CH4 H2O
Reaksi Pada suhu 1000 K, P 5 atm = P=
CO -H2
CH4
1
H2O
1
5 atm
Komponen
CH4
H2O
CO
M
1
1
B
0.29
0.29
0 .2 9
S
0.71
0.71
0 .2 9
Rumus Kesetmbangan (K)
Kone!si CH4"
K=( 〖〖 ( 〗 _2) 〗 ^3 〖〖 ( 〗 _) 〗 ^ #n$uk %& 'a$m an H2O CH4 "1)/ 11 & maka *a!ga Kp aa+a* " %e!*i$ungan ni+ai K +ama K" Perbandingan=
Kone!si H2O" 1 . 422 ,
( 〖〖 ( 〗 _2) 〗 ^1 〖〖 ( 〗1_4) .42279〗 ^1 ) 〖 () 〗 62
K=( 〖〖 ( 〗 _2) 〗 ^3 〖〖 ( 〗 _) 〗 ^1)/ ( 〖〖 ( 〗 _2) 〗 ^1 〖〖 ( 〗 _4) 〗 ^1 ) 3
CH4 H2O
1
Komponen
CH4
H2O
CO
M
-
1
B
S
-/
1/
(-/)(42)
(1/)(42)
(42)
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.24,092211,
0.0511-
1.-515'
, . 259 7
0.4-,02'0955
0.72',9
0.595,9
14.500,
0.'0'47-1494
1.422'9
0.00020
15.,491
0.'5,,07590'
2.''-50
/1.1-0,1
1,.950-
0.5211'7524-
4.0'7--
/2.5-4''
20.70'-
0.555,007471
5.0--,0
/4.51102
22.2257
0.7057094,41
,.'421'
/7.119-5
2-.''70
0.7415477'7
11.54145
/10.21,57
24.7215
1.422'9
0.00020
15.,491
oa+ Seek 0.'0'47-1494
Perbandingan=
CH4
2
H2O
1
Komponen
CH4
H2O
M
2
1
B
S
2/
1/
(2/)(-2)
(1/)(-2)
(-2)
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.29000-,-,
0.-05,-
1.11'9'
14.'002
0.411,9,714'
1.422,1
/0.00002
20.'949
0.'0'49'-91,
-.705,2
/2.2,404
2'.274,
0.',170---7
7.'1'''
/5.09277
29.0,'2
0.54'0,074'-
1-.20'95
/11.7,-17
-2.2'40
0.59,27-,0-9
21.1-7-'
/19.714'5
-4.91-7
0.74-0950-74
-1.570'0
/-0.24771
-7.1'4,
0.7,091,4504
4'.15'57
/4-.742,9
-9.04'9
0.,12,41,,4,
51.9,10'
/50.'',27
40.5421
oa+ Seek 0.411,9,714'
1.422,1
/0.00002
20.'949
Perbandingan=
CO
CH4
1
H2O
2
Komponen
CH4
H2O
CO
M
1
2
B
S
1/
2/
(1/)(-2)
(2/)(-2)
(-2)
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.29000-,-,
0.-05,-
1.11'9'
29.0004
0.411,9,714'
1.422,1
/0.00002
41.1,99
0.'0'49'-91,
-.705,2
/2.2,404
'0.'49'
0.',170---7
7.'1'''
/5.09277
',.170-
0.54'0,074'-
1-.20'95
/11.7,-17
54.'0,1
0.74-0950-74
-1.570'0
/-0.24771
74.-095
0.7,091,4504
4'.15'57
/4-.742,9
7,.091,
0.,12,41,,4,
51.9,10'
/50.'',27
,1.2,42
1.422,1
/0.00002
41.1,99
oa+ Seek 0.411,9,714'
Perbandingan=
CH4
1
H2O
3
Komponen
CH4
H2O
CO
M
1
-
B
S
-/
1/
(1/)(42)
(-/)(42)
(42)
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.24,092211,
0.0511-
1.-515'
24.,092
0.-'40925541
0.2,010
1.1425,
-'.409-
0.4-,02'0955
0.72',9
0.595,9
4-.,02'
0.'0'47-1494
1.422'9
0.00020
'0.'47-
0.'5,,07590'
2.''-50
/1.1-0,1
'5.,,0,
0.5211'7524-
4.0'7--
/2.5-4''
52.11',
0.555,007471
5.0--,0
/4.51102
