EXPERIMENT 1
BENZOIC ACID Appearance: white. Warning! Causes respiratory tract irritation. Causes severe eye irritation and possibe in!ury. Causes "oderate s#in irritation. May cause aer$ic s#in reaction. May be har"%u i% swaowed& inhaed& or absorbed throu$h the s#in. Target Organs: 'un$s& eyes& s#in.
Chemical Stability: (tabe under nor"a te"peratures and pressures. )oatie in stea". Conditions to Aoid: *ust $eneration& e+cess heat. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& stron$ bases& a"ines& a""onia& isocyanates. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide.
EXPERIMENT -
()ACIA) ACETIC ACID Appearance: cooress iuid. /ash Point: 0 de$ C. Danger! Corrosive. *lammable li+&id and aor, Causes severe di$estive and respiratory tract burns. Causes severe eye and s#in burns. May be har"%u i% absorbed throu$h the s#in. Acetic acid %or"s ice2i#e soid beow 3-4/ 5164C7. Target Organs: Teeth& eyes& s#in& "ucous "e"branes.
Boiling 'oint: 1162118 de$ C *ree%ing-#elting 'oint: 13.3 de$ C #olec&lar *orm&la: C-9;#olec&lar Weight: 3<.< Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& e+cess heat. Incomatibilities "ith Other #aterials: Metas& acetic anhydride& acohos& a"ines& a""oniu" nitrate& chorine tri%uoride& nitric acid& per"an$anates& pero+ides& sodiu" h ydro+ide& sodiu" pero+ide& hydro$en pero+ides& acetadehyde& caustics 5e.$. a""onia& a""oniu" hydro+ide& caciu" hydro+ide& potassiu" hydro+ide& sodiu" hydro+ide7& acid anhydrides& chorosu%onic acid& oeu"& chro"iu" trio+ide& potassiu" hydro+ide& carbonates& bro"ine penta%uoride& perchoric acid& chro"ic anhydride& potassiu"2tert2buto+ide& caciu" sats& ethyenei"ine& Attac#s so"e %or"s o% pastics& rubbers& and coatin$s.& -2a"inoethano& ethyene dia"ine& phosphorus trichoride& chro"ic acid anhydride& phosphorus isocyanate& diay "ethy carbino = o,one& nitric acid = acetone& +yene& sodiu" sats. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur.
n.B/TANO) Appearance: coouress. /ash Point: 06 de$ C. Warning! *lammable Warning! *lammable li+&id and aor, May be har"%u i% swaowed. May cause centra nervous syste" depression. May cause adverse reproductive e%%ects based upon ani"a studies. May cause iver and #idney da"a$e. Causes severe eye and s#in irritation. Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. Causes respiratory tract irritation. May be har"%u i% absorbed throu$h the s#in. Target Organs: ?ood& #idneys& centra nervous syste"& iver& eyes& ears.
Boiling 'oint: 116. de$ C *ree%ing-#elting 'oint: 2< de$ C #olec&lar *orm&la: C905C9-7-C9-;9 #olec&lar Weight: 6.1Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& e+cess heat.
Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents& reducin$ a$ents& acid chorides& a#ai "etas& au"inu"& copper& copper aoys& hao$ens& or$anic pero+ides& acid anhydrides& chro"iu" trio+ide& "inera acids. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur.
NIN$0D1IN SO)/TION Appearance: si$hty yeow. 'i$ht sensitive. Causes eye and s#in irritation. Warning! Causes respiratory tract irritation. 9ar"%u i% swaowed. May be har"%u i% absorbed throu$h s#in or i% inhaed. Target Organs: Eyes& s#in& "ucous "e"branes.
*ree%ing-#elting 'oint: 33 de$ / 5dec7 #olec&lar *orm&la: C93; #olec&lar Weight: 168.1 Chemical Stability: (tabe under nor"a te"peratures and pressures. May discoor on e+posure to i$ht. Ninhydrin beco"es anhydrous with reddenin$ at -@64/& swes at -8-4/ and deco"poses at 334/. Ninhydrin is sensitive to proon$ed e+posure to i$ht. ) spectrophoto"etric stabiity screenin$ indicates that soutions o% this co"pound in ethano are stabe %or at east - hours. Conditions to Aoid: 9i$h te"peratures& i$ht& dust $eneration. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& bases& a"ines. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur.
EXPERIMENT 0
ACETONE Appearance: coouress. /ash Point: 2 de$ /. Danger! Causes eye and s#in irritation. May cause centra nervous syste" depression. May cause iver and #idney da"a$e. Causes respiratory tract irritation. E+tre"ey %a""abe iuid and vapor. )apor "ay cause %ash %ire. Target Organs: Bidneys& centra nervous syste"& iver& respiratory syste"& eyes& s#in.
Boiling 'oint: 100.- de$ / *ree%ing-#elting 'oint: 210.3 de$ / #olec&lar *orm&la: C093; #olec&lar Weight: @8.<8 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: 9i$h te"peratures& i$nition sources& te"peratures above --<4C. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& stron$ acids& perchorates& aiphatic a"ines& chro"y choride& he+achoro"ea"ine& chro"ic anhydride& choro%or" = a#ai& potassiu" tert2buto+ide. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide.
$E2ANE Appearance: cear cooress. /ash Point: 2-- de$ C. Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. Causes respiratory tract irritation. Causes eye and s#in irritation. Danger! E+tre"ey %a""abe iuid and vapor. )apor "ay cause %ash %ire. Possibe ris# o% i"paired %ertiity. ?reathin$ vapors "ay cause drowsiness and di,,iness. *an$erous
%or the environ"ent. May cause nervous syste" e%%ects. Target Organs: Centra nervous syste"& respiratory syste"& eyes& s#in& periphera nervous syste".
Boiling 'oint: 3 de$ C 63< ""9$ *ree%ing-#elting 'oint: 2@ de$ C #olec&lar *orm&la: C391 #olec&lar Weight: 83.18 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: I$nition sources& e+cess heat& eectrica spar#s. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& dinitro$en tetrao+ide. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur.
BENZOIC ACID Appearance: white. Warning! Causes respiratory tract irritation. Causes severe eye irritation and possibe in!ury. Causes "oderate s#in irritation. May cause aer$ic s#in reaction. May be har"%u i% swaowed& inhaed& or absorbed throu$h the s#in. Target Organs: 'un$s& eyes& s#in.
