Surf Act Ants for Industrial Applications

Exactly your chemistry.

Division Functional Chemicals

Surfactants for Industrial Applications

Nonionic and Anionic Emulsifiers, Copolymerizable Surfactants, Dispersing Agents and Defoamers

Contents

2

Surfactants from Clariant What we offer for industrial customers

Alkyl polyethyleneglycol ether

4

Product Range

13

phosphoric acid esters Alkyl phosphonic acids

13

Alkyl polyethylene glycol

13

ether carboxylic acid

Nonionic Surfactants

Fatty acid condensates

Alkyl ethoxylates

6

(fatty acid isethionates, methyl taurides,

Nonylphenol ethoxylates

9

sarkosin and sarkoside)

Tributylphenol ethoxylates

9

Alkyl benzene sulphonates, Ca-salts

Tristyrylphenol ethoxylates

9

Alkyl alkoxylates

10

Copolymerizable Surfactants

Ethylene oxide-propylene

10

Vinyl ether alkoxylates

oxide block polymers

(PO-EO-block polymers)

13

13

14

Fatty acid polyethyleneglycol esters

11

Allyl ether alkoxylates

Fatty acid polyglycerol esters

11

(PO-EO-block polymers)

14

Fatty acid polyglycerol

11

Allyl polyoxyalkylene sulphates

14

Castor oil ethoxylates

11

Dispersing Agents

15

Sorbitan ester ethoxylates

11

Wax emulsifiers

11

ester ethoxylates

Anionic Surfactants

Defoamers Fluorine containing defoamers

16

Silicone containing defoamers

16

Silicone and fluorine-free defoamers

16

Secondary alkyl sulphonates

12

Olefin sulphonates

12

Alkyl sulphates

12

Surfactants from Clariant

Alkyl ether sulphates

12

Emulsifiers for emulsion

Alkyl aryl ether sulphates

12

polymerization

Polyglycol ether sulphates

12

Sulphosuccinic acid esters

12

Fatty alkyl amine sulphosuccinamates

12

Alkyl phosphoric acid esters

12

®=

Registered trademark of Clariant

17

3

Surfactants from Clariant What we offer for industrial customers Clariant’s Division Functional Chemi-

Production and sales

Research and development

cals is one of the world's leading

Our surfactants are manufactured at our

In addition to the product range we offer

manufacturers of surfactants and po-

production sites in Gendorf/Burgkirchen

our customers comprehensive advice

lyglycols. The product range encom-

and Wiesbaden (Germany), Tarragona

and technical service. Our application

passes anionic, nonionic, cationic and

(Spain), Charlotte (USA), Clear Lake

laboratories assist you in developing

amphoteric surfactants. These include

(USA), Mexico City (Mexico), Coatza-

modern system solutions and help you to

raw materials for detergents and

coalcos (Mexico), Maracay (Venezuela),

select the products that are suitable

cleaners, cosmetics and special pro-

Sao Paulo (Brazil), Zarate (Argentina)

for your applications.

ducts for chemical and industrial

and elsewhere, and are available world-

applications.

wide through our sales organization.

This brochure presents a selection

Our product range is constantly being expanded by intensive research and development work and is thus geared to

of our products for chemical and indu-

the requirements of our customers as

strial applications.

well as to optimization of the production methods.

Quality and environment Clariant’s Functional Chemicals Division in Germany has established a quality management system in accordance with ISO 9001 in the production, research & development and marketing sectors. All products are subject to strict quality control in our analytical department to ensure our high quality standard. To safeguard environmentally friendly operations the environment management system in accordance with the eco

4

audit regulations (EEC 1836/93) was introduced at Gendorf/Burgkirchen The largest production site of Division Functional Chemicals: Clariant Gendorf/ Burgkirchen.

(Germany), our largest production site.

Production site of Division Functional Chemicals in Tarragona (Spain).

Industrial Applications of Surfactants

Our service: new emulsifiers –

Surfactants are used as wetting agents,

from the laboratory to production

offers smaller sample amounts of

emulsifiers and dispersing agents

In selecting suitable emulsifier systems

non-commercial products for labora-

for different chemical and industrial

preliminary trials are necessary to

tory investigations. These include

applications. Clariant offers products for

determine the stability of the monomer

nonionic emulsifiers based on alcohol

the following fields:

emulsion and polymer dispersion and

ethoxylates, which are synthesized in

Besides the existing range Clariant

s

Emulsifiers for emulsion polymerization

the properties of the polymer films.

our development laboratory. If requi-

s

Dispersing agents for pigment pre-

We will gladly supply product samples

red, almost any alcohol can be reac-

parations, coatings, inks and paints

from our commercial range for these

ted with the desired amount of ethylene

Wetting agents for hard surfaces,

preliminary trials.

oxide and a sample provided.

s

ceramics, wood, plastics and metals s

s

s

Our production know-how permits

Emulsifiers for micro- and macro

rapid scale-up of new products from

emulsions of fats, hydrocarbons and

the laboratory to the production stage.

silicon oils

Development products are thus

Emulsifiers for polyolefin wax

rapidly available commercially. We

emulsions

will gladly advise you of what we

Wetting agents for electroplating

can do for you.

processes s

Surfactants for the building industry

s

Emulsifiers for bitumen emulsions

s

Auxiliaries for the sugar industry

s

Defoamers

5

Nonionic Surfactants Product range The following product range provides

New development products, which

a selection of our products and contains

will extend our product range, are not

nonionic and anionic surfactants used

yet included in this list.

as emulsifiers and wetting agents, and further more dispersing agents and defoamers.

