SeparaciónFlash Mezcla Cloroformo Metanol

Constantes de Antoine presión en Kiloa ! " en #C

Sist Sistema ema:: A1 A2 A3

Acet Acetoni onitr trililo( o(A) A) 14.2724 2$4%.47 224

Nitr Nitrome ometa tano( no(B) B) 14.2043 2$72.&4 20$


Siste istema ma:: A1 A2 A3

Benc Bencen eno( o(A A) 13.% 27.%1 220.7$

'ti 'tilen lence ceno no(B (B)) 14.004% 327$.47 213.2


Sistema: Sistema: 1*Cloro+tano(A) 1*Cloro+tano(A) Cloroenceno(B Cloroenceno(B)) A1 13.$& 13.$$2& A2 22&.2& 32$%.12 A3 224.1 217.%%


Siste istema ma:: A1 A2 A3

Aceto cetona na(A (A)) 14.%4&3 2$40.4& 237.22

Aceto cetoni nitr trililo( o(B) B) 14.2724 2$4%.47 224


Sist Sistem ema: a: A1 A2 A3

n*e n*ent ntan ano( o(A) A) 13.13 2477.07 233.21

n*,e n*,ept ptan ano( o(B) B) 13.%7 2$11.32 21&.&4


Sistema: ma: A1 A2 A3

Bence nceno(A o(A) 13.% 27.%1 220.7$

"ol+eno( eno(B B) 13.$$7 30$&.%2 21$.4




Sistema Sistema:: 1*Clor 1*Cloro+t o+tano( ano(A) A) A1 13.$& A2 22&.2& A3 224.1

Benceno( Benceno(B) B) 13.% 27.%1 220.7$



n*e n*ent ntan ano( o(A) A) 13.13 2477.07 233.21

n*,e n*,e--ano( ano(B) B) 13.21& 2&$7.%% 224.37


n*,e n*,e-a -ano no(A (A))

"riet rietililam amin ina( a(B) B)

lnP sat

= A1 −

A2 T

+ A3

Benc Bencen eno( o(A) A) 13.% 27.%1 220.7$

'til tilen ence ceno no(B (B)) 14.004% 327$.47 213.2

S'AAC/N AS, Constantes de Antoine presión en S/A ! " en #

Sistema: A1 A2 A3 c psia

Calor especiico 5apores ideales " en # Cp en Bt+lmol#

Benceno(A) %.&%37% %307.13 37$.4%& 714.2

"ol+eno(B) %.$442%1 %3&.27 374.74% %7.

a1 1.&3$2200'601 a2 4.0203&$00'*02 a3 &. &.$2 $2%3 %3$$ $$00 00'* '*0& 0& a4 *4.11420 *4.11420200' 200'*0 *0 a% 2.3 2.3$0 $0$0 $00' 0'*1 *11 1

2.11772200'601 4.&3$%4&00'*02 $.$& $. $&13 13& &00 00'* '*0& 0& *4.&22& *4.& 22&400' 400'*0 *0 2.%% 2. %%77 7700' 00'*1 *11 1

 P v A = A1 − 2  A3 + T  Pc ideal C pv = a1 + a2T + a3T 2 + a4T 3 + a5T 4 ln 

Mezcla

= ∑ yi H videal i H L = ∑ xi ( H viideal − λ i ) R(T + 459.6)2 A2 λ = ( A3 + T )2 H v

∂ ln ln( P v ) ∂T

λ

= RT 2

T

= temp temper erat atura ura abso absolu luta ta

1ar8 1atm8 1atm8 1atm8 1atm8

100 Kpa 7&0 mm ,9 14&$& psi 10132% ar 10132% Kpa

#

#C 32

0

/n9resa resión  psia8 "empe #8

1 210.%

Comp+esto  A B /n9resa resión  psia8 "empe #8

5apor psia K 0.% 2%.403&7$22% 1.41%%7%$$& 0.% 10.%2$&%&%7& 0.%4$$2%37

1 222.%

Comp+esto  A B

5apor psia K 0.% 30.323&&%3%34 1.&4&407% 0.% 12.7$47$%03 0.710%2&&3$

"#

;N"< =' B;B;>A ?K 0.70777$$7 0.2$24$&2&3 1.000242&&1 *0.000242&&1

;N"< =' 
-

! 0.% 0.70777$$ 0.% 0.2$24$&2& 1 1.000242&&

!

