Formulation Isp

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Table of Contents

1.

Overview of HI&I Cleaning Formulary

2.

ISP Products & Properties in HI&I Cleaning

3.

Hand Soap Formulations 3.10

4.

Laundry Formulations 4.10 4.11 4.20 4.21 4.30 4.40 4.41 4.50

5.

Liquid Hand Soap

Laundry Pre-spotter Laundry Pre-spotter & Stain Remover Liquid Laundry Detergent (clear & non-builder) Heavy Duty Liquid Laundry Detergent Powder Laundry Detergent (Color-Safe) Laundry Detergent Tabs (Formula #1) Laundry Detergent Tabs (Formula #2) Fabric Softener (3 Formulations)

Dishwashing Formulations 5.10 5.11 5.12 5.15 5.20 5.30 5.50 5.51

Manual Liquid Dishwash Detergent Liquid Dishwash Detergent (Formula #1) Liquid Dishwash Detergent (Formula #2) Ecological Liquid Dishwash Detergent Automatic Dishwash Liquid Detergent Dishwash Detergent Tabs Automatic Dishwash Rinse-Aid (Formula #1) Automatic Dishwash Rinse-Aid (Formula #2)

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6.

Household Cleaning Formulations 6.10 Multipurpose Hard Surface Cleaner 6.20 Multipurpose Alkaline Degreaser 6.21 Kitchen Disinfectant Cleaner 6.22 Kitchen Degreaser (Formula #1) 6.23 Kitchen Degreaser (Formula #2) 6.24 Kitchen Degreaser (Formula #3) 6.25 Oven Cleaner 6.26 Kitchen Cleaning Wipes 6.30 Glass Cleaner (Formula #1) 6.31 Glass Cleaner (Formula #2) 6.32 Glass Cleaning Wipes 6.40 Bathroom Cleaner (Formula #1) 6.41 Bathroom Cleaner (Formula #2) 6.42 Toilet Bowl Cleaner 6.50 Floor Cleaner 6.51 Floor Polish (2 Formulations) 6.52 Carpet Cleaner 6.53 Machine Carpet Cleaner 6.55 Silicone Furniture Polish 6.60 Windscreen Cleaner 6.70 Air Freshener (Formula #1) 6.71 Air Freshener (Formula #2 – Poppy Fragrance)

7.

Industrial & Institutional Cleaners 7.10 7.11 7.12 7.13 7.20 7.30

8.

Car Wash Shampoo Car Wash & Wax Cleaner High Gloss Tire Wax Liquid Car Polish Alkaline Grill Cleaner Metal Cleaner

Appendix A: Summary of Chemical Functionalities

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1. Overview of HI&I Cleaning Formulation Guide This guide is a collection of HI&I (Household, Industrial & Institutional) cleaning formulations developed by several ISP scientists over the last 10 years. The main purpose of these formulations was to prepare and test different types of cleaners in order to measure the benefits of various ISP specialties in many diverse HI&I applications. Thus, most formulations were developed and tested to measure specific properties and features, without any attempt to have a complete evaluation of long-term stability and performance in the manner that commercial cleaners are tested before introduction to the consumer market. With this background in mind, this guide is not intended as a comprehensive treatise on the complex subject of cleaning formulations. Even within a specific cleaning category, the number of possible formulations is quite extensive due to differences in water conditions, regional regulations, consumer preferences, performance, affordability, and marketing strategies. As it is impossible to cover all these combinations, this formulation guide documents one to three representative formulations for each cleaning category, that in some cases are specific to the geographic region where the formulation was originally developed and tested. This guide can be used as a starting reference tool for sales engineers as well as formulators that want to examine how ISP specialties are employed in different cleaning formulations. It is strongly recommended that formulators use many other sources and ideas to develop, optimize and test their cleaning formulas. Considering the broad nature of cleaning formulations around the globe, it is quite unlikely that any of the formulations found in this guide can be used “as is” without any modifications or additional testing. Thus, we encourage scientists and engineers to use this guide as a starting point in their quest for better cleaning formulations and products. This guide was developed as a collective effort with significant contributions from many ISP scientists around the world. Most of the formulations included in this guide are credited to the following individuals:

Americas:

Frank Fusiak

Michael Jurek

Purvita Shah

Europe:

Jon Virgoe

Rob Gibbison

J.J. Gulka

Asia-Pacific:

Siaw-Ee Loh

T.L. Tan

Editor:

Sotiri A. Papoulias

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2. ISP Products, Properties & Functionalities in HI&I Cleaning ISP Overview ISP is a global supplier of water-soluble chemicals including wetting agents, solvents, thickeners, dye-transfer inhibitors, disintegrants, biocides and other specialties marketed to the HI&I market. Most ISP products are environmentally friendly, biodegradable and thus suitable for household, industrial & institutional cleaning formulations. ISP Product A. Environmentally Friendly Solvents Summaries A-1: M-Pyrol® (N-methyl pyrrolidone) ♦ Excellent chemical stability ♦ High boiling point (202°C) ♦ Good solvency B. Surface Active Agents B-1: Surfadone® LP-100 (N-octyl pyrrolidone) B-2: Surfadone® LP-300 (N-dodecyl pyrrolidone) ♦ High surface activity at low concentrations: LP-100 (28 dynes/cm at 0.12%) LP-300 (26 dynes/cm at 20ppm) ♦ Synergism with anionic surfactants ♦ Low foaming and rapid wetting ♦ Biodegradable C. Water-Soluble Polymers C-1: PVP (Poly N-vinyl pyrrolidone) ♦ Soluble in water and many organic solvents ♦ Stabilizes emulsions, dispersions & suspensions ♦ Highly effective dye-complexing agent ♦ Viscosity modifier for aqueous systems C-2: Gantrez® (Methyl vinyl ether / Maleic Anhydride Copolymer) ♦ Highly soluble in water ♦ Stable in acidic and alkaline conditions ♦ Effective binder for zinc, calcium and magnesium ions ♦ Surface active in aqueous solution ♦ Dispersing, coupling and stabilizing properties ♦ Thickener for aqueous and organic solvent C-3: Antara® 430 (N-vinyl pyrrolidone and Styrene Copolymer) (Antara 430 is marketed as Polectron® in the U.S.) ♦ Opacifier of thermoplastic latex ♦ Excellent mechanical and chemical stability ♦ Forms transparent, thermoplastic films ♦ Broad compatibility with other lattices D. Biocides D-1: Integra® 44 (Aqueous sodium hydroxymethyl glycinate) ♦ Broad spectrum antimicrobial activity ♦ Effective against bacteria and fungi ♦ Active from pH 3.5 to 12 ♦ EPA registered

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3 Hand Soap Formulations 3.10 Liquid Hand Soap Formulation Ingredients

Weight %

01. 02. 03. 04. 05. 06. 07. 08. 09.

15.00 1.00 2.00 1.50 0.15 q.s. q.s. up to 100 to pH 7.0

Sodium lauryl ether sulphate 70% paste Surfadone® LP-300 (ISP) Empigen® BB Sodium Chloride Integra® 44 (ISP) Dye Fragrance Water Citric acid

Formulation Instructions 1. Dissolve sodium lauryl ether sulphate, Surfadone LP-300 and Empigen BB in water. 2. Add NaCl. Adjust pH to 6.5~7.0 with citric acid or caustic soda. 3. Add Integra 44, dye and fragrance. Suppliers 01 03 02, 05 Others

Sodium lauryl ether sulphate 70% paste Empigen BB (Lauryl dimethyl betaine) Surfadone LP-300, Integra 44 Dye, fragrance and Sodium Chloride

Huntsman, Rhodia Huntsman, Rhodia ISP Local supplier

The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.

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4 Laundry Cleaning Formulations 4.10 Laundry Pre-Spotter Formulation Ingredients 01. Unisan® SS5053 02. Gantrez® AN 149 (ISP) 03. Nonylphenol ethoxylate (9EO) 04. Surfadone® LP-100 (ISP) 05. M-Pyrol® Solvent (ISP) 06. Sodium tripolyphosphate 07. Integra®44 (ISP) 08. Dye 09. Fragrance 10. Water

Weight % 6.20 0.50 1.00 0.50 3.00 0.50 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Dissolve Unisan SS5053 in water. 2. Add Gantrez AN 149 and sodium tripolyphosphate, stir until all dissolved. 3. Add nonylphenol ethoxylate (9EO), Surfadone LP-100, n-methyl pyrrolidone (M-Pyrol) and Integra 44 and mix until homogeneous. 4. Add dye and fragrance. Suppliers 01. Unisan SS5053 (sodium alkyl benzene sulphonate 50% paste) 03. Nonylphenol ethoxylate 9EO 06. Sodium tripolyphosphate 02, 04 Gantrez AN 149, Surfadone LP-100 05, 07 M-Pyrol, Integra 44 Others Dye and fragrance

Huntsman, Rhodia Huntsman, Rhodia Rhodia, Haifa ISP ISP Local supplier


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4 Laundry Cleaning Formulations 4.11 Laundry Pre-Spotter & Stain Remover Formulation Ingredients 01. 02. 03. 04. 05. 06. 07. 08. 09. 10.

