TUGAS PRA RANCANGAN PABRIK HIDROGEN PEROKSIDA BAHAN BAKU 2-ETHYL ANTHRAQUINONE DENGAN PROSES AUTOOKSIDASI KAPASIT KAPASITAS AS 55000 TON/TAHUN TON/TAHUN
KELOMPOK 2 :
-
LAEL LAELA A RIZA RIZA KURN KURNIA IAW WAN PUPUT DWI RAHAYU ANNI ANNISA SA RIZK RIZKY Y RAHA RAHAYU YU ITA RACHMAWATI
2016 201671 7104 0450 5033 330 0 2016710450334 20167 016710 1045 4503 0335 35 2016710450356
PROGRAM STUDI TEKNIK KIMIA FAKULT AKULTAS TEKNOLOGI T EKNOLOGI INDUSTRI UNIVERSITAS JAYABAYA
TUGAS 1
1
I.
Pe!"#$%$" H&!'()e *e'(+,&!" -H 2O2 "!"%"# /"&'" e&) ,e!&+& %e&# +e"% !"'&*"!" "&' ") e'$*"+" (+,&!"(' +$". Se"" && !&e$+" (%e# L($&, "/$e, T#e"'! *"!" "#$ "# $ 181 1818. 8. Se Se")" ")"&& "# "#" " +& +&&" &" "( "(') ')"& "&+ + !"% !"%" " &! &!") ") &! &!$, $,'& '& e+ e+(% (%()& ()& " ") ) !&)$"+" !&)$ "+" $$+ #&!'( #&!'()e )e *e'(+ *e'(+,&!" ,&!" "!"%"# "$( (+,&! (+,&!",& ",& "#'" "#'"$&( $&(e. e. De)" /&'& +#"," ") e'"$ +#", +e","" !" $!"# %"'$ !"%" "&' !"%" +(!&,& ('"% -ambient +(!&,&" ,")" ,"&% !e)" %"9$ !e+(*(,&,& +&'"+&'" +$'") !"'& 1; *e' "#$. <"#" "+$ *e$"" #&!'()e *e'(+,&!" "!"%"# )", #&!'()e -H 2 !" )", (+,&)e -O2. Te+(%()& ") ""+ !&)$"+" !& !"%" &!$,'& #&!'()e *e'(+,&!" "!"%"# "$( (+,&!",& A#'"$&(e. S"%"# ,"$ +e$))$%" #&!'()e *e'(+,&!" !&"!&)+" !e)" (+,&!"(' ") %"& "!"%"# "!" %"# ,&= ,&=" "" " " ") ) '" '""# "# %& %&)+$ )+$)" )". . I" &! &!"+ "+ e e&) &))"% )"%+" +" 'e,& 'e,&!$ !$ #" #"" " "&' !" (+,&)e (+, &)e. . Ke+ Ke+$" $"" " (+, (+,&!" &!"(' ('" " *$ !"* !"*" " !&" !&"$' $' ,e, ,e,$"& $"& !e !e)" )" +e +e$$ $$#" #".. Se Se")" ")"&& /((# /( (# !"% !"%" " &! &!$, $,'& '& *$% *$%* * !" +e' +e'", ", *e *e))$ ))$"" "" #&! #&!'() '()e e *e' *e'(+, (+,&!" &!" &" &"," ,""" !& +(& +( &",&+ ",&+" " !e !e)" )" N"O N"OH H ""$ ,(! ,(!"" "*& "*&.. Se Se"+& "+& ", "," " "+ "+"" %"9 %"9$ $ !e+ !e+(* (*(,& (,&,& ,& #&!'()e *e'(+,&!" *$ ,e"+& &))& K"'e" #&! K"'e" #&!'() '()e e *e' *e'(+, (+,&!" &!" "!" "!"%"# %"# (+, (+,&!" &!"(' (' " ") ) +$" +$" "# "#" " && !& !&"= "=""+ ""+" " "$,& " $,&"" ,e ,e")" ")"&& "# "#" " *e *e$& $&# # -bleach bleach !&, !&,&= &=e+ e+" " (+ (+,&! ,&!"( "('' !" ,e" ,e")"& )"& "# "#" " "+"' '(+e. H&!'()e Pe'(+,&!" "!"%"# "#" *e$&# ") *"%&) e*" !" e=&,&e $$+ e+,&%. H&!'()e *e'(+,&!" !&9$"% e", !e)" e'")"& e'e+ !")") !"%" +(,e'",& 'e!"# -35; -3 5; ,e ,e")" ")"&& *e *ee' e',&# ,&# %$+ %$+"" "" ""$ $ ,e ,e")" ")"&& *e *e$& $&# # )&) )&)&& -*" -*"!" !" +( +(,e ,e'", '",&& e' e'$+$ $+$'. '. D"%" D"% " +( +(,e ,e'",& '",& ")" ")"+ + & &))& ))& -& -&,"% ,"%" " e' e'e+ e+ !") !")") ") >% >%'(? '(?%@ %@ !&9 !&9$"% $"% ,e ,e")" ")"&& *e$&# *"+"&" !" !&,&=e+". Pe))$"" #&!'()e *e'(+,&!" !"%" +(,e&+" !" "+"" "+ "" &! &!"+ "+ !& !&e" e"'+" '+" +"' +"'e" e" " && $! $!"# "# e' e'e"+ e"+,& ,& -(+ -(+,&! ,&!" " +$" +$" !" +(' +('(,& (,&=. =. H&!'()e Pe'(+,&!" 9$)" !&*e')$"+" $$+ ee',&#+" "&' %&"# ") e'/e"' *(%$,& ,e*e'& : H&!'()e S$%=&!" -H2S P#e&%&/, C"&!e, !" $,$' %"& ") e'!"*" !"%" %&"# "&' B1. Ke$$#" &!$,'& "+" #&!'()e *e'(+,&!" e'$, e&)+" !"'& "#$ +e "#$.