Chemical Stability: (tabe under nor"a te"peratures and pressures. )oatie in stea". Conditions to Aoid: *ust $eneration& e+cess heat. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& stron$ bases& a"ines& a""onia& isocyanates. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide.
EXPERIMENT
ET$ANO) Appearance: cear& cooress. /ash Point: 10 de$ C. Danger! /a""abe iuid. Causes severe eye irritation. May cause bindness i% swaowed. May be %ata i% swaowed. May cause s#in i rritation. May cause centra nervous syste" depression. May cause iver and #idney da"a$e. May cause reproductive and %eta e%%ects. May be absorbed throu$h intact s#in. May %or" e+posive pero+ides. Target Organs: Bidneys& centra nervous syste"& iver.
Boiling 'oint: 160.0 de$ / *ree%ing-#elting 'oint: 2< de$ C Chemical Stability: (tabe. This "ateria "ay be sensitive to pero+ide %or"ation. Conditions to Aoid: This "ateria "ay be sensitive to pero+ide %or"ation.& inco"patibe "aterias& i$nition sources. Incomatibilities "ith Other #aterials: Isopropano is susceptibe to auto+idation and there%ore shoud be cassi%ied as pero+idi,abe.& acids 5"inera& non2o+idi,in$& e.$. hydrochoric acid& hydro%uoric acid& "uriatic acid& phosphoric acid7& acids 5"inera& o+idi,in$& e.$. chro"ic acid& hypochorous acid& nitric acid& su%uric acid7& acids 5or$anic& e.$. acetic acid& ben,oic acid& %or"ic acid& "ethanoic acid& o+aic acid7& a,o& dia,o& and hydra,ines 5e.$. di"ethy hydra,ine& hydra,ine& "ethy hydra,ine7& isocyanates 5e.$. "ethy isocyanate7& "etas 5a#ai and a#aine& e.$. cesiu"& potassiu"& sodiu"7& nitrides 5e.$. potassiu" nitride& sodiu" nitride7& pero+ides and hydropero+ides 5or$anic& e.$. acety pero+ide& ben,oy pero+ide& buty pero+ide& "ethy ethy #etone pero+ide7& epo+ides 5e.$. buty $ycidy ether7& o+idi,in$ a $ents 5stron$& e.$. bro"ine& hydro$en pero+ide& nitro$en dio+ide& potassiu" nitrate7& reducin$ a$ents 5stron$& e.$. au"inu" carbide& chorosiane& hydro$en phosphide& ithiu" hydride7& water reactive substances 5e.$. acetic anyhdride& a#y au"inu" choride& caciu" carbide& ethy dichorosiane7. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide.
EXPERIMENT @
/1EA Appearance: white. Causes eye and s#in irritation. Causes di$estive and respiratory tract irritation. May cause cardiac disturbances. Warning! Muta$en. Reproductivey active. May cause bood abnor"aities. Target Organs: ?ood& cardiovascuar syste".
Boiling 'oint: deco"poses *ree%ing-#elting 'oint: 10- de$ C #olec&lar *orm&la: C9N-; #olec&lar Weight: 3<.<<8 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& dust $eneration& e+cess heat. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& sodiu" hypochorite& sodiu" nitrate& caciu" hypochorite& nitrosy perchorate& $aiu" perchorate& diphosphorus p entachoride. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& o+ides o% nitro$en& irritatin$ and to+ic %u"es and $ases& carbon dio+ide.
$E2ANE Appearance: cear cooress. /ash Point: 2-- de$ C. Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. Causes respiratory tract irritation. Causes eye and s#in irritation. Danger! E+tre"ey %a""abe iuid and vapor. )apor "ay cause %ash %ire. Possibe ris# o% i"paired %ertiity. ?reathin$ vapors "ay cause drowsiness and di,,iness. *an$erous %or the environ"ent. May cause nervous syste" e%%ects. Boiling 'oint: 3 de$ C 63< ""9$ *ree%ing-#elting 'oint: 2@ de$ C #olec&lar *orm&la: C391 #olec&lar Weight: 83.18
Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: I$nition sources& e+cess heat& eectrica spar#s. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& dinitro$en tetrao+ide. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur.
BENZOIC ACID Appearance: white. Warning! Causes respiratory tract irritation. Causes severe eye irritation and possibe in!ury. Causes "oderate s#in irritation. May cause aer$ic s#in reaction. May be har"%u i% swaowed& inhaed& or absorbed throu$h the s#in.
Chemical Stability: (tabe under nor"a te"peratures and pressures. )oatie in stea". Conditions to Aoid: *ust $eneration& e+cess heat. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& stron$ bases& a"ines& a""onia& isocyanates. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide.
EXPERIMENT 3
SODI/# #ETA) Appearance: i$ht siver soid. Danger! May i$nite spontaneousy on e+posure to "oist air. Co"bustibe soid. Causes eye burns. Causes di $estive tract burns. Corrosive. >ater2reactive. Contact with s#in causes irritation and possibe burns& especiay i% the s#in is wet or "oist. Causes respiratory tract burns. Boiling 'oint: 13-1 de$ / *ree%ing-#elting 'oint: -<8 de$ / #olec&lar *orm&la: Na #olec&lar Weight: --. Chemical Stability: Reacts vioenty with water. Reacts vioenty with a broad ran$e o% "aterias.
Conditions to Aoid: *ust $eneration& e+posure to "oist air or water. Incomatibilities "ith Other #aterials: >ater& choro%or"& stron$ acids& su%ur dio+ide& stron$ o+idi,in$ a$ents& hao$ens. $a%ardo&s Decomosition 'rod&cts: Irritatin$ and to+ic %u"es and $ases& sodiu" o+ide.
