Akzo Nobel General Catalog

SURFACE CHEMISTRY

G E N E R A L C AT AT A L O G

CONTENTS I N T R O D UC UC T I O N . . . . . . . . . . . . . . . . 1 P R O D U CT C T A P P L I CA C A TI TI O N S

. . . . . . . . . .2

F AT AT T Y A MI M I N E C H EM E M I S T RY R Y O V ER ER V I E W

. .3

L I S T I N G O F N I T R O G E N D E R I VA VA T I V E S . . 1 0 AMINES Armeen® Amines

A N I O N I C C H E M I S T R Y O V E R V I E W

. . . . . .22

Primary Amines Dialkyl Secondary Amines

L I S T I N G O F A N IO I O N I C S U R FA F A C TA TA N TS TS

Alkyl Dimethyl Tertiary Tertiary Amines

SULFONIC ACIDS AND SULFONATES

Dialkyl Methyl Tertiary Amines

Petro® Alkyl Naphthalene Sulfonates

Trialkyl Tertiary Amines

Witconate™ Alpha Olefin Sulfonates

Duomeen® N-Alkyl Propane Diamines

Witconate™ Alkylbenzene Sulfonates

Triameen® and Tetrameen® N-Alkyl Higher Amines

Witconate™ Aryl/Alkyl Aryl Sulfonic Acids

Ethomeen® Ethoxylated Amines Ethoduomeen® Ethoxylated Diamines Propomeen® Propoxylated Amines AMINE SALTS SALTS Armac® Amine Acetates Acetates

. . . .24

SULFATES Witcolate™ Alkyl/Alkyl Ether/Alkyl Aryl Ether Sulfates PHOSPHATE PHOSPHA TE ESTERS Phospholan™ Alcohol Phosphates Phospholan™ Alcohol Ethoxylate Phosphates

QUATERNARY AMMONIUM SAL SALTS TS

Phospholan™ Phenol/Alkyl Phenol Ethoxylate Phosphates

Arquad® Quaternary Quaternary Salts

Phospholan™ Alkyl Amine Phosphate

Alkyltrimethyl Quaternary Quaternary Salts Dialkyldimethyl Quaternary Salts Trialkylmethyl Quaternary Salts Benzylalkyl Quaternary Salts Ethoquad® Ethoxylated Quaternary Salts

CARBOXYLATES Emcol® Ethoxylated Carboxylate SULFOSUCCINATES Lankropol™ Sulfosuccinat Sulfosuccinates es

Duoquad® Diquaternary Salts AMINE OXIDES OXIDES Aromox®® Amine Oxides Aromox Alkyl Dimethyl Amine Oxides Bis(2-hydroxethyl) Bis(2-hydro xethyl) Alkyl Amine Oxides

N O N I O NI N I C C H E MI M I S T R Y O V E RV RV I E W

L I S T I N G O F N ON O N I O N I C S U R FA F A C TA TA N T S Emulpon™ Castor Oil Ethoxylates Ethofat® Ethoxylated Fatty Acids

Armid® Amides

Ethylan™ Linear and Branched Alcohol Alkoxy Alkoxylates lates

Ethomid® Ethoxylated Amides

Witconol™ Alkyl Phenol Alkoxy Alkoxylates lates

Arneel® OD

. . .36

Amadol® Alkanolamides Alkanolamides

AMIDES

NITRILES

. . . . .34

Witconol™ Polyols/Polyol Esters Witconol™ Resin Alkoxylates

CORROSION INHIBITORS

A P P E N D I C E S . . . . . . . . . . . . . . . . . . . 4 2

Armohib® Products Products

Solubility of Armeen Amines Solubility of Ethoxylated Products Solubility of Arquad Quaternary Ammonium Compounds CUSTOMER SERVICE & SUPPORT . . . . . . .47 T R A D E M A RK R K E D P R O D U C TS TS N O T L I ST ST E D . . . 4 8

INTRODUCTION

This catalog contains information about specialty chemicals offered by Akzo Nobel Surface Chemistry LLC. Among these are fatty amines, amine salts, quaternary ammonium compounds, amine oxides and amides. Naphthalene and alpha olefin sulfonates, alkyl and alkyl ether sulfates, alcohol and phenol-derived alkoxylates, alkoxylates, polyols, phosphate esters, sulfosuccinates and alkanolamides are also offered. The maj majorit orityy of these compounds compounds are

surface active agents ,

used in hundreds of commercial applications.

Our product portfolio, with the acquisition of the Industrial Specialties division of Crompton Corporation, has expanded to include nitrogen-based cationic, anionic and nonionic surfactants. We now offer the formulator and chemical investigator a robust portfolio of surface-active agents and intermediates from which to choose. Our chemical technology expertise, efficient manufacturing facilities, research and development support and commitment to providing quality products help fulfill our promise to be your

responsive partner in rheology and surface

chemistry wherever you are.

This catalog lists our product range, specifications, typical properties and applications. Minimum order quantities may be required for some of the chemicals in this catalog. Should you require additional

information or wish to inquire

about the availability of related products, please contact our Customer Service or Technical Service personnel at 1-800-906-9977, email [email protected] or via our website at http://surface.a http://surface.akzonobelusa.com. kzonobelusa.com. We will be pleased to help you.

INTRODUCTION

1

RECOMMENDED PRODUCTS Many applications are made possible using the cationic, anionic and nonionic products presented in this catalog. Their versatility is illustrated by the following list of industrial, detergent and personal care applications with examples of Akzo Nobel products to be used. APPLICATION APPLICA TION

NITROGEN DERIVATIVE DERIVATIVES S

ANIONICS

Agricultural Chemicals Agricultural • inert ingredients (under Title 40 CFR 180.1001) • adjuvants • emulsifiers • anticaking • dispersing

Ethomeen, Arquad, Ethoquad, Armeen Armac chemicals

Petro chemicals

Antistatic Agents Agents • textiles • polymers • electronics • paper • electrostatic spraying

Arquad, Ethoquad, Ethomeen, Armac chemicals

Phospholan chemicals

Bitumen Chemicals

Arquad,, Duomeen, Duoquad chemicals Arquad

Corrosion Inhibitors • acid • petroleum

• metal working • water treatment

Armeen, Arquad, Ethomeen, Duomeen chemicals Armohib® chemicals

Demulsifiers • paper • petroleum

• pharmaceuticals

Arquad, Ethomeen, Propomeen chemicals

Detergents • fa fab bric so soft ften ener erss • cleaners

• th thic ickkene nerrs


Amadol chemicals

Arqua uad d, Eth tho oquad ad,, Aromo mox, x, Armosoft chemicals

Wit itco collat atee, Witco connat atee, Phospholan chemicals

Wit itco connol, Eth thyl ylan a n ch chem emic icaals

Aromox chemicals

Witcolate, Witconate chemicals

Witconol, Ethylan, Amadol chemicals

• paints

Arquad, Armeen, Armac, Duomeen, Duomac, Triameen chemicals

Petro, Phospholan, Lankropol chemicals

Witconol, Ethylan chemicals

• wax polish • solvent c leaners • triglycerides

Arquad, Ethomeen, Duoquad, Ethoquad, Ethomid chemicals


Witconol, Ethylan, Amadol chemicals

Arquad, Aromox chemicals

Witconic, Witcolate, Witconate, Petro, Phospholan chemicals

Dishwashing Dishwashin g Liquids Dispersing Agents • pigments • inks Emulsifiers • oil • leather treatment • silicones Foaming Agents Metal Working • cutting fluids • lubricants

• metal cleaning

Armeen, Ethomeen, Duomeen chemicals


Mineral Processing • anticaking agents • flocculating aids

• flotation agents

Armeen, Armac, Lilamin®, Armoflo® chemicals

Petro chemicals

Organoclays

Arquad chemicals

Paper Manufacture • deinking • printing aids • coatings • absorbency • softening/debonding/pulping

Armid, Ethofat, Ethomeen chemicals

Lankropol, Petro, Phospholan chemicals

Arquad Arqu ad,, Et Etho hoqu quad ad ch chem emic ical als, s, Armeen, Ethomeen chemicals, Ampholak, Aromox chemicals

Witcol Witc olat atee, Wi Witc tcon onat atee, La Lank nkro ropo pol, l, Phospholan chemicals

Ethoquad, Aromox chemicals, Armac, Duomeen, Arquad chemicals, Arquad chemicals, Duomac, Arquad, Armeen chemicals

Petro, Witconate chemicals, Witconate chemicals

Personal Care/Cosmetics • ha hair ir co cond ndit itio ione ners rs • re resi sinn ne neut utra ralilize zers rs • shampoo cosurfactants • thickeners Petroleum Production • thickened fracturing fluids • diesel oil emulsions • antiswelling agents • corrosion inhibition/water • demulsifiers • paraffin control Petroleum Refined Products • corrosion inhibition/lubricants Pigment Producing Additives • filler dispersants • stabilizer intermediates • mold release agents

2

NONIONICS

Amad Am adol ol ch chem emic ical alss

Armeen, Ethomeen, Aromox, Armid, Duomeen, Arquad chemicals Duomeen, Triameen chemicals Arquad, Ethomeen chemicals Armeen chemicals Armid, Arneel chemicals

Petro, Witconate chemicals

Sugar Refining Additives

Arquad chemicals

Textile Auxiliaries • dyeing assistants • lubricants/scrooping • scouring

Arquad, Armeen, Ethomeen, Ethoquad chemicals, Ethomid chemicals

Petro chemicals, Witconic, Witconate, Witcolate, Phospholan, Lankropol, Emcol chemicals

Amadol chemicals Witconol chemicals

Vehicle Veh icle Cleaning Formulations Formulations

Arquad,, Ethomeen chemicals Arquad

Witcola Wit colate te,, Witconat tconate, e, Pe Petro tro che chemic micals als

Witconol chemicals chemicals

Water Treatment Chemicals • filming amines • flocculants • corrosion inhibitors

Armeen, Armac chemicals Arquad chemicals Arquad, Duomeen chemicals

FATTY AMINE CHEMISTRY OVERVIEW

FAT T Y A M I N E

CHEM ISTRY OVERVIEW


3

Finished Products Kortacid® Nouracid®

Armid

Amidation

Raw Materials Animal Based Fats Vegetable B ased Oils

Distillation

Fat/Oil Hydrolysis

Nitrilation

Esterification

Quaternization Armeen Duomeen Triameen Redicote® Berol®

Hydrogenation

Glycerine

Arquad Duoquad Ethoquad Armosoft® Redicote

Armac Duomac

Neutralization

Ethomeen Ethomid Ethofat Redicote Berol Elfacos® Bermodol®

Alkoxylation

Cellulose Alcohols Ethylene Glucose

Aromox Ethylene Oxide

Oxidation

Bermocoll® Ampholak® Berol

Alkylation

FIGURE 1. AKZO NOBEL SURFACE CHEMISTRY PROCESS OVERVIEW

Introduction This review describes the chemistry of fatty amines and related nitrogen derivatives offered by Akzo Nobel Surface Chemistry LLC. These products are produced at three plants in North America. This output output,, when combined combined with the production production of our European, Brazilian and Japanese plants, makes Akzo Nobel the world's leading supplier of fatty amines and their derivatives. The combined research programs of our group are extensive and ensure that Akzo Nobel will maintain its foremost position in fatty amine technology. The basic building blocks of the products are the primary, secondary and tertiary amines and diamines described in this brochure. These are based on alkyl groups ranging from C 8 to C22, with C 12 to C18 most predominant. In most cases, the products are derived from natural feedstocks. Table 1 displays the alkyl percent distributions for the various fattyalkyl groups used in the manufacture of our products. By protonation, alkylation or ethoxylation, the product group is extended in order to form a range of surfactants offering a wide spectrum of melting point, solubility and cationic activity. The range of derivatives is sufficiently extensive to meet the needs of almost all Cationic Surfactan Surfactantt users • as chemical intermediates • as essential processing aids, and • as functional ingredients in many formulations. formulations. Figure 1 gives an overview of the interconnecting process steps to produce these derivatives. Our major trademarks are given for the finished products.

swap in hi res

n o i t i s o p l y m k l o A C

l y c e d o d

l y c e d a x e h

l y c e d a t c o

l y e l o

o c o c

a y o s

0.5 1.5

6 7 51 19

0.5 1.0

9

16

2

15

6

1.0 49.5 13

w o l l a t

d d e t e t a a n n d e e e g g e s o w o r l r e o d d y l y p a h t h a r

SATURATED C8 C10 C1 0 C12 C1 2 C14 C1 4 C15 C1 5 C16 C1 6 C17 C1 7 C18 C1 8 C20 C2 0 C22 C2 2

0.5 99 0.5

0.5 97 2.5

2.5

4 0.5 96.5 8-14 0.5

3 0.5 29 1 20

3.5 0.5 31 1 61

0.5 2 44

3

UNSATURATED

Many applications are made possible using fattyalkyl amine surfactants because of one or more of the three functions described in the next section. Their versatility can be illustrated by the following list of industrial, detergent and personal care applications with examples of Akzo Nobel products used: (see chart on page 2)

C14’ C16’ C18’ C18”

0.5 4 0.5 70-74 5

* Composition is that of base acids from which amines were derived.

TABLE 1.

