UNIVERSIDAD NACIONAL MAYOR DE SAN MARCOS FACULT ACULTAD DE GEOLOGÍA, MINAS, METALURGIA METALURGIA Y CIENCIAS GEOGRÁFICAS DEPARTAMENTO ACADÉMICO DE INGENIERÍA METALÚRGICA
REMEDIACIÓN DE EFLUENTES
Nombre: Camac Rom! "o#a! G$% Me&$!a "oe% Par&o Na%'ar(e L)$* P)%c#a +a! Ro!a%&o
C)r*o: O-erac$o!e* . -roce*o* me(a%/r0$co* I1
Pro2e*or G)3a: I!01 Da!$e% Lo'era1
2014
Operaciones y Procesos Metalúrgicos I
UNMSM
Resumen E! e% -re*e!(e e4-er$me!(o &e reme&$ac$5! &e e6)e!(e* ()'$mo* 7)e (raba8ar (a!(o co! %a &o%om$(a . carb5! ac($'a&o, e%%o a -ar($r &e )!a *o%)c$5! &e *)%2a(o &e cobre -e!(a#$&ra(a&o co! %a comb$!ac$5! &e% (r$c%or)ro 29rr$co1 E*(e -re*e!(e (raba8o 2)e #ec#o a )! -rome&$o &e ; 0ra&o* ce!(30ra&o*, -or e8em-%o e% ($em-o <; =re>r$9!&ome a 7)e %o* -r$mero* <; m$!)(o*? (e!emo* @ 0ra&o* ce!(30ra&o* ca-()ra&o*, !)e*(ro B e* @1, !)e*(ro - e* ;1 . e% B< e* ;1;@, -ara )! ($em-o ; a @;HC m)e*(ro B e* @1, !)e*(ro - e* ;1< . e% B< e* ;,;@<<1 Y com-ara!&o co! )! ($em-o @; a HC 'amo* a ob(e!er 7)e !)e*(ro B e* , !)e*(ro - e* ;,< . e% B< e* ;,;<; co! e%%o -o&emo* !o(ar 7)e m$e!(ra* e% ($em-o *)be e% - ba8a, . co! e%%o 'amo* a (e!er c)r'a1
Introdu!"n No*o(ro* -ara #acer reme&$ac$5! &e e6)e!(e*, (e!&remo* 7)e *aber 7)e *aber 7)e e*(e e4-er$me!(o *e ba*a (a!(o e! %a a&*orc$5! como (amb$9! %a &e*orc$5!1 E*(a (9c!$ca &e (ra(am$e!(o re*)e%'e e% -rob%ema &e 0e!erac$5! &e e6)e!(e* me(a%/r0$co* co! e% em-%eo &e %a &o%om$(a, m$!era% !o me(%$co &e carbo!a(o &ob%e &e ca%c$o . ma0!e*$o =CaCO @1M0CO@?, 7)e *e com-or(a como )! e2ec($'o reac($'o &e reme&$ac$5!, &eb$&o a %a* -ro-$e&a&e* >*$co7)3m$ca* &e %a !e)(ra%$ac$5! &e %a ac$&e &e a0)a* c$&a*, a*3 como %a a&*orc$5! &e $o!e* me(%$co* &$*)e%(o* e! %a* a0)a* c$&a*1 A*$m$*mo, %a a-%$cac$5! &e e*(e (ra(am$e!(o &e reme&$ac$5! -ro-o!e e*(ab%ecer )!a me(o&o%o03a &e (raba8o 7)e
REMEDIACION DE EFLUENTES – LABORATORIO N°10
Operaciones y Procesos Metalúrgicos I
UNMSM
&e*arro%%e )!a (ec!o%o03a &e %$m-$ea a !$'e% &e %abora(or$o, co! -er*-ec($'a* a &e*arro%%ar %a m$*ma (ec!o%o03a a !$'e% &e -%a!(a -$%o(o, co! e% -o*(er$or &e*arro%%o &e )!a -%a!(a &e (ra(am$e!(o &e reme&$ac$5! a !$'e% $!&)*(r$a%1
#r!n!$!os te"r!os Para -o&er #ab%ar &e reme&$ac$5! &e e6)e!(e*, (e!emo* 7)e 'er %a (eor3a e! a&*orc$5! . &e*orc$5! .a 7)e e*(e e4-er$me!(o *e 2)!&ame!(a e! e%%o1 INTERCAM%IO IONICO& E% $!(ercamb$o $5!$co e* )!a reacc$5!