0.% 0.2$&7$7$3 0.% 0.70370333 1 1.000%01277

 lmol@ 8 (A)8  psia8 " #8 5 A 5 B s+ma(?K) s+ma(K) ,5 A Bt+l mol ,5 B Bt+lmol lamda A Bt+l mol lamda B Bt+lmol ,5 mecla ,l mecla ,

32 Condiciones del separado  psia 8 1 " # 8 217 100 0.% 1 200 21.%32100%21 .723$321$%& 0.4044%3%33 1.44$&2%4&2 3%40.$&3$%&% 44$0.0372%7$ 13&&%.7&102 1%273.740147 401%.%00&072 *104%4.2%037 *104%4.2%

5 Benceno(A) 27.$%%&71% "ol+eno(B) 11.&7$043 D Bt+@

7$&2$$.3%7

Condiciones del separado  psia 8 $ " # 8 1&$.&1 5 Benceno(A) 13.02&2$22 "ol+eno(B) 4.$7341%

/S<"/C<: no @a! 5l5+la racc E K ?K K 1.%%30$2& 0.77&%4&43 0.321$32% 0.&43&02 0.3244101 0.770&1073 1.100$&444 1.0$2%4$

0.%1$2$ N+e5o E

0.%1$2$

9 9F2 ! 0.2147$107 0.0$22704 0.334%4 0.&0313&4& *0.2147$107 0.0$22704 0.&11&%4& 0.3$&&3%4 *7.%4%'*011 *0.14%401 1 1

A=/ABA"/C<: 5l5+la adiatica racc E

K

?K K 1.4473&% 0.723&2$ 0.34%4%%17 0.%%2&017& 0.27&300 0.$041072 0.$$$$37 1.2%02&%$



" $

0.0000103

N+e5o E *.1030'*0%

9 9F2 ! 0.223&747$ 0.1000&02 0.4$$$1 0.723&%&&7 *0.22370723 0.1000$% 0.%000113 0.27&310$ 1 0.$$$$&7%7 G1 *3.244'*00% *0.2001%0&7

E D " para D80 E para D80 1&$.&1 0.0000103 to +r+Ga *1012%3.&&4 170.&&%3 0.0&7&377$ 11.13% 1 to rocio 13$741.7%

4

12.%4% 140.7&

0.00007 1

1%

1$$.% 211.2

0 1

*23774.113 12$1011.37

130.44%4$ 0.1%%&4%72

*1&$&.7%$& 1$$.%1341% 0.00114&%$ 147234.37

1.2 1 0. 0.&

,5 amda ,l 3$&1.&77 13%71.274 *$&0$.%70213& %022.&$02 1%1&1.0%07 *1013.3%2&%3 432.7&40& *$$33.00$741 'ntalpia mecla 'ntalpia mecla

0.4 0.2 0 1&

170

172

*0.2

,5 amda ,l 222.7043& 134.%74 *1102%.&$&%% 3%1.$72% 1%4$1.$$3$ *11$10.021444 3032.40&7 *114&7.$&1&0%$ 'ntalpia mecla 'ntalpia mecla

G2

D

*0.0$&%40&1 *1012%3.&&4103

17$ 17% 174 173 172 171.% 170.% 170.2 170.& 170. 170.7 170.&4

1.2 1 0. 0.& 0.4 0.2 0 174

17&

17

10

0 *0.2

0.74$4 0.$72& 0.4271 0.%0 0.3477 0.3$% 0.2&73 0.20% 0.1%2 0.1&4 0.1432 0.10% 0.0%70277 *0.010& 0.0304320& *0.0%4 0.0&%1323 *0.00447 0.0327047 0.0201104 0.074%&04& 0.007440% 0.0&$31&&& 0.0004&13

0.1

0.2

0.3

0.4

0.%

0.&

0.7

0.