I I.
<"#" <" <"+$ !" !" P' P'(!$+
2.1 <"#" <"+$ U"" 2
1. H&!'()e A. S&=" &,&, R$$, (%e+
%$: H2
%$: 2 )')(%
: >",
S*e,&=+ )'"F& -2527 (C
: 0070G
T&&+ Le%e# -K
: 13G5
T&&+ !&!&# -K
: 203G
Te+"" K'&&, -"
: 128
Te*e'"$' +'&&, -K
: 3318
<. S&=" K&&" H&!()e !"*" e'e!$+,& &+"" '")+"* &,"% "," ",e".
De)" "$" +""%&, #&!'(,$%=$'&,",& !"*" ee/"# &+"" +"'( !" ,$%=$'. RSH -e'/"*" H2
H2S
RSR -,$%=&!"
2H
RH
2H2R RH RH
C4H4S -#&(*ee 4H 2 H2S C4H10 D"*" e'e"+,& !e)" CO ee$+ e"" *"!" ,$#$ 400 (C
2. U!"'" A. S&=" =&,&, Tabel 1.4. Sifat sis Udara 3
N(. S&=" >", 1 2
N2
O2
2802 )",
32 )",
&!"+ e'"'"
&!"+ e'"'"
&!"+ e'"$ 125
&!"+ e'"$ 17
3
S*e,&=&+ >'"F&
4
Me%&) P(&
20G8G
2148
5
T&&+ D&!&# -(C T&&+ K'&&, -K Te+"" K'&&, -"'
1G58
183
1261 335
15458 4G8
G01
734
805
114G
6 7 8 G
J(%$e K'&&, -/3(% L&$&! !e,&", -)'/3
-Pe'' 6e! E!&&( S&=" K&&"
O2 e'e"+,& !e)" ,e$" , e$" e%ee +e/$"%& HeNe !" A'. A'. &+" &+" !&'e"+ !&'e"+,& ,&+" +" !e) !e)" " "#" "#" "+"' "+"' *e' *e'(% (%e$ e$ (&% (&% "$'"% "$'"% )", )"," "$ $ "'" "'" "+" !&#",&%+" *"", CO 2 H2O ,e'" 'e,&!$ !"'& $!"'". - Pe'' 6e! E!&&(
3. 2E#% A#'"$&(e
R$$, M(%e+$% : C 16H12O2
2.2 <"#" Pe!$+$) 1.
%$: C6H6
%$: 78 )')'(%
: /"&'
Ke$'&"
: G8; -&
I*$'&", -H2O
: 2;-"+,
T&&+ %e%e#
: 55(C
T&&+ !&!&#
: 80(C
De,&-25(C
: 087 )'/3
2. K""%&, P"%%"!&$
R$$, (%e+$% : P! 4
I I I.
H2O2 *e+" !"*" e'e"+,& !e)" #&!'",& #&!'" ee$+ &()e !" "&' !&,e'"& %e!"+". H2O2 NH2 NH NH2.2H2O N2 5 H2O H2O2 !"*" e'e!$+,& ,e"" (+,&!" A)O H2O2 2 A) H 2O O2 2 MO4 5 H2O2 6 H 2M2 8 H 2O 5 O 2
De,+'&*,& P' P'(,e, P'(, P'(,e, e, *e *e$" $"" " "$( "$((+ (+,& ,&!" !",& ,& e) e))$ )$" "+" +"
"# "#'" '"$ $& &( (.. *'(, *'(,e, e,
#&!' #&!'() ()e e *e'( *e'(+, +,&! &!"" P'(, P'(,e, e,
"$( "$((+ (+,& ,&!" !",& ,&
*e *e$" $"" "
") ") !&)$ !&)$" "+" +" #&!' #&!'() ()e e
"# "#'" '"$ $& &( (ee
"& "&$ $
*e'( *e'(+, +,&! &!""
