Sulfur Dioxide

VLA-ED VLA-EC

2 5

5.3 13

SWEDEN

Sulfur Dioxide

NGV TGV

2 5

5 13

SWITZERLAND

Sodium Bisulfite (Inhalable dust)

TWA

Sulfur Dioxide

TWA STEL

UNITED KINGDOM

Sodium Bisulfite

TWA

5

POLAND

Sulfur Dioxide

MAC-NDS MACNDSCh

2 5

HUNGARY

Sulfur Dioxide

ÁK CK

5 5

CZECH REPUBLIC

Sulfur Dioxide

PEL NPK-P

CROATIA

Sodium Bisulfite

MDK

Sulfur Dioxide

MDK KDK

ROMANIA

Sulfur Dioxide

TWA STEL

SLOVAKIA

Sulfur Dioxide

TWA

ITALY

NETHERLANDS

NORWAY

SPAIN

0.5

1.3

1 4

2.7 11 5

5 2 5

5 2 5 5 2



5 5

2

5 5

5 0.5 0.5

1.3 1.3

5 10 5 2 5

5 10 5 10

0.5


4 / 11

5 13

1.3



SLOVENIA

Sulfur Dioxide

TWA

0.5

1.3

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes.

MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant Sodium Bisulfite US OSHA: 121 Ion chromatography Cellulose ester filter

Sulfur Dioxide

US NIOSH: 6004

Ion chromatography

Cellulose ester filter treated with Sodium Bicarbonate

ENGINEERING MEASURES : General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are generated. The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: E The applicable European standard can be found in EN 141, EN 143 and EN 371. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : When handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended. A full slicker suit is recommended if gross exposure is possible. The applicable European standard can be found in EN 345. EYE PROTECTION : Wear chemical splash goggles. The applicable European standard can be found in EN 166.


5 / 11





HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Keep an eye wash fountain available. Keep a safety shower available.

9.


PHYSICAL STATE

Liquid

APPEARANCE

Amber

ODOR

Sulfurous

FLASH POINT : SPECIFIC GRAVITY SOLUBILITY IN WATER pH (1 %) VISCOSITY FREEZING POINT BOILING POINT VAPOR PRESSURE

None 1.31 (25 °C) Complete 4.2 6 cps (20 °C) -7 °C 100 °C Same as water 4.26 kPa (28 °C)


10.


STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID : Freezing temperatures. Avoid extremes of temperature. MATERIALS TO AVOID : Bases, Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfi de, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors., Contains Sulfite., SO2 may react with vapors from neutralizing amines and may produce a visible cloud of amine salt particles.Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors., SO2 may react with vapors from neutralizing amines and may produce a visible cloud of amine salt particles. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of sulfur


6 / 11





11.


The following results are for a similar product. ACUTE ORAL TOXICITY : Species LD50 Rabbit 41,000 mg/kg

Test Descriptor Similar Product

ACUTE DERMAL TOXICITY : Species LD50 Rabbit 3,038 mg/kg


PRIMARY SKIN IRRITATION : Draize Score 1.0 / 8.0


PRIMARY EYE IRRITATION : Draize Score 9.4 / 110.0


SENSITIZATION : This product is not expected to be a sensitizer. Sulfites can cause an allergic reaction in sensitive individuals. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). For additional information on the hazard of the preparation, please consult section 3 and 12.

12.


ECOTOXICOLOGICAL EFFECTS : The following results are for the product. ACUTE FISH RESULTS : Species Exposure Bluegill Sunfish 96 hrs Rainbow Trout

96 hrs

LC50 100 - 1,000 mg/l 100 - 1,000 mg/l

Method

Test Descriptor Product Product

ADDITIONAL ECOLOGICAL DATA: Depletes oxygen content in water courses. MOBILITY : The environmental fate was estimated using a level III f ugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of t his product under the NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • 0031 71 5241100

7 / 11





defined conditions of the models. If released into the environment this material i s expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air <5%

Water 30 - 50%


The portion in water is expected to be soluble or dispersible. PERSISTENCY AND DEGRADATION : Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not applicable. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

13.


If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product will generate an ash if burned. It can be burned directly in appropriate equipment. This product is NOT suitable for disposal via municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 03* - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code.