'.C$)O1OANI)INE 'otential Ac&te $ealth E33ects : 9a,ardous in case o% s#in contact 5per"eator7& o% eye contact 5irritant7& o% in$estion& o% inhaation. (i$hty ha,ardous in case o% s#in contact 5irritant& sensiti,er7. (evere over2e+posure can resut in death. Boiling 'oint : -0-4C 5.34/7 #elting 'oint : 6-.@4C 513-.@4/7 Secial 1emar4s on 1eactiity : 'i$ht sensitive. Air sensitive. Inco"patibe with acids& acid chorides& acid anhydrides& choro%or"ates& and stron$ o+idi,in$ a$ents. Air and i$ht sensitive. > hen heated to deco"posItion& it e"its hi$hy to+ic %u"es. S/)*ANI)IC ACID 'otential Ac&te $ealth E33ects: )ery ha,ardous in case o% in$estion. 9a,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7& o% inhaation. #olec&lar Weight : 160.1 $D"oe #elting 'oint : *eco"poses. 5-884C or @@<.4/7 Corrosiity: Non2corrosive in presence o% $ass *E11O/S S/)*ATE Appearance: bue2$reen soid. Ca&tion! May cause eye and s#in irritation. May cause respiratory tract irritation. May be har"%u i% swaowed. Air sensitive. Moisture sensitive. Target Organs: 'iver& $astrointestina syste"& eyes& s#in& "ucous "e"branes. Boiling 'oint: 0<< de$ C 5dec7 *ree%ing-#elting 'oint: 3 de$ C #olec&lar *orm&la: /e(;.69-; #olec&lar Weight: -68.<1 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. /e(;.69-; o+idi,es in "oist ai r %or"in$ a brown coatin$ o% basic %erric su%ate. Aueous soutions are o+idi,ed sowy by air when cod& rapidy when hot rate o% o+idation increased by addition o% base or e+posure to i$ht. Conditions to Aoid: 'i$ht& dust $eneration& "oisture& e+cess heat& proon$ed e+posure to air. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& bases& ead acetate& siver sats& i"e water& carbonates& potassiu" tartrate& $od sats& potassiu" iodide& sodiu" borate& sodiu" tartrate& tannin. $a%ardo&s Decomosition 'rod&cts: ;+ides o% su%ur& o+ides o% iron. SODI/# NIT1O'1/SSIDE Appearance: red crystas. >arnin$F Contact with acid iberates cyanide $as. May cause respiratory tract irritation. 9y$roscopic 5absorbs "oisture %ro" the air.7 9ar"%u i% swaowed& inhaed& or absorbed throu$h the s#in. May cause eye and s#in irritation. Target Organs : ?ood& cardiovascuar syste" #olec&lar *orm&la :C@/eN3;.Na-.-9-; #olec&lar Weight :
[email protected] Chemical Stability : (tabe under nor"a stora$e and handin$ conditions. Conditions to Aoid: *ust $eneration& e+cess heat& e+posure to water or "oist air Incomatibilities "ith Other #aterials : (tron$ o+idi,in$ a$ents& stron$ acids. $a%ardo&s Decomosition 'rod&cts : 9ydro$en cyanide& nitro$en o+ides& irritatin$ and to+ic %u"es and $ases& sodiu" o+ide. *E11IC C$)O1IDE Appearance: yeow to brown. May cause iver and #idney da"a$e. May cause centra nervous syste" e%%ects. May cause cardiac disturbances. 9y$roscopic. Danger! Corrosive. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. May be har"%u i% swaowed. Target Organs: Bidneys& centra nervous syste"& iver. Boiling 'oint: Not appicabe. *ree%ing-#elting 'oint: @03 de$ / #olec&lar *orm&la: /eC0.39-; #olec&lar Weight: -6<.-83 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: 9i$h te"peratures& inco"patibe "aterias& "oisture. Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents& ay choride& potassiu"& sodiu".
$a%ardo&s Decomosition 'rod&cts: 9ydro$en choride& chorine& irritatin$ and to+ic %u"es and $ases& choride %u"es& o+ides o% iron. 'OTASSI/# *)/O1IDE 'otential Ac&te $ealth E33ects: )ery ha,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7& o% in$estion& o% inhaation. (i$hty ha,ardous in case o% s#in contact 5corrosive& per"eator7& o% eye contact 5corrosive7. (evere over2 e+posure can resut in death. In%a""ation o% the eye is cha racteri,ed by redness& waterin$& and itchin$. (#in in%a""ation is characteri,ed by itchin$& scain$& reddenin$& or& occasionay& bisterin$. #olec&lar Weight : @8.1 $D"oe Boiling 'oint : 1@<@4C 5-614/7 #elting 'oint : 8@.4C 51@6.84/7 Secial 1emar4s on 1eactiity : Absorbs "oisture %ro" the air. Reacts with stron$ acids to %or" hydro$en %uoride. A##ONI/# $0D1O2IDE Appearance: coouress. Danger! Corrosive. Causes eye and s#in burns. Causes di$estive and respiratory tract burns. To+ic. 'achry"ator 5substance which increases the %ow o% tears7. 9ar"%u i% swaowed. Target Organs: Eyes& s#in& "ucous "e"branes. Boiling 'oint: 03 de$ C *ree%ing-#elting 'oint: 266 de$ C Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: 9i$h te"peratures& inco"patibe "aterias. Incomatibilities "ith Other #aterials: Acroein& acryic acid& chorosu%onic acid& d i"ethy su%ate& %uorine& $od = aua re$ia& hydrochoric acid& hydro%uoric acid& iodine& nitric acid& oeu"& propioactone& propyene o +ide& siver nitrate& siver o+ide& siver o+ide = ethy a coho& nitro"ethane& siver per"an$anate& su%uric acid& hao$ens. /or"s e+posive co"pounds with "any heavy "etas and haide sats. $a%ardo&s Decomosition 'rod&cts: Nitro$en o+ides 5N;+7 and a""onia 5N907. NIT1IC ACID Appearance: cear to yeow. Danger! Corrosive. (tron$ o+idi,er. Contact with other "ateria "ay cause a %ire. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. Boiling 'oint: 1-- de$ C *ree%ing-#elting 'oint: 2- de$ C #olec&lar *orm&la: 9N;0 #olec&lar Weight: 30.