Tabla de contenido Pag. 1. RESUMEN. RESUMEN..... ......... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ......... ......... .......... .......... .......... .......... .............. ............. ....2 2 2. INTRODUC INTRODUCCION. CION...... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ......... ......... .......... .......... .......... ............ ......... 3 3. PRINCIPIOS PRINCIPIOS TEORICOS. TEORICOS...... .......... .......... .......... .......... .......... .......... .......... .......... ............ ................. ..................... ...................4 ........4 3.1
VELOCID VELOCIDAD AD DE DE REACC REACCIÓN.. IÓN....... ......... ......... .......... .......... .......... .......... .......... .......... .......... ............. .................. ............ 4
3.2
TEORÍA TEORÍA DE COLISIONE COLISIONES.... S......... ......... ......... .......... .......... .......... .......... .......... .......... ......... ......... .............. .................4 ........4
3.3
FACTORES ACTORES QUE AFECT AFECTAN A LA VELO VELOCIDA CIDAD D DE UNA REACCIÓN REACCIÓN...... ........... ........5 ...5
3.4
ORDEN ORDEN DE REACCIÓN REACCIÓN..... ......... ......... .......... .......... .......... .......... .......... .......... .......... .......... ......... ......... .............. ..............6 .....6
3.5
REACCION REACCIONES ES DE PRIMER PRIMER ORDEN.... ORDEN......... .......... .......... .......... .......... .......... .......... .......... ............... ................7 ......7
4. DETALLE DETALLES S EXPERIME EXPERIMENT NTALES ALES.... ......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ........... ................ ............. ...8 8 4.1.
REACTIVOS REACTIVOS UTILIZADOS....................... UTILIZADOS........................................... ........................................ ........................... ....... 8
4.2.
MATERIALES MATERIALES EQUIPOS UTILIZADOS........................... UTILIZADOS................................................ ....................... ..8 8
4.3.
PROCEDIMIENTO PROCEDIMIENTO EXPERIMENTAL.................... EXPERIMENTAL.............................................. .................................... .......... 8
5. TA!LAS DE DATOS DATOS RESUL RESULT TADOS EXPERIMEN EXPERIMENT TALES..... ALES.......... ................ ..................... .............." ...." 5.1
TA!LAS DE DATOS DATOS EXPERIME EXPERIMENT NTALES ALES..... ......... ......... .......... .......... ............... .................... ..................." ........."
5.2
TA!LA DE DATOS DATOS TEORICO TEORICOS.... S......... .......... .......... .......... .......... .......... .......... .......... .......... ............. ................1# ........1#
5.3
TA!LAS DE RESUL RESULT TADOS PORCENT PORCENTA$E A$E DE DE ERROR ERROR............ ....................... .................1# ......1#