e'$ e'$*" *"+" +"
*'(, *'(,e, e,
*'( *'(,e, ,e, !e) !e)" " ") ")
!&*e'+e"%+ !&*e'+e"%+" " *e'"" *e'"" (%e# &!$,'& I> "'e "'e !& e'" *"!" "#$ 1G40". P'(,e, "$((+ "$((+,&! ,&!",& ",& "#'" "#'"$& $&( ( e'!&' e'!&'&& !"'& !"'& "#"* "#"* #&!'() #&!'()e" e",& ,& (+,&!" (+,&!",& ,& e+,'"+ e+,'"+,& ,& !" !&,&%",& 2 e&% "#'"$&(e e9"!& #&!'()e *e'(+,&!" B1. P'(,e, "$((+,&!",& "#'"$&( !e)" +""%&,"(' *"%"!&$ !&*&%&# !"%" *e$"" #&!'()e *e'(+,&!" !e)" *e'&")" ""'" %"& *e'"%"" ") !&$$#+" 'e%"&= %e&# ,e!&+& ,e#&))" &"" ") !&*e'%$+" $$+ &Fe,",& %e&# $'"# !" $!"# !"%" *e)(*e'",&"". 5
TINJAUAN PROSES
1. T"#"* "#"* H&!' H&!'() ()e e", ",&& U*" ,e)"' #&!'()e !e)" +"!$)" N 2 ,e")"& &e' 2 ; (% !&/"*$' !e)" )", #&!'()e *"!" "%&'" 'e//%e !" !&"",& 9$%"# N 2 5; (%. U*" ",$+ +e 'e"+(' #&!'()e",& *"!" ,$#$ 40 ⁰C !" e+"" 4 ". U*" /"&' ") e'$*" working solution ") e'!&'& !"'& 2e&% "#'"$&( ") !&%"'$+" !"%" eee !&'e"+,&+" !"%" 'e"+(' #&!'()e",& ") e'$*" 'e"+(' !e)" +""%&, *"%"!&$. Re"+,& ") e'9"!& "!"%"# ,e")"& e'&+$ : C16H12O2-L H2-) C16H12-OH2 -L 2. T"#"* "#"* O+,& O+,&!" !",& ,& H",&% H",&% 'e"+ 'e"+,& ,& ") ") e'$ e'$*" *" e' e'"# "#&! &!'( '(" "# #'" '"$& $&( (e e -C16H12-OH2 +e$ +e$!& !&" " !&'e"+,&+" !e)" O 2 !& !"%" 'e"+(' (+,&!",& *"!" e+"" 4 " !" ,$#$ 40 ⁰
C. Re"+,& ") e'9"!& "!"%"# ,e")"& e'&+$ : C16H12 -OH2-L O2 -) C16H12O2-L H2O2-L 3. T"#"* "#"* E+, E+,'" '"+, +,&& H&!'()e *e'(+,&!" ") ",&# e'/"*$' ('+&) ,(%$&( +e$!&" !&*&,"#+" !&e"'" e+,'"+,& 4. T"#"* "#"* D&, D&,&% &%", ",&& H&!'()e *e'(+,&!" ") ",&# e'/"*$' "&' !&$'&+" !"%" e"'" !&,&%",& $$+ e!"*"+" +e$'&" ") !&&)&+". IJ. IJ.
D"" D"" I*( I*('' !" !" E+,* E+,*(' (' H&!' H&!'() ()e e Pe'( Pe'(+, +,&! &!"" 4.1 D"" I*(' T"e% 3.1 D"" I*(' H&!'()e Pe'(+,&!" !& I!(e,&" TAHUN
JUMLAH (Kg)
2013 2014 2015 2016
19727862 20554013 20646548 21636777
2017
29991408
-.*,.)(.&!
6
D"" I*(' H&!'()e Pe'(+,&!" T"#$ 20132017
4.2 D"" E+,*(' TAHUN
JUMLAH (kg)
2013 2014 2015 2016
3982858 368571 1519616 2898507
2017
5345987
-.*,.)(.&! Re=e'e,& 1.#*:/#&4&*"&e,.%(),*(./(.&!20120G*'(,e,*e$""#&!'()e 1.#*:/#&4&*"&e,.%(),*(./(.&!2 0120G*'(,e,*e$""#&!'()e *e'(+,&!".#% -1 M"'e 2018 1G:30 WI<
7
TUGAS 2
8
I.
P! P!!" !"#$ #$! ! K$% K$%$& $&'" '"$& $& P$() P$()'* '*
Ke$$#" #&!'()e *e'(+,&!" !& I!(e,&" e'$, e)"%"& *e&)+"""%"$*$ I!(e,&" I!(e,&" ,$!"# e*'(!$+ e*'(!$+,& ,& ,e!&'& ,e!&'& e"*& ",&# ee'%$+" ee'%$+" &*(' !"'& e)"'" e)"'" %"& #"% && !"*" !&%&#" *"!" "e% 3.1. -
JUMLAH (Kg)
2013 2014 2015 2016
19727862 20554013 20646548 21636777
2017
29991408
-.*,.)(.&!
