Ejercicios Fogler Catálisis 10-4 a 10-6

INGENIERÍA DE LAS REACCIONES 2 TRABAJOS DE INVESTIGACIÓN FORMATIVA C"%%e%": Nive&: Asign"'(%": In'eg%"n'es: Doen'e:

Código: IQ8048 Revisión: 01 Fe!": 2016/11/25 #"g: $ de 10

INGENIERÍA QUÍMICA NOVENO SEMESTRE INGENIERÍA DE LAS REACCIONES 2 CABASCANGO WILLIAM ING !UGO SOLÍS

Te)": E"e#$%$%&' de C()*+%'%' ,&+e# C(.)+& 10 EJERCICIO #$*+, E+ (+$&&+ )-)+%$& 3ATB e'  e"&#(d&# %.&#)()e de+ &$)(("e 7e 'e e.+e( .(#( #ee.+((# (d%)%9&' de .+&& e +( ('&+%( E+ (+$&&+ ))+%$& 'e .#&d"& .&# %d#()($%: e ;('e +7%d( 3W de %'&)e& 3+ '&#e $()( $( )(+% +%( (d& d&## A Ae e#+ #+<' <'))-15 15 E+ '%')e( &#(+e)e e'  ( ( e e$ $+( +( +)%;*'%$( de %d#&$(# %d#&$(##&= #&= (( < $()(+%(d&#e' ':+%d&' S% e(#&= $& e+ '& de $&d%'&+9e)e' & e>$e'& de ATB 'e +&#( ( %'$%%+%d(d #(&(+e Se $#ee 7e e+ e$(%'& de #e($$%: e' e+ '%%e)e? I + S↔I·S W + S↔W·S

w· S + IS ↔ TBA . S + S TBA·S↔TBA + S

De#%9e ( +e< de 9e+&$%d(d '.&%ed&? ( 7e +( #e($$%: '.e#@$%(+ e' +%%)()e de +( 9e+&$%d(d  7e +( (d'&#$%: de %'&)e& e' e+ .('& +%%)()e $ 7e +( #e($$%: '%e ( $% $%)%$( de E+e<-R%de(+ I·S + W ↔TB ↔TBA ·S

< 7e +( #e($$%: '.e#@$%(+ e' +%%)()e d E+ %'&)e& 3I < e+ (( 3W 'e (d'&#e e '%)%&' d%')%)&' I + S 1 ↔ I · S1 W + S2 ↔W·S2

EL ATB & 'e e$e)#( '&#e +( '.e#@$%e= e )()& 7e +( #e($$%: '.e#@$%(+ e' ( +%%)()e de +( 9e+&$%d(d e Q ee#(+%($%&e' .&d#( ($e# (+ $&.(#(# +(' +e
Código: IQ8048 Revisión: 01 Fe!": 2016/11/25 #"g: 2 de 10

INGENIERÍA DE LAS REACCIONES 2 TRABAJOS DE INVESTIGACIÓN FORMATIVA

[

r ADI = k AI C I C V −

I + S ↔ I · S

C I ∗S K I

]

[

r ADW = k AW C W C V −

W + S↔W ·S

[

W · S + I · S ↔TBA · S + S

r S =k S C W ∗S C I ∗S−

TBA·S↔TBA + S

r D= K D C TBA∗S−

[

C W ∗S K W

C V C TBA∗S K S

C TBA C V K D

]

]

]

Se ig("& " e%o de-endiendo .(e e'"-" se onside%e &i)i'"n'e ( r ADI k A

=0

C I ∗S= K I C I C V C W ∗S = K W P W C V r ADW k W r D k D

=0

=0

C TBA ∗S=

C TBA C V K D

= K TBA C TBA C V ,

I = K TBA K D

L( de de'&#$%: '%e.#e e' +( de+ .#&d$)& e e')e $('& e' +( de TBA 2

r S =k S K I K W C V

[

C I C W −

C TBA K P

]

K S K I K W K P = K TBA

C T = C V + C I ∗S + C W ∗S + C TBA∗S =C V ( 1+ K I C I + K W C W + K TBA C TBA )

2

[

k S K I K W C T C I C W − , −r I ,=−r W = r S=

C TBA K P

]