<1 Chemical Stability: (tabe. *eco"poses when in contact with air& i$ht& or or$anic "atter. Conditions to Aoid: 9i$h te"peratures& inco"patibe "aterias& i$nition sources& dust $eneration& "oisture& co"bustibe "aterias& reducin$ a$ents. Incomatibilities "ith Other #aterials: Reducin$ a$ents& acids 5or$anic& e.$. acetic acid& ben,oic acid& %or"ic acid& "ethanoic acid& o+aic acid7& acohos and $ycos 5e.$. buty acoho& ethano& "ethano& ethyene $yco7& adehydes 5e.$. acetadehyde& acroein& chora hydrate& %or"adehyde7& a"ides 5e.$. butyra"ide& diethytoua"ide& di"ethy %or"a"ide7& a"ines 5aiphatic and aro"atic& e.$. di"ethy a"ine& propya"ine& pyridine& triethya"ine7& a,o& dia,o& and hydra,ines 5e.$. di"ethy hydra,ine& hydra,ine& "ethy hydra,ine7& carba"ates 5e.$. carbanoate& carbo%uran7& caustics 5e.$. a""onia& a""oniu" hydro+ide& caciu" hydro+ide& potassiu" hydro+ide& sodiu" hydro+ide7& cyanides 5e.$. potassiu" cyanide& sodiu" cyanide7& dithiocarba"ates 5e.$. %erba"& "aneb& "etha"& thira"7& esters 5e.$. buty acetate& ethy acetate& propy %or"ate7& ethers 5e.$. dio+ane& %ur%uran& tetrahydro%uran 5T9/77& %uorides 5inor$anic& e.$. a""oniu" %uoride& caciu" %uoride& cesiu" % uoride7& hydrocarbons 5aro"atic& e.$. ben,ene& chrysene& cu"en. $a%ardo&s Decomosition 'rod&cts: Nitro$en o+ides. S/)*/1IC ACID Appearance: cear cooress 2 oiy iuid. Danger! Corrosive. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. Cancer ha,ard. May cause %eta e%%ects based upon ani"a studies. May cause #idney da"a$e. May be %ata i% inhaed. May cause u n$ da"a$e. 9y$roscopic. (tron$ o+idi,er. Contact with other "ateria "ay cause a %ire. May cause severe eye& s#in and respiratory tract irritation with possibe burns. Target Organs: Bidneys& heart& un$s& respiratory syste"& cardiovascuar syste"& teeth& eyes. Boiling 'oint: 0< de$ C *ree%ing-#elting 'oint: 1<.0@ de$ C #olec&lar *orm&la: 9-(; #olec&lar Weight: 8.<613 Chemical Stability: Co"bines vi$orousy with water with the evoution o% heat. Reported to have e+poded when in a seaed container. This was "ost i#ey due to pressure o% hydro$en by reduction o% water. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& "etas& e+cess heat& co"bustibe "aterias& or$anic "aterias& reducin$ a$ents& e+posure to "oist air or water& o+idi,ers& a"ines& bases. Incomatibilities "ith Other #aterials: ?ases& stron$ dehydratin$ a$ents& or$anic "aterias& %iney powdered "etas& "oisture& carbides& chorates& cyanides 5e.$. potassiu" cyanide& sodiu" cyanide7& a,ides& %u"inates& picrates& nitrates& a#ai haides& ,inc& iodides& per"an$anates& hydro$en pero+ides& perchorates& nitro"ethane& phosphorus& nitrites&
cycopentadiene& cycpentanone o+i"e& nitroary a"ines& ithiu" siicides& iron& "ercuric nitride& ben,ene& potassiu" chorates& stee& cesiu" acetyene carbide& trihydro+ydia"ino phosphate& phosphorus trio+ide& reducin$ a$ents. $a%ardo&s Decomosition 'rod&cts: ;+ides o% su%ur& irritatin$ and to+ic %u"es and $ases.
SI)5E1 NIT1ATE Appearance: cooress or white. Danger! (tron$ o+idi,er. Contact with other "ateria "ay cause a %ire. May cause cyanosis 5buish discooration o% s#in due to de%icient o+y$enation o% the bood7. May cause iver a nd #idney da"a$e. Corrosive. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. Target Organs: ?ood& #idneys& iver. Boiling 'oint: 8- de$ / *ree%ing-#elting 'oint: 1 de$ / #olec&lar *orm&la: A$N;0 #olec&lar Weight: 13.8601 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& co"bustibe "aterias& reducin$ a$ents. Incomatibilities "ith Other #aterials: (tron$ acids& stron$ bases& stron$ reducin$ a$ents& stron$ o+idi,in$ a$ents. $a%ardo&s Decomosition 'rod&cts: Nitro$en o+ides& irritatin$ and to+ic %u"es and $ases& o +ides o% siver.
EXPERIMENT 6
SODI/# $0D1O2IDE Appearance: white. Danger! Corrosive. Causes eye and s#in burns. 9y$roscopic. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. Target Organs: Eyes& s#in& "ucous "e"branes. Boiling 'oint: 10< de$ C 63< "" 9$ *ree%ing-#elting 'oint: 018 de$ C #olec&lar *orm&la: Na;9 #olec&lar Weight: <.<< Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: Moisture& contact with water& e+posure to "oist air or water& proon$ed e+posure to a ir. Incomatibilities "ith Other #aterials: Acids& water& %a""abe iuids& or$anic hao$ens& "etas& au"inu"& ,inc& tin& eather& woo& nitro"ethane. $a%ardo&s Decomosition 'rod&cts: To+ic %u"es o% sodiu" o+ide. $0D1OC$)O1IC ACID Appearance: cooress to si$ht yeow. Danger! Corrosive. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. May cause %eta e%%ects based upon ani"a studies. Possibe sensiti,er. May be har"%u i% swaowed. 9y$roscopic. Target Organs: Teeth& circuatory syste". Boiling 'oint: 81.