C 142 (Expt. No. 1) NAME : ______________________ _________________________________ ______________ ___ ROLL No. : ______________________ _________________________ ___ SIGNATURE : ______________________ ___________________________ _____
BATCH : _______ DATE :
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DETERMINATION OF THE HEAT OF SOLUTION (Δ H ) OF OXALIC ACID FROM ITS SOLUBILITY AT DIFFERENT TEMPERATURES AIM To determine the solubility of oxalic acid in and to calculate the heat of solution ( Δ H ). ).
water at
different temperatures,
THEORY
The dissolution of a solid into a liquid is usually accompanied with a heat effect (heat is either evolved evolved or absorbed). absorbed). The heat heat evolved or absorbed absorbed can be determined when 1 mole of the solid is dissolved in a solution which is already saturated. Since the solubility of a substance is a special case of the equilibrium constant, the van’t Hoff relation is applicable. Thus, by obtaining the solubility at different temperatures, and by applying the van’t Hoff equation, it is possible to determine the heat of solution (Δ H ). ). When applied applied to solubility, the the van’t Hoff equation equation can be expressed expressed as : log s = Δ H / 2.303 RT (1) where s is the solubility at different temperatures (T ), ), Δ H is the average heat of solution over the temperature range used, and -1 -1 R = 8.314 J mol degree . The solubility is expressed as grams of solute per 100g of solvent. The heat of solution so calculated is approximately the average heat of solution over the temperature range studied, and corresponds corresponds to the heat heat of solution at the saturation concentration. In this experiment, the heat of solution of oxalic acid in water will be measured o temperatures (25 , 30 , 35 , and 40 C). at 4 temperatures MATERIALS REQUIRED Oxalic acid, 2N NaOH solution, thermometer, water bath, distilled water, hard glass test tube, pipettes (2 ml), phenolphthalein indicator. PROCEDURE 1. 25 ml of distilled water is taken in the hard glass test tube containing a given amount of oxalic acid.
2. The solution is temperatures on the temperature).
made saturated, and this solution is brought to different hot water bath (or ice cubes when required to lower the
3. The saturated solution is maintained at 4 different temperatures , in turn. At each temperature , 2 ml of the saturated solution is pipetted out using a filter tip attached to the pipette (a rubber tubing stuffed with glass wool / cotton), so as to prevent solid particles from entering into the pipette. 4. This solution is titrated against 0.2N NaOH solution, using phenolphthalein as indicator. 1
OBSERVATIONS AND CALCULATIONS
1. From the volumes of NaOH used and its strength, the weight of oxalic acid and the equivalent weight of oxalic acid, calculate the grams of oxalic acid per 100 g of water for each temperature. 2. Suppose the solubilities come out to be s1, s2, s3, s4 at the 4 different temperatures. Then these values are converted into solubilities, in moles per 1000 g of water, as follows : o
S1 (moles per 1000 g of water ) = (s1 x 1000) / m1 x 100 at T 1 C, o S2 (moles per 1000 g of water ) = (s2 x 1000) / m1 x 100 at T 2 C, and so on for S3 and S4 .
Here, m1 is the molecular weight of oxalic acid = 126.0 This will give the solubility of oxalic acid (in moles per 1000g each temperature. 3.
Plot log S versus 1 / T ,
Note S corresponds (water).
to
the
and obtain
solubility
of
Δ H
of
water) at
from the slope.
oxalic
acid
in
1000 g
of
solvent
Table 1 __________________________________________________________________ Serial No. Temperature Volume of NaOH Solubility o o C K required (ml) __________________________________________________________________ 1 2 3 4 __________________________________________________________________
RESULTS
2