N+.
1 2 3 4
N$,$ P$()'*
PT. Pe'(+,&!" I!(e,&" PT. S&!(*e? Pe'("" PT. R&,"! <'","%& PT. S""(' I& Pe'(+,&!"
M#$' P)+#*&' 1GG0 1GG2 1GG7 1GG8
K$%$&'"$& T+!/T$#! 21000 18000 30000 20000
L+*$&'
C&+"*e+ "&
'e,&+ - ./&/./( ./&/./( P'(!$,e P'(!$,e H&!'()e H&!'()e Pe'(+,&!" Pe'(+,&!" 9$)" e'!"*" !& Ae'&+" Ae'&+" Se'&+" ") !"*" !&%&#" !&%&#" !"'& "e% 3.3 e'&+$ :
9
T"e% 3.3 P'(!$,e H&!'()e Pe'(+,&!" !& #$eri!a Seri!at
N+. 1 2 3
P$()'* C#e**'(? De)$," D$ P(
4 5
E+" N(e% MC
6 (' H("'! 7 S(%F" Ie'(?
L+*$&' P$()'* K$%$&'"$& "+!/" &,(, O. 36000 >&,(,.A%" 36000 C(%$$, M&,,&,,&*& 35000 <"*(' Te?", 43000 P'&/e )e(')e <.C. 41000 S"" C%"'" Me?&/( 10000 S*'&) #&%% W.J". 38000 M$,+()ee O+%"#(" 3000 L()F&e 50000 W",#&)( -K&'+ K.E O#e' F(%. 13 2000
>""' 3.1. >'"=&+ I*(' H&!'()e Pe'(+,&!" !& I!(e,&" D"'& )'"=&+ !&!"*"+" *e',""" )"'&, %$'$, "&$ Y 2160G8560Q 2251132160 !&"" Q "!"%"# "#$ ") !&#&$) !"'& "#$ 2013 ,"*"& "#$ ") "+" !&#&$) ,e!")+" Y "!"%"# "!"%"# +e$$ +e$$#" #" &*(' &*(' #&!'() #&!'()e e *e'(+, *e'(+,&!" &!" *"!" *"!" "#$ "#$ e'e e'e$ $ !"%" !"%" ,"$" ,"$" +). Pe'+&'"" &*(' #&!'()e *e'(+,&!" !"'& "#$ 2013 #&))" "#$ 2020 !"*" !&%&#" *"!" "e% 3.3 ,e")"& e'&+$ : T"e% 3.4 Pe'+&'"" Pe'+&'"" I*(' Hidrogen Hidrogen ero!sida Ta%&n 2013 ' 2020 TAHUN
x
Y (kg)
2013 2014
-2 -1
19727862 20554013 10
2015 2016 2017 2018 2019
0 1 2 3 4
20646548 21636777 29991408 28994278 31155264
2020
5
33316250
D"'& "e% 3.4 !&$" )'"=&+ *e'+&'"" &*(' #&!'()e *e'(+,&!" !"'& "#$ 2013 #&))" "#$ 2020 ") !&$9$++" !"%" >""' 3.2.
Pe'+&'"" I*(' H&!'()e Pe'(+,&!" T"#$ 20132020
>""' 3.2 >'"=&+ Pe'+&'"" I*(' H&!'()e Pe'(+,&!" T"#$ T"#$ 2013 2020 U$+ *e'+&'"" &*(' #&!'()e *e'(+,&!" ,ee%"# *"'&+ e'(*e'",& !"'& "#$ 2020 #&))" "#$ 2030 !"*" !&%&#" *"!" "e% 3.4.
T"e% 3.5 Pe'+&'"" I*(' Hidrogen Hidrogen ero!sida ada Ta%&n 2020 ' 2030 TAHUN
x
Y (kg)
2020 2021
5 6
33316250 35477235 11
2022 2023 2024 2025 2026 2027 2028 2029
7 8 9 10 11 12 13 14
37638221 39799206 41960192 44121178 46282163 48443149 50604134 52765120
2030
15
54926106
>""' 3.3 >'"=&+ Pe'+&'"" I*(' H&!'()e Pe'(+,&!" T"#$ T"#$ 2020 2030
Re=e'e,& 1. #*,:&!.&+&*e!&".(')&+&H&!'()e*e'(+,&!" #*,:&!.&+&*e!&".(')&+&H&!'()e*e'(+,&!" -2 -2 M"'e 2018 17.34 WI< 12
2. #*,:e*'&,.$,."/.&!2457162801506200G03441.*!= #*,:e*'&,.$,."/.&!2457162801506200G03441.*!= -1 M"'e 2018 18.30 WI<
13
TUGAS
V.
