Equilibrio Liquido Vapor Etanol-Agua Uniquac, Wilson NTRL

CONSTANTES DE ANTONE! SE OBTENEN DEL DATA BAN"# COMPONENTES

ETANOL

A

B

C

x1

agua

18.3036

3816.44

-46.13

 

0.0303

etanol

18.9119

3803.98

-41.66

 

0.0606

n propanol

17.5439

3166.38

-80.15

 

0.0909 0.1212

A12

A21

-117.3 7.3381 381

425.7 5.7681 681

0.1515  

0.1818 0.2121 0.2424 0.2727

Diagonal

0.3030

0

1

 

0.3333

1

0

 

0.3636 0.3939 0.4242 0.4545 0.4848 0.5151

0.5454 0.5757 0.6000 0.6363 0.6666 0.6969 0.7272 0.7575 0.7878 0.8181

Mol$%&l$ ETANOL  AGUA N-!TOANOL

'1 1.8701 3.0198 2.42 l1 -0.13 .1396

(1 1.724 2.9160 1.3 l2 -1.5008

SISTEMA ETANOL,AGUA Y N-PROP 1.0000 0.9000 0.8000 0.7000 0.6000

AGUA

0.5000 0.4000 0.3000 0.2000 0.1000 0.0000 0

0.1

0.2

0.3

0.4

0.5

ETANOL

0.6

0.7

0.8

0.9

A)*A x2

x3

ln(ϒ1)

+

ln(ϒ2)

ln(ϒ3)

ϒ1

0.21

0.7597

8.3140

-0.4287397039 0.23579919 0.69069944 0.6513294456

0.2200

0.7194

8.3140

-0.3802362819 0.24878727 0.34838778 0.6836998442

0.23

0.6791

8.3140

-0.3292861274 0.26214425 0.71548538 0.7194371366

0.2400

0.6388

8.3140

-0.275735322 0.27591264 0.96160303 0.7590137984

0.25

0.5985

8.3140

-0.2193376328 0.29014273 0.13965956 0.8030505362

0.2600

0.5582

8.3140

-0.1598138157 0.30489437 0.27300228 0.8523024596

0.27

0.5179

8.3140

-0.0968459197

0.2800

0.4776

8.3140

-0.0300703802 0.33626423 0.44931049 0.9703772358

0.29

0.4373

8.3140

0.0409304128 0.35307492

0.3000

0.3970

8.3140

0.1166384882

0.3708017 0.53962397 1.1237131207

0.31

0.3567

8.3140

0.1976131732

0.389607 0.55881656 1.2184909577

0.3020

0.3344

8.3140

0.2386730969 0.38198346 0.56277725 1.2695634445

0.281

0.3251

8.3140

0.2477258612 0.35544974 0.56054357 1.2811086825

0.2750

0.3008

8.3140

0.2948985022 0.35200919

0.262

0.2835

8.3140

0.324679869 0.33880522 0.53757873 1.3835876457

0.2430

0.2722

8.3140

0.3384787919 0.31749296 0.52349032 1.4028119976

0 23

0 2549

8 3140

0.3684116612 0.30580162 0.50341453 1.4454369468

0.3202393 0.37386209 0.9076958534 0.5036675 1.0417796085

0.5509421 1.3429900413

0.2150

0.2396

8.3140

0.3929743509 0.29201942 0.48187624 1.4813803928

0.21

0.2143

8.3140

0.4463152224 0.29379899 0.44872271 1.5625439378

0.1950

0.2050

8.3140

0.4576009927 0.27957099 0.43052538 1.5802783347

0.17

0.1937

8.3140

0.466021655 0.25200063 0.40530213 1.5936415093

0.1600

0.1734

8.3140

0.5053712625 0.24714684 0.37030428 1.6576008112

0.13

0.1731

8.3140

0.4848068441 0.21419693 0.36000264 1.6238613201

0.1000

0.1728

8.3140

0.4645860991 0.18234343 0.35014888 1.5913553891

0.09

0.1525

8.3140

0.502450505 0.17886664 0.31377648 1.6527664248

0.0800

0.1322

8.3140

0.5408641969 0.17597716 0.27541654

0.07

0.1119

8.3140

0.5798313923 0.17368829

1.717490471

0.2351871 1.7857373163

Φ1

0.0241040851 0.0495797705 0.0765475573 0.1051424881 , 10

 