( 1 + K I C I + K W C W + K TBA C TBA )2

 L" de "dso%ión de& iso/('eno es e& -"so &i)i'"n'e



[

r ADI = k AI C I −

]

C TBA

( ) r ADW

C C W K P V =

C TBA ∗S=C TBA C V K TBA

( )

C I ∗S=

rS k S

F0

[

r ADI = k AI C I −

C TBA C W K P

] [

, I

−r F

[

C V C TBA∗S

C I ∗S=

C W ∗S K S

K P F

C V

k AI C T C I −

F0=

k AW

C W ∗S =C W C V K W ,

C TBA C W K P

1+ C W K W + K TBA C TBA +

( ) r D

k D

F0

C TBA K TBA C V C W K W K S

K W K S K TBA

] C TBA

C W K P

]

$

[

r S =k S C W C I ∗S−

C TBA∗S K S

]

C I ∗S= K I C I C V C TBA ∗S= K TBA C TBA C V

−r I , F

[

k C W C I −

C TBA K H

]

F k S K I C I

1 + K I C I + K TBA C TBA

d 2 +¿ S1

W · S2 + I ∗ S 2 ↔TBA + S ¿

[

r S =k S C W ∗S 2 C I ∗S 1 − C T 1 =C V 1 + C I ∗S 1

C TBA C V 1 C V 2 K S

]

K I K S K H = K TBA


Código: IQ8048 Revisión: 01 Fe!": 2016/11/25 #"g: , de 10

C T 2 =C V 2 + C W ∗S 2 C I ∗S 1= K I C I C V 1 ,

1 + K I C I

C T 1 =C V 1 ¿

C W ∗S 2= K W C W C V 2 ,

r I F

[

k C I C W −

C T 2 = C V 2 ( 1+ K W C W ) C TBA K S

]

F k S K W K I C T 1 C T 2

( 1 + K I C I )( 1 + K W C W ) EJERCICIO #$*+1 L( +e< de 9e+&$%d(d .(#( %d#&e($%: 3! de e)%+e& 3E .(#( ;&#(# e)(& 3A '&#e $()(+%(d&# de $&(+)&-&+%de& [Collection Czech. Chem. Commun., 51=2H60 3188J e'?

−r ' E=

k P E P H 1 + K E P E

( S%e#(  e$(%'& <  .('& +%%)()e de +( 9e+&$%d(d $&#e)e $& +( +e< de 9e+&$%d(d  C*+ ;e +( .(#)e *' d%;$%+ .(#( e$&)#(# e+ e$(%'& $ Se $#ee 7e +( ;&#($%: de .#&.(&+ e +( '.e#@$%e de $()(+%(d&# .#&$ede de+ '%%e)e e$(%'&?



O2K2S  2O+S C!6K OSC!5O!S C!6O!S  C!5O! K S S%e#(  .('& +%%)()e de +( 9e+&$%d(d < de#%9e ( +e< de 9e+&$%d(d ( T&(d& e $e)( +( #e($$%:? H 2+ C 2 H 4 c at C 2 H 6

⃗

H + E → A

A'%ed& ( #e($$%: de E+e< R%de(+? E . S ↔ A + S E + S ↔ E . S

C E . S= K E P E C V



[

r S =k S C E .s P H

]

C T =C V + C E . S

r ' A = k S K E C T

[

P E P H 1 + K E P E

]

 L( .(#)e *' d%;$%+ ;e ('%# e+ )%.& de #e($$%:= e d&de e .#%e# +(# 'e ('%: 7e +( #e($$%: e#( de '%)%& %$& < +e& de '%)%& d(+= e (&' $('&'= +( #e'.e')( @(+ & )e( $&$&#d($%( $& e+ e"e#$%$%& .+()e(d&= e' (' 7e= (+ #e.e)%# e+ .#&$ed%%e)&= e'$&%ed& +( #e($$%: e+e<-#%de(+ 'e &)9& ( #e'.e')( ;(9&#(+e $ (#)%ed& de+ e$(%'& .#&.e')&? O 2+ 2 S ↔ 2 O . S C 3 H 6 + O . S ↔ C 3 H 5 O H . S C 3 H 5 OH .S↔ C 3 H 5 OH + S

