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MATERIAL SAFETY DATA SHEET
Calcium Hypochlorite Section 01 - Chemical An !rouct An Company In"ormation !rouct Ienti"ier ……………………... Accu-Tab SI Calcium Hypochlorite Tablets !rouct #$e ………………………… …………………………..... ..... Disifectio!saiti"er Disifectio!saiti"er for potable #ater$ #aste#ater$ i%ustrial processig a% coolig #ater. Supplier %ame…………… %ame………………………. ………….…. …. ClearTech I%ustries I%ustries Ic. &'(& Haselma A)eue Sas*atoo$ S+. Caa%a S, /' !repare &y........... &y................……… .....……………..… ……..….. .. ClearTech I%ustries Ic. Techical Departmet Phoe0 '(23224-&&& !reparation Date.........… Date.........…………… ………….….. .….. 5o)ember 6$ &(1( '(-Hour Emer)ency !hone…… !hone ………… …….. .. '(2-22 '(2-224-& 4-&&& &&
Section 0' - Compo$ition * In"ormation on In)reient$ Ha+arou$ In)reient$....……… In)reient$ ....…………....Calcium …....Calcium Hypochlorite Calcium Hy%ro7i%e Calcium Carboate Calcium Chlorate
29 : &9 : &9 : &9
CAS %um,er ...................…… ...................…….…….... .…….... Calcium Hypochlorite Calcium Hy%ro7i%e Calcium Carboate Calcium Chlorate
,,,8-4-' 1'(-2&-( 4,1-'4-1 1(1',-,4-'
Synonym $....................……………...5oe $....................……………...5oe
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Section 0/ - Ha+ar Ienti"ication Inhalation...................………….….... Dust a% mist irritate the ose a% throat. I cofie% areas$ mechaical agitatio ca result i high le)els of %ust$ a% reactio #ith icompatibles materials aci%s a% #ater!moisture3 ca result i high cocetratios of chlorie )apour$ either of #hich may result i burs to the respiratory tract$ pro%ucig lug e%ema$ shortess o f breath$ #hee"ig$ cho*ig$ chest pais$ impairmet of lug fuctio$ a% possible permaet lug %amage. Sin Contact * A,$orption…….…... Calcium hypochlorite %ust a% solutios ca cause irritatio a% chemical burs$ #hich are characteri"e% by re%ess$ s#ellig a% tissue %estructio. Eye Contact................………….…... ;7posure to calcium hypochlorite ca cause se)ere eye irritatio a% )isio impairmet iclu%ig bli%ess. In)e$tion.....................………………. Igestio ca cause burig of the mouth a% throat. Pro%uct ca be fatal if s#allo#e%. Epo$ure Limit$…………………….. ACSHA-T=A0 (.mg!m ' chlorie3 >SHA-ST;0 1.(mg!m ' chlorie3 >SHA-T=A0 mg!m ' calcium hy%ro7i%e3 >SHA-P;0 1mg!m' calcium carboate$ total %ust3
Section 0( - Fir$t Ai Mea$ure$ Inhalation....................……………….. ?emo)e )ictim to fresh air.
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Aitional In"ormation.....…………... 5ot a)ailable
Section 02 - Fire Fi)htin) Conition$ o" Flamma,ility……….... 5o-flammable. 5ote calcium hypochlorite is a strog o7i%i"ig aget may form e7plosi)e mi7tures #ith combustibles$ orgaic$ or other o7i%i"able materials. Mean$ o" Etinction........………….... Drech #ith #ater$ a% cool surrou%ig pro%ucts a% area #ith #ater oly. Do ot use %ry chemicals or foams. Fla$h !oint....…………………………. 5ot applicable Auto-i)nition Temperature…………. 5ot applicable #pper Flamma,le Limit …………….. 5ot applicable Lo3er Flamma,le Limit...……….….. 5ot applicable Ha+arou$ Com,u$ti,le !rouct$... Chlorie$ o7yge$ a% chlorie moo7i%e at higher temperatures. =ater i cotact #ith hot calcium hypochlorite ca release hy%rochloric aci% or chlorie gas. Special Fire Fi)htin) !roceure$..... =ear 5I>SH-appro)e% self-cotaie% breathig apparatus a% protecti)e clothig. Pro%uct %ecomposes at appro7imately 1,(-18(oC #hich releases o7yge. Eplo$ion Ha+ar$…………………... 5ot sesiti)e to mechaical impact or static %ischarge.
Section 04 - Acciental Relea$e Mea$ure$ Lea * Spill................….…………….. Bse e7treme cautio i ha%lig spille% material. Do ot mi7 #ith ay other chemicals. Cotamiatio #ith moisture$ aci%s$ orgaics or other easily combustible materials such as petroleum$ pait pro%ucts$ #oo% or paper may cause fire or )iolet %ecompositio. If fire or %ecompositio occurs i area of spill$ imme%iately %ouse #ith plety of #ater. >ther#ise$ s#eep up all )isible material usig a clea e#$ if possible3$ %ry sho)el a% broom a% %issol)e material i #ater. Spille% material that has bee s#ept up a% %issol)e% i #ater shoul% be use% imme%iately i the ormal applicatio for #hich this pro%uct is beig cosume%.