55.5,01
0.7057094,41
,.'421'
/7.119-5
70.5709
0.7415477'7
11.54145
/10.21,57
74.154,
1.422'9
0.00020
'0.'47-
oa+ Seek 0.'0'47-1494
8abe+ Hubungan n$a!a Rasio CH4H2O engan Kone!si %aa % " ' a$m Rasio CH4H2O -
2
1
0.'0'47-1
0.411,9,7
0.2900000
Kp
1.422'9
1.422,1
1.42279
Kone!si CH4
15.,491
20.'949
29.0000
Kone!si H2O
'0.'47-
41.1,99
29.0000
Kone!si CH4
0.29
-H2 0.,7 0.,7
mo+ $o$a+"
2.',
29 29
〖 () 〗 62
-H2 - -
mo+ $o$a+"
-(42)
Kone!si H2O 24.,092
42
4-.,02' '0.'47'5.,,0, 52.11', 55.5,01 70.5709 74.154, '0.'47-
-H2 - -
mo+ $o$a+"
-2
mo+ $o$a+"
-2
-(-2) Kone!si H2O 29.0004 41.1,99 '0.'49' ',.17054.'0,1 59.,274 74.-095 7,.091, ,1.2,42 41.1,99
-H2 - - -(-2) Kone!si H2O 14.'002 20.'949 2'.274, 29.0,'2 -2.2'40
-7.1'4, -9.04'9 40.5421 20.'949
-H2 - -
mo+ $o$a+"
42
-(42) Kone!si H2O ,.2597 11.,0-1 14.500, 15.,491 1,.95020.70'22.2257
7!a:k Kone!si CH4 (an H2O s Rasio CH41H2
2-.''70
50.0000
24.7215
'0.0000
15.,491 & i s ! e n o K
40.0000 -0.0000 20.0000 10.0000
0.'
0.--
0.411,9,7
0.'0'47-1
1.422,1
1.422'9
41.1,99
'0.'47-
20.'949
15.,491
0.0000
0
0.'
1
1.'
2
Rasio CH4H2O
2.'
-
pa(a ' a$m
CH4 H2O
-.'
%e!baningan pe!eaksi 11 $api a+am be!bagai a!iasi $ekanan Pada suhu 1000 K, P 5 atm = P=
CH4
1
H2O
1
5 atm
Komponen
CH4
H2O
CO
-H2
M
1
1
B
0.29
0.29
0.29
0.,7
S
0.71
0.71
0.29
0.,7
Rumus Kesetmbangan (K)
#n$uk %& 'a$m an H2O CH4 " 11 & maka *a!ga Kp aa+a* " %e!*i$ungan ni+ai K +ama K"
K=( 〖〖 ( 〗 _2) 〗 ^3 〖〖 ( 〗 _) 〗 ^1)/ ( 〖〖 ( 〗 _2) 〗 ^1 〖〖 ( 〗 _4) 〗 ^1 ) 〖 () 〗 6
1.4227,52-'5
Kone!si CH4&
29
Kone!si H2O&
29
K=
K=( 〖〖 ( 〗 _2) 〗 ^3 〖〖 ( 〗 _) 〗 ^1)/ ( 〖〖 ( 〗 _2) 〗 ^1 〖〖 ( 〗 _4) 〗 ^1 ) 〖 () 〗 6
1.42279
Komponen
CH4
H2O
CO
-H2
M
1
1
B
-
S
1/
1/
-
(1/)(22)
(1/)(22)
(22)
-(22)
Kone!si H2O
P=
3 atm
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.-54-21024
1.42290
/0.0001
-5.4-21
-5.4-21
0.41190-2-22
2.'-541
/1.11-5
41.190-
41.190-
0.'0'49'-91,
7.1'574
/'.7-40
'0.'49'
0.',170---7
1'.,90-5
/14.4575
',.170-
'0.'49' ',.170-
0.54'0,074'-
-0.,',09
/29.4-'-
54.'0,1
54.'0,1
0.59,27-,0-9
''.00'72
/'-.',29
59.,274
59.,274
0.74-0950-74
92.-72-1
/90.949'
74.-095
74.-095
0.7,091,4504
14,.4121-
/145.9,9-
7,.091,
7,.091,
0.,12,41,,4,
2-0.-7-97
/22,.9'12
,1.2,42
,1.2,42
0.,-97,149,7
-47.7-921
/-45.-154
,-.97,1
,-.97,1
1.42290
/0.0001
-5.4-21
-5.4-21
oa+ Seek 0.-54-21024
P=
1 atm
K=
1.42279
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