Benceno(A) %.&%37% %307.13 37$.4%& 714.2

"ol+eno(B) %.$442%1 %3&.27 374.74% %7.

a1 1.&3$2200'601 a2 4.0203&$00'*02 a3 &.$2%3$$00'*0& a4 *4.11420200'*0 a% 2.3$0$00'*11

2.11772200'601 4.&3$%4&00'*02 $.$&13&00'*0& *4.&22&400'*0 2.%%7700'*11

 P v A = A1 − 2  A3 + T  Pc ideal C pv = a1 + a2T + a3T 2 + a4T 3 + a5T 4 ln 

Mezcla

= ∑ yi H viideal H L = ∑ xi ( H viideal − λ i ) R(T + 459.6)2 A2 λ = ( A3 + T )2 H v

∂ ln( P v ) ∂T

λ

= RT 2

T

= temperatura absoluta


100 Kpa 7&0 mm ,9 14&$& psi 10132% ar 10132% Kpa

#

#C 32

0


4 12.%%


5apor psia K 0.% %.$3703$7&%& 1.442%$$41 0.% 2.0&3&&2701 0.%1%$1%&77

4 140.%


5apor psia K 0.% 7.%4444$2$ 1.7111232 0.% 2.700420$02 0.&7%120%23

"#

;N"< =' B;B;>A ?K 0.74212$$707 0.2%7$%73% 1.000070$2 *.70$217$&703'*00%

;N"< =' 
-

! 0.% 0.74212$$71 0.% 0.2%7$%73$ 1 1.000070$

!

0.% 0.2&4$%%23% 0.% 0.740&0%04 1 1.00%%&373$

 lmol@ 8 (A)8  psia8 " #8 5 A 5 B s+ma(?K) s+ma(K) ,5 A Bt+l mol ,5 B Bt+lmol lamda A Bt+l mol lamda B Bt+lmol ,5 mecla ,l mecla ,

32 Condiciones del separado  psia 8 1 " # 8 217 100 0.% 1 200 21.%32100%21 .723$321$%& 0.4044%3%33 1.44$&2%4&2 3%40.$&3$%&% 44$0.0372%7$ 13&&%.7&102 1%273.740147 401%.%00&072 *104%4.2%037 *104%4.2%

5 Benceno(A) 27.$%%&71% "ol+eno(B) 11.&7$043 D Bt+@

7$&2$$.3%7

Condiciones del separado  psia 8 $ " # 8 170.&3&2%& 5 Benceno(A) 13.204$3 "ol+eno(B) %.04$7%32

0.0&$$& 0.0&$$03 170.&3&2%& 170.&3&2%&

/S<"/C<: no @a! 5l5+la racc E K ?K K 1.%%30$2& 0.77&%4&43 0.321$32% 0.&43&02 0.3244101 0.770&1073 1.100$&444 1.0$2%4$

0.%1$2$ N+e5o E

0.%1$2$

9 9F2 ! 0.2147$107 0.0$22704 0.334%4 0.&0313&4& *0.2147$107 0.0$22704 0.&11&%4& 0.3$&&3%4 *7.%4%'*011 *0.14%401 1 1

A=/ABA"/C<: 5l5+la adiatica racc E

K ?K K 1.4&721033 0.733&0%17 0.3407277 0.%&1042& 0.20%4213 0.$11317& 1.0141472$ 1.231$14%3

0.0&$$03

9 9F2 ! 0.22&310&3 0.10243301 0.44370% 0.710&$7& *0.22&310&4 0.10243301 0.%1%&12$% 0.2$30231 *7.4%'*00$ *0.204&&02 1 0.$$$$$$$$ G1(V/F)



" $

N+e5o E &.$$'*02

G1'(V/F)

E D " para D80 E para D80 1&$.$ 0.0000103to +r+Ga *$&2$7 170.&&204 0.0&4&3074 11. 1 to rocio 13$%40$

4

12.% 140.7&

0.00007 1

1%

1$$.% 211.2

0 1

*231$77 12%27

130.41%4 0.1%&2$72&

13.%01 1$$.4$3%%$ *0.000%%0%2 147%1&.01

,5 amda ,l 3$&1.&77 13%71.274 *$&0$.%70213& %022.&$02 1%1&1.0%07 *1013.3%2&%3 432.7&40& *$$33.00$741 'ntalpia mecla 'ntalpia mecla

