Ferrero Toys Testing Protocol 2016

S.A. FINDEL BUSINESSCENTER COMPLEXE B,RUE DE TRÈVES, L-2632 FINDEL, Luxembourg TEL: (352) 34 97 11-1 FAX: (352) 34 94 11 - R.C. LUXEMBOURG: B 176980 Soremartec S.A. is a Company of theFERRERO

GROUP

FERRERO TOYS TESTING PROTOCOL

VERSION 2016 Valid from: 11 October 2016

This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.

Group Quality Department

FERRERO TOYS TESTING PROTOCOL 8-1-018-16

Valid from: 11/10/16 Page 2 of 69

Document valid from:

11 October 2016

Document issued by:

Soremartec S.A. - FINDEL BUSINESS CENTER COMPLEXE B, RUE DE TRÈVES, L-2632 FINDEL, Luxembourg

This version cancels and substitutes the previous version. The changes to the previous version are highlighted in yellow. The srcinal signed copy of this document is kept at the Ferrero Luxemburg DQG offices. In case of printing, the copy shall be considered uncontrolled document; therefore, it is needed to verify the update on the company portal my.ferrero.com Issued by: Work group: DQG – KSC – CHEMICAL EXPERT – LEGAL OFFICE – NOMINATED

CERTIFICATION AND TESTING LABORATORIES (UL – TÜV/LGA) Verified by: Dario Quassolo:

Kinder Surprises Products Quality Account & Surprises Quality

Jianpierre Stüder: DQG Laboratory Monica Battistel: DQG Food safety Matteo Abrate: KSC Quality Gerhard Neuberger: Chemical expert Roberto Testa: Legal toys safety department Approval Directions Group Quality Department

Salvatore Ranchetti Toy Safety and IP Director

Daniele Lingua Kinder Surprise Company

Alessandro Nervegna





SUMMARY SCOPE Requirements

0.1 1.0

Green List .................................................................................................................................... 6 Additional Mechanical Tests based on ISO and voluntary requirements .................................. 8

1.1

Test on Fitness for Use – Production Quality / Corrosion ........................................................ 13

1.2

Test on Fitness for Use – Mounting / Handling / Use Instructions / Mounting Instructions ... 13

1.3

Test on Fitness for Use – Function Test ................................................................................... 14

1.4

Test on the Fitness for Use – Durability (10 x Drop Test: 138 cm) ........................................... 14

1.5

Safety assessment..................................................................................................................... 14

1.7

Quality-Test on the aggressiveness of the loose adhesive (sticker) on various standard test surfaces (24 hours label on surface) ........................................................................................ 14

1.8

Test according to EN ISO 105-E04 "Colourfastness of textiles against sweat" ........................ 15

1.9

Test on Proper Odour ............................................................................................................... 15 MECHANICAL TESTS ..................................................................................................................... 16

2.1

Tests according to EN 71-1 in the last harmonized version ..................................................... 16

2.2

Cross Cut Test following EN ISO 2409 ....................................................................................... 16

2.3

Adhesion of Stickers.................................................................................................................. 16

2.4

Soaking Test .............................................................................................................................. 16

2.5

Test according to EN ISO 105-X12 "Colourfastness against Rubbing" ..................................... 16

2.6

Test Washing characteristics of textile toys according to EN ISO 6330 .................................. 17

2.7

Colourfastness to water ............................................................................................................ 17

2.8

Physical – Mechanical tests on Kinder-Surprise one-piece capsule ......................................... 17

3.1

ELECTRIC COMPLIANCE................................................................................................................ 19 Test according to EN 62115 " Electric Toys – Safety" in the last harmonized version ............. 19

3.2

Test according to EMC Directive (2014/30/EC) "Electromagnetic Compatibility" ................... 19

3.3

Test according to 2011/65/EU (RoHS 2) on the restriction of the use of certain hazardous substances in electrical and electronic equipment ................................................................. 19

3.4

Marking according to WEEE Directive 2012/19/EU.................................................................. 19 FLAMMABILITY............................................................................................................................. 21

4.0

Test according to EN 71 "Safety of Toys" - Part 2 "Flammability" in the last harmonized version ...................................................................................................................................... 21

4.1

Test Flammability on Textile part of dolls, Hairs, and Soft filled toy, according to Canadian Toy Regulation SOR /2011-17 ......................................................................................................... 21





CHEMICAL TESTS .......................................................................................................................... 22 5.1

Test according to ISO 8124-3 .................................................................................................... 22

5.1a Test according to EN 71-3 "Migration of certain Elements" .................................................... 22 5.1bis Test according to Canadian Regulation "Migration of certain Elements" ............................... 23 5.2

Test on the Release of Nickel according to EN 1811 (Nickel Release) in case of coated materials in addition according to EN 12472 (abrasion and corrosion test) - legal requirement ............................................................................................................................. 24

5.4

Heavy Metals Content including nickel.................................................................................... 24

5.5

Mercury and Arsenic ................................................................................................................. 24

5.6

Test on the resistance to saliva and sweat ............................................................................... 25

5.7

Test following EN 646 "Determination of Bleeding in case of Coloured Papers" .................... 25

5.8

Solvent and monomers ............................................................................................................. 25

5.9

Determination of the Formaldehyde Release (Wood, Textiles, Paper, stickers ) .................... 26

5.10 pH Value .................................................................................................................................... 26 5.11 Test on regulation (EC) No 1907/2006 annex XVII on the Existence of the Arylamines listed in Annex I, No 43 after Reductive Splitting of the Azo Dye including ӦekoTex Standard 100 .... 27 5.12 Test on colorants which are classified as carcinogenic and/ or causing allergic reactions incl. Disperse yellow 23 and Disperse orange 149 .......................................................................... 28 5.13 Preservatives............................................................................................................................. 29 5.14 Flame Retardants ...................................................................................................................... 29 5.15 Phenols...................................................................................................................................... 30 5.16 Wood Preservatives .................................................................................................................. 30 5.17 Organotins................................................................................................................................. 30 5.18 Monomers................................................................................................................................. 31 5.19 N-Nitrosamines and N-Nitrosatable substances release .......................................................... 32 5.20 Optical Brighteners ................................................................................................................... 32 5.21 Determination of plasticizers.................................................................................................... 32 5.22 Determination of NonylPhenol and NonylPhenol ethoxylate content .................................... 33 5.23 Determination of Solvent Migration......................................................................................... 33 5.24 Dermal Irritation ....................................................................................................................... 33 5.25 Primary aromatic amines in case of food contact .................................................................... 34 5.26 Cellulose Nitrate ....................................................................................................................... 34 5.27 Formamide and Dymethylformamide ...................................................................................... 34 5.28 Toluene Based on Chile Legislation .......................................................................................... 35 5.29 Japanese Food sanitization law ................................................................................................ 35 This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




5.30 Arnolds base Michlers Ketone .................................................................................................. 35 5.31 UV prints ................................................................................................................................... 35 MICRO BIOLOGICAL TESTS ........................................................................................................... 37 6.1

Microbiological Test - Mould Fungi .......................................................................................... 37

6.2

Microbiological Control ............................................................................................................ 37 OTHER TESTS ................................................................................................................................ 38

7.1

Verification of the Formula and Safety Data Sheets ................................................................ 38

7.2

Food Contact tests applicable only to packaging in contact with fatty food (e.g. capsule) ..... 39

7.2.1 Overall Migration According to Regulation (EU) No 10/2011 and further amendments ........ 39 7.2.2 Food grade declarations according to Regulation (EU) No 10/2011 and further amendments ............................................................................................................................................................ 39 7.2.3. Test on Colour Release (acc. to Italian Law DM 21-03-73) ...................................................... 39 7.3

Test on the Total Content of Lead, Cadmium, Mercury and Chromium (VI) in Packaging Materials (European Directive 94/62/EC) ................................................................................ 40

7.4 Test according to Directive 2006/66/EC (including amendment 2013/56/EC) on Batteries and Accumulators containing Hazardous Substances .................................................................... 40 7.5

Test on the Release of Dysprosium (luminescent materials) ................................................... 41

7.6

Release of Antimony (Textile Materials) .................................................................................. 41

7.7

Test on content of polycyclic aromatic hydrocarbons (PAHs).................................................. 41

7.8

Fragrances ................................................................................................................................. 42

8.1

REACH SVHC .............................................................................................................................. 42

ANNEX I – List of solvents .................................................................................................................... 43 ANNEX II - Test Procedures of Cross Cut Test Rev.1 ............................................................................ 57 ANNEX III - Parts to be considered as articles according to REACH..................................................... 60 ANNEX IV - Synoptic table full protocol ............................................................................................... 61 ANNEX V - Synoptic table reduced Protocol ........................................................................................ 66





SCOPE The aim of this Quality manual is to collect in one guide line all the Ferrero requirements applicable for the testing of surprises and promotional articles defined as “toys” . It is regularly updated on yearly base (or when there will be important changes in the legislation) taking into account the progresses of the legislation and the need to maintain the protection of the Ferrero brand always at the highest level. The green list’s annex will be updated separately in case of new amendments. For what it concerns the standards, in all the cases the last version of the standards shall be applied, in particular in case of harmonized standard. It is possible to find the reference of the latest version of the standards : - EN standards: https://www.cen.eu -> insert the standard reference in “search standards” + check “committee: CEN/TC 52”” - ISO standards: http://www.iso.org -> use the search engine

REQUIREMENTS 0.1

Green List

All materials for Green list must be produced from reliable suppliers with clear and reproducible coding. • Resins - Test according to EN 71 part 3 (para. 5.1a) - Test on the total content of lead, cadmium, mercury and chromium (VI) (para. 5.4) - Test on Primary aromatic amines (only in case of PUR and PA plastics) (para. 5.11) - Test on plasticizers (para. 5.21) - Determination of the content of Acrylonitrile, Styrene and Butadiene - Test on Polycyclic aromatic Hydrocarbons- PAHs (all colours) (para. 7.7)

according to5.17) REACH (para. 8.1) -- SVHC Organotins (para. - BPA total content (Any new material_ Total content 5 mg/kg) - N-Nitrosamines on sintetic natural rubber, elastomer (e.g. TPE, SBS) (para.5.19) - Toluene according with Chile Legislation (170 mg/kg) (para. 5.28) • Paints - Test according to EN 71 part 3 (para. 5.1a) - Test on the total content of lead, cadmium, mercury and chromium (VI) (para. 5.4) - Test following EU Directive 2002/61/EC on the existence of the arylamines listed in Annex I, No 43 after reductive splitting of the azo dye (para. 5.11) - Test for solvents (para. 5.8) according to annex Green list for solvents and monomer residues. - Test on plasticizers (para. 5.21) This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




- Test on primary aromatic amines (all materials) (para. 5.11) - Test on colorants (all materials, except white colorants) (para. 5.12) - Test on the release of Dysprosium (luminescent materials) (para. 7.5) - Test on Polycyclic aromatic Hydrocarbons- PAHs (all colours) (para. 7.7) - SVHC according to REACH (para. 8.1) - Canadian Regulation "Migration of certain Elements" (para. 5.2) (para. 5.17) -- Organotins BPA total content (Any new material_ Total content 5 mg/kg) • Pigments/ Colourants - Test according to EN 71 part 3 (para. 5.1a) - Test on the total content of lead, cadmium, mercury and chromium (VI) (para. 5.4) - Test following EU Directive 2002/61/EC on the existence of the arylamines listed in Annex I, No 43 after reductive splitting of the azo dye (para. 5.11) - Test on primary aromatic amines (all, except white materials) (para. 5.11) - Test on colorants (all materials, except white pigments/ colorants) (para. 5.12) - Test on the release of Dysprosium (luminescent materials) (para. 7.5) - Test on Polycyclic aromatic Hydrocarbons- PAHs (all colours) - SVHC according to REACH (para. 8.1) - Organotins (para. 5.17) - BPA total content (Any new material_ Total content 5 mg/kg)

• Other Materials - Test according to EN 71 part 3 (para. 5.1a) - Test on the total content of lead, cadmium, mercury and chromium (VI) (para. 5.4) - Test following EU Directive 2002/61/EC on the existence of the arylamines listed in Annex I, No 43 after reductive splitting of the azo dye (para. 5.11) - Test for solvents (para 5.8) according to annex Green list for solvents and monomer residues if any solvent is part of the composition - Test on primary aromatic amines (para. 5.11) - Test on colorants (all materials, except white materials) (para. 5.12) - Test on plasticizers (para. 5.21) - Assessment of the safety data sheets and of the formula (para. 7.1)

- Test on Polycyclic aromatic Hydrocarbons- PAHs (all colours) (para. 7.7) - SVHC according to REACH (para. 8.1) - Organotins (para. 5.17) - Arnolds base respectively Michlers ketone (only on Blue and violet inks to be used in stamps ) (para. 5.30)




1.0


Additional Mechanical Tests based on ISO and voluntary requirements

The additional requirements included into this section are complementary to all requirements included into official standard EN 71 and ISO 8124, therefore all products to be considered as CONFORM shall PASS all tests included into EN 71 and ISO 8124. PERFORM EACH TEST ON THREE DIFFERENT SAMPLES Note: take 9 samples, Mark 3 samples as “a” samples Mark 3 samples as “b” samples Mark 3 samples as “c” samples Each of the three “a” samples has to be subjected to all the applicable test corresponding to a “X” in the “a” column in the sequence defined in the table below. Each of the three “b” samples has to be subjected to all the applicable test corresponding to a “X” in the “b” column in the sequence defined in the table below. Each of the three “c” samples has to be subjected to all the applicable test corresponding to an “X” in the “c” column in the sequence defined in the table below. Sample

a B X

Test

Description

c § 1.0.1.