Kone!si H2O
0.220-120'09
0.017'7
1.40'2
22.0-12
22.0-12
0.-1'--10,-1
0.0,229
1.-40'
-1.'--1
-1.'--1
0.-9199201
0.222'0
1.200-
-9.1992
-9.1992
0.4'7-'5,-24
0.47224
0.9'0'
4'.7-'7
4'.7-'7
0.'14-92-1'-
0.,7-,4
0.'4,9
'1.4-92
'1.4-92
0.'50,921,',
1.42211
0.0007
'5.0,92
'5.0,92
0.5094,274,-
2.-'774
/0.9-'0
50.94,-
50.94,-
0.549-92--
-.',9'5
/2.155,
54.9-92
54.9-92
0.5,'055'422
'.27914
/-.,'5-
5,.'057
5,.'057
1.42211
0.0007
'5.0,92
'5.0,92
oa+ Seek 0.'50,921,',
P=
0.3333333333 atm
K=
1.42279
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
Kone!si H2O
0.-54-1-4-,
0.005-2
1.415'
-5.4-1-
-5.4-1-
0.'121,'07--
0.0-41'
1.-,,5
'1.21,'
'1.21,'
0.51,1-52'1-
0.10-24
1.-19'
51.,1-5
51.,1-5
0.59,70025'
0.24'54
1.1772
59.,700
59.,700
0.75107-4,99
0.'1157
0.9111
75.107-
75.107-
0.,095'7594
0.9779-
0.4449
,0.95',
,0.95',
0.,47',-,,75
1.7'721
/0.--44
,4.7',4
,4.7',4
0.,772291'55
-.01017
/1.',74
,7.7229
,7.7229
0.90041,0757
4.9''4-
/-.'-25
90.041,
90.041,
0.'1207
0.9107
75.11-7
75.11-7
oa+ Seek 0.7511-57'0'
P=
0.2 atm
K=
1.42279
3i+ai ($!ia+)
Kp $!ia+
(Kp/Kp $!ia+)
Kone!si CH4 ()
Kone!si H2O
0.-20,49-1-'
0.00-'5
1.4192
-2.0,49
-2.0,49
0.4'-9212
0.01,1,
1.4045
4'.-921
4'.-921
0.''-45-,744
0.0'25'
1.-701
''.-454
''.-454
0.5-24-99219
0.1199,
1.-02,
5-.2440
5-.2440
0.595-9,01,
0.2-940
1.1,-4
59.5-9,
59.5-9,
0.74,'50574'
0.4-,',
0.9,42
74.,'51
74.,'51
0.7912-14757
0.7'574
0.5551
79.12-1
79.12-1
0.,-45021149
1.4227,
0.0000
,-.4502
,-.4502
0.,'47925--4
1.9,719
/0.'544
,'.479-
,'.479-
1.4227,
0.0000
,-.4502
,-.4502
oa+ Seek 0.,-45021149
8abe+ Hubungan an$a!a %e!uba*an 8ekanan engan Kone!si CH4 an H2O %aa %e!baningan 11 '
-
8ekanan& a$m 1
K
1.42279
1.42290
0.29
0.-54-21024
Kone!si CH4&
29
-5.4-21
Kone!si H2O&
29
-5.4-21
1.42211
0.'50,921,', '5.0,92 '5.0,92
0.---------
0.'1207
0.7511-57'0' 75.11-7
75.11-7
n$o$a+
2.',
2
n$o$a+
22
Kone!si CH4 pa(a Be!bagai 8ekanan (engan %e!ban(ingan 1)1 90 ,0 70 50 4 & '0 i s !
CH4
n o K
-0 20 10 0
0
1
2
-
4
'
5
8ekanan& a$m
0.2 1.4227,
Kone!si H2O pa(a Be!bagai 8ekanan (engan %e!ban(ingan 1)1
0.,-4502 ,-.4502
90
,-.4502
70
,0
50 4 & '0 i s ! e 40 n o -0 K
H2O
20 10 0
0
1
2
-
8ekanan& a$m
4
'
5
Untu !"# CH4=
1
Reaksi Se;a!a umum Komponen
CH4
H2O
M
a
b
B
S
(a/)
K=
-
(b/)
-
CH4H2O
3i+ai ($!ia+)
Kp $!ia+
0.--
0.'0'474212,
1.4225
0.411,997909
1.422,
a$m
' Mo+ H2O (b)
Mo+ CH4 (a)
1
-
1
2
0.'