14.


The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Packing Group : ADR/RID H.I.n. : CLASSIFICATION CODE :

BISULFITES, AQUEOUS SOLUTION, N.O.S. Sodium Bisulfite UN 2693 8 III 80 C1

AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : Technical Name(s) : UN/ID No :

BISULPHITES, AQUEOUS SOLUTION, N.O.S. Sodium Bisulfite UN 2693


8 / 11





Hazard Class - Primary : Packing Group : IATA Cargo Packing Instructions : IATA Cargo Aircraft Limit : IATA Passenger Packing Instructions : IATA Passenger Aircraft Limit :

8 III 820 60 L (Max net quantity per package)

MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Packing Group :

BISULPHITES, AQUEOUS SOLUTION, N.O.S. Sodium Bisulfite UN 2693 8 III

OTHER APPLICABLE INFORMATION CEFIC TREMCARD REFERENCE : EMERGENCY ACTION CODE :

80GC1-II+III 2X

15.


CLASSIFICATION AND LABELLING : GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations Directive 1999/45/EC. HAZARD SYMBOLS

HARMFUL Contains:..Sodium Bisulfite RISK PHRASES R22 - Harmful if swallowed. R31 - Contact with acids liberates toxic gas. SAFETY PHRASES S23 - Do not breathe vapor. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of water. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S46 - If swallowed, seek medical advice immediately and show this container or label. NATIONAL REGULATIONS FRANCE Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s): 66 Classified Industrial Sites (ICPE): Not-applicable. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • 0031 71 5241100

9 / 11





NATIONAL REGULATIONS GERMANY WGK 1 (Annex 4) NATIONAL REGULATIONS HOLLAND ABM RESULT ABM RESULT Substance(s) 11 B

% (w/w)

NATIONAL REGULATIONS, USA FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act : When use situations necessitate compliance with FDA regulations, this product is acceptable under : 21 CFR 173.310 Boiler Water Additives Limitations: no more than required to produce intended technical effect. PRODUCT REGISTRATION NUMBER Norway 019388

INTERNATIONAL CHEMICAL CONTROL LAWS UNITED STATES The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations. EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

16.

OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 2 R22 - Harmful if swallowed. R31 - Contact with acids liberates toxic gas. - REVISED INFORMATION: section(s): -3 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.


10 / 11





EMERGENCY TELEPHONE NUMBER(S) Trans-European

+32-(0)3-575-5555

Belgium / Luxembourg Czech Republic Denmark Finland France / French Switzerland Germany / Austria / German Switzerland Hungary Italy / Italian Switzerland The Netherlands Norway Poland Portugal Russia / Belarus Saudi Arabia Slovak Republic Spain Sweden UAE UK and Republic of Ireland Nalfleet International

+32-(0)3-575-0330 +420-602-669421 +47-22-33-69-99 +358-(0)9-4711 +33-(0)6-11-07-32-81 +49-(0)6232-130128 +36-30-9-506-447 +39-333-210-7947 +32-(0)3-575-0330 +47-22-33-69-99 +48-(0)601-66-2626 +351-91-911-1399 +7-812-449-0474 +966-(3)847-1515 +421-(0)905-585-938 +34-977-551577 +47-22-33-69-99 +44-(0)7071-223-738 +44-(0)7071-223-738 +32-(0)3-575-5555


+32-70-245245 +420 224 91 92 93 +33-(0)145-42-59-59 ORFILA +421 (0)2 5477 4166

Prepared By : SHE Department Date issued : 15.06.2006 Version Number : 1.9 Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth


11 / 11


PRODUCT EC9610A


PRODUCT EC9610A EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone N umbers.

1.


PRODUCT NAME :

EC9610A

APPLICATION :

CLEANER






14.03.2006 1.7

COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. NALCO AB (SE) NALCO ANADOLU KIMYA (TR) NALCO APPLIED SERVICES OF EUROPE BV NALCO BELGIUM N.V./S.A. (B) NALCO DANMARK A/S NALCO DEUTSCHLAND GmbH (D)

+32 (0)3-450 69 10 +45-48195800 +49 (0)69-79340

NALCO ESPAÑOLA S.A. (E) NALCO FINLAND OY (FI) NALCO FRANCE SAS

+34 93-4095555 +358 (0)9 2517 4700 +33 (0)3 20 11 70 00

2.