Trade name

Chemical name

Active content Appearance (20°C) Cloud point (°C) HLB value

Alkyl ethoxylates

6

62 – 65(3)*

Emulsogen EPN 118

Alkyl polyglycol ether with 11 EO

ca. 80 %

liquid

Emulsogen EPN 217


ca. 70 %

liquid

–

ca. 17

Emulsogen EPN 287


ca. 70 %

liquid

–

ca. 18

Emulsogen EPN 407


ca. 70 %

liquid

–

ca. 18

Emulsogen LCN 050


ca. 100%

liquid

67 – 70(2)

ca. 11

Emulsogen LCN 070


ca. 100%

liquid

54 – 56(1)

ca. 13

Emulsogen LCN 088


ca. 80%

liquid

62 – 65(1)*

ca. 13

Emulsogen LCN 118


ca. 80 %

liquid

62 – 65(3)*

ca. 15

(3)

69 – 71 *

ca. 15

Emulsogen LCN 158


ca. 80 %

liquid

ca. 16

Emulsogen LCN 217


ca. 70 %

liquid

–

ca. 17

Emulsogen LCN 287


ca. 70 %

liquid

–

ca. 18

Emulsogen LCN 407


ca. 70 %

liquid

–

ca. 18

Emulsogen 3896

Fatty alcohol ethoxylate

ca. 100 %

waxy

73 – 75(3)

ca. 15

Genapol C 050

Coconut fatty alcohol ethoxylate with 5 EO

ca. 100 %

liquid

71 – 74(2)

ca. 10

Genapol C 100

Coconut fatty alcohol ethoxylate with 10 EO ca. 100 %

paste

89 – 92(1)

ca. 14

Genapol C 200


waxy

76 – 78(3)

ca. 16

Genapol C 250


waxy

77 – 79(3)

ca. 17

Genapol LA 030

C12 / C14 fatty alcohol ethoxylate with 3 EO

ca. 100 %

liquid

53 – 55(2)

ca. 8

Genapol LA 040


ca. 100 %

liquid

64 – 66(2)

ca. 10

(2)

ca. 11

Genapol LA 050


ca. 100 %

liquid

70 – 73

Genapol LA 070


ca. 100 %

liquid

53 – 59(1)

ca. 12

Genapol LA 079


ca. 90 %

liquid

53 – 59(1)*

ca. 12

Genapol V 4463

C12 / C14 fatty alcohol ethoxylate with 10 EO ca. 100 %

waxy

(1) 1

g in 100 cm 3 distilled water •

(2) 5

g in 25 cm 3 25 % aqueous BDG •

(3) 1

–

g in 100 cm 3 10 % aqueous NaCl solution • * relative to the active substance

ca. 14

Trade name

Chemical name

Active content Appearance (20°C) Cloud point (°C)

Genapol O 020

Oleyl alcohol ethoxylate with 2 EO

ca. 100 %

liquid

35 – 38(2)

Genapol O 050


ca. 100 %

liquid

67 – 69(2)

Genapol O 080


ca. 100 %

liquid paste

HLB value

Alkyl ethoxylates

> 40(1)

ca. 5 ca. 9 ca. 11

79 – 81 (2) Genapol O 100


ca. 100 %

paste

> 75(1) 49 – 51

ca. 12

(3)

Genapol O 150


ca. 100 %

waxy

71 – 73(3)

ca. 13

Genapol O 200


ca. 100 %

waxy

74 – 76(3)

ca. 15

Genapol O 300


ca. 100 %

waxy

Genapol OA 040

C14 / C15 oxo alcohol ethoxylate with 4 EO

ca. 100 %

liquid

51 +/- 1,5(2)

Genapol OA 070


ca. 100 %

paste

72 – 74(2)

ca. 12

Genapol OA 080


ca. 100 %

paste

76 – 80(2)

ca. 12

Genapol OA 089


ca. 90 %

liquid

76 – 80(2) *

ca. 12

Genapol OX 050


ca. 100 %

liquid

63 – 64,5(2)

ca. 10

Genapol OX 060


ca. 100 %

liquid paste

64 – 67(2)

ca. 11

Genapol OX 070


ca. 100 %

liquid paste

ca. 73(2)

ca. 12

Genapol OX 080


ca. 100 %

paste

75 – 78(2)

ca. 13

(1)

ca. 14

–

ca. 17

Genapol OX 100


ca. 100 %

paste

62 – 65

Genapol OX 109


ca. 90 %

liquid

62 – 65(1) *

(1) 1


(2) 5


(3) 1

ca. 9

ca. 14

g in 100 cm 3 10 % aqueous NaCl solution • * relative to the active substance „Alkyl ethoxylates“ to be continued on page 8

