UNI NI VERS RSI DADE DE ESTADUA UAL DO SUDO DOESTE DA BAHI HI A DEPART RTAME MENTO DE QUÍ UÍ MI CA E EXATAS CUR URSO DE DE EXT XTENSÃO: O:EXT XTRA RAÇÃO DE ÓL ÓLEOS ESSENCI CI AI S DOCEN ENTE: E:BARA RAQU QUIZI O BRA RAGA GA
CONTROLE DE QUALIDADE DOS ÓLEOS ESSENCIAIS
DAISE PORTO EMANUELA MOTA GÉSSICA COSTA SAYONARA SAYONARA CARIBÉ CARI BÉ UANDERSON SILVA
JEQUIÉ, BAHIA OUTUBRO DE 2014
Su má r i o-2
SUMÁRIO SUMÁRIO........................................................................................................................................ 2 1.0.
INTRODUÇÃO E JUSTIFICATIVA........................................................................................ 3
2.0.
OBJETIVOS.......................................................................................................................... 5
3.0.
METODOLOGIA...................................................................................................................
4.0.
RESULTADOS E DISCUSSÃO.............................................................................................!
5.0.
CONCLUSES................................................................................................................... 11
!.0.
REFER"NCIAS................................................................................................................... 12
Introdução - 3
1.0. INTRODUÇÃO H" #$% &'%()* )+*'-+)%)* )* /%(%- $*)++(%+- %'$"+%- ')#'%- )* /**--*(+%+-. E-*- - +- )* '$6(+- 7#* %8#)%$ %- /%(%- ( '*-+$*(, '*9 ('% %'%-+%- * /+(+:%9 * - *;'%<)- )* /%(%- %'%=- )% =(+% )* %''%-* % %', (% &'%()* $%+'+% )%- *:*-, %--+$ $ %$>=$ */% '*(-%&*$ ) *'+%' )* ?'#- <'+- 7#*, ( B'%-+/, )$+(%$ $*'%) )* *;'%9. S $-- '+(+%/$*(* )* $( * -*-7#+*'*(- * )* ?*(+/'%(+)*-, $*%>/+-, 7#* (?*'*$ -#%- %'%*'<-+%- '&%(/=+%-. @/'*-, ?/%-, %-%-, '+:$%- * ?'#- - $%='+%-'+$%- %'% -#% ')#9, % *;*$/ )- /*- *--*(+%+- )* '-%-, *#%/+, %(*/% * /%'%(8%, '*-*+%$*(*. N #$'*$ %*(%- ?#(9*- *'%#+%-, $%- %$>=$ - %$/%$*(* %/+%)- #/+("'+%, *'?#$%'+%, -$=+%, *('* #'-. O #- '*-*(* )%- -#>-(+%- *;'%<)%- )%- /%(%-, %'% #- )* ?+*'"+-, ' *;*$/, ' #$% &'%()* ?%+;% )% #/%9 >'%-+/*+'%, ( *$ -*() %$%(%) ) ('/* )* 7#%/+)%)* )*--%- )'&%- *&*%+-, *, $#+%- *:*-, % %#*(++)%)* )* $#+%- /%(%- #-%)%- = )#+)-%. D*+- )* -*%-, "'+%- /%(%- ( - ?%+/$*(* '*(*+)%-, $*-$ ' *-*+%/+-%-, )*+) - -*$*/%(9%- $'?/&+%-. N %- )* /*-, '>/*$% = %+()% $%+- &'%*. P%'% 7#* #$ /* *--*(+%/ -*8% #+/+:%), (**--+%-* 7#* $*-$ %'*-*(* 7#%/+)%)*. Q#%( % *-* 7#*-+, - $*-$%'*-*(%$ ?'*7#*(*$*(* )*?++(+%, )*+) %'+%>+/+)%)* )% -#% $-+9, ()+9*- %$>+*(%+- * %)#/*'%9. O- /*- *--*(+%+-, %/=$ )* )*'*$ -?'*' '%(-?'$%9*- 7#<$+%- )#'%(* %'$%:*(%$*(, )*$ -*' %)#/*'%)- $ #'- /*-, +(/#-+* )* *-=+*- %?+(-. P' +-- = ?#()%$*(%/ 7#* -* (*9% % (-+#+9 7#<$+%, %?+$ )* 7#* --%$ -*' )*-*(/+)- $=)- %(%/<+- )* ('/* )* 7#%/+)%)*. U$% )%- %("/+-*- #+/+:%)%%'% *'+?+%' *-% 7#%/+)%)* '*?*'*-* - %'%*'<-+%- '&%(/=+%-, $ ' * )'. O- $%+- <+- ?%'*- 7#* )*$ $'$**' %- ''+*)%)*- * 7#%/+)%)* )/*- *--*(+%+- -F % %'+%>+/+)%)* &*(=+%, % +)%)* ) $(*(* )* ()* -* ?%'" % *;'%9, %- ()+9*- %$>+*(%+-, + )* $%(*8 ?/'*-%/ * - $=)- #+/+:%)- %'% %$-'%&*$ )%- ?/%-, - '*--- )* *;'%9 * %("/+-* ) /*.