Requirement: 1,5 mm. thickness

CORDS THICKNESS APPLICABLE ONLY ON : 

Plush toys

Cords and elastics with a diameter <1,5mm are allowed only if their length, (measured in accordance with cl. 4.11.1 of ISO 8124-1) is less than 50mm after the tension test of cl. 8.4.2 of EN71-1

X

§ 1.0.2.a CORDS



Toys suitable for children under 36 months (without 0-3 warning)



Toys with cords connected to a self retraction mechanism



Pull along toys

APPLICABLE ON ALL TOYS:

LENGHT The length of cords and elastics ATTACHED TO TOYS shall be less than 220mm when measured according to cl. 4.11.1 of ISO 8124-1 The length of “free ends” cords ( this means cords not attached to the toy, but free on both sides, for example a ribbon for the bag attached to soft filled toy) shall be less than 300 mm when measured according to cl. 4.11.1 of ISO 8124-1 Two cords that are attached at one point and that can entangle (e.g. Knot, bowl, grip, Velcro ) : the length measured form end to end shall not exceed 220 mm.





Any fixed loop (loop in a cord fixed by any permanent means that doesn’t detach with 25 N) shall have a perimeter less than 360 mm. (an example of fixed loop is an ELASTIC) x

§ 1.0.2.b CORDS (in self retraction cord-activated mechanism)

APPLICABLE ONLY ON: 

Toys with cords connected to a self retraction mechanism

Accessible cords used in cord-activated mechanism shall comply to requirements of 4.11.2 of ISO 8124-1 and EN 71 part 1 point 5.4 e)

X

§ 1.0.3. SHARP ALL ITEMS: Check the presence of accessible sharp edges or sharp points with 4.7 Edges EDGES AND SHARP and 4.8 Points POINTS

X

§ 1.0.4. DROP TEST

Height of Drop: 138cm. The test is conform if after 10 drops no elements break.

-Method: If the toy has to be assembled, the test has to be carried out on the assembled item. When and if after some drops some parts of the toy result disassembled, rebuilt the toy and go on until 10 drops. Make the ten drops on all the different sides of the sample (all the 6 faces of the toy should be tested at least once) When only a part of the toy is submitted for testing, DROP TEST is not applicable (N/A) Use equipment specified into ISO 8124

X

§ 1.0.5.

- In case of breaking take a picture on graph paper of the broken piece and indicate its dimension. Please check if on broken pieces there are any sharp edges and/or sharp points. Torque: 0,45 Nm. The test is conform if no elements break.

TORQUE TEST Torque and tension tests shall be applied to: When the test is not applicable due to sample/detail shape, indicate the part with arrows and circle on photo anyway. Table with results shall be filled with N/A* due to “clamps failure” or “clamps slippage”.

-

each part of the item that protrudes for a length of 6mm or more Measurements shall be taken on the longest side of the protruding part ( example: a nose protrudes 4 mm. On the upper side and 6,3 mm. On the bottom side: this has to be tested because is considered > 6mm.);

-

to all preassembled pieces of any dimension, for pre-assembled we mean welded, glued or otherwise specified by MPG;

-

to parts of any dimension made of soft material (see details in Method);

-

to flat surfaces regardless of their dimension: fix the whole clamps on the flat part of the toy along the border (in the most critical position for ex. corners) ; test shall be applied only when at least 7,5 mm. of the clamps (half the surface) can be fixed on the part to be tested, otherwise the test is not applicable;

-

to connecting parts of two structure when the connecting part is about 50% width of the connected parts: for example head and body of a figure: if the neck (connecting part) has a width of 5mm. and the head or the body has a width of 10 mm. the neck is a part to be tested;

-

to paper having a weight of more than 400 gr /m2



Group Quality Department -


to plasticized paper independently from its specific weight

Torque and Tension Tests shall not be applied to : T00 (Kinder Surprise) small decals made of paper only or slightly plasticized - Method: Apply the torque once in a clockwise direction and once in an anticlockwise direction until you reach the required torque force. If the material is soft and it doesn’t reach the required torque you have to apply a torque of 180 ° once in a clockwise direction and once in an anticlockwise direction  

Time to reach the required torque: 5 seconds Time to keep under torque: 10 seconds

Note on method to apply clamps:

- It’s possible to apply torque test even not keeping the toy into clamps in a perfect horizontal position: this allows to carry out a safety check on a part which protrudes. - When and if there are any other protruding part of the toy which creates obstacle (impediment) during torque, go on to torque the part to be tested and if the required force (0,45Nm) is reached, consider the test as pass. This way to carry out torque test really simulates child behaviour while handling the toy. Specify this situation with a note. - Clamps shall be fixed on protruding part in a way that doesn’t change the structure of the part. In case of breaking take a picture on graph paper of the broken element and indicate its dimension and the strength of breaking. Please check if on broken pieces there are any sharp edges or sharp points. When the breakage is partial (not completed detached) give a FAIL and write a note, take a new sample for tension test. Method for soft materials (example SBS): this method is applied only when previously agreed with Ferrero. The applied torque is 360° and a sort of “bite-manipulation test” is applied X

§ 1.0.6. A

Force: 70 N The test is conform if no elements break.

TENSION TEST For SOFT FILLED TOYS Force: 90 N When torque test is fail, take a new sample to carry out axial and perpendicular test.

When it is not possible to complete the perpendicular test in all the 4 directions on a single sample because of a breakage, take new samples to complete the perpendicular test. Method: An axial and perpendicular tension (4 directions) must be applied to the same parts/ testing points on which torque test has been applied :

- apply UL-IISG clamps for axial tension and compression gauge for perpendicular tension

- if, during the perpendicular test, you have a slippage without reaching 70 N, apply the tension with IISG clamps in the 4 main directions. ON WHEELS USE ASTM CLAMPS FOR AXIAL TENSION. This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




Time to reach the required tension: 5 seconds Time to keep under tension: 10 seconds In case of breaking take a picture of the broken element and indicate its dimension and the strength of breaking. Please check if on broken pieces there are any sharp edges and/or sharp points  

When the breakage is partial (not completed detached) give a FAIL and write a note, take a new sample for other tension tests. X

§ 1.0.6. B

(1) Suction cups attached to the toy:

-

The toy or the part of the toy attached to the suction cup shall not pass entirely through template E

-

Suction cups shall not become detached from a toy when tested according to torque test, tension test, drop test, impact test and compression test

-

If the suction cup becomes detached from a toy when tested according to torque test, tension test, drop test, impact test and compression test, this is written in the test report. In case this is considered as acceptable by MPG for the specific toy, a “Pass” rating is given if the detached suction cup does not pass entirely through template E. A “Fail” rating is given if the detached suction cup passes entirely through template E

SUCTION CUP TEST

(2) Loose suction cups, removable suction cups and suction cups attached to a toy by a string, elastic cord or similar tether shall not pass entirely through template E. Method: Position and clamp template E (a template with a circular hole with a diameter of 44.5mm and a thickness of 6.4mm) so that the axis of the slot is substantially vertical and the slot is unobstructed at its top and bottom openings. Place the suction cup without compressing it, in any orientation in the slot so that the force on the suction cup is only the force due to its mass. Determine whether the suction cup passes entirely through template E. For test method for torque test, tension test, drop test, impact test and compression test, see the specific methods defined in EN 71-1, with the following parameters: Torque: 0.34Nm Tension: 90 N Drop height: 850mm; number of drops: 5 Impact test weight: 1kg; impact mass diameter: 80mm; drop height: 100mm; number of impacts: 1 Compression force: 110N; compression probe diameter: 30mm; time to reach the maximum force: 5s; time of application of maximum force: 10s. X

X

§ 1.0.7 AIR FLOW

The air flow test, according to ISO 11540 shall apply to each part with holes such as wheels, coins or others round and flat items.

§ 1.0.8 COMPRESSION TEST

Force: 136 N

The test is conform if no elements break. Method: Use a disk of 30 mm diameter. This test must be carried out on the assembled toy in the standing position (position of normal use). After the test the toy can disassemble and this does not influence the result.




 


Time to reach the required compression force: 5 seconds Time to keep under compression: 10 seconds

In case of breaking take a picture of the broken element and indicate its dimension. Please check if on broken pieces there are any sharp edges and/or sharp points.

§ 1.0.9 HOLES

Check holes on single pieces before assembling the toy ( these holes are accessible to children while playing building up the toy). There shall be no circular or substantially circular with a diameter between 5mm and 13mm, if the thickness is less than or equal to 1,6mm (picture N°1) This requirement is satisfied regardless of the thickness of the holes, if a 5 mm. test probe cannot be inserted to a depth greater than 10 mm. (picture N.4) Holes with a diameter between 5mm and 13 mm : N° 1

≤ 1,6mm FAIL N° 2

> 1,6mm

N° 3

≤ 1,6mm

N° 4

>10mm

≤ 1,6mm

N° 5

PASS

≤10mm

PASS FAIL

>10mm

N° 6

FAIL

Note: in this case the thickness of the holes is considered as zero (=0)

> 1,6mm PASS

Holes with a diameter between 5mm and 25 mm (“effetto tubo”): holes (blind or not) To avoidshape the risk that fingers intoshall “tubular completely circular between 5mm entrap and 25mm haveshapes”, a depth greater than 1,6 mm. having but notagreater than 10mm (Note: when a holes has an “insert” along its thickness, the requirement doesn’t apply . See picture N.3) N° 1

=>5mm >1,6 <=10mm

N° 2

PASS

=>5mm >10mm

FAIL



N°3



PASS (for any diameter and depth of the hole)

It being complied standard requirements, the toy design shall be developed taking into account the minimization of hazards, and thus inspired to the “good father behaviour”. § 1.0.10 Projectile toys with stored energy

According with ISO 8124-1 projectile toys with stored energy shall not have projectiles that enter into the small parts cylinder ( including paper, textiles and any other material)

QUALITY CONTROL DURING PRODUCTION TOLERANCE FOR TORQUE AND TENSION TEST

A maximum of 5% defective samples can be accepted provided the samples can stand a torque and a tension force not lower than 10% below the required force (Torque test not lower than 0.40Nm, tension test not lower than 63N) and NO sharp points are created.

1.1

Test on Fitness for Use – Production Quality / Corrosion

• Production Quality The exterior design must not show any clearly visible and/or touchable failures (visual and optic test). • Corrosion (applicable on accessible or visible metal parts. If non

accessible or visible metal parts: only, if the function is affected) Test Method: Following EN ISO 6270-2 Coating substances – Determination of the resistance against humidity

– part 2 „Procedure for stressing of sample materials in condensate climates“ (without salt) – 24 h condensate test at 40° C Limit: No corrosion damages must occur. Minor visual impairments are admissible, provided that the function is

not affected.