APPROXIMATE ALKYL PERCENT DISTRIBUTION FOR FATTYALKYL AMINES

4


0.5 3.5 38 8 50

orientation in water

orientation in non-polar solvent

orientation at air/water interface

orientation at air/oil i nterfa nterface ce

F I G U R E 2 . O R I E N T AT A T I O N O F S U R F A C TA TA N T IN SEVERAL SYSTEMS

Functional Properties of Fatty Amines and Derivatives The molecular structure of fatty amines and derivatives is characterized by one or more C8 to C22 aliphatic alkyl groups, R, with one or more amine or quaternary ammonium functionalities: Because of the number of carbon atoms in the alkyl group, this group

A. Surface Activity

B. Substantivity Substantivity

C. Reactivity is strongly hydrophobic hydrophobic,, that is, it is repelled by water. On the other hand, the nitrogen atom is hydrophilic or water loving, particularly when it is protonated, alkoxylated or quaternized. Substances which contain groups in the same molecule with such opposite functions are referred to as amphiphilic amphiphilic.. When dissolved or dispersed in water or non-aqueous solvents, solvents, one portion of the molecule is strongly repelled by its surrounding solvent. Because of this repelling force, these molecules tend to orient themselves at surfaces and interfaces, or form micelles (aggregates of oriented molecules), as shown in Figure 2. 2. Such orientation/aggregation phenomena are called surface activity and materials that exhibit it are surface active agents, agents, often referred to as surfactants surfactants.. Surfactants are classified by the nature of their hydrophilic moiety, moiety, which carries a negative ionic charge in anionic surfactant surfactantss, or a positive ionic charge in cationic surfactants. surfactants. The hydrophilic moiety in non-ionic surfactant surfactantss is usually a neutral polyoxyalkylene group. In cationic surfactants the positive charge may be derived from several chemical functional groups, such as sulphoxonium, oxonium, phosphonium, iodonium, etc. Commercially Commercially,, however, however, it is usually associated with a nitrogen atom contained in an amine or quaternary ammonium group. The cationic nature of fatty amines and derivatives has given rise to a wide variety of uses in many applications. These functions may be recognized as being derived from three basic properties:

1. The surface active properties of many fatty amines and derivatives relate to the amphiphilic molecular structure, which leads to orientation at i nterfaces (see figure 2). As a result, result, interfacial interfacial tension tension is affecte affected d and a number of surfactant functions can be seen: • emulsification • wetting

• foaming • thickening

2. The term substantivity substantivity refers refers to the adsorptive properties of cationic surfactants and related nitrogen derivatives. Adsorption, particularly onto solid surfaces, results from the attraction between the positive charge on the nitrogen atom and the negative charge characteristic of most surfaces. Consequently, Consequently, substantivity leads to surface modification and to the following functions: • softening • anti-static properties • lubrication

• corrosion inhibition • adhesion • hydrophobation

3. Reactive properties of cationic surfactants can be identified in several uses, in particular when complexes are formed with anionic species on a molecular level, governed by stoichiometry stoichiometry.. Frequently, such complexes show very low solubility in water, so that the following functions can be found in such areas as water treatment, sugar refining, and the production of organo clays: • flocculation • decolorization

• ion exchange


5

Selection Criteria for Fatty Amines and Derivatives The following properties of fatty amines and derivatives may be used as guideposts in their selection in a variety of applications.

Solubility Solubility of surfactants is a primary criterion for their selection. Tables 1, 2 and 3 in the Appendices summarize the solubility behavior in various solvents for fatty amines and their ethoxylated and quaternary derivatives, respectively. respectively. A. Solubility in water Alkylamines of C8-C22 chain length are only slightly protonated at neutral pH and thus are insoluble in water:

In acidic media, protonation is proportional to the strength of the protonating acid and the resulting amine salt is much more soluble:

pH, for example. The increased aqueous solubility associated with protonation comes with a considerable increase in positive charge. This is also achievable by alkylation of the nitrogen atom, forming quaternary ammonium compounds. Monoalkyl trimethyl ammonium chlorides are soluble in water up to a concentration range of 30% (for C18) to 40% (for C12). Above this concentration level, the surfactant forms a liquid crystalline phase. For dialkyl dimethyl ammonium chlorides, literature states that this solubility limit is found at much lower levels, as low as 0.001% for Arquad® 2HT . di(hydrogenated tallowalkyl) ammonium chloride, Arquad® This quaternary salt, however however,, can form stable dispersions as a result of molecular aggregation into vesicles. These consist of bilayers spaced by aqueous layers arranged in concentric circles. Water solubility also is increased by the introduction introduction of neutral hydrophilic groups such as polyoxyethylene groups, in which case there is no increase in charge on the nitrogen atoms. Ethoxylation of aliphatic amines yields the Ethomeen® the Ethomeen® series. series. Solubility of Ethomeen compounds is dependent upon the degree of ethoxylation (see Table Table 2 in Appendices). Ethomeen Appendices). Ethomeen C/12 C/12,, for example,, contains two oxyethylene units per molecule and is example insoluble in water water,, whereas Ethomeen whereas Ethomeen C/25 contains fifteen oxyethylene units per molecule and is water soluble. Factors which affect water solubility are summarized inTable in Table 2. 2.

In general, one protonated amino group is sufficiently hydrophilic to solubilize an alkyl chain containing up to twelve methylene groups. Solubilization Solubilization of an octadecyl (C18) alkyl group requires T at low two protonated amino groups as provided in Duomeen® in Duomeen® T at

WATER SOLUBILITY INCREASES: a. influence of alkyl chain • by decrease in chain length (or molecular mass) • by increase in unsaturation b. influence of nitrogen moiety • by increase in number of functional groups • by increase in degree of ethoxylation • by formation of salts • by quaternization c. influence of medium • by decreasing pH T A B L E 2 . F A C TO TO R S A F F E C T I N G WA WA T E R S O L U B I L I T Y

6


B. Solubility in non-aqueous media Fatty amines and derivatives generally show appreciable solubilities in polar organic solvents such as methanol, ethanol and isopropanol, and in non-polar solvents. In hydrocarbons, solubility depends on the alkyl chain length, on the degree of unsaturation and on the cationic character of the nitrogen moiety. C. Solubility in two-phase systems When a surfactant is dissolved in a two-phase system system consisting of water and, for example, a hydrocarbon such as n-heptane, it distributes itself in the two phases. The relative solubility is dependent on the nature of the surfactant and on the nature of the system, and can be expressed by the so-called partition coefficient. The effect of pH on partitioning may be dramatic as in the case of amines that can be protonated and consequently have a preference for the aqueous phase at low pH. This is illustrated in Figure 3, 3, showing the partition of Armeen® Armeen® C C (a (a primary amine) between n-heptane and water as a function of the pH of the aqueous phase.

Emulsions may be classified as oil in water, in which hydrophobic material is dispersed in water, or as water in oil, in which water is dispersed in hydrophobic material. Formation of oil in water (O/W) emulsions is favored by emulsifiers having a high HLB value. Thus, ethoxylated amines such as Ethomeen as Ethomeen C/15 and and Ethomeen Ethomeen C/25 are used in applications where O/W emulsions are desired. In similar applications but at high pH, the corresponding Ethoquad® corresponding Ethoquad® ethoxylated quaternary salt might be preferred, due to increased solubility derived from the quaternized amine group. For water in oil (W/O) emulsions, low HLB surfactants are more effective. Lower ethoxylates of higher molecular weight alkylamines would be considered for such applications, including Ethomeen including Ethomeen S/12 and Ethomeen and Ethomeen T/12. T/12.

Hydrophile-Lipophile Balance The orientation of surfactant molecules at a water/solvent interface, interface, as shown in Figur Figure e 2, leads to important performance properties of the surfactant such as emulsification. A classification of surfactants that can help in selecting an appropriate emulsifier is the Hydrophile-Lipophile Hydrophile-Lipop hile Balance (HLB) value . The HLB value indicates where the relative hydrophilicity of a particular surfactant lies. Higher HLB values correspond to stronger hydrophilic character of the surfactant. Akzo Nobel Surface Chemistry uses the Davies scale of 0-40 to classify its surfactants. These values are found in the product description section of this catalog.

F I G U RE R E 3. 3.

P A RT R T I TI T I O N O F C O C OA OA MI N E [ AR ME E N C ] I N N - H E P T A N E / W AT AT E R .


7

Surface tension Surfactants exhibit both adsorption phenomena and the ability to form micelles. Due to adsorption at the air/water interface, a decrease of surface tension is observed with increasing surfactant concentration (see Figure 4). 4). At a rather distinct surfactant concentration, the Critical Micelle Concentration (CMC), the formation of micelles starts and thereafter the free surfactant concentration remains constant, as does the surface tension,γ c.

Table 3 shows typical values of the surface tension for representative represent ative fatty amine derivatives.

SURFACTANT

γ c DYNES/CM (WATER, 20ºC)

Armeen 12D (at pH 4, neutralized with HCl)

27

Aromox C/12-W

31

Arquad 16-50

34

Ethomeen S/12

32

Ethomeen T/15

33

Ethomeen C/25

41

Ethoquad 18/25

50

TABLE 3. TYPICAL SURFACE TENSION VALUES

Other surfactant characteristics

FIGURE 4. SURFACE TENSION AS A FUNCTION OF SURFACTANT CONCENTRATION

In order to select the appropriate fatty amine or derivative, the determination of the following surface active properties can be helpful: • foaming characteristics (e.g., according to Ross-Miles) • Kraft point • Cloud point

Other physical and chemical properties During processing, properties such as melting point, boiling point and flash point are important. Some properties are affected by the degree of unsaturation; for example, the melting point increases with increasing removal of double bonds (by hydrogenation) in the alkyl chain. Solubility is also influenced. Unsaturation may play a role in applications where chemical reactivity has an influence.

8


Representative Examples of Nitrogen Derivatives Offered by Akzo Nobel

CHEMICAL TYPE

TRADE NAME

FORMULA

CHEMICAL TYPE

TRADE NAME

FORMULA


9

NITROGEN DERIVATIVES

10


A M I N E S

Primary Amines SPECIFICATIONS

PRODUCT

COMMON NA NAME*

TSCA NU NUMBER

% , e n i m A y r a m i r P

r e b m u N e n i m A

r o l o C r e n d r a G

Min.

Min.

Max.

98

297

TYPICAL PROPERTIES

% e r u t s i o M

* * t h g i e W t n e l a v i u q E


C º , t n i o P g n i t l e M


e l a c S s e i v a D B L H

e u l a V e n i d o I

PRIMARY AMINES

ARMEEN 12D***

Dodecylamine

ARMEEN 16D

Hexadecylamine

143-27-1

98

228

1

0.5

243

48

99

231

1

8.6

ARMEEN 18D

Octadecylamine

124-30-1

98

204

1

0.5

270

55

99

208

2

8

ARMEEN C

Cocoalkylamines

61788-46-3

97

272

3

0.5

204

16

98

275

9

10.3

ARMEEN CD

Cocoalkylamines

61788-46-3

98

275

1

0.5

200

16

100

281

9

10.3

ARMEEN HR

Hydrogenated 125328-43-0

93

178

12

1.0

3.5

48

95

181

6

6

61788-45-2

97

207

3

0.5

271

55

98

207

3

8.2

tallowalkylamines

61788-45-2

98

209

1

0.5

263

55

100

213

3

8.2

ARMEEN O

Oleylamine

112-90-3

97

205

3

0.5

266

24

98

211

89

8

ARMEEN OD

Oleylamine

112-90-3

98

207

1

0.5

265

23

99

212

89

8

ARMEEN OL

Oleylamine

112-90-3

95

202

4

0.5

273

20

97

206

89

8

ARMEEN OLD

Oleylamine

112-90-3

98

207

1

0.5

265

19

99

212

90

8

ARMEEN R

Rapeseedalkylamines

125328-46-3

95

180

12

1.5

306

18

97

183

83

6

ARMEEN S

Soyaalkylamines

61790-18-9

97

206

4

0.5

273

29

97

206

92

8

ARMEEN SD

Soyaalkylamines

61790-18-9

98

208

2

0.5

264

29

100

213

92

8

ARMEEN T

Tallowalkylamines

61790-33-8

97

208

3

0.5

267

40

98

210

46

8.2

ARMEEN TD

Tallowalkylamines

61790-33-8

98

210

1

0.5

262

40

100

214

46

8.2

rapeseedalkylamines ARMEEN HT

1

0.5

186

24

99.5

0.5

10.7

Hydrogenated

R 2 NH Secondary Amines

Secondary Amines SPECIFICATIONS****

PRODUCT

303

Hydrogenated tallowalkylamines

ARMEEN HTD

124-22-1

COMMON NA NAME*

TSCA NU NUMBER

y r a d n o c e S t n e r a p p A



Min.

Max.

Max.

TYPICAL PROPERTIES


* * t h g i e W t n e l a v i u q E

Max.

Max.


% , e n i m A y r a d n o c e S




SECONDARY AMINES

ARMEEN 2C

Dicocoalkylamines

61789-76-2

93

6

155

2

401

43

94

145

8

4.2

ARMEEN 2HT

Ditallowalkylamines

61789-79-5

90

5

116

2

510

62

91

112

3

1

* **

Common Com mon name name may may be be differ different ent fro from m the the name name list listed ed by by TSCA TSCA.. Equivalentt Weigh Equivalen Weightt = 56,110 10/Ami /Amine ne Numb Number er..

*** D = D is is titil le le d **** All secondar secondaryy amines meet moisture moisture specifications specifications of 0.5% max.

Some products may be subject to minimum quantity orders.


11

A M I N E S

Te r t i a r y A m i n e s – M o n o a l k y l * SPECIFICATIONS**

PRODUCT

COMMON NA NAME***

TSCA NU NUMBER

% , e n i m A y r a i t r e T

TYPICAL PROPERTIES



t h g i e W t n e l a v i u q E





TERTIARY AMINES - MONOALKYL-DIMETHYLAMINES Min.

Min.

Max.