Surfadone LP-100 (ISP) Gafac BX-660 (80%, Rhodia) Tetrapotassium Pyrophosphate Ammonium Hydroxide (28%) Isopropanol Dipropylene Glycol Monomethyl Ether Perchloroethylene Alipal HP-433 (Rhodia) Triethanolamine Water

Weight % Formula A Formula B 2 4 4 --4 --8 1 8 2 2 10 --22 --40 --5 72 17

Formulation Instructions 1. Charge water to a clean, dry vessel. 2. Add remaining raw materials in the order shown and mix until homogenous.

Performance Data The above formulae were tested for stain removal ability versus a commercial European pre-wash on pre-stained 65/35 polyester/cotton swatches. For the commercial pre-wash, label use instructions were followed prior to laundering. The soiled test swatches were evaluated after pre-treatment only, not after machine laundering. The percent removal was estimated visually after rinsing with water. Stain Type Wine Chocolate Pudding Motor Oil Lipstick Grass / Humus / Blood Blood

Commercial Brand 20 20 5 5 0 0

% Stain Removal Formula A 60 40 15 70 40 0

Formula B 85 75 75 60 20 0

The test results & formulations above show that Surfadone LP-100 can provide performance superior to a contemporary solvent pre-wash product. This superior performance can be obtained with or without chlorinated solvents, demonstrating that Surfadone can be used to develop solvent-free formulas.


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4 Laundry Cleaning Formulations 4.20 Liquid Laundry Detergent (Clear & non-builder) Formulation Ingredients 01. UnisanSS5053 02. Tinopal CBS-X (Optical brightener) 03. Sodium lauryl ether sulphate 70% paste 04. Nonylphenol ethoxylate (9EO) 05. Surfadone LP-100 (ISP) 06. PVP K-30 (ISP) 07. Soda ash 08. Integra 44 (ISP) 09. Dye 10. Fragrance 11. Water

Weight % 25.60 0.05 15.00 3.00 1.00 0.50 1.00 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Dissolve Unisan SS5053 in water. 2. Add Tinopal CBS-X, soda ash and PVP K-30. 3. Add sodium lauryl ether sulphate, nonylphenol ethoxylate 9EO and Surfadone LP-100, stir until all ingredients are dissolved. 4. Add Integra 44, dye and fragrance. Suppliers 01. 02. 03. 04. 05, 06, 08 Others:

Unisan SS5053 (Sodium alkyl benzene sulphonate Tinopal CBS-X (Optical brightener) Sodium lauryl ether sulphate 70% paste Nonylphenol ethoxylate 9EO Surfadone LP-100, PVP K-30 and Integra 44 Soda ash, dye and fragrance

Huntsman, Rhodia Ciba Huntsman, Rhodia Huntsman, Rhodia ISP Local supplier


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4 Laundry Cleaning Formulations 4.21 Heavy Duty Liquid Laundry Detergent Formulation Ingredients Part A 01. UnisanSS 5053 02. Lauryl alcohol ethoxylate (7EO) or KB7 03. Surfadone LP-100 (ISP) 04. PVP K-30 (ISP)  05. Gantrez AN 149 (ISP) 06. Glycerin 07. Water Part B 08. Sodium sulphate 09. Sodium tripolyphosphate (ISP) 10. Antara 430 (Polectron)  11. Integra 44 (ISP) 12. Water

Weight % 14.00 2.00 1.00 0.50 1.00 7.20 26.00 0.70 22.0 0.50 0.15 25.00

Formulation Instructions Part A 1. Dissolve Unisan SS-5053 in water 2. Add KB7, LP-100, PVP K-30, Gantrez AN 149 and glycerin Part B 1. Dissolve sodium sulphate and sodium tripolyphosphate in water 2. Mix part A and B, followed by Integra 44 and Antara (Polectron) 430 Suppliers 01 02 06 03, 04, 05 10, 11 08, 09

Unisan SS 5053 (sodium alkyl benzene sulphonic 50% paste) Lauryl alcohol ethoxylate (KB7) Glycerin Surfadone LP-100, PVP K-30, Gantrez AN-149 Antara 430 and Integra 44 Sodium sulphate and sodium tripolyphosphate

Rhodia, Huntsman Huntsman, Rhodia Kao, Henkel ISP ISP Local supplier


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4. Laundry Cleaning Formulations 4.30 Powder Laundry Detergent (Color-Safe) Formulation Ingredients 01 NaPAS or NaLAS Surfactant 02 Nonionic Surfactant 7EO 03 Hardened tallow soap 04 Zeolite MAP (anhydrous basis) 05 Sodium citrate (2aq) 06 Sodium carbonate (light) 07 Sodium carboxymethylcellulose (70%) 08 EDTMP (DEQUEST 2047) 09 Protease (SAVINASE 6.0T 1635 GU/mg) 10 Lipase (LIPOLASE 100T 287 LU/mg) 11 Amylase (TERMAMYL *60T 4.3 MU/mg) 12 Antifoam granule 13 Fragrance 14 CHROMABOND S-100 or S-400 (ISP) 15 Minor other additives Powder Bulk density

Weight % 6.34 14.26 2.21 40.14 21.93 1.26 0.98 1.43 1.20 0.28 0 or 0.06 3.15 0.45 0.03 - 1.0 to 100.00 800-900 g/l

Formulation Instructions See Instructions in Formulation Reference: Research Disclosure, July 1998, Number 41175


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4. Laundry Formulations 4.40 Laundry Detergent Tabs (Formula #1) Formulation Ingredients Base Powder 01. Sodium linear alkylbenzene sulfonate 02. C13-15 fatty alcohol 7EO 03. C13-15 fatty alcohol 3EO 04. Soap 05. Zeolite A24 06. Sodium acetate trihydrate 07. Sodium carbonate 08. Sodium Carboxymethylcellulose 09. Moisture & impurities Laundry Tab Formula 10. Base Powder (see composition above) 11. Sodium percarbonate granules 12. TAED granules 13. Anti-foam granules 14. Perfume, enzymes, etc. 15. HPA tripolyphosphate 16. DISINTEX-600 (ISP disintegrating agent) 17. Sodium carbonate

Weight % 20.8 6.0 3.2 1.6 46.4 5.9 6.9 0.9 8.3 45.0 15.0 3.4 3.2 3.5 20.0 2-5 balance to 100.0

Formulation Instructions 1. Prepare base powder with ingredients listed above. 2. Mix base powder and remaining tab formula ingredients in a V-mixer for 30 minutes. 3. Press mixed powder at 2.4 Tons pressure using dry compression to make 40 gr tablets. (lab tabs were pressed with Carver Automated Press at 100 psi and 1sec. dwell time) 4. Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until complete dissolution enabled tab granules to pass through a metal gauze cage. Reference: Patents WO 98/55590, WO 00/32741


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4. Laundry Formulations 4.41 Laundry Detergent Tabs (Formula #2) Formulation Ingredients Base Powder 01. C25 Alkylethoxy 5 02. Glucose Amide 03. Zeolite A 04. Sodium carbonate 05. DISINTEX-600 (ISP-tab disintegrating agent) 06. Moisture, others Laundry Tab Formula 10. Base Powder (see above list of ingredients) 11. Percarbonate 12. NaSKS-6 13. Carbonate 14. Polycarbonate 15. Sulfate 16. Zeolite A 17. NaAS 18. NaAE3S 19. Na LAS 20. TAED 21. Citric acid monohydrate 22. Enzymes 23. Optical Brightener 24. SOREZ-100 (ISP – soil release agent) 25. Carboxymethylcellulose (soil anti-redeposition) 26. Perfume, others

Weight % 18.0 6.0 50.0 8.0 10.0 8.0 20.0 18.0 11.0 7.0 3.0 6.0 11.0 7.0 2.0 1.0 5.0 3.0 1.0 0.25 0.5 0.35 1.0

Formulation Instructions 1 Prepare base powder with ingredients listed above. 2 Mix base powder and remaining tab formula ingredients in a V-mixer for 30 minutes. 3 Press mixed powder at 2.4 Tons pressure using dry compression to make 40 gr. tablets. (lab tabs were pressed using a Carver Automated Press at 100 psi and 1sec. dwell time) 4 Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until complete dissolution enabled tab granules to pass through a metal gauze cage. Reference: Patent - WO 99/36493


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4. Laundry Cleaning Formulations 4.50 Fabric Softener (3 Formulations) Formulation Ingredients 01. 02. 03. 04. 05. 06. 07. 08.

Adogen 442 Arquad 2HT-75 Integra 44 (ISP) Surfadone LP-100 (ISP) Surfadone LP-300 (ISP) Dye Fragrance Water

Formula A 6.70 0.15 0.50 q.s. q.s. up to 100

Weight % Formula B 6.70 0.15 1.0 q.s. q.s. up to 100

Formula C 6.67 0.15 0.30 q.s. q.s. up to 100

Formulation Instructions 1. Warm Adogen 442 to 55°C, then add into water and stir well at 55°C. 2. Cool to 35°C. 3. Add Surfadone, Integra 44, fragrance and dye. Suppliers 01 02 03, 04, 05 06, 07

Adogen 442 Arquad 2HT-75 Surfadone LP-100, LP-300 and Integra 44 Dye and fragrance

Goldschmidt Akzo Nobel ISP Local supplier


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5 Dishwashing Formulations 5.10 Manual Liquid Dishwash Detergent Formulation Ingredients 01. Deionized Water 02. Dodecyl Benzene Sulphonic Acid (DDBSA) 03. Sodium Hydroxide (50%) 04. Sodium Lauryl Sulphate (29%) 05. Lauryl Dimethyl Amine oxide (30%) 06. 07.