1.2

Test on Fitness for Use – Mounting / Handling / Use Instructions / Mounting Instructions

-

Under consideration of the mounting instructions, mounting must be simple and easily to perform. Moving parts as well as detachable connections must be easy to operate in correspondence with the purpose of use. Toys which are already mounted completely must be easy and good to handle. The use instructions / mounting instructions shall be clearly understandable.

-



1.3



Test on Fitness for Use – Function Test

All functions, including repeated assembly and disassembly when required by the nature of the toy (ex. Infinimix), are submitted to a use endurance test under normal stress conditions. Small surprises 50 times, Big surprises 100 times. For writing instrument: 10 meters including roller stamps. For stamps: minimum 40 times stamping. The test shall verify that proper function is maintained throughout the test and no parts, intended to remain attached, detach. The results will be FAIL in the following situations: when parts (intended to remain attached) detach and when function is compromised. In case of FAIL a note will always be present specifying the nature of the fail.

1.4

Test on the Fitness for Use – Durability (10 x Drop Test: 138 cm)

The toy must guarantee a sufficient durability during intended use (ISO 8124-1)

1.5

Safety assessment

A Safety Assessment file shall be prepared by KSC for each single toy and kept in the KSC informatics systems together with the Technical documentation of each toy

1.7

Quality-Test on the aggressiveness of the loose adhesive (sticker) on various standard test surfaces (24 hours label on surface)

This test is only carried out in case of loose stickers Test Method : • upholstery cover textile - flat fabric • upholstery cover textile - pile fabric • upholstery cover leather • upholstery cover artificial leather • floor tile - veneered, varnished • floor tile - laminated • furniture surface kitchen work desk - laminated • furniture surface kitchen furniture front board - film-covered • furniture surface living room table board - veneered, varnished • furniture surface living room cupboard - front board - plastic-coated • furniture surface solid wood oiled • furniture surface solid wood waxed Limit: No permanent changes must occur on the test surface. (When there is a trace that can be easily removed, the test should be considered as PASS)




1.8


Test according to EN ISO 105-E04 "Colourfastness of textiles against sweat"

Test Method : Transition of colour to a multi-fibre accompanying fabric which had been soaked with acid

and/or alkaline sweat solution (contact: 4 h, 40 °C). Multi-fibre accompanying fabric according to ISO 105-F10 Limit:

Requirement according to ӦekoTex standard 100 (current edition) for textiles with and without skin contact: • Resistance to acid sweat: fastness mark 3 - 4 • Resistance to alkaline sweat : fastness mark 3 - 4

1.9

Test on Proper Odour

This test should be applied on finished articles including leaflets. Test Method: A) The articles are stored for 12 hours in an oven at 50°C (carried out by the manufacturer). "Big surprises" B) The article is stored loosely in an air tightly closing glass vessel (preparation jar “Duran Schott Specimen

Jars 157 x 203 mm”) for 24 hours at 20°C ± 2°C. "Small surprises" B) The articles are stored loosely in an air tightly closing glass vessel (preparation jar “Duran Schott

Specimen Jars 65 x 103 mm”) for 24 hours at 20°C ± 2°C. Limit : Scale for the odour behaviour:

• (a) • (b) • (c) • (d) • (e)

no odour very slight - hardly perceptible odour slight odour significantly perceptible odour strong odour

Ferrero requirement: at least (c)

Additional note/ remark to be added on test report about the “perceived fragrance”. During odour test a check shall be performed to verify if there is any “presence of fragrance”. If there is a suspicious of a fragrance further chemical analysis shall be done to confirm the absence of fragrance.

Rating: no fragrances perceived= PASS / smell of fragrances perceived = FAIL : further chemical analysis to be performed.





MECHANICAL TESTS 2.1

Tests according to EN 71-1 in the last harmonized version 2.2

Cross Cut Test following EN ISO 2409

For soft materials: only apply the adhesive tape without cutting Test Method: EN ISO 2409 Limit of cross cut test: 1 piece means : fail (see Annex II for details of the procedure)

NOTE: if the surface is so small or with a shape that does not allow the use of the standard cutter, use a common cutter to cut one or more (as permitted by the painted surface dimensions) little squares with 1mm sides, taking care to cut the whole thickness of the paint. Apply the standard adhesive tape to this cut surface.

2.3

Adhesion of Stickers

To be performed only on stickers- plastic coated or not- with a specific weight of 400 gr/ m2 or more Test Method : In case of all stickers which are already glued on in the state of delivery the test following EN 71, part 1, para. 8.25.2 „Adhesion“ is carried out. Limit: The feeler gauge shall not be inserted more than 2mm in any point and the sticker must not detach.

2.4

Soaking Test

To be performed only on stickers – plastic coated or not- with a specific weight of 400 gr/ m2 or more Test Method: In case of all stickers which are already glued on in the state of delivery test according to EN 71, part 1, para. 5.1 e). Limit: No additional swallowable parts must detach.

2.5

Test according to EN ISO 105-X12 "Colourfastness against Rubbing"

Test Method: EN ISO 105-X12 Limit: Requirement for textiles with and without skin contact:

• Resistance to dry rubbing: fastness mark 4 • Resistance to wet rubbing: fastness mark 3 -4





Final assessment by Ferrero: Step at the grey scale (at least step 3 – 4)

one lab

min. 3 – 4

one lab

3

Final assessment by Ferrero

passed

one lab

4

one lab

2.6

min. 3 –

fail

<3

Test Washing characteristics of textile toys according to EN ISO 6330

Test Method: EN ISO 6330

- 24 hour conditioning of the samples at 20°C ± 2°C and relative air humidity of 65% ± 5% before the test - Washing agent according to EN ISO 6330 "ECE Colour washing agent" - if washing instructions existing, performance of 6 cycles according to it Limit: The sample shall pass all mechanical tests (EN 71 part 1) after 6 cycles.

2.7

Colourfastness to water

To be performed only on textile in Kinder Surprise Test Method: EN ISO 105- E01 Limit: fastness mark 3-4

2.8

Physical – Mechanical tests on Kinder-Surprise one-piece capsule

Test n. 1 – TENSION TEST Test Method: Tension Test of th e connection stripe (“cerniera”) up to breaking. Limit:

of the connection stripe (“cerniera”) shall be at least 150 Breaking strength Newton. Tolerance: 5% of samples with strength 135 N - 150 N.

Test n. 2 – 10 ROTATIONS Test Method: 10 complete rotations anticlockwise (with pre-separation of connection stripe This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




“cerniera”). Limit:

Test is PASS if at least 85% ≥ 9-10 rotations. The remaining 15% could be equal to 8 rotations.

Test n. 3 – ROTATION +3/-3/ TENSION TEST Test Method: 3 complete rotations in anticlockwise direction followed by 3 complete

rotations in clockw ise direction to return to the “0 position”; 3 complete rotations in clockwise direction followed by 3 complete rotations in anticlockwise direction to return to the “0 position” After the rotations, a tension test up to breaking shall be performed. Limit:

No breakage shall occur after the rotations.

Test n. 4 – COMPLETE ROTATIONS OF THE CONNECTION STRIPE “CERNIERA” ONLY Test Method: 3 complete rotations of the connection stripe “cerniera”. Limit:

No breakage shall occur after the rotations.

Test n. 5 – ONE-PIECE CAPSULE OPENING Test Method: Opening strength after axial tension test Limit:

Opening strength shall be at least 11 kg. The average should be maintained at around 15 kg.





ELECTRIC COMPLIANCE Test according to EN 62115 " Electric Toys – Safety" in the last harmonized version

3.1

Clause 15.2 has to be applied always even if exemption of clause 6.1 or 6.2 applies

3.2

Test according to EMC Directive (2014/30/EC) "Electromagnetic Compatibility"

Starting from 20th July 2009 CE mark for EMC shall be printed DIRECTLY on the product. (End of transitional period 20/04/2016)

3.3

Test according to 2011/65/EU (RoHS 2) on the restriction of the use of certain hazardous substances in electrical and electronic equipment

Parameter

Limit

PBB/PBDE

0.1 weight-%

Lead Cadmium Mercury Chromium hexavalent

0.1 0.01weight-% weight-% 0.1 weight-% 0.1 weight-%

Remark:

The test is to be carried out on every material which is separable by mechanical means in all components. Test results will indicate which specific flame retardant is present.

3.4

Marking according to WEEE Directive 2012/19/EU

Technical Standard: EN 50419 Marking general description : Crossed out wheeled bin (the same required for batteries

and defined in EN 61429/A 11) with an horizontal solid bar under the wheeled bin. Minimum size recommended: 1 x 1 cm Minimum dimensions (a=3,33)





The following information should be reported in the leaflet: The crossed-out wheeled bin symbol indicates that waste electrical products shall not be mixed with municipal waste or disposed of as unsorted municipal waste. It is mandatory to collect waste electrical and electronic equipment separately . It is possible to return the waste electrical product to the distributor when purchasing a new one. If necessary, please consult local authorities for more information on the available disposal systems. Incorrect disposal can damage the environment and human health and is sanctioned by law





FLAMMABILITY 4.0

4.1

Test according to EN 71 "Safety of Toys" - Part 2 "Flammability" in the last harmonized version

Test Flammability on Textile part of dolls, Hairs, and Soft filled toy, according to Canadian Toy Regulation SOR /2011-17





CHEMICAL TESTS 5.1

Test according to ISO 8124-3

Test Method : Extraction with 0.07 n hydrochloric acid; determination by means of ICP-OES

Limit

: Antimony Arsenic

Remark

Small surprises and big surprises : Reduced limit value for lead 15 mg/kg

(Sb) 60 (As) 25 mg/kg mg/kg Barium (Ba) 300 mg/kg Cadmium (Cd) 15 mg/kg Chromium (Cr) 15 mg/kg Lead (Pb) 15 mg/kg Mercury (Hg) 60 mg/kg Selenium (Se) 500 mg/kg Underlined and violet text indicates “Ferrero reduced limits”

In the individual case, it is to be clarified by the Ferrero chemical experts, by the Ferrero legal office and by the nominated external laboratories, if the correction factor of 30% according to the standard shall be applied to the reduced values or not. Testing of metallic components not accessible and contained into swallowable finished toys: 1. Test on raw materials: Pre-assessment of components containing metal parts with the above limits, in case a single metal component FAIL the above limits, contact Ferrero to ask additional information about the finished toy. 2. Test on final product (including gear box that shall be considered as 1 part ): the test shall be done on all items which are swallowable (small parts cylinder) even if the metallic components are coated or capsuled.

5.1a Test according to EN 71-3 "Migration of certain Elements" LIMITS: CATEGORY I Dry, brittle, powder like or pliable mg/kg Aluminium Antimony Arsenic Barium Boron Cadmium

CATEGORY II

Liquid or sticky

CATEGORY III Scraped-off mg/kg

mg/kg

5.625

1.406

70.000

45

11,3

60

3,8

0,9

25

300

300

300

1.200

300

15.000

1,3

0,3

15


Group Quality Department Chromium III Chromium VI Cobalt Copper Lead Manganese Mercury Nickel Selenium Strontium Tin Organic Tin Zinc



15

9,4

15

0,02

0,005

0,2

10,5

2,6

130

622,5

156

7.700

2

0,5

15

1.200

300

15.000

7,5

1,9

60

75

18,8

930

37,5

9,4

460

4.500

1.125

56.000

15.000

3.750

180.000

0,9

0,2

12

3.750

938

46.000

Underlined and violet text indicates “Ferrero reduced limits” Remark:

Small surprises and big surprises : Reduced limit value for lead 15 mg/kg Testing of metallic components not accessible and contained into swallowable finished toys: 1. Test on raw materials : Pre-assessment of components containing metal parts with the above limits, in case a single metal component FAIL the above limits, contact Ferrero to ask additional information about the finished toy. 2. Test on final product (including gear box that shall be considered as 1 part): the test shall be done on all items which are swallowable (small parts cylinder) even if the metallic components are coated or capsuled.

