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Istilah yang menyatakan diperlukannya kecenderungan/tendensi dari suatu reak Master yourkimia semester with Scribd disebut : “Driving Read Force” Free Foron 30this Days Sign up to vote title & The New York Times Useful Not useful CHOnly4 + 3 O2 CO2 + 2 H2O + 213 kcal Special offer for students: $4.99/month.
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Energi disosiasi ikatana ( ): jumlah energi yang dibutuhka untuk memutuskan satu ikatan sehingga dihasilkan dua fragmen radikal pada suatu molekul dalam fas gas pada 2 C. semester with Scribd Master your
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Energi ikatan (Kkal/mol) H
H
104
C
C
99 C semester C MasterHyour withCScribd & The H NewNYork Times 93 C C Special offer for students: Only $4.99/month.
H
O
88
C
83
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Contoh :
+
CH3CH2―H 101
Cl―Cl 58
Master your semester with Scribd & The New York Times ∆H = 159 – 187 °
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= -28
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Contoh :
CH2 CH2 + HCl Master your semester with Scribd 2 molekul & The New York Times Special offer for students: Only $4.99/month.
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Ukuran konstanta kesetimbangan
Jika nilai K eq lebih besar dari 1, maka hal ini Master yourmenunjukkan semester with Scribd bahwa kesetimbangan reaksi Read Free For 30this Days Sign up to vote on titlecenderu & The New York Times Useful Not useful ke arah produk, misal : Cancel anytime.
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Energi bebas dan kesetimbanga
Rasio produk terhadap reaktan dikontrol oleh ene Master yourbebas semester withrelatifnya. Scribd Gibbs Read Free Foron 30this Days Sign up to vote title & The New York Times Useful Not useful kesetimbangan Energi ini dilepaskan oleh sisi rea Cancel anytime. Special offer for students: Only $4.99/month. yang favorable. You're Reading a Preview
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Hubungan numerik antara Keq dan perubahan energi bebas.
Perubahan energi bebas standar pada tekanan 1 Master yourdan semester with Scribd up temperatur 298 K disebutRead Gº Free Foron 30this Days Sign to vote title
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Hubungan antara perubahan energi bebas dan
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A = U – TS
G = H – TS = U – TS + pV G = A + pV Master your semester with Scribd For Sign to vote title dU = T dS – p dV dG =Read V upFree dP –on30this SDays dT & The New York Times Useful Not useful Special offer for students: ( Only G $4.99/month. ) p = -S / p) T = V / T ( G You're Reading a Preview
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dU = dq + dw (The First Law of Thermodynamics)
◦ U= Total energy (ikatan2 kimia, gaya2 inter da Master your semester with Scribd Read Free For 30this Days Sign up to vote on title intramolecular , energi vibrational dan rotationa & The New York Times Useful Not useful ◦ q= panas and w = kerja yang dikenakan pada Special offer for students: Only $4.99/month.
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C (graphite) + 2 H 2 (g) CH4
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(g) +
17.9 kcal
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Persamaan perubahan entropi dengan perubahan panas yang reversibel : dS = dqrev/T MasterPersamaan your semester with Scribd perubahan entropi terhadap temperatu Read Free Foron 30this Days Sign up to vote title T 2 & The New York Times Useful Not useful dH Special offer for students: Only $4.99/month. S (T 2 ) S (T 1You're ) Reading a Preview
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Faktor penyumbang Entropy
Entropy merupakan manifestasi dari gerakan molekul :
Master your semester Scribd ◦ Sgas >Sliquid with >Ssolid Read Free Foron 30this Days Sign up to vote title & The New York Times Useful Not useful ◦ C = 0,57 C = 1,3 C = 37.7 ca gas diamond Graphite Special offer for students: 1 Only $4.99/month. -1
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•Cenderung meningkat seiring bertambahnya kompleks molekul ( more molecular motion ) Master your semester with Scribd -1 -1 Free Foron 30this Days Sign to vote title mol CH 4 = 44.4 C 2 H 6 = 54.5 C 3H 8 Read = up64.5 cal K & The New York Times Useful Not useful Special offer for students: Only $4.99/month.
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Meningkat ketika terjadi percampuran atau terjadi pela
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GIBBS FREE ENERGY Master your semester with Scribd Read Free Foron 30this Days Sign up to vote title KOMBINASI (H-T & The New York Times ENTROPI DAN ENTALPI Useful Not useful Special offer for students: Only $4.99/month. HARUS NEGATIFYou're UNTUK MENDAPATKAN Reading a Preview REAKSI ANG SPONT Cancel anytime.
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The Gibbs Functions, G G
= H – TS Master your semester Scribd Afinitas suatu with reaksi kimia dinyatakan dalam Read Free Foron 30 Days Sign up to vote this title & The New York Times Useful Not useful bebas Gibbs dan persamaan perubahan energi Special offer for students: Only $4.99/month. Reading a Preview hanya berlangsungYou're spontan ketika G negative Cancel anytime.
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KESETIMBANGAN KIMIA H
H
H
CH3
Master your semester with Scribd Read Free Foron 30this Days Sign up to vote title & The New York Times Useful Not useful Special offer for students: H f Only $4.99/month. -3.3 -4.1 kcal mol You're Reading a Preview S 0.08 0.078 kcal K -1 H3C
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Kesetimbangan : dua kasus umum [B] [produk] K = B ScribdK = Master1.yourA semester with Free Foron 30this Days [A]Read [reaktan] Sign up to vote title & TheKNew York Times Useful Not useful = konstanta kesetimbangan Special offer for students: Only $4.99/month.