6. AN%LISIS AN%LISIS DISCUSIÓN DISCUSIÓN DE RESUL RESULT TADOS...... ADOS........... .......... .......... .......... .......... ......... ......... .......... .............12 ........12 7. CONCLUSIO CONCLUSIONES NES RECOMENDA RECOMENDACIONE CIONES.... S......... .......... .......... .......... ............... .................... ....................12 ..........12 8. !I!LIO&R !I!LIO&RAFIA AFIA..... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ............... .................... ..................... ............. ..13 13 ". ANEXOS.. ANEXOS....... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ............. ................... ..................... ................ ......14 14 ".1
CUESTION CUESTIONARI ARIO..... O.......... .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ............. ................... .................14 ......14
".2
&RAFIC &RAFICOS... OS........ .......... .......... .......... .......... .......... .......... .......... .......... .......... .......... ......... ......... .......... ............. ................... ............. ..15 15
1
1. RESUMEN E' ()*+,-( /+ +0, ,- + ' (),+-9 /+ /,(0 -:,-(0 ' +-9 ,';,- /+ -<+ (/+ = /+,+<--9 /+ ' (0,,+ /+ +'(-// /+ +-9. L0 (/--(+0 /+ ')(,(-( '0 '+0 0+ ,)*( +( /+ 21>C /+ ,+<+,? +0-9 /+ 756<<@ = B<+// +',- /+ "2. E ' ++-+- 0+ ,)*9 ,+<+, /+ 4#>C? <,++ +0, ,+<+, 0+ ,-'-9 ,+<(0,,(? 0+ 09 +' +,,( /+ +,-'( (<( +,,+ = +' @C' (<( ,'-/(? 0+ 09 5
2
2. INTRODUCCION L -:,- ;<- +0 + /+ ' 0-(;<- + 0+ + /+' +0,/-( /+ ' -/+ /+ +-9? 9<( <)- ' -/+ /+ +-9 )*( (/--(+0 -)'+0 = : ++,(0 <('+'+0 0+ ++,K <+/-,+ ' +-9 ++' D-0-9? -+- /+ 0+-+0? ,'-0-0. L -:,- ;<- +0 +0,/-( <+,+ +<;-( = ++-<+,' +' + ;<- + +<-,+ -/ + '0 <+-0 /+ +-9 0+ ((+ (<( /-<- ;<-. U /+ '0 ,,0 '--(+0 0+ ++, + +' <+/-( <)-+,+? +' <(/( + + '0 0 ,'+0 /-++ 0 (<(0--9 +0, (,('/( ( ---(0 ,+<(/-<-(0 /+' +-'-)-( ;<-( = /+ ' -:,-. A' )( /+' ,-+<(? + 0 ,=+,(- 0),++? +' (,(' '( +*++ + ' -:,- ;<-. E <B(0 ,)*(0 +'-(/(0 ( ' '-// /+ '0 0 ,'+0? ( 0+ (0-/+ +' +' + *+ +' ,( ,-+<( + +' (+0( /+ /-0('-9 /+ '(0 <-+'+0? '-<-,/(0+ 0('( +0,/- /-B '-// + (/--(+0 /+ +-'-)-(. S- +<)(? +' ,-+<( /+ +-9 *,( ' ,+<+, = +' (,+-/( /+ CO2? 0( '(0 ,+0 --'+0 +'+<+,(0 +/+ ,+<- +' (+0( /+ /-0--9 /+ ' (<(0--9 ;<- ,:0 /+ '0 /-0,-,0 0+0 +0+,+0 0? ';-/( = 09'-/(.
3
3. PRINCIPIOS TEORICOS 3.1 VELOCIDAD DE REACCIN. S+ /+ ++0 (<( ' +'(-// + ' + 0+ ++,K <)-( + ' (+,-9 //, ( + '-+ (-+// /-+,<+,+ ((-(' ' (+,-9? (<( ' +'(-// /+ <)-( /+ ' +0-9 -'? //, +-9 +,+ 0+0. L (+,-9 /+ +,-( 0+ /+,+<-? '0 ++0? ( <+/-( /+ ' (+,-9 /+ ( /+ '(0 (,(0 +,-(0 ( (/,(0 + 0+ +/+ /+,+<- ++-<+,'<+,+ ( <0 -'-// = '-/( ' +'-9 +0,+-(<+,- (+0(/-+,+? 0; + ' +-9 A 2! A!2 −d ( A ) −d ( B ) d ( A B2 ) = = dt
2dt
dt
L(0 0;<)('(0 +,+ :,+0-0? + ++0+, '(0 (<+0,(0 ;<-(0? -/- + '0 (+,-(+0 +0, ++0+,/0 + <('+0 ( '-,(. L +'(-// /+ +-9 ( +0 (0,,+. A' ---(? /( ' (+,-9 /+ +,-(0 +0 <=(? ,<)-: +0 <=( ' ())-'-// /+ + 0+ /+ B(+0 +,+ '0 <(':'0 /+ +,-(? = ' +'(-// +0 <=(. <+/-/ + ' +-9 ? ' - /-0<-=+/( ' (+,-9 /+ '(0 +,-(0? /-0<-=+ ' ())-'-// /+ B(+0 = ( +'' ' +'(-// /+ ' +-9.
3.2 TEOR!A DE COLISIONES. L ,+(; /+ ('-0-(+0? (+0, B- 1"2# ( &-')+, N. L+-0 1875H 1"46 = (,(0 ;<-(0? < + + ( <)-( ;<-( +0 ++0-( + '0 <(':'0 /+ ' 00,- ( 00,-0 ---'+0 +,+ + (,,( <+/-,+ ('-0-9 ( B(+.