ARMEEN DM12D

Dodecyl-dimethylamine

112-18-5

95

250

1

219

-19

258

98

9.8

ARMEEN DM16D

Hexadecyl-dimethylamine

112-69-6

95

198

1

276

8

203

98

7.7

ARMEEN DM18D

Octadecyl-dimethylamine

124-28-7

95

180

1

303

20

185

98

7.1

ARMEEN DMCD

Cocoalkyl-dimethylamines

61788-93-0

95

234

1

236

-22

239

98

9.4

ARMEEN DMHTD

Hydrogenated tallowalkyldimethylamines

61788-95-2

95

184

2

292

18

192

98

7.3

ARMEEN DMOD

Oleyl-dimethylamine

28061-69-0

95

183

1

295

-10

190

98

7.1

ARMEEN DMSD

Soyaalkyl-dimethylamines

61788-91-8

95

183

2

297

-10

189

98

7.3

ARMEEN DMTD

Tallowalkyl-dimethylamines

68814-69-7

95

184

1

291

5

193

98

7.3

Tertiary Amines Dialkyl

Te r t i a r y A m i n e s – D i a l k y l * SPECIFICATIONS**

PRODUCT

COMMON NA NAME***


TYPICAL PROPERTIES t h g i e W t n e l a v i u q E




Min.

Min.

Max.

61788-62-3

97

137

2

395

-2

142

99

3.7

61788-63-4

97

105

1

524

38

107

99

1

TSCA NU NUMBER




TERTIARY AMINES - DIALKYL-METHYLAMINES

ARMEEN M2C

Dicocoalkyl-methylamines

ARMEEN M2HT

Dihydrogenated tallowalkyl-methylamines

Tertiary Amines Trialkyl

T e r t i a r y A m i n e s – Tr Tr i a l k y l * SPECIFICATIONS**

PRODUCT

COMMON NA NAME***

TSCA NU NUMBER



TYPICAL PROPERTIES r o l o C r e n d r a G






TERTIARY AMINES - TRIALKYLAMINES Min.

Min.

Max.

102-87-4

95

102

1

540

-9

104

96

<1

82

3

668

38

84

99

<1

2

385

96

<1

ARMEEN 312

Tridodecylamine

ARMEEN 316

Trihexadecylamine

67701-00-2

98

ARMEEN 380

Tri(octyl/decyl)amine

68814-95-9

95

*

Addition Addi tional al tertiar tertiaryy amines amines are listed listed under under “Ethoxy “Ethoxylate lated d Amines.” ** All tertiary tertiary amines amines meet moisture specifications of 0.5% max. Some products may be subject to minimum quantity orders.

12


*** Common name may be different different from the name listed listed by TSCA.

A M I N E S

Diamines

Polyamines—Diamines SPECIFICATIONS

PRODUCT

COMMON NAME*

Diamines TYPICAL PROPERTIES


C º 5 2 @ e c n a r a e p p A





Min.

Max.

Min.

Max.

61791-63-7

409

3

–

1.0

133

Liquid

422

17.5

61791-63-7

409

2

–

1.0

130

Liquid

432

17.5

7173-62-8

320

5

60

1.0

163

Liquid

344

15.2

7173-62-8

320

5

70

1.0

163

Liquid

344

15.2

61791-55-7

334

7

32

1.0

161

Paste

348

15.6

68783-25-5

271

6

–

1.0

199

Liquid

282

14.2

61791-67-1

303

6

68

1.0

160

Paste

320

15.6

TSCA NUMBER

% e r u t s i o M


POLYAMINES—DIAMINES

DUOMEEN C

N-coco-1,3-

DUOMEEN CD

N-coco-1,3-

diaminopropane diaminopropane DUOMEEN O

N-oleyl-1,3diaminopropane

DUOMEEN OL

N-oleyl-1,3diaminopropane

DUOMEEN T

N-tallow-1,3diaminopropane

DUOMEEN TTM

N.N.N’-trimethyl-N’tallow-1,3-diaminopropane

DUOMEEN S

N-soya-1,3diaminopropane

P o l ya m i n e s — H i g h e r A m i n e s SPECIFICATIONS

PRODUCT

COMMON NAME*

TYPICAL PROPERTIES t h g i e W t n e l a v i u q E





% e r u t s i o M

Min.

Max.

Min.

Max.

68911-79-5

475

6

25

0.5

114

37

492

–

61791-57-9

413

8

–

0.5

133

34

422

32.4

85632-63-9

390

12

–

–

–

20

403

32.4

TSCA NUMBER

t n i o P g n i t l e M


P O L YA YA M I N E S — H I G H E R A M I N E S

TETRAMEEN T

N-tallowalkyl dipropylene tetramines

TRIAMEEN T

N-tallowalkyl tripropylene triamines

TRIAMEEN YT

N-(3-Aminopropyl)-Ntallowalkyl trimethylene diamines

*

Common Com mon name name may may be be diffe differe rent nt from from the the name name list listed ed by by TSCA. TSCA.



13

A M I N E S

R-N

Ethoxylated Amines*

COMMON NA NAME***

TSCA NU NUMBER

(CH2CH2O)yH

X + Y = 2, 5 , 10, 15, 50

SPECIFICATIONS**

PRODUCT

(CH2CH2O)xH



TYPICAL PROPERTIES % , e n i m s A u y l p r a y r d a n o m i r c e P S




ETHOXYLATED AMINES* Min.

ETHOMEEN 18/12

10.9

26635-92-7

900

960

8

1

60

Liquid to Paste

14.4

26635-92-7

2370

2570

10

0.5

23

Paste to Solid

26.6

61791-31-9

280

300

4

3

193

Liquid

12.2

61791-14-8

410

435

7

2

133

Liquid

13.3

61791-14-8

830

890

10

1

65

Liquid

16.8

13127-82-7

343

363

8

3

160

Liquid

9.7

73246-96-5

342

362

6

3

159

Liquid

10.0

61791-24-0

470

495

10

2

116

Liquid

11.1

61791-24-0

895

955

10

1

61

Liquid

14.7

61791-44-4

340

360

6

3

160

Paste

10.1

61791-26-2

470

495

7

2

116

Liquid to Paste

11.2

61791-26-2

690

752

12

0.4

78

Liquid

13.0

61791-26-2

890

950

8

1

61

Liquid to Paste

14.7

61791-26-2

1250

1300

12

1

44

Liquid

17.0

Base Ba se amin amines es can can be offer offered ed as as propo propoxyl xylat ated ed deriv derivati atives ves.. The ethoxyl ethoxylated ated amines amines and and diamines diamines all meet meet moisture moisture specific specificatio ations ns of 1.0% max. max. Common Comm on name may may be differe different nt from name name listed listed by TSCA. TSCA.


14

Solid

Ethoxylated (20) tallowalkylamines

* ** ***

114


ETHOMEEN T/30

2


ETHOMEEN T/25

8


ETHOMEEN T/20

505


ETHOMEEN T/15

480

Ethoxylated (15) soyaalkylamines

ETHOMEEN T/12

26635-92-7


ETHOMEEN S/25

9.8


ETHOMEEN S/15

Solid

Ethoxylated (2) oleylamines

ETHOMEEN S/12

155

Ethoxylated (15) cocoalkylamines

ETHOMEEN O/12

3


ETHOMEEN C/25

2


ETHOMEEN C/15

374

Ethoxylated (50) octadecylamine

ETHOMEEN C/12

350


ETHOMEEN 18/60

10213-78-2


ETHOMEEN 18/25

Max.


ETHOMEEN 18/15

Max.


A M I N E S

(CH2CH2O)xH R-NCH2CH2CH2N

SPECIFICATIONS**

PRODUCT

COMMON NAME***

TSCA NUMBER

(CH2CH2O)zH

X + Y + Z = 3, 10, 15 Ethoxylated Diamines

P o l ya m i n e s — E t h o x y l a t e d D i a m i n e s *

TYPICAL PROPERTIES % , e n i m s A u y l p r a y r d a n o m c i r e P S


(CH2CH2O)yH




19.0

P O L YA YA M I N E S — E T H O X Y L A T E D D I A M I N E S

ETHODUOMEEN T/13

220

250

2

239

Liquid

Proprietary blend

265

272

2

209

Liquid

61790-85-0

375

405

2

144

Liquid

23.7

61790-85-0

485

515

2

112

Liquid

24.5

Ethoxylated (15) N-tallow-1, 3-diaminopropane

* ** ***

61790-85-0


ETHODUOMEEN T/25

Max.


ETHODUOMEEN T/20

Max.


ETHODUOMEEN T/13N

Min.

Base Ba se amine aminess can be offer offered ed as as propo propoxyl xylat ated ed deriv derivat ative ives. s. The ethoxyl ethoxylated ated amines amines and and diamines diamines all meet meet moisture moisture specific specificatio ations ns of 1.0% max. max. Common Comm on name name may be differ different ent from from name liste listed d by TSCA. TSCA.

CH3 R-N CH2CHOH

Propoxylated Amines SPECIFICATIONS*

PRODUCT

COMMON NAME

TSCA NUMBER

2

Propoxylated Amines



TYPICAL PROPERTIES % , e n i m A y r a i t r e T




PROPOXYLATED AMINES

PROPOMEEN O/12

Max.

65086-71-7

371

391

6

97

147

Clear Liquid

8.9

68951-72-4

368

388

6

97

148

Clear Liquid

9.2

N-tallowalkyl-1, 1’-iminobis-2-propanol

*

Max.

N-oleyl-1, 1’-iminobis-2-propanol

PROPOMEEN T/12

Min.

All prop propoxyl oxylated ated amin amines es meet moist moisture ure speci specificat fications ions of 1.0% 1.0% max.



15

A M I N E S A LT S

RNH2 • CH3CO2H Amine Salts RNHCH2CH2CH2NH2 • 2R'CO2H Diamine Salts

A m i n e A c e t a t e s a n d D i a m i n e S a l t s SPECIFICATIONS

PRODUCT

COMMON NAME***

TSCA NUMBER

n o i t t a z n i e l l a r a v t i u u e q N E

TYPICAL PROPERTIES



Min.



A M I N E A C E TA T E S A N D D I A M I N E S A LT S

ARMAC 18D-40*** 18D-40*** ARMAC HT***

124-30-1

38

42

11

190

200

Flake**

7.5

61790-59-8

95

102

10

165

–

Flake**

6.8

61790-60-1

–

–

10

165

–

Solid

6.8

61791-53-5

98

104

10

120

130

Liquid to Paste

6.4

Mixture

98

104

10

94

107

Viscous Liquid

6.4

Hydrogenated tallowalkyl Tallowalkylamine N-tallow-1,3N-tallow-1,3-(a) diaminopropane ditallates

** *** (a)) (a

Common Comm on name name may may be differ different ent from from the the name name listed listed by by TSCA. TSCA. Only flak flaked ed forms ava availab ilable. le. 80% 80 % in mi mine nera rall sp spir irit itss


16

Max.

2190-04-7

diaminopropane ditallates DUOMEEN TDO-IHF

Max.

and octadecyl amine

acetates DUOMEEN TDO

Max.

Octadecylamine acetate

amine acetates ARMAC T

Min.


Q U AT A T E R N A R Y A M M O N I U M S A LT LT S

RN+(CH3)3 CI– Alkyltrimethyl Quaternary Ammonium Salts

A l k y l t r i m e t h y l SPECIFICATIONS

PRODUCT

COMMON COM MON NAM NAME** E** TSC TSCA A NUMBE NUMBER R

, t l a S y r a n r e * t a * u * Q %

s u l p % , e t n l i a S m A e n e i e r m F A

TYPICAL PROPERTIES

H p


h s a C l F º , C t C i n M o P P

@ e c n a r a e C p º p 5 A 2


A L K Y LT R I M E T H Y L A M M O N I U M C H L O R I D E S Min.

Max.

Max.

ARQUAD 12-37W

Dodecyl–

112-00-5

35

39

1

6.5-9

2

Non-Flammable

Liquid

23.3

ARQUAD 12-50

Dodecyl–

112-00-5

49

52

2

6-9

1

19

Liquid

23.3

ARQUAD 16-29

Hexadecyl–

112-02-7

27

30

2

6-9

3

Non-Flammable

Liquid

21.2

ARQUAD 16-50

Hexadecyl–

112-02-7

49

52

2

6-9

3

17

Liquid

21.2

ARQUAD 18-50

Octadecyl–

112-03-8

49

52

2

6-9

3

18****

Liquid

20.5

ARQUAD C-33W

Cocoalkyl–

61789-18-2

32

35

2

6-9

4

Non-Flammable

Liquid

22.9

ARQUAD C-50

Cocoalkyl

61789-18-2

49

52

2

6-9

4

20

Liquid

22.9

ARQUAD S-50

Soyaalkyl

61790-41-8

49

52

2

6-9

5

16

Liquid

20.8

ARQUAD T-27W T-27W

Tallowalkyl

8030-78-2

26

29

2

6-9

3

Non-Flammable

Liquid

20.8

ARQUAD T-50 T-50

Tallowalkyl

8030-78-2

49

52

2

6-9

4

16

Liquid

20.8

* **

Prepare Pre pared d in aqueo aqueous us isoprop isopropanol anol or water water (W). (W). Can Can be prepa prepared red in in other other solvent solvents. s. Common name Common name may may be differ different ent fromt fromthe he name name listed listed by by TSCA. TSCA.

Max.

*** In many cases, activity activity (concentration) (concentration) can can be changed changed to suit your needs. needs. **** ** ** Set Setafl aflash ash

R2 N+ (CH3)2 (X)– (X) = CI, NO 2, OSO2OCH3

Dialkyldimethyl SPECIFICATIONS

PRODUCT

COMMO COM MON N NAME** NAME** TSC TSCA A NUMB NUMBER ER

s u l p % , e t n l i a m S A e n e i e r m F A

y r * a * n r * e % t , t a l u a Q S

TYPICAL PROPERTIES

H p





DIALKYLDIMETHYL AMMONIUM CHLORIDES **

ARQUAD2C-70 ARQUAD2C70 Nitrit Nitrite e Dicocoalkyl–(b) ARQUAD 2C-70 PG Dicocoalkyl–

ARQUAD 2C-75

Dicocoalkyl–

ARQUAD 2HT-75 2HT-75

Di(hydrogenated tallowalkyl)–

Min.