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Gibbs Free Energy, ∆G Master your semester with Scribd G YorkR T K & The New Times
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Kesetimbangan dan energi bebas Pada 25ºC (298 K): ΔGº = - 1.36 logK °
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°
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Entalpi ∆H dan Entropi ∆S
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cal-1 deg-1 mol-1 or entropy un Gyour semester H T Master withS Scribd Read Free Foron 30this Days Sign up to vote title & The New York Times -1 Useful Not useful °
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Diagram Energi Reaksi dan Transition States Titik energi tertinggi Master yourdalam semester with Scribd suatu tahap Read Free Foron 30this Days Sign up to vote title & The New York Times Useful Not useful reaksi dikenal dengan Cancel anytime. Special offer for students: Only $4.99/month. transition state You're Reading a Preview
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Intermediet Jika reaksi terjadi dengan lebih dari satu tahap, maka Master your semester with Scribd Read Free Foron 30this Days reaksi akan melibatkan Sign up to vote title & The Newsuatu Yorkspesies Timesyang bukan Useful Not useful Cancel anytime. Special offer for students: Only $4.99/month. merupakan reaktan dan You're Reading a Preview juga bukan produk akhir
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Aplikasi termodinamika terhadap laju proses
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Prinsip Curtin-Hammett
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Contoh
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Kinetika
Hukum laju dan mekanisme reaksi pendekatan keadaan tetap (steady)
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Master your semester with Scribd Read Free Foron 30this Days Sign up to vote title setimbang (kondisi reaksi reversibel) , rasi & ThePada New keadaan York Times Useful Not useful Special offer for students: Only $4.99/month. You're Reading ditentukan a Preview oleh stabilita produk dari reaksi yang kompetitif Cancel anytime.
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Kontrol kinetic vs termodinamik Master your semester with Scribd & The New York Times Special offer for students: Only $4.99/month.
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Reaksi Intramolecular vs Intermolecular
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Pada pembentukan cincin yang kecil, bertambahnya regangan cincin pada produk akan menurunkan kecepatan laju reaksi(enthalpy of activation yang besar), yang menyebabkan of activation yang berkurangnya laju with percepatan Master your semester Scribdentropy Read Free For 30 Days Sign up to vote on this title favorable
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Perbandingan antara reaksi Biologis dan Laboratoris Reaksi Laboratorium Master your semester with Scribd umumnya dilakukan dalam pelarut organik. & The Newmedium York Times
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ENERGI AKTIVASI CH4 + 3 O2
CO2 +
2 H2O + 213 kcal
Master H your semester with Scribd C=CH + H H C-CH + 32.7 kcal, Pt as cata Read Free For 30 Days Sign up to vote on this title 2 2 2 3 3 & The New York Times Useful Not useful Special offer for students: Only $4.99/month.
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Potential Energy Surface (PES) x
x # G Master your semester with Scribd
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= kompleks teraktiva keadaan transisi G# = energi bebas aktiv Read Free Foron 30this Days Sign up to vote title
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z = intermediet
x1 x2
G1#
G2# Z Master Eyour semester with Scribd R & The New York Times Special offer for students: Only $4.99/month. o
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X3
x1
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Evans, Polanyi and Eyring:
◦ The transition state is deemed to be a species
which all theScribd usual thermodynamic Master yourto semester with Read Free For 30 Days Sign up to vote on this title quantities may be ascribed since this must be & The New York Times Useful Not useful possible Special offer for students: Only $4.99/month.for any assemblage of atoms of You're Reading a Preview definite geometry and bonding. Cancel anytime.
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Arrhenius equation E kt
E kt
log A k Ae logwith k Scribd Master your semester Read Free Foron 30this Days Sign up to vote title 2,303 RT & The New York Times Useful Not useful Special offer for students: 1 You're E kt k 1Only $4.99/month. 1 Reading a Preview log RT
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LAJU EMPIRIK DARI REAKSI Master semesterstoichiometric with Scribd your Persamaan tidak dapat Read Free Foron 30this Days Sign up to vote title memberikan & The New York Times informasi mekanisme Useful Not useful Special offer for students: Only $4.99/month. You're Reading adinyatakan Preview OKI, persamaan tersebut dalam Cancel anytime.
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R3N + CH3I → R3N+-CH3Ilaju reaksi, v = k2 [R3N] [CH3I] Master your semester with Scribd Foron 30this Days Sign to vote title substitusi bimolekuler (SNRead 2)upFree
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kobs = k1
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Postulat Hammond
G. S. Hammond (1921– ), menyatakan bahwa pada setiap yang melibatkan tahap perubahan elementer,geom Master yourreaksi semester with Scribd Read Free Foron 30this Days Sign up to vote title leb dan struktur keadaan transisi pada tahap tersebut akan & The New York Times Useful Not useful dekat ke/mewakili reaktan atau produk pada tahap itu Special offer for students: Only $4.99/month. You're Reading a Preview bilamana memiliki energi yang lebih tinggi.
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Postulat Hammond Master your semester with Scribd “Early TS” & The New York Times Special offer for students: Only $4.99/month.
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Menurut Hammond postulate ◦ Jika dua keadaan terjadi secara berurutan selama
reaksi berlangsung dan keduanya memiliki konten Master your semester ak energi yangwith samaScribd maka interkonversi keduanya Read Free Foron 30this Days Sign up to vote title & The Newmelibatkan York Timesreorganisasi kecil Useful Not useful dalam struktur molek Cancel anytime. Special offer for students: Only $4.99/month.
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