4
P+( ( ,(/(0 '(0 B(+0 0( -'+0. E' B(+ + (( ' +-9 0+ /+(<- B(+ + = /+)+ <'- +0,(0 /(0 +-0-,(0 Q+ +' B(+ +++ ' 0-+,+ ++; (<+ '(0 +'+0 +,+ '(0 ,(<(0. Q+ +' B(+ 0+ +'-+ ( ' (-+,-9 /+/ (< ' + <(':'.
L(0 B(+0 + ( <'+ +0,0 (/--(+0 =? ( ,,(? ( / ' ' +-9? 0+ /+(<- B(+0 -++0. A ++0? +' 0( /+ +,-( (/,( 0+ +'- <+/-,+ ' (<-9 /+ (<+0,( -,+<+/-( ( (<'+*( ,-/( + 0+ ,0(< (0,+-(<+,+ + '(0 (/,(0. L ene"g#a de acti$aci%n + ;<- +0 ' ++; + ++0-, 0-0,+< ,+0 /+ (/+ --- /+,+<-/( (+0(. L ++; /+ ,--9 0+'+ ,-'-0+ /+(<- ' ++; <;-< ++0- + 0+ (/ +-9 ;<- //. P + ( +-9 +,+ /(0 <(':'0? :0,0 /+)+ ('-0-( + ' (-+,-9 (+, = (0++ ,-// /+ ++; <;-<.
3.3 &ACTORES 'UE A&ECTAN A LA VELOCIDAD DE UNA REACCIN. U +-9 ;<- 0+ (/+ <+/-,+ ('-0-(+0 ++0 +,+ '0 ,;'0 /+ '(0 +,-(0? ( ,,(? +0 -' /+/- + +''0 0-,-(+0 ( ,(+0 + <+,+ +' K<+( /+ +0,0 ('-0-(+0 -<'- <=( +'(-// /+ +-9. V+<(0 '(0 /+ +0,(0 ,(+0. TEMPERATURA. A' <+, ' ,+<+,? ,<)-: '( B+ ' +'(-// ' + 0+ <++ '0 ,;'0 =? ( ,,(? <+, +' K<+( /+ ('-0-(+0 = ' -('+- /+ +0,0. E' 5
+0',/( +0 <=( +'(-// + ' +-9. S+ /-+? /+ <+ (-</? + ( / 1# >C /+ <+,( + ' ,+<+,? ' +'(-// 0+ /'-.
(RADO DE PULVERI)ACIN DE LOS REACTIVOS. S- '(0 +,-(0 +0, + +0,/( ';-/( ( 09'-/(? ' '+--9? +0 /+-? ' +/-9 ,;'0 /+ <+( ,<(? <+, +(<+<+,+ ' +'(-// /+ +-9? = + -'-, +' (,,( +,+ '(0 +,-(0 =? ( ,,(? ' ('-0-9 +,+ '0 ,;'0. NATURALE)A DE LOS REACTIVOS. D++/-+/( /+' ,-( /+ +,-( + -,++? /+,+<-/ +-9 ,+/ ++; /+ ,--9 <= ',? +,(+0 ' +'(-// /+ +-9 0+ <= '+, = 0- ' ++; /+ ,--9 +0 <= )*? +,(+0 0 +'(-// 0+ <= -/. CONCENTRACIN DE LOS REACTIVOS. S- '(0 +,-(0 +0, + /-0('-9 ( 0( 0+0 ++/(0 + +--+,+? ,( <=( 0+ 0 (+,-9? <0 ', 0+ ' +'(-// /+ ' +-9 + ' + ,--+? = +? ' B)+ <0 ,;'0 + +' <-0<( +0-(? <+, +' K<+( /+ ('-0-(+0. CATALI)ADORES. L(0 ,'-/(+0 0( 00,-0 + -'-, ' +-9 <(/-/( +' <+-0<( ( +' + 0+ /+0(''. E -K 0( +' ,'-/( (( ' +-9 ;<- ( ; 0 '( /+ +-9. L(0 ,'-/(+0 0+ /+ + ++0 ,-//+0 = 0( <= +0+;(0 +0 /+-? / ,'-/( 0-+ 0 /+,+<-/0 +-(+0. E' ,'-/( 0+ +/+ ++ ' ' /+ ' +-9? +0,( + ( +0 +,-( - ,-- + ' +-9.