+31 71 5241 100 +46 (0)8-50074000 +90 216 5743464 +31 (0)73 6456980

NALCO ITALIANA S.R.L.(I) NALCO Kft. (HU) NALCO LIMITED

+39 06-542971 +36 (0)1 471 91 81 +44 (0)1606 74488

NALCO NETHERLANDS B.V. NALCO NORGE AS (NO) NALCO ÖSTERREICH Ges.m.b.H. (A) NALCO POLSKA Sp.z.o.o. (PL) NALCO PORTUGUESA LDA. (P) WYSS WASSERTECHNIK AG (CH)

+31 (0)13-5952200 +47 51 96 36 00 + 43(0)1 27026350 +48 (0)32-3262750 +351 214130996 +41 (0)52 235 38 38


This product is classified as dangerous in accordance with the Substance Directive 1967/548/EEC. Hazardous Substance(s) 2-Butoxyethanol

EINECS / ELINCS NO 203-905-0

SYMBOL Xn

R-PHRASES / NOTAS R20/21/22, R36/38

% (w/w) 60 - 100


3.


HAZARD CLASSIFICATION : This product is classified as dangerous in accordance with the Substance Directive 1967/548/EEC. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes and skin. HUMAN HEALTH HAZARDS - ACUTE : INHALATION : Aerosols or product mist may irritate the upper respiratory tract.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • +31 71 5241 100

1 / 11


PRODUCT EC9610A



SKIN CONTACT : May cause irritation with prolonged contact. EYE CONTACT : Can cause moderate to severe irritation. INGESTION : Not a likely route of exposure. Large quantities may cause kidney and liver damage. HUMAN HEALTH HAZARDS - CHRONIC : Contains ethylene glycol monobutyl ether (butoxyethanol). Prolonged and/or repeated exposure through inhalation or extensive skin contact with EGBE may result i n damage to the blood and kidneys. PHYSICAL AND CHEMICAL HAZARDS : Combustible.

4.

FIRST AID MEASURES

INHALATION : Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. SKIN CONTACT : Immediately wash with plenty of soap and water. If symptoms develop, seek medical advice. EYE CONTACT : Get medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids open. INGESTION : Get medical attention. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. If conscious, washout mouth and give water to drink. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5.


FLASH POINT :

71 °C PMCC

LOWER EXPLOSION LIMIT :

1.1 V%

UPPER EXPLOSION LIMIT :

10.6 V%

AUTOIGNITION TEMPERATURE :

244 °C

EXTINGUISHING MEDIA : Dry powder, Carbon dioxide, Water spray, Foam, Other extinguishing agent suitable for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning material. Keep containers cool by spraying with water.


2 / 11


PRODUCT EC9610A



FIRE AND EXPLOSION HAZARD : Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6.


PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water.

7.


HANDLING : Avoid eye and skin contact. Do not take internally. Ensure all containers are labelled. Keep the containers closed when not in use. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Do not use, store, spill or pour near heat, sparks or open flame. STORAGE CONDITIONS : Store the containers tightly closed. Store in suitable labelled containers. Store away from heat and sources of ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be grounded to avoid electrical charges. Store separately from oxidizers. SUITABLE CONSTRUCTION MATERIAL : Teflon, Kalrez, Perfluoroelastomer, TFE, HDPE (high density polyethylene), Aluminum, Mild steel, Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, Hastelloy C-276, MDPE (medium density polyethylene) UNSUITABLE CONSTRUCTION MATERIAL : Copper, Neoprene, Ethylene propylene, Polypropylene, Polyethylene, Nitrile, Plexiglass, EPDM, Alfax, Brass, Nylon, PVC, Buna-N, Natural rubber, Polyurethane, Hypalon, Viton SPECIFIC USE(S) : CLEANER For specific dosages and customized applications please contact your representative. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • +31 71 5241 100

3 / 11


PRODUCT EC9610A



8.


OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source __ AUSTRIA

Substance(s) 2-Butoxyethanol

Category: MAK MAK STEL Skin*

ppm 20 40

mg/m3 98 200

BELGIUM

2-Butoxyethanol

TWA STEL Skin*

20 50

98 246

DENMARK

2-Butoxyethanol

GV Skin* GV Skin*

20

98

20

FINLAND

2-Butoxyethanol

HTP 8H HTP 15MIN Skin*

20 50

98 250

GERMANY

2-Butoxyethanol

MAK Skin*

20

98

IRELAND

2-Butoxyethanol

TWA STEL Skin*

20 50

98 246

ITALY

2-Butoxyethanol

TWA STEL Skin*

20 50

98 246

NETHERLANDS

2-Butoxyethanol

MAC TGG MAC-TGG 15 Skin*

20 50

100 246

NORWAY

2-Butoxyethanol

ADM. NORM Skin*

10

50

SPAIN

2-Butoxyethanol

VLA-ED VLA-EC Skin*

20 50

98 245

SWEDEN

2-Butoxyethanol

NGV KTV Skin*

10 20

50 100

SWITZERLAND

2-Butoxyethanol

TWA STEL Skin*

20 80

100 400

UNITED KINGDOM

2-Butoxyethanol

TWA STEL Skin*

25 50

POLAND

2-Butoxyethanol

MAC-NDS MACNDSCh


4 / 11


PRODUCT EC9610A

98 200



HUNGARY

2-Butoxyethanol

ÁK CK Skin*

98 246

CZECH REPUBLIC

2-Butoxyethanol

PEL NPK-P Skin*

100 200

CROATIA

2-Butoxyethanol

MDK Skin*

ROMANIA

2-Butoxyethanol

TWA TWA STEL STEL Skin*

SLOVAKIA

2-Butoxyethanol

TWA CEILING Skin*

20

98 246

SLOVENIA

2-Butoxyethanol

TWA Skin*

20

98

5

98 150 246 250

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes.

MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant 2-Butoxyethanol US NIOSH: 1403 Gas chromatography Charcoal BIOLOGICAL EXPOSURE INDICES : 2-Butoxyethanol A biological index of exposure to 2-butoxyethanol (CAS 111-76-2) is the detection of butoxyacetic acid in the urine at the end of the work shift (UK, 240mmol/mol creatinine) or at the end of the l ast shift of the working week (Germany, 100mg/l). ENGINEERING MEASURES : General ventilation is recommended. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. The applicable European standard can be found in EN 141, EN 143 and EN 371. Consider the use of filter type: A In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • +31 71 5241 100

5 / 11


PRODUCT EC9610A

25



HAND PROTECTION : When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : Wear standard protective clothing. When handling this product, the use of overalls is recommended. EYE PROTECTION : Wear chemical splash goggles. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

9.


PHYSICAL STATE

Liquid

APPEARANCE

Colorless

ODOR

Glycol Ether

FLASH POINT :

71 °C PMCC

LOWER EXPLOSION LIMIT :

1.1 V%

UPPER EXPLOSION LIMIT : SPECIFIC GRAVITY SOLUBILITY IN WATER VISCOSITY FREEZING POINT BOILING POINT VAPOR PRESSURE VAPOR DENSITY

10.6 V% 0.89 - 0.91 (16 °C) ASTM D-1298 Complete 2.53 cst (38 °C) -71 °C ASTM D-1177 171 °C ASTM D-86 0.1 kPa (20 °C) ASTM D-323 0.06 kPa (20 °C) 1 (Air = 1)


10.


STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur.


6 / 11


PRODUCT EC9610A



CONDITIONS TO AVOID : Heat and sources of ignition including static discharges. MATERIALS TO AVOID : Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or t oxic vapors. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon

11.


No toxicity studies have been conducted on this product. ACUTE ORAL TOXICITY : Species LD50 Rat 470 mg/kg


ACUTE DERMAL TOXICITY : Species LD50 Rabbit 222 mg/kg


ACUTE INHALATION TOXICITY : Species LC50 Rat 7 mg/l (7 hrs)


SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). For additional information on the hazard of the preparation, please consult section 3 and 12.

12.