Weight % 70.00 10.50 3.00 13.00 2.00 1.50 q.s.

Surfadone LP-100 (ISP) Fragrance, Dye, Preservative etc.

Formulation Instructions 1. Charge the mixing vessel with water, and commence stirring. 2. Add the DDBSA while mixing and SLOWLY add the sodium hydroxide solution. (Caution - this is an exothermic reaction. Cool the mixing vessel if necessary) 3. Check & adjust the pH to neutral with either more sodium hydroxide or phosphoric acid, as needed. 4. While stirring, add the remaining ingredients in the order given and mix until homogenous. Suppliers 02 Nansa SSA 04 Empicol LX28 05 Ammonyx LO 06 Surfadone LP-100 07 Fragrance, dye, preservatives

Albright & Wilson Americas Albright & Wilson Americas Stepan ISP Local supplier

Additional Formulation Information Detergency is provided by a blend of DDBS and SLS surfactants. Amine oxide acts as a foam stabilizer / booster, and may in addition help to reduce the skin irritation potential of the DDBS. Surfadone LP-100 improves the wetting performance of the aqueous solution, aids the penetration and solubilization of greasy soils and in conjunction with the other surfactants increases the viscosity of the product, removing the need for electrolyte or thickeners.


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5 Dishwashing Formulations 5.11 Liquid Dishwash Detergent (Formula #1) Formulation Ingredients 01. Alkyl benzene sulphonic acid (LABSA) 02. Caustic soda 50% 03. Sodium lauryl ether sulphate 70% 04. Coco/diethanol amide 05. Surfadone LP-300 (ISP) 06. Sodium Chloride 07. Integra 44 (ISP) 08. Dye 09. Lemon Fragrance 10. Citric acid 11. Water

Weight % 9.80 2.55 5.80 1.00 1.00 0.40 0.15 q.s. q.s. to pH 7.0 up to 100

Formulation Instructions 1. Add caustic soda to water. 2. Add alkyl benzene sulphonic acid, stir until all neutralized. 3. Add sodium lauryl ether sulphate, coco-diethanol amide and Surfadone LP-300, and stir until all ingredients are dissolved. 4. Add Integra 44, dye, lemon and citric acid. 5. Add sodium chloride. Suppliers: 01. 03. 04. 05, 07 Others

Alkyl benzene sulphonic acid (LABSA) Sodium lauryl ether sulphate 70% paste Coco-diethanol amide Surfadone LP-300 and Integra 44 Caustic soda, sodium chloride, dye, fragrance

LG Chemicals, Rhodia Rhodia, Huntsman Huntsman, Henkel ISP Local supplier


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5 Dishwashing Formulations 5.12 Liquid Dishwash Detergent (Formula #2) Formulation Ingredients 01. SLES - Sodium lauryl ether sulphate (70%) 02. Coconut diethanolamine 03. Surfadone LP-300 (ISP) 04. Sodium Chloride 05. Integra 44 (ISP) 06. Dye 07. Fragrance 08. Citric acid to pH 7.0 09. Water

Weight % 15.0 1.0 1.0 2.5 0.15 q.s. q.s. q.s. up to 100

Formulation Instructions 1. Charge the water into the vessel. 2. Add SLES, stir with mechanical stirrer until all dissolved. 3. Add coconut diethanolamine and Surfadone LP-300, stir until all dissolved. 4. Add Integra 44, dye and fragrance, stir all until homogeneous. 5. Add Sodium Chloride 6. Adjust pH to 6.8~7.0 with citric acid (or caustic soda). Suppliers: 01 02 03, 05 04, 07, 08

Sodium lauryl ether sulphate (70%) Coconut diethanolamine Surfadone LP-300 and Integra 44 NaCl, Citric acid, dye and fragrance

Rhodia Rhodia ISP Local supplier


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5 Dishwashing Formulations 5.15 Ecological Liquid Dishwash Detergent Formulation Ingredients 01. Sodium lauryl ether sulphate 70% 02. Empigen BB (lauryl dimethyl betaine) 03. Empilan KB9 (lauryl alcohol eth25oxylate (9EO)) 04. Empigen OB (lauryl dimethyl amine oxide) 05. Surfadone LP-100 (ISP) 06. Sodium Chloride 07. Integra 44 (ISP) 08. Dye 09. Lemon Fragrance 10. Citric acid 11. Water

Weight % 16.9 6.5 1.0 3.5 1.0 1.0 0.15 q.s. q.s. to pH 7 up to 100

Formulation Instructions 1. Charge water to the vessel. 2. Add SLES stir until all dissolved. 3. Add Empigen BB, Empilan KB9 and Empigen OB, stir until all dissolved. 4. Add Integra 44, dye and lemon fragrance. 5. Add NaCl. 6. Adjust pH to 6.8~7.0 with citric acid or NaOH. Suppliers 01 02 03 04 05, 07 06, 09, 10

Sodium lauryl ether sulphate 70% Empigen BB (lauryl dimethyl betaine) Empilan KB9 (lauryl alcohol ethoxylate (9EO)) Empigen OB (lauryl dimethyl amine oxide) Integra 44, Surfadone LP-100 NaCl, citric acid, dye and lemon

Rhodia, Huntsman Huntsman, Kao Huntsman, Rhodia Huntsman, Rhodia ISP Local supplier


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5 Dishwashing Formulations 5.20 Automatic Liquid Dishwash Detergent Formulation Ingredients 01. Eltesol SX pellets (sodium xylene sulphonate) 02. Sodium metasilicate 03. Empilan KA590 (C9-11 alcohol ethoxylate (5EO, 90%) 04. Surfadone LP-100 (ISP) 05. Potassium hydroxide (pellets) 06. Gantrez AN 169 (ISP) 07. EDTA 08. Tetrapotassium pyrophosphate 09. Isopropyl alcohol 10. Integra 44 (ISP) 11. Dye 12. Fragrance 13. Water

Weight % 6.5 4.0 1.0 1.0 3.0 0.85 0.15 15.0 3.0 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Dissolve Eltesol SX pellet, sodium metasilicate, KOH, EDTA and tetrapotassium pyrophosphate in water. 2. Add Empilan KA 590, Surfadone LP-100 and Gantrez AN-169. 3. Add isopropyl alcohol, and the remaining ingredients, stir until clear. Suppliers 01 03 04, 06, 10 Others

Eltesol SX pellet (Sodium xylene sulphonic pellet) Empilan KA 590 (C9-11 alcohol ethoxylate (5EO) 90% liquid) Surfadone LP-100, Gantrez AN 169 and Integra 44 EDTA, KOH, Tetrapotassium Pyrophosphate, Isopropyl Alcohol, Dye, Fragrance, Sodium Metasilicate

Huntsman Huntsman ISP Local supplier


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5 Dishwashing Formulations 5.30 Dishwash Detergent Tablets Formulation Ingredients Base Powder 01. STTP 02. Sodium Carbonate 03. Sodium Sulfate 04. Sodium Metasilicate 05. Sodium Sterate 06. C13-15 fatty alcohol 9EO Dishwashing Tab Formula 07. Base Powder (see composition above) 08. DISINTEX-200 Disintegrating Aid (ISP)

Weight % 40.0 32.8 19.3 6.4 0.8 0.7 98.0 2.0

Formulation Instructions 1. Prepare base powder with ingredients listed above. 2. Mix base powder and Disintex-200 disintegrating agent in a V-mixer for 30 minutes. 3. Press mixed powder at 11 tons pressure using dry compression to make 20 gr. tablets. (lab tabs were pressed using a Carver Automated Press at 387 psi and 1 sec. Dwell time) 4. Individual tabs were tested by submerging in 3 liters of DI water agitated at 700 rpm until complete dissolution enabled tab granules to pass through a metal gauze cage.


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5 Dishwashing Formulations 5.50 Automatic Dishwash Rinse Aid (Formula #1) Formulation Ingredients 01. Deionized water 02. Synperonic LFRA 30 03. Synperonic LFRA 260 04. Surfadone LP-100 (ISP) 05. Sodium Cumene Sulphonate (40%) 06. Dye, Preservative, etc.

Weight % 79.00 12.00 3.00 2.00 4.00 q.s.