3.*ORDEN DE REACCIN. L +'(-// /+ +-9 ;<- /++/+ /+ ' (+,-9 /+ '(0 +,-(0 0- +<)(? ' +'(-// +/+ /++/+ ,<)-: /+ ' (+,-9 /+ (,0 00,-0 + ( +0,: -'-/0 + ' +-9 +0,+-(<+,-. A ' +-9 + ++0 ' +'(-//? + -9 /+ ' (+,-9 /+ / /+ '0 00,-0 + +, ' +'(-// /+ +-9? 0+ '+ /+(<- '+= /+ ' +'(-// /+ +-9. C/( + ' +-9 /+ ' +'(-// /+ +-9 ++ '0 (+,-(+0 +'+/0 ' (,+-? +' (/+ /+ ' +-9? + 6
-9 /+ ( /+ '(0 +,-(0 +0 -' 0 +(+,+ + ' '+= /+ ' +'(-// /+ +-9. E +' 0( /+ +-9 ( '(0 +,-(0 A? !? C? ' +'(-// /+ ' +-9 (/ ,++ '-+ /+ '0 0--+,+0 (<0 P-<+ (/+ ( +0+,( A
−d ( A ) dt
−d ( A )
S+/( (/+ ( +0+,( A
T++ (/+ ( +0+,( A
O/+ +( ( +0+,( A
=kxA
dt
−d ( A ) dt
−d ( A ) dt
2
=kx ( A ) ( B)
=kx ( A )
=kx ( A )
3
0
S- ' +-9 +0 /+ -<+ (/+ ( +0+,( A = /+ -<+ (/+ ( +0+,( !? 0+ /-+ + + ,(,'? +0 /+ 0+/( (/+. L '+= /+ ' +'(-// /+ +-9 K-<+,+ 0+ +/+ /+,+<- '-/( +0,/-(0 -:,-(0 = ( +/+ /+/-0+ /+ ' +-9 ;<- )'+/.
3.+ REACCIONES DE PRIMER ORDEN. L +'(-// /+ +-9 /+ -<+ (/+ 0+ ++0 (<( dc =−kc dt
D(/+ ++0+, ' (+,-9 /+ ' 00,- + +-(? = +' ,-+<(? //, +0 ' +'(-// ( ' + <)-9 ' (+,-9 /+' +,-( = +0 ' (0,,+ /+ ' +'(-// /+ +-9. L (0,,+ /+ ' +'(-// /+ +-9 + '0 +-(+0 /+ -<+ (/+ ,-++ '0 /-<+0-(+0 /+ ,H1 = +/+ ++00+ ( +' '( +;(( /+ '(0 0+/(0 ( '-+ (, -// /+ ,-+<( S- -,+<(0 ' +-9 ,+-( (),++<(0 ln c =−kt + constante
7
log c = log c 0 −
k t 2.303
P( '( ,,(? +-9 /+ -<+ (/+ 0+ (),-++ ';+ +,? /( +' '( /+ +' +,-(? 0+ ''+ ( +0+,( ' ,-+<(? ' (0,,+ /+ +'(-// /+ +-9 +/+ ''0+ <',-'-/( ' +/-+,+ /+ ' ';+ ( H2?3#3. S-,+<(0 ' +-9 ,+-( +,+ '(0 ';<-,+0 /+ (+,-9 1 + +' ,-+<( ,1 = 2 + ,-+<( ,2? ,++<(0 + k =
2.303 t 2−t 1
log
( ) c1 c
Q+ 0+ +/+ <(/- ( 2.3#3, '( # D(/+ # +0 ' (+,-9 + ---' + +' ,-+<( +(? = +0 ' (+,-9 '+( /+ ,0- +' ,-+<( ,. E0 +-/+,+ + '0 +-(+0 -) <+-(/0 + (/+ /+,+<- ' (0,,+ /+ ' +'(-// /+ +-9 + +-9 /+ -<+ (/+? 0('<+,+ +0 ++0-( /+,+<- ' +'-9 + +-0,+ +,+ '0 (+,-(+0 + /(0 ,-+<(0 /-0,-,(0.