7

Nonionic Surfactants Product range Trade name

Chemical name

Active content Appearance (20°C) Cloud point (°C) HLB value

Alkyl ethoxylates continued from page 7 Genapol T 080

Tallow fatty alcohol ethoxylate with 8 EO

ca. 100 %

waxy

83 – 85(2)

ca. 11

Genapol T 110

Tallow fatty alcohol ethoxylate with 11 EO ca. 100 %

waxy

84 – 90(1)

ca. 13

60 – 63 (3) Genapol T 150


waxy

71 – 73(3)

ca. 14

Genapol T 200


waxy

75 – 77(3)

ca. 15

(3)

Genapol T 250


waxy

77 – 79

ca. 16

Genapol T 250 p


powder

77 – 79(3)

ca. 16

Genapol T 500


waxy

–

ca. 18

Genapol T 500 p


powder

–

ca. 18

Genapol T 800


waxy

–

ca. 19

Genapol T 800 p


powder

–

ca. 19

Genapol UD 030

C11 oxo alcohol ethoxylate with 3 EO

ca. 100 %

liquid

37 – 41(2)

ca. 9

Genapol UD 050


ca. 100 %

liquid

66 – 69(2)

ca. 11

Genapol UD 079


ca. 90 %

liquid

52 – 55(1)*

ca. 13

Genapol UD 080


ca. 100 %

liquid

62 – 65(1)

ca. 13

Genapol UD 088


ca. 80 %

liquid

62 – 65(1)*

ca. 13

Genapol UD 110


ca. 100 %

liquid paste

62 – 65(3)

ca. 15

(2)

ca. 6

Genapol X 020


ca. 100 %

liquid

25 – 30

Genapol X 050


ca. 100 %

liquid

59 – 62(2)

ca. 10

Genapol X 060


ca. 100 %

liquid

64 – 66(2)

ca. 11

Genapol X 080


ca. 100 %

liquid

> 45(1)

ca. 13

74 – 76 (2) Genapol X 089


ca. 90 %

liquid

> 45(1)*

ca. 13

74 – 76 (2)*

8

62 – 65(1)

Genapol X 090


ca. 100 %

liquid

Genapol X 158


ca. 80 %

liquid

–

ca. 15

Genapol X 250


ca. 100 %

waxy

–

ca. 18

Genapol X 307


ca. 70 %

liquid

–

ca. 17

Genapol X 407


ca. 70 %

liquid

–

ca. 18

Genapol X 1000


ca. 100 %

solid

–

ca. 19

Genapol X 1003


ca. 35 %

liquid

–

ca. 19

Genapol X 1005


ca. 50 %

liquid

–

ca. 19

Genapol 1879

C13 oxo alcohol ethoxylate

ca. 40 %

liquid

–

ca. 15

Genapol 3214

C13 oxo alcohol ethoxylate

ca. 25 %

liquid

–

ca. 18

(1)

1 g in 100 cm 3 distilled water •

(2)

5 g in 25 cm 3 25 % aqueous BDG •

(3)

1 g in 100 cm 3 10 % aqueous NaCl solution • * relative to the active substance

ca. 13

Trade name

Chemical name

Active content

Appearance (20°C)

Cloud point (°C)

HLB value

Nonylphenol ethoxylates ®

Arkopal N 040

Nonylphenol ethoxylate with 4 EO

ca. 100 %

liquid

36 – 38(2)

ca. 9

Arkopal N 060


ca. 100 %

liquid

61 – 63(2)

ca. 11

Arkopal N 080


ca. 100 %

liquid

32 – 34(1)

ca. 12

76 – 78 (2) Arkopal N 090


ca. 100 %

liquid

52 – 54(1)

ca. 13

(1)

Arkopal N 100


ca. 100 %

liquid

62 – 65

ca. 13

Arkopal N 110


ca. 100 %

liquid

71 – 74(1)

ca. 14

Arkopal N 130


ca. 100 %

liquid paste

83 – 86(1)

ca. 14

Arkopal N 150


ca. 100 %

paste

92 – 95(1)

ca. 15

61 – 63 (3) Arkopal N 200


ca. 100 %

paste

70 – 73(3)

ca. 16

Arkopal N 208


ca. 80 %

liquid

70 – 73(3)*

ca. 16

Arkopal N 230


ca. 100 %

waxy

73 – 75(3)

ca. 16

Arkopal N 238


ca. 80 %

liquid

73 – 75(3)*

ca. 16

Arkopal N 300


ca. 100 %

waxy

76 – 78(3)

ca. 17

Arkopal N 307


ca. 70 %

liquid

76 – 78(3)*

ca. 17

Arkopal N 308


ca. 80 %

liquid

76 – 78(3)*

ca. 17

Arkopal N 1000


ca. 100 %

waxy

–

ca. 19

Tributylphenol ethoxylates ®

Sapogenat T 060

Tributylphenol ethoxylate with 6 EO

ca. 100 %

liquid

53 – 56(2)