@211< de$ C 63< ""9$ *ree%ing-#elting 'oint: 26 de$ C #olec&lar *orm&la: 9C.9-; #olec&lar Weight: 03.3 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Mechanica shoc#& inco"patibe "aterias& "etas& e+cess heat& e+posure to "oist air or water& bases. Incomatibilities "ith Other #aterials: ?ases& acetic anhydride& a#ai "etas& au"inu"& a"ines& copper& copper aoys& %uorine& iron& sodiu" hydro+ide& stee& su%uric acid& viny a cetate& ,inc& potassiu" per"an$anate& cesiu" acetyene carbide& rubidiu" acetyene carbide& rubidiu" carbide& sodiu"& chorosu%onic acid& oeu"& carbonates& perchoric acid& caciu" phosphide& "eta o+ides& acetates& cesiu" carbide& beta2propioactone& ethyenei"ine& propyene o+ide& ithiu" siicides& acohos = hydro$en cyanide& -2a"inoethano& a""oniu" hydro+ide& caciu" carbide& 1&12 di%uoroethyene& ethyene dia"ine& "a$nesiu" boride& "ercuric su%ate& siver perchorate = carbon tetrachoride& uraniu" phosphide. $a%ardo&s Decomosition 'rod&cts: 9ydro$en choride& chorine& carbon "ono+ide& carbon dio+ide& hydro$en $as. $a%ardo&s 'olymeri%ation: >i not occur. '$OS'$O1IC ACID Appearance: AP9A: 1< "a+ 2 cooress viscous i uid. Danger! Corrosive. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. Causes severe eye and s#in irritation and burns. May cause cyanosis 5buish discooration o% s#in due to de%icient o+y$enation o% the bood7. 9ar"%u i% inhaed. May be har"%u i% swaowed. Target Organs: ?ood& iver& bone "arrow. Boiling 'oint: 1@8 de$ C 63<.<<"" 9$ *ree%ing-#elting 'oint: -.0@ de$ C #olec&lar *orm&la: 90;P
#olec&lar Weight: 8.<< Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& "etas& e+cess heat. Incomatibilities "ith Other #aterials: (tron$ bases& a""onia& %iney powdered "etas& or$anic pero+ides& caustics 5e.$. a""onia& a""oniu" hydro+ide& caciu" hydro+ide& potassiu" hydro+ide& sodiu" hydro+ide7& cyanides 5e.$. potassiu" cyanide& sodiu" cyanide7& %uorides 5inor$anic& e.$. a""oniu" %uoride& caciu" %uoride& cesiu" %uoride7& hao$enated or$anics 5e.$. dibro"oethane& he+achoroben,ene& "ethy choride& trichoroethyene7& "ercaptans and other or$anic su%ides 5e.$. buty "ercaptan& carbon disu%ide& "ethanethio7& nitro"ethane& sodiu" tetrahydroborate& su%ites& "inera acids& beechin$ powder& adehydes& stron$ a#aies& chorides& nic#e carbonate. $a%ardo&s Decomosition 'rod&cts: Phosphine& o+ides o% phosphorus& irritatin$ and to+ic %u"es and $ases. $a%ardo&s 'olymeri%ation: May occur. SODI/# BICA1BONATE Appearance: white. May cause respiratory and di$estive tract irritation. Moisture sensitive. May cause s#in irritation. Causes eye irritation. Warning! Target Organs: None. *ree%ing-#elting 'oint: -6< de$ / #olec&lar *orm&la: Na9C;0 #olec&lar Weight: 80.@ Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: Inco"patibe "aterias& dust $eneration& "oi sture& e+cess heat. Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. DIET$0)ET$E1 Potentia Acute 9eath E%%ects: 9a,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7& o% in$estion& o% inhaation. (i$hty ha,ardous in case o% s#in contact 5per"eator7 ?oiin$ Point: 0.34C 5.04/7 Metin$ Point: 2113.04C 52166.04/7 (oubiity: (oube in acetone. Partiay soube in cod water. Inco"patibiity with various substances: 9i$hy reactive with o+idi,in$ a$ents& acids. Corrosivity: Non2corrosive in presence o% $ass ANI)INE Appearance: cooress iuid. /ash Point: 6< de$ C. Warning! Co"bustibe iuid. Causes di$estive and respiratory tract irritation. May cause "ethe"o$obine"ia. May cause cyanosis 5buish discooration o% s#in due to de%icient o+y$enation o% the bood7. May cause iver and #idney da"a$e. 9y$roscopic 5absorbs "oisture %ro" the air7. 'i$ht sensitive. May cause centra nervous syste" depression. 9ar"%u i% swaowed or absorbed throu$h the s#in. Ca uses severe eye irritation and possibe eye in!ury. Causes s#in irritation. Possibe sensiti,er. May cause %eta e%%ects. *an$erous %or the environ"ent. Target Organs: Bidneys& centra nervous syste"& iver& speen& cardiovascuar syste"& red bood ces& bone "arrow& badder. Boiling 'oint: 18 de$ C 63<.<< ""9$ *ree%ing-#elting 'oint: 23 de$ C #olec&lar *orm&la: C396N #olec&lar Weight: 0.10 Chemical Stability: (tabe under nor"a te"peratures and pressures. )oatie in stea". (ensitive to i$ht. May discoor on e +posure to air and i$ht. Conditions to Aoid: Inco"patibe "aterias& i$ht& i$nition sources& e+cess heat& e+posure to "oist air or water. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& stron$ acids& bases& au"inu"& %uorine& %or"adehyde& iron& nitric acid& siver perchorate& sodiu" pero+ide& su%uric acid& ,inc& hydro$en pero+ides& o,one& acid anhydrides& chorosu%onic acid& oeu"& perchro"ates& nitro"ethane& diben,oy pero+ide& ben,enedia,oniu"2-2carbo+yate& boron trichoride& tetranitro"ethane& trichoronitro"ethane& diisopropy pero+ydicarbonate& he+achoro"ea"ine& pero+o"onosu%uric acid& abu"in& iron sats& perchoric acid& nitroben,ene& a#ais& "oisture& potassiu" pero+ide& $ycerine& %u"in$ nitric acid& N2choro co"pounds& N2bro"oi"ides 5e.$. n2bro"osuccini"ide7& pero+ydisu%uric acid& nitrosy %uoride& touene diisocyanate. $a%ardo&s Decomosition 'rod&cts: Nitro$en o+ides& carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur. BENZA#IDE Potentia Acute 9eath E%%ects: )ery ha,ardous in case o% in$estion. 9a,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7& o% inhaation. (i$hty ha,ardous in case o% s#in contact 5per"eator7. Moecuar >ei$ht: 1-1.1 $D"oe ?oiin$ Point: -884C 5@@<.4/7
Metin$ Point: 10-.@4C 5-6<.@4/7 Inco"patibiity with various substances: Reactive with acids.
