MAKALAH PROSES INDUSTRI KIMIA TEKNOLOGI BAHAN “ POLIETILEN TEREFTALAT (PET)”
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KATA PEN;ANTAR Pue%$ %n %n %hm% %hm%$?N $?N*% *% m%% m%%l%h l%h $en$%n $en$%n# # teknologi teknologi bahan bahan *%n# >ee%#%im%n% mes$i*%' M%%l M%%l%h %h teknologi bahan ini bahan ini i>u%$ un$u %p%$ memenuhi s*%%$ %l%m men#iu$i ueisi $en$%n# in1om%si men#en%i ”Polie$ilen Tee1$%l%$ Tee1$%l%$ (PET)” *%n# melipu$i pen#e$i%n5 l%si1i%si5 @%% pem>u%$%n5 1%>i%si5 %n %pli%si %i Polie$ilen Tee1$%l%$ Tee1$%l%$ (PET)' Penulis >eh%%p m%%l%h ini >is% men<%i pen#e$%hu%n >%#i pem>%@% p%% umumn*% umumn*% %n penulis penulis senii senii hususn* hususn*%% men#en% men#en%ii $enolo $enolo#i #i polime polime $en$%n# $en$%n# Polie$ilen Tee1$%l%$ (PET)' Penulis Penulis men*%% men*%%i i >%h+% >%h+% m%%l%h m%%l%h ini m%sih m%sih >%n*% >%n*% $e%p% $e%p%$$ es%l%h% es%l%h%n n m%upun eu%n#%n' Oleh %en% i$u5 s%%n %n i$i *%n# mem>%n#un s%n#%$ penulis h%%p%n emi esempun%%n %l%m pem>u%$%n m%%l%h i m%s% *%n# %%n %$%n#' Ahi %$%5 penulis men#u@%p%n $eim% %sih ep%% semu% pih% *%n# $el%h mem>%n$u %l%m pen*usun%n m%%l%h ini'
7ile#on5 No4em>e 0:&3
Penulis
DAFTAR DAFTAR ISI IS I H%l%m%n HALAMAN 6UDUL
i
KATA KATA PEN;ANTAR PEN; ANTAR
ii
DAFTAR ISI
iii
9A9 I PENDAHULUAN &'& L%$% L%$% 9el%%n 9el%%n# # &'0 Rumus%n Rumus%n M%s%l%h M%s%l%h &', Tu
& 0 0
9A9 II TIN6AUAN PUSTAKA 0'& Pen#e$i%n Pol*e$h*lene Teep$h%l%$e Teep$h%l%$e (PET)
,
0'0 Si1%$?si1%$ Re%$%n %n Pou
2
0', Desipsi Poses Pem>u%$%n
2
0'3 Kl%si1i%si p%% Polie$h*lene Teeph$%l%$e Teeph$%l%$e (PET)
2
0'- F%>i%si p%% Polie$h*lene Teeph$%l%$e (PET)
2
0'. Apli%si %i Polie$h*lene Teeph$%l%$e Teeph$%l%$e (PET)
2
0'/ 9%h%*% %i Polie$h*lene Teeph$%l%$e Teeph$%l%$e (PET)
2
9A9 III KESIMPULAN DAN SARAN ,'& Kesimpul%n
2
,'0 S%%n
2
DAFTAR PUSTAKA
9A9 I PENDAHULUAN &'& &'& L%$% L%$% 9el% 9el%%n %n# # Se>%#%i Se>%#%i ne#%% ne#%% >eem>% >eem>%n#5 n#5 Inonesi Inonesi%% mel%s% mel%s%n%% n%%n n pem>%n# pem>%n#un%n un%n %n pen#em>%n#%n i >e>%#%i se$o5 s%l%h s%$un*% %%l%h se$o inus$i' Den#%n Den#%n em%
%* %*%$ %$''
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pem pem>%n# >%n#un un%n %n* *%5
se$ se$o o
inu inus$ s$i i
ini ini
iem>%n#%n iem>%n#%n %l%m >e>e%p% $%h%p %n se@%% $ep%u mel%lui penin#%$%n hu>un#%n %n$%% se$o inus$i en#%n se$o l%inn*%' Inus$i imi% meup%%n meup%%n s%l%h s%$u @on$oh se$o inus$i *%n# se%n# iem>%n#%n i Inonesi%5 %n ih%%p%n %p%$ mem>ei%n on$i>usi *%n# *%n#