Introdução - 4
A %#-(+% )% 7#%/+)%)* )* #$ /* *--*(+%/ )* %%''*%' (-*7#(+%(*&%+%- %'% % -%)* ) #-#"'+ *, '%(, *-*+%/ %*(9 )** -*' '*-*'%)% % *--* + )* '>/*$%. N'$%/$*(*, - $=)- #+/+:%)- %'% ?%/-+?+%9 )*--*/*-, -F %)+9 )* $-- -+(=+- )* >%+; '*9, $+-#'% ) /* *--*(+%/ $ #'- /*- )% $*-$% *-=+*, '=$, )* 7#%/+)%)* +(?*'+' %#$*(%() '*()+$*(, )+/#+9 *$ #$ *<#/ $ #$ /* %''*%)' #+/+:%) %'% )+/#+' /* *--*(+%/.
CONTROLE DE QUALIDADE E NORMAS DE E#TRAÇÃO DOS ÓLEOS ESSENCIAIS. 1$ F%&'()* +,) %-&)(% '* /-)'* )**)%* A $-+9 )* #$ /* = )**'$+(%)% */% *-=+* *&*%/ 7#* ')#: * */% %'* ) *&*%/ *$ 7#* -* *(('% ?/%-, %-%, -*$*(*-, *. * )* %'+%'F P*/ *-"&+ )* )*-*(/+$*( )% *-=+*F % (*('%9 )* %)% #$ )(-+#+(*- ) /* *--*(+%/ )* %'+%' )#'%(* )*-*(/+$*( ) *&*%/, ( *(' Coriandum sativum L., ' *;*$/, *' )* /+(%// * 50 $%+' (- ?'#-*- ) 7#* (- *')*-K % %$$+/% Matricaria recutita 7#%() /+)% */% $%(, %'*-*(% $%+' *' *$ %/?%>+-%>//, -*# '+(+%/ '+(<+ %+ $ %(++(?/%$%'+. P'=$ -* /+)% % ?+$ )% %')*, %'*-*(%'" -$*(* *-<&+-. •
P*/%- ()+9*- %$>+*(%+-F *$*'%#'%, #$+)%)* '*/%+%, *$ )* *;-+9 % -/ * *(- %?*%$ - *&*%+- #8% %'* 7#* (=$ $%+- *;*'(%- $ %- ?/%- * ?/'*-, $ *;*$/ *$- /* )* $*(% Mentha ; piperita L. 7#* = ')#:+) *$ $%+' 7#%(+)%)* 7#%() - )+%-K •
P*/%- ()+9*- )* /*+%F &*'%/$*(*, )** -*' >*$ *) */% $%(, +- %/' ) -/ )* /*%' % *')%- 7#%(+%+%-. O +/%(&#*+/%(&#* Canada odorata = /+) >*$ *) +- %'*-*(%$ $%+' *' )* /*- *--*(+%+-. Rosa centifolia * R. damascena, - -#>$*+)%- % '*-- )* *;'%9 #+/+:%() %- =%/%- ?'*-%-, #'%- *-=+*- $ :+$>' Juniperus comumnis (**--+%$ 7#* -*#- ?'#- -*8%$ )*-+)'%%)-. •
P*/% ?'$% )* >*(9F $=) )* *;'%9 %'+% (?'$* % /%/+:%9 ) /* *--*(+%/ (% /%(% * $ + )* #- $*)++(%/, %/+$*(%', -$=+. O- $=)$%+- #+/+:%)- -F •
E(?/'%9 *;'%9 ) /* )%- =%/%- )* ?/'*- )* /%'%(8*+'% * '-%-, 7#* - /%)%- ->'* #$% %$%)% )* &')#'% )#'%(* #$ *'<) )* *$, %- - -#>-+#<)%- ' #'%-, 7#%() % &')#'% *-+*' -%#'%)% */% = '%%)% $ "// %'% '*+'%' /* *--*(+%/. •