"60.01# 8 ,5 i amda ,l i 240.73317 1343.&04& *11002.713$$$ 3&04.7%4%1 1%4&.0%72 *111.302&74 30&1.7&&2$ *114%%.01$4$$ $.%742&2'*00 Hv m

Hl m

'ntalpia mecla D

G2(V/F)

170.&4&2%&

5 K 13.20720$4 1.4&74&771 %.0%074$2% 0.%&11$43& 1.3&7&2073 G2'(V/F)

'ntalpia mecla

0.1000$172

Gacoiano *0.204&&02 0.017$3171 1.3&7&21 0.00314&%$

E " 0.0&17$7 170.&13031 0.0&$$47& 170.&3&31

9 ,5 lamda ,l 0.22&43141 240.$&% 1343.%40& *11002.%74&$ *0.22&2%21 3&0%.04%7 1%4%.$07 *110.$321%& 0.00017$31 *7.440'*00$ 0.017$3171 30&2.01&7% *114%%.4&711 3.1%&17'*00% G1(T+DT)

G1(T)

G1'(T)

atri in5ersa del Gacoiano *0.12317370$ 0.701$3$3 %4.3%$$441% .01$%04&

H1 H2 *0.0002%073 *0.001204%3 *&.$&7'*00 .14%4$'*00&

G2(T+DT)

H *7.4%'*00$ $.%74'*00

>*1H &.1274'*00 3.&0$3%'*007

$.%742&2'*00 0.00314&%$2 G2(T)

G2'(T)

N+e5o E8 0.0&$$&2 "8 170.&3&2%%&




Constantes de 5an aar

α β

etanol(A) 7.%13334 &4&.101 3$&.2&%2 11%3.&

a1 a2 a3 a4 a%

$.010400'600 .430&4200'*03 &.&&$1%00'*0& *.20$100'*0$ 2.%00&300'*12

0.3 0.%1

A9+a(B) &.%3247 7173.7$ 3$.4747 320&.7

7.$%74200'600 4.&331$100'*04 1.4024100'*0& *&.%73700'*10 $.7$%200'*14

 P v A = A1 − 2  A3 + T  Pc ideal = a1 + a2T + a3T 2 + a4T 3 + a5T 4 C pv

= RT 2

T


ln 



Mezcla

ln 

L




ideal vi

100 Kpa 7&0 mm ,9 14&$& psi 10132% ar 10132% Kpa

A

B

= ∑ yi H H L = ∑ xi ( H viideal − λ i ) R(T + 459.6)2 A2 λ = ( A3 + T )2 H v

∂ ln( P v ) ∂T

λ

L

ln 

#

  1 

  1 

#C 1%.24% %.13&1111 327.24% 1&4.02%


4% 222.2


2

x A     x B     2

x B     x A   

9amma 0.% 1.1277%4$%71 0.% 1.21&12141

4% 242.%




5apor psia -8 0.% &0.&3171%&73 0.% 17.7&72104$17

5apor psia -s+p+esto 9amma 0.% 4.&02&3$%4 0.14&3402& 1.&&0$%%%%$2 0.% 2%.$%7714%02 0.%3&%$74 1.024%&3%1$7

;N"< =' B;B;>A K ?K 1.%207$43$ 0.7&03$71$% 0.401%74% 0.24007724 1.00047%$1$ *0.00047%$1$

;N"< =' 
-

! 0.% 0.7&03$71$% 0.% 0.2400772% 1 1.00047%$2

!

0.% 0.1&0107474 0.% 0.403&$%2 1 1.0014442&

"#

32

 lmol@ 8 100 (A)8 0.%  psia8 4% " #8 220 5 A %.4%$33%0%7 5 B 17.03074231 Hamma A 1.1277%4$%71 Hamma B 1.21&12141 s+ma(?K) 0.$&2&%3$34 en caso de 5 s+ma(K) 1.427&37$$& No +sar la ta ,5 A Bt+l mol 20&1.3%$%2$$ ,5 B Bt+lmol 1%17.2&%22 lamda A Bt+l mol 1%&2$.%3&$&7 lamda B Bt+lmol 17723.1$03&& ,5 mecla 17$.31402& ,l mecla *147.04$&4 , *147.04$&4