>es% >es%
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pen pen%p %p%$ %$%n %n
ne#% ne#%% %''
D%l% D%l%m m
men#e en#em> m>%n %n# #%n %n
%n %n
menin#%$%n menin#%$%n inus$i ini ipelu%n ipelu%n ilmu pen#e$%hu%n %n $enolo#i' Un$u i$u Inonesi% h%us m%mpu mem%n1%%$%n po$ensi *%n# %%5 %en% inus$i imi% mem>u$uh%n pe%n#%$?pe%n#%$ pe%n#%$?pe%n#%$ *%n# mem%n# i>u$uh%n i>u$uh%n %n u$uh%n sum>e %*% %l%m see1isien mun#in' Dis%mpin# i$u pelu %i *%n# seeh%n% m%upun *%n# @%n##ih5 sehin##% >%n#s% Inonesi% %p%$ menin#%$%n esis$ensin*% %n ei>ili$%sn*% se<%<% en#%n >%n#s%?>%n#s% l%in *%n# $el%h m%u$uh%n Ke>u$uh%n inus$i?inus$i inus$i?inus$i imi% s%%$ ini5 m%% e>u$uh%n %%n >%h%n >%u inus$i imi% $ese>u$ pun sem%in menin#%$' 9%h%n 9%h %n >%u inus$i inus$ i %% *%n# >e%s%l %i %l%m ne#ei %n %% %h%n >%u *%n# m%sih iimpo %%l%h Pol*e$h*lene Pol*e$h *lene Teep$h%l%$e Teep$h%l%$e (PET)' Pol* Pol*e$h e$h*l *lene ene Teep$h ep$h%l% %l%$e $e (PET (PET)) ini sein# sein# ien ien%l %l en#%n en#%n n%m% n%m% pol*es$e memilii umus s$u$u s$ u$u se>%#%i >eiu$ >e iu$ !
PET en#%n >e%$ moleul *%n# >es% >%n*% i#un%%n un$u mem>u%$ se%$ se%$ sin$e$ sin$e$is5 is5 esin esin55 pem>un pem>un#u #uss m%%n m%%n%n %n %n minum minum%n5 %n5 %n l%in?l l%in?l%i %in' n' Pen*imp%n%n PET %l%m +uu$uh%n $empe%$u *%n# $in##i sehin##% pe%l%$%n *%n# i#un%%n %%n le>ih m%h%l' Sel%in i$u PET %l%m +uih e1e$i1 >il% PET @%i iu>%h men<%i p%%$%n en#%n poses is$%lis%si'
&'0 &'0 Rumus% Rumus%n n M%s% M%s%l% l%h h A%pun umus%n m%s%l%h p%% penulis%n m%%l%h ini *%i$u &' Ap% *%n# *%n# im%su en#%n Polie$ilene Polie$ilene Teeph$%l% Teeph$%l%$e $e (PET) (PET) 0' Ap% s%<% s%<% l%si1i%si l%si1i%si %i Polie$il Polie$ilene ene Teep Teeph$%l%$e h$%l%$e (PET) (PET) ,' 9%#%im 9%#%im%n% %n% poses poses pem>u%$ pem>u%$%n %n Polie$i Polie$ilene lene Teeph Teeph$%l $%l%$e %$e (PET) (PET) 5 1%>i%s 1%>i%sii se$% %pli%sin*%
&', &', Tu%h%n men#en%i Polie$ilene Teeph$%l%$e (PET) %n men#e$%hui Pen#e$i%n5 l%si1i%si5 poses pem>u%$%n5 1%>i%si se$% %pli%si %i polie$ilene $eephl%$%$e