Introdução - 5
P' %''%-* $ %' )"&#%F /* = %''%-%) */ %' * )*+- -*%'%). A "&#% 7#* '*-#/% = (*+)% $ +)'/%. •
E;'%9 $ -/*(*F %- /%(%- - /%)%- *$ #$ %$>' $ -/*(*, 7#* )+--/* /*, )*+- )* ?+/'%)% % -/#9, */% = (*('%)% * )*-+/%)% %= % >*(9 ) /* #'. •
P'*(-%&*$F +()+%) %'% >*(9 )* /* )* ?'#- <'+-, %- %-%- - '*(-%)%%= -/%' /*, % %$%)% -#*'?++%/ = -*%'%)% * )*+- )*-+/%)%. •
E;'%9 ' )+;+) )* %'>( -#*''<+F = % ?'$% $%+- *?++*(*, CO 2 -> %/% '*-- '(%-* /<7#+) * /* -* )+--/* (*/*, )*+- % '*'(%' % '*-- ('$%/ */* -* '(% &"- * *$-* /* #'. •
2$ A,-&)(%' ) 6%-*6%' ) /-)'* )**)%* A %#-(+% )* 7#%/+)%)* )* #$ /* *--*(+%/ )* %%''*%' (-*7(+%(*&%+%- %'% % -%)* ) #-#"'+ *, '%(, *-*+%/ %*(9 )** -*' '*-*'%)% % *--* + )* '>/*$%. T++%$*(*, - -*&#+(*- '*)+$*(- - #-%)- %'% ?%/-+?+%' /*- /"*+-F
A)+9 )* $-- -+(=+-, )* >%+;- '*9- )+?*'*(*- # +&#%+-K M+-#'% ) /* *--*(+%/ $ #'- /*- )% $*-$% *-=+* )* 7#%/+)%)* +(?*'+', %#$*(%() '*()+$*(K D+/#+9 *$ #$ *<#/, &*'%/$*(* #$ /* %''*%)' #+/+:%) %'% )+/#+' /*-.
3$ C,%'* % %+,*' ) /-)'* )**)%* O- /*- *--*(+%+- - ?--*(-<*+- '%( ( )**$ -*' %)7#+'+)- *$ *$>%/%&*$ '%(-%'*(*-, +- *$ (% $ % /#: ;+)%-* $ ?%+/+)%)*, *')*() *( -#%- ''+*)%)*- *'%#+%-. A -*' %)7#+'+) )** *-%' (-*'%) *$ ?'%-)* ' $>%' $%+- $#$ # %:#/ >%/. R%'%$*(* - /*- *--*(+%+- --#*$ '*- ?'*-, -* +- ''*' = '7#* ?'%$ %)++(%)- '%(*-. O /* )* %$$+/% %'*-*(% /'%9 %:#/%)%, %)++(%()-* %:#/*(. O- /*- )* %(&*'+(%, /%'%(8% * '=&%( $ % ' %/%'%(8%)%, - /*- )* %#/+, %-% )* %(*/% * *+*' % ' $%''$ * *)' )* H+$%/%+% * % >*'&%$% % ' *-*')*%)%. A $%+'+% )- /*- %'*-*(% '*- 7#* %/=$ ) '%(-%'*(* * ) %$%'*/ /%'. T) /* *--*(+%/ %'*-*(% )' %'%*'<-+ * ')#- $ *+'- %/*'%)-, $ )' )* "// # /* #+/+:%) (% $+/, &+'%--/ *- %)#/*'%)- # *$ )*$-+9 * ( )**$ -*' #+/+:%)-. C%- /* *--*(+%/ *(% )+/#<), ' -*'