0.1355164081 0.1678406631 0.2023093328 0.2391431317 0.2785941394 0.3209515781 0.3665489149 0.402398268 0.4286810524 0.4661918529 0.4981967808 0.5244805717 0.5558388696 0.5850040248 0.6245746224 0.6444476225 0.6704367077 0.7042024051 0.7137309091 0.7226947378 0.7546670225 0.7867976902 0.8190879205

NOL

Column G Column B

1

SSTEMA SOBA+CO

ϒ2

ϒ3

P!--g#

T

P/1

/2

/3

1.26592007 1.99511051

760.04

3.521E"02

5 .20E"02

7.79E"02

3.65E"02

1.28246918 1.41678154

760.04

3.530E"02

3 .53E"02

8.08E"02

3.80E"02

1.29971402 2.04517914

760.04

3.538E"02

3 .65E"02

8.34E"02

3.93E"02

1.31773274 2.61588645

760.04

3.547E"02

3 .78E"02

8.62E"02

4.07E"02

1.33661824 1.14988227

760.04

3.555E"02

3 .91E"02

8.91E"02

4.22E"02

1.35648171 1.31390324

760.04

3.564E"02

4 .05E"02

9.21E"02

4.38E"02

1.37745735 1.45333671

760.04

3.573E"02

4 .19E"02

9.52E"02

4.54E"02

1.39970883 1.56723119

760.04

3.581E"02

4 .33E"02

9.85E"02

4.70E"02

1.42343778 1.65477906

760.04

3.590E"02

4 .48E"02

1.02E"03

4.87E"02

1.44889573 1.71536171

760.04

3.598E"02

4 .62E"02

1.05E"03

5.03E"02

1.47640046 1.74860191

760.04

3.605E"02

4 .75E"02

1.08E"03

5.18E"02

1.46518785 1.75554131

760.04

3.611E"02

4 .87E"02

1.10E"03

5.31E"02

1.42682221 1.75162437

760.04

3.615E"02

4 .95E"02

1.12E"03

5.40E"02

1.42192159 1.73488668

760.04

3.617E"02

4 .98E"02

1.13E"03

5.44E"02

1.40326999 1.71185696

760.04

3.616E"02

4 .95E"02

1.12E"03

5.41E"02

1.37367957 1.68790872

760.04

3.610E"02

4 .84E"02

1.10E"03

5.28E"02

1 35771294

760 04

3 598E"02

4 63E"02

1 05E"03

5 04E"02

1 6543605

1.33912902

1.6191094

760.04

3.580E"02

4.31E"02

9.79E"02

4.68E"02

1.34151422 1.56631027

760.04

3.554E"02

3 .88E"02

8.85E"02

4.19E"02

1.3225623 1.53806537

760.04

3.534E"02

3.58E"02

8.19E"02

3.85E"02

1.28659685 1.49975556

760.04

3.603E"02

4 .72E"02

1.07E"03

5.14E"02

1.28036711

1.4481752

760.04

3.604E"02

4 .73E"02

1.07E"03

5.15E"02

1.2388666

1.4333332

760.04

3.602E"02

4.70E"02

1.06E"03

5.12E"02

1.20002624 1.41927883

760.04

3.601E"02

4 .67E"02

1.06E"03

5.09E"02

1.19586125

1.3685838

760.04

3.595E"02

4.56E"02

1.03E"03

4.96E"02

1.19241082 1.31707918

760.04

3.588E"02

4 .44E"02

1.01E"03

4.83E"02

1.18968467 1.26514545

760.04

3.580E"02

4 .31E"02

9.79E"02

4.68E"02

Φ2

θ 1

θ 2

τ 12

τ  21

0.97589591

0.0230371263 0.9769628737 1.04089703 0.8646391538

0.95042023

0.0474399576 0.9525600424 1.04078831 0.8649669198

0.92345244

0.0733336478 0.9266663522 1.04069285 0.8652548665

0.89485751

0.1008591248 0.8991408752 1.04059512 0.8655497472

0.86448359 0.83215934 0.79769067 0.76085687 0.72140586 0.67904842 0.63345109 0.59760173 0.57131895

0.1301756568 0.1614639357 0.1949298049 0.2308087931 0.2693716662 0.3109312724 0.3558510488 0.3913004396 0.4173646061

0.53380815

0.454673234

0.8698243432 0.8385360643 0.8050701951 0.7691912069 0.7306283338 0.6890687276 0.6441489512 0.6086995604 0.5826353939