9A9 II TIN6AUAN PUSTAKA 0'& Pen#e$i%n Pen#e$i%n Pol*e$h*lene Pol*e$h*lene Teep$h%l% Teep$h%l%$e $e (PET) (PET) Peem>%n#%n ilmu %n $enolo#i men#en%i pol*es$e (pol*e$h*lene $eep$h% $eep$h%l%$ l%$e) e) imul%i imul%i en#%n en#%n peneli$ peneli$i%n i%n *%n# il%u% il%u%n n oleh Ken@le Ken@le %n 7%o$he 7%o$hesp% sp%% % %hi %hi $%hun $%hun &B,:' &B,:' A%pun A%pun peneli$i peneli$i%n %n Ken@le Ken@lemen men#en% #en%ii h%l $ese>u$ i %$%s >e%s%%n p%% $eni %lil esin *%i$u e%si %n$%% #l*@eol en#%n en#%n ph$%li@ ph$%li@ %@i %nh*i %nh*i'Se 'Se%n# %n#%n %n peneli$ peneli$i%n i%n l%in l%in 5 *%i$u *%i$u 7%o$he 7%o$hes s mempel%<%i pesi%p%n %n h%l?h%l l%in *%n# >een%%n en#%nelinie%%n pol*es$e (pol*e$h*lene $eep$h%l%$e)' D%i pe@o>%%nn*% $el%h i$emu%n >e>e%p% si1%$ pem>en$u%n 1i>e'H%sil pe@o>%%n ini meup%%n em%e>%s %i polime' polime' Penemu%n ini men%s%i pol% pii le>ih l%ne *%n# ih%sil%n memilii $i$i leleh *%n# s%n#%$ en%h' (Ki O$hme5 &B"&) P%% $%hun &B305 Re2 =hin1iel %n = Di@son *%n# >ee<% p%% peus%h%%n 7%li@o Pin$es Asso@i%$ion i In##is menemu%n sin$e$is polime linie*%n# %p%$ ipousi mel%lui Es$e E2@h%n#e %n$%% E$h*lene ;l*@ ;l*@ol ol(E (E;) ;)
%n %n
Dime Dime$h $h*l *l
$ee $eep$ p$h% h%l% l%$e $e
(DMT (DMT))
*%n# *%n#
men#h en#h%s %sil il% %n n
pol*e$h*lene $eep$h%l%$e' $eep $h%l%$e' (h$$p!CC+++'+iipei%'o#C+iiCpol*e$h*lene$eep$h%l%$e h$$p!CC+++'+iipei%'o#C+iiCpol*e$h*lene$eep$h%l%$e ) ) P%% P%% peem> peem>%n#% %n#%n n sel%n%h%n >%u Teep$h%l%$e eep$h%l%$e A@i (TPA) %n E$h*lene ;l*@ol E;)' Pousi se%$ pol*es$e (pol*e$h*lene $eep$h%l%$e) se@%% omesi%l imul%i p%% $%hun &B33 i In##is en#%n n%m% %#%n# “Te*lene” %n p%% $%hun &B-, i Amei% Sei%$ (Dupon$) en#%n n%m% %#%n# “D%@on” (Ki O$hme5 &B"&)
Polie$ilen% Polie$ilen% $ee1$%l%$ $ee1$%l%$ (isin#%$ PET5 PETE %$%u ulu PETP5 PETP5 PET?P PET?P)) %%l %%l%h %h su%$ su%$u u e esi sin n polime pl%s$i$emopl%s$ pl%s$i$emopl%s$ %i %i elo elomp mpo o polies$e ' PET PET >%n*% ipousi %l%m inus$i imi% %n imi% %n i#un%%n %l%m se%$ sin$e$is5 sin$e$is5 >o$ol
minum%n
%n
+%%h
m%%n%n5
%pli%si thermoforming 5
%n
iom>in%si%n en#%n se%$ %@% %l%m esin $eni' PET meup%%n s%l%h s%$u >%h%n s%$u >%h%n men$%h $epen$in# men$%h $epen$in# %l%m e%
;%m>% & S$u$u imi% polie$ilen% $ee1$%l%$
PET PET %p% %p%$$ >e+ >e+u< u%#%i se>%#%i >%h%n >%h%n semi?is$%l semi?is$%l *%n# pu$ih %n $i% $%nsp%%n5 $e#%n$un# ep%% poses %n i+%*%$ i+%*%$ $em%ln*%' $em%ln*%' Monomen*% %p%$ %p%$ ipousi ipousi mel%lui mel%lui es$ es$ei ei1i 1i%si %si%s%m %s%m $ee1$%l%$ en#%n e$il $ee1$%l%$ e$ilen en #li #liol ol55 en#%n en#%n %i %i se>%# se>%#%i %i pou pou s%mpin s%mpin#n* #n*%' %' Monom Monome e PET PET %#%i se>%#%i h%sil h%sil s%mpin# s%mpin#'' Polime