Introdução - 6
$#+ %', $ /* )* '-%-, )** -*' +(?'$%)% (% *$>%/%&*$, % (*('%9 ) /* *--*(+%/ ( /* %''*%)'. /*- (%#'%+- *$ #- -#*'+' * %$>=$ % 7#%/+)%)* %- /*- -+(=+-. A %'+%9 ) '*9 )* #$ /* *--*(+%/ )**()* %$>=$ ) *' )* /* 7#* % *-=+* %'*-*(% * (-*7#*(*$*(* -*# '*()+$*( )#'%(* '*-- *;'%+. P' *;*$/, %'% (-*&#+'-* 1 /+' )* /* )* Eucaliptus globulus, - (**--"'+- %';+$%)%$*(* )* 30& )* ?/%-. P' #' /%), %'% (-*&#+'-* % $*-$% 7#%(+)%)* )* /* )* '-%-, #+/+:%$-* )* 1 % 3 (*/%)%- )* =%/%-, 7#* *7#+%/* % 1 *%'* )* /%(%9 )* '-%-. O- /*- (%#'%+- )#'%$ $%+- *$ (% */*, 7#%() *$'*&%)- $ *'?#$*- # 7#%() #+/+:%)- (% $%--%&*$, ('"'+ %- -+(=+- 7#* ( *'$%(**$ - *:*$%+- ) 7#* #%- '%-. A %)7#+'+' #$ /* *--*(+%/ )**-* *'+?+%' -#% '*)(+% * % +)(*+)%)* ) ?'(**)' - *:*- ( '#/ )* (-%' ($* +*(., -* ?' )% E-%(%, Lippia graveolens H. B. ., -* ?' ) M=;+, # )* Origanum onites L., -* ?' )% T#'7#+% BRUNETON, 13K % %'* #-%)%, ' *;*$/, )% %-% )% %(*/% %'*-*(% $%+' (*('%9 *$ %/)*<) 5, -#>-(+% 7#* )* %#-%' 7#*+$%)#'%- (% */* * 7#* *$ %9 -#)'
4$ C,%'* % A(%7)%8) D* %') $ HUDSON 1, % %/+)%)* )% $%+'+% )- /*- = )* )+- %(-, <'+- )**$ -*' #-%)- %= #$ %( % %'+' )* -#% )%% )* ?%>'+%9, 7#%() )+/#<)*$ /*- %''*%)'*-, -#% %/+)%)* = )* %/&#(- $*-*- )**-* >-*'%' %/*'%9*- (% /'%9 * ( )'. A )**'+'%9 )* #$ /* *--*(+%/ '*)#: -*# %/' $*'+%/, #$ ?*(6$*(. P%'% &%'%(+' % 7#%/+)%)* ) ')#, )**$ -*'F &#%')%)- *$ ?'%-- )* *7#*( /#$*, *$ *$>%/%&*(- (*#'%-, % $%+- $#$ = +)' $>%' + I # )* >'-+/+%, $/*%$*(* *+- * *'$*+%$*(* ?*%)-K •
•
'#/%)-, +()+%() % ''9 )% )+/#+9, % )%% *$ 7#* ''*# * +K
Introdução - 7
)**$ -*' *-%)- *$ >%+;%- *$*'%#'%-, 7#%() %'$%:*(%)- ' /(& *$, )*() -/+)+?+%' $%- /%' % *-%) /<7#+) 7#%() *$ *$*'%#'% %$>+*(*. P%'% #- )+"'+ &#%')%' *$ /%/ ?'*- 1!C. •
O- '*++*(*- /"-+- %'*-*(%$ '>/*$%- )* *'$*%>+/+)%)* * %)-'9 )$(*(*- )- /*- *--*(+%+-. A/=$ )+--, /"-+ *)* -#>-(+%- %'% /*.