D&*)'%&' P)+&&
14
O+,&!",& *"',&"% !"'& "%+(#(% *'&e' ""$ ,e+$!e' !"%" =",e %&$&! ""$ $"* e)#",&%+" #&!'()e *e'(+,&!" !" "%!e#&! ""$ +e( !e)" &e%! ") &))&. Re"+,& e'%"),$) *"!" ,$#$ 70 160 (C !" e+"" 10 20 ". >", (+,&)e !"'& $!"'" !&%e"+" ee$, "%+(#(% ,e+$!e' *"!" ")&" ""# +(%( (+,&!"(' &","" "%+(#(% ,e+$!e' , e+$!e' ") ,e'&) !&)$"+". Re"+,& ") e'9"!& "!"%"# ,e")"& e'&+$ : Re"+,& ") e'9"!& "!"%"# ,e")"& e'&+$ : -CH32CHOH O2 H2O2 CH3COCH3 S$#$ !&"", 70 (C !&*e'%$+" ")"' e)#",&%+" %"9$ ") "&+ !" e+"" !"'& ,&,e !&9")" ,e&!"+&!"+" ,"" !e)" e+"" $"* !"'& =",e %&$&! *"!" ,$#$ 'e"+,& ") !&)$"+" ,e" %"9$ (+,&!",& "%+(#(% ,")" e'*e)"'$# e'#"!"* 9$%"# "," (')"&+ ") "!" !"%" e$+ %&$&!" ,e#&))" "+$$%",& !"'& 9$%"# "," ") /$+$* !"*" ee"+" 'e"+,& &!"+ e'+('(% &%" +(,e'",& #&!'()e *e'(+,&!" &))&. H",&% H",&% /"*$' /"*$'" " ") ") e'&,& e'&,& "%+(#( "%+(#(%% ") ") &!"+ &!"+ e'*"+ e'*"+"& "& #",&% #",&% +e( +e( !" #&!'() #&!'()e e *e'(+, *e'(+,&!" &!" +e$!& +e$!&" " !&*&,"# !&*&,"#+" +" !e)" !e)" falling film evaporator !&"" "#" (')"&+ !" "&' e%"%$& ")&" "", +(%( !" #&!'()e *e'(+,&!" e'"!" !&")&" ""# +(%( *"!" +(%( !&""#+" "&' ") /$+$* ,e#&))" +(,e'",& #&!'()e *e'(+,&!" !&""# 50; $$+ e9")" e'9"!&" %e!"+" "+&" *e)"'$# *"", !" +(,e'",& #&!'()e *e'(+,&!" ") e)"!$) "#" "#" (')"&+ %"&". Se%"9$" #&!'()e *e'(+,&!" !&$'&+" !e)" e+,'"+,& counter current !" !&%"9$+" e$9$ ion exchanger $$+ e)#",&%+" #&!'()e *e'(+,&!" $'& !"%" +(,e'",& ") ,e,$"& !e)" +e$$#". (. P)+&& P)+&& A#"++*&'$ A#"++*&'$&' &' A!")$3#'!+ A!")$3#'!+! ! P'(, P'(,e, e, *e *e$" $"" " #&!' #&!'() ()e e
*e'( *e'(+, +,&! &!""
!e) !e)" "
e) e))$ )$" "+" +"
*'(, *'(,e, e,
"$((+ "$((+,&! ,&!",& ",& "#'" "#'"$& $&( (ee e'$*" e'$*"+" +" *'(,e, *'(,e, ") ") !&*e'+ !&*e'+e" e"%+" %+" *e'" *e'""" (%e# (%e# &!$,'& I> "'e !& e'" *"!" "#$ 1G40". P'(,e, "$((+,&!",& "#'"$&( e'!&'& !"'& "#"* #&!'()e",& (+,&!",& e+,'"+,& !" !&,&%",& 2 e&% "#'"$&(e e9"!& #&!'()e *e'(+,&!" B1. R&e! R&e!%% !" !" *=e&! *=e&!e' e'e' e' e$ e$%" %"&& *'(, *'(,e, e, ,e/"'" ,e/"'" +(e +(e',& ',&"% "% $$ $$+ + *e *e$" $"" " #&!'()e *e'(+,&!" !e)" 'e!$+,& !" (+,&!",& ,&+%&, !"'& 2 e&% "#'"$&(e.