U)%+%(d& e9( &e$+()#(? A 2 + 2 S ↔ 2 A . S


Código: IQ8048 Revisión: 01 Fe!": 2016/11/25 #"g:  de 10

B + A . S ↔C . S C . S ↔ C+ S

−r B= r S =k 3 P B C A .S

[

2

2

r AD= k A P A C V −

r AD k A

2

C A . S K A

]

=0

C A .S = C V √ K A P A C A .S = C V √ K A P A

−r B= r S = K 3 P B C V √ K A P A

[

P C C V r C . S=k D C C .S − K D r C .S k D

]

= k D [ C C .S − K C P C C V ]

=0

C C . S= K C PC C V

[

]

C T =C V + C A . S + C C . S=C V 1 + √ K A P A + K C P C

−r B= r S =

K 3 P B C T √ K A P A 1 + √ K A P A + K C P C

EJERCICIO #$*3/+ L( de'%d#()($%: de (+$&&+ -)+%$& 3)(&+ '&#e $()(+%(d&# de (+%( - '+%$( ;e %9e')%(d( .&# P , M(#e# 3)e'%' d&$)&#(+= U%9e#'%d(d de M%$%( L&' d()&' de +( @#( 'e &)9%e#& ( H50 & , e  #e($)&# d%;e#e$%(+ &d%@$(d& L( (+%e)($%: ;e )(&+ .#& ( S%e#(  e$(%'& <  .('& 7e $&)#&+e +(' 9e+&$%d(de' $&#e)e' $& +&' d()&' e>.e#%e)(+e'  E9(+e +&' .(#*e)#&' de +( +e< de 9e+&$%d(d



$ E e+ .)& e e+ $(+ +( 9e+&$%d(d %%$%(+ e' *>%(= $*+ e' +( ;#($$%: de '%)%&' 9($&' C*+ e' +( ;#($$%: de '%)%&' &$.(d&' .&# A < B d Q ee#(+%($%&e' .&d#( e;e$)(# )#(' (e# e')d%(d& e')e .#&+e( e E'$#%( ( .#e)( 7e #e7%e#( de .e'(%e)& $#)%$& < de'.' e>.+%7e .&# 7 +& #e7%e#e

( A ( butano ) ↔ B ( But!no ) + C ( A"ua )

Me"nis)o #%o-(es'o

(

)

A + S ↔ A · S

C AS r AA = K AA P A C S − K AA

A · S + S ↔ B · S + C · S

r S = K S ( C A· S C S −C B · S C C · S / K S )

B · S ↔ B+ S

r DB= K DB ( C B ·S − PB C C · S / K DB )

C · S ↔ C+ S

r DC = K DC ( C DS − PC C S / K DC )

A'%ed& 7e +( e)(.( $&)#&+()e e' +( '.e#@$%e de +( #e($$%:?

−r AA K AA

=0

C A ·S = P A K AA C S



−r DB K DB

−r DC K DC

P B C 5 = P B K AB C S C B ·S = K DB

=0

=0

C C · S=

(

2

−r ' A= r S= K S P A K AA C S −

PB PC C S

2

K S K DB K DC

)

PC C 5 K DC

= PC K AC C S

(

)

P B PC

= K S K AA C S2 P A −

K !#

K !# = K S K AA K DC K DB

D&de? B(+($e de S%)%&?

1 + K AA P A + K AB P B + K AC PC

C T =C S + C AS + C BS+ C CS =C S ¿

&# ede= +( e$($%: de 9e+&$%d(d 'e#* +( '%%e)e?

−r ' A =

(

P B PC 2 K S K AA C T P A − K !#

) 2

( 1 + P A K AA + PB K AB + PC K AC )

S% PB 0 =0 < PC 0=0 = e)&$e'? 2

−r A 0=

K S K AA C T P A 0

( 1 + P A K AA )

2

=

K 1 P A 0 1 + K 2 P A 0

2

+ K 3 P A 0

(

2

K 1= K 3 K AA C T

$on$! :

K 2= K AA

2

K 3 = 2 K AA

)

E')e &de+& e')* ($&#de $& +(' &'e#9($%&e' e>.e#%e)(+e'

/6 De &" Fig(%" se -(ede o/'ene% &os sig(ien'es %es(&'"dos: N7)e%o

(

−r A 0 b %o

&r .bcat

P A 0 ( at%)

)

$ 0

2 0=2H5

0 0=5

, 0=HH

1 0=HH

 0=5

0

4=5

2H

54

112

22


√−

33333

P A

,9*1

9,1

59$,

Código: IQ8048 Revisión: 01 Fe!": 2016/11/25 #"g: 8 de 10 $29*

r A 0

E  9(+&# de P A 0 #(de?