Condiciones del separador /S<"/C<  psia 8 4% " # 8 23% 5 9amma etanol(A) 7%.017$077 0.30&73 1.0$$4$&04 A9+a(B) 22.%$%447& 0.2%&7133 1.2%040301& D Bt+@ por sorecalentado la de criterio

124&43.%

Condiciones del separador A=/ABA"/C<  psia 8 1 " # 8 2.1$ 5 9amma etanol(A) 2.44133$% 0.0$&1$074 1.27&23301& A9+a(B) 0.%4&%$&43 0.$030$2& 1.0111704$7

racc E K ?K K 1.32$3%&% 0.$1&4&72 0.2727&4% 0.&27%372 0.313$2&& 0.7$&3&34 1.2303$4& 1.0&$1%02$

0.74327122 N+e5o E

9 9F2 ! 0.2%72222&%& 0.13232&%$ 0.30140$ 0.%&&03&3& *0.2%72222&& 0.13232&%$ 0.&$11%$1 0.433$&3&4 H1 *2.40&4'*010 *0.2&4&%31 1 1

racc E

K ?K K %.1$00%47 2.%$$00274 0.0$&1$074 0.%%270&32 0.27&3%31& 0.$04&3$%& 2.7%3%%$ 1.0003031



0.74327122

1 N+e5o E

0.$$72$&2

9 9F2 ! 0.4030$2%& 0.32&1233 0.0$&1$074 *0.404&3$%&4 0.3274&&3% 0.$04&3$%& H1 *0.0003030% *0.&%3%$01$ 1.0003031

"

E

0.% 0.% 1

D

+r+Ga rocio

10

14&.42 1&7.77

" para D80 E para D8 0 *%$43.%%% 14&.4$3203 0.0034273 1 1727%13.&

+r+Ga rocio

%

117.3% 13.&

0 *%%32&.$03 1 1&$$%$7.0&

+r+Ga rocio

1%

1&% 1&.1%

0 24&11.2$$ 1&4.&$7%23 *0.014301%1 1 174%4$$.2$

+r+Ga rocio

1

&0.4 2.1$

0 *1%$3$.204 &2.323%&44 0.02773$ 1 1&4&1&0.2$

11.0214 0.031%2&71

H1

*0.0&$3& 0.2% *0.01%& 0.2$0472 *0.011& 0.32&$&% *0.004& 0.34241 *0.002% 0.3%14%1 *0.0011 0.3%%&1307

,5 amda ,l 2240.$740 1%%&0.3$1% *1331$.4174707 1&3$.72$1% 17&3%.443& *1%$$%.7144447 1$0.0%%&4 *1%1&$.23&22%4 'ntalpia mecla 'ntalpia mecla

,5 amda ,l %17.14701$ 1&47$.1 *1%$&2.733$$3 402.37&4%1 107.$&24 *140%.%%$337 4%$.7&173% *11%.44$ 'ntalpia mecla 'ntalpia mecla H2 D