Max.

Max.

71487-01-9 61789-77-3

68 68

72 72

– 2

6-8.5 6-9

Max.

14 4

23 107

Liquid Liquid

17.3 17.3

61789-77-3

74

77

1.5

6-9

3

23

Liquid

17.3

61789-80-8

74

77

1.5

6-9

2

25

Paste

13.2

61789-80-8

74

77

1.5

6-9

3

107

Paste

13.2

Liquid

17.5

ARQUAD 2HT-75 2HT-75 PG Di(hydrogenated tallowalkyl)–(a) ARQUAD ARQ UAD HTL8 MS

2-Ethylhexyl hydrogenated tallowalkyl–(c)

* ** ***

NonEPA Listed

Can Ca n be be pre prepa pare red d in in oth other er so solv lven ents ts.. Common name Common name may may be differe different nt from from the the name name listed listed by TSC TSCA. A. In many cases, activity activity (concentration) (concentration) can can be changed changed to suit your needs. needs.

81.5

84.5

4

6-8

5

Flammable

(a) Propylene glycol (b) Nitrite (c) Methyl Sulfate Anion



17

QUATERNARY AMMONI UM SALTS

Trialkylmethyl

R3 N+ CH3 CI– SPECIFICATIONS

PRODUCT

COMMON NA NAME**

TSCA NU NUMBER


y r * a * n r * e % t , t a l u a Q S

TYPICAL PROPERTIES

H p





TRIALKYLMETHYL

ARQUAD 316(W)

Trihexadecylmethyl

52467-63-7

Min.

Max.

86

90

Max.

2

Max.

6-8

4

Non-Flammable

Solid

7.6

ammonium chloride [in water (W)] **

Common Comm on name name may may be differ different ent from from the the name name listed listed by TSCA. TSCA.

CH3 –

R2 N CH2 C6 H5 CI +

Benzylalkyl

CH3

CH3

SPECIFICATIONS

PRODUCT

COMMON NA NAME**

TSCA NU NUMBER

s u l p % , e l n t i a S m A e n e i e r m F A

y r * a * n r * e % t , t a l u a Q S

H p

RN+ CH2 C6 H5 CI–

TYPICAL PROPERTIES r o l o C r e n d r a G




A M M O N I U M C H L O R I D E S

ARQUAD DMCB-80

Min.

Max.

Max.

Max.

61789-71-7

79

82

1.5

6-8

4

27

Liquid

20.1

61789-72-8

75

80

2

7-9

4

23

Solid

18.0

61789-73-9

82

84

2

7-9

3

23

Solid

10.4

61789-68-2

73

77

2

6-9

12

26

Liquid

23.7

Benzyldimethyl– cocoalkyl–

ARQUAD ARQUA D DMHTB-75 DMHTB-75 Benzyldimethyl– (hydrogenated tallowalkyl) ARQUAD ARQUA D M2HTB

Benzylmethyl– di(hydrogenated tallowalkyl)

ETHOQUAD C/12B

Benzylcocoalkyl [ethoxylated (2)]–

*

Prepared in aqueous isopropanol. Can be prepared in other solvents.


18


**

Common name may be different from the name listed by TSCA.

Q U A T E R N A R Y A M M O N I U M S A L TS TS [CH2CH2O]zH RN + CH3 [X] – [CH2CH2O]yH

Z + Y = 2 or 15 [X] = CI or NO3

RN+ (CH2 CH2 OH)2 CH3 CO2– Ethoxylated Monoalkyl Quaternary Acetates

Ethoxylated Monoalkyl Quaternary Salts

Ethoxylated Quaternary Salts—Monoalkyl Ethoxylates SPECIFICATIONS

PRODUCT

COMMON NAME*

TSCA NUMBER

% , t l a S y r a n r e t a u Q


H p

TYPICAL PROPERTIES



C º , t n i o P h s a l F


MONOALKYLMETHYL [ETHOXYLATED (N)]-AMMONIUM CHLORIDES [NITRATES] [ACETATES]

ETHOQUAD 18/12

ETHOQUAD C/12

Cocoalkylmethyl

NITRATE

[ethoxylated (2)]– ammonium nitrate

2

7-9

7

22**

Paste

23.4

28724-32-5

95

2

7-9

11

149

Liquid

28.0

70750-47-9

74

2

7-9

9

21

Liquid

25.8

71487-00-8

59

–

6.5-7.5

8

20

Liquid

25.8

61791-10-4

95

2

7-9

11

127

Liquid

30.4

18448-65-2

65

2

6-8

5

104

Liquid

23.4

91080-64-7

27

1.5

6-8

5

63

Liquid

26.0

64755-05-1

95

–

7-9

12

93

Liquid

28.3

Oleylmethyl [ethoxylated (2)]–

ETHOQUAD T/13-27W

70

Cocoalkylmethyl [ethoxylated (15)]–

ETHOQUAD O/12 PG

3010-24-0

Cocoalkylmethyl [ethoxylated (2)]–

ETHOQUAD C/25

Max.

Octadecylmethyl [ethoxylated (15)]–

ETHOQUAD C/12-75

Max.

Octadecylmethyl [ethoxylated (2)]–

ETHOQUAD 18/25

Min.

Tris(2-hydroxyethyl) tallowalkyl ammonium acetates

ETHOQUAD T/25

Tallowalkylmethyl [ethoxylated (15)]–

* **

Common Com mon name name may may be be diffe differe rent nt from from the the name name list listed ed by by TSCA. TSCA. Setaflash

(PG) (P G)

Prop Pr opyl ylen ene e gl glyc ycol ol

CH3 R

A l k y l D i a m m o n i u m P e n t a m e t h y l C h l o r i d e s SPECIFICATIONS

PRODUCT

COMMON NAME**

TSCA NUMBER

% , t l a S y r a n r e t a * u * Q *

N+ CH2 CH2 CH2 N+ (CH3)3 2CI– CH3 TYPICAL PROPERTIES


H p


C º , t n i o P h s a l F C C M P


ALKYL DIAMMONIUM DIAMMONIUM PENTAMETHYL PENTAMETHYL CHLORIDES CHLORIDES

DUOQUAD T-50

Min.

Max.

Max.

Max.

48

52

2

6-9

N,N,N’,N’,N’-pentamethylN-tallow-1,3-propane diammonium dichloride

*

68607-29-4

Prep ar are d i n aq ue ueo us us i so so pr pro pa pano l.l. Ca Ca n al so so be be pr pre pa pared in in o th the r so lv lven ts ts.

**

7

15

Liquid

Co mm mmo n n am ame ma may b e di ff ff er ere nt nt f ro ro m the na nam e l is is te te d by TS CA CA .



19

A M I N E O X I D E S / A M I D E S

CH2CH2OH R

A m i n e O x i d e s

N

O

COMMON NAME**

R

N

CH2CH2OH

SPECIFICATIONS

PRODUCT

CH3

% , e d i x O e n i m A

O

CH3

TYPICAL PROPERTIES

% , e n i m A


% , e d i x o r e P

Min.

Max.

Max.

Max.

61791-47-7

49

2.5

6

0.34

22

24.7

61791-47-7

30

1.0

6

0.34

>100

24.7

61788-90-7

39

1.5

–

0.34

21

22

7128-91-8

39

1.5

1

0.34

26

20.3

68390-99-8

24

1.5

2

0.34

20

19.8

68390-99-8

24

1.5

2

0.34

20

19.8

TSCA NUMBER


3 l e H a p c t S a s B i v L a H D

A M I N E O X I D E S

Bis(2-hydroxyethyl)-

AROMOX C /12

cocoalkylamine oxides Bis(2-hydroxyethyl)-

AROMOX C /12W

cocoalkylamine oxides AROMOX DMC

Dimethylcocoalkylamine oxides Dimethylhexadecyl-

AROMOX DM16

amine oxide Dimethylhydrogenated

AROMOX DMHT

tallowalkylamine oxides Dimethyl

AROMOX T/12 DEG*

tallowalkylamine oxides *

Prepared in diethylene glycol.

**

Common name may be different from the name listed by TSCA.

A m i d e s

RCONH2 SPECIFICATIONS

PRODUCT

COMMON NAME*

TSCA NUMBER

TYPICAL PROPERTIES

% , e d i m A

% , d i c A y t t a F e e r F


Min.

Min.

Max.



m r o F l a c i s y h P

e l a c S s i v a D B L H

AMIDES

ARMID HT ARMID O *

Hydrogenated tallowalkylamides

61790-31-6

90

5

7

3

98

Flakes

<1

Oleamide

301-02-0

90

3.5

7

85

71

Flakes

<1

Common Com mon nam name e may may be diff differ erent ent fro from m the the name name liste listed d by TSCA TSCA..


20


E T H O X Y L AT AT E D A M I D E S / N I T R I L E S / C O R R O S I O N I N H I B I T O R S

RCONH(CH2CH2O)XH X = 7 or 13

Ethoxylated Amides SPECIFICATIONS

PRODUCT

COMMON NAME*

TSCA NUMBER


% , e d i m A e e r F

Max.

Max.

TYPICAL PROPERTIES

e u l a V l y x o r d y H

O E s e l o M

C º 5 2 t a e c n a r a e p p A

e l a c S s i v a D B L H

ETHOXYLATED AMIDES

ETHOMID O/17

Ethoxylated (7) oleamide

ETHOMID HT/23

Ethoxylated (13)

26027-37-2

8

15

7

110

Liquid

10.5

68155-24-8

9

15

13

105

Solid

13.5

hydrogenated tallowalkylamides *

Common Com mon name name ma mayy be diffe differen rentt from from the the name name liste listed d by TSCA TSCA..

Nitriles

RCN SPECIFICATIONS

PRODUCT

COMMON NAME*

e u l a V n o i t a c i f i n o p a S

TSCA NUMBER

TYPICAL PROPERTIES

e u l a V d i c A





NITRILES

ARNEEL OD *

Oleonitrile

112-91-4

Min.

Max.

Max.

Max.

Min.

195

203

1.2

3

85

5

>149

Common Com mon name name ma mayy be diffe differe rent nt from from the the name name list listed ed by by TSCA. TSCA.

Corrosion Inhibitors SPECIFICATIONS

PRODUCT

USE

COMMON NAME*

n o i t t a z n i e l l a r a v t i u u e q N E

TSCA NUMBER

e r u t s i o M

TYPICAL PROPERTIES C 5 2 @ e c n a r a e p p A

s p c y t i s o c s i V

C º , t n i o P r u o P

CORROSION INHIBITORS

ARMOHIB 28

Propri Pro prieta etary ry Ble Blend nd

Inhibi Inh ibitt hyd hydroc rochlo hloric ric

ARMOHIB 31

Propri Pro prieta etary ry Blen Blend d

Inhibi Inh ibitt sulfur sulfuric, ic, sulf sulfami amicc

and hydrofluoric acids

Min.

Max.

750

800

phosphoric, citric acids ARMOHIB 209

Liquid

11

2.0

Liquid

0

Intermediate

68442-97-7

208

222

0.2

Liquid

Intermediate

61790-69-0

187

200

1.0

Solid

200

<0

Tall Oil Amido Amine

*

4.5

Tall Oil Imidazoline

ARMOHIB 210

Max. %

32

Common Com mon name name may may be be differ different ent fro from m the the name name liste listed d by TSCA TSCA..



21

A N I O N I C S U R F A C T A N T S

22

AN IO NI C SU RFA CTA NTS

A n i o n i c S u r f a c t a n t s Anionic surfactants can be structurally described as an organic hydrophobe (water-insoluble) that contains one or more negatively charged substituents (anions). (anions). Akzo Nobel Surface Chemistry offers anionic surfactants having sulfonate, sulfonic acid, sulfate, phosphate or carboxylic acid groups, which bear the negative (anionic) charge.

An io ni c Pr oc es s Ch em ic al s Alkylbenzenes Alkylnaphthalenes Olefins Alcohols

Figure 1 shows the variety of hydrophobes we use to make our anionic surfactant products. products. The hydrophobes are reacted reacted with an appropriate reactant to form the anionic surfactant species listed in the right-hand column.

Alcohol Ethers Alkylphenols Alkylphenol Ethers Fatty Acids

Below are listed the trademarks we use to identify the anionic surfactants we market. Trademark

Surfactant Type

EMCOL®

Ethoxylated Carboxylic Acid (terminated)

LANKROPOL™

Sulfosuccinates

PETRO®

Alkyl Naphthalene Sulfonates

UDET™

Detergent Surfactant Blend

PHOSPHOLAN™

Phosphate Es Esters

WITCOLATE™

Alkyl Sulfates; Alkyl Ether/ Alkylaryl Ether Sulfates

WITCONATE™

Alkylaryl and ∝ – Olefin Sulfonates (Air/SO3)

WITCONIC™

Sulfonic Acids

Sulfonic Acids SO3

Sulfates

H2 SO4

Ether Sulfates

NaHSO3

Sulfonates

Na2SO3

Ethoxylated Carboxylates

NaOAcCI P2O5 (H3PO4) x

Sulfosuccinates Phosphate Esters Naphthalene Sulfonates

FIGURE 1

Anionic surfactants are important for their dispersing and detergency properties in aqueous media. By choosing the appropriate hydrophobe and anion combination, the formulator can achieve the desired surfactant effect for their formulations. Listed below are the examples of the types of properties that can be optimized with anionic surfactants from Akzo Nobel Surface Chemistry: • Water solubility • pH stability • Thermal stability • Cloud point • Detergency • Dispersancy • Hard water tolerance Recommendations of the surfactant type for various applications are found on page page 2. Advice for specific products products for individual requirements can be obtained by contacting our Technical Service at 1-877-565-8432.


