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Mecanismos de Reaccion

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2.3 Reacciones múltiples,

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Conversión.

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C A



C A0 1

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X A

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Ecuación de velocidad de primer orden Integrada.

 C   ln  A    ln 1  X A   kt  C A0  Ecuación de velocidad de segundo orden Integrada. 1

C A

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1

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 X A     kt C A0  1  X A  1

Relación molar inicial de los reactivos. M

C B 0 

C A0

Ecuación para reacciones biomoleculares biomoleculares irreversibles de segundo orden.

 C B C A0   1  X B   M  X A   C B     ln  ln  ln      1  X   M 1  X    MC   C C  A  A     A   B 0 A   C A0  M  1kt  C B0  C A0 kt .............................. M  1

ln 

 C B C A0   M  2 X A    ln   M 1  X    C C   C A0  M  2kt .............................. M  2 A    B 0 A 

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 X A     2kt ..........M  2  X 1  A 

Sign up to vote on this title Ecuación para reacciones trimoleculares irreversibles de tercer orden.  Useful  Not useful

2C  C C  C  A0

B 0

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 C C  2  ln  A0 B   2C A0  C B 0  kt

M

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problema

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Ecuación cinética empírica de orden n.

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1 n

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Ecuación cinética para orden cero.

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 C   ln  A   k 1  k 2 t  C A0 

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C S

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k 1 k 2

Reacciones homogéneas catalizadas.

 C   ln  A    ln 1  X A   k 1  k 2 C C t  k observadat  C A0  Reacciones autocatalíticas.

 C A0 C 0 

ln 

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 Useful  C R   C   C A   R 0   ln    C kt  C  C kt

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Variación de la concentración de R.

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 C A

C R

 k t  e  k t  e  k   k  k k  k    1

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Variación de la concentración de S. C S

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Concentración máxima de R. C R , max C A0

 k    1   k 2 

k 2

 k 2  k 1 


Ecuaciones para reacciones reversibles de primer orden. k C

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C Re C Ae

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 X Ae  1  X Ae M

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Ecuación para reacciones reversibles de segundo orden.

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Ecuaciones para sistemas de volumen variable

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A

V

V XA1

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Cuando...... A  0 V F A0 

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Reactores de flujo pistón. Cuando...... A V

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0 X A

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dX A

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1

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C A

dC A

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