1.0303334& 1%34&1.13747

E 0.& 0.432$ 0.4%41&223 0.43073&$2 0.4211$217 0.41%1023

0.02

0.01

0 0.2% *0.01

*0.02

0.3

0.3%

0.4

0.4%

0.%

0.%%

0.&


Sistema: Cloroormo (A) A1 %.$40%7 A2 %2$.3% A3 3$3.07% c psia 7$3.&


Constantes de 5an aar

a1 a2 a3 a4 a%

1.4400000'601 1.24%00000'*02 *&.4$%00000'*0& 1.2%$00000'*0$ 0.00000000'600

α β

etanol (B) 7.%13334 &4&.101 3$&.2&%2 11%3.&

$.010000'600 .430&4000'*03 &.&&$1$000'*0& *.20$000'*0$ 2.%00&4000'*12

0.$3%& 1.&

 P v A = A1 − 2  A3 + T  Pc ideal = a1 + a2T + a3T 2 + a4T 3 + a5T 4 C pv

= RT 2

T


ln 



Mezcla

ln 

L



= ∑ yi H H L = ∑ xi ( H viideal − λ i ) R(T + 459.6)2 A2 λ = ( A3 + T ) 2 H v

∂ ln( P v ) ∂T

λ


L

ln 

B

ideal vi

100 Kpa 7&0 mm ,9 14&$& psi 10132% ar 10132% Kpa

A

#

  1     1  

#C 1%.24% %.13&1111 327.24% 1&4.02%


30 1&.%20% 7%.44722


2

 x A     x B    2

 x B     x A  

9amma 0.% 1.%1$300%2& 0.% 1.23042$10

%$30 1&4.31 73.%0%%%& Comp+esto  A B



5apor psia -8 0.3 23.3&0&$0002 0.7 22.4%44302&

5apor psia -s+p+esto 0.3 21.7001131 0.7 20.&073%23321

9amma 0.3 1.$44$70%3 0.7 1.0%$&$3$%&

;N"< =' B;B;>A K ?K 1.140&0101 0.3%%210302 0.$21117402 0.&4472112 1.0000002114 *2.113$4277&33'*007

;N"< =' 
-

! 0.3 0.3%%2103 0.7 0.&447211 1 1.000000211

!

0.3 0.21700077 0.7 0.$&1&%32&4 1 1.103%3341

"#

32

 lmol@ 8 100 (A)8 0.%  psia8 4% " #8 220 5 A %1.%733&4771 5 B %.4%$33%0%7 Hamma A 1.%1$300%2& Hamma B 1.23042$10$% s+ma(?K) 1.&&$&2&&04 en caso de 5 s+ma(K) 0.&0002&&2& No +sar la ta ,5 A Bt+l mol 30&2.%$0&134 ,5 B Bt+lmol 20&&.1&41041 lamda A Bt+l mol 12$14.&47$7 lamda B Bt+lmol 1%&2$.%3&$&7 ,5 mecla 2%&4.3773% ,l mecla *11707.71%12 , *147.04$&4

Condiciones del separador /S<"/C<  psia 8 30 " # 8 1&%.2% 5 9amma etanol(A) 22.1307% 0.3%$77304 1.7720&%1%&2 A9+a(B) 21.00$2&% 0.&4022&$& 1.0$37&747% D Bt+@ por sorecalentado la de criterio

$4302.1$3

Condiciones del separador A=/ABA"/C<  psia 8 1 " # 8 &2 5 9amma etanol(A) 2.%7$3320& 0.437313& 1.&200231%7 A9+a(B) 1.%&777&3 0.%&2&1&4 1.1%723$323

0.1$03$%$& &2.0012&32

0.142 &&

racc E K ?K K 1.30723$$7 0.&%3&1$$$ 0.324%24 0.7&%$7%0& 0.32$7%3 0.&%27&277 1.03&&07%2 1.03%2401

0.%0$13203 N+e5o E 9

9F2 ! 0.13240342 0.03%2$311 0.4323&&73 0.%&%20707 *0.13240342 0.03%2$311 0.%&7&3327 0.4347$2$3 2.0$104'*010 *0.070%&23 1 1 G1

racc E

K ?K K 4.1$$1%%7 2.0$$%7$2 0.11$07147 1.142$177 0.$0714%$ 0.27%%$&3 3.00&72%17 0.3$4&&111

G1'

0.17 N+e5o E

0.7%0047&%

9 9F2 ! 1.03&0$2$344 2.14&$7714 0.323&42 1.3%$$%714 0.3%7&317%3 0.2%%1013 0.43$201%1 0.7$&3$&$ 1.3$373110$7 *2.4027727 0.7&30&%71 2.1%&7$&2 G1



0.%0$13203

"

G1'

E

D

" para D80 E para D8 *%2%.$77 14&.4%&4& 0.0003043 17274$4

+r+Ga rocio

10

14&.4% 1&7.7&

0 1

+r+Ga rocio

%

117.3% 13.&

0 *%%32&.$03 11.02143 0.031%2&7 1 1&$$%.3

+r+Ga rocio

1

&0.4 2.1

0 1

*1%$3$.2 &2.31%70 0.021%1 1&4&07&

"

,5 amda ,l 2131.%07 131&3.774 *11032.1$4072 142&.004 1%$14.72$ *144.0&44$ 12%.1%0%7 *12$$3.&1310& 'ntalpia mecla 'ntalpia mecla