7)3m$ca re'er*$b%e, 7)e ($e!e %)0ar c)a!&o )! Io! &e )!a &$*o%)c$5! *e $!(ercamb$a -or o(ro Io! &e $0)a% *$0!o 7)e *e e!c)e!(ra )!$&o a )!a -ar(3c)%a *5%$&a $!m5'$%1 E*(e -roce*o ($e!e %)0ar co!*(a!(eme!(e e! %a !a()ra%ea, (a!(o e! %a ma(er$a $!or0!$ca como e! %a* c9%)%a* '$'a*1 Por *)* -ro-$e&a&e* como &$*o%'e!(e . *) )($%$ac$5! e! &$'er*o* -roce*o* $!&)*(r$a%e*, e% a0)a aco*()mbra a (e!er m)c#a* $m-)rea* . co!(am$!a!(e*1 La* *a%e* me(%$ca* *e &$*)e%'e! e! e% a0)a *e-ar!&o*e e! $o!e*, c).a -re*e!c$a -)e&e *er $!&e*eab%e -ara %o* )*o* #ab$()a%e* &e% a0)a1 A&em*, e% crec$e!(e $!(er9* -or e% me&$o amb$e!(e, $m-o!e e*(ab%ecer (ra(am$e!(o* e>cace* 7)e e'$(e! e% &e(er$oro &e %a ca%$&a& &e %a* a0)a*, e*-ec$a%me!(e -or e% 'er($&o &e e6)e!(e* $!&)*(r$a%e* a%(ame!(e co!(am$!a&o*1 E!(re (o&o* %o* (ra(am$e!(o* -o*$b%e*, e% $!(ercamb$o $5!$co e* )!a o-c$5! a co!*$&erar1 Por *) re%e'a!c$a e! e% (ra(am$e!(o &e a0)a* . &$'er*o* -roce*o* $!&)*(r$a%e*, e! e*(e &o**$er *e -re(e!&e &ar )!a '$*$5! 0e!era% &e %o*
REMEDIACION DE EFLUENTES – LABORATORIO N°10
Operaciones y Procesos Metalúrgicos I
UNMSM
$!(ercamb$a&ore* $5!$co*, *) 2)!c$o!am$e!(o . *)* -r$!c$-a%e* a-%$cac$o!e*1 ADSORCION& E* )!a -ro-$e&a& &e *)-er>c$e -or %a c)a% c$er(o*
*5%$&o* ca-(a! co! -re2ere!c$a &e(erm$!a&a* *)*(a!c$a* &e )!a *o%)c$5! co!ce!(r!&o%a* e! *) *)-er>c$e1 Se -re*e!(a -or %a acc$5! &e 2)era* *)-er>c$a%e* !o com-e!*a&a* e! e% *5%$&o . mo%9c)%a* &e %a *)*(a!c$a a&*orb$&a =ab*orc$5! 23*$ca?1 E* )!a o-erac$5! re'er*$b%e 7)e -erm$(e re0e!erac$5! &e% a&*orbe!(e1 ISOTERMA DE ADSORCION& So! &$a0rama* 0e!era%me!(e -ara
0a*e* ='a%$&o -ara *o%)c$o!e* &$%)$&a*? &o!&e *e re-re*e!(a %a co!ce!(rac$5! &e e7)$%$br$o &e% *o%)(o e! *o%)c$5! e! 2)!c$5! &e %a ca!($&a& &e *o%)(o a&*orb$&o -or )!$&a& &e ma*a &e a&*orbe!(e a (em-era()ra co!*(a!(e1 La re%ac$5! e!(re %a ca!($&a& &e *)*(a!c$a a&*orb$&a -or )! a&*orbe!(e . %a -re*$5! o co!ce!(rac$5! &e e7)$%$br$o a )!a (em-era()ra co!*(a!(e *e &e!om$!a $*o(erma &e a&*orc$5!1
REMEDIACION DE EFLUENTES – LABORATORIO N°10
Operaciones y Procesos Metalúrgicos I
UNMSM
Metodo'o()* e+$er!ment*' E% -r$mer -a*o 2)e -e*ar %o* 0ramo* &e *)%2a(o &e cobre, 7)e como *abemo* (or!a &e co%or a)%, . e% (r$c%or)ro 29rr$co 7)e (or!a )! co%or a!ara!8a&o, *e comb$!a! %o* . *e 'a a !o(ar )! co%or 'er&o*o1 E*(a *o%)c$5! 'amo* a -o!er a a0$(ar . %e 'amo* a ec#ar carb5! como reme&$a&or -ero e! (oma*, -or ($em-o* &e <;, ;, @;, ; . ; m$!)(o*1 L)e0o &e ec#ar%e e! ca&a ($em-o, *e 'a a (omar )!a -r)eba co! )!a -$-e(a, (omar %a (em-era()ra . (amb$9! (omar e% - . %o* 'o%(eo*1 acer %a* me&$c$o!e* correc(a* -ara -o&er (e!er &a(o* cer(ero*1
REMEDIACION DE EFLUENTES – LABORATORIO N°10
UNMSM
Operaciones y Procesos Metalúrgicos I
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REMEDIACION DE EFLUENTES – LABORATORIO N°10
UNMSM
Operaciones y Procesos Metalúrgicos I
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REMEDIACION DE EFLUENTES – LABORATORIO N°10
Operaciones y Procesos Metalúrgicos I
UNMSM
D!sus!"n de Resu't*dos •
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&o%om$(a .a 7)e e* -re2er$b%e (raba8ar -or e*()&$o* rea%$a&o* co! %a &o%om$(a1 REMEDIACION DE EFLUENTES – LABORATORIO N°10
Operaciones y Procesos Metalúrgicos I
UNMSM
La c)r'a K * ( &ebe *er *$em-re ma.or a %a &e (em-era()ra
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Operaciones y Procesos Metalúrgicos I
UNMSM
•
1b$o%o0$a1e&)1ar(e*$*2orc$%%oc)r($&oa%cromo1#(m
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REMEDIACION DE EFLUENTES – LABORATORIO N°10