H')+4!$&' D&!"%" D&!"%" #&!'() #&!'()e" e"(' (' "#'" "#'"$& $&( ( !&%"'$ !&%"'$+" +" !"%" !"%" ,e$"# ,e$"# *e%"'$ *e%"'$ ""$ ""$
/"*$'" *e%"'$ ") !&,e$ %"'$" +e'9" !e)" "!"" +""%&, !" )", #&!'()e *"!" e+"" *"',&"% ") &))& !" ,$#$ !&""# 100 (C e'9"! e'9"!&& 'e"+,& 'e"+,& ,e")"& ,e")"& e'&+$: C16H12O2-L H2-) C16H12-OH2 -L 15
De'"9 De'"9" " #&!' #&!'() ()e e",& ",& $$ $$ "" !&" !&"" ",& ,& ,e+& ,e+&"' "' 50; 50; $$ $$+ + e& e&& &" ",& ,& 'e"+ 'e"+,& ,& ,e+$!e'. L"9$ #&!'()e",& !&9")" +(," ,e/"'" *e'&(!&+ ""$ e)$"# +""%&, ""$ !e)" e)('(% e+"" *"',&"% #&!'()e -%"9$ &!"+ !&*e)"'$#& *"!" e+"" #&!'()e ") %e&# !"'& 405 K*". -M/.+e" F(%.271G87 O*&'$&' L"'$" +e'9" ") e%"# !& *&,"#+" !"'& +""%&, !&"" e$9$ (+,&!&e' !&"" "#'"$&(% !&(+,&!",& !e)" )", (+,&)e *"!" ,$#$ 4070 (C &","" ") !&*"+"& $!"'" $$+ ee$+ "#'"$&( e,e'" #&!()e *e'(+,&!" -56 )'"%&e' ,e/"'" ,e'e"+ ,e*e'& ") !&$9$++" !&""# &&: C16H12 -OH2-L O2 -) C16H12O2-L H2O2-L R+6)7 H')+4! P)+*&'$ H&!'()e *e'(+,&!" +e$!&" !&e+,'"+,& !"'& %"'$" "#'"$&( ,e!")+" e+,'"+ e+,'"+ %"'$" %"'$" "#'" "#'"$& $&( ( !&+e !&+e"%& "%&+" +" e$9$ e$9$ #&!'() #&!'()e" e"(' (' ") ") e'=$ e'=$),& ),& ,e")"& %"'$" +e'9" Se%"9$" #&!'()e *e'+,&!" !&$'&+" !" !&+(,e'",&+" e$'$ +e$$#". Y&e%! Y&e%! #&!'()e *e',&+%$, *'(,e, ,")" &))&. L$)#"$! K)8$ Working solution solution <"#" +&&" !"'& ,$"$ ,&,e e'",$+ !"%" %"'$" (')"&+ ") e"" $&(#& $&(#&!'($ !'($&( &( e%"%$& e%"%$& 'e"+,& #&!'()e", #&!'()e",&& !" (+,&!",& (+,&!",& ,e'" e%"%$& e%"%$& ,e%$'$# ,e%$'$# %")+"# e+,'"+,& !&,e$ %"'$" +e'9". L"'$" +e'9" #"'$, ,"&% ,e/"'" +&&" e%"%$& ,e%$'$# *'(,e,. L"'$" +e'9" ,e%"%$ e'!"*" !&""'" *'(,e, ,e%"" $$' *"'&+ #"" !&)"& ,e!&+& !e)" "+e $* $$+ *e&%"," !" +e#&%")"+e#&%")". $&( $'& #&!'($&( $'& !" "#" "#" ") e'#$$)" !"%" *'(,e, e'"!" !"%" +e"!"" *"!" *"!" e*e'"$' +""' e"*& +(*(,&,& %"'$" +e'9" !&*&%&# !&*&%&# ,e#&))" ,e#&))" ""," +e%"'$" +e%"'$" !"'& *"!"" *"!"" !"%" *e%"'$ &!"+ e%e&#& ""," +e%"'$". L"'$" (')"&+ ,e%"%$ #(()e ,e&"* "+$ !e)" "*" ,(%&! ""$ ="," %&$&! +e!$" !"%" ,e&"* &&+ *"!" *'(,e, +(e',&"%. -M/. Ke" F(%.271G87. TINJAUAN PROSES 1. T"#"* H&!'()e",& U*" ,e)"' #&!'()e !e)" +"!$)" N 2 ,e")"& &e' 2 ; (% !&/"*$'
!e)" )", #&!'()e *"!" "%&'" 'e//%e !" !&"",& 9$%"# N 2 5; (%. U*" ",$+ +e 'e"+(' #&!'()e",& *"!" ,$#$ 40 ⁰C !" e+"" 4 ". U*" /"&' ") e'$*" working solution ") e'!&'& !"'& 2e&% "#'"$&( ") !&%"'$+" !"%" eee !&'e"+,&+" !"%" 'e"+(' #&!'()e",& ") e'$*" 'e"+(' !e)" +""%&, *"%"!&$. Re"+,& ") e'9"!& "!"%"# ,e")"& e'&+$ : C16H12O2-L H2-) C16H12-OH2 -L 2. T"#"* O+,&!",& 16
H",&% H",&% 'e"+ 'e"+,& ,& ") ") e'$ e'$*" *" e' e'"# "#&! &!'( '(" "# #'" '"$& $&( (e e -C16H12-OH2 +e$ +e$!& !&" " !&'e"+,&+" !e)" O 2 !& !"%" 'e"+(' (+,&!",& *"!" e+"" 4 " !" ,$#$ 40 ⁰
C. Re"+,& ") e'9"!& "!"%"# ,e")"& e'&+$ : C16H12 -OH2-L O2 -) C16H12O2-L H2O2-L . T"#"* E+,'"+,& H&!'()e *e'(+,&!" ") ",&# e'/"*$' ('+&) ,(%$&( +e$!&" !&*&,"#+" !&e"'" e+,'"+,&. 9. T"#"* D&,&%",& H&!'()e *e'(+,&!" ") ",&# e'/"*$' "&' !&$'&+" !"%" e"'" !&,&%",& $$+ e!"*"+" +e$'&" ") !&&)&+".