−r A 0=

K 1 P A 0 K 2 P A 0

= 2

K 1

K 2 P A 0

!n ! unto 6 2

K 1 K 2

=( 229 ) ( 0,5 )=114

E  9(+&# de P A 0 .e7e&?

−r A 0= K 1 P A 0 (usan$o! unto 2 $!a taba s! t)!n! : K 1=0,061 → K 2=5,34 * 10−4 −r A 0=

{

0,061 P A 0 −4

1 + 5,34 * 10 P A 0

2

+ K 3 P A 0 −2

+san$o 'unto 3: K 3 =7,05 * 10

−2

+san$o 'unto 4 : K 3=3,19 * 10

−2

+san$o 'unto 5 : K 3 =1,05 * 10

}

!ntonc!s K 3=

0,061

1

−r A 0 P A 0

→ K 3=3,19 * 10

$ E+  de +&' '%)%&' 9($()e' 'e#*?

−

−2

−5,34 * 10−4

2$9,


Vacant! =

C S C T

=

Código: IQ8048 Revisión: 01 Fe!": 2016/11/25 #"g: $* de 10

C S C S ( 1 + P A K AA + P B K AB + PC K AC )

PB - P c =0, !ntonc!s a!cuac)onat!r)or s! r!$uc! a :

Vacant! =

1

( 1 + P A 0 K AA )

=

1 1 + 0,01596 * 90

=0,41

Se $&'%de#(#* 7e e+ .&#$e)("e de &$.($%: de B 'e#* $(d&  =0 = e)&$e'? A =

( 0,01595 )( 90 ) = 0,59 ( 1 + P A K AA ) ( 1 +( 0,01595)( 90)) P A K AA

=

d L( de'%d#()($%: de (+$&&+e' e' $()(+%(d( .&# *$%d&'= .(#( $&9e#)%# e+ (+$&&+ e ( e'.e$%e .#&)&(d( 7e .ede ';#%# e)e#:+%'%' .(#( .e#de# +( &+$+( de (( d%+e)e *'%$( E ('e$%( de *$%d& +( e)e#:+%'%' #e7e#%#* +( .#d%d( de  %: %d#:>%d&= ;e#)ee)e *'%$&=  .#&$e'& #(#(' 9e$e' '$ede E e+ (*+%'%' de (+7e&'= '%e.#e 7e 'e( .&'%+e 'e+e$$%&(&' .(#( ( .#e( de $(#($)e#%($%: ( #e($$%: 7e .ed( #e(+%(#'e #*.%d( < d%#e$)(e)e= < 7e de &#%e (  $(%& ;*$%+e)e &'e#9(+e 3$(%& de $&+&# L( de$&+&#($%: de+ .e#((()& & .#e( 7e  $&.e')& 'e( (+7e&' 'e(  (+7e&'= '&+(e)e 7e $&)%ee (+ #.& ;$%&(+ &>%d(+e .&# e+ .e#((()& <( 7e e+ $&.e')& .&d#( 'e#  (+7e&'= .e#& )(% .&d#( 'e#  (+7%&'=  (+ded& & $(+7%e# &)#( '')($%( ;*$%+e)e &>%d(+e e A(+%$e e+ &de+& ()e*)%$& .+()e(d&= '.&%ed& 7e +( e)(.( *' +e)( e' +( e)(.( ;'%$( Me')#e $& 7e .#&$ed%%e)& e>.e#%e)(+ .&d#( ++e(# ( de)e#%(# e')( .#e%'( < $:& (;e$)(#( e +&' #e'+)(d&' &)e%d&'

Ejercicios Fogler Catálisis 10-4 a 10-6

Recommend Documents