Formulation Instructions 1. Charge the mixer with the deionized water and commence stirring. 2. Add the ingredients in the order listed above with stirring, mix until homogeneous. Note: The level of Sodium Cumene Sulphonate has been selected to give a cloud point of around 45oC, but this can be altered by changing the level of SCS used. Suppliers 02. Synperonic LFRA 30 03. Synperonic LFRA 260 04. Surfadone LP-100 05 Eltesol SC40

ICI Surfactants Americas ICI Surfactants Americas ISP Albright & Wilson Americas

Formulation Information The two Synperonic LFRA surfactants (Fatty Alcohol EO/PO adducts of proprietary formula) have been selected to give a blend of wetting and defoaming properties. The blend properties can be altered by varying the ratio of wetting (LFRA 30) & defoaming (LFRA 260) ingredients. Surfadone LP-100 acts in combination with the nonionic blend to greatly reduce the surface tension of the formulation when dispersed in aqueous solution, and hence improve the potential of this solution to form a continuous thin film on the surface of the rinsed items. This in turn reduces the drying time, and helps to reduce the amount of streaking and smearing seen on the dried articles. Surfadone LP-100 has no effect on the amount of foaming caused by the formulation. Sodium Cumene Sulphonate acts as a Hydrotrope, to ensure that the cloud point of the formulation is high enough to prevent separation occurring under warm conditions.


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5 Dishwashing Formulations 5.51 Automatic Dishwash Rinse-Aid (Formula #2) Formulation Ingredients 01. Empilan PF7158 (alcohol-ethoxylate-propoxylate copolymer) 02. Surfadone LP-100 (ISP) 03. Citric acid 04. Isopropyl alcohol 05. Eltesol SX pellet (sodium xylene sulphonate) 06. Integra 44 (ISP) 07. Dye 08. Fragrance 09. Water

Weight % 30.0 2.5 8.0 8.0 1.5 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Charge water into the vessel. 2. Add Eltesol SX and citric acid, stir until dissolved. 3. Add Empilan PF7158 and Surfadone LP-100, stir until dissolved. 4. Add isopropyl alcohol. 5. Add Integra 44, dye and fragrance. Suppliers: 01 Empilan PF7158 (alcohol-ethoxylate-propoxylate copolymer) 05 Eltesol SX pellet (sodium xylene sulphonate pellet) 02, 06 Surfadone LP-100, Integra 44 Others Isopropyl alcohol, citric acid, dye, fragrance

Huntsman, Rhodia Huntsman, Huls ISP Local supplier


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6 Household Cleaning Formulations 6.10 Multi-purpose Hard Surface Cleaner Formulation Ingredients 01. LABSA (Linear alkyl benzene sulphonic acid) 02. Caustic soda 50% 03. Surfadone LP-100 (ISP) 04. M-Pyrol Solvent (ISP) 05. Integra44 (ISP) 06. Dye 07. Fragrance 08. Water

Weight % 6.0 1.5 1.5 1.0 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Charge water into the vessel. 2. Add caustic soda 50%. 3. Add LABSA, stir until all dissolved. 4. Add Surfadone LP-100, M-Pyrol, Integra 44, dye and fragrance. Suppliers: 01. LABSA (Linear alkyl benzene sulphonic acid) 03, 04, 05 Surfadone LP-100, M-Pyrol, Integra 44 02, 06, 07 Caustic soda, dye and fragrance

Rhodia, LG Chemical ISP Local supplier


24

6 Household Cleaning Formulations 6.20 Multipurpose Alkaline Degreaser Formulation Ingredients 01. Tetrapotassium pyrophosphate 02. Surfadone LP-300 (ISP) 03. LABSA (Linear alkyl benzene sulphonic acid) 04. Caustic soda 50% 05. Eltesol SX pellet 06. M-Pyrol Solvent (ISP) 07. Integra 44 (ISP) 08. Dye 09. Fragrance 10. Water

Weight % 5.0 1.0 1.5 0.5 4.5 2.0 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Charge water into the vessel. 2. Add caustic soda, followed by LABSA, stir until all neutralized. 3. Add tetrapotassium pyrophosphate, Eltesol SX pellet, stir until dissolved. 4. Add Surfadone LP-300, stir until all dissolved. 5. Add the remaining components and stir well to homogeneous. Suppliers: 01 03 05 02, 06, 07 08, 04, 09

Tetrapotassium pyrophosphate LABSA (Linear alkyl benzene sulphonic acid) Eltesol SX pellet (Sodium xylene sulphonate) Surfadone LP-300, M-Pyrol, Integra 44 Dye, Caustic Soda and Fragrance

Rhodia Rhodia, Huntsman Huntsman ISP Local supplier


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6

Household Cleaning Formulations

6.21 Kitchen Disinfectant Cleaner Formulation Ingredients 01. Empigen BAC 80 (benzalkonium 80%) 02. Surfadone LP-100 (ISP) 03. Tetrapotassium pyrophosphate 04. Ethylene diamine tetraacetate, sodium salt (EDTA) 05. Dye 06. Fragrance 07. Water

Weight % 2.0 1.5 3.0 0.2 q.s. q.s. up to 100

Formulation Instructions 1. Charge water into the vessel. 2. Add tetrapotassium pyrophosphate and EDTA, stir until all dissolved. 3. Add Empigen BAC 80, stir until homogeneous. 4. Add Surfadone LP-100, stir until dissolved. 5. Add dye and fragrance. Suppliers 01 02. 03. 04, 05, 06

Empigen BAC 80 Surfadone LP-100 Tetrapotassium pyrophosphate EDTA, dye & fragrance

Huntsman ISP Rhodia Local supplier


26

6. Household Cleaning Formulations 6.22 Kitchen Degreaser (Formula #1) Formulation Ingredients 01. SLES (Sodium lauryl ether sulphate 70%) 02. Surfadone LP-100 (ISP) 03. Surfadone LP-300 (ISP) 04. Propylene glycol methyl ether 05. M-Pyrol Solvent (ISP) 06. EDTA 07. Integra 44 (ISP) 08. Blue dye 09. Fragrance 10. Water

Weight % 1.0 0.3 0.1 3.0 3.0 3.0 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Charge water into the vessel. 2. Add EDTA, stir until all dissolved. 3. Add SLES, stir until all dissolved. 4. Add Surfadone LP-100 and 300. 5. Add the remaining component and stir until homogeneous. Suppliers: 01. SLES (Sodium lauryl ether sulpahte 70%) 04. Propylene glycol methyl ether 02, 03 Surfadone LP-100, Surfadone LP-300 06, 07 M-Pyrol and Integra 44 Others EDTA, dye, fragrance

Huntsman, Henkel Dow and Lyodell ISP ISP Local supplier


27

6 Household Cleaning Formulations 6.23 Kitchen Degreaser (Formula #2) Formulation Ingredients 01. Deionized Water 02. Sodium Lauryl Ether Sulphate (27%) 03. C13 Alcohol / 9EO 04. Propylene Glycol Methyl Ether 05. M-Pyrol® Solvent (ISP) 06. Na3NTA (38%) 07. Surfadone LP-300 (ISP) 08. Dye, Fragrance, Preservative etc.

Weight % 87.65 2.50 0.75 3.00 3.00 3.00 0.10 q.s.

Formulation Instructions 1. Introduce the water and commence stirring. 2. Add the SLES with stirring. 3. Add the alcohol ethoxylate. Stir until homogenous. 4. Add the remaining ingredients with stirring. Suppliers 02 03 04 05, 07 08

Empimin KSN27 Synperonic 13/8 Dowanol PM M-Pyrol, Surfadone LP-300 Na3NTA, dye, fragrance, preservative

Albright and Wilson Americas ICI Surfactants Americas Dow ISP Local Supplier

Additional Formulation Information The two surfactants provide a range of detergency properties - wetting, foaming etc. The nonionic is particularly effective on oils and greases, providing soil removal and emulsification properties and helping to prevent redeposition. Surfadone LP-300 acts in conjunction with the surfactants, improving the wetting properties, and aiding the penetration of the surfactants into the soils. The solvents increase the cleaning effect by helping to dissolve hydrophobic soils. The glycol ethers offer anti-redeposition properties. The complexing agent (NTA) improves the tolerance of the formulation (particularly the anionic surfactant) to the presence of water hardness ions. In addition, it improves the cleaning effect, notably on particulate soils.


28

6 Household Cleaning Formulations 6.24 Kitchen Degreaser (Formula #3) Formulation Ingredients 01. Deionized Water 02. Sodium Lauryl Ether Sulphate (27%) 03. C13 Alcohol / 9EO 04. Propylene Glycol Methyl Ether 05. M-Pyrol Solvent (ISP) 06. Na4EDTA (38%) 07. Surfadone LP-300 (ISP) 08. Dye, Fragrance, Preservative etc.

Weight % 87.65 2.50 0.75 3.00 3.00 3.00 0.10 q.s.

Formulation Instructions 1. Introduce the water and commence stirring. 2. Add the SLES with stirring. 3. Add the alcohol ethoxylate. Stir until homogenous. 4. Add the remaining ingredients with stirring. Suppliers 02 03 04 05, 07 06, 08

Empimin KSN27 Synperonic 13/8 Dowanol PM M-Pyrol, Surfadone LP-300 Na4EDTA, Dye, Fragrance, Preservative

Albright & Wilson Americas ICI Surfactants Americas Dow ISP Local Supplier

Additional Formulation Information The two surfactants provide a range of detergency properties - wetting, foaming etc. The nonionic is particularly effective on oils and greases, providing soil removal and emulsification properties and helping to prevent redeposition. Surfadone LP-300 acts in conjunction with the surfactants, improving the wetting properties, and aiding surfactant penetration into the soils. The solvents increase the cleaning effect by helping to dissolve hydrophobic soils. The glycol ethers offer anti-redeposition properties. The complexing agent (EDTA) improves the tolerance of the formulation (particularly the anionic surfactant) to the presence of water hardness ions. In addition, it improves the cleaning effect, notably on particulate soils.