1
1
1
0.2,997-1'55
1.4222
2
1
2
0.411,997909
1.422,
-
1
-
0.'0'472,4,7
1.4225
CH4H2O
3i+ai ($!ia+)
Kp $!ia+
0.--
0.51,1,,4459
1.42-2
0.'12212'-,7
1.42-1
%aa %"
a$m
Mo+ H2O (b)
Mo+ CH4 (a)
1
-
1
2
0.'
1
1
1
0.-54-211001
1.4229
2
1
2
0.'12212'-,7
1.42-1
-
1
-
0.51,1,,4'-2
1.42-2
CH4H2O
3i+ai ($!ia+)
Kp $!ia+
0.--
0.,'499-,947
1.422,
0.7''5-',572
1.4224
%aa %"
a$m
1 Mo+ H2O (b)
Mo+ CH4 (a)
Mo+ CH4 (a)
-H2
1.42279
%aa %"
%aa %"
CO
1
-
1
2
0.'
1
1
1
0.'50,919974
1.4221
2
1
2
0.7''5-',572
1.4224
-
1
-
0.,'499-,947
1.422,
3i+ai ($!ia+)
Kp $!ia+
a$m
0.---------Mo+ H2O (b)
CH4H2O
1
-
0.--
0.97-'5,410'
1.4227
1
2
0.'
0.9-'941'2-9
1.4229
1
1
1
0.7511',2--'
1.422,
2
1
2
0.9-'941'2-9
1.4229
-
1
-
0.97-''54'9-
1.4220
CH4H2O
3i+ai ($!ia+)
Kp $!ia+
0.--
0.9,9,5024,5
1.4227
0.972917',99
1.4222
%aa %"
a$m
0.2 Mo+ H2O (b)
Mo+ CH4 (a)
1
-
1
2
0.'
1
1
1
0.,-45021105
1.422,
2
1
2
0.972917',99
1.4222
-
1
-
0.9,9,5022,2
1.4227
Kone!si CH4 8e!*aap Rasio CH4H2O paa Be!bagai
50.00 '0.00 40.00 -0.00 20.00 10.00 0.00 0.00
0.'0
1.00
1.'0
2.00
8ekanan& a$m
2.'0
-.00
-.'0
mo+ $o$a+"
K=( 〖〖 ( 〗 _2) 〗 ^3 〖〖 ( 〗 _) 〗 ^ 1)/ ( 〖〖 ( 〗 _2) 〗 ^1 〖〖 ( 〗 _4) 〗 ^1 ) 〖 () 〗 62
ab2
(Kp/Kp $!ia+)
Kone!si CH4 ()
Kone!si H2O ()
0.0002
'0.''
15.,491404254
0.0000
41.19
20.'949,9'4-1
0.0005
29.00
2,.997-1'5'95
0.0000
20.'9
41.1,99790,5-
0.0002
15.,'
'0.'472,4,7-'
(Kp/Kp $!ia+)
Kone!si CH4 ()
/0.0004
51.,2
20.5052,1'547
/0.000-
'1.22
2'.5105259-4'
/0.0001
-5.4-
-5.4-21100092
/0.000-
2'.51
'1.2212'-,591
/0.0004
20.51
51.,1,,4'-249
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.0000
,'.'0
2,.4997954,,7
0.0004
7'.'5
-7.7,179--524
0.0007
'5.09
'5.0,91997-,7
0.0004
-7.7,
7'.'5-',57249
0.0000
2,.'0
,'.499-,9455,
(Kp/Kp $!ia+)
Kone!si CH4 ()
Kone!si H2O ()
Kone!si H2O ()
Kone!si H2O ()
0.0001
97.-5
-2.4'22,0-'15
/0.0001
9-.'9
45.7970751972
0.0000
75.12
75.11',2--454
/0.0001
45.,0
9-.'941'2-944
0.000,
-2.4'
97.-''54'9-22
(Kp/Kp $!ia+)
Kone!si CH4 ()
0.0001
9,.99
-2.99'-41520,
0.0005
97.29
4,.54',794952
0.0000
,-.45
,-.4502110521
0.0005
4,.5'
97.2917',992-
0.0001
--.00
Kone!si H2O ()
9,.9,5022,17
Kone!si H2O 8e!*aap Rasio CH4H2O paa Be!bagai
& O 2 H i s ! e n o K
50 '0 40 -0 20 10 0 0.00
0.'0
1.00
1.'0
2.00
8ekanan& a$m
2.'0
-.00
-.'0
an
' a$m - a$m 1 a$m 1- a$m 1' a$m