ca. 10

Sapogenat T 080


ca. 100 %

liquid

60 – 68(2)

ca. 11

Sapogenat T 110


ca. 100 %

liquid

42 – 44(1)

ca. 13

Sapogenat T 130


ca. 100 %

liquid

62 – 64(1)

ca. 14

Sapogenat T 139


ca. 90 %

liquid

62 – 64(1)*

ca. 14

Sapogenat T 180


ca. 100 %

waxy

61 – 64(3)

ca. 15

Sapogenat T 300


ca. 100 %

waxy

–

ca. 17

Sapogenat T 500


ca. 100 %

waxy

–

ca. 18

Tristyrylphenol ethoxylates ®

Emulsogen TS 050

Tristyrylphenol ethoxylate with 5 EO

ca. 100 %

liquid

23 – 27(2)

ca. 7

Emulsogen TS 100

Tristyrylphenol ethoxylate with 10 EO ca. 100 %

liquid

65 – 69(2)

ca. 10

Emulsogen TS 160


liquid

58 – 62(1)

ca. 13

Emulsogen TS 200


waxy

55 – 60(3)

ca. 14

Emulsogen TS 290


waxy

67 – 69(3)

ca. 15

Emulsogen TS 540


waxy

72 – 74(3)

ca. 17

Emulsogen TS 600


waxy

(1) 1


(2) 5


(3) 1

–

g in 100 cm 3 10 % aqueous NaCl solution • *relative to the active substance

ca. 17

9

Nonionic Surfactants Product range Trade name

Chemical name

Active content

Appearance (20°C) Cloud point (°C) HLB value

Alcohol EO-PO adduct

ca. 100 %

liquid

Alkyl alkoxylates Genapol EP 0244

33,5 – 36,5 (2)

(former name Genapol 2822)

Genapol EP 2424

ca. 20(1)


ca. 100 %

liquid

25 – 27(2)


ca. 100 %

liquid

42 – 44(2)

Oxoalcohol EO-PO adduct

ca. 100 %

liquid

31 – 33(2)


ca. 100 %

liquid

39 – 41(2)


ca. 100 %

liquid

27,5 – 31(1)


ca. 100 %

liquid

39 – 42(1)


ca. 100 %

liquid

> 25(1)

(former name Genapol 3970)

Genapol EP 2464 (former name Genapol 3938)





Genapol PL 120

31 – 34 (2)

Ethylene oxide-propylene oxide block polymers Emulsogen 4084

EO-PO block polymer with 60 % EO

ca. 100 %

waxy

68 – 70(3)

ca. 12

Genapol PF 10


ca. 100 %

liquid

34 – 37(2)

ca. 2

Genapol PF 20


ca. 100 %

liquid

55 – 58(2)

ca. 4

Genapol PF 40


ca. 100 %

liquid

66 – 69(2)

ca. 8

Genapol PF 80 p


ca. 100 %

powder

69 – 72(3)

ca. 16

Genapol ED 3030

Ethylenediamine EO-PO block polymer

ca. 100 %

liquid

52 – 55(2)

ca. 9

Ethylenediamine EO-PO block polymer

ca. 100 %

liquid

27 – 30(2)

ca. 6

ca. 100 %

liquid

36 – 39 (2)

ca. 100 %

liquid

ca. 100 %

liquid

(former name Genapol B)

Genapol ED 3060 (former name Genapol PN 30)

End capped Alkylethoxylates

10

Genapol BE 2410

Lauryl ethoxylate with 10 EO, butyl-end capped

Genapol BE 2805

Coconut fatty alkyl ethoxylate with 5 EO, butyl-end capped

Genapol BE 2810

Coconut fatty alkyl ethoxylate with 10 EO, butyl-end capped

(1) 1

–


(2) 5


(3) 1

39 – 42(2)


Trade name

Chemical name

Active content

Appearance (20°C)