5.1bis Test according to Canadian Regulation "Migration of certain Elements"

Applicable on surface coating only (paints) Test Method: Extraction with 5% hydrochloric acid (10 minutes at 20° C); determination by means of ICP-OES Limit:

Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Selenium (Se)

1000 mg/kg 1000 mg/kg 1000 mg/kg 1000 mg/kg 1000 mg/kg

To carry out the analysis on final products we collect all the applied paints mixed together up to 100 mg and perform the test This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




5.2 Test on the Release of Nickel according to EN 1811 (Nickel Release) in case of coated materials in addition according to EN 12472 (abrasion and corrosion test) legal requirement This test is applied, if the part is accessible. Test Method:

EN 12472: • Pre-corrosion at 50 °C • Abrasion with grinding components EN 1811: • Migration 7 days in synthetic sweat solution at 30 °C • Determination of Nickel by means of ICP -OES Limit: Following Regulation EC 1907/2006 (REACH) amendment 17, point 27 b, nickel must not be used in

products which might come in contact with the skin, if the rate of the nickel release from the part of the product which comes directly in contact with the skin, is more than 0,28 micrograms per cm² per week. (Ferrero limit)

5.4

Heavy Metals Content including nickel

(nickel applicable only on accessible metal or metalized components) Test Method:

-

Lead, cadmium, chromium, mercury and nickel: Following ISO 8124-5 for the determination of total concentration of certain elements in toys Chromium (VI): If detected Chromium content lead to an exceeding of the limit value the determination of Chromium VI would be carried out following IEC 62321-7-1 and IEC 62321-7-2

Remark: Total content of lead is not tested in case of cable insulations. Limit:

100 mg/kg (sum of Lead, Cadmium, Mercury and Chromium VI) for the whole article. Cadmium alone 100 mg/kg for each polymeric component and painting. Lead alone 40 mg/kg for each polymeric component and painting. Mercury alone 10 mg/kg for each single painting (surface coating). Nickel alone 1% (10.000 mg/kg) for each single metal or metalized component.

5.5

Mercury and Arsenic

Test Method: ISO 8124-5 Determination of total concentration of certain elements in toys Limit: 100 mg/kg (following EU Regulation 1907/2006 (REACH) – ex EU Directive 76/769/EEC) Remark: Applicable only for wooden parts. This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.


5.6



Test on the resistance to saliva and sweat

Test Method: § 64 LFG B82.02-13 and B82.92-3 -1 Test on the transition of colorants to paper strips soaked with

saliva and sweat simulation solution (contact time: 2 h; 37°C) Limit: Requirement following recommendation 47 of the BfR's plastics commission:

Toys must only be coloured in such a way that during foreseeable use no dyestuff must pass over to the mouth, mucous membranes or skin. On the grey scale (ISO 105-A03) a limit 4-5 is accepted.

5.7

Test following EN 646 "Determination of Bleeding in case of Coloured Papers"

Test Method:

The test is carried out in accordance with procedure B - short-time contact (10 min. 23 plus or minus 2 °C) Test of the transition of colour to fibre-glass papers soaked with olive oil, saliva and sweat simulation solution. Limit: Requirement following recommendation 47 of the BfR's plastics commission:

Toys must only be coloured in such a way that during foreseeable use no dyestuff must pass over to the mouth, mucous membranes or skin. On the grey scale (ISO 105-A03) a limit 4-5 is accepted.

5.8

Solvent and monomers

a) Solvents and monomer residues for painted articles (final product) Articles with a painted area (sum of all painted areas of on toy) below 1 cm 2 will not be analysed for solvent and monomer residues. For bigger areas, the paints are scratched from the surface and analysed: Solvents and monomer in the final product: 1. Extraction by use ofresidues CS2-shaking 4 h/room temperature (200mg of paint and 1 to 2ml of CS2) GC/MS: NO CMT-substances category I, II and III (please refer to CMT-list). If they were found, analysis must be stopped and result discussed with Ferrero. GC/MS-results must be evaluated according to the Ferrero Green list for solvents and monomer residues (see Annex - Green list) 2. Emission chamber method: If the CS2-method shows critical results (above limits), the emission chamber method is applied, according to LGA method. Evaluation of the emission chamber method again according to the Ferrero Green list of solvents. If necessary, the content of solvents /monomer residues in the resins must be analysed and evaluated. list for solvents: see Annex I b) Solvents and monomer residues for liquid and ink (in the f inal product and basic materials) This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




Solvents and monomer residues in the final product: 1. NO CMT-substances category I, II and III (please refer to CMT-list). GC/MS-results must be evaluated according to the Ferrero Green list for solvents and monomer residues (see Annex - Green list) 2. Formula assessment according to paragraph 7.1. Any accessible liquid used in toy should not be classified in accordance with Directive 1999/45/EC as very toxic, harmful, corrosive, irritant and sensitising (according to EN 71.-9, paragraph 4.2) Annex I: Green list for solvents and monomer residues (the list is not exhaustive. In the list have been included the most common solvent and monomers used in liquid toy classified CMT). c) Solvent and monomer residues per printed textiles ( in the final product and basic materials) 1. Sample submitted as complete article: Imprint of textile subbase is not mechanically separable, then CHAMBER TEST. 2. Sample submitted as individual component: Cutting out of printed textile and application of CS2 method

5.9

Determination of the Formaldehyde Release (Wood, Textiles, Paper, stickers )

Test Method:

Wood and textiles: Test procedure according to EN 71-9 The test was carried out following EN ISO 14184-1 Paper: Test procedure according to EN 71-9 EN 645 & EN 1541 Limit for toys intended for children under 3 years (every applicable materials): 16 mg/kg Limit for toys intended for children over 3 years (every applicable materials) : 30 mg/kg Remark: Any paper shall be tested on all toys for formaldehyde (paper of the toys and leaflets) Note about stickers testing : the test shall be performed both on the sticker part and on the support.

5.10 pH Value Test Method:

-

Decals: According to DIN 53124: apply only cold extraction

-

Liquids & Inks: According to EN ISO 787-9

-

Textiles & Tattos: According to EN 1413.

Limit: According to EN 71, part 7: 4-9 This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




5.11 Test on regulation (EC) No 1907/2006 annex XVII on the Existence of the Arylamines listed in Annex I, No 43 after Reductive Splitting of the Azo Dye including

ӦekoTex Standard 100 Full-coloured materials tested on arylamines if the resistance to saliva and sweat according to DIN 53160 plastic is < step 5 on themust grey only scalebe (ISO 105-A03). Test Method:

-

Natural and synthetic fibre (ex. polyester), paper, plastic, coating: EN 14362-1

-

Synthetic fibre (only polyester): EN 14362-1

-

Leather: CEN ISO/TS 17234

Limit: 20 mg/kg ("ӦekoTex Standard 100")

4-aminodiphenyl benzidine 4-chlorine-o-toluidine 2-naphthylamine o-aminoazotoluol 2-amino-4-nitrotoluol p-chloraniline 2,4-diaminoanisol 4,4'-diaminodiphenylmethane 3,3'-dichlorinebenzidine 3,3'-dimethoxybenzidine o-anisidine-2-methoxyaniline Aniline 2,4-xylidine **) *) **)

3,3'-dimethylbenzidine 3,3'-dimethyl-4,4'-diaminodiphenylmethane p-kresidine 4,4'-methylen-bis-(2-chlorineaniline) 4,4'-oxydianilind 4,4'-thiodianiline o-toluidine 2,4-toluylendiamine 2,4,5-trimethylaniline 4-aminoazobenzene *) 2,6-xylidine **)

4-Aminoazobenzene: Official collection of test method according LFGB § 64 B 82.02-9 additional requirements of ӦekoTex Standard 100

Remark: When laboratories detect results between 20 and 30 mg/kg the test shall be repeated and based on

the double checked results Ferrero will make a decision.

• Primary Aromatic Amines PUR and PA plastic materials which are not yet in the green list, must in any case be tested on primary aromatic amines. Test Method: EN 71-10 & EN 71-11

Remark: Apply according to table 2C of EN 71-9 This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




Limit: 5 mg/kg (for each primary aromatic amines listed in table 2 C of EN 71-9) General Remarks

-

Paints and coatings on plastic materials are only to be tested if the available mass is more than 10 mg per item. For masses less than 10 mg the coating has to be tested with its basic material. If the paint or coating is included in the green list, the test must be done only in the way of a random check, if it seems to be necessary.

5.12 Test on colorants which are classified as carcinogenic and/ or causing allergic reactions incl. Disperse yellow 23 and Disperse orange 149 Limit: The following colorants listed in EN 71-9 and " ӦekoTex Standard 100" (current version) must not be

detectable (detection limit: 10 mg/kg fabric) Test Method: According to DIN 54231, the sample material is extracted with methanol in the ultrasonic bath at

70 °C/30 min. The extract is narrowed down and examined by means of HPLC-DAD Disperse Blue 1 Disperse Blue 3 Disperse Blue 106

Disperse Orange 37 Disperse Orange 76 Disperse Red 1

Basic Red 9 Basic Violet 1 Basic Violet 3

Basic Violet 10 Acid Red 26 Disperse Yellow 3 Disperse Blue 7 Direct Black 38 Disperse Blue 35 Direct Blue 6 Disperse orange 149 Disperse Yellow 1 Disperse Orange 1

Disperse Blue 124 Solvent Yellow 2 Disperse Orange 3 Disperse Orange 11 Disperse Yellow 39 Disperse Yellow 49 Direct Red 28 Disperse Brown 1 Disperse Red 17 Navy Blue (Blue Colourant)

Solvent Yellow 1 Acid Violet 49 Solvent Yellow 3 Disperse Yellow 9 Disperse Blue 26 Disperse Blue 102 Basic Violet 14 Disperse Yellow 23 Disperse Red 11

Remark : A: Sewing yarns: Samples of the basic material shall be selected in such a way that seams are also covered. B: Trimmings (embroidery silks for mouth or eyebrow lines etc.) - due to the low quantity of sample material

together with the basic material, the basic material is tested once again separately. Remark:

-

Full-coloured plastic materials and paints/coating are only subject to testing both for colorants, if the resistance to saliva and sweat according to DIN 53160 is < step 5 on the grey scale (ISO 105-A03).

-

Full-coloured plastic materials and paints/coating not already green listed have to be tested in all cases

General Remarks Paints and coatings on plastic materials have only to be tested if the available mass is more

than 10 mg per item. For masses less than 10 mg the coating has to be tested with its basic material. If the paint or coating is included in the green list, the test must be done only in the way of a random check, if it seems to be necessary.