29

6 Household Cleaning Formulations 6.25 Oven Cleaner Formulation Ingredients 01. Deionized Water 02. M-Pyrol Solvent (ISP) 03. Gantrez S97-BF (ISP) 04. C9-11 Alcohol / 8EO (Synperonic 918) 05. Surfadone LP-300 (ISP) 06. Monoethanolamine

Weight % 72.30 20.00 0.50 2.00 0.20 5.00

Formulation Instructions 1. Charge the mixing vessel with the water, and commence stirring. 2. Premix Gantrez S97-BF in some M-Pyrol to form slurry, and add to mixer. 3. Use the remaining M-Pyrol to rinse the premix vessel into the mixer, to ensure that all the Gantrez S97-BF is added. 4. Add the Alcohol Ethoxylate and Surfadone LP-300 with stirring. 5. Finally add Monoethanolamine. The neutralization of the acidic functionalities causes the polymer to swell, resulting in a clear, viscous solution. 6. Continue stirring to ensure the polymer becomes fully hydrated. Suppliers 04 02, 03, 05 06

Synperonic 918 ICI Surfactants Americas M-Pyrol, Gantrez S97-BF, Surfadone LP-100 ISP Monoethanolamine Local Supplier

Additional Formulation Information Surface activity is provided by the combination of the nonionic surfactant and the Surfadone LP-300, giving the formulation the ability to wet greasy surfaces. Surfadone LP-300 has also the ability to penetrate into oily and greasy soils, thus helping to dislodge them from the surfaces. Once in solution, the M-Pyrol, Surfadone LP-300 and the nonionic surfactant in combination with the alkalinity from the MEA act to solubilize and emulsify the soils to leave a clean surface. Gantrez S97-BF is present to add viscosity to the formulation, helping it to “cling” to the surfaces being cleaned and hence maximize the contact time.


30

6 Household Cleaning Formulations 6.26 Kitchen Cleaning Wipes Formulation Ingredients 01. Deionized Water 02. Isopropyl Alcohol (IPA) 03. M-Pyrol® Solvent (ISP) 04. Surfadone® LP-100 (ISP) 05. Sodium Cocoyl Glutamate 06. Sodium Hydroxide (10% aqueous solution) 07. Integra® 44 (ISP) 08. Fragrance

Weight % 91.65 2.00 2.00 1.50 1.50 1.18 0.15 0.02

Formulation Instructions 1. Add the ingredients in the order listed, stirring thoroughly after each addition. 2. Apply to wipe substrate in a 1:1 weight ratio. Suppliers 03, 04, 07 Others

M-Pyrol, Surfadone LP-100, Integra-44 IPA, Sodium Cocoyl Glutamate, NaOH, fragrance

ISP Local Supplier


31

6 Household Cleaning Formulations 6.30 Glass Cleaner (Formula #1) Formulation Ingredients 01. Surfadone LP-100 (ISP) 02. Dipropylene glycol methyl ether 03. Isopropyl alcohol 04. Integra 44 (ISP) 05. Dye 06. Water

Weight % 0.15 1.0 9.0 0.15 q.s. up to 100

Formulation Instructions 1. Mix all components and stir mixture until homogeneous. Suppliers: 02. 01, 04 03, 05.

Dipropylene glycol methyl ether Surfadone LP-100 and Integra 44 Isopropyl alcohol (IPA) and Dye

Lyondell, Dow ISP Local supplier


32

6 Household Cleaning Formulations 6.31 Glass Cleaner (Formula #2) Formulation Ingredients 01. Deionized Water 02. Isopropanol alcohol (IPA) 03. Propylene Glycol Methyl Ether 04. Magnesium Lauryl Ether Sulphate (27%) 05. Monoethanolamine 06. Ammonia (28%) 07. Surfadone LP-300 (ISP) 08. Fragrance, Dye, Preservative, etc.

Weight % 90.79 5.00 4.00 0.02 0.15 0.15 0.01 q.s.

Formulation Instructions 1. Charge the mixing vessel with the water, and commence stirring. 2. Add the remaining ingredients with stirring in the order given above. Suppliers 03. 04. 07. Others

Dowanol PM Empicol EGC Surfadone LP-300 IPA, PG/ME, MLES, Monoethanolamine, etc

Dow Albright & Wilson Americas ISP Local Supplier

Additional Formulation Information Isopropyl alcohol and glycol ether give the volatility necessary for fast drying. MgLES aids wetting of the surface. Tests show that the magnesium salts are more efficient than the corresponding sodium salts in reducing the amount of streaking or smearing. Nitrogenous buffers (in this case MEA) also help in this regard. Ammonia as a co-buffer aids removal of greasy soils, and is also easily volatilized, promoting streak-free appearance. Surfadone LP-300 acts as a co-solvent for removing greasy soils, and in addition promoting the solubility of fragrances where necessary. The tremendous wetting power of Surfadone LP-300 in conjunction with the anionic enables excellent coverage of the surface to be achieved whilst using very low levels of non-volatile components - reducing the amount of smearing and streaking.


33

6 Household Cleaning Formulations 6.32 Glass Cleaning Wipes Formulation Ingredients 01. Deionized Water 02. Isopropyl Alcohol (IPA) 03. Dipropylene Glycol Methyl Ether 04. Integra® 44 (ISP) 05. Surfadone® LP-100

Weight % 89.70 9.00 1.00 0.15 0.15

Formulation Instructions 1. Add the ingredients in the order listed, stirring thoroughly after each addition. 2. Spray onto wipes and package in air-tight containers. Suppliers 04, 05 Others

Integra 44, Surfadone LP-100 IPA, Dipropylene Glycol Methyl Ether

ISP Local Supplier


34

6 Household Cleaning Formulations 6.40 Bathroom Cleaner (Formula #1) Formulation Ingredients 01. Deionized Water 02 Lauryl Dimethyl Amine oxide (30%) 03 Glycolic Acid (65%) 04 Acetic Acid (Glacial) 05 Alkyl Dimethyl Benzyl Ammonium Chloride (50%) 06 Surfadone LP-100 (ISP) 07 Fragrance, Dye, Preservative etc.

Weight % 89.60 2.00 3.00 1.50 1.40 2.50 q.s.

Formulation Instructions 1. Charge the mixing vessel with the water and commence stirring. 2. Add the remaining ingredients with stirring in the order given above. Suppliers 02. 05. 06. Others

Ammonyx LO Empigen BAC Surfadone LP-100 Glycolic Acid, Acetic Acid, etc.

Stepan Albright & Wilson Americas ISP Local Supplier

Additional Formulation Information The acidic nature of the formulation aids in the break-down and dissolution of hardness salt based soils, such as limescale and soap scum. Detergency and surface activity are provided by the combination of the amine oxide and Sufadone LP-100. The amine oxide also acts as a coupler for the formulation - it has been found that if the amount of coupler used is increased to more than is actually necessary to solubilize the other ingredients, a remarkable increase in the cleaning ability of the formulation is observed. It has also been observed that the Surfadone LP100 has the ability to reduce soap scum deposition on surfaces. The quaternary ammonium chloride is present to give the formulation a bactericidal effect.


35

6 Household Cleaning Formulations 6.41 Bathroom Cleaner (Formula #2) Formulation Ingredients 01. Deionized Water 02. Sodium Lauryl Sulphate (29%) 03. C9-11 Alcohol / 8EO 04. Phosphoric Acid (85%) 05. Surfadone LP-100 (ISP) 06. Citric Acid Monohydrate 07. Glycolic Acid (65%) 08. Magnesium Sulphate Heptahydrate 09. Fragrance 10. Dye, Preservative etc.

Weight % to 100 13.00 3.00 0.10 0.025 1.50 3.50 1.50 0 - 1.0 q.s.

Formulation Instructions 1. 2. 3. 4. 5.

Charge the mixing vessel with the water and commence stirring. Add the anionic and nonionic surfactants, and stir until completely dispersed. Add the remaining ingredients, except the Fragrance, with stirring. Adjust the pH to 3.0 (Use NaOH if required) Stir in the Fragrance to form a clear microemulsion.

Suppliers 02. 03. 05. Others

Empicol LX28 Synperonic 918 Surfadone LP-100 All other ingredients

Albright & Wilson Americas ICI Surfactants Americas ISP Local Supplier

Additional Formulation Information Detergency is provided by the blend of nonionic and anionic surfactants. The acidic nature of the formulation aids in the break down and dissolution of hardness salt based soils, such as limescale and soap scum. The combination of phosphoric acid, carboxylic acid and Surfadone LP100 protects certain surfaces from acid etching. It is suggested that a complex forms, which can attach to negatively charged surfaces and hence reduce acid attack. Surfadone LP100 addition reduces the soap scum deposition on surfaces. The inclusion of magnesium ions and the fragrance are necessary to enable a microemulsion to form. The levels of the two can be varied - in addition the type of fragrance used will also affect the amount required for the microemulsion to form. It has also been suggested that the inclusion of a small amount of magnesium ions improves the cleaning efficiency of the product, particularly in soft water areas.