Fatty acid polyethyleneglycol esters ®

Genagen C 100

C12 / C14 fatty acid polyglycol ester with 10 EO

ca. 100 %

liquid

Genagen O 060


ca. 100 %

liquid

Genagen O 100


ca. 100 %

liquid

Genagen O 150


ca. 100 %

liquid

Genagen S 250

Stearic acid polyglycol ester with 25 EO

ca. 100 %

waxy

Fatty acid polyglycerol esters Emulsogen OG

Diglycerol oleate

ca. 100 %

liquid

Hostacerin DGI

Diglycerol diisostearate

ca. 100 %

liquid

Hostacerin DGMS

Diglycerol monostearate

ca. 100 %

pellets

Hostacerin TGI

Polyglycerol diisostearate

ca. 100 %

liquid

Fatty acid polyglycerol ester ethoxylates Hostacerin DGSB

Diglycerol distearate ethoxylated with 4 EO

ca. 100 %

waxy

Hostacerin DGL

Diglycerol laurate ethoxylated with 10 EO

ca. 100 %

liquid

Emulsogen EL 200

Castor oil ethoxylate with 20 EO

ca. 100 %

liquid

Emulsogen EL 360


ca. 100 %

liquid

Emulsogen EL 400


ca. 100 %

liquid

Emulsogen EL 540


ca. 100 %

liquid

Emulsogen HCO 040

Hydrogenated castor oil ethoxylate with 40 EO

ca. 100 %

paste

Emulsogen HCO 060


ca. 100 %

paste

Emulsogen HCP 049


ca.090 %

liquid

Lauroyl sorbitane ethoxylate with 20 EO

ca. 100 %

liquid

Emulsogen P

Alkylethoxylate

ca. 100 %

paste

Emulsogen PN extra

Mixture of different alkyl ethoxylates

ca. 100 %

paste

Castor oil ethoxylates

Sorbitane ester ethoxylate Emulsogen 4156

Wax emulsifiers

(1) 1


(2) 5


(3) 1


11

Anionic Surfactants Product range Trade name

Chemical name

Active content

Appearance (20°C)

Secondary alkyl sulphonates (Secondary alkane sulphonates) ®

Hostapur SAS 30

Secondary alkyl sulphonate, Na salt

ca. 30 %

liquid

Hostapur SAS 60


ca. 60 %

paste

Hostapur SAS 93


ca. 93 %

waxy pellets

Hostapur OS liquid

C14 / C16 alpha-olefin sulphonate, Na salt

ca. 42 %

liquid

Hostapur OSB

C14 / C16 alpha-olefin sulphonate, Na salt

ca. 90 %

powder

Emulsogen EPA 1954

C12 / C14 alkyl sulphate, Na salt

ca. 30 %

liquid

Emulsogen LS

C12 alkyl sulphate, Na salt

ca. 15 %

liquid

Emulsogen EPA 073

Alkyl ether sulphate with 7 EO, Na salt

ca. 28 %

liquid

Emulsogen LCA 073

Alkyl ether sulphate with 7 EO, Na salt

ca. 28 %

liquid

Emulsogen LA 083

Alkyl ether sulphate with 8 EO, Ammonium salt

ca. 30 %

liquid

Genapol LRO liquid

C12 / C 14 alkyl ether sulphate with 2 EO, Na salt

ca. 27 %

liquid

Genapol LRO paste


ca. 68 %

paste

Emulsogen ZRO liquid


ca. 27 %

liquid

Zeliquid LP 2

Lauryl ether sulphate with 3 EO, ammonium salt + organ. solvent

ca. 50 %

liquid

Hostapal BV conc.

Tributyl phenol ether sulphate with 7 EO, Na salt

ca. 50 %

paste

Hostapal BV liquid

Tributyl phenol ether sulphate with 7 EO, Na salt

ca. 17 %

liquid

Polyalkylene glycol ether sulphate, ammonium salt

ca. 50 %

liquid

Emulsogen SB 10

Diisodecyl sulphosuccinate, Na salt +IPA

ca. 65 %

liquid

Emulsogen SF 8

Diisooctyl sulphosuccinate, Na salt

ca. 50 %

liquid

Olefin sulphonates

Alkyl sulphates

Alkyl ether sulphates

®

Alkyl aryl ether sulphates ®

Polyglycol ether sulphates Emulsogen PF 20 S

Sulphosuccinic acid esters

Fatty alkyl amine sulphosuccinamates Emulsogen OLS

Octyl amine sulphosuccinamate, Na salt

ca. 36 %

liquid

Emulsogen TAS

Tallow alkyl amine sulphosuccinamate, Na salt

ca. 36 %

liquid

Phosphoric acid mono esters Hostaphat CC 100

12

Cetyl phosphoric acid ester, acid form

ca. 100 %

powder

Phosphoric acid di esters Hostaphat L 327

Phosphoric acid ester of lauryl ethoxylate (2 EO)

ca. 95 %

liquid

and polyethylene glycol

Phosphoric acid mono/di esters Hostaphat MDAH

Mono-/di-2-ethylhexyl phosphoric acid ester, acid form

ca. 98 %

liquid

Hostaphat CG 120

Mono-/diisostearyl phosphoric acid ester, acid form

ca. 90 %

liquid

Hostaphat CS 120

Mono-/distearyl phosphoric acid ester, acid form

ca. 92 %

wax

Hostaphat 1306

Isotridecyl polyoxethyl (6 EO) phosphoric acid mono/diester,

ca. 96 %

liquid

acid form

Trade name

Chemical name

Active content

Appearance (20°C)