5.13 Preservatives Test on preservatives acc. to Directive (EC) 2009/48, Appendix C; (EC) 2015/2116; (EC) 2015/2117  Methode: - Phenol, Benzisothiazolinone (BIT): EN 71-10 and EN 71-11 - Methylisothiazolinone, Chlormethylisothiazolinone, Octylisothiazolinone: Determination of OIT, CIT, MIT in material after aqueous extraction, quantification by HPLC-DAD

- Formaldehyde total:

Determination after extraction with a capable solvent, derivatisation with DNPH and determination of the derivatives by HPLC-DAD



Limit value: - Phenol: - Benzisothiazolinone (BIT): - Methylisothiazolinone ( MIT): - Chlormethylisothiazolinone (CIT): - Reaction mass CIT/MIT: - Octylisothiazolinone: - Formaldehyde total:

< 10 mg/kg < 5 mg/kg < 0,25 mg/kg < 0,75 mg/kg < 1 mg/kg < 5 mg/kg < 10 mg/kg (detection limit)

5.14 Flame Retardants Test on Flame Retardants according to Annex XVII REACH, POP Ordinance and additional voluntary restrictions Flame retardants are applicable on plastic and textile (in toys for children aged both under and over 3 years) Test the following flame retardants

Tris (2,3-Dibromoprolyl) phosphate (TRIS)_ (CAS number 126-72-7)-

Limit: 25 mg/kg

Tris (aziridinyl) phosphinoxide (TEPA)_ (CAS number 545-55-1) Tri-o-cresyl phosphate (CAS number 78-30-8) Tris (2-chloroethyl) phosphate (TCEP) _(CAS number 115-96-8) Tris (2-chloro-1-methylethyl) phosphate (TCPP) _ (CAS number 13674-84-5) Tris (1,3-dichloro-2-propyl) phosphate (TDCPP)_ (CAS number 13674-87-8)

Limit 50 mg/kg Limit 50 mg/kg Limit 5 mg/kg Limit 5 mg/kg Limit 5 mg/kg

Polibrominated biphenyls (PBBs) Polychlorinated –terphenyls (PCTs) Pentabromodiphenylether Octabromodiphenylether Polybrominated-biphelyn ethers (PBDEs)

Limit Limit 50 50 mg/kg mg/kg Limit 10 mg/kg Limit 50 mg/kg Limit 1000 mg/kg

Test Method:

Extraction with appropriate solvent, afterwards determination by means of GC-MSD and LC-MSD





5.15 Phenols Test Method:

In house method based on saponification with caustic potash solution. After derivatization determination by means of GC-ECD respectively GC-MSD. Limit:

Detection limit: • Pentachlorphenol (PCP) < 1 mg/kg • 2,3,5,6 – Tetrachlorophenol (TeCP) < 1 mg/kg • Ortophenylphenol (OPP) < 5 mg/kg •sum of all three phenols < 5 mg/kg

5.16 Wood Preservatives Test Method: EN 71-10 & EN 71-11 Limit: The wood preservatives indicated in EN 71-9 table 2 G must not be detectable according to EN 71-11 (table

18)

5.17 Organotins TEXTILE, in addition flocking material > 10 cm² (not for KS and KJ)

Test Method : A defined quantity of the material sample is mixed with the internal standard and extracted by methanolic buffered solution by means of acetic acid. Subsequent derivation with sodiumtetra-ethylborate. The obtained derivate is extracted with n-Hexane, the Hexane extract is submitted to a column cleaning and later on determined at the capillary gas chromatograph with mass selective detector. Limits:

MonoButylTin (MBT) DiButylTin (DBT) TriButylTin (TBT)

1.0 mg/kg 0.025 mg/kg 0.025 mg/kg

DioctylTin (DOT) TriphenlyTin (TPT) Tetrabutyl tin Monoctyl tin Methyl tin Di-n-propyl tin Diphenyl tin Tricyclohexyl tin

1.0 mg/kg 1.0 mg/kg 1.0 mg/kg 1.0 mg/kg 1.0 mg/kg 1.0 mg/kg 1.0 mg/kg 1.0 mg/kg

ALL THE OTHER MATERIALS and for all materials of Kinder Surprise (T00) + Kinder Joy toys (KJ)

(excepted metal components) Test Method: Decomposition in the microwave oven. Determination of TIN by means of ICP This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




Limit value of 0,1 % calculated as tin

In case the Tin found is more than 0,1%, perform additional analysis (GCMC) in order to verify the TIN comes from Organotins banned by the law

5.18 Monomers Test Method: EN 71-10 & EN 71-11

Applicable on: (based on Table 1 EN 71- 9) - Tattoo; Glues + Plastic parts for all toys intended for children < 36 months - Components of graphic instruments sold as toys or used in toys - Toy and components of toys which mimic food - Imitation jewellery - Mouthpiece components of mouth-actuated toys Limit:

The monomers indicated in EN 71-9 table 2 D must keep the requirements of EN 71-9 table 2D and EN 71-11 table 7. For Bisphenol A apply a limit of 0,04 mg/l The analysis is performed, depending on the type of plastic material. For styrene, always monomer Styrene must be analysed. For polymeric POM, always formaldehyde must be analysed. Monomers in accordance with EN 71-9

Plastic type ABS SBS SEBS PC PE TPE PP PS Resin PA PA + ABS PET-Polyester Acetal Copolymer EVA Rubber TPR PMMA Acrylic resin PBT POM KResin

Acrylamide x -

Bisphenol A x x x

Formaldehyde x x x

Phenol x x x

Styrene x x x x x x x -

x x x -

-

x x x

x x -

x x X





5.19 N-Nitrosamines and N-Nitrosatable substances release Test Method: EN 71-12including Annex C, A-deviations Limit: Synthetic rubber for toys under 3 years and Natural rubber

0.01 mg/ kg for N-Nitrosamines 0.1 mg/kg for N-nitrosatable substances NOTE: STAMPS are not likely to be put into the mouth therefore the test shall not be applied on pad of stamps.

Limit: Finger Paints

0,02 mg/kg NDELA 1 mg/kg for NDELA after nitrosation

5.20 Optical Brighteners Carry out a preliminary UV lamps checking to identify optical brighteners and if present carry out the following tests: Limit: Grade 4-5 Remark:

Apply this test on: PAPER : Test only in case of articles which are completed made of paper e.g. cover of flip-books, puzzles

(prolonged skin contact paper only) Test according to EN 648 - short time contact 10 min. Testing media: saliva and sweat simulation solution according to DIN 53160 TEXTILE (only for prolonged skin contact textiles, including LABELS even if slightly plasticized) Test according to EN ISO 105-E04 “Colourfastness of Textiles against sweat”

5.21 Determination of plasticizers According to Annex XVII Regulation (EC) No 1907/2006, point 51 and 52 (ex Directive 2005/84/EC Phthalates) Test Method: solvent extraction followed by GC-MS or HPLC-DAD/MS Limit:

bis (2-ethylhexyl)phthalate (DEHP) dibutyl phthalate (DBP) benzyl butyl phthalate (BBP) sum of the three ≤ 0.1 weight -%

di-isononyl phthalate (DINP) di-isodecyl phthalate (DIDP) di-n-octyl phthalate (DNOP) sum of the three ≤ 0.1 weight -% This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.



di-isopropylheptylphthalate (DPHP) di-isobutyl phthalate (DiBP)


≤ 0.1 weight -% ≤ 0.1 weight -%

All other phthalates detachable by the above mentioned test method have also a limit of 0.1 weight -%

•EN 71-9: 2005 (Plasticizers migration ) Test Method: EN 71-10 & EN 71-11 Remark: Apply according to table 2L of EN 71-9 Limit: 0.03 mg/L (for each plasticizer listed in table 2 L of EN 71-9)

5.22 Determination of NonylPhenol and NonylPhenol ethoxylate content Test Method:

NPEO – solvent extraction (methanol, ultrasonic – 40 °C) followed by LC-MSD NP – solvent extraction followed by GC-MSD or LC-MS Limit: According to Annex XVII Regulation (EC) No 1907/2006 REACH Regulation

NonylPhenol < 0.01% by mass NonylPhenol Ethoxylate < 0.01% by mass

5.23 Determination of Solvent Migration Test Method: EN 71-10 & EN 71-11 Remark: Apply according to table 2E of EN 71-9 Limit: Apply according to table 2E of EN 71-9 Remark: The assessment of polymers and paints is included in para. 5.8 “Assessment of solvents”

5.24 Dermal Irritation Test Method: In vitro test on protein matrix followed by an optical density evaluation.

The test method used is a standardize quantitative in vitro testing procedure used to detect, predict and rank dermal irritation potential of cosmetics, consumer products, pharmaceuticals and chemical raw materials. The method is based on the principle that chemicals that cause dermal irritation are known to induce alteration in the structure of keratin, collagen and other dermal proteins. So in the test we mimic the biochemical alteration applying the sample to a synthetic bio barrier composed of a semi-permeable membrane containing a KeratinThis document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




collagen matrix coated with dye. After exposure. we evaluate how the samples promote the conformational changes of the bio barrier, detecting, at a specific wavelength, the change in the turbidity of the protein solution after a contact with the sample. Comparison of these optical density changes to those produced by a standard chemical irritant permit to calculate a specific equivalent score for human related to potential dermal irritation of the material. Limit: Not irritant

5.25 Primary aromatic amines in case of food contact Test Method:

-

Migration with 3% acetic acid / 40° / 10 days Determination in accordance with § 64 LFGB L 00.00-6 (Photometric determination)

Limit:

Following Regulation (EU) No. 10/2011: not detectable (detection limit: 0,01 mg/kg foodstuff) Remark:

Only applicable for PUR and PA, furthermore all coloured plastic materials which come directly in contact with food stuff.

5.26 Cellulose Nitrate Canadian Hazardous Products Act – Schedule I Part 1, Item 7 Test Method: Health Canada, method C-17 (FT-IR Analysis ) Limit: no presence of cellulose Nitrate Remark:

Only applicable on final products as a whole.

5.27 Formamide and Dymethylformamide Test Method:

Formamide: Extraction by means of organic solvent, quantification by means of GS-MS Test procedure acc. to ISO/TS 16189

Dimethylformamide:

Limit: 30 mg/kg (total content) Remark:

Applicable on all toys only on FOAMED PLASTIC material (eg. EVA- Polyethylene (PE) foam or Polyurethane (PU) foam and pad of the stamps)





5.28 Toluene Based on Chile Legislation Decreto nº 158 de 2003, que prohibe el uso del tolueno en juguetes y articulos de uso infantil + amendment decreto 135 del 2004 Test Method: ASTM D 4526, Standard Practice for Determination of Volatiles in Polymers by Static Headspace Gas Chromatography Limit: The residual concentration of toluene on the toy shall not exceed 170mg/kg Remark:

Applicable on plastic and rubber because on paints toluene is already tested under 5.8 Solvents and Monomers residue.

5.29 Japanese Food sanitization law Test Method and Limit: Japanese Food Sanitation Law Remark:

Applicable the complete toy (including decal and leaflets) and components intended to be in direct contact with food (e.g. valve). Specific applicable tests will be chosen based on the BOM/technical sheet of the toy.

5.30 Arnolds base Michlers Ketone Test Method: GC-MS Determination Limit: The total content shall be < 10 mg/kg Remark:

Applicable on blue and violet liquid inks only

5.31 UV prints Limit: It is not allowed to use inks which are applied to the article/toy with the UV printing technology.

This requirement does not apply to part of an article not in close contact with the food item (e.g. an hangtag of a plush, etc..) for which there is no risk of migration of the photo-initiators to the food stuff. Only in case of specific needs to use this kind of technique, it will be necessary to conduct a deeper migration test in the DQG Ferrero laboratories till the end of shelf life of the food in order to check if there is a migration of the photo-initiators to the food. In this case, also the processes of the UV printing technique and the machineries used will be subject to a specific Ferrero certification process procedure. Remark:

We require the testing laboratories to inform DQG Surprise as soon as an item with this technique and characteristic would be proposed for testing. Ferrero DQG Surprise after an internal verification with the involved offices will evaluate if necessary to conduct further internal tests. This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Information Owner prior consent.




List of photo-initiators not allowed:

-

4-Methylbenzophenone Benzophenone Benzyldimethylketal (BDK) Irgacure 184

-

Irgacure 907 Isopropylthioxanthone (ITX) Quantacure (EHA) 4-Benzoylbiphenyl 2 hydroxy-2-methyl-propiophenone Ethyl 4-Dimethylamino-benzoate 2.4-Diethyl-9H-Thioxanthen-9-one Diphenyl(2.4.6Trimethylben) peroxide





MICRO BIOLOGICAL TESTS 6.1

Microbiological Test - Mould Fungi

Test Method:

The determination of mould fungi is performed according to the common microbiological practice. Limit: 500 KBE (colony forming units) per toy

6.2

Microbiological Control

The microbiological control is performed in order to evaluate the risks connected with the presence of pathogen agents. In particular the following should be determined: TPC: max 100cfu/g or ml Enterobacteriaceae: max 10/g or ml Yeasts and Moulds: max 10/g or ml Salmonella spp.: n.d. (Absence / 10 g or ml) Staphylococcus aureus: N.d. (Absence 1 g o ml) Candida albicans n.d.(Absence 1 g o ml) Pseudomonas aeruginosa n.d. (Absence 1 g o ml) Escherichia Coli or Entorococci faecalis in liquids n.d. (Absence 1 g o ml) n.d = not detectable in 1 ml or g.