1.04049559 1.04039492 1.04029404 1.04019432 1.04009761 1.04000649 1.03992442 1.03985607 1.03980766

0.8658502166 0.866154282 0.8664590712 0.8667605247 0.867052989 0.8673286911 0.8675770755 0.8677840034 0.8679306317

0.545326766 1.03978687

0.8679936

0.50180322

0.4866082407 0.5133917593 1.03980386 0.8679421392

0.47551943

0.5129055586 0.4870944414 1.03987058 0.8677400675

0.44416113

0.5443640515 0.4556359485 1.04000096 0.8673454114

0.41499598

0.5737048117 0.4262951883 1.04021019 0.8667125526

0.37542538 0.35555238 0.32956329 0.29579759 0.28626909 0.27730526 0.24533298 0.21320231 0.18091208

0.6136412536 0.6337536301 0.6601121283 0.694453549 0.7041641641 0.7133072247 0.7459814237 0.7789163774 0.8121152196

0.3863587464 0.3662463699 0.3398878717 0.305546451 0.2958358359 0.2866927753 0.2540185763 0.2210836226 0.1878847804

1.04051377 1.04074966 1.03994487 1.03994074 1.03995824 1.03997553 1.04004365 1.04012196 1.04021019

0.8657953434 0.8650834853 0.8675151765 0.8675276878 0.8674747098 0.8674223666 0.8672162284 0.8669793417 0.8667125526