ECOTOXICOLOGICAL EFFECTS : The following results are for the product. ACUTE FISH RESULTS : Species Exposure Bluegill Sunfish 96 hrs Inland Silverside 96 hrs Mosquito Fish 96 hrs (Gambusia spp.)

LC50 > 1,000 mg/l > 1,000 mg/l > 1,000 mg/l

Method

Test Descriptor Product Product Product


7 / 11


PRODUCT EC9610A



ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 Acartia tonsa 48 hrs 730 mg/l AQUATIC PLANT RESULTS : Species Exposure Marine Algae 72 hrs (Skeletonema costatum)

EC50/LC50 570 mg/l (EC50)

EC50

Method

Method



MOBILITY : The environmental fate was estimated using a level III f ugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of t his product under the defined conditions of the models. If released into the environment this material i s expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air <5%

Water 50 - 70%


The portion in water is expected to float on the surface. PERSISTENCY AND DEGRADATION : The organic portion of this preparation is expected to be readily biodegradable. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

13.


If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. This product is suitable for disposal in an approved landfill or by controlled incineration. This product is ashless and can be burned directly in appropriate equipment. This product is NOT suitable for disposal via municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code.


8 / 11


PRODUCT EC9610A



14.


The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT Proper Shipping Name : AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name :

15.

PRODUCT IS NOT REGULATED DURING TRANSPORTATION PRODUCT IS NOT REGULATED DURING TRANSPORTATION PRODUCT IS NOT REGULATED DURING TRANSPORTATION



HARMFUL Contains:..2-Butoxyethanol RISK PHRASES R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/38 - Irritating to eyes and skin. SAFETY PHRASES S36/37 - Wear suitable protective clothing and gloves. S46 - If swallowed, seek medical advice immediately and show this container or label. NATIONAL REGULATIONS GERMANY WGK 1 (Annex 4)


9 / 11


PRODUCT EC9610A



NATIONAL REGULATIONS HOLLAND ABM RESULT ABM RESULT Substance(s) 11

% (w/w)

NATIONAL REGULATIONS NORWAY YL code: 5 (> 3200 M³/L) PRODUCT REGISTRATION NUMBER Norway 019505

INTERNATIONAL CHEMICAL CONTROL LAWS UNITED STATES The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations. EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or E LINCS inventories., The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).

16.

OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 2 R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/38 - Irritating to eyes and skin. This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. EMERGENCY TELEPHONE NUMBER(S) Trans-European

+32-(0)3-575-5555

Belgium / Luxembourg Czech Republic Denmark Finland France / French Switzerland

+32-(0)3-575-0330 +420-602-669421 +47-22-33-69-99 +358-(0)9-4711 +33-(0)6-11-07-32-81


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PRODUCT EC9610A



Germany / Austria / German Switzerland Hungary Italy / Italian Switzerland The Netherlands Norway Poland Portugal Russia / Belarus Saudi Arabia Slovak Republic Spain Sweden UAE UK and Republic of Ireland Nalfleet International

+49-(0)6232-130128 +36-30-9-506-447 +39-333-210-7947 +32-(0)3-575-0330 +47-22-33-69-99 +48-(0)601-66-2626 +351-91-911-1399 +7-812-449-0474 +966-(3)847-1515 +421-(0)905-585-938 +34-977-551577 +47-22-33-69-99 +44-(0)7071-223-738 +44-(0)7071-223-738 +32-(0)3-575-5555


+32-70-245245 +420 224 91 92 93 +33-(0)145-42-59-59 ORFILA +421 (0)2 5477 4166

Prepared By : SHE Department Date issued : 14.03.2006 Version Number : 1.7 Numbers quoted in the MSDS are given in t he format: 1,000,000 = 1 million and 1,000 = 1 thousand


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PRODUCT


PRODUCT

NALCO® EC6527G EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

1.