*. DETALLES E,PERIMENTALES *.1. REACTIVOS UTILI)ADOS
A+,,( /+ +,-'( F+(','+; !-,',( /+ (,0-( S('-9 /+ @CL S('-9 /+ NO@ A /+0,-'/ @-+'(
8
*.2. MATERIALES - E'UIPOS UTILI)ADOS T+<(0,,(? (9<+,(? 2 <,+0 +'+<+=+ /+ 125<' = 3 /+ 1##<'? <, /+ 25#<'? 3 -+,0 ('<:,-0 /+ 5<' = /+ 5#<'? ()+, = )+,0.
*.3. PROCEDIMIENTO E,PERIMENTAL S+ ,-'-9 +' ,+<(0,,( ,+<+, /+ 4#>C? '+( 0+ <-/-9 2 ++0 ( -+, ('<:,- /+ 5#
HCl ≅ 1 N
? 0+ ('(9 +
<, /+ 25#
HCl
0+ +<+9 ,(< +'
,-+<(. L+( /+ + 0( '(0 5 <-,(0? 0+ +9 <, ( B+'/ = 0+ +,*( 5
+. TALAS DE DATOS - RESULTADOS E,PERIMENTALES +.1 TALAS DE DATOS E,PERIMENTALES A/ TALA N01 CONDICIONES DE LAORATORIO
"
CONDICIONES DE LAORATORIO P577g/ 756 <<@ T50C/ 21>C 9R "2
/ TALA N02 ESTANDARI)ACIN DEL NaO. 4 5g/
V 57l/ #.65
#.#515
NaOga6tado
N NaO 5N/ #.388#
C/ TALA N03 ESTANDARI)ACIN DEL CL 8.1N. VCL 57l/
V 57l/ 12.6
5
NaOga6tado
N CL 5N/ #."778
D/ TALA N0* VOLUMEN (ASTADO DE NaO PARA CADA TIEMPO EN + 7l DE ACIDO TOTAL. t 57in/
t "eal
t "eal 57in/
5 1# 15 2# 3# 5# 7# "# 12#
5 17 1# 53 15 #6 2# 45 3# 34 5# 33 7# #1 "# 22 12# #7
5.28 1#.88 15.1# 2#.75 3#.57 5#.55 7#.#2 "#.37 12#.12
V NaO 57l/ 12." 13.2 14.# 14.8 15.1 15.5 15.8 16.1 16.4
ga6tado
+.2 TALA DE DATOS TEORICOS
1#
E/ TALA N0+ DENSIDAD DEL ACETATO COE&ICIENTE DE E,PANSIN C:ICA.
DE
ETILO
-
< 50C=1/
20 °C
ρ A . ETILO
5g;7l/ #."##3
1.38"1# H3
&/ TALA N0> PESO MOLECULAR 5ESTER/? CONSTANTE DE VELOCIDAD - TIEMPO DE VIDA MEDIA. ´ M
5g;7ol/ 88.1
4 57in=1/
t1;257in/
".781# H3
7#.87
+.3 TALAS DE RESULTADOS - PORCENTA@E DE ERROR. (/ TALA N0 DENSIDAD DEL BSTER A LA TEMPERATURA TRAA@ADA. T 50C/
ρ A . ETILO
5g;7l/ #.876#
4#
/ TALA N0 CONCENTRACIN DEL CL CORRE(IDA POR DILUCIN. VCL REAL 57l/ 1##
V CL 57l/ "5
RESTANTE
N CL 5N/ #."28"
I/ TALA N0 CONCENTRACIN ORI(INAL DEL BSTER EN 5MOL;L/. ESTER 5g/
V
4.38
#.1
SOLUCION
5L/
FESTERGO 57ol;L/ #.4"72 11
12
@/ TALA N018 CONCENTRACION DE Ac PRODUCIDO CONCENTRACION DEL ESTER 'UE REACCIONA. t 57in/ 5.28 1#.88 15.1# 2#.75 3#.57 5#.55 7#.#2 "#.37 12#.12
NACIDO 5N/ 1.##1# 1.#243 1.#864 1.1485 1.1718 1.2#28 1.2261 1.24"4 1.2726
TOTAL