C$)O1OBENZENE Potentia Acute 9eath E%%ects: )ery ha,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7& o% in$estion& o% inhaation. 9a,ardous in case o% s#in contact 5corrosive& sensiti,er& per"eator7. In%a""ation o% the eye is characteri,ed by redness& waterin$& and itchin$. (#in in%a""ation is characteri,ed by itchin$& scain$& reddenin$& or& occasionay& bisterin$. Moecuar >ei$ht: 11-.@3 $D"oe ?oiin$ Point: 10-4C 5-3.34/7 Metin$ Point: 2@.34C 52@<.14/7 ;ther To+ic E%%ects on 9u"ans: )ery ha,ardous in case o% s#in contact 5irritant7& o% in$estion& o% inhaation. 9a,ardous in case o% s#in contact 5corrosive& sensiti,er& per"eator7. C0C)O$E2ANE Appearance: coouress. /ash Point: 2-< de$ C. Danger! Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. May cause respiratory and di$estive tract irritation. May cause eye and s#in irritation. May cause centra nervous syste" depression. May cause iver and #idney da"a$e. 9i$hy %a""abe. May %or" e+posive pero+ides. Target Organs: Bidneys& centra nervous syste"& iver& cardiovascuar syste". Boiling 'oint: 8<.6 de$ C *ree%ing-#elting 'oint: 3.@ de$ C #olec&lar *orm&la: C9-5C9-7C9#olec&lar Weight: 8.<8 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. E+posive pero+ides "ay %or" on concentration. Pero+ides can be detonated by %riction& i"pact& or heatin$. Pero+ide %or"ation "ay occur in containers that have been opened and re"ain in stora$e. Nor"ay stabe however& on on$ ter" stora$e& "aterias containin$ si"iar %unctiona $roups %or" pero+ides o% un#nown stabiity. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& e+cess heat& o+idi,ers. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& nitro$en dio+ide. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. A)ANINE Appearance: white. Ca&tion! The to+icoo$ica properties o% this "ateria have not been %uy investi$ated. 'i$ht sensitive. Moisture sensitive. May cause eye and s#in irritation. May cause respiratory and d i$estive tract irritation. *ree%ing-#elting 'oint: 01.@< 2 013.@< de$ C #olec&lar *orm&la: C90C95N9-7C;-9 #olec&lar Weight: 8.< Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& dust $eneration& e+cess heat. Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents. $a%ardo&s Decomosition 'rod&cts: Nitro$en o+ides& carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. '$ENO) Appearance: coouress. /ash Point: 6 de$ C. Danger! Corrosive. May cause centra nervous syste" e%%ects. May cause iver and #idney da"a$e. 9ar"%u i% swaowed or absorbed throu$h the s#in. May be h ar"%u i% inhaed. Comb&stible li+&id and aor, May cause centra nervous syste" depression. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. This substance has caused adverse reproductive and %eta e%%ects in ani"as. Target Organs: Bidneys& centra nervous syste"& iver. Boiling 'oint: 1- de$ C 63<.<< ""9$ *ree%ing-#elting 'oint: 0 de$ C #olec&lar *orm&la: C393; #olec&lar Weight: .11 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& e+cess heat. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& acids& isocyanates& acetadehyde& nitrides 5e.$. potassiu" nitride& sodiu" nitride7& caciu" hypochorite& pero+o"onosu%uric acid& nitroben,ene& sodiu" nitrite& au"inu" choride& pero+ydisu%uric acid& 1&02butadiene& boron tri%uoride diethy ether. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide.
EXPERIMENT 8
CA)CI/# CA1BIDE Potentia Acute 9eath E%%ects: 9a,ardous in case o% in$estion& o% inhaation. (i $hty ha,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7. #olec&lar Weight : 3.1 $D"oe
#elting 'oint : -0<<4C 516-4/7 Inco"patibiity with various substances: E+tre"ey reactive or inco"patibe with acids& "oisture. 9i$hy reactive with a#ais. Reactive with o+idi,in$ a$ents. The product reacts vioenty with water to e"it %a""abe but non to+ic $ases. 'ar$e (pi: /a""abe soid that& in contact with water& e"its %a""abe $ases. (top ea# i% without ris#. *o not $et water inside container. *o not touch spied "ateria. Cover with dry earth& sand or other non2co"bustibe "ateria. Prevent entry into sewers& base"ents or con%ined areas di#e i% needed. Ei"inate a i$nition sources. Ca %or assistance on disposa. Corrosivity: Non2corrosive in presence o% $ass 'OTASSI/# 'E1#AN(ANATE Appearance: dar# purpe soid. Danger! (tron$ o+idi,er. Contact with other "ateria "ay cause a %ire. May cause #idney da"a$e. May be har"%u i% swaowed. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. Causes severe eye and s#in irritation with possibe burns. Reproductivey active. Target Organs: ?ood& #idneys& centra nervous syste"& iver& un$s& respiratory syste"& eyes& s#in. *ree%ing-#elting 'oint: 3 de$ / #olec&lar *orm&la: BMn; #olec&lar Weight: 1@8.<00 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: 9i$h te"peratures& inco"patibe "aterias& dust $eneration& co"bustibe "aterias& reducin$ a$ents. Incomatibilities "ith Other #aterials: (tron$ reducin$ a$ents& pero+ides& au"inu"& ,inc& ead& copper& copper aoys& or$anic "aterias& su%uric acid& $ycero& phosphorus& co"bustibe or$anics& a""oniu" nitrate& di"ethy %or"a"ide& ethyene $yco& hydro+ya"ine& hydro$en trisu%ide& anti"ony& a""oniu" sats& acids& su%ur& acetic acid& acetic anhydride& arsenites& bro"ides& iodides& hydrochoric acid& charcoa& %erric sats& "ercurous sats& hypophosphites& su%ites& acohos& rubber. $a%ardo&s Decomosition 'rod&cts: Irritatin$ and to+ic %u"es and $ases& o+y$en& o+ides o% potassiu"& o+ides o% "an$anese. ST01ENE Appearance: cear& cooress. /ash Point: 88 de$ /. Warning! *lammable li+&id and aor, Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. May cause eye and s#in irritation. May cause respiratory and di$estive tract irritation. May cause centra nervous syste" depression. May cause reproductive and %eta e%%ects. May cause cancer based on ani"a studies. ninhibited "ateria "ay %or" e+posive pero+ides. Target Organs: Centra nervous syste". Boiling 'oint: -0 de$ / *ree%ing-#elting 'oint: 2-0 de$ / #olec&lar *orm&la: C8 98 #olec&lar Weight: 1<.1 Chemical Stability: (tabe under nor"a te"peratures and pressures. May %or" pero+ides in the absence o% inhibitors. Conditions to Aoid: Inco"patibe "aterias& i$nition sources. Incomatibilities "ith Other #aterials: )apor is e+posive when e+posed to heat or %a"e and reacts with o+y$en at te"peratures above 1< /& unhibited "ateria "ay %or" e+posive pero+ides. ninhibited "ateria "ay po y"eri,e which beco"es se%2sustainin$ at te"peratures above 3@ C. E+posure to butyithiu"& diben,oy pero+ide& a,oisobutyronitrie or di2tert2butypero+ide "ay cause vioent poy"eri,ation. )ioent reaction with chorosu%onic acid& oeu"& su%uric acid and o+idi,ers. ;+y$en = heat is e+posive. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide. $a%ardo&s 'olymeri%ation: May occur.