23

A L K Y L N A P H T H A L E N E S U L F O N A T E S

A l k y l N a p h t h a l e n e S u l f o n a t e s Petro® alkyl naphthalene sulfonates are regarded as surface-active surface-active hydrotropes. They exhibit characteristics such as wetting, foaming, detergency and surface tension reduction. They have excellent excellent rinseability, rinseability, acid and base stability, stability, hard-water tolerance and high-temperature stability. stability. These versatile surfactants surfactants are used in a variety of applications including carpet cleaners, transportation cleaners, rinse aids, metal cleaners, rust removers and hard surface cleaners.

PRODUCT

DESCRIPTION

APPEARANCE

TYPICAL ACTIVITY,%

A L K Y L N A P H T H A L E N E S U L F O N AT E S

PETRO 11 LIQUID

Sodium Alkyl Naphthalene Sulfonate

Liquid

50

PETRO 11 POWDER


Powder

95

PETRO 22 LIQUID


Liquid

50

PETRO 22 POWDER


Powder

95

PETRO 375 LIQUID


Liquid

68

PETRO AA LIQUID


Liquid

50

PETRO AA POWDER


Powder

95

PETRO AG SPECIAL


Liquid

50

PETRO AG SPECIAL


Powder

95

PETRO AGS-SUPERFINE


Powder

95

PETRO BA LIQUID


Liquid

50

PETRO BA POWDER


Powder

95

PETRO BAF LIQUID


Liquid

50

PETRO BAF POWDER


Powder

95

PETRO BP POWDER


Powder

95

PETRO D-425 LIQUID

Sodium Naphthalene Sulfonate Condensate

Liquid

43

PETRO D-425 POWDER

Sodium Naphthalene Sulfonate Condensate

Powder

88

PETRO DISPERSANT 98

Sodium Naphthalene Sulfonate

Liquid

95

PETRO LBA LIQUID


Liquid

50

PETRO LBA POWDER


Liquid

95

PETRO LBAF LIQUID


Liquid

50

PETRO LULF LIQUID


Liquid

50

PETRO P LIQUID


Powder

95

PETRO P POWDER


Powder

95

UDET 950 POWDER


Powder

95

PETRO ULF LIQUID


Liquid

50

PETRO X-3158 LIQUID


Liquid

70

24


A L K Y L N A P H T H A L E N E S U L F O N A T E S

A L K Y L N A P H T H A L E N E S U L F O N AT E S

FUNCTIONALITY

g n i k a c i t n A

g n i l p u o C

y c n e g r e t e D

MARKETS

n o i s r e p s i D

g n i m a o F

g n i p o r t o r d y H

g n i t t e W

I & I H

s t n e g r e t e D y r d n u a L

s r e n a e l C g n i s s e c o r P d o o F

s r e n a e l C n o i a t r o p s n a r T

•

•

•

M

•

•

•

•

•

•

•

M

•

•

•

•

•

L

•

•

•

•

•

•

L

•

•

•

•

•

•

•

KEY (H)

• •

•

•

M

•

•

•

•

•

•

•

M

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

M

•

•

•

•

•

•

•

M

•

•

•

•

•

H

•

•

•

•

•

•

H

•

•

•

•

•

• •

•

•

•

•

•

•

•

•

M

•

•

•

•

•

•

•

M

•

•

•

•

H

•

•

•

•

•

•

•

•

•

•

Low

•

• •

M/H

•

•

M/H

•

•

H

•

•

•

L

•

•

•

•

(L)

•

•

•

High

(M)) Mo (M Mode dera rate te

•

•

•

•



25

SULFONATES

Sulfonates Witconic™ sulfonic acids are the base acids used to make detergent sulfonates. They can be neutralized in situ to produce the anionic surfactant desired. Witconate™ anionic surfactants include alkylaryl sulfonates, olefin sulfonates, alkane sulfonates and specialty sulfonates. These products are workhorse surfactants surfactants in numerous Household and Industrial & Institutional cleaning applications.

PRODUCT

DESCRIPTION

APPEARANCE

TYPICAL ACTIVITY,% ACTIVITY,%

pH

COLOR, MAX

Sodium Dodecylbenzene Sulfonate, Branched Sodium Dodecylbenzene Sulfonate, Linear Potassium Dodecylbenzene Sulfonate, Linear Sodium Dodecylbenzene Sulfonate, Linear Fatty Acid Sulfonate Specialty Sulfonate Isopropylamine salt of 1298S in IPA Calci um um Sa Salt of of DD DD BS BSA (B (Branched) in in Ar Aromatic 15 150 TEA-Dodecylbenzene Sulfonate TEA-Dodecylbenzene Sulfonate Sodium Dodecylbenzene Sulfonate Isopropylamine Dodecylbenzene Sulfonate Sodium C14-16 Alpha Olefin Sulfonate Sodium C14-16 Alpha Olefin Sulfonate Sodium C14-16 Alpha Olefin Sulfonate Sodium C14-16 Alpha Olefin Sulfonate Sodium C14-16 Alpha Olefin Sulfonate Sodium C14-16 Alpha Olefin Sulfonate Linear Sodium Alkylbenzene Sulfonate Linear Sodium Alkylbenzene Sulfonate Sodium Dodecylbenzene Sulfonate

Liquid Liquid Liquid Light slurry Clear-slightly hazy liquid Dark amber liquid Clear amber liquid D ar ark vi viscous Li Liquid Liquid Clear yellow liquid Cream colored flake Clear amber liquid Light liquid Cream colored flake Clear yellow liquid Clear amber liquid Clear yellow liquid Liquid Cream colored flake Off-white flakes Cream colored flake

21-23 22-23 20.5-21.5 38-40 48-52 (s) 48-52 (s) 74-76 59.5-60.5 57-58 51.3-53.1 90-91 90-93 38-40 90 38 - 40 40 (s) 38-40 38-40 90 90 90

7.5-8.5 (g) 7.5-8.5 (g) 7.5-8.5 (g) 7.5-9 (e) 6.5-7.5 (b) 7-8 (e) 3-4 * 5-7 (d (d) 5.5-7 (e) 6.5-8 ( c) 6.5-8.7 (e) 4-5 (g) 6.5-8.5 (e) 7-10 (e) 8-10 (f) 8-10 (b) 7.5-8.5 (f) 6.5-8.5 (f) 6.5-8.7 (e) 1.5-7 (e) 6.5-8.7 (e)

120 (K) 75 (K) 100 (K) 90 (K)

Sodium Dodecylbenzene Sulfonate / Sodium Xylene sulfonate

Flake

91

Powder

91

Clear-slightly hazy liquid Clear-slightly hazy liquid Clear amber liquid Clear amber liquid Dark amber liquid Clear amber liquid Clear amber liquid Dark brown liquid

37 38 90 60 70 60 54 60

6-7 (a) 6-7 (a) 4.5-5.5 (f) 5-7 ( c ) 5-7 ( c ) 5-7 ( c ) 5-7 ( c ) 5-7 ( c )

2 ( G) 2 (G) 7 ( G) 12 (G) 12 (G) 12 (G) 12 (G)

SULFONATES

WITCONATE 1223H WITCONATE WITCONATE WITCONA TE 1223L WITCONATE WITCONA TE 1223SK WITCONATE WITCO NATE 1238 1238 Slurry Slurry WITCONATE 1840X WITCONATE WITCONATE WITCONA TE 3203 WITCONATE WITCONA TE 4133 WITCONATE WITCONA TE 605 A WITCONATE WITCONA TE 60T WITCONATE WITCONA TE 79S WITCONATE WITCONA TE 90 Flake WITCONATE WITCONA TE 93S WITCONATE WITCONA TE 96A WITCONATE WITCONA TE AOK WITCONATE WITCONA TE AOS WITCONATE WITCONA TE AOS-12 WITCONATE WITCONA TE AOS-EP WITCONATE WITCONA TE AOS-PC WITCONATE WITCONA TE DS Dense WITCONATE WITCONA TE DS Flake WITCONATE WITCONA TE K Dense WITCONATE WITCONA TE LX Flake

WITCONATE WITCONA TE LX Powder Sodium Dodecylbenzene Sulfonate / Sodium Xylene sulfonate Sodium Octane Sulfonate WITCONATE WITCONA TE NAS-8 Sodium Octane Sulfonate-Winterized WITCONATE WITCONA TE NAS-8W Isopropylamine Dodecylbenzene Sulfonate WITCONATE WITCONA TE P-1059 Calcium Salt of DDBSA, Branched WITCONATE WITCONA TE P-1220 WITCO WIT CONA NATE TE P-12 P-1220 20 Bust Bust Calcium Salt of DDBSA, Branched WITCONATE WITCONA TE P-1220EH Calcium Salt of DDBSA (Branched) in 2-Ethylhexanol Calcium Salt of DDBSA (Branched) in 2-EH/PG WITCONATE WITCONA TE P-1220S Calcium Salt of DDBSA (Branched) in Octanol WITCONATE WITCONA TE P-1860

6 (G) 350 (K) 6 ( G) 200 (K) in 10% aq 7 ( G) 120 (K) 275 (K) in 10% aq 120 (K) in 12.8% aq 400 (K) 100 (K) 70 (K) 200 (K) 120 (K) in 10% aq 200 (K) in 10% aq

WITCONATE WITCONA TE SK Flake

Sodium Dodecylbenzene Sulfonate / Sodium Xylene sulfonate

Cream colored powder

40

8.5-8.5 (e)

180 (K)

WITCONATE WITCONA TE SXS

Sodium Xylene Sulfonate

Liquid

40-42

7-9 (a)

50 (K)

Black liquid Dark brown liquid Dark amber liquid Dark amber liquid Dark brown liquid Dark visc. Liquid

50 94-97 97 96-97 92 94-96

SULFONIC ACIDS

Diisopropyl Naphthalene Sulfonic Acid Dodecylbenzene Sulfonic Acid, Branched WITCO WI TCONIC NIC 12 1298 98 So Soft ft a acid cid Dodecylbenzene Sulfonic Acid, Linear WITCO WI TCONIC NIC 13 1398 98 Soft Soft acid acid Alkylaryl Sulfonic Acid, Linear Methyl Naphthalene Sulfonic Acid WITCONIC AN Acid Toluene Sulfonic Acid, Modified WITCONIC TX Acid PETRO IPSA Liquid

WITCO WI TCONIC12 NIC1298 98 Ha Hard rd aci acid d

26

AN IO NI C SU RFA CTAN TS

400 (K) 150 (K) 150 (K) 150 (K)

SULFONATES

SULFONATES

SULFONIC ACIDS

FUNCTIONALITY

g n i l p u o C

• •

•

• • •

g n i m a o f e D

y c n e g r e t e D

•1

• • • • •

r e i f i s l u m e D

n o i s r e p s i D

W / O r e i f i s l u m E

r e z i l i b a t S m a o F

g n i m a o F

g n i t t e W

• • • •

• • • • •

• • • • • • • • • • • • • • • •

• •

• •

t n a r e l o T e t y l o r t c e l E

n o i t a z i r e m y l o P n o i s l u m E

g n i t h g i F e r i F

r e m a o F t n e m e C / d r a o b l l a W

KEY

• • •

• • • • • • • • •

•

•

•

•

•

•

•

•

• • •

L L

• • • • • • • •

• •

•

• •

• •

•

•

• • • • • • •

e l i t x e T

• • •

• • • • • • • • • • • • • •

• •

MARKETS

•

•

• • • • • •

• • • • • • • • •

• • • • • •

1.

In acidic solution

*

1% aq

(a)

as is

(b)) (b

5% aq aq sol solutio u tionn

(c)) (c

5% in in 25% 25% IPA IPA solu soluti tion on

(d)

5% in 75 75 % IP IPA A solu solutio tionn

(e)) (e

10 % aq so solu luti tion on

(f)) (f

12.8 12 .8% % aq so solu luti tion on

(g)) (g

20% 20 % aq so solu luti tion on

( G) G)

Ga rd rd ne ne r

(h)

20% in 25% IPA solution

(K)

Klett

( L)

Low Foam

(m)

% moisture

(s)

% solid

•

•

•

•

• • • •

• • • •

• • • •

• • •

• • • •

•

•

• •

•

Some products may be subject to minimum quantity orders. AN IO NI C SU RFA CTA NTS

27

SULFATES

Sulfates Witcolate™ sulfates, alkyl ether sulfates sulfates and alkylaryl ether sulfates are available with a variety of hydrophobe structures, ethylene oxide content and cations. Ether sulfates exhibit exhibit flash foam and have lower irritation irritation properties than the the corresponding alkyl sulfates. sulfates. These anionic surfactants surfactants provide detergency, detergency, foaming, and wetting to many products such as liquid hand dishwash, transportation cleaners, hard-surface cleaners and a variety of industrial and institutional products.