Phosphoric acid mono/di/tri esters Emulsogen DMR

Stearoyl polyoxyethylene phosphate

ca. 100 %

flakers

Hostaphat B 310

Tributoxyethyl phosphate, acid form

ca. 87 %

liquid

Hostaphat KL 340 D

Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt

ca. 90 %

liquid

Hostaphat KL 340 N

Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt

ca. 90 %

liquid

Hostaphat KW 340 D

Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt

ca. 90 %

liquid

Hostaphat KW 340 N

Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt

ca. 90 %

liquid

ca. 100 %

waxy

ca. 75 %

liquid

Alkyl phosphonic acids Hostaphat OPS 100

n-Octane phosphonic acid

Hostaphat OPS 75

n-Octane phosphonic acid + organ. solvent/water

Alkyl polyethylene glycol ether carboxylic acids Emulsogen CLA 020

Fatty alcohol polyoxyethylene carboxylic acid with 2 EO

ca. 90 %

liquid

Emulsogen CLA 030


ca. 90 %

liquid

Emulsogen CLA 050


ca. 90 %

liquid

Emulsogen CLA 070


ca. 90 %

liquid

Emulsogen CLA 110


ca. 90 %

liquid

Emulsogen COA 070


ca. 90 %

liquid

Emulsogen COL 020


ca. 90 %

liquid

Emulsogen COL 050


ca. 94 %

liquid

Emulsogen COL 080


ca. 90 %

liquid

Emulsogen COL 100


ca. 90 %

liquid

Coconut fatty acid isethionate, Na salt

ca. 65 %

flakes

Fatty acid isethionates Hostapon SCI-65

Fatty acid methyl taurides Arkopon T Teig 8015

Oleic acid methyl tauride, Na salt

ca. 40 %

paste

Hostapon CT Teig

Coconut fatty acid methyl tauride, Na salt

ca. 30 %

paste

Hostapon TPHC

Oleic acid methyl tauride, Na salt

ca. 60 %

powder

Fatty acid sarkosin and sarkoside Arkomon SO

Oleyl sarkosin

ca. 95 %

liquid

Medialan LD

Lauroyl sarcoside, Na salt

ca. 30 %

liquid

Alkyl benzenesulphonates, Ca-salts Calsogen 3546

Tetrapropylene benzenesulphonate, Ca-salt in 2-ethyl hexanol

ca. 60 %

liquid

Calsogen 4814

n-Dodecyl benzenesulphonate, Ca-salt in 2-ethyl hexanol

ca. 60 %

liquid

Phenylsulfonate CA

Tetrapropylene benzenesulphonate, Ca-salt in isobutanol

ca. 70 %

pasty

Phenylsulfonate

Tetrapropylene benzenesulphonate, Ca-salt in solvent naphtha

ca. 40 %

viscous liquid

CA 100

and a nonionic surfactant, flash point > 100°C

Phenylsulfonate CAL

n-Dodecyl benzenesulphonate, Ca-salt in isobutanol

ca. 70 %

pasty

ca. 62 %

liquid

Phenylsulfonate CAN Tetrapropylene benzenesulphonate, Ca-salt in isobutanol and a nonionic surfactant

13

Copolymerizable Emulsifiers & Speciality Monomers Product range Trade name

Chemical name

Active content

Appearance (20°C)

Vinyl ether alkoxylates (PO-EO-block polymers) Emulsogen R 109

Vinyl ether alkoxylate with 10 EO

ca. 90 %

liquid

Emulsogen R 208


ca. 80 %

liquid

Emulsogen R 307


ca. 70 %

liquid

Allyl ether alkoxylates (PO-EO-block polymers) Emulsogen RAL 109

Allyl ether alkoxylate with 10 EO

ca. 90 %

liquid

Emulsogen RAL 208


ca. 80 %

liquid

Emulsogen RAL 307


ca. 70 %

liquid

Allyl polyoxyalkylene sulphates Emulsogen APS 100

Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt

ca. 100 %

liquid

Emulsogen APS 104

Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt

ca. 40 %

liquid

ca. 100 %

liquid

ca. 90 %

liquid

Emulsogen APS 100 S Allyl polyoxyalkylene sulphate with 10 EO, Na salt

Allyl polyoxyarylene sulphates Emulsogen APG 2019 Allyl phenylpolyol ether sulphate with 20 EO, ammonium salt

Methacrylic acid esters

14

Genagen M 750 MA

Methacrylic acid ester of polyethyleneglycol ether

ca. 100 %

pasty

Genagen M 1100 MA

Methacrylic acid ester of polyethyleneglycol ether

ca. 100 %

waxy

Genagen LA 070 MA

Methacrylic acid ester of C12 /C14 fatty alcohol ethoxylate with 7 EO

ca. 100 %

liquid

Dispersing Agents Product range Trade name

Chemical name

Active content

Appearance (20°C)

ca. 80 %

powder

ca. 95 %

powder

ca. 92 %

powder

ca. 80 %

powder

ca. 35 %

liquid

ca. 26 %

liquid

ca. 35 %

liquid

Naphthalene sulphonic acid - formaldehyde condensates Dispersogen NN

Condensation product of formaldehyde and naphthalene sulphonate, sodium salt, max. 20 % Na2SO4

Dispersogen R 5


Dispersogen 5338


Alkylphenol - formaldehyde - bisulphite condensates Dispersogen 1494

Condensation product of formaldehyde, cresol, nonylphenol and sodium bisulphite; contains NaCl