PET
ih%sil%n
mel%lui
e%si polime%si polime%sionens%si onens%si
%i
monomen*%' Re%si ini $e<%i ses%%$ se$el%h es$ei1i%siC$%nses$ei1i%sin*% en#%n e$ilen #liol se>%#%i pou s%mpin# (%n e$ilen #liol ini >i%s%n*% i%u i%u ul%n#)' ul%n#)' Ke>%n*%%n (sei$% .:) %i pousi PET uni% i#un%%n %l%m se%$ se%$ sin$e sin$e$i $is5 s5 %n pousi pousi >o$ol >o$ol men@% men@%p% p%ii ,: %i %i pemin$%%n pemin$%%n uni%' D%l%m D%l%m pen##u pen##un%% n%%nn* nn*%% i >i%n >i%n# # $es$ $es$il il55 PET PET >i%s% >i%s%n*% n*% ise> ise>u$ u$ en#%n en#%n poliester s%<%' s%<%' Pl%s$i PET meup%%n se%$ sin$esis polies$e (%on) *%n# $%nsp%%n en#%n %*% $%h%n u%$5 $%h%n $eh%%p %s%m5 e%p u%%5 1lesi>el5 %n $i% $i% %puh %puh'' D%l%m D%l%m h%l pen## pen##un% un%%n* %n*%5 %5 pel%s pel%s$i $i PET PET menem menemp%$ p%$ii uu$% uu$%n n pe$%m% ' Pen##un%%n*% sei$% /0 se>%#%i em%s%n minum%n en#%n u%li$%s *%n# >%i' Pel%s$i PET meup%%n polies$e *%n# %p%$ i@%mpu
en#%n polime %l%m sepe$i ! su$e% 5 +ol %n %$un un$u men#h%sil%n >%h%n p%%i%n *%n# *%n # >esi1%$ $%hn l%m% %n mu%h mu %h pe%+%$%nn*%' PET meup%%n i%s%n*% $e$e% lo#o %u ul%n# en#%n %n#% & i $en#%hn*% se$% $ulis%n PETE %$%u PET (pol*e$h*lene $eeph$h%l%$e) i >%+%h se#i$i#%' 9i%s% ip%%i un$u >o$ol pl%s$i5 >e+%n% us p%n%n# sepe$i >o$ol %i mine%l5 >o$ol o$ >o$ol ol mi minum num%n %n l% l%inn inn*% *%'' 9O 9OTO TOL L 6E 6ENI NIS S PE PETC TCPE PETE TE ini ieomen%si%n ieomen %si%n HAN HANA A SEKALI SEKALI PA PAKAI' KAI' 9il% $el%lu sein# ip%%i5 %p%l %p %l%# %#ii i i#u #un% n%% %n n un un$u $u me men* n*im imp% p%n n %i %i h% h%n# n#%$ %$ %p %p%l %l%# %#ii p% p%n% n%s5 s5 % %%n %n men#% me n#%i i>%$ >%$% %n n l% l%pis pis%n %n pol polim ime e p% p%%% >o >o$ol $ol $e $ese se>u$ >u$ % %%n %n me melel leleh eh %n men#elu%%n %$ %sino#eni (%p%$ men*e>%>%n %ne) %l%m <%n#% p%n<%n#'
0'0 Si1%$?s Si1%$?si1%$ i1%$ Re%$ Re%$%n %n %n Pou Pou P%% pem>u%$%n pol*e$h*lene $eep$h%l%$e >%h%n?>%h%n *%n# i#un%%n %%l %%l%h %h $ee $eep$ p$h% h%l% l%$e $e %@i %@i %n %n e$h* e$h*le lene ne #l*@ #l*@ol ol se% se%n# n#% %n n po pou u *%n# %n# ih%sil ih%sil%n %n %%l%h %%l%h pol*e$h* pol*e$h*lene lene $eep$h% $eep$h%l%$ l%$e' e' Si1%$?s Si1%$?si1% i1%$$ 1isi% 1isi% %n imi% imi% >%h%n?>%h%n $ese>u$ $es e>u$ iu%i%n se>%#%i se> %#%i >eiu$ !
&' Teep$h eep$h%l%$ %l%$ee A@i A@i (TPA (TPA) %' Si1%$?s Si1%$?si1%$ i1%$ Fisi% Fisi% ! S$u$u imi%!