PRODUCT NAME :

NALCO® EC6527G

APPLICATION :

BIOCIDE






16.11.2006 1.0

COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. NALCO AB (SE) NALCO ANADOLU KIMYA (TR) NALCO APPLIED SERVICES OF EUROPE BV NALCO BELGIUM N.V./S.A. (B) NALCO DANMARK A/S NALCO DEUTSCHLAND GmbH (D) NALCO ESPAÑOLA S.A. (E) NALCO FINLAND OY (FI)

+31 71 5241 100 +46 (0)8-50074000 +90 216 5743464 +31 (0)73 6456980

NALCO NORGE AS (NO) NALCO POLSKA Sp.z.o.o. (PL) NALCO PORTUGUESA LDA. (P) NTD S.r.l (IT)

+47 51 96 36 00 +48 (0)32-3262750 +351 214130996 +39 (0) 313351325

+32 (0)3-450 69 10 +45-48195800 +49 (0)69-79340 +34 93-4095555 +358 (0)9 2517 4700

+41 (0)56 4606260 +41 (0)41 760 2220 +41 (0)52 235 38 38 +7 (0)495 980 72 80 + 43(0)1 27026350

NALCO FRANCE SAS

+33 (0)3 20 11 70 00

NALCO HELLAS S.A. (GR)

+30 210 238 9620

NALCO ITALIANA S.R.L.(I)

+39 06-542971

NALCO LIMITED

+44 (0)1606 74488

CHEMIA BRUGG AG (CH) OEKOPHIL AG (CH) WYSS WASSERTECHNIK AG (CH) ZAO Nalco (RU) NALCO ÖSTERREICH Ges.m.b.H. (A) local support: Nalco Czechia s.r.o. (CZ) Local Support: Nalco Hungary Kft. (HU) Local Support: Nalco Österreich Ges.m.b.H., Representation Office Predstavnistvo Zagreb (HR) Local Support: Nalco Österreich Ges.m.b.H. Representation Office ROMANIA (RO)

NALCO NETHERLANDS B.V.

+31 (0)13-5952200

2.

+420 (0)2 679 123 50 +36 (0)1 471 91 81 +385 (0)1 377 95 21 +40 (0) 21 224 17 93


This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Hazardous Substance(s) Tetrakis(hydroxymethyl) phosphonium sulfate Polymer containing phosphonate, sulphonate, and carboxyl functional groups, sodium salt

EINECS / ELINCS NO 259-709-0 Polymer

SYMBOL T, N

R-PHRASES / NOTAS R23, R22, R41, R43, R63, R50 R52/53

% (w/w) 30 - 60


3.


HAZARD CLASSIFICATION : This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100

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PRODUCT


Harmful if swallowed. Toxic by inhalation. Risk of serious damage to eyes. May cause sensitization by skin contact. Very toxic to aquatic organisms. Possible risk of harm to the unborn child. HUMAN HEALTH HAZARDS - ACUTE : INHALATION : Not a likely route of exposure. Toxic by inhalation. SKIN CONTACT : May cause irritation with prolonged contact. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. EYE CONTACT : Severely irritating. If not removed promptly, will injure eye tissue and may result in permanent eye damage. INGESTION : Not a likely route of exposure. Harmful if swallowed. ENVIRONMENTAL HAZARDS : Keep out of waterways. This product may pose a risk to the aquatic ecosystem if released.

4.

FIRST AID MEASURES

INHALATION : Get immediate medical attention. Remove to fresh air, treat symptomatically. SKIN CONTACT : Seek medical advice with urgency. For a large splash, flood body under a shower. Immediately wash with plenty of soap and water. If symptoms develop, seek medical advice. EYE CONTACT : Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. INGESTION : Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5.


FLASH POINT :

None

EXTINGUISHING MEDIA : This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire.


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PRODUCT


FIRE AND EXPLOSION HAZARD : May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6.


PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Prevent material from entering sewers or waterways. Spilled product may pose a risk to the aquatic ecosystem if released. If drains, streams, soil or sewers become contaminated, notify local authority.

7.


HANDLING : Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. STORAGE CONDITIONS : Store in suitable labeled containers. Store the containers tightly closed. SUITABLE CONSTRUCTION MATERIAL : Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use., Stainless Steel 304, Stainless Steel 316L, TFE, Nitrile, Neoprene, Viton, EPDM, FEP (encapsulated), PTFE, MDPE (medium density polyethylene), HDPE (high density polyethylene) UNSUITABLE CONSTRUCTION MATERIAL : Carbon Steel C1018 SPECIFIC USE(S) : BIOCIDE For specific dosages and customized applications please contact your representative.