36

6 Household Cleaning Formulations 6.42 Toilet Bowl Cleaner Formulation Ingredients 01. 02. 03. 04.

Deionized Water Mulgofen ON-870 (Rhodia) Gantrez AN-169 (ISP) Hydrochloric Acid (37%)

Viscosity (cps)

Weight % Formula A Formula B 71.0 74.4 1.0 0.6 3.0 2.0 25.0 23.0 1200

130

Formulation Instructions 1. Charge water to a clean, dry vessel. 2. Add Mulgofen ON-870 to the water and mix until homogenous. 3. Add Gantrez AN-169 slowly to the water/surfactant mix and heat to 70-80°C. Stir until a thick gel results. (Note: Make up any water loss and cool to 40°C.) 4. Add the hydrochloric acid and mix well until homogenous. Suppliers 02. 03. 04.

Mulfogen ON-870 Gantrez AN-169 Hydrochloric Acid

Rhodia ISP Local Supplier

Additional Formulation Information The acidic nature of the formulation aids in the breakdown of hardness salt based soils, such as limescale and soap scum. The Gantrez AN:ethoxylated surfactant partial ester imparts thickening emulsion and freezethaw stability and surface activity to aid in the cleaning ability of the formulation. The ester complex of Gantrez AN will not form if the order of addition is reversed.


37

6 Household Cleaning Formulations 6.50 Floor Cleaner Formulation Ingredients Part A 01. Unisan SS5053 02. Water Part B 03. Antara 430 (Polectron) (ISP) 04. Water Part C 05. Sodium tripolyphosphate 06. Nonylphenol ethoxylate 9EO 07. Integra 44 (ISP) 08. Dye 09. Fragrance

Weight (%) 5.10 81.80 0.10 9.55 1.00 2.30 0.15 q.s. q.s.

Formulation Instructions 1. Part A: Dissolve Unisan SS5053 in water. 2. Part B: Disperse Antara 430 in water. 3. Part C: Mix Parts A, B and C well. Suppliers 01. Unisan SS5053 (Sodium alkylbenzene sulphonate 50% paste) 03, 07 Antara 430 (Polectron), Integra-44 05. Sodium tripolyphosphate 06. Nonylphenol ethoxylate 9EO 08, 09 Dye and fragrance

Huntsman, Rhodia ISP Rhodia Huntsman, Rhodia Local supplier


38

6 Household Cleaning Formulations 6.51 Floor Polish (2 Formulations) Formulation Ingredients 01. 02. 03. 04. 05. 06. 07. 08. 09. 10. 11. 12. 13. 14.

Surfactant FC-120 Surfadone LP-300 (ISP) Wacker SRE Ethylene glycol methyl ether Dipropylene glycol methyl ether 2-Pyrol Solvent (ISP) M-Pyrol Solvent (ISP) Dibutyl phthalate Tributoxy ethyl phosphate Integra 44 (ISP) Primal B-924 Primal E-1531 Michem ME 39235 Water

Weight % Formula A Formula B 0.04 0.04 0.03 0.03 0.10 0.10 1.00 1.00 3.34 3.34 1.20 1.20 1.13 1.13 1.13 1.13 0.15 0.15 37.31 37.31 5.92 5.92 7.59 7.59 up to 100 up to 100

Formulation Instructions 1. Mix chemicals in the following order: Water, Surfactant FC-120, Surfadone LP-300, Wacker SRE, Ethylene glycol methyl ether, Dipropyl glycol methyl ether, 2-Pyrol or M-Pyrol, Dibutyl phthalate, Tributoxy ethyl phosphate and Integra 44. Agitate for a few minutes. 2. Slowly add Primal B-924 with constant stirring and continue to stir for 30 minutes. 3. Slowly add Primal E-1531 with constant stirring and continue to stir for 10 minutes. 4. Slowly add Michem ME 39235 with constant stirring and continue to stir for 1 hour. 5. Allow standing for a day before use. Suppliers 01. 02,06,07,10 03. 04. 05. 08. 09. 11. 12. 13.

Surfactant FC-120 Surfadone LP-300, 2-Pyro, M-Pyrol, Integra-44 Wacker SRE (defoamer) Ethylene glycol methyl ether Dipropylene glycol methyl ether Dibutyl phthalate Tributoxy ethyl phosphate Primal B-924 (acrylic binder) Primal E-1531 (alkali soluble resin) Michem ME 39235 (wax emulsion)

3M, Ciba ISP Wacker, Dow Corning Dow (Union Carbide) Dow (Union Carbide) Eastman Rhodia, FMC Rohm & Haas Rohm & Haas Michelman


39

6 Household Cleaning Formulations 6.52 Carpet Cleaner Formulation Ingredients 01. Sodium lauryl sulphate 02. Coco/diethanol amide 03. Surfadone LP-100 (ISP) 04. Isopropyl alcohol 05. Integra 44 (ISP) 06. Dye 07. Fragrance 08. Water

Weight % 10.00 2.00 1.00 10.00 0.15 q.s. q.s. up to 100

Formulation Instructions 1. Dissolve sodium lauryl sulphate in water. 2. Add coco/diethanolamide, isopropyl alcohol and Surfadone LP-100. 3. Add Integra 44, dye and fragrance, mix until homogenous. Suppliers 01. 02. 03, 05 04, 06, 07

Sodium lauryl sulphate Coco-diethanol amide Surfadone LP-100 and Integra 44 Isopropyl alcohol, dye and fragrance

Huntsman, Henkel Huntsman, Henkel ISP Local supplier


40

6 Household Cleaning Formulations 6.53 Machine Carpet Cleaner Formulation Ingredients 01. 02. 03. 04. 05. 06. 07. 08. 09. 10.

Weight %

Eltesol SX 40 (sodium xylene sulphonate 40%) Surfadone LP-100 (ISP) Tetrapotassium Pyrophosphate Butyl Carbitol EDTA 38% Integra 44 (ISP) Dye Fragrance Phosphoric acid (85%) Water

6.50 1.00 7.50 8.00 0.50 0.15 q.s. q.s. to pH 7 up to 100

Formulation Instructions 1. Dissolve all solids in water. 2. Then add the remaining ingredients and mix until homogenous. Suppliers 01. 02, 06 04. Others

Eltesol SX 40 (sodium xylene sulphonate 40%) Surfadone LP-100 and Integra 44 Butyl Carbitol Tetrapotassium pyrophosphate, phosphoric acid EDTA, dye and fragrance

Huntsman ISP Dow, Huntsman Local supplier


41

6 Household Cleaning Formulations 6.55 Silicone Furniture Polish Formulation Ingredients

Weight %

01. 02. 03. 04. 05. 06. 07. 08. 09. 10.

0.30 20.00 1.00 1.50 2.50 4.00 1.50 1.50 0.10 up to 100

KELGIN HV (ISP) Mineral Spirits Carnauba Wax Cardis 319 Wax Paraffin Wax SF96-300 Silicone Fluid Span 60 Tween 60 Dowcide A (preservative) Water

Formulation Instructions 1. Dissolve KELGIN HV in cold water with gradual addition and good agitation. 2. Take the KELGIN HV solution and add Dowcide A and Tween 60. 3. Heat a mixture of all other ingredients to 170 F. 4. Heat the Kelgin solution (Step 1) to 170 F. 5. Mix hot solutions from Steps 3 and Step 4 until homogeneous. Suppliers 01. 04. 06. 07, 08 09. 02, 03, 05

Kelgin HV (Sodium Alginate thickener) Cardis 319 Wax SF96-300 Silicone Fluid Span 60, Tween 60 (emulsifying agents) Dowcide A (preservative) Mineral Spirits, Carnauba Wax & Paraffin Wax

ISP Warwick Wax Company General Electric Atlas Powder Company Dow Chemical Local supplier

Additional Formulation Information Kelgin HV is a refined industrial grade of sodium alginate, which is a valuable ingredient to all types of liquid polishes. This excellent thickening, stabilizing and suspending agent, provides the following important properties: ♦ Ease of Solution in either hot or cold water, without any prolonged period of hydration; ♦ Uniformity to assure superior and dependable thickening performance; ♦ Improved Stability for most finished polish formulations;


42

6 Household Cleaners 6.60 Windscreen Cleaner Formulation Ingredients 01. Dipropylene glycol methyl ether 02. M-Pyrol Solvent (ISP) 03. Surfadone LP-100 (ISP) 04. Isopropyl alcohol 05. Silwet 7608 (Silicone surfactant) 06. Integra 44 (ISP) 07. Dye 08. Water

Weight % 6.0 10.0 1 10.0 0.2 0.15 q.s. up to 100

Formulation Instructions 1. Mix all components, stir until homogeneous. Suppliers 01. 05. 03, 02, 06 04, 07

Dipropylene glycol methyl ether Silwet 7608 (silicone surfactant) Surfadone LP-100, M-Pyrol, Integra 44 Isopropyl alcohol, dye