DESCRIPTION

APPEARANCE


WITCOLATE WITCOLA TE 1300

Surfactant Blend

Clear amber liquid

53-57 (s)

8-9 (b)


Surfactant Blend

Liquid

31.5-33

8-9.6 (b)


Sodium C8-10 Sulfate

Liquid

37-39

10-11 ( c )

WITCOLA WITC OLATE TE A POWDER POWDER

Sodium Lauryl Sulfate

Off-white powder

92.5

7-10 ( c )

WITCOLATE WITCOLA TE C*


Off-white powder

90.6

WITCOLATE WITCOLA TE D-510

Sodium 2-Ethylhexyl Sulfate

Liquid

38.5-40.5

9-10.5 ( c )

4 (G)

WITCOLATE WITCOLA TE EP

DEA Lauryl Sulfate

Liquid

31.8-34.7

7.5-8.5 ( c )

55 min (T%)

WITCOLATE WITCOLA TE LCP


Liquid

28-30

7-8.5 ( a )

100 (A)

WITCOLATE WITCOLA TE ME DRY


Off-white powder

60

WITCOLATE WITCOLA TE NH

Ammonium Lauryl Sulfate

Liquid

28-30

6.3-6.8 ( c )

200 (A)

WITCOLATE WITCOLA TE NHK


Liquid

28-30

6.3-6.8 ( c )

200 (A)

WITCOLATE WITCOLA TE NHP


Liquid

28-30

6.3-6.8 ( c )

200 (A)

WITCOLATE WITCOLA TE SL-EP

Sodium C10-16 Sulfate

Liquid

29-30

7.5-8.5 ( c )

50 (K)

WITCOLATE WITCOLA TE TLS-500

TEA-Lauryl Sulfate

Liquid

40-42

6.5-7.5 ( c )

150 (PCC)

WITCOLATE WITCOLA TE WA PASTE PASTE


White paste

19-20

7.5-8.5 ( c )

85 min (T%)

WITCOLATE WITCOLA TE WAC LA


Liquid

28-30

8-8.5 ( c )

100 (A)

WITCOLATE WITCOLA TE WAQ


Liquid

19-20

7.5-8.5 ( c )

65-100 (T%)

WITCOLATE WITCOLA TE WAQE


Clear yellow liquid

19.2-20.2

7.5-8.5 ( c )

60 min (T%)

PRODUCT

pH

COLOR, MAX

A L K Y L S U L FA T E S

3 (G) 60 min (T%)

60 min (T%)

A L K Y L E T H E R S U L FA T E S


Sodium C12-15 Pareth Sulfate (1 EO)

Clear yellow liquid

38-40

8.5-11 ( c )

220 (K)

WITCOLATE WITCOLA TE 1247HF

Ammonium C6-10 Alcohol Ether Sulfate (3 EO)

Clear yellow liquid

64-66

7-8.5 (b)

50 (K)

WITCOLATE WITCOLA TE 1247H


Clear yellow liquid

64-66

7-8.5 (b)

50 (K)


C6-10 Alcohol Ether Sulfate (3 EO), IPA Salt

Liquid

80

7-8 (b)

100 (K)

WITCOLATE WITCOLA TE 1259FS

C6-10 Alcohol Ether Sulfate (3 EO), IPA Salt

Clear amber liquid

88.5

7-8.5 (b)

100 (K)



Clear yellow liquid

52.5-53.5

7-8 (b)

30 (K)


Sodium C6-10 Alcohol Ether Sulfate (3 EO)

Liquid

38-39

7-8.5 (a)

300 (K)

WITCOLATE WITCOLA TE LES-60A

Ammonium Lauryl Ether Sulfate (3 EO)

Light liquid

58-62

7-7.5 ( c )

50 (K) in 5% aq

WITCOLATE WITCOLA TE LES-60C

Sodium Lauryl Ether Sulfate (3 EO)

Light liquid

60

7.5-9 ( c )

1 ( G)

4 ( G)

A L K Y L A R Y L E T H E R S U L FA T E S

WITCOLATE WITCOLA TE D-51-51

Sodium Nonylphenol Ethoxylate Sulfate (4 EO)

Liquid

28-30

7.5-8.5 (b)

WITCOLATE WITCOLA TE D-51-53

Sodium Nonylphenol Ethoxylate Sulfate (10 EO)

Liquid

28-30

7.5-8.5 (b)

28


SULFATES

A L K Y L S U L FA T E S

A L K Y L E T H E R S U L FA T E S

FUNCTIONALITY

ACID # to pH 5.5

g n i l p u o C

y c n e g r e t e D


•

g n i m a o F

MARKETS

g n i t t e W




r e m a o F t n e m e C / d r a o b l l a W

e l i t x e T

KEY

• •

•

S

•

•

•

M

3

•

•

•

3.5

•

•

•

L

•

•

A L K Y L A R Y L E T H E R S U L FA T E S

•

•

•

(M)) Mo (M Mode dera rate te

• •

M

•

•

3.5 1.3

•

•

•

•

3.5

•

•

•

•

1-1.8

•

•

•

•

1.8

•

•

•

•

1-1.8

•

•

•

•

0.7

•

•

•

•

•

•

•

•

1.8-2.3

•

•

•

•

1.3

•

•

•

1.8-2.3

•

•

•

•

1.3

•

•

•

•

1.7

•

•

•

•

M

•

•

S

•

• •

2

4

(S )

S up upe riri or or

(L)

Low

(a)

As is

(b)) (b

5% aq aq sol solutio u tionn

(c)) (c

10 % aq so solu luti tion on

(A)

APHA

(G )

G ar ar dn dn er er

(K)

Klett

(PCC)Platinum Cobolt Color (T%) % transmi transmittance ttance

•

•

•

•

•

•

•

S

•

•

•

•

•

•

S

•

•

•

•

•

•

S

•

•

•

•

M

•

•

•

•

S

•

•

•

•

M

•

•

•

M

•

•

•

M

•

•

•

•

M

•

•

•

•



29

PHOSPHATE ESTERS

Phosphate Esters Phospholan™ organic phosphate esters are derived from ethoxylated alcohols, alkyl phenols or phenols and are composed of mixtures of mono- and diesters. Most of these surfactants surfactants are supplied as free acids that can be converted to to salts by the addition of bases. Excellent compatibility,, detergency, coupling, emulsification and low to moderate compatibility foaming can be attained by the proper selection from the Phospholan Phospholan phosphate esters listed below.

PRODUCT

DESCRIPTION

APPEARANCE


MOISTURE %, MAX

COLOR, MAX

ACID # to pH 5.5

A L C O H O L P H O S P H AT E

PHOSPHOLAN NBAP

N-Butyl Mono/DiPhosphate

Liquid

96-99

1

4 (G )

300-320

PHOSPHOLAN PS-400

C6-10 Alkyl Phosphate Ester

Liquid

96-99

0.5

1 (G )

213-224

-

A L C O H O L E T H O X Y L AT E P H O S P H AT E

PHOSPHOLAN 5AP

C8-10 Alcohol Ethoxylate Phosphate Ester

Liquid

96-99

1

2 (G )

PHOSPHOLAN PS-131

Tridecyl Alcohol Ethoxylate Phosphate Ester

Liquid

96-99

1

2 ( G)

75-85

PHOSPHOLAN PS-220


Liquid

96-99

1

8 (G )

104-109

PHOSPHOLAN PS-222


Clear-slightly ha hazy lil iquid

96-99

1

1 (G )

101-109

PHOSPHOLAN PS-236


Liquid

96-99

2

2 (G )

90-93

PHOSPHOLAN PS-331

C12-14 Sec. Alcohol Ethoxylate Phosphate Ester

Amber liquid

90

1

1 ( G)

140-143

PHOSPHOLAN PS-413

Butyl Cellosolve Phosphate Ester

Liquid

77-82

0.5

12 (G)

342-348

PHOSPHOLAN PS-810

Oleyl Alcohol Ethoxylate Phosphate Ester

Clear-slightly ha hazy liliquid

96-99

1

1 (G )

84-90

PHOSPHOLAN PS-900

Tridecyl Alcohol Phosphate Ester

Liquid

96-99

1.5 - 2.0

3 (G )

151-163

A L K Y L P H E N O L E T H O X Y L AT E P H O S P H AT E

PHOSPHOLAN 9NP

Nonylphenol Ethoxylate Phosphate Ester

Yellow viscous liquid

96-99

1

2 ( G)

-

PHOSPHOLAN CS-121


Liquid

96-99

1

3 (G )

92-98

PHOSPHOLAN CS-131


Liquid

96-99

0.4

1 (G )

93-101

PHOSPHOLAN CS-1361 Nonylphenol Ethoxylate Phosphate Ester, Sodium Salt Liquid

90

9.5/10.5

100 (A)

25-35 (AV)

PHOSPHOLAN CS-141


Liquid

96-99

1

100 (A)

63-67

PHOSPHOLAN CS-147


Liquid

96-99

1.5

4 (G )

86-90

PHOSPHOLAN CS-151


Liquid

96-99

0.5

200 (A)

50-56

PHOSPHOLAN CS-341

Dinonylphenol Ethoxylate Phosphate Ester

Liquid

96-99

1

6 (G )

61-63

PHENOL ETHOXYLATE PHOSPHATE

PHOSPHOLAN TS-210

Phenol Ethoxylate Phosphate Ester

Liquid

96-99

1

4 (G )

154-160

PHOSPHOLAN TS-211


Liquid

83-87

1

7 (G )

230-260

PHOSPHOLAN TS-230


Liquid

96-99

1-2

8 ( G)

84-90

Liquid

43

50 (A)

1.85-2.03 (TA)

A L K Y L A M I N E P H O S P H AT E

PHOSPHOLAN TEAP

30

Triethylammonium Phosphate


PHOSPHATE ESTERS


A L K Y L P H E N O L E T H O X Y L AT E P H O S P H AT E

A L C O H O L E T H O X Y L AT E P H O S P H AT E

PHENOL ETHOXYLATE PHOSPHATE

A L K Y L A M I N E P H O S P H AT E

KEY FUNCTIONALITY

(A) (G)) (G

APHA Gardne Gard nerr for for colo colorr or Good for other (H) High (M)) Mo (M Mode dera rate te (L) Low (AV) (A V) acid value value

FREE PHOSPHORIC ACID, MAX

t a t s i t n A

g n i p o r t o r d y H

4

•

3

•

r o t i b i h n I n o i s o r r o C

g n i l p u o C

•

•

-

•

2 •

1.5

•

•

•

•

•

17.5 - 22.5

• •

•

3

3

•

•

L

M

•

•

M/L

M

•

•

t a t s i t n A / c i t s a l P

r e p a P

•

•

•

•

•

M/L

•

M

•

L

•

G

•

•

•

•

M/L

•

M

•

•

•

•

•

•

•

•

•

•

•

M L

•

L

•

M

•

• •

•

• •

• •

L

•

M

M •

g n i n a e l C l a t e M

•

•

•

e r a C l a n o s r e P

•

•

•

•

•

G

•

2.5

L

e l i t x e T

g n i t t e W


•

•

•

•

g n i m a o F

n o i t a c i r b u L

r e i f i d o M y t i s o c s i V

s t n a c i r b u L

r e i f i s l u m E

• •

•

n o i s r e p s i D

•

•

-

2

y c n e g r e t e D

•

2

12

g n i m a o f e D

MARKETS

•

M/L

• •

•

M

•

M

•

• •

•

•

•

•

•

M

•

•

•

•

•

•

•

•

M

•

M

•

•

•

•

1

•

•

•

•

M/L

•

M

•

•

M

•

•

1.5

M/H •

•

L

•

•

•

-

•

G

•

1

1.5

•

•

•

M •

•

•

• •

•

3

•

•

•

•

•

•

17

•

•

•

•

•

•

3

•

•

•

•

•

•

•

•

•

•

-

•



31

SULFOSUCCINATES

Sulfosuccinates Lankropol® sulfosuccinates are well-known as mild anionics and are used where mildness and foaming are key considerations in formulating formulating liquid hand soaps and light duty liquids.

PRODUCT

DESCRIPTION

APPEARANCE


MOISTURE %, MAX

COLOR, MAX

33-36

61-64

6 ( G)

6.5-7.5*

pH


LANKROPOL 4161L

Disodium Oleamido MIPA-Sulfosuccinate

Clear amber liquid

LANKROPOL 4500

Sodium Dioctyl Sulfosuccinate

Clear-slightly hazy liquid

70

21.5

35 (A)

6*

LANKROPOL 4560

Blend

Liquid

70

1

200 (A)

4-5.5** 4-

LANKROPOL K-8300

Disodium Oleamido MIPA-Sulfosuccinate

Clear amber liquid

38

62.5

9 ( G)

6.5-7.5***

Carboxylated Ethoxylates Emcol® carboxylated ethoxylates are mild surfactants suitable for personal care cleansing applications with good emulsification and hydrotroping properties.

PRODUCT

DESCRIPTION

APPEARANCE

Carboxylated Nonylphenol + 9 EO

Liquid


MOISTURE %, MAX

COLOR, MAX

pH

80

9-11

3 (G)

1.5-3.5***


EMCOL CNP-110

32


CARBOXYLATED ETHOXYLATES

SULFOSUCCINATES

FUNCTIONALITY y c n e i l l o m E & g n i n o i t i d n o C

•

g n i l p u o C

•

n o i s r e p s i D

g n i n a e l C & y c n e g r e t e D


MARKETS t n a r e l o T e t y l o r t c e l E

g n i m a o F

g n i t t e W

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•


e l i t x e T

KEY

•

•

*

1% aq solution

**

3% aq solution

*** 5% aq solution ****10% aq solution

•

CARBOXYLATED ETHOXYLATES


g n i l p u o C


g n i m a o f e D

n o i s r e p s i D


MARKETS


g n i m a o F


g n i t t e W




KEY

•

•

•

•

•

•

*

1% aq solution

**

3% aq solution

*** 5% aq solution ****10% aq solution



33

N O N I O N I C S U R F A C TA TA N T S

34

NONIONIC SURFACTANTS

N o n i o n i c S u r f a c ta n t s Nonionic surfactants by definition contain no functionality that has a formal charge. Surface activity derives from a balance of hydrophobic and hydrophilic structures contained in the surfactant molecule. Altering the balance toward more more hydrophobic or more hydrophilic influences the surfactant’s functional properties to achieve a desired effect.

Nonionic Process Chemicals

Alcohols Polyols

Below are listed the trademarks we use to identify the nonionic surfactants we market.