Tabel 3.1 erbandingan Tiga (ara )a*a$ roses Unt&! e$b&atan Hidrogen ero!sida Tinjauan
Ke!utuhan "ahan "aku
Katalis
Proses Autooksidasi
Proses Autooksidasi
Alkohol Sekunder
Anthrauinon
2-ro+anol )&da% dida+at
2-,l #nt%ra&inone dii$+or dari (ina
Tida! $e$erl&!an !atalis
)engg&na!an !atalis
!%&s&s
alladi&$
Kondisi
S&%& /T
70 - 160 (
40 - 70 (
#$erasi
Te!anan /at$
10 - 20 at$
$a!s 2 at$ ea!tor Hidrogenasi
%ea&tor
ea!tor !sidasi ea!tor !sidasi
%esiden Ti'e
60 - 120 $enit
30 - 60 $enit
Hasil Sa'$ing
17
)asala% +enanganan
,!stra! ,!stra! lar&tan
Kondisi %eaksi
+rod&! sa$+ing /#seton ea! ea!si si berl berlan angs gs&n &ng g la$ba la$batt
ant%ra&inon di!e$bali!an di!e$bali!an ea!s ea!sii berla berlang ngs& s&ng ng la$b la$bat at
Konersi
90
95
Siat %eaksi
"rreersible
"rreersible
18
G$,($) .1 D'$4)$, A') P)+&& A#"++*&'$&' $*++ &*#!)
G$,($) .2 D'$4)$, A') P)+&& A#"++*&'$&' A!")$3#'!+!
19
PEMILIHAN PROSES
&& !&*&%&# *'(,e, *e$"" !e)" *'(,e, "$((+,&!",& "#'"$&(. P'(,e, && !&*&%&# +"'e" e&%&+& e'")"& +e$$)" ,e")"& e'&+$: 1. K(Fe' K(Fe',& ,& ") ") !&#",&% !&#",&%+" +" %e&# %e&# &) &))& )& "&$ "&$ G5; G5; 2. Te+"" e+"" !" ,$#$ %e&# +e/&% !&"! !&"!&) &) *'(,e, *'(,e, %"& %"& 3. Re,&!e Re,&!e &e &e 'e%" 'e%"&= &= %e& %e&# # /e*" /e*" 4. P'(, P'(,e, e, ") ") *"%& *"%&) ) " ""+ "+ !&)$ !&)$" "+" +" !"%" !"%" &!$ &!$, ,'& '& ,e#& ,e#&) ))" )" e$ e$!" !"#+ #+" " *e/"'&" 'e=e'e,& 5. K(! K(!&, &,&& (*e'" (*e'",& ,& ") ") e! e!e+ e+" "&& %&) %&)+$ +$) )" " ,e#& ,e#&)) ))"" #e" #e" ee' ee')& )&.. P'(, P'(,e, e, #&!'()e",& "#'"$&( !"*" !&%"+$+" !e)" e+"" 2 " !" +&,"'" ,$#$ 4070 C. 6. R" "e'&"% "e'&"% "F"&%" "F"&%"&%& &%& ") ") "&+. U$+ U$+ *e)(* *e)(*e'", e'",&" &" *"'&+ *"'&+ !& I!(e I!(e,&" ,&" #"" !&*e'%$+" &*(' "#'"$&( ,e")"& "#" "+$.