Test Method: Test for microbial contamination European Pharmacopeia EP_ latest available version_ a) European Pharmacopeia, 7th edition, 2011 (“microbiological examination of non-sterile products”) Chapter 2.6.12 b) European Pharmacopeia, 7th edition, 2011 (“microbiological examination of non-sterile products”) Chapter 2.6.13





OTHER TESTS 7.1

Verification of the Formula and Safety Data Sheets

The Qualitative & Quantitative Formula should be examined in order to evaluate the risks connected with the toy use. In particular the toxicity in contact with the skin has to be considered. Laboratories shall only accept formula on supplier letterhead, with a signature, and a date. (E-mail text will be no more accepted as formula) It’s responsibility of KSC to collect the detailed information in order to identify the composition of the formulas used to produce the toy.

Laboratories will then verify the formula. Depending on the result of the assessment, additional tests may be required. Laboratories will test randomly some of the content of the declared formula about which there are some “technical doubts” Material

1 Any inks, liquids and paste present as such in Toys, e.g. inks present into stamps inks present into felt tip pens / pens Any liquid material even if not accessible present in toy modeling clay dried watercolours

SDS Formula evaluation 1) evaluation required

REACH-conform SDS required 2)

X

X

X

X

X

-

X

-

-

Solid material intended to leave a trace, e.g. wax crayon crayon chalk

Glue that leaves a trace, e.g. glue stick 2 Glue on stickers Material with special physical effects, e.g. Glow in the dark paints or plastic that change colours with temperature or paints or plastic that change colours, when getting wet 3 Raw material, e.g. Resins pigments/colourants paints other materials like solvents, thinners, form release agents, grease )



1) 2)



for ingredients for imported mixture required, not for ingredients

The "SDS evaluation" means: 1. Examination if the SDS contains enough information for an evaluation 2. Evaluation of the material on base of the information given in the SDS:  

7.2

Are there any CMR or SVHC substances, or other critical substances? Is there any substance that restricts the usage of this material for toys?

Food Contact tests applicable only to packaging in contact with fatty food (e.g. capsule)

7.2.1 Overall Migration According to Regulation (EU) No 10/2011 and further amendments Test Method: According to EN 1186-11 with olive oil with contact time 10 d, 40 °C Limit: 10 mg/dm².

7.2.2 Food grade declarations according to Regulation (EU) No 10/2011 and further amendments Food grade declarations for food contact should be provided for material in contact with food stating that the monomers, other starting substances and master batch used for capsules are in compliance with Regulation (EU) No 10/2011 and further amendments. The declaration should highlight any eventual component that would need to be verified with a specific migration test. The laboratory commissioned with the test sorts the documents and states in the test report whether the requirements of the mentioned guidelines are met in regards to the composition and if specific migrations have to be carried out. Specific migration limit values, if analytically possible, have to be checked.

7.2.3. Test on Colour Release (acc. to Italian Law DM 21-03-73) Test Method: Migration of the sample material with olive oil for 10 days at 40°C; subsequently determination of

the transition in the wave length range of 400 – 750 nm and evaluation against a blind value. Limit: The transition of the sample material must be at least 95% of the blind value.



7.3



Test on the Total Content of Lead, Cadmium, Mercury and Chromium (VI) in Packaging Materials (European Directive 94/62/EC)

Test Method:

Lead, cadmium, chromium and mercury:

-

ISO 8124-5 Determination of total concentration of certain elements in toys

-

Chromium (VI): If detected Chromium content lead to an exceeding of the limit value the determination of Chromium VI would be carried out following IEC 62321-7-1 and IEC 62321-7-2

Limit:

-

According to EU Directive 94/62/EC, the concentration of lead, cadmium, mercury and chromium (VI) must cumulatively not exceed 100 mg/kg. Limit for cadmium in certain materials, applications and / or products according to regulation (EC) No 1907/2006 Annex XVII. Limit value: cadmium (Cd) 100 mg/kg

7.4 Test according to Directive 2006/66/EC (including amendment 2013/56/EC) on Batteries and Accumulators containing Hazardous Substances Test Method: Decomposition with aqua regia, measurement by means of ICP-OES. Limit:

Appliances which are marketed with batteries (e. g. toys, watches etc.) must be labelled in accordance with Annex II and Art. 21 of the battery ordinance, if the batteries are to be classified as containing harmful substances, i. e. they exceed the following limit values: Battery type - all batteries: Limit value:

0.0005 weight % mercury 0.002 weight % cadmium *) 0.004 weight % lead *) Acc. to Directive 2006/66/EC (including amendment 2013/56/EC), marketing of portable batteries and accumulator containing more than 0.002 weight % cadmium is prohibited. Remark:

Appliances have to be designed in such a way that waste batteries and accumulators can be readily removed Recommendation:

If the batteries are marketed together with the article, the following note for the consumer shall be given in the mounting instructions and/or use instructions: "Don't give used batteries into the domestic waste, but only give to the existing collecting points."



7.5



Test on the Release of Dysprosium (luminescent materials)

Test Method:

The test is carried out following EN 71- part 3 :2013 Extraction with 0.07 n HCL; determination by means of ICP-OES. Limit: Dysprosium: 150 mg/kg

7.6

Release of Antimony (Textile Materials)

Test Method:

The test is carried out following EN 71 - part 3 Extraction with 0.07 n HCL; determination by means of ICP-OES. Limit: 30 mg/kg

7.7

Test on content of polycyclic aromatic hydrocarbons (PAHs)

1)GREELISTED INK: PAH are tested as part of the greenlist process on ink. PAH shall be tested on the final toy only if the quantity of ink is over 50 mg. 2)INK NOT GREENLISTED: - ink less than 50 mg on the final toy -> PAH are tested on the microscopic slides - ink more than 50mg -> PAH are tested directly on the toy. Test Method: AfPS GS 2014: 01 PAH Version 04.08.2014 Limits:

BENZO(a)PYRENE BENZO(e)PYRENE BENZO(a)ANTHRACENE BENZO(b)FLUORANTHENE BENZO(j)FLUORANTHENE BENZO(k)FLUORANTHENE CHRYSEN DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE INDENO(l,2,3-cd)PYRENE

Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg Limit <0,2 mg/kg

NAPHTHLENE

Limit < 3,0 mg/kg

Sum of 18 PAH

Limit < 10,0 mg/kg





Detailed List of 18 PAH: BENZO(a)PYRENE, BENZO(e)PYRENE, BENZO(a)ANTHRACENE, BENZO(b)FLUORANTHENE, BENZO(j)FLUORANTHENE, BENZO(k)FLUORANTHENE, CHRYSEN, DIBENZO(a,h)ANTHRACENE, BENZO(g,h,i)PERYLENE, INDENO(l,2,3-cd)PYRENE, NAPHTHALENE, ACENAPHTHYLENE, ACENAPHTHENE, FLUORENE, PHENANTHRENE, ANTHRACENE, FLUORANTHENE, PYRENE.

7.8

Fragrances

This test shall be performed only if there is a FAIL results at Odour test because any kind of fragrances has been found to be present in the tested toys. Limit value: not detectable Remark: At the moment there is a method only for 26 of the fragrances.

8.1

REACH SVHC

Updated SVHC list will be tested according with www.ECHA.com website. (see section “parts to be considered as articles according to REACH”, last page of this document) Test SVHC also on raw materials when they are considered as “an article” based on Annex III of this document.


Valid from: 11/10/16



Page 43 of 69

ANNEX I – List of solvents Classification acc. CLP or C&L inventory

Limit for Classification acc. CLP

Limit for varnishes, Thinner, Paints

Limit for accessible liquids

Limit for the maximum organic residue per article mg/toy

Limit for the emission rate per article in capsule 24 h, µg/h

Carc. 1 (A, B) Muta. 1 (A, B) Repr. 1 (A, B) Carc. 2 Muta. 2 Repr. 2 Acute Tox. 1, 2, 3

≥ 0,1%

Absent (< 0,01%)

< 1 mg/kg

Absent (< 0,001)

< 0,005

Absent (< 0.01%) ≥ 3% Depends from the LD < 0,1% 50

< 1 mg/kg

Absent (< 0.001)

< 0.005

< 5 mg/kg below the concentration that triggers labelling of the mixture below the concentration that triggers labelling of the mixture below the concentration that triggers labelling of the mixture below the concentration that triggers labelling of the mixture

< 0,01

< 0,05

< 0,5

< 0,1

< 0,1

< 0,1

< 1,0

< 0,1

< 1,0

< 0,1

≥ 0,3% ≥ 1%

Acute Tox. 4

< 10 % Skin Sens. 1 A

Skin Sens. 1 or 1B

≥ 0,1% or less depending on the substance

< 0,1%

≥ 1% or less depending on the substance

< 1%

Skin Irrit. 2

≥ 10%

< 10 %


Classification acc. CLP or C&L inventory

Limit for Classification acc. CLP

Limit for varnishes, Thinner, Paints

Eye Irrit. 2

≥ 10%

No limit value

Skin Corr. 1A

≥ 5%

<5%

≥ 3%

No limit value

≥ 20%

No limit value

≥ 10%

No limit value

Eye Dam. 1

STOT SE 3

STOT RE 2

Asp. Tox. 1




< 10%

Limit for accessible liquids

below the concentration that triggers classification of the mixture below the concentration that triggers classification of the mixture below the concentration that triggers classification of the mixture below the concentration that triggers classification of the mixture below the concentration that triggers classification of the mixture <1

Page 44 of 69 Limit for the maximum organic residue per article mg/toy

Limit for the emission rate per article in capsule 24 h, µg/h

< 1,0

< 0,1

< 1,5

< 0.1

< 1,0

< 0,1

< 1,5

< 0,1

< 1,5

< 0,1

< 1.0

< 0,1

This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subj ect to Information Owner prior consent.




ORDER OF PRECEDENCE ACC. TO HAZARD POTENTIAL FOR THE FINAL USER relative Maximum solvents bp rema Recommended Maximum Emission Rate CAS No hazard residue (°C) rk Limit in Raw Materials per article in capsule characteristic per article CLP Accessible liquids in 24 h, (EC) No Varnishes, Polymer toy (mg/toy) µg/h; 1272/2008 Thinner, Paint 4) 3) (Oct.2014)

Benzene

71-43-2

80

Carc. 1A Muta. 1B

1)

Acrylonitrile

107-13-1

77

Carc. 1B

1)

1,3 Butadiene

106-99-0

4.5

1)

2-Ethoxyethylacetate

111-15-9

156

Carc. 1A Muta. 1B Repr. 1B

1)

5 mg/kg 1 mg/kg

Absent (<0,01%)

<1 mg/kg

Absent (<0,001)

< 0.005

Absent (<0,01%)

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

Absent (<0,01%) Absent (<0,01%)

Phthalates (DEHP – DBP – BBP – DNOP – DINP – DIDP –DIBP --- Bis(2-methoxyethyl) phthalat)

> 340 u.A. Repr. 1B

1)

Chloroform

67-66-3

61

Carc. 2 Repr. 2

1)

2-Methoxy1 propylacetate-

70657-70-4 150

Repr. 1B

1)

Isophorone

78-59-1

215

Carc. 2

1)

Absent (<0,01%)

<1 mg/kg

Absent (<0,001)

< 0.005

n-Hexan

110-54-3

69

Repr. 2

1)

Absent (<0,01%)

<1 mg/kg

Absent (<0,001)

< 0.005

Absent (<0,01%) Absent (<0,01%) Absent (<0,01%)




CAS No

bp (°C)

Page 46 of 69

relative Maximum solvents rema Recommended Maximum Emission Rate hazard residue rk Limit in Raw Materials per article in capsule characteristic per article CLP Accessible liquids in 24 h, (EC) No Varnishes, Polymer toy (mg/toy) µg/h; 1272/2008 Thinner, Paint 4) 3) (Oct.2014)

2-Ethoxyethanol (Ethylenglykolmonoethylet 110-80-5 her)

Repr. 1B

1)

THF

Carc. 2

1)