Deacti5atin) Material$...……….…... Dissol)e spille% material i #ater a% carefully a%% hy%roge pero7i%e '9 ((m hy%roge pero7i%e per pou% calcium hypochlorite3 the %ilute further #ith #ater a% %ispose accor%ig to local regulatory byla#s.
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Section 06 - Hanlin) an Stora)e Hanlin) !roceure$.......………….. Bse proper euipmet for liftig a% trasportig all cotaiers. Bse sesible i%ustrial hygiee a% house*eepig practices. = ash thoroughly after ha%lig. A)oi% all situatios that coul% lea% to harmful e7posure. Stora)e Re7uirement$......……...….. Store i a cool$ %ry$ #ell-)etilate% place. +eep cotaier tightly close%$ a% a#ay from icompatible materials such as combustible a% flammable pro%ucts. +eep out of the su. +eep pro%uct paca*gig clea a% free from cotact iclu%ig other pool treatmet pro%ucts$ aci%s$ orgaic materials$ itroge-cotaiig compou%s$ %ry po#%er fire e7tiguishers cotaiig moo-ammoium phosphate3$ o7i%i"ers$ all corrosi)e liui%s$ flammable or combustible materials$ etc.
Section 08 - !er$onal !rotection an Epo$ure Control$ !rotecti5e E7uipment Eye$.………………………….………... Chemical goggles$ full-face shiel%$ or a full-face respirator is to be #or at all times #he pro%uct is ha%le%. Cotact leses shoul% ot be #or they may cotribute to se)ere eye iury. Re$piratory………………………….... Bse 5I>SH-appro)e% respirator - full facepiece #ith chlorie a% %ust!mist cartri%ges #he %ust is preset. A self-cotaie% breathig apparatus shoul% be use% for maor spills. 9lo5e$………………………………..... Imper)ious glo)es of chemically resistat material eopree$ butyl rubber$ itrile3 shoul% be #or at all times. =ash cotamiate% clothig a% %ry thoroughly before reuse. Clothin)………………………..…….... Eo%y suits$ apros$ a%!or co)eralls of chemical resistat material shoul% be #or at all times. =ash cotamiate% clothig a% %ry thoroughly before reuse. Foot3ear ……………………………..... Imper)ious boots of chemically resistat material shoul% be #or at all times.
En)ineerin) Control$ :entilation Re7uirement$………...... Fechaical )etilatio %ilutio or local e7haust3$ process or persoel eclosure a% cotrol of process co%itios shoul% be pro)i%e%. Supply sufficiet replacemet air to ma*e up for air remo)e% by e7haust systems. ;ther ………………………………….... ;mergecy sho#er a% eye#ash shoul% be i close pro7imity.
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Section 0< - !hy$ical an Chemical !ropertie$ !hy$ical State.......……....………….... Soli% ;or an Appearance…..…………... =hite tablets #ith a slight chlorie o%our ;or Thre$hol....……………............ 5ot a)ailable Speci"ic 9ra5ity =ater>1.………….. 5ot applicable :apor !re$$ure mm H)? '0C.….….. 5ot applicable :apor Den$ity Air>1...…………….... 5ot applicable E5aporation Rate........……..…….….. 5ot applicable &oilin) !oint...............………….…..... 5ot applicable Free+e*Meltin) !oint....…………….... Decomposes at 1,(-18(GC pH@@..........................……………….….. Al*alie =ater*;il Di$tri,ution Coe""icient.... 5ot applicable &ul Den$ity..............…………….….. 1.(,-1.1' g!cm ' :olatile$ ,y :olume………..……... 5ot a)ailable Solu,ility in =ater ...………………..... &1,g! at &,GC Molecular Formula......………….….... Ca>Cl3 & Molecular =ei)ht........……………..... 14&.68
Section 10 - Sta,ility an Reacti5ity Sta,ility.................…………....……………. Stable i optimum storage co%itios. Heat$ sulight a% cotamiatio coul% cause %ecompositio. Incompati,ility ..............…………..……….. Aci%s$ re%ucig agets$ combustible materials such as #oo%$ cloth$ or orgaic materials$ %ry po#%er fire e7tiguishers cotaiig mooammoium phosphate$ metals such as iro a% copper a% their alloys$ #ater or steam$ ammoia$ urea$ amies. Ha+arou$ !rouct$ o" Decompo$ition.. =ater i cotact #ith calcium hypochlorite releases chlorie gas. Cotact #ith icompatibles presets a e7plosio a% fire ha"ar%. To7ic or corrosi)e fumes may be liberate%. These iclu%e chlorie gas.