NCL 5N/ #."28" #."28" #."28" #."28" #."28" #."28" #."28" #."28" #."28"
NAc PRODUCIDO 5N/ #.#721 #.#"54 #.1575 #.21"6 #.242" #.273" #.2"72 #.32#5 #.3437
N ESTER 5N/ 1.442 1."#8 3.15# 4.3"2 4.858 5.478 5."44 6.41# 6.874
R,NA
4/ TALA N011 CONCENTRACIN DEL ESTER SIN REACCIONAR. t "eal 57in/
FESTERGO
FAcGH"odcido
FESTERG SIN R,NAR
5.28 1#.88 15.1# 2#.75 3#.57 5#.55 7#.#2 "#.37 12#.12
#.4"72 #.4"72 #.4"72 #.4"72 #.4"72 #.4"72 #.4"72 #.4"72 #.4"72
#.#721 #.#"54 #.1575 #.21"6 #.242" #.273" #.2"72 #.32#5 #.3437
#.4251 #.4#18 #.33"7 #.2776 #.2543 #.2233 #.2### #.1767 #.1535
L/ TALA N012 DATOS PARA (RA&ICAR LogFESTERG S.R VS T 57in/. LO( FESTERG H#.3715 H#.3"6# H#.468" H#.5566 H#.5"47 H#.6511 H#.6""# H#.7528
t 57in/ 5.28 1#.88 15.1# 2#.75 3#.57 5#.55 7#.#2 "#.37
H#.813"
12#.12
M/TALA N013 CONSTANTE DE VELOCIDAD - TIEMPO DE VIDA MEDIA. TEORICO 457in=1/ t1;257in/
".781#H3 7#.87
E,PERIMENT ERROR 59/ AL 8.461# H3 H13.5# 81."3 15.61
>. ANJLISIS - DISCUSIN DE RESULTADOS E ' 0+ /( ()0+ + ' +'(-// /+ +-9 /++/+ K-<+,+ /+ +,-(. E '-+ +-9 /+ -<+ (/+ /+' ,-( AW!? B) ;/ /+ ' (+,-9 /+' +,-(? (<( 0+ +/+ + + +' (? +0,( + +' (/,( 0+ (< <+/-/ + /+0++ +' +,-(? 0+ /+)+; (/- (+0(/-+,+ -+<+,( + ' (+,-9 /+' (/,(. A ,+ 0+ /( ()0+ + + ' ? B= ,(0 + 0'+? '0 '+0 /-+( B)+ 0-/( ((/0 ( <' '+, + '( + 0+ +++ -,+'(0 /+ ,-+<(? (-/(0 /+0/+ +' <(<+,( + + 0+ + ' <-,/ /+' ('<+ (+-+,+ /+ ' -+, ( + +' B+B( /+ ( B)+ B(<(+-/( )-+ ' 0('-9 ' <(<+,( /+ + +' +,,( /+ +,-'( 0()+ +' -/( '(B;/-(. O,( <(,-( /( B)+ 0-/( + ' <(<+,( /+ ''+ +' <, B+'/( ,-,' /( B)+ <+,/( 0 ,+<+,? ' ' B-( + ' +-+- /+' B+'/ (<( -B-)-/(? /-0<-=.
. CONCLUSIONES - RECOMENDACIONES
S+ +/+ +- + ' (0,,+ +0 ,( /+ ((-('-// + 0+ /+(<- (0,,+ /+ +'(-// ( +'(-// /+ +-9 ' -// /+ (+,-9. E '0 +-(+0 /+ 1 Y (/+? ' +'(-// /++/+ 0('<+,+ /+ ' -<+ (,+- /+ ' (+,-9 /+ 0-<'+ 00,- +-(,+. L + 0+ (),( +0 /+ ,+/+- '-+' = /+ +/-+,+ +,- ( '( ' 0+ /-+ + +0 /+ (/+ 1. E' @C' -(( (<( ,'-/( /+ ' +-9 = +' B+'/ (<( -B-)-/( /+ ' +-9. E0 <= -<(,,+ <,++ +' ,+<(0,,( ' ,+<+, /+ ,)*( + 0+ *9 ( ,---9? = + --9 /+ ,+<+, -- + ' +'(-// /+ +-9 +0, ,+,(0[.