BENZENES/)*ON0) C$)O1IDE Potentia Acute 9eath E%%ects: 9a,ardous in case o% s#in contact 5corrosive& irritant7& o% eye contact 5irritant& corrosive7& o% in$estion& o% inhaation. 'iuid or spray "ist "ay produce tissue da"a$e particuary on "ucous "e"branes o% eyes& "outh and respiratory tract. (#in contact "ay produce burns. Inhaation o% the spray "ist "ay produce severe irritation o% respiratory tract& characteri,ed by cou$hin$& cho#in$& or shortness o% breath Moecuar >ei$ht: 163.3- $D"oe ?oiin$ Point: -@-4C 5
[email protected]/7 Metin$ Point: 1.@4C
[email protected]/7 (pecia Re"ar#s on Reactivity: Corrosive and water2reactive. Inco"patibe with a""onia& aIphatic a"ines& di"ethy su%o+ide& "ethy %or"a"ide& water or "oisture. *eco"poses in hot water to produce corrosive and to+ic hydrochoric acid& ben,esu%onic acid. Rate o% reaction decreases as te"perature decreases. Corrosive to "etas in presence o% water due to %or"ation o% hydrochoric acid and ben,ensu%onic acid
TO)/ENE Appearance: coouress. /ash Point: < de$ /. *lammable li+&id and aor, May cause centra nervous syste" depression. May cause iver and #idney da"a$e. This substance has caused adverse reproductive and %eta e%%ects in ani"as. Causes di$estive and respiratory tract irritation. May cause s#in irritation. Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. Danger! 9ar"%u or %ata i% swaowed. Causes eye irritation and possibe transient in!ury. PoisonF May be absorbed throu$h intact s#in. )apor har"%u. Ca physician i"""ediatey. Target Organs: Bidneys& centra nervous syste"& iver. Boiling 'oint: -0- de$ / *ree%ing-#elting 'oint: 210 de$ / #olec&lar *orm&la: C39@C90 #olec&lar Weight: -.<@3 Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& e+cess heat. Incomatibilities "ith Other #aterials: Ntro$en tetro+ide& nitric acid = su%uric acid& siver perchorate& stron$ o+idi,ers& sodiu" di%uoride& . $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& carbon dio+ide. N.B/T0) A)CO$O) Appearance: coouress. /ash Point: 06 de$ C. Warning! *lammable li+&id and aor, May be har"%u i% swaowed. May cause centra nervous syste" depression. May cause adverse reproductive e%%ects based upon ani"a studies. May cause iver and #idney da"a$e. Causes severe eye and s#in irritation. Aspiration ha,ard i% swaowed. Can enter un$s and cause da"a$e. Causes respiratory tract irritation. May be har"%u i% absorbed throu$h the s#in. Target Organs: ?ood& #idneys& centra nervous syste"& iver& eyes& ears. Boiling 'oint: 116. de$ C *ree%ing-#elting 'oint: 2< de$ C #olec&lar *orm&la: C905C9-7-C9-;9 #olec&lar Weight: 6.1- Chemical Stability: (tabe under nor"a te"peratures and pressures. Conditions to Aoid: Inco"patibe "aterias& i$nition sources& e+cess heat. Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents& reducin$ a$ents& acid chorides& a#ai "etas& au"inu"& copper& copper aoys& hao$ens& or$anic pero+ides& acid anhydrides& chro"iu" trio+ide& "inera acids. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur. *E11IC C$)O1IDE Appearance: yeow to brown. May cause iver and #idney da"a$e. May cause centra nervous syste" e%%ects. May cause cardiac disturbances. 9y$roscopic. Danger! Corrosive. Causes eye and s#in burns. May cause severe respiratory tract irritation with possibe burns. May cause severe di$estive tract irritation with possibe burns. May be har"%u i% swaowed. Target Organs: Bidneys& centra nervous syste"& iver. *ree%ing-#elting 'oint: @03 de$ / #olec&lar *orm&la: /eC0.39-; #olec&lar Weight: -6<.-83 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: 9i$h te"peratures& inco"patibe "aterias& "oisture. Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents& ay choride& potassiu"& sodiu". $a%ardo&s Decomosition 'rod&cts: 9ydro$en choride& chorine& irritatin$ and to+ic %u"es and $ases& choride %u"es& o+ides o% iron.
)/CAS 1EA(ENT 'ucas rea$ent is hi$hy to+ic and corrosive and shoud be handed care%uy whie conductin$ the e+peri"ent. The to+icity and corrosiveness arises as a resut o% the constituents. 9ydrochoric acid can irritate the s#in. The vapors shoud not be inhaed as it "i$ht a%%ect the respiratory syste". Ginc Choride i s hi$hy corrosive and "ay cause da"a$e to the s#in and the respiratory syste". Apart %ro" the constituents the vapors o% the acoho are si$hty i rritatin$ to the eyes and nose. It shoud not be inhaed as it "ay turn %ata. #I))ON6S 1EA(ENT Mercuric Nitrate 51<1@26@2@7 08H& Nitric Acid 5636206<2- 7 18H& and >ater 5660-2182@7 H Cooress iuid with characteristic nitric acid odor. Corrosive iuid& severe body tissue ha,ard. Avoid contact with any body tissues. 9i$hy to+ic as "ercury. Irritatin$ to respiratory syste". Avoid inhaation Avoid contact with ethy acoho& su%ur and e+posure to i$ht. SC$I**6S 1EA(ENT (odiu" "etabisu%ite 2 H& 9ydro$en choride 2 <.06H& >ater 2 .3H& ?asic %uchsin 2 1H
Potentia Acute 9eath E%%ects: 9a,ardous in case o% in$estion& o% i nhaation. (i$hty ha,ardous in case o% s#in contact 5corrosive& irritant& per"eator7& o% eye contact 5irritant7 Corrosivity: Corrosive in presence o% stee& o% au"inu"& o% copper. Non2corrosive in presence o% $ass. (pecia Re"ar#s on Reactivity: Reacts vioenty with water especiay when water is added to the product. 59ydro$en choride7