109-99-9


Repr. 1B

Absent (<0,01%)

Absent (<0,01%) Absent 1) (<0,01%) 1) < 10 % Absent 1) 400 mg/kg (<0,01%) Absent 5 mg/kg (<0,01%) 1) < 10 % 1) Absent [< order 0,01%]

2-Methoxy-1-propanol

1589-47-5

1,2-Dichlorbenzene

95-50-1

180

Acute Tox. 4

Styrene

100-42-5

145

Repr. 2

Bisphenol A

80-05-7

360

Repr. 2

2-Butoxyethanol

111-76-2

171

Acute Tox. 4

Cyclohexanone

108-94-1

155

Acute Tox. 4

Methyl-iso-butylketone

108-10-1

116

Acute Tox. 4

1)

Naphthalene

91-20-3

218

Carc. 2

1) PAH

2-Ethyl-1-hexanol

104-76-7

185

Acute Tox. 4 (MAK Wert als 6) SSc Stoff)

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005

Below classific. limit < 0,5

< 0.1

<1 mg/kg

Absent (<0,001)

< 0.005

<1 mg/kg

Absent (<0,001)

< 0.005


< 0.1

Below classific. limit Absent (<0,001)

< 0.1

< 10 %


< 0.1

Absent (<0,01%)

<1 mg/kg

Absent (<0,001)

< 0,005

Absent (<0,01%)

<1 mg/kg

Absent (<0,001)

< 0,005




CAS No

bp (°C)

1589-47-5

Methanol

67-56-1

65

Acute Tox. 3

Nitrobutane

627-05-4

153

Flam. Liq. 3

108-90-7

Repr. 1B

132

Page 47 of 69



Chlorobenzene


Acute Tox. 4

1)

1)

Absent (<0,01%) < 0,1 %

<1 mg/kg

Absent (<0,001)

< 0,005

<5 mg/kg

< 0,01

< 0,05

no limit value Below classific. limit < 1,5

<1

< 10 %


< 0,1

2-Butoxyethyl-acetate

112-07-2

192

(>5%) Acute Tox. 4

< 10 %


< 0,1

2-Phenyl-2-propanol

617-94-7

202

Acute Tox. 4

< 10 %


< 0,1

Acetophenone

98-86-2

202

Acute Tox. 4

< 10 %


< 0.1

1-Butanol

71-36-3

117

Eye Dam. 1

No limit value Below classific. limit < 1,0

< 0.1

2-Methylpropanol-2 (tert.75-65-0 Butanol)

82

Acute Tox.4

< 10%

< 0,1

Di-sec-butylether

6863-58-7

121

Flam Liq. 3

no limit Value Below classific. limit < 1,5

<1

Ethoxypropylacetate (Isomers)

54839-24-6 ./.

STOT SE 3


< 0.1

Diethylene glycol

111-46-6

Acute Tox. 4

< 10 %

< 0.1

247








CAS No

bp (°C)

α-Pinene

80-56-8

156

Skin Sens.1

< 1%

Below classific/labelling. limit

< 1,0

< 0,1

4-methyl-3-penten-2-one (mesityl oxide)

141-79-7

130

Acute Tox. 4

< 10 %


< 0,1

1-Pentanol

71-41-0

138

Acute Tox. 4

< 10 %


< 0,1

Benzyl alcohol

100-51-6

205

Acute Tox. 4

< 10 %


< 0,1

Oxoisophorone(nur mit isophoron)

1125-21-9

222

Acute Tox. 4

< 10 %


< 0,1

2-Phenoxyethanol

122-99-6

242

Acute Tox. 4

< 10 %


< 0,1

Butyrolacton

96-48-0

Acute Tox. 4 Eye Dam.1

< 10 %


< 0,1

2-Pentanol

6032-29-7

Acute Tox 4

< 10 %


< 0,1

2-methyl-1-butanol 3-methyl-1-butanol

137-32-6 123-51-3

Acute Tox 4 Acute Tox 4

< 10 % < 10 %

Below classific. limit < 0,5 Below classific. limit < 0,5

< 0,1 < 0,1





Page 49 of 69


CAS No

bp (°C)

Acetic acid

64-19-7

118

Skin Corr. 1A

iso-Heptenes (Isomers)

./.

./.

no data available

Cyclohexane

110-82-7

81

Asp. Tox. 1

Methylcyclohexane

108-87-2

101

Ethylbenzol

100-41-4

1-Dodecen Isopropylbenzol (cumol)

112-41-4 98-82-8

n-Propylbenzol Hexadekan Tetradekan

pung ent odour

<5%


< 0,1

< 1,0

< 0,2

< 10 % < 10 %

<1%

< 1,0

< 0,2

Asp. Tox. 1

< 10 %

<1%

< 1,0

< 0,1

136

Asp. Tox. 1

< 10 %

<1%

< 1,0

< 0,1

213 152

Asp. Tox. 1 Asp. Tox. 1

< 10 % < 10 %

<1% <1%

< 1,0 < 1,0

< 0,1 < 0,1

103-65-1

159

Asp. Tox. 1

< 10 %

<1%

< 1,0

< 0,1

544-76-3

287

Asp. Tox. 1

< 10 %

<1%

< 1,0

< 0,1

629-59-4

253

Asp. Tox. 1

< 10 %

<1%

< 1,0

< 0,1

< 1%


< 1,0

< 0,1

< 1%


< 1,0

< 0,1

Methylmethacrylate

80-62-6

100

Skin Sens. 1

Butyl acrylate

141-32-2

148

Skin Sens. 1

odour

Allerg e.pun gent odour




bp (°C)

2-ethylhexyl acrylate

103-11-7

214

Skin Sens. 1

< 1%

1,6-hexanediol diacrylate

13048-33-4 107

Skin Sens. 1

<1%

Butylmethacrylat

97-88-1

162165

Skin Sens. 1

<1%

Phenylbenzoat

93-99-2

298

Skin Sens. 1

<1%

./.

./.

none and/or Xi or Xn

< 25 %

Acute Tox 4

< 10 %

627-93-0 (119-40-0 106-65-0 95481-62-2)

Page 50 of 69


CAS No

Dipropylene glycolderivatives Dicarboxylic acid dimethyl ester, DBE (mixture of dimethyl adipate, dimethyl glutarate and dimethyl succinate


Below classific/labelling. limit Below classific/labelling. limit Below classific/labelling. limit Below classific/labelling. limit

< 1,0

< 0,1

< 1,0

< 0,1

< 1,0

< 0,1

< 1,0

< 0,1

< 0,5

< 0,5

< 0,5

< 0,1

-Below classific. Limit

Diacetone alcohol

123-42-2

166

Eye Irrit. 2


<1

Methylacetate

201-185-2

58

Eye Irrit. 2


<1




1-Methoxy-2propylacetate DPGME (Dipropylene glycol-methylether, isomers)

CAS No

bp (°C)

108-65-6

146



Flam. Liq. 3


<1

34590-94-8 187u. 13429-07192 7

Not Classified

no limit Value No limit Value

<1

78-83-1

108

Eye Dam. 1


< 0,1

57-55-6

188

Not Classified

no limit Value No limit Value

<1


107-98-2

116119

STOT SE 3


< 0,1

n-Butylacetate

123-86-4

126

STOT SE 3


< 0,1

i-Butylacetate

110-19-0

117

Flam. Liq. 2


<1

sec-Butylacetate

105-46-4

112

<1

5131-66-8

170

< 10 %

< 0,1

3-Methoxybutyl acetate

4435-53-4

172

Flam. Liq. 2 Eye Irrit. 2 Skin Irrit. 2 Not classified STOT SE 3 C ≥ 10 %


1-Butoxy-2-propanol

2-Methylpropanol-1 (iso-

< 1,5

Butanol) 1,2-Propanediol

2,6 Dimethylheptan-4-one 108-83-8

168

< 1,5


no limit value no limit value

< 1,5



<1 < 0,1



CAS No

bp (°C)

97-64-3

154

Tetrahydrofurfuryl alcohol 97-99-4

178

Tetrahydrofurfuryl acrylate 2399-48-6

205

2-Butanol

78-92-2

Phthalsäure (nur als anhydrit)

88-99-3

Ethyl lactate



Eye Dam. 1


< 0,1

Repr. 1B

Absent (<0,01%)

<1 mg/kg

Absent (<0.001)

< 0,005

Eye Irrit. 2 Skin Irrit. 2

< 10 %

Below classific. Limit

< 1,0

< 0.1

99


< 10 %


< 0,1

/

EYE Irrit. 2 Skin Irrit 2

< 10 %


< 0,1

Hexamethylcyclotrisiloxan 541-05-9

134

Skin Irrit. 2 Eye Irrit. 2

< 10 %


< 0,1

n-Dodecylacrylat

2156-97-0

120


< 10 %


< 0,1

2- Butoxy-1-propanol

1589-47-5


< 10 %

Below classific. limit < 1.0

< 0,1

2-Hexanol

626-93-7


< 10 %


< 0,1




CAS No

bp (°C)




< 10 %


< 0,1

--

1-butoxy-2propanol Eye Irrit. 2 Skin Irrit. 2

< 10 %


< 0,1

617-35-6 617-51-6

146 167

Flam. Liq 3 Kein Eintrag

no limit value Below classific. limit < 1,5 no limit value no limit value < 1,5

<1 <1

71-23-8

97

Eye Dam. 1


< 0,1

4,6 Dimethylheptan-2-one 19549-80-5 163

Not classified


<1

1-Ethoxy-2-propanol

1569-02-4

130

STOT SE 3


< 0,1

2-Propanol

67-63-0

82

STOT SE 3


< 0,1

Benzophenon

119-61-9

305

STOT RE 2


< 0,1

Butanone = MEK

78-93-3

80

Eye Irrit. 2


<1

Ethylacetate

141-78-6

77

Eye Irrit. 2


<1

2- Butoxy-1-propanol

1589-47-5

Propylene glycol mono butylether, mixture of 1butoxy-2-propanol and 2butoxy-1-propanol

5131-66-8 and 1582183-7

Ethyl pyruvate Isopropyl lactate 1-Propanol

< 1,5






CAS No

bp (°C)

Acetone

67-64-1

56

Eye Irrit. 2


<1

α-Methylstyrol

98-83-9

166

Eye Irrit. 2

no limit value Below classific limit < 1,0

< 0,1

Dimethoxymethane

109-87-6

Eye Irrit. 2


< 0.1

n-Propylacetat

109-60-4

Eye Irrit. 2


< 0,1

Isobutylformiat

542-55-2

Eye Irrit.2


< 0,1

Dimethoxymethane

109-87-6

Eye Irrit. 2


< 0,1

n-Propylacetat

109-60-4

Eye Irrit. 2


< 0,1

Methylacetat

79-20-9

Eye Irrit. 2


< 0,1

Ethanol 3-Hexanol Dipropylene glycol dibenzoate

64-17-5 623-37-0

Flam. Liq. 2 Flam Liq. 3

no limit value Below classific. limit < 1,5 no limit value Below classific. limit < 1,5

<1 <1


<1

78

27138-31-4 > 250 Not classified

< 1,5




Butylglycolate n- and iso-Alkanes (C6-C19) Dimethylglutarate Dipropylene glycol (isomeres) BHT (2,6-di-tert-butylp-cresol) TXIB (= 2,2,4-Trimethyl1,3- pentanediol diisobutyrate)

CAS No

bp (°C)

7397-62-8

180188

---

100235



Not classified

Not classified

n-C6C8 each <10 %


< 1,5

<1


< 1,5

<1

1119-40-0 214 25265-71-8 222and 238 110-98-5

Not classified


< 1,5

<1

Not classified


< 1,5

<1

128-37-0

265

Not classified


< 1,5

<1

280

Not classified


< 1,5

<1

mostl y Not classified >250


< 1,5

<1

261

Not classified


< 1,5

<1

6846-50-0

Silicone oils / Polysiloxanes and similar substances Dodecanol

111-53-8

1-Methylbutyl acetate

626-38-0

Flam liqu 3


<1

3-Methyl-2-butyl acetate

5343-96-4

Not classified


<1

< 1.5




CAS No

bp (°C)