Dow, Lyondell Crompton ISP Local supplier


43

6 Household Cleaners 6.70 Air Freshener (Formula #1) Formulation Ingredients 01. Isopropyl alcohol 02. Surfadone LP-300 (ISP) 03. Lemon fragrance 04. Dye (Green) 05. Integra 44 (ISP) 06. Water

Weight % 5.00 0.10 2.00 q.s. 0.15 up to 100

Formulation Instructions 1. Add isopropyl alcohol, and Surfadone LP-300 to the lemon fragrance. 2. Add water, followed by dye and Integra 44. Suppliers 02, 05 01, 03, 04

Surfadone LP-300 and Integra 44 Isopropyl Alcohol, lemon fragrance and dye

ISP Local supplier


44

6 Household Cleaners 6.71 Air Freshener (Formula #2 - Poppy Fragrance) Formulation Ingredients Phase A 01. Water 02. Preservative 03. Sodium Hexametaphosphate (Calgon) Phase B 04. Glycerine 05. Manugel GHB (ISP) Phase C 06. Poppy Fragrance (Independent Fragrance Company) 07. Polysorbate 80 Phase D 08. Water 09. Calcium Sulphate Dihydrate (Terra Alba) 10. Sodium Hexametaphosphate (Calgon)

Weight % 69.250 q.s. 0.060 5.000 2.000 20.000 1.000 1.700 0.340 0.150

Formulation Instructions 1. Phase A: Dissolve Phase A Calgon in water and add then add preservative. 2. Phase B: Slurry Manugel GHB alginate in glycerine and add to Phase A with mixing. Mix for 10-15 minutes until alginate thickener is fully hydrated. 3. Phase C: Mix the poppy fragrance and the Polysorbate 80 solubilizer. Add Phase C to Phase AB with high speed mixing until homogenized. 4. Phase D: Dissolve the Phase D Calgon in the water and then slurry the Terra Alba. 5. Inject Phase D into Phase ABC and mix with high shear for 10 seconds. 6. Place into suitable containers and leave to set for at least four hours. Suppliers 03. 05. 06. Others

Sodium Hexametaphosphate (Calgon) Manugel GHB (Alginate) Poppy Fragrance All other ingredients

Calgon Corporation ISP Independent Fragrance Company Local Supplier


45

7 Industrial & Institutional Cleaners 7.10 Car Wash Shampoo Formulation Ingredients 01. 02. 03. 04. 05. 06. 07. 08.

Triethanolamine salt of alkyl benzene sulphonic acid (TS-6053) Surfadone LP-300 (ISP) Coco/diethanol amide Integra 44 (ISP) M-Pyrol Solvent (ISP) Dye Fragrance Water

Weight % Non-Wax Wax 30.00 30.00 2.00 2.00 2.00 2.00 0.15 0.15 2 q.s. q.s. q.s. q.s. up to 100 up to 100

Formulation Instructions 1. Dissolve TS 6053, Coco-diethanol amide and Surfadone LP-300 in water. 2. Add the M-Pyrol solvent. 3. Add Integra 44, dye and fragrance. Suppliers 01. 03. 02, 04, 05 06, 07

Triethanolamine salt of alkyl benzene sulphonic acid Coco-diethanol amide Surfadone LP-300, Integra 44 and M-Pyrol Dye and fragrance

Huntsman, Stepan Huntsman, Henkel ISP Local supplier


46

7 Industrial & Institutional Cleaners 7.11 Car Wash & Wax Cleaner Formulation Ingredients 01. 02. 03. 04. 05. 06. 07. 08. 09.

Triethanolamine salt of alkyl benzene sulphonic acid (TS 6053) Surfadone LP-300 (ISP) Coco/diethanol amide Integra 44 (ISP) Carnauba wax M-Pyrol Solvent (ISP) Dye Fragrance Water

Weight % Non-Wax Wax 30.00 30.00 2.00 2.00 0.15 1.00 q.s. q.s. up to 100

1.00 1.00 0.15 1.00 2 q.s. q.s. up to 100

Formulation Instructions 1. Dissolve TS 6053, Coco/diethanol amide and Surfadone LP-300 in water. 2. Add carnauba wax and M-Pyrol. 3. Add Integra 44, dye and fragrance. Suppliers 01. 03. 05. 02, 04, 06 07, 08

Triethanolamine salt of alkyl benzene sulphonic acid Coco/diethanol amide Carnauba wax Surfadone LP-300, Integra 44 and M-Pyrol Dye and fragrance

Huntsman, Stepan Huntsman, Henkel Bronson & Jacob ISP Local supplier


47

7 Industrial & Institutional Cleaners 7.12 High Gloss Tire Wax Formulation Ingredients 01. L45 (350 cts) 02. L45 (1000 cts) 03. Surfadone LP-300 (ISP) 04. Emulsifier 05. Antara 430 (ISP) 06. Gantrez AN 169 (ISP) 07. Water

Weight % 25.00 5.00 0.50 6.00 1.00 0.80 up to 100

Formulation Instructions 1. Add emulsifier and Surfadone LP-300 to L45, mix well 2. Add Antara 430, Gantrez AN 169 and water, mix well. Suppliers 01, 02 Dimethicone 350 cts and 1000 cts (L45) 04. Emulsifier 03, 05, 06 Surfadone LP-300, Antara 430, Gantrez AN 169

Crompton, Dow Corning Mutiara Chemical Trading ISP


48

7 Industrial & Institutional Cleaners 7.13 Liquid Car Polish Formulation Ingredients

Weight %

01. 02. 03. 04. 05. 06. 07. 08. 09.

16.00 1.40 4.10 10.20 0.20 0.50 0.13 0.67 up to 100

Light Mineral Oil Carnauba Wax Glycerine Celite 315 Calgon KELGIN HV (ISP) Dowcide A (preservative) Pluronic L44 Water

Formulation Instructions 1. Dissolve KELGIN HV in cold water by gradual addition and good agitation. 2. Take the KELGIN HV solution and add Calgon, Pluronic L44, Dowcide A and Glycerine. 3. Add Celite 315 to the liquid mixture and heat up to 140 F. 4. In another container, dissolve the carnauba wax in mineral oil. 5. Add the hot liquid mixture of Step 3 slowly to the Step 4 solution with good agitation. 6. Cool the resulting product, pass through a colloid mid and package. Suppliers 04. 05. 06. 07. 08. 01, 02, 03

Cellite 315 (diatomaceous earth) Calgon Kelgin HV (Sodium Alginate thickener) Dowcide A (preservative) Pluronic L44 (emulsifying agent) Light Mineral Oil, Carnauba Wax & Glycerine

Johns-Manville Corp. Calgon Corporation ISP Dow Chemical BASF Local supplier

Additional Formulation Information Various simple modifications of the above formula should produce a polish which would satisfy all product requirements. Durability of the polished film may be changed with the type of abrasive used together with wax constituent variations. The gloss of the polished film may be enhanced with the addition of silicone oil, variation of the wax constituent, or variations in the oil content. Finally, drying time may be altered by the addition of mineral spirits. The percentage of KELGIN HV required should remain relatively constant for most modifications of the given formula, but in a few cases it may be necessary to alter the quantity slightly to obtain the desired results. It is suggested that the 0.5% level is tried first and then, if necessary, altered in the direction indicated. The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.

49

7 Industrial & Institutional Cleaners 7.20 Alkaline Grill Cleaner Formulation Ingredients 01. Caustic soda 50% 02. Gantrez AN 149 (ISP) 03. Mackam OAB 04. Water

Weight % 20.00 1.00 1.00 up to 100

Formulation Instructions 1. Add caustic soda to water. 2. Add Mackam OAB, followed by Gantrez AN 149. Suppliers 01. 02. 03.

Caustic soda (50%) Gantrez AN 149 Mackam OAB (Amine oxide stable in acid)

Local supplier ISP McIntyre, Rhodia


50

7 Industrial & Institutional Cleaners 7.30 Metal Cleaner Formulation Ingredients 01. Phosphoric acid 85% 02. M-Pyrol Solvent (ISP) 03. Water

Weight % 12.00 4.00 up to 100

Formulation Instructions 1. Add acid to M-Pyrol and water with continuous stirring. 2. A slight exothermic reaction will occur. 3. Mix all ingredients until you have a homogenous cleaner solution. Suppliers 01. 02.