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PRODUCT


8.


OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source __

Substance(s) Tetrakis(hydroxymethyl) phosphonium sulfate

Category: TWA

ppm

mg/m3 2

* A skin notation refers to the potential significant c ontribution to overall exposure by the cutaneous route, including mucous membranes and the eyes.

ENGINEERING MEASURES : The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from Nitrile . Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN ISO 20345. EYE PROTECTION : Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100

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PRODUCT


ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS : Consider the provision of containment around storage vessels.

9.


PHYSICAL STATE

Liquid

APPEARANCE

Clear

ODOR

None

FLASH POINT : SPECIFIC GRAVITY SOLUBILITY IN WATER pH ()

None 1.24 (15.5 °C) Complete 4.0


10.


STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID : Avoid extremes of temperature. MATERIALS TO AVOID : None known HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon, Oxides of sulfur, Oxides of phosphorus

11.


No toxicity studies have been conducted on this product. SENSITIZATION : Repeated or prolonged contact may cause skin sensitization. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). For additional information on the hazard of the preparation, please consult section 3 and 12.


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PRODUCT


12.


ECOTOXICOLOGICAL EFFECTS : No toxicity studies have been conducted on this product. MOBILITY : The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air <5%

Water 10 - 30%


The portion in water is expected to be soluble or dispersible. PERSISTENCY AND DEGRADATION : The organic portion of this preparation is expected to be readily biodegradable. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

13.


If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code.

14.


The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.


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PRODUCT


LAND TRANSPORT Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Packing Group : ADR/RID H.I.n. : CLASSIFICATION CODE :

TOXIC LIQUID, ORGANIC, N.O.S. Tetrakis(hydroxymethyl) phosphonium sulfate UN 2810 6.1 III 60 T1

AIR TRANSPORT (ICAO/IATA) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Packing Group : IATA Cargo Packing Instructions : IATA Cargo Aircraft Limit : IATA Passenger Packing Instructions : IATA Passenger Aircraft Limit :

TOXIC LIQUID, ORGANIC, N.O.S. Tetrakis(hydroxymethyl) phosphonium sulfate UN 2810 6.1 III 618 220 L (Max net quantity per package) Y611 / 611 2 L / 60 L

MARINE TRANSPORT (IMDG/IMO) Proper Shipping Name : Technical Name(s) : UN/ID No : Hazard Class - Primary : Packing Group :

TOXIC LIQUID, ORGANIC, N.O.S. Tetrakis(hydroxymethyl) phosphonium sulfate UN 2810 6.1 III

OTHER APPLICABLE INFORMATION CEFIC TREMCARD REFERENCE : EMERGENCY ACTION CODE :

61GT1-III 2X

15.



TOXIC Contains:..Tetrakis(hydroxymethyl) phosphonium sulfate RISK PHRASES R22 - Harmful if swallowed. R23 - Toxic by inhalation. NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100

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R41 - Risk of serious damage to eyes. R43 - May cause sensitization by skin contact. R50 - Very toxic to aquatic organisms. R63 - Possible risk of harm to the unborn child. SAFETY PHRASES S23 - Do not breathe .. (gas/fumes/vapor/spray). S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories

16.

OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 2 R22 - Harmful if swallowed. R23 - Toxic by inhalation. R41 - Risk of serious damage to eyes. R43 - May cause sensitization by skin contact. R50 - Very toxic to aquatic organisms. R63 - Possible risk of harm to the unborn child. This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. EMERGENCY TELEPHONE NUMBER(S) Trans-European

+32-(0)3-575-5555

Belgium / Luxembourg Czech Republic Denmark Finland France / French Switzerland Germany / Austria / German Switzerland Hungary Italy / Italian Switzerland The Netherlands Norway Poland Portugal

+32-(0)3-575-0330 +420-602-669421 +47-22-33-69-99 +358-(0)9-4711 +33-(0)6-11-07-32-81 +49-(0)6232-130128 +36-30-9-506-447 +39-333-210-7947 +32-(0)3-575-0330 +47-22-33-69-99 +48-(0)601-66-2626 +351-91-911-1399


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7.1 MSDS Complete.pdf

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