590-01-2

2,6-Dimethyl-4-heptanol

108-82-7

Ethyl-3-ethoxypropionat

763-69-9

Flam Liq. 3 No classification Flam Liq. 3

CMT (category 1 , 2)

---

T

-----

> 110

Page 56 of 69


n-Butylpropionat

Mixtures of aromatic hydrocarbons (without benzene and polycyclic compounds) Total VOC (TVOC)


Xn, Xi or no classification


<1


<1

< 1,5

no limit value Below classific. limit < 1,5 Absent <5 mg/kg Absent (<0.001) (<0.01%)

2)

10 %; (0,5 % Toluene)

Σ

0,1

Σ 1,5

NOTES: 1) Should not be a component of the formula 2) used hydrocarbon mixture benzene free (no classification with T) 3) If the 24-hour emission values are exceeded by about 25 %, the test will be continued. After 7 days, the values must remain below the limit values. 4) The requirements acc. to EN 71 part 9, para 4.2 must be observed. 5) When tested in dry conditions 6) national classification (acc. DFG 2011): reproduction toxic (teratogenic)


<1 < 0,005

Σ

< 0,2

Σ1




ANNEX II - Test Procedures of Cross Cut Test Rev.1 1

Equipment use:

1. Steel ruler 2. Standard adhesive tape (comply with EN 2409) 3. ISO Cutter (cutter as common, the standard cutter is too big for KS toys.) 4. Soft brush

2

3

4

Step 1:

Use the cutter to cut along the paints with uniform pressure to construct a 5mm x 5mm lattice onto the paint. Use the steel ruler as the cutting guild. Each lattice should have 1 mm sides. Care should be taken to cut the whole thickness of the paint. IF the surface of the paint is too small that not allow to cut of 1mm x 1mm square go directly to a tape test. As soon as the cut has been performed on the toy evaluate any detachment of complete square of 1mm x 1mm : if 1 piece detach give FAIL (this is considered as grade 3 of the Scale of Results) .

Step 2:

Brush the cut surface lightly with the soft brush several times backwards and several times forwards along diagonals of the lattice pattern. As soon as the brushing has been performed on the toy evaluate any detachment of complete square of 1mm x 1mm : if 1 piece detach give FAIL(this is considered as grade 3 of the Scale of Results) .





Step 3:

Apply the centre of the standard adhesive tape to the surface that shall be tested. Ensure good contact with the paint by rub the tape firmly with a fingertip. Step 4:

Within 5 min of applying the tape. Remove the tape by grasping the free end and pulling it off steadily in 0.5s to 1.0s at an angle which is as close as possible to 60°. Classify the degree of flaking by using the Scale of Results





SCALE OF RESULTS CROSS CUT TEST Limit of cross cut test: 1 mm x 1 mm. piece means: FAIL (score 3 ) Classification requirements 0

--

The edges of the cuts are completely smooth; none of the squares of the lattice is detached.

1

Detachment of small flakes of the coating at the intersections of the cuts.

2

The coating has flaked along the edges and/or at the intersections of the cuts.

3

The coating has flaked along the edges of the cuts partly or wholly in large ribbons, and/or it has flaked partly or wholly on different parts of the squares.

4

The coating has flaked along the edges of the cuts in large ribbons and/or some squares have detached partly or wholly.

5

--

Any degree of flaking that cannot even be classified by classification 4.





Page 60 of 69

ANNEX III - Parts to be considered as articles according to REACH

B

1+2 3 4+5

Ariel Skin + Ariel Sleeves/ Skirt Ariel Hair Leg Skin + Shoes/ Underpants

1 2

Blue Body Wheel holder

1 2

Head Extra Head Part

1 2

3

Front Wheel

3

Cap Right

3

Cap Left

Body Big Spine Part

1 2

Small Spine Part

3

EARS ON FRONT

4

CRAYON; no test as this is a mixture, no article

5

LEAF BASE

Legal Leaflet

Flocking is exempted, this is part of the article

6

Base

4

DOWN CASE

4

7

Skirt

5

MIDDLE CASE

5+6

Pad printing color is exempted, this is part of the article

6

UP CASE

7

Stamp Tube

6

7

GEAR 1

8

Stamp Lid

7

8

GEAR 2

9

Axle With Wheels (2 pcs./toy)

Body Woodstock + Seatpart

9

GEAR 3

10

Head Light

10

GEAR 4

11

Frame

11

GEAR 5

12

Zamboni Lower Plate

12

REAR Wheel

13

Zamboni Upper Body

13

Decal

14

Stamp Cover


Rabbit Front Rabbit Rear

Marketing Leaflet Pad printing color is exempted, this is part of the article






Page 61 of 69

ANNEX IV -Synoptic table full protocol Synoptic table full protocol Synthetic rubber for toys under 3 / finger Inks, paints / Metal or liquids, Natural metalized paste rubber components

Mass coloured plastic or Paper Textile synthetic (instruction (plush) and rubber and sheet, flocked Complete flocked for KS- Varnishes and stickers, materials toy KJ paints etc.) >10 cm2

0.1

YES

Green List

YES

Solid materials intended to leave a trace

YES

1,0

Mechanical protocol on prototype

X (UL-IISG issue ISO8124)

1,1

Production quality/ corrosion

X

1,2 1,3

Mounting/handling Function test

X X

1,4

Durability

1,5

SAFETY assesment

1.7

Aggressiveness on household surfaces

1.8

CF against sweat

1.9

Odour /fragrance presence evaluation

X

2.1

EN 71/1

X

2.2

Cross cut

2.3

Adhesion

X (decals already applied on toy)

2.4

Soaking test

X(decals already applied on toy)

YES

X

X

X X by KSC X (on decals and tags) X

X X

X

This document must be disclosed only to authorized individuals. Any reproduction and/or disclosure must be subject to Inf ormation Owner prior consent.




Page 62 of 69

Synoptic table full protocol Synthetic rubber for toys under 3 / finger Inks, paints / Metal or liquids, Natural metalized paste rubber components


2.5

Colourfastess to Rubbing

2.6

Washing

2.7

CF to water

2.8

Mechanical test on capsule

3.1 3.2


X

X (plush only) X (KS only) X (on capsule only)

EN 62115 EMC (2014/30/EC)

X X

3.3

RoHS2 (2011/65/EU)

X

3.4

WEEE (2012/19/EU)

X

4

EN 71/2 Flammability

4.1

Canada Flammability

5.1

ISO 8124-3

X

5.1a

EN 71 part 3

X

Migration of 5.1bis elements Canadian Regulation 5.2 Nickel release Heavy Metals (incl. 5.4 Nickel)

X X (including hairs)

X

X

X

X

X

X

X

X

X

X

X

X

X

This document must be disclosed only to authorized individuals. Any reproduction and/or d isclosure must be subject to Information Owner prior consent.

X






5.5

Mercury and Arsenic

5.6

Saliva and sweat

5.7 5.8 5.9

Bleeding of stained paper Assessment of solvents Determination of formaldehyde release

X X

X

X

pH

5.11 5.12 5.13

Aromatic amines Colourants Preservatives

X X

5.14

Flame retardants

X

5.16 5.17 5.18 5.19 5.20

Phenols (chlorinated and OPP) Wood preservatives Organotins (T00 and KJ apply all other materials approach) Monomers Nitrosamines Optical Brightners

X

X

X (only for food contact)

X (no finger paints)

X

X (only for PE wax crayon)

X

5.10

5.15


X X

X (printed)

X (printed)

x (for ALL TOYS

X

X

X (stickers)

X

X

X

X X X (stickers)

X X

X X X

X X X

X

X

X

X X

X

X

X X X X

X

X (on plastified part)

X

X (stickers)

X

X

X

X X

X (prolonged skin contact)

X







5.21

5.22

5.23

Plasticizers

X

X

Nonyl phenol and nonyl phenol etoxylate Solvents migration (EN 71-9)



X


X

X

X

X (stickers) X (intended to be worn)

5.24

Dermal irritation

5.25

Primary aromatic amines

5.26

Cellulose nitrate (Canada)

5.27

Formamide and Dymethylformamide

5.28

Toluene (Chile)

X

5.29

Food sanitation law (Japan)

X

5.30

Arnolds-Michlers Ketone

6.1

Mould fungi

6.2

Micro Biological control

X

X (intended to be worn)

X

X X (only for food contact)

X X (only on foamed) X (only for food contact)

X X (on blue and violet liquid inks) X

X

X (on liquids and paste)







7.1

Verification of the formula

7.2

Food contact tests

X (only special effect)

7.5 7.6 7.7

Antimony PAH

7.8

FRAGRANCES

X

8.1

Updated SVHC list will be tested according with www.ECHA.com website

X

7.4

X (stickers)

X

X

X X (only for food contact)

Heavy metals in packaging materials Heavy metals in batteries Disprosium

7.3



X X X

X

X

X

X

X

X

X X X

X

x

X

X (also for capsules)





ANNEX V -Synoptic table reduced Protocol Synoptic table Reduced Protocol

Complete toy

0.1 1,0 1,1 1,2 1,3 1,4 1,5 1.7 1.8 1.9 2.1 2.2 2.3 2.4 2.5

Synthetic rubber for toys under 3 / finger Inks, paints Metal or liquids, /Natural metalized paste rubber components

Glues (lenticular cards, Solid stickers to materials be used intended to more than leave a ones) trace

Green List

Mechanical protocol on prototype Production quality/ corrosion Mounting/handlin g Function test Durability SAFETY assesment Aggressiveness on household surfaces CF against sweat Odour /fragrance presence evaluation EN 71/1 Cross cut Adhesion Soaking test Colourfastness to Rubbing

2.6

Washing

3.1

EN 62115 EMC (2014/30/EC)

3.2

Mass coloured plastic or Paper Textile synthetic (instruction (plush) and rubber and sheet, flocked flocked for Varnishes stickers, materials KS-KJ and paints etc.) >10 cm2

x (IISG issue ISO 8124)

by KSC

X

X

x (plush only) X X





Page 67 of 69

Synoptic table Reduced Protocol

Complete toy

3.3 3.4 4

4.1

Canada Flammability

ISO 8124-3 EN 71 part 3 Migration of elements 5.1 Bis Canadian Regulation EN71/9 (when 5.1.B applicable) 5.1 5.1 a

5.2

Nickel release

5.4

Cadmium Lead content Nickel content Mercury and Arsenic

5.4C 5.5 5.6



RoHS2 (2011/65/EU) WEEE (2012/19/EU) EN 71/2 Flammability

5.4B


Saliva and sweat

X X X x (including hairs) X X

X

X

X

X

X

X

X

X

X

X

X x (accessible)

X (for <3 years)






Complete toy

5.11

Bleeding of stained paper Assessment of solvents Determination of formaldehyde release Aromatic amines

5.14

Flame retardants

5.7 5.8 5.9

5.15 5.16

5.17

Phenols (chlorinated and OPP) Wood preservatives Organotins (T00 and KJ apply all other materials approach)

5.19

Nitrosamines

5.20

Optical Brightners

5.21

Plasticizers

5.22 5.24

Nonyl phenol and nonyl phenol etoxylate Dermal irritation


X

X

X (printed)

X (printed)

x (for ALL TOYS

x


X X

x X


X

X

X

X

X

X


X

X

X

X

x (only toys under 3 years) EN71-12

X

X



X

X

X


X

X





Complete toy

5.25

Primary aromatic amines

5.26

Cellulose nitrate (Canada)

5.27

Formamide and Dymethylformami de

6.1

Toluene (Chile) Mould fungi

6.2

Microbiologic control

5.28

7.1

Verification of the formula

7.2

Food contact tests

7.3 7.4 7.5 7.6 7.7 8.0

Heavy metals in packaging materials Heavy metals in batteries Disprosium / Zinc Antimony PAH Toy Directive




x (only for food contact) X

X (only on foamed) X



X

X (on liquids and paste)

X

X

X (Always)

X

X

X

x (only for food contact) X X

X

X

X

X

X

X

X


Ferrero Toys Testing Protocol 2016

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