Trademark

Surfactant Type

AMADOL®

Alkanolamides

ARMOTAN® ARMOT AN®

Sorbitan Ester Ethoxylates

E MUL P O N ™

Castor Oil Ethoxylates

ETHOFAT®

Fatty Acid Ethoxylates

ETHYLAN™

Linear and Branched Alcohol Alkoxylates

WITCONOL™

Alkyl Phenol Alkoxylates; Block Copolymers; PEG Esters

Nonionic surfactants have attributes that make their use advantageous over other surfactant types. With their lack of charge, nonionic surfactants are compatible with both cationic and anionic surfactants. In mixed surfactant systems systems the properties of each

EO

Glycol Ethers Fatty Acids

Akzo Nobel Surface Chemistry’s nonionic surfactant offerings use hydrophobic structures represented by fatty alc ohols/acids/esters, alkyl-substituted phenols and blocks of polypropylene oxide. oxide. Hydrophilic character is imparted using ethylene oxide and its polymers, alkanolamines and sugar polyols. Figure 1 illustrates the process chemistries we employ employ..

Alkoxylates

Alkylphenols

Sorbitol

PO

PEG-Esters Acids

Amines Castor Oil Methyl Esters

Ethoxylated Alcohol Alkyl Phenol Ethoxylates Ethoxylates EO-PO Co-polymer Ethoxylated Castor Oil

CH O 2

Alkanolamides Amine Ethoxylates Sorbitan Esters

Glycerides FIGURE 1

surfactant influence performance at the surface or interface. Detergency,, emulsification and hard s urface cleaning are applications Detergency where the use of nonionic surfactants is indicated. Further, their inverse relationship of solubility and temperature in water is particularly useful in cleaning formulations. Listed below are the examples of the types of functions that can be optimized with nonionic surfactants from Akzo Nobel Surface Chemistry: • Detergency • Wetting • Emulsification • Foam stabilization • Defoaming • Viscosifying • Solubilization The table on page 2 shows our recommendations of the surfactant type for various applications. Advice for specific products for individual requirements can be obtained by contacting our Technical Service at 1-877-565-8432.


35

NONIONICS

Nonionics Ethylan™ linear and branched alcohol ethoxylates, Witconol™ alkyl phenol ethoxylates, polyols and PEG esters offer the formulator nonionic surfactants for a wide variety of industrial cleaners and household detergents, detergents, including applications requiring requiring low foaming. PEG esters are low-irritation low-irritation viscosity modifiers when added to many anionic surfactants. Emulpon™ castor oil ethoxylates are co-emulsifiers used to balance the hydrophilic-lipophilic balance (HLB).

PRODUCT

DESCRIPTION

APPEARANCE


MOISTURE %, MAX

pH

COLOR, MAX

A L K O X Y L AT E D A L K Y L P H E N O L S

WITCONOL 9N

Nonyl Phenol (9 EO) Ethoxylate

Liquid

100

0.2

5-7***

100 (A)

WITCONOL NIO

Dodecyl Phenol (6 EO) Ethoxylate

Clear yellow liquid

100

0.3

7-8.5 (d)

4 ( G)

WITCONOL NIW

Dodecyl Phenol (11 EO) Ethoxylate

Clear yellow liquid

92

8

7-8.5 (h)

6 ( G)

WITCONOL NP-100


Liquid

99

0.3

5-8 (a)

100 (A)

WITCONOL NP-120


Light liquid

99

0.3

5-8 (a)

100 (A)

WITCONOL NP-15

Nonyl Phenol (1.5 EO) Ethoxylate

Liquid

99

0.2

6-7.5 (f)

WITCONOL NP-200


White solid

99

0.5

6-7.5***

1 ( G)

WITCONOL NP-300


White solid

99

0.5

6-7.5 (b)

100 (A)

WITCONOL NP-330

Nonyl Phenol Ethoxylate/Propoxylate

Light liquid

99

0.5

6-8 (b)

3 ( G)

WITCONOL NP-40


Liquid

99

0.5

5-8 (a)

2 ( G)

WITCONOL NP-400


White solid

99

0.5

6-7.5 (b)

1 ( G)

WITCONOL NP-507


Viscous liquid

70

30

6-8***

1 (G)

WITCONOL NP-60


Liquid

99

0.2

5-8 (a)

200 (A)

WITCONOL NP-90


Liquid

99

0.3

5-8****

1 ( G)

WITCONOL NS-108LQ

Nonyl Phenol Ethoxylate/Propoxylate

Liquid

99

0.2

6-7 (e)

WITCONOL S-100

Octyl Phenol (10 EO) Ethoxylate

Liquid

100

0.5

5-7*

100 (A)

A L K O X Y L AT E D A L C O H O L S

ETHYLAN 1204

C12-14 Alcohol (4 EO) Ethoxylate

Liquid

99

0.2

6-7***

100 (A)

ETHYLAN 1206

C10-12 Alcohol Ethoxylate/Propoxylate

Liquid

99

0.5

6-8 (b)

6 ( G)

ETHYLAN 4061

Butanol EO/PO Copolymer in PG

Light liquid

70

0.5

6-8

ETHYLAN 25-3


Liquid

100

0.1

5.5-7.5*

50 (A)

ETHYLAN DA-4

Isodecyl Alcohol (4 EO) Ethoxylate

Clear-hazy liquid

100

0.5

5-7 (b)

100 (A)

ETHYLAN DA-9

Isodecyl Alcohol (9 EO) Ethoxylate

Clear-hazy liquid

100

0.2

6-7***

ETHYLAN LA-230


Solid

100

0.1

5-7*

ETHYLAN NS-500LQ

Butanol Ethoxylate/Propoxylate

Hazy liquid

99

0.2

6.5-7.5 (b)

3 ( G)

ETHYLAN OLA-200

Oleyl Alcohol (20 EO) Ethoxylate

Light amber solid

100

0.2

6.5-7.5***

2 (G)

ETHYLAN PT-750

Glycerin (13 PO) Propoxylate

Clear liquid

100

0.5

5-7*

ETHYLAN SN-120


Light liquid

100

0.2

6-8*

ETHYLAN SN-70


Clear-Hazy pale yellow liquid

100

0.2

6-7*

ETHYLAN SN-90


Light liquid

100

0.5

6-8*

ETHYLAN TD-100

Tridecyl Alcohol (10 EO) Ethoxylate

Clear liquid

100

0.2

6.5-7.5***

ETHYLAN TD-1407


Clear liquid

75

24-25

6.5-8.5***

ETHYLAN TD-60


Pale yellow liquid

100

0.5

6-8*

36


200 (A)

1 ( G) 1 ( G)

200 (A)

NONIONICS

A L KO X Y L AT E D A L K Y L P H E N O L S

A L KO X Y L AT E D A L C O H O L S

FUNCTIONALITY

CLOUD PT. °F

HLB

g n i l p u o C


r e m a o f e D

12.6 9

•

n o i s r e p s i D


g n i m a o F

•

•

•

•

•

•

12.6

•

•

52-61 °C

13.1

•

•

168-180

14.1

•

4.6


•

120-130

MARKETS


g n i t t e W

n o i t n a c i r b u L

•



•

•

•

•

• •

•

•

•

•

•

e l i t x e T


•

KEY *

1% aq

**

3%aq

* ** ** 5% aq aq

•

•

•

(a)

1% in 62.5% IPA

(b)

5% in 25% IPA

(c)

1% in 25% IPA

(d)

5% in 50% IPA

160-164

16 16

•

•

•

165-170

17.2

•

•

•

•

•

•

•

•

•

•

(g)

1% in 75% IPA

•

(h)

5% in 50% Ethanol

142-152 8.9 175-180

•

17.8

• •

18.2 10.9 124-133

•

13

170-185 62-68 °C

62-66 °C 88-92

•

•

•

•

•

•

• 9.5

•

•

• 15.6

85-91.7 °C

14.3

•

36.7-38.9 °C

12

•

58.3-60

12.9

•

13.7

•

•

•

•

•

• •

•

•

• •

• L

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

• •

•

•

•

•

•

• •

• •

•

•

•

•

• 11.4

Low Foa m

W/O Wa Water ter-in -in-oi -oill

•

•

32-40 °C

( L)

W /O

17 45-55 °C

•

•

8 10.5

APNA

•

•

5% in 75% IPA

Gardne r

•

W/O

• 65-75

•

1% in 50% IPA

(f)

(G)

• •

(e)

(A)

•

• 13.4

•

W/O

•

•

•

****10% aq

•

• •

• •

•

•

• •

•

•

•

•

• L

•

•

•



37

NONIONICS

PRODUCT

continued

DESCRIPTION

APPEARANCE


MOISTURE %, MAX

pH

COLOR, MAX

POLYOLS

WITCONOL 324

EO/PO Copolymer

Paste

100

0.2

6-8 (f)

WITCONOL 324D

Witconol 324 in Butyl Cellosolve/Water

Liquid

51-53

13.5

5-7 (b)

WITCONOL PEG-400

Polyethylene Glycol 400

Liquid

100

0.5

6.5*

WITCONOL PD-2000

Polypropylene Glycol 2000

clear amber liquid

100

0.5

12 typical (g)

ARMOTAN AL-69-66 AL-69-66

Sorbitol Tallate (30 EO) Ethoxylate

Liquid

100

0.5

EMULPON CO-100

Castor Oil (10 EO) Ethoxylate

Liquid

99

0.5

EMULPON CO-200


Liquid

99

EMULPON CO-360


Paste

99

EMULPON CO-550


Paste

99

0.5

6-8

P O L YO YO L E S T E R S

6-7 (b)

6 (G )

0.5

6-7 (b)

6 (G )

0.2

6.5-7.5 (b)

ETHOFAT 242/25

Tall Oil Fatty Acid (15 EO) Ethoxylate

Liquid

99

3

6

12 (G)

WITCONOL 14

Polyglycerol Oleate

Liquid

100

0.2

8-9.5**

10 (G)

WITCONOL H-31A

PEG 400 Monooleate

Clear amber liquid

100

0.5

3-4**

3 (G)

WITCONOL H-32

PEG 600 Ditallate

Clear amber liquid

100

0.5

6-7**

8 (G)

WITCONOL H-33

PEG 400 Ditallate

Amber liquid

100

0.5

5-8***

8 (G)

A L K O X Y L AT E D R E S I N S

WITCONOL NS-98

Resin Alkoxylate

Hazy viscous liquid

94

0.2

WITCONOL NS-145

Resin Ethoxylate/Propoxylate

Dark amber lizuid

99

0.3

WITCONOL NS-179

Resin Propoxylate

Amber liquid

99

0.3

38


continued

NONIONICS

POLYOLS

FUNCTIONALITY

CLOUD PT. °F

HLB

158-164

8.0

g n i l p u o C


r e m a o f e D

n o i s r e p s i D

•

•

•

•



MARKETS

g n i m a o F


•

g n i t t e W

n o i t n a c i r b u L



e l i t x e T

KEY

• •

•

•

•

•

•

*

1% aq

**

3%aq

* ** ** 5% aq aq ****10% aq

•

•

6.3


•

•

(a)

1% in 62.5% IPA

(b)

5% in 25% IPA

(c)

1% in 25% IPA

(d)

5% in 50% IPA

(e)

1% in 50% IPA

(f)

5% in 75% IPA

10.2

•

(g)

1% in 75% IPA

166-176

13.5

•

(h)

5% in 50% Ethanol

138-142

14.4

•

(G)

Gardne r

12.2

•

6

•

•

12.5

•

•

10

•

•

8.4

•

•

•

•

•

•

•

•

•

•

•

•

•

•

• •

• • •



39

A L K A N O L A M I D E S

A l k a n o l a m i d e s Amadol® alkanolamides are reaction reaction products of various fatty acids and short chain amines in 1:1 or 2:1 ratios. These perform as foam boosters and viscosity control agents for detergents, cleaners and hand soaps.

PRODUCT

DESCRIPTION

APPEARANCE


MOISTURE %, MAX

pH

COLOR, MAX


AMADOL 1017

Modified Cocamide DEA

Clear amber liquid

95

0.5

8-10***

160 (K)

AMADOL 128 T

Cocamide DEA (1:1)

Clear amber liquid

90

0.5

9-10.5*

5 (G)

AMADOL 272


Liquid

90

9.5-10.5

6.8-8.8*

14 (G)

AMADOL 511

Fatty Alkanolamide

Clear-hazy amber liquid

98

0.3

9-11**

11 (G)

AMADOL 511H

Fatty Alkanolamide

Clear amber liquid

90

0.5

8-10**

10 (G)

AMADOL 512

Blend

Dark liquid

47

20-25

8-9*

AMADOL 5130


Clear amber liquid

95

2

8* (typical)

14 (G)

AMADOL 5133

Cocamide DEA (2:1)

Clear amber liquid

95

0.5

9-12.5*

8 (G)

AMADOL 5138

Fatty Alkanolamide

Clear tan liquid

90

1

9.2-9.7***

10 (G)

AMADOL 5195

Lauramide DEA

Clear yellow liquid

92

0.5

9-11*

2 (G)

AMADOL 61

Oleamide MIPA

Paste (yellow-light tan)

>90

0.5

8-9.5*

AMADOL CDA


Clear amber liquid

>90

0.5

8-10*

7 ( G)

AMADOL WE

Fatty Alkanolamide

Clear-hazy amber liquid

99

0.3

9-10**

11 (G)

40





g n i l p u o C


g n i m a o f e D

• •

•

•

•

•

•

•

•

g n i t s o o B m a o F


•

•

•

•

•

W/O

•

•


•

•

•

•

W/O

•

•

•

•

W/O

•

•

•

•

•

•

• •

n o i s r e p s i D


•

•

•

•

•

•

MARKETS

g n i t t e W



• •

• •

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

e l i t x e T

KEY

•

•

•


/ g n i k r o W l a t e M / r e p k a n P I

1% aq solution

**

3% aq solution 5% aq solution

•

•

***

•

•

**** 10% aq solutio solutionn

•

•

• •

•

*

•

(a)

5% in 25% IPA

(b)