Dispersogen 1494 liquid

Condensation product of formaldehyde, cresol, nonylphenol and sodium bisulphite; contains NaCl

Dispersogen P liquid

Condensation product of formaldehyde, cresol and sodium bisulphite; contains NaCl

Novolac derivatives Dispersogen 1728

Nonylphenol novolac polyoxyethylene sulphosuccinate, Na salt

Dispersogen 2774

Nonylphenol novolac ethoxylate

ca. 100 %

liquid

Dispersogen 2774-1

Nonylphenol novolac ethoxylate in ethylene glycol

ca. 50 %

liquid

Dispersogen 2774-2

Nonylphenol novolac ethoxylate in propylene glycol

ca. 50 %

liquid

Tristyrylphenol derivatives, anionic Dispersogen LFH

Tristyrylphenol polyoxyethylene phosphoric acid ester

ca. 96 %

liquid

Dispersogen LFS

Tristyrylphenol polyoxyethylene phosphoric acid ester,

ca. 92 %

liquid

Castor oil polyoxyethylene sulphosuccinic acid ester, Na salt

ca. 80 %

liquid

Stabilizer and dispersing agent for sodium silicate

n.n.

liquid

triethanolamine salt

Castor oil derivatives, anionic Dispersogen 4387

Quaternary dispersing agents Dispersogen SPS

in silicate paints

15

Defoamers Product range Trade name

Ionicity

Flash Point

Appearance (20°C)

Application example

> 100°C

liquid

FDA-approved defoamer for paper

Silicone containing defoamers Antimussol 4752

nonionic

treatment and other industrial applications Antimussol V 4847

nonionic

> 100°C

liquid

EPA-approved defoamer for crop protection

Antimussol V 5282

nonionic

> 100°C

liquid

defoamer for water miscible formulations

Polyalkylene glycol based defoamers Antimussol TW

nonionic

> 100°C

liquid

emulsion polymers, water treatment

Antimussol V 5084

nonionic

> 100°C

liquid

defoaming of surfactant formulations

Genapol PH 10

nonionic

> 100°C

liquid

EO/PO block polymer for metal working fluids and other industrial applications

Genapol PF 10

nonionic

> 100°C

liquid

EO/PO block polymer for industrial applications e.g. sugar refinement

Phosphate ester based defoamers Antimussol TIP

anionic

ca. 27°C

liquid

Phosphorus containing defoamer for emulsion polymerization and other industrial applications, water treatment

Mineral oil based defoamers Antimussol 4846 N

anionic

> 100°C

liquid

Phosphorus containing defoamer for emulsion polymers and other industrial applications

Antimussol V 5348

nonionic

> 150°C

liquid

emulsion paints, coatings, pigment preparations

16

Surfactants from Clariant Emulsifiers for emulsion polymerization Diagram: emulsion polymerization

Emulsifiers are substances that become active at interfaces. They perform a number of tasks in the complex system of emulsion polymerization. For example they enable the water-insoluble monomers to be distributed extremely finely in the aqueous phase and stabilize the polymer dispersion produced from it. Clariant emulsifiers are used to manufacture a variety of polymer systems: s

In the polymerization of vinyl acetate to homopolymers or co- and ter-

Polymer Particle

polymers together with other vinyl esters, acrylates, vinyl chloride and ethylene s

In the polymerization of pure acrylate and styrene-acrylate dispersions

s

In the manufacture of butadienestyrene latices

s

In the manufacture of polyvinyl chloride using the emulsion polymerization process

s

styrene rubber

Explanation:

s

Protective Colloid Molecules

In the manufacture of butadieneIn the manufacture of ABS plastic

The diagram beside shows a model of the complex interactions involved in the stabilization of the polymer particles.

OH Groups

Emulsifier Molecules

17

Surfactants from Clariant Emulsifiers for emulsion polymerization Apart from stabilizing the monomer

Vinyl acetate dispersion, model formulation

emulsion, emulsifiers have a great

Composition

influence on the properties of the poly-

Water ®

mer dispersions. These include important parameters such as particle size and

Concentration 32.02%

Tylose H 200 YG4

1.06%

Borax

0.26%

particle size distribution of the polymer

®

Emulsogen EPA 073

0.91%

particles, viscosity, electrolyte stability,

®

Emulsogen EPN grade

1.51%

Acetic acid 98 %

0.11%

Nipacide CI 15 (preservative)

0.15%

application properties of the polymer

Initiator solution (to liquor)

4.50%

dispersion.

Monomer mixture (to liquor)

5.30%

Initiator solution (stock batch)

6.48%

frost resistance of the dispersion, film®

forming properties and many other

The slightest changes to the polymerization system can lead to consider-

Monomer mixture (stock batch)

47.70%

able variations in the dispersion proper ties. To ensure consistent quality of the polymer dispersion, our emulsifiers

Monomer mixture ®

are subject to strict quality control.