Rumus moleu l! 7.H3(7OOH)0 9e%$ moleul! &..5&, #Cmol=uu %$%u is$%l >e+%n% pu$ih Densi$%s ! &5-00 #C@m, Ti$i le>u! 30/ o7 Ti$i iih! 3:0o7 Kel%u$%n %l%m %i! &5/ #C &:: mL (0- o7) P%n%s spesi1i! &0:0 6C(#'K) L%u$ %l%m ime$h*l sul1o2ie %n %l%lise$% seii$ l%u$ %l%m e$%nol5 me$%nol5 %s%m %se$%$5 %n %s%m sul1%$' (Ki O$hme5 &B"&)
>' Si1%$?si1%$ Kimi% ! 9ee%si si en#% en#%n n e$h* e$h*len lenee #li@ol #li@ol men#h men#h%si %sil l%n %n pol*e pol*e$h* $h*len lenee 9ee%
$eep$h%l%$e 9ee%si en#%n me$%nol men#h%sil%n ime$h*l $eep$h%l%$e Dih%sil%n en#%n men#osi%si%n p?ime$il >enen%
Dih%sil%n en#%n men#osi%si%n p?2*leneen#%n men##un%%n
%$%lis @o>%l$' Dih%sil%n Dih%sil%n en#%n mee%si%n ipo$%ssium $eep$h%l%$e en#%n %s%m sul1%$
(Ki O$hme5 &B"&)
0' E$h* E$h*le lene ne #l*@ #l*@ol ol %' Si1%$?s Si1%$?si1%$ i1%$ Fisi% Fisi% ! S$u$u imi%!
Rumus moleu l! 70H3(OH)0 9e%$ moleul! .05:." #Cmol Densi$%s! &5&&,0 #C@m, Ti$i le>u ! ?&05B o7 Ti$i iih! &B/5, o7 Ti$i n*%l%! &&& o7 (@lose @up) Tempe%$u Tempe%$u Au$oi#ni$ion! 3&: o7 Giso si$%s! 0:5B mP%'s (0: o7) Ine2 e1%@$i4e! &53,&"0:D P%n%s pen#u%p%n! -0503 6Cmol (p%% &:&', P%) L%u$ %l%m %i
(Ki O$hme5 &B"&)
%' Si1%$?s Si1%$?si1%$ i1%$ Kimi% Kimi% !
9ee% 9ee%si si en#% en#%n n e$h*l e$h*lene ene #li@ol #li@ol en#% en#%n n men## men##un% un%%n %n %$%l %$%lis is
%n$imon Tiosi% men#h%sil%n pol*e$h*lene $eep$h%l%$e' 9ee%s 9ee%sii en#%n en#%n 7%>on% 7%>on%$$ men#h%s men#h%sil% il%n n e$h*lene e$h*lene @%>on% @%>on%$$ %n
me$%nol Dihi%s Dihi%sii en#%n en#%n men##un men##un%%n %%n %$%lis %$%lis %s%m men#h%s men#h%sil% il%n n &53?
io2%ne 9ee%si en#%n Me$h*l%mine men#h%sil%n N?me$h*lmopholin' 9ee%s e%sii en en#%n #%n e$ e$on %n %n %le %lehi hi men#h% n#h%si sill%n %n &5,? &5,?