. ILIO(RA&IA PA(INAS E
5$i6itado B,,<(.'0.+/@(T(0('+,0+,B='+,,+.B,< 8;11;1>/ B,,-+-0+)B-''+,(.)'(0(,.+2#11#5+'(-//H/+H+-(H 5$i6itado 8;11;1>/ =H+-'-)-(.B,<'
LIROS
MARON S? LANDÓ $? GFISICOQUÍMICA FUNDAMENTALJ 1. E/--9? +/-,. L-<0? M:-(? 1"78. P-0 (0',/0 555 \ 563? 57#. &ASTON PONS MUZZO GFISICOQUIMICAJ 1. E/--9? +/-,. U-+0(? 1"6". P-0 (0',/0 515H518.
. ANE,OS .1 CUESTIONARIO A. KCle6 6on algna6 de la6 tcnica6 6ada6 en el e6tdio de la cintica de "eacci%n EHlie Ho" lo 7eno6 do6 de ello6. &OTOLISIS DE DESTELLO. E0,+ <:,(/( (0-0,+ + '- '0( /+ ' /+ -,+0-// /-0('-9 + +/+ ,++ ( /(0 +0+-+0. L(0 '0(0 ++/(0 ( '<0 /+ /+0,+''( 0( /+ (0 ,(0 <-(0+/(0 = ( +' /+-<-+,( /+ '(0 '0++0 /+ (,+-? +0 ,-)'+ (),++ /-(+0 /+ (0 ,(0 -(0+/(0. SALTO DE TEMPERATURA. E0,+ +0 +' <:,(/( <0 +<'+/( +0,( + ' <=(; /+ '0 +-(+0 ,-++ '(+0 /+ '(+0 /+ ]@ /-++,+0 +( /+ <+ + 0+ +/+ +0+ + ' (0,,+ /+ +-'-)-( <)-+ ( ' ,+<+, 0; ( ' ,+<+, 0; E' <:,(/( (0-0,+ '+, ),<+,+ /+0/( -,( ,:0 /+ ' /-0('-9. . De6c"iba Q H"oHonga n 7todo eHe"i7ental Ha"a n
6i6te7a o7%logo e aHlie lo6 obeti$o6 de la H"ctica. M:,(/( +-<,-( ('(-<:,-( /+ '-0-0 -:,-( ' /+,+<--9 /+ +,-- + 0+( = (- /+0(''/( ( +,-(0 /+ (/-9 -(' 0 '--9 + '(0 ')(,(-(0 ';-(0. S+ '- /+,+<--(+0 -:,-0
,- /+ ' <+/--9 +0+,((,(<:,- '(-,/ /+ (/ /+ 55# < /+ ' -(+-<- (</. S+ +'-9 ' '-/-9 +'/( '(0 <+,(0 +0+--//? '-+'-//? +-0-9? +,-,/? ';<-,+ /+ /+,+-9 = /+ ,--9? <'-+/( ( '0 +'-(+0 -+,+0 + C). C. Adnte Q co7ente b"e$e7ente na Hblicaci%n cient#ca de lo6 lti7o6 + ao6 en "eWe"encia al e6tdio "ealiXado. L 0--+,+ )'--9 0+ +, + +' +0,/-( -:,-( /+ ' (-/-9 /+' (<'+*( B-+( II (+,('-? /(/+ B--+( '+, /+ ' )0()- + 0+ (/*( ( ' ,0(<-9 /+' -( +(0( + 0 (< :-? ' ' + (<'+*( /+ ('( (*( = ,:0 /+ ' 0+ '(9 ()0+ + + +-9 /+ 0+/( -<+ (/+. T<)-: 0+ +0+-9 + '0 +'(-//+0 /+ (-/-9 +( <+(+0 /( 0+ '+ -((( ' <+/-( +,,( /+ ')+/(0. E0,(0 ,-(0 /+ )'--9 0( <= -,++0,+0 = + (0 /+, (( <0 ' +0,/-( /+ ' -:,- ;<-? +( ( -+' <=(? /+<0 0+ /( +-)- + 0 +0,/-(? '-( +' M:,(/( /+ '(0 E0,/(0 E0,-(-(0 = '0 +-(+0 /+ V, @(^ + +( /+ 0< -<(,- 0 ++-+-.
.2 (RA&ICOS