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!olymeri+ation...........…………….…….…. =ill ot occur
Section 11 - Toicolo)ical In"ormation Irritancy.................……..………….…. Causes irritatio a% burs to eyes a% s*i. Sen$iti+ation........…….......…………. 5ot a)ailable Chronic*Acute E""ect$……...………. S*i irritatio may occur from repeate% or prologe% s*i cotact. Chroic ihalatio e7posure may cause impairmet of lug fuctio a% permaet lug %amage. Asthma$ respiratory a% car%io)ascular %isease may be aggra)ate% by e7posure to this chemical. Syner)i$tic Material$...……....……... 5ot a)ailable Animal Toicity Data......…..……….. C (ihalatio$rat$1 hour30 o mortality at '.mg! slight to )ery lo# to7icity3 D(oral$rat30 8(mg!*g D(%ermal$rabbit30 1(((mg!*g Carcino)enicity......……......………... 5ot cosi%ere% to be carciogeic as per IA?C$ 5TP$ >SHA$ a% AC
Section 1' - Ecolo)ical In"ormation Fi$h Toicity..................…………….. C (bluegill$62 hour30 (.(88mg!
&ioe)raa,ility .............……….….... 5ot a)ailable En5ironmental E""ect$………………. To7ic to fish
Section 1/ - Di$po$al Con$ieration =a$te Di$po$al...........…...………….. Dispose i accor%ace #ith all fe%eral$ pro)icial$ a%!or local regulatios iclu%ig the Caa%ia ;)irometal Protectio Act.
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Section 1( - Tran$portation In"ormation TD9 Cla$$i"ication Cla$$……………..………………..….... .1 9roup...............…………….......……... II !I% %um,er .................……..………... B5 &88( ;ther ………………………………….... Secure cotaiers full a%!or empty3 #ith suitable hol% %o# %e)ises %urig shipmet.
Section 12 - Re)ulatory In"ormation =HMIS Cla$$i"ication.......…………....C$ ; %;TEB THE !R;D#CT LISTED ;% THIS MSDS HAS &EE% CLASSIFIED I% ACC;RDA%CE =ITH THE HAARD CRITERIA ;F THE CA%ADIA% C;%TR;LLED !R;D#CTS RE9#LATI;%S@ THIS MSDS C;%TAI%S ALL I%F;RMATI;% RE#IRED &Y TH;SE RE9#LATI;%S@ %SF Certi"ication................................Pro%uct is certifie% u%er A5SI!5S@ Sta%ar% 2( for %isifectio$ o7i%atio a% algici%e treatmet at a ma7imum %osage of 1mg!.
Section 14 - ;ther In"ormation %oteB The resposibility to pro)i%e a safe #or*place remais #ith the user. The user shoul% cosi%er the health ha"ar%s a% safety iformatio cotaie% herei as a gui%e a% shoul% ta*e those precautios reuire% i a i%i)i%ual operatio to istruct employees a% %e)elop #or* practice proce%ures for a safe #or* e)iromet. The iformatio cotaie% herei is$ to the best of our *o#le%ge a% belief$ accurate. Ho#e)er$ sice the co%itios of ha%lig a% use are beyo% our cotrol$ #e ma*e o guaratee of results$ a% assume o liability for %amages icurre% by the use of this material. It is the resposibility of the user to comply #ith all applicable la#s a% regulatios. AttentionB Recei5er o" the chemical )oo$ * MSDS coorinator As part of our commitmet to the Caa%ia Associatio of Chemical Distributors CACD3 ?esposible Distributio iitiati)e$ ClearTech I%ustries Ic. a% its associate% compaies reuire$ as a co%itio of sale$ that you for#ar% the attache% Faterial Safety Data Sheets3 to all affecte% employees$ customers$ a% e%-users. ClearTech #ill se% ay a)ailable supplemetary ha%lig$ health$ a% safety iformatio to you at your reuest. If you ha)e ay uestios or cocers please call our customer ser)ice or techical ser)ice %epartmet.
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ClearTech Inu$trie$ Inc@ - Location$ Corporate Hea ;""iceB '/0' Han$elman A5enue? Sa$atoon? S? S6L 2/ !honeB /04-44(-'2'' FaB /04-442-4'14 333@ClearTech@ca Location ?ichmo%$ E.C. Calgary$ AE. ;%moto$ AE. Sas*atoo$ S+. ?egia$ S+. =iipeg$ FE. Fississauga$ >5.
Are$$ 1&4'1 Horseshoe =ay 12; - 4(th St. S.;. 11,( - 18(th Street &'(& Haselma A)eue He%erso Dri)e '4( Saulteau7 Crescet ,48( Eath ?oa%
!o$tal Coe ,A 4J2 T&C &A1 TS 15, S, /' S4& J& ?'K 'T& 4T 1&
!hone %um,er 2(4-&,&-4((( 4('-&,6-1(62 ,8(-4&-2((( '(2-6''-(1,, '(2-,&1-,,', &(4-68,-6,,, 6(-21&-(22
Fa %um,er 2(4-&,&-462 4('-&'2-(686 ,8(-4&-42(( '(2-6''-'&8& '(2-,&1-8211 &(4-68,-6,,( 6(-21&-(,
'( Hour Emer)ency %um,er - All Location$ - /04-44(-'2''