io2ol%nes(@*@li@ Ke$%ls %n %@e$%ls) %n %i' Dih%sil%n %i e%si hiolisis e$*lene o2ie'
(Ki O$hme5 &B"&)
,' An$im An$imon* on* Tio2i io2ie e %' Si1%$?s Si1%$?si1%$ i1%$ 1isi% 1isi% Rumus moleu l! S>0O, 9e%$ moleul! 0B&5-0 #Cmol =ue+%n% pu$ih , Densi$%s! -50 #C@m Ti$i le>u! .-. o7 Ti$i iih! &30- o7 Kel%u$%n %l%m %i! &53 m#C&:: ml (,: o7) ( h$$p!CC+++'+iipei%'o#C+iiC%n$imon*?$io2ie )
>' Si1%$?si1%$ imi% ! Di#un%%n se>%#%i %$%lis p%% e%si pem>en$u%n polyethylene pem>en$u%n polyethylene Di#un%%n
terepthalate %i terepthalate %i terepthalate acid dan ethylene glycol Dih%sil%n %i e%si osi%si %n$imon 3S> ,O0 J 0S>0O, 9ee%si en#%n %s%m loi% men#h%sil%n
trihloride%n trihloride%n %i S>0O, .H7l J 0S>7l, ,H0O 9ee%si en#%n %s%m >omi% men#h%sil%n men#h%sil%n %n$imon* $i>omie $i>omie
%n %i S>0O, .H7l J 0S>7l, ,H0O 9ee%si en#%n %s%m loi% men#h%sil%n %n$imon* o2*@hloie
%n %i S>0O, 0H7l J 0S>O7l H0O
antimony
(Ki O$hme5 &B"&)
3' Pol*e$h* Pol*e$h*lene lene $eep$h% $eep$h%l%$ l%$ee %' Si1%$?s Si1%$?si1%$ i1%$ Fisi% Fisi% ! S$u$u imi%!
Rumus moleu l Densi$%s Moulus *oun# Tensile s$en#$h
! 7&:H"O3 ! &,/: #Cm, ! 0"::?,&:: Mp% ! --?/- Mp%
Tempe%$ue #l%ss
! /- ℃
Ti$i le>u
! 0.:
Konu$i4i$%s $hem%l ! :'03 =C(m'K) P%n%s Spe@i1i@ ! &': K6C(K#'K) Pen*e%p%n %i ! :'&. Gisos sosi$ i$%s %s in$ in$i ins ns$i $i ! :'.0 :'.0B B lC# lC# Si1%$?si1%$ imi%! Dih%sil Dih%sil%n %n %i e%si %n$% terephlatate acid %n ethylene ethylene glycol
en#%n men##un%%n %$%lis S>0O, Dih%s Dih%sil il%n %n %i %i e%s e%sii %n$% %n$%%% dimetyil terephlatate %n ethylene terephlatate %
℃
glycol (Ki O$hme5&B"&)
0', Desips Desipsii Poses Poses Pem>u%$ Pem>u%$%n %n Polie$h*lene Teephl%$%$e (PET) %p%$ ipeoleh en#%n 0 @%%5 *%i$u mel%lui e%si e%si es$e es$e e2@h%n#e e2@h%n#e %n$%% %n$%% dimethyl terephlatate terephlatate (DMT) (DMT) en#%n en#%n ethylene glycol (E;) (E;) %n mel%lui es$ei1i%si l%n#sun# %n$%% $eephl%$%$e %@i (TPA) %n ethylene glycol (E;)' &' Poses pem>u%$%n pem>u%$%n en#%n en#%n e%si e%si es$ei1i es$ei1i%si %si l%n#sun# l%n#sun# %' T%h%p T%h%p Pesi%p%n Pesi%p%n 9%h%n 9%u Terepthalate acid (TPA) *%n# >e>en$u >u>u i%n#u$ %i $%n#i pen*imp%n%n $eep$h%l%$e %@in en#%n men##un%%n >u@e$ ele4%$o un$u im%su%n e %l%m $%n#i pen@%mpu ' 9es%m%%n en#%n i$u im%su im%su%n %n
glycol *%n# * %n# i%l i%li i% %n n en# en#%n %n men# men##u #un% n%% %n n pomp pomp%% %n %n el%n#sun# sel%m% ,: meni$ p%% $empe%$u "::7 se$% $e%n%n & %$m' 7%mpu%n *%n# ih%sil%n >eup% sl!rry >eup% sl!rry
>' T%h%p T%h%p e%si i' Re%si pem>en$u%n pem>en$u%n Bishydro"yethyl Terepthalate Terepthalate (9HET) (9HET) Slu* (TPA (TPA E;) *%n# ih%sil ih%sil%n %n %i $%n#i $%n#i pen@%mpu pen@%mpu%n %n i%li i%li%n %n e e%$o e%$o es$ei1i es$ei1i%si %si en#%n en#%n men##un% men##un%%n %n pomp% pomp% 'Sel%n 'Sel%n0O,)
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terepthalate(9H terepthalate(9HET) ET)55 %i (H0O) (H0O) %n terepthalate acid (TPA) (TPA) *%n# $i% >ee%si' P%% e%$o ini5 e%si >e<%l%n se@%% eno$emis' Konisi ope%si e%$o es$ei1i%si ini p%% $empe%$u 0-: :7 %n $e%n%n & %$m sel%m% &:: meni$' Re%si *%n# $e<%i p%% e%$o es$ei1i%si %%l%h !