Phosphoric acid (85%) M-Pyrol® Solvent

Rhodia ISP


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Appendix A: Summary of Chemical Functionalities Chemical names Functionalities 01 Caustic soda or NaOH pH adjuster 02 Alkyl benzene sulphonates. Dispersant, detergency and foaming Alkali earth salts 03 Sodium lauryl ether sulphonate Emulsifier, surfactant (shampoo), textile auxilliary 04 Sodium lauryl sulphate Emulsifier, foaming agent, wetting agent 05 Methanol Co-solvent 06 Coconut acid diethanolamide Foam booster, stabilizer, emulsifier, thickener 07 NaCl Filler, salting-out reagent 08 Citric acid Buffering agent, pH adjuster 09 Nonylphenol ethoxylate Emulsifier, surfactant, wetting agent, defoaming agent 10 Lauryl alcohol ethoxylate Emulsifier 11 Glycerol or glycerin Humectant, solvent 12 Sodium tripolyphosphate Detergent builder, softening agent 13 Adogen/quaternary ammonium salts Emulsifier, dispersant, softener, antistat 14 Silwet or dimethicone copoly Surfactant, dispersant, emulsifier, leveling agent 15 IPA Disinfectant 16 Sodium xylene sulphonate Hydrotrope (heavy duty detergent) 17 Empilan or ethoxylate ether\ester Emulsifier, foamer, wetting agent, dispersant 18 EDTA Chelating agent, metal deactivator, anti-oxidant 19 Phosphoric acid Etchant, acidulant 20 Tetrasodium pyrophosphate Detergent builder, sequesterant 21 Triethanolamine alkylbenzene Pigment dispersant, surfactant, dry cleaning sulphonate detergent 22 Carnauba wax Car, floor or shoe polish, paraffin wax modifier 23 Dimethyl lauryl amine oxide Foam booster, stabilizer 24 Sodium metasilicate Detergent builder, stabilizer of peroxide bleach 25 Briquest or phosphonic acid Powder detergent, peroxide stabilizer, scale inhibitor 26 Benzalkonium chloride Disinfectant 27 Propylene glycol monomethyl ether Coalescing solvent 28 Hexylene glycol Solvent 29 Dipropylene glycol Solvent 30 Soda Ash or sodium carbonate Neutralizing agent, pH adjuster 31 Tinopal Fluorescent whitening agent 32 Arquat/quaternary ammonium salts Emulsifier, foaming agent, wetting agent, softener 33 Acusol or acrylic acid Thickener, detergent polymer, emulsion stabilizer, suspending agent 34 Mackam or sulfosuccinate uSurfactant 35 Ethylene glycol methyl ether Solvent 36 Dibutyl phthalate Plasticizer 37 Tributoxy ethyl phosphate Coalescing solvent, antifoamer 38 Primal Pigment dispersant The foregoing information is accurate to the best of our knowledge and is offered as guide to formulators. No warranty is expressed or implied as to the results obtained from use of the formulation, procedure or products suggested herein, neither is any permission or recommendation to practice any invention covered by patent either expressed or implied. All users should test formulation stability, toxicology and microbiology.

GLOBAL LOCATIONS FOR SALES & CUSTOMER SERVICE WORLD HEADQUARTERS INTERNATIONAL SPECIALTY PRODUCTS

1361 Alps Road, Wayne, New Jersey 07470, USA Tel: 973-628-4000 www.ispcorp.com [email protected]

INTERNATIONAL SPECIALTY PRODUCTS

USA & CANADA REGIONAL SALES OFFICES CENTRAL REGION LOMBARD, ILLINOIS Tel: 1 630 932-4022 Toll Free: 1 (800) 323-2272 Fax: 1 630 495-0245 [email protected]

EASTERN REGION WAYNE, NEW JERSEY Toll Free: 1 (877) 389-3083 Fax: 1 973 628-4117 [email protected]

WESTERN REGION SHERMAN OAKS, CALIFORNIA Toll Free: 1 (800) 505-8984 Fax: +1 818-906-3504 [email protected]

CANADA Tel: +1 905 607-2392 Toll Free: 1 (800) 465-5094 Fax: +1 905 607-9086 [email protected]

CUSTOMER SERVICE: Toll Free: 1 (800) 622-4423 Fax: 1 973 628-4001 [email protected] SAMPLE CENTER: Toll Free: 1 (800) 243-6788 [email protected]

COLOMBIA Tel: + 57 (1) 638-6203 Fax: + 57 (1) 616-3030/6030 [email protected]

MEXICO Tel: + 52 55 5589-0721 Fax: + 52 55 5589-7345 [email protected]

VENEZUELA Tel: + 58 212 991-4545 + 58 212 992-9703 + 58 212 991-7775 Fax: + 58 212 991-9705 [email protected]

ITALY Tel +39 (0) 2 75 419-642 Fax: +39 (0) 2 75 419-644 [email protected] NETHERLANDS Tel: +31 (0) 20 65 45-361 Fax: +31 (0) 20 65 45-368 [email protected] NORDEN (Denmark, Estonia, Iceland, Finland, Norway, Sweden) Tel: +46 (0) 8 519 920-10 Fax: +46 (0) 8 519 920-12 [email protected]

POLAND Tel: +48 (0) 22 556 25 20 Fax: +48 (0) 22 556 25 22 [email protected] RUSSIA Tel: +7 095 232-0214 Fax: +7 095 232-3385 [email protected] SPAIN (Also Portugal) Tel: +34 91 375-3026 Fax: +34 91 375-3028 [email protected]

SWITZERLAND Tel: +41 (0) 1 439 53-66 Fax: +41 (0) 1 439 53-68 [email protected] TURKEY (Also Middle East) Tel: +90 (0) 216 485-0972 Fax: +90 (0) 216 485-0973 [email protected] [email protected] UK Tel: +44 (0) 207 519-5054/55 Fax: +44 (0) 207 519-5056 [email protected]

MUMBAI, INDIA Tel: +9122 2837-0472 Tel: +9122 2839-2624 Tel: +9122 2837-0449 [email protected] INDONESIA Tel: +6221 530-7181/82 Fax: +6221 530-7183 [email protected] OSAKA, JAPAN Tel: +816 6838-5544 Fax: +816 6838-5566 [email protected] TOKYO, JAPAN Tel: +813 5566-8661 Fax: +813 5566-8682 [email protected]

KOREA Tel: +822 554-6622/6934 Fax: +822 554-6944 [email protected] MALAYSIA Tel: +603 5513-1448/28/98 Fax: +603 5512-8311 [email protected] PHILIPPINES Tel: +632 848-7188 Fax: +632 848-7191 [email protected] SINGAPORE Tel: +656 223-3778 Fax: +656 226-0853 [email protected]

TAIWAN Tel: +8862 2508-0212 Fax: +8862 2504-3543 [email protected] THAILAND Tel: +662 267-8103 Fax: +662 236-0041 [email protected]

LATIN AMERICA CUSTOMER SERVICE ARGENTINA Tel: + 54 11 4314-8971/0659/ 3293 Fax: + 54 11 4314-8976 [email protected]

BRAZIL Tel: + 55 11 3649-0469 Fax: + 55 11 3835-4212 [email protected]

EUROPE & AFRICA CUSTOMER SERVICE AFRICA Tel: +49 (0) 2236 9649-237 Fax: +49 (0) 2236 9649-212 [email protected] AUSTRIA Tel: +43 (0) 1 360 27-71220 Fax: +43 (0) 1 360 27-71221 [email protected] BELGIUM Tel: +32 (0) 2 626-49 30/34 Fax: +32 (0) 2 626-49 32 [email protected] BULGARIA Tel: +359 (0) 2 958-2596 Tel/Fax: +359 (0) 2 850-5480 [email protected]

CZECH REPUBLIC Tel: +420 (0) 2 72 123-332 Fax: +420 (0) 2 72 123-305 [email protected] FRANCE Tel: +33 (0) 1 49 93 21-58/59 Fax: +33 (0) 1 49 93 21-62 [email protected] GERMANY Tel: +49 (0) 2236 9649-260/64/66 Fax: +49 (0) 2236 9649-295 [email protected] HUNGARY Tel: +36 (0) 1 385-8288 Fax: +36 (0) 1 466-2550 [email protected]

ASIA PACIFIC CUSTOMER SERVICE N.S.W. AUSTRALIA Tel: +612 9648-5177 Fax: +612 9647-1608 [email protected] VICTORIA, AUSTRALIA Tel: +613 9899-5082 Fax: +613 9899-5102 [email protected] BEIJING, CHINA Tel: +8610 6515-6265 Fax: +8610 6515-6267 [email protected] CHENGDU, CHINA Tel: +8628 8557-1040 Fax: +8628 8557-2313 [email protected]

™ Trademark registration applied for

GUANGZHOU, CHINA Tel: +8620 3758-9970 Fax: +8620 3758-9907 [email protected] SHANGHAI, CHINA Tel: +8621 6249-3900 Fax: +8621 6249-3908 [email protected] HONG KONG Tel: +852 2881-6108 Fax: +852 2895-1250 [email protected] HYDERABAD, INDIA Tel: +9140 2335-1009 Fax: +9140 2335-1009 [email protected]

® Registered trademark of the ISP group

© International Specialty Products. 2002 Designed & Printed in USA.

Product Code HI&I Formulation Guide 5/2003

The information contained in this brochure and the various products described are intended for use only by persons having technical skill and at their own discretion and risk after they have performed necessary technical investigations, tests and evaluations of the products and their uses. While the information herein is believed to be reliable, we do not guarantee its accuracy and a purchaser must make its own determination of a product’s suitability for purchaser’s use, for the protection of the environment, and for the health and safety of its employees and the purchasers of its products. Neither ISP nor its affiliates shall be responsible for the use of this information, or of any product, method, or apparatus described in this brochure. Nothing herein waives any of ISP’s or its affiliates’ conditions of sale, and WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY PRODUCT FOR A PARTICULAR USE OR PURPOSE. We also make no warranty against infringement of any patents by reason of purchaser’s use of any information, product, method or apparatus described in this brochure.

Formulation Isp

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