5% in 75% IPA

(G)

Gardner

(A)

APHA

(K)

Klett

•

•

•

•

(s)

•

•

(W/O) Wat Waterer-inin-Oil Oil

(PCC) Platinum Cobolt Color

% solid

• •

•

•

•



41

A P P E N D I C E S

42

AP PE ND IC ES

Ta b l e 1 : S o l u b i l i t y D a t a f o r F a t t y A l k y l A m i n e s All temperatures are in degrees Centigrade. Solubilities are in g amine per 100 g/solvent. NO. OF CARBON ATOMS IN AMINES

NO. OF CARBON ATOMS IN AMINES

TEMPERATURE

TEMPERATURE

A C E T O N E

BENZENE

10.0°

20.0°

30.0°

40.0°

50.0°

-20.0°

0.0°

20.0°

30.0°

40.0°

50.0°

10

395

∞

∞

∞

∞

10

6.6

54

∞

∞

∞

∞

12

72

277

∞

∞

∞

12

0.3

8.1

266

∞

∞

∞

14

26.4

83

302

∞

∞

14

0.1

15.5

228

∞

∞

16

10.0

30.7

98

388

∞

16

<0.1

4.7

445

∞

18

4.2

14.8

52

173

1000

18

<0.1

3.7

17.0

2-BUTANONE

CYCLOHEXANE

10.0°

20.0°

30.0°

40.0°

50.0°

-20.0°

0.0°

20.0°

30.0°

40.0°

50.0°

10

318

∞

∞

∞

∞

10

13.3

69

∞

∞

∞

∞

12

57

230

∞

∞

∞

12

4.4

23.0

221

∞

∞

∞

14

19.9

68

268

∞

∞

14

1.4

9.7

62

233

∞

∞

16

7.4

26.6

86

360

∞

16

0.2

3.5

23.9

64

295

∞

18

2.8

13.2

42.9

144

940

18

1.0

11.4

30.4

100

845

METHANOL

TETRACHLOROMETHANE

-40.0° -20.0° 0.0°

20.0°

30.0°

40.0°

50.0°

10

31.0

∞

∞

∞

∞

12

∞

14

-20°

0.0°

20.0°

30.0°

40.0°

50.0°

10

10.5

57

∞

∞

∞

∞

12

5.5

19.8

148

∞

∞

14

2.3

7.7

56

235

∞

16

0.5

3.2

21.2

73

335

∞

16

18

<0.1

0.6

7.7

27.9

120

835

18

TRICHLOROMETHANE

-40.0° -20.0°

172

550

∞

4.8

29.7

196

930

∞

∞

∞

0.2 0.2

2.8

62

292

770

∞

∞

0,2

6.1

116

256

785

∞

0.6

15.6

95

256

1440

20.0°

30.0°

40.0°

50.0°

ETHANOL

0.0°

20.0°

30.0°

40.0°

50.0°

-40.0° -20.0° 0.0°

10

17.7

43.0

148

∞

∞

∞

∞

10

8.5

91

350

∞

∞

∞

∞

12

9.2

20.0

56

315

∞

∞

∞

12

2.0 2.

14.1

115

660

∞

∞

∞

14

4.5

11.2

29.5

110

308

∞

∞

14

1.5

30.2

218

660

∞∞

16

2.4

6.6

17.0

56

117

378

∞

16

3.0

83

239

770

∞

18

1.2

3.3

9.4

31.9

63

149

845

18

0.1

7.2

75

280

1630

-40.0° -20.0° 0.0°

20.0°

30.0°

40.0°

50.0°

11.1

49.0

228

∞

∞

∞

∞

ISOPROPANOL

ETHYL ETHER

-40.0°

-20.0°

0.0°

20.0°

30.0°

34.5°

10

1.4

12.1

86

∞

∞

∞

10

12

0.2

3.4

22.6

275

∞

∞

12

4.7

15.0

75

492

∞

∞

∞

0.2

5.8

71

273

705

14

0.6

3.7

25.1

154

458

∞

∞

0.2

18.5

72

135

16

0.4

7.3

68

169

580

∞

4.4

22.7

46.8

18

0.5

30.0

86

228

1330

-40.0° -20.0° 0.0°

20.0°

30.0°

40.0°

50.0°

9.5

∞

∞

∞

∞

14 16 18 ETHYL ACETATE

n–BUTANOL

-20.0°

0.0°

20.0°

30.0°

40.0°

50.0°

10

14.8

69

∞

∞

∞

∞

10

12

4.7

18.6

211

∞

∞

∞

12

14

1.7

7.8

57

233

∞

∞

14

16

0.3

3.2

19.7

63

295

∞

16

0.9

9.5

27.0

100

845

18

18 BUTYL ACETATE

-20.0°

30.8

182

2.4

8.5

57

430

∞

∞

∞

0.2

2.4

16.5

130

405

∞

∞

<0.1

3.9

55

148

515

∞

0.4

22.7

75

208

1240

20.0°

30.0°

40.0°

50.0°

A C E T O N I T R I L E

0.0°

20.0°

30.0°

40.0°

50.0°

-20.0°

0.0°

2.8

12.7

∞

∞

∞

∞

0.2

27.7

∞

∞

∞ ∞

10

13.3

69

∞

∞

∞

∞

10

12

4.4

23.0

221

∞

∞

∞

12

14

1.4

9.7

62

233

∞

∞

14

1.8

14.9

∞

16

0.2

3.5

2 3.9

64

295

∞

16

0.2

1.3

14.8

∞

1.0

11.4

30.4

100

845

18

0.3

1.9

10.5

18

AP PE ND IC ES

43

Ta b l e 2 : S o l u b i l i t y C h a r a c t e r i s t i c s o f E t h o x y l a t e d ® P r o d u c t s At room temperatures (g/100 g solution at 25˚C/77˚F).

PRODUCT

ACETONE 0

ISOPROPANOL

25

50

75

100

0

25

CARBON TETRACHLORIDE 50

75

100

0

25

ETHOFAT 242/25 ETHOMEEN® C/12 ETHOMEEN C/15 ETHOMEEN C/20 ETHOMEEN C/25 ETHOMEEN 18/12 ETHOMEEN 18/15

very cloudy

fluid

paste

paste

ETHOMEEN 18/60

cloudy

paste

cloudy

ETHOMEEN T/12 ETHOMEEN T/15

sl. cloudy

ETHOMEEN T/25

very cloudy

cloudy

paste

ETHOMEEN S/12 ETHOMEEN S/15

cloudy

ETHOMEEN S/20

cloudy

ETHOMEEN S/25

cloudy

ETHOMID® HT/23

fluid

ETHOMID HT/60

paste

ETHOMID O/17 ETHOQUAD® C/12 ETHOQUAD C/25 ETHOQUAD 18/12 ETHOQUAD 18/25 ETHOQUAD 0/12

44

AP PE ND IC ES

paste

cloudy

cloudy

cloudy

cloudy

cloudy

50

75

100

KEY

DIOXANE 0

25

STODDARD SOLVNET 50

75

100

0

25

50

Solution

Gel

Dispersion

Insoluble

BENZENE 75

100

0

25

WATER 50

75

100

0

25

50

75

100

viscous

cloudy

cloudy

paste

sl. cloudy

cloudy

paste

cloudy

paste

very cloudy

cloudy

paste

cloudy

cloudy

paste

cloudy

cloudy

viscous

fluid

paste

paste

cloudy

paste

paste

stiff

paste

fluid

paste

fluid

paste

paste

paste

viscous

AP PE ND IC ES

45

T ab l e 3 : S o l ub i l i ty D a t a F or Q u a t er n a ry A m m o ni u m Compounds at 25ºC QUATERNARY AMMONIUM AMMONIUM SALT**

WATER

METHANOL/ ETHANOL/ ETHANO L/ ISOPROPANOL

ACETONE

BENZENE

N-HEXANE/ N-HEXA NE/ CYCLOHEXANE

CHLOROFORM

XX

XX

NA

O

O

XX

XX

NA

NA

D

XX

X

XX

NA

XX

XX

NA

NA

Arquad Benzylalkyl

XX

XX

XX

X

NA

NA

NA

NA

NA

Duoquad Alkyl Diquaternary

XX

XX

NA

O

O

XX

XX

NA

NA

Ethoquad Ethoxylated Quaternary

XX

XX

XX

XX

NA

NA

XX

XX

O

Propoquad Propoxylated Quaternary

XX

XX

XX

XX

NA

NA

XX

XX

NA

Arquad Alkyltrimethyl

Arquad Dialkyldimethyl

* Solubility Solubility generally generally decreases decreases in a given solvent with increasing increasing chain chain length of alkyl substituent substituents. s. ** Most quaternar quaternaryy ammonium ammonium salts are are soluble in hot ethyl ethyl acetate. acetate. KEY

XX X D O

46

Very Soluble ( ≥5% by weight) Slightly Soluble (between 1 and 5% by weight) Disp Di sper ersi sibl blee Insoluble Insolu ble <0.5% < ( 0.5% by weight) weight)

AP PE ND IC ES

CARBON CARBO N HEXYLENE (1,2) GLYCOL TETRACHLORIDE

MINERAL OIL

C U S TO M E R S E R V I C E & T E C H N I C A L S U P P O R T

CUSTOMER SERVICE & TECHNICAL SUPPORT

47

Tr a d e m a r k e d P r o d u c t s N o t L i s t e d i n C a t a l o g This catalog provides information on those products which have a broad range of industrial applications. However However,, Akzo Nobel Surface Chemistry LLC markets many more that are directed toward specific applications or markets. To facilitate obtaining information on these products, products, their trademarks are listed below alphabetically with their main application area identified. For more information on any products using these trademarks, please contact Customer or Technical Service.

Trademark

Responsible Marketing Function

Trademark

Responsible Marketing Function

ADSEE®

Agro Applications

EMULPONTM

Agro Applications

AGTM

Cleaning Applications

ETHOPROPOMEEN TM

Agro Applications

AMADOL®

Mining Applications

FLO MO®

Agro Applications

ARDEFOAM ARDEFOA MTM

Industrial Applications

KETJENLUBE ®

Oilfield Applications

ARMACFLOT ARMAC FLOT®

Mining Applications

KETJEN-OX®


ARMIXTM

Agro Applications

LASARTM

Agro Applications

ARMOCARE ARMOCAR E®

Personal Care

LILAMINTM

Mining Applications

ARMOFLOTM

Mining Applications

MORWET®

Agro Applications

ARMOGLOSS®


PCTM


ARMOLUBE®


PROPODUOMEEN TM

Asphalt Applications

ARMOSOFT®

Fabric Care

REDICOTE®


ARMULTM

Agro Applications

SPONTO®

Agro Applications

BALAB®


WETFIX®


BEROL SPIN®

Viscose

WITBREAK TM


BEROL VISCOTM

Viscose

WITCAMINETM


BEROL®


WITCODETTM


DUOMAC®

Mining Applications

WITCOMULTM


ELFACOS®

Personal Care

WITCORTM


ELFAN®

Personal Care

WITFLOWTM


EMPHOS TM

Agro Applications

48

CUSTOMER SERVICE AND TECHNICAL SUPPORT

Surface Chemistry C u s t o m e r S e r v i c e a n d Te Te c h n i c a l S u p p o r t North America

Customer Service

Technical Support

Akzo Nobel Surface Chemistry LLC 525 W. Van Buren Street Chicag Chi cago, o, IL IL 606 6060 07-3 7-3823 823 United States

Tel el:: (800 (800)) 906906-99 9977 77 (312) 544-7000 Fax: (312) 544-7159

Tel el:: (877 (877)) 565565-84 8432 32 (312) 544-7139 Fax: (312) 544-7410

[email protected] http://surface.akzonobelusa.com

Regional Offices A s i a / A u s t r a l i a

Europe/Middle East/Africa

Brazil

Akzo Nobel Chemicals Pte. Ltd 41, Science Park Road # 03-03 & 12 The Gemini Singapore Science Park Park II SG-117610 Singapore

Akzo Nobel Surface Chemistry AB SE-444 85 Stenungsund Sweden

Akzo Nobel Ltda - Divisão Quimica Rodovia Akzo Nobel 707 Bairro São Roque da Chave 13295-000 Itupeva, São Paulo Brazil

Tel: +46 303 85000 Fax: +46 303 770578

Tel: +65 773 8488 Fax: +65 773 8484

www.surfactan www .surfactantsasia.akzo tsasia.akzonobel.com nobel.com

Tel: +55 11 4591 8800 Fax: +55 1 11 1 4591 4591 1495 www.se.akzonobel.com www.se.akz onobel.com OR: www.surface.akzonobel.com

www.akzonob www .akzonobel.com.br el.com.br

Akzo Nobel, based in the Netherlands, serves customers throughout th e world with healthcare products, coatings and chemicals. The Company currently employs approximately 64,000 people in more than 80 countries. All information concerning these products and/or all suggestions for handling and use contained herein are offered in good faith and believed to be reliable. Akzo Nobel Surface Chemistry LLC and its affiliates, however, however, make no warranty as to the accuracy and/or sufficiency of such information and/or suggestions, as to the products’ products’ merchantability or fitness for any particular purpose, purpose, or that any suggested use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by preliminary tests tests or otherwise,, the suitability of these products for his purposes. The information contained herein supersedes all previously issued bulletins on the subject otherwise matter covered. The user may forward, distribute distribute and/or photocopy this document only if unaltered and complete, including all of its headers and footers, and should refrain from any unautho rized use. You may not copy this document to a website.

©2004 Akzo Nobel Surface Chemistry LLC, all rights reserved

Publication SC04-10

Akzo Nobel Surface Chemistry LLC 525 W. Van Buren Street Chicag Chi cago, o, IL 606 60607 07-38 -3823 23 United States http://surface.akzonobelusa.com

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