20
TUGAS 9
9. 1
SPES SPESIF IFIK IKAS ASII PER PERAL ALA ATAN PROS PROSES ES 21
9.1.1 9.1.1
9.1. 9.1.2 2
T$!4*' $!4*' P!7',% P!7',%$! $! 2 E"7 E"7 A!")$3# A!")$3#'!+! '!+! +%%) +%%) $),& : Se")"& e*" *e"*$) 2 e#% "#'"$&(e T&*e : T") T")+& +& ,&%& ,&%&!e !e'' !e)" !e)" !","' !","' e'e e'e$+ $+ /(&/" /(&/"%% T$!4* $!4*'' P!7' P!7',% ,%$! $! B!: B!:! ! $),& $),& : Me&*" Me&*"
e'e$+ +e'$/$ -conical -conical 9.1. 9.1. T$!4*' $!4*' P!7', P!7',%$! %$! H') H')+4 +4! ! $),& $),& : Me&*" Me&*" #&!'()e #&!'()e =",e =",e /"&' T&*e : Sperical tank 9.1.9 M';) $),& : Me/"*$' 2 e#% "#'"$&(e !e)" !e)" ee" T&*e &*e : T" T")+ )+&& e'* e'*e e)" )"! !$+ 9.1.5 9.1.5 R$*"+ R$*"+)) H')+ H')+4! 4!$&' $&' $),& $),& : Me'e"+, Me'e"+,&+" &+" ('+& ('+&) ) ,(%$& ,(%$&( ( ") ") e)" e)"!$ !$) ) 2 e&% e&% A#' A#'"$ "$&( &(e e !e)" H2 T&*e : ixed Bed Reactor 9.1. 9.1.< < R$* R$*"+ "+)) O O*& *&' '$& $&'' $),& : Me'e"+,&+" H&!'((&(e H&!'((&(e !"%" ('+&) ('+&) ,(%$&( !e)" O2 !"%" $!"'" T&*e : Packed bed Reactor 9.1. 9.1.= = M!$ M!$)$ )$ E*& E*&") ")$* $*&' &' $),& $),& : Mee' Mee'"* "* H2O2 ") e'!"*" *"!" W('+&) S(%$&( !"'& 'e"+(' O+,&!",& !e)" "&' *'(,e,. T&*e : Packed bed Ekstraktor 9.1. 9.1.> > D*$ D*$!" !") ) $),& $),& : Me&,"#+" Me&,"#+" ('+&) ,(%$&( ,(%$&( ,e")"& ,e")"& ='"+,& '&)" !" H 2O2 ,e")"& ='"+,& e'" T&*e &*e : T" T")+ )+&& ,&%& ,&%&! !e' e' #(' #('&, &,( (" "%% 9.1. 9.1.? ? T$!4* $!4*'' P!7' P!7',% ,%$! $! H2O2 $),& $),& : Me&* Me&*" " H2O2 ,e%"" 7 #"'& T&*e &*e : T" T")+ )+&& ,&%& ,&%&!e !e'' e)"+ e)"+ !e !e)" )" "%", "%", !"" !""'' - flat flat bottom bottom !" ")&" "", e'e$+ +e'$/$ 9.1.10 9.1.10 M!$)$ M!$)$ D'&"'$&' D'&"'$&' $),& $),& : Me!"*" Me!"*"+" +" H2O2 70; e'" !"'& H 2O2 30; e'" ") +e%$"' !"'& ""'" e+,'"+,& T&*e &*e : Me" Me"'" '" D&, D&,& &%" %",& ,& !e !e)" )" *%" *%"e e 9.1.11 9.1.11 A*#,#$"+ A*#,#$"+)) $),& $),& : Pe"*$) Pe"*$) #",&% "", e"'" e"'" !&,&%",& !&,&%",& ") e'$*" H2O T&*e &*e : T" T")+ )+&& ,&%& ,&%&! !e' e' #(' #('&, &,( (" "%% 9.1.12 B+@) $),& $),& : Me"&++" Me"&++" e+"" e+"" $!"'" $!"'" !"'& 1 " e9"!& e9"!& 4 " T&*e : Centrifugal single stage 9.1.1 B" C+!67+) $),& : Me)")+$ *"!"" 2e#% "#'"$&(e !"'& #(**e' +e mixer 9.1.19 E;%$!) $),& : Me$'$+" e+"" $*" #&!'()e !"'& !"'& 10 " e9"!& e9"!& 4 " T&*e : Centrifugal single stage 9.1.15 K+!!&+) 22
$),& : Me)e$+" Me)e$+" $"* ") ") +e%$"' !"'& *$/"+ *$/"+ !&,&%",& T&*e : Shell & Tube Condenser 9.1.1< 9.1.1< S%$)$"+ S%$)$"+)) $),& $),& : e&,"#+ e&,"#+" " H2 ") &!"+ e'e"+,& !"'& #&!'()e"(' T&*e : Twophase separator hori!ontal
23
A%""%" *'(,e, : 9.1.1 T$!4*' $!4*' P!7',% P!7',%$! $! 2 E"7 E"7 A!")$3# A!")$3#'!+! '!+! +%%) +%%)
9.1.2
T$!4*' P!7',%$! B!:!
9.1.
T$!4*'
9.1.9
M&?e'
9.1.5
P!7',%$! H')+4!
R$*"+) H')+4!$&'
24
9.1.<
Re"+(' O+,&!",&
9.1.=
Me"'"
De+"e'
9.1.>
4.1.G
9.1.?
E+,'"+,&
T")+& Pe&*" H2O2
)enara islasi
25
4.1.16 Se+arator
26