1

2

3

S*MA

0.01350238 0.9862150953 0.0002825275 0.9997174725 0.01927032 0.9809873405

1.268E"01 1.0002576562

0.03143092 0.9687824687

1.890E"01 1.0002133851

0.04572253 0.9544527609

2.498E"01 1.0001752887

0.0625708 0.937572146

1.135E"01 1.0001429436

0.08249042 0.9176254594

1.342E"01 1.0001158838

0.10610019 0.8939934216

1.535E"01 1.0000936134

0.1341366 0.8659390278

1.711E"01 1.0000756233

0.16746203 0.8325993792

1.866E"01

1.000061412

0.20706032 0.7929901879

1.994E"01 1.0000505116

0.25400755 0.7460349688

2.089E"01 1.0000425205

0.29553895 0.7099772847

2.145E"01 1.0055162331

0.32846896 0.6830229269

2.175E"01 1.0114918878

0.37346563 0.6341490613

2.169E"01 1.0076146884

0.40985171 0.5865285005

2.128E"01 0.9963802069

0.433256 0.5392264777

2.053E"01 0.9724824826

0.45363906 0.4779840322

1.927E"01 0.9316230934

0.45824258 0.4134356203

1.759E"01 0.8716782005

0.4597651 0.3349092732

1.537E"01 0.7946743697

0.44689529 0.2920139145

1.394E"01 0.7389092067

0.62980295 0.3506560592

1.779E"01 0.9804590054

0.6872445 0.3128150773

1.721E"01 1.0000595751

0.699658 0.3004047242

1.693E"01 1.0000627241

0.71124383 0.2888221191

1.667E"01 1.0000659537

0.75174399 0.2483359379

1.571E"01 1.0000799272

0.79094381 0.2091549856

1.473E"01 1.0000987943

0.82858617 0.1715381045

1.374E"01 1.0001242794

agua etanol

CONSTANTES DE ANTONE!SE OBTENEN DEL DATA BAN"#  A # $ 18.3036 3816.44 -46.13 18.9119 3803.98 -41.66

n propanol

17.5439

3166.38

PA+AMET+OS DE LSON!OBTENDO DE TABLA DE P+A*NT# A12 A21 A31 975.49 276.76 1128.2 A13 A23 A32

-80.15

1338.8

102.671

LN &1

ln'2

ln'3

-40.8745

DATOS DE E*LB+O L*DO APO+!TOMADO DE LO+A1992# ag&a

$anool

%1

%2

n 'oanol %3

&1

0.09

0.56

0.3500

3.09984731 1.86800931 2.34378908

22.19

0.11

0.54

0.3500

3.68692559 1.72039727 1.94845781

39.921922

0.19

0.48

0.3300

2.12259152 1.29471962 2.91231317

8.352756

0.3

0.45

0.2500

0.86967542 0.85698327

2.0342806

2.386136

0.4

0.39

0.2100

0.36177156 2.43958695 1.31580329

1.435871

0.5

0.35

0.1500

0.13863471 1.97240824 1.58968831

1.148704

0.6

0.3

0.1000

0.08131559 2.36012778 2.69415857

1.084713

0.8

0.19

0.0100

0.44883083 3.58298626 2.82322453

1.566480

SINTEMA ETANOL, AGUA, N!"O!ANOL 1 0.9

0.8 0.7 0.6

AGUA

0.5

C

0.4

C

0.3 0.2 0.1 0 0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

ETANOL

1

SISTEMA ISOBARICO

agua

Y2 6.47539 5.58675 3.64997 2.35604 11.46830 7.18797 10.59230 35.98083

Y3   10.4206465   7.01785638   18.3993101   7.64674907   3.72774423   4.90222072   14.7930662   16.8310354

P 760 760 760 760 760 760 760 760

T

p(p1

p(p2

p(p3

&1

313.770482 57.0554287 138.706151 54.0754052 0.05401477 318.140754 71.7455132 173.006526 69.3568903 0.02918771 318.435131 72.8420231

175.55684 70.5062954 0.23733151

337.43636 181.722093 424.494569 188.117739 0.52581368 345.942262 263.530038 608.146289 278.916408 0.80339304 354.060322 368.616654 841.579128 397.019406 0.89742953 358.208775 434.635677 987.185293 471.751056 0.96721841 355.471437 390.057393 888.944317 421.252997 0.99506239

0

1

1

0

lumn C lumn L

etanol

n-propanol

&2

&3

)u*a

0.47384878 0.47204912 0.99991267 0.42460571

0.5464967 1.00029013

0.56930826 0.19332949 0.99996926 0.3419565 0.13208303

0.9998532

0.04249824 0.15350153 0.99939282 0.04397245 0.05857338 0.99997535 0.02180448 0.01089037 0.99991326 0.00451462 0.00107191 1.00064893

SISTEMA ETANOL -AGUA -N PROPANOL

Componentes

1 2 3

ethanol water n propanol

CONSTANTS ! ANTO"N#!ATOS TO$A!OS ! !ATA %AN&' ANTA ANTB ANTC 18.9119 3803.98 -41.68 18.3036 3816.44 -46.13 17.5439 3166.38 -80.15

Parametos de interaccion del chemcad i  Bi Bi

ALP!A "#

1 1 2

2 3 3

-55.1581 -1.28794 1005.23

670.441 28.3007 223.596

0.3031 0.3007 0.485

T"(

T("

R

SISTEMA ISOBARICO Presion

T $%&

'"

'(

')

1.987 1.987 1.987

760 760 760

346.79748483 352.73058996 356.89599504

0 0.09 0.18

0.56 0.51 0.46

0.44 0.4 0.36

-0.080045236 0.9729415689 -0.078698835 0.9565762046 -0.077780325 0.9454118109

1.987 1.987 1.987 1.987 1.987 1.987 1.987

760 760 760 760 760 760 760

356.13459891 354.59502761 352.07591118 349.2136532 346.23318353 343.18183536 339.5426185

0.27 0.36 0.45 0.54 0.63 0.72 0.81

0.41 0.36 0.31 0.26 0.21 0.16 0.11

0.32 0.28 0.24 0.2 0.16 0.12 0.08

-0.077946616 -0.078285042 -0.078845175 -0.079491413 -0.080175697 -0.080888566 -0.08175553

0.9474330492 0.9515465889 0.9583549407 0.9662099001 0.9745272984 0.9831921571 0.9937300079

1 0.9 0.8 0.7 0.6

fraccion olar a#$a

0.5 Column AM 0.4

Column E

0.3 0.2 0.1 0 0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

fraccion olar !"anol

1

T")

T)"

T()

T)(

G"(

G("

G")

G)"

-0.001869054 0.0410698741 1.4587861621 0.3244817114 1.0245584212 0.7446070946 1.0005621825 0.9877262336 -0.001837615 0.0403790583 1.4342486485 0.3190237665 1.0241403902 0.7483097761 1.0005527237 0.9879314336 -0.001816168 0.0399077861 1.4175092434 0.3153003758 1.0238553088 0.7508462915 1.000546271 0.9880714448

