Diktat Teknik Kimia 2014 (kimia organik)

DAFTAR ISI

I.

Kimia Organik

II.

Mekanika Fluida

III.

Permodelan Teknik Kimia

IV.

Perpindahan Kalor

V.

Termodinamika

JANGAN TERPAKU PADA DIKTAT INI. Diktat ini dijawab oleh mahasiswa. Pemikiran dosen mungkin berbeda. Untuk penggunaan diktat yang efektif, berkonsultasilah dengan asisten dosen.

Kritik dan Saran : Dimas Nurwansyah TK 14 ( 081934165726 ) ‘

Mahdi TK 14 ( 081297100469 ) ’

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UJIAN TENGAH SEMESTER GENAP 2013/2014 : KIMIA ORGANIK MATA KULIAH DOSEN : DR. IR. EVA F. KARAMAH, MT. DR. IR. SETIADI, M.ENG. HARI/TANGGAL : JUMAT/4 APRIL 2014 : 90 MENIT WAKTU SIFAT : BUKU TERTUTUP (CLOSED BOOK}

Soal 1 (20%) Untuk setiap pasangan molekul berikut ini, tuliskan nama  dari setiap senyawa dan lingkarilah  asam yang lebih kuat dan berikan alasan Anda (dalam bentuk gambar ataupun kalimat).

Soal 2 (15%) Jawablah pertanyaan-pertanyaan berikut terkait dengan 3 jenis alkena di bawah ini. Gunakan kalimat dan ilustrasi dalam penjelasan Anda.

a. Senyawa alkena mana yang paling reaktif terhadap H ? Mengapa?  b. Senyawa alkena mana yang paling tidak reaktif terhadap H+? Mengapa? c. Senyawa alkena mana yang paling reaktif di bawah kondisi hidrogenasi katalitik? Mengapa? d. Apakah ketiga jenis senyawa alkena di atas mengalami reaksi adisi HBr Markovnikov? Jika tidak, mana yang mengalami dan mana yang tidak? Mengapa?

Soal 3 (15%) Tuliskan nama reaktan dan reagen yang dibutuhkan untuk menghasilkan senyawa berikut ini.

Soal 4 (20%) Tuliskan nama senyawa berikut dan gambarkan produk utama dari reaksi-reaksinya berikut ini. Lengkapi jawaban Anda dengan aspek stereokimia jika memang diperlukan.

Soal 5 (30%) Usulkan mekanisme sintesis yang dialami oleh transformasi berikut ini. Perlihatkan semua reagent dan produk antara yang dihasilkan sepanjang proses.