5$ T'9%) O- /*- *--*(+%+- - ')#- )* *;'%9 )* #$% *-=+* *&*%/ * '%( $%+(*('%)-, %'*-*(%$ ;++)%)* $%+- */*%)% 7#* % )% /%(% )* '+&*$ SIMES, 1. O #- %>#-+ * -*$ '+*(%9 ( = %(-*/%). A ;++)%)* )* -*' %&#)% # '6(+% * %+()% )* *;+-+' %$>=$ % +(*'%9 $*)+%$*(-% *('* - +($*'$(*(*- ) /* $ *'- $*)+%$*(- #+/+:%)- */ +()+<)#. O &'%# )% ;++)%)* )**()*'" )% )-* #+/+:%)% )* /* *--*(+%/, *$ %/&#(- %->%+;%- )-%&*(- %%''*%$ +(;+%9*- )*+) % -*(-+>+/+)%)* +()++)#%/, '%() )*-)* -*(-+>+/+:%9 (#$ '+$*+' (% *;*$/F /* )* %(*/%, %/*'&+%- ' (% (-*#+- * '*%9*- )* ?--*(-+>+/+)%)* *;*$/F /* )* >*'&%$% 7#* (=$ ?#'#$%'+(% %= '>/*$%- $%+- &'%*-, '+(+%/$*(* 7#%() #+/+:%)- ' +% '%/. A/&#(- /*- '+- *$ #8(% /-(% * -"/+%, ?*((% ?#(, (?'% - (*#';+*$ %/%- )-*-, )*() '%' (#/-*-, )+-'>+--*(-'+%+-. C#+)%)-F
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
!$ R)8,-%)&' :%(% )&6%' ) /-)'* )**)%* ' ;<&' REAC= N') ', ',&(' )&6%'( % *,<*&%%
Introdução - 8
N$* )* %') $ % ($*(/%#'% IUPAC, # #' ($* 7#<$+ +(*'(%+(%/K O#'- ($*- ($* '++%/, $*'+%/, %>'*+%#'%-K EINECS # ELINCS -* )+-(<*/K N$* * (#$*' CAS -* )+-(<*/K O#' )+& )* +)*(+?+%9 -* )+-(<*/.
I6'(%>)* ()-%'%%* ' % 6'(,-% '-),-%( ) )*&(,&,(%- ) %% *,<*&%%.
@'$#/%- $/*#/%' * *-'##'%/ +(/#+() $ (%9*- S$+/*-, -* )+-(<*/K I(?'$%9 ->'* % %++)%)* +% * ->'* % '%: <+% ) *-='*+-$*'- -* %/+"*/ * %''+%)K P*- $/*#/%' * &%$% )* *-- $/*#/%'*-K
C':'*' ) %% *,<*&?%
G'%# )* #'*:%K N%#'*:% )%- +$#'*:%-, +(/#+() +-$*'- * -#>')#-K P*'*(%&*$ %'% +$#'*:%- '+(+%+-K N%#'*:% * ')*$ )* &'%()*:% )* ...$... )* 7#%+- 7#*' %)++- *$ &*'%/ %&*(*- *-%>+/+:%)'*- # +(+>+)'*-K D%)- *-*'%+- UV,IR,NMR,MS C'$%&'%$%- HPLC, GPCK D*-'+9 )- $=)- %(%/<+- # '*?*'(+%- >+>/+&'"?+%- %''+%)%- %'% +)*(+?+%9 )% -#>-(+% *, -* %''+%) %'% +)*(+?+%9 )* +$#'*:%- * %)++-. A +(?'$%9 *'" 7#* -*' -#?++*(* %'% % '*')#9 )- $=)-.
Obj et i v os-9
2.0. OBJETIVOS A%/+%' 7#%+- ''+*)%)*- ?<-+7#<$+%-, >+/&+%- * ?%'$%/&+%- - $(+'%)%- )* #$ $) &*'%/ (- /*- *--*(+%+-K A(%/+-%' 7#%/ % +$'(+% )*--* $(+'%$*(K P*-7#+-%' - %'$*'- +$'%(*- %'% ('/* )* 7#%/+)%)* ) /* *--*(+%/ )% %(*/% )* */.
Metodologia - 10
3.0. METODOLOGIA A $*)/&+% %'% % */%>'%9 ) '*-*(* '%>%/ ?+ >%-*%)% (% *-7#+-% '*%/+:%)%
$
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Re sul t a dosedi s c us s ão-1 1
4.0. RESULTADOS E DISCUSSÃO A- % '*%/+:%9 )% *-7#+-%, )*: %'+&- ?'%$ *(('%)-, *-*- ?'%$ %(%/+-%)- * +( ?'%$ -*/*+(%)- %'% -*'*$ #+/+:%)- (% */%>'%9 ) '%>%/.
Re s ul t a do sed i s c u s s ão- 12
Co nc l u s õ es-1 3
5.0. CONCLUSES
Ref er ênc i as-14
!.0. REFER"NCIAS 1. . A*-- *$F 04Z-**$>'Z2014. 2.