-0.001820051 0.0399931068 1.4205398 0.3159744706 1.023906915 0.7503864359 1.0005474392 0.9880460953 -0.001827953 0.0401667478 1.4267074621 0.3173463602 1.0240119498 0.7494514267 1.0005498167 0.9879945069 -0.001841032 0.0404541424 1.4369156078 0.3196169854 1.0241858173 0.7479064449 1.0005537517 0.9879091286 -0.001856122 0.0407857164 1.4486929915 0.3222366604 1.0243864492 0.7461279187 1.0005582917 0.9878106347 -0.0018721 0.041136811 1.4611637358 0.3250105614 1.0245989355 0.7442492966 1.000563099 0.9877063529 -0.001888746 0.0415025726 1.474155447 0.3279003425 1.0248203454 0.7422972253 1.0005681071 0.9875977265 -0.001908989 0.0419473971 1.4899554411 0.3314147775 1.0250896796 0.7399300936 1.0005741978 0.9874656355

G()

G)(

*"

0.4928692818 0.8543847754 0.4973652956 -0.401718423 -2.261342323 0.1146701594 0.3244817114 0 0.4987698089 0.8566494161 0.4904960518 -0.26814431 -1.183390754 0.3824952625 0.234717399 0.0404081919 0.5028356092 0.8581977894 0.4859976735 -0.179949858 -0.662137891 0.7004095277 0.1684314287 0.0885627354

0.5020970742 0.8579172595 0.4875190813 -0.121443015 -0.385628137 0.9806378317 0.1183271092 0.1493677581 0.5005973873 0.85734662 0.4901560111 -0.080639648 -0.225190022 1.2024081542 0.0777423889 0.2278093028 0.4981250795 0.856402984 0.4942692276 -0.052127969 -0.129120004 1.3675505981 0.0440481402 0.3330674556 0.4952878844 0.8553155787 0.4992803758 -0.032236638 -0.070746035 1.4863117317 0.0153965168 0.4804687921 0.4923012703 0.8541656604 0.5052476 -0.01859405 -0.035592837 1.5699765973 -0.00937801 0.7000213974 0.4892090421 0.8529693483 0.5128550185 -0.009566546 -0.015223564 1.6291605943 -0.031089964 1.059399551 0.4854745616 0.8515166996 0.524945075 -0.003993181 -0.004481694 1.6761008952 -0.050428353 1.7517545545

*(

*)

P+p"

P+p(

0 1.3833135045 1.4587861621 0 0 4.3007359624 629.31804706 273.2467182 0.2174906141 1.6365922847 1.0587817169 -0.051520445 0.0704267988 2.9378795247 798.26642231 349.32576256 0.2733920574 1.6995885995 0.7961761091 -0.113163495 0.1026305903 2.1938175596 938.27954275 412.7525953

0.2724713308 1.7162920829 0.6133102736 -0.19137744 0.1144845291 1.7098700316 911.25954457 400.48882381 0.246960374 1.7376125369 0.4745551053 -0.292897675 0.1138503589 1.3438085569 858.60504086 376.62168523 0.2118146582 1.8020596379 0.3655854744 -0.43021213 0.1057551882 1.041986026 777.93918956 340.14394669 0.1734223091 1.9528456529 0.2773261427 -0.62460943 0.0929804501 0.7754569295 694.07987473 302.34383551 0.1349301144 2.2831898033 0.2042688114 -0.918778084 0.0773131171 0.5287729446 614.94718917 266.80213467 0.0978601584 3.0838220278 0.1427683225 -1.412532735 0.0599225967 0.2982444534 541.92505431 234.12987459 0.0629254125 5.8372022428 0.0903144867 -2.408662513 0.0416282105 0.1026202687 464.50805454 199.64180338

+,agonal P+p)

,"

,(

,)



289.77965523 0 0.2785159081 0.7215222962 1.0000382044 375.24994425 0.03615787 0.3836433716 0.5802311199 1.0000323616 446.94413677 0.1556478785 0.424597919 0.4644539505 1.044699748

'

,

0 0.1 0.2

1 0.9 0.8

433.05662293 0.3174686943 0.3708103645 0.3117770701 1.0000561289 406.06267175 0.4890285958 0.3099896346 0.2010364974 1.0000547278 364.90072449 0.6299237392 0.2500230263 0.1200699334 1.0000166989 322.3878476 0.7329924904 0.2019894995 0.0657889185 1.0007709085 282.57306273 0.8003094713 0.1683205024 0.0314562085 1.0000861822 246.13729359 0.8364154202 0.1520031294 0.0115909078 1.0000094574 207.88791299 0.8297835743 0.1686690185 0.002245633 1.0006982258

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.7 0.6 0.5 0.4 0.3 0.2 0.1 0