E 1&% 0.440724% 1&%.2% 0.%0$13203 1&%.% 0.%74%%% 1&& 0.70717$&2 1&&.% 0.42$007& 1&7 0.$213&

"60.01# 8

&2.01

,5 amda ,l 5 4&2.31373 1307.4111 *1334%.0$73374 2.%7$$$0$2 0.323&42 30&.377017 1&&%0.0702 *1&343.&$31403 1.%&2%$23 0.&7&13% 72.&02$4 *11%00.173$$7$ 0.3&7$&4 0.311273& 'ntalpia mecla 'ntalpia mecla G2 G2'

D

i8

%4$02$.14717&

>acoiano *2.4027727 %.&$%471 0.311273& *22.177&1&

"

E

*0.2737304013

71. &7.3& &7.2401 &7.243 &7.347& &7.2& && && && &4 &2

H1 0.&1$ 0.47&& 0.1$%&3 0.2013$ 0.3$2&27 0.12 0.12$ 0.14 0.17 0.17 0.17

*0.00 *0.02 0.140 0.1377 0.031217 0.17%$4 0.1332$ 0.1203$ 0.113% 0.04$417 *0.0127

D D 441.12&1032 44112.&1032 $43.021$32& $4302.1$32& 103$%.$%1%41 103$%$%.1%41 1234%.4$317% 1234%4$.317% 143%3.1&%0%1 143%31&.%0%1 1&43&.137&7 1&43&13.7&7

T vs. V/F 1.2 1 0.8 0.6 0.4 0.2 0 164.5

165

165.5

166

166.5

167

! 9amma K 9 ,5 1.3%$$%713%& 1.41$%2&227 4.7%222104 1.14%4%2227 4&2.4&$&%&3 0.7$&3$&%% 1.071$$%$21 1.&11&7%$ 0.30%237721 30&.40%117 1.4%0&$$%&$ 1.3$373110$7 %.&$%471% 3%&.$$$114 G1(T+DT)

>acoiano *1 *0.4%&7&0$1& *0.11730$72 *0.017117%014 *0.04$4&&&

H2 0.%%07 0.371&2 0.07& 0.031$ 0.243 *0.00300$ *0.00$&& 0.003277 0.034 0.02%707 0.013214

0.3033344$ 0.13%014244 0.02%&00&4 0.02%$2713 0.041&&3&& 0.030$&3$377 0.017&3%&21 0.01&4047243 0.0143&2$&04 0.003102$7 0.000337$32

G1(T)

H 1.3$373110$7 0.3&7$&477

G1'

*0.&7$&%30$ *0.042107&$$

T vs. Q/F 18000 16000 14000 12000 10000 8000 6000 4000 2000 167.5

0 164.5

165

165.5

166

amda ,l 1307.3337 *13344.&407 1&&4$.$1$ *1&343.%0141 *1%372.3%013 0.14701$&& 0.3&7$&4 *22.177&1& G2(T+DT)

t8

0.03 N+e5os V/F= 0.1$03

3 T= &2.0012&3231

G2(T)

G2'

166.5

167

167.5

S'AAC/N AS, Constantes d presión en 

Sistema: Cloroormo (A) A1 %.$40%7 A2 %2$.3% A3 3$3.07% c psia 7$3.&

Calor especi " en # Cp e

a1 a2 a3 a4 a%

Constantes d α β

1.4400000'601 1.24%00000'*02 *&.4$%00000'*0& 1.2%$00000'*0$ 0.00000000'600 0.$3%& 1.&

"#

etanol (B) 7.%13334 &4&.101 3$&.2&%2 11%3.&

$.010000'600 .430&4000'*03 &.&&$1$000'*0& *.20$000'*0$ 2.%00&4000'*12

 lmol@ 8 (A)8  psia8 " #8 5 A 5 B Hamma A Hamma B s+ma(?K) s+ma(K) ,5 A Bt+l mol ,5 B Bt+lmol lamda A Bt+l mol lamda B Bt+lmol ,5 mecla ,l mecla ,

SeparaciónFlash Mezcla Cloroformo Metanol

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