VeoVa 10, Shell1)

25 %

Vinyl acetate

75 %

Initiator solution

The influence of the nonionic emul-

Potassium peroxodisulphate

1.17%

Water

98.83 %

sifier on the dispersion properties was investigated by means of a model

The ®Emulsogen EPN grades investigated are nonionic emulsifiers based on an

formulation for a polyvinyl acetate

oxoalcohol with different degrees of ethoxylation.

dispersion.

1)

Nonionic emulsifier

Degree of ethoxylation

Emulsogen EPN 118

11 mol ethylene oxide

Emulsogen EPN 207


Emulsogen EPN 287


Emulsogen EPN 407


VeoVa 10 is a registered trademark of S hell for 2,2-dimethyloctanoic acid vinyl ester

The two graphs that follow on page 8 show the influence of the degree of ethoxylation of the fatty alcohol ethoxylates on the viscosity of the dispersion

18

and on the particle size. The emulsifier concentrations were kept constant.

Influence of the emulsifier on the viscosity of a vinyl acetate/ VeoVa 10 dispersion

Viscosities of Emulsogen-containing polymer dispersions (vinyl acetate/VeoVa 10) Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91%)

Influence of the emulsifier on the particle size 2) of a vinyl acetate/ VeoVa 10 dispersion

Particle size of polymer dispersions (vinyl acetate/ VeoVa 10) with: Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91 %); Emulsogen EPN grades (1.51 %)

2)

Determined by turbidity measurements, these values are not absolute but indicate a tendency

Not only the constitution of the emul-

illustrate this effect on the viscosity

sifier but also its concentration has

of the dispersion by means of the model

an influence on the properties of the

formulation vinyl acetate/ VeoVa 10.

dispersion. The next four graphs

19

Surfactants from Clariant Emulsifiers for emulsion polymerization Influence of the concentration of Emulsogen EPN 118 on the viscosity of the dispersion

Viscosities of Emulsogen EPN 118-containing polymer dispersions (vinyl acetate/VeoVa 10); Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91%)

Influence of the concentration of Emulsogen EPN 207 on the viscosity of the dispersion

Viscosities of Emulsogen EPN 207containing polymer dispersions (vinyl acetate/ VeoVa 10); Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91%)

20


Viscosities of Emulsogen EPN 287-containing polymer dispersions (vinyl acetate/VeoVa 10); Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91%)


Viscosities of Emulsogen EPN 407-containing polymer dispersions (vinyl acetate/VeoVa 10); Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91%)

21

Surfactants from Clariant Emulsifiers for emulsion polymerization The following graphs on this page show

amount of coagulate and the water ab-

the effect of the emulsifier system on the sorption of the polymer film.

Influence of the emulsifier on the amount of coagulate in a vinyl acetate/ VeoVa 10 dispersion

Amount of coagulate in Emulsogen-containing polymer dispersions (vinyl acetate/VeoVa 10) with: Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91%); Emulsogen EPN grades (1.51%)

Method: Filtration of the dispersion through a 100- µm screen, then filtration of the filtrate thr ough the fine r 40- µm screen.

Influence of the emulsifier on the water absorption of a dispersion film based on vinyl acetate/ VeoVa 10

Wate r a bso rpt ion of Emulsogen-containing polymer dispersions (vinyl acetate/VeoVa 10) with: Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91%); Emulsogen EPN grades (1.51%)

22

This information is based on our present knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific Our products are constantly upgraded

properties of the products described

on the basis of the latest research re-

or their suitability for a particular appli-

sults. Products may occasionally be

cation. Any existing industrial property

deleted in the course of updating the

rights must be observed. The quality

sales range. Development products

of our products is guaranteed under

that have reached the production stage

our General Conditions of Sale.

are not included in this list.

February 2004

23

Exactly your chemistry. Clariant GmbH Division Functional Chemicals Industrial Performance Chemicals Research & Development Worldwide 65926 Frankfurt, Tel.: +49-69-305-6308, Fax: +49-69-305-16504

Marketing Europe 65840 Sulzbach, Tel.: +49-6196-757-7437, Fax: +49-6196-757-8945

USA & Canada Mount Holly NC 28120, Tel.: +1-704-822-2514, Fax: +1-704-822-2193

Mexico 53500 Naucalpan, Tel.: +52-55-5329-1877, Fax: +52-55-5387-3248

Latin America 04795-900 São Paulo SP, Tel.: +55-11-5683-7413, Fax: +55-11-5683-7694

China Tsuen Wan, Hong Kong, Tel.: +852-2406-4189, Fax: +852-2506-1636

Japan Tokyo 113-8662, Tel.: +81-3-5977-7934, Fax: +81-3-5977-7893

South-East Asia Tangerang, Jakarta, Tel.: +62-21-5579-3656, Fax: +62-21-5579-7139

Australia/New Zealand Chadstone Vic 3148, Tel.: +61-3-9254-1092, Fax: +61-3-9254-1011

Internet: www.ipc.clariant.com

4 0 / 2 0 E 6 1 2 5 R B E K & B S D

Surf Act Ants for Industrial Applications

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