#ET$0)A#INE Appearance: cear& cooress. /ash Point: 218 de$ C. Danger! May cause iver da"a$e. May cause un$ da"a$e. Corrosive. Causes eye and s#in burns. May cause respiratory and di$estive tract burns. 9ar"%u i% inhaed or swaowed. E+tre"ey %a""abe iuid and vapor. )apor "ay cause %ash % ire. May be har"%u i% absorbed throu$h the s#in. Target Organs: 'iver& respiratory syste"& eyes& s#in. Boiling 'oint: 8 de$ C 63< "" 9$ *ree%ing-#elting 'oint: 208 de$ C #olec&lar *orm&la: C9@N #olec&lar Weight: 01.<3 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. Conditions to Aoid: I$nition sources& e+cess heat& attac#s au"inu"& copper& ead& tin& ,inc and a oys. Incomatibilities "ith Other #aterials: Nitro"ethane& acids& o+idi,in$ a$ents& chorine& hypochorite& hao$enated a$ents& "ercury& copper& copper aoys& ,inc& ,inc aoys& au"inu"& perchorates. $a%ardo&s Decomosition 'rod&cts: Nitro$en o+ides& carbon "ono+ide& carbon dio+ide& a""onia andDor derivatives& a"ines. *O1#A)DE$0DE Appearance: not avaiabe. /ash Point: @< de$ C. May cause aer$ic s#in reaction. May cause centra nervous syste" depression. This substance has caused adverse reproductive and %eta e%%ects in ani"as. May cause iver and #idney da"a$e. Cannot be "ade non2poisonous. Potentia cancer ha,ard. Respiratory sensiti,er. Contains %or"adehye. /a""abe iuid and vapor. Causes eye and s#in irritation. Causes di$estive and respiratory tract irritation. *an$erF May be %ata or cause bindness i% swaowed. )apor har"%u. Target Organs: Bidneys& centra nervous syste"& iver. ?oiin$ Point: -1- de$ / /ree,in$DMetin$ Point:0- de$ / Che"ica (tabiity: (tabe under nor"a te"peratures and pressures. Conditions to Avoid: Inco"patibe "aterias& i$nition sources& e+cess heat& o+idi,ers. Inco"patibiities with ;ther Materias: (tron$ o+idi,in$ a$ents. 9a,ardous *eco"position Products: Carbon "ono+ide& o+ides o% phosphorus& irritatin$ and to+ic %u"es and $ases& carbon dio+ide& to+ic %u"es o% sodiu" o+ide. ACETIC AN$0D1IDE Appearance: cooress iuid. /ash Point: 1-3 de$ /. Danger! Corrosive. Causes di$estive and respiratory tract burns. *lammable li+&id and aor, May be har"%u i% swaowed. May cause centra nervous syste" depression. Causes eye and s#in burns. 9ar"%u i% inhaed. Moisture sensitive. Target Organs: Centra nervous syste"& eyes& s#in& "ucous "e"branes. Boiling 'oint: 106 de$ C #olec&lar *orm&la: C93;0 #olec&lar Weight: 1<-.< Chemical Stability: (tabe. 9owever& "ay deco"pose i% e+posed to "oist air or water. (ubstance is readiy hydroy,ed. Reacts with water to %or" correspondin$ acid. Conditions to Aoid: I$nition sources& contact with water& e+cess heat& e+posure to "oist air or water. Incomatibilities "ith Other #aterials: (tron$ o+idi,in$ a$ents& stron$ reducin$ a$ents& bases& acohos& "eta powders& "oisture. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. SA)IC0)IC ACID Appearance: white. Warning! Contact with s#in causes irritation and possibe burns& especiay i% the s#in is wet or "oist. 'i$ht sensitive. Moisture sensitive. May be har"%u i% swaowed. May cause centra nervous syste" e%%ects. Causes severe eye irritation. May cause reproductive and %eta e%%ects. Causes di$estive and respiratory tract irritation. Target Organs: Bidneys& centra nervous syste"& pancreas. Boiling 'oint: -11 de$ C -<.<<"" 9$ *ree%ing-#elting 'oint: 1@8 2 13< de$ C #olec&lar *orm&la: C693;0 #olec&lar Weight: 108.1- Chemical Stability: (tabe under nor"a te"peratures and pressures. Moisture sensitive. 'i$ht sensitive. *ar#ens on e+posure to i$ht. Conditions to Aoid: 9i$h te"peratures& inco"patibe "aterias& i$ht& "oisture& stron$ o+idants. Incomatibilities "ith Other #aterials: ;+idi,in$ a$ents& ead acetate& iron sats& a#ais& i odine& spirit nitrous ether. $a%ardo&s Decomosition 'rod&cts: Carbon "ono+ide& irritatin$ and to+ic %u"es and $ases& carbon dio+ide. $a%ardo&s 'olymeri%ation: >i not occur.
EXPERIMENT
SODI/# NIT1ITE Appearance: white to i$ht yeow crystas. Danger! May be %ata i% inhaed. (tron$ o+idi,er. Contact with other "ateria "ay cause a %ire. 9ar"%u i% swaowed. Causes eye& s#in& and respiratory tract irritation. May cause "ethe"o$obine"ia. This substance has caused adverse reproductive and %eta e%%ects in ani"as. Air sensitive. 9y$roscopic 5absorbs "oisture %ro" the air7. Target Organs: ?ood& cardiovascuar syste"& s"ooth "usce. Boiling 'oint: 0-< de$ C *ree%ing-#elting 'oint: -61 de$ C #olec&lar *orm&la: NaN;#olec&lar Weight: 3 Chemical Stability: (tabe at roo" te"perature in cosed containers under nor"a stora$e and handin$ conditions. nstabe i% heated& "ay e+pode at te"peratures $reater than @004C. Conditions to Aoid: I$nition sources& dust $eneration& e+posure to air& e+posure to "oist air or water& te"peratures above 0-<4C. Incomatibilities "ith Other #aterials: Reducin$ a$ents& acids& a"ines& chorates& per"an$anates& cyanides 5e.$. potassiu" cyanide& sodiu" cyanide7& "etas as powders 5e.$. ha%niu"& raney nic#e7& hypophosphites& su%ites& tannic acid& or$anic "atter& antipyrine& a""oniu" sats& acetaniide& iodides& "ercury sats& "oisture& air& activated carbon& ve$etabe astrin$ents. $a%ardo&s Decomosition 'rod&cts: ;+ides o% nitro$en& irritatin$ and to+ic %u"es and $ases. $a%ardo&s 'olymeri%ation: >i not occur. STA1C$ IODIDE Potentia Acute 9eath E%%ects: 9a,ardous in case o% s#in contact 5irritant7& o% eye contact 5irritant7& o% in$estion. Inco"patibiity with various substances: (i$hty reactive to reactive with o+idi,in$ a$ents& "etas. Corrosivity: Non2corrosive in presence o% $ass& o% copper& o% stainess stee50<7& o% stainess stee50137. (pecia Re"ar#s on Reactivity: Inco"patibe with cyanides& su%ides 5Ginc choride7