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TP TPA
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ii' Poses Pepolimeis%si Pepolimeis%si Poses pepolimeis%si >el%n#sun# %l%m e%$o pepolimeis%si *%n# ilen#%pi en#%n pen#%u p%% suhu 0/: :7 %n $e%n%n & %$m en#% en#%n n on4e on4esi si bishydro"yethyl terepthalate(9HET) terepthalate(9HET) se>es% B- ' Pose Posess ini men#h men#h%si %sil% l%n n monom monome e en#% en#%n n e%<% e%<%$$ polim polimei eis%s s%sii 0: (pepolime)5 e$h*lene #l*@ol5 %n >ish*o2*e$h*l $eep$h%l%$e *%n# $i% >ee%si' Re%si *%n# $e<%i %l%m e%$o pepolimeis%si %%l%h ! Bishydro"ythyl Bishydro"y thyl Terephlatate Terephlatate
0/:
℃
5 & %$m
Ethylene Glycol #
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iii' Poses Polionens%si Polionens%si P%% P%% pose posess polio polione nens% ns%si si %%n %%n $e>en $e>en$u $u i%$% i%$%n n monom monome e ?monome ?monome men<%i polime polime *%n# p%n<%n# p%n<%n# en#%n e%<%$ e%<%$ polimeis%si polimeis%si *%n# sem%in >e$%m>%h >es%' Poses polionens%si>el%n#sun# p%% $empe%$u 0B::7 %n $e%n%n :5::&B/ %$m (0:: P%) en#%n on4esi pepolime se>es% BB %l%m e%$o polionens%si' Un$u mem4%um%n $e%n%n %i & %$m men<%i :5::&B/ %$m i#un%%n s$e%m e
P%% poses ini u%p e$h*lene #l*@ol*%n# $i% >ee%si %%n i his%p oleh %li%n s$e%m *%n# s%n#%$ en@%n# *%n# ih%sil%n oleh s$e%m eih %hulu iin#in%n p%% @oole'
@' T%h%p %h%p Pemis%h% Pemis%h%n n Pou 7%i%n 7%i%n en$%l en$%l pol*e$h* pol*e$h*lene lene $eep$h% $eep$h%l%$ l%$ee (PET) (PET) *%n# ih%sil ih%sil%n %n %i e%$o e%$o polion polionens% ens%si si i%li% i%li%n n e 1il$e 1il$e pess pess un$u un$u ipis%h ipis%h%n %n %i %$%lis S>0O,' Sel%nu$ ipomp%%n ipomp%%n %n sel%nu$ im%su%n e is$%lise is$%lise
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0' Pos Poses es pem> pem>u% u%$% $%n n Poli Polie$ e$h* h*le lene ne Teeph ephl% l%$% $%$e $e (PET (PET)) en# en#%n %n Re%si $%nses$ei1i%si P%% P%% %s%n*% %s%n*% poses poses pem>u%$ pem>u%$%n %n Polie$h Polie$h*le *lene ne Teeph$ eeph$%l%$ %l%$ee (PET) (PET) en#%n en#%n e%si e%si $%nses$ $%nses$ei1 ei1i%s i%sii %n$%% %n$%% %n$%% %n$%% dimethyl terephlatate terephlatate (DMT) en#%n ethyle ethylene ne glycol glycol (E;) (E;) i>%n i>%nin in#% #%n n en#% en#%n n e%s e%sii es$ei es$ei1i 1i%si %si l%n#sun# l%n#sun# %n$%% %n$%% $eephl $eephl%$%$ %$%$ee %@i (TPA (TPA) %n ethylen ethylenee glycol glycol (E;)5 pinsip e<%n*% s%m% s%<%' %n# >e>e% %%l%h pou s%mpin# *%n# ih%sil%n' 6i% p%% e%si es$ei1i%si es$ei1i%si l%n#sun#5 pou s%mpin# *%n# $e>en$u %%l%h %i se%n#%n p%% e%si $%nses$ei1i%si5 pou s%mpin# *%n# $e>en$u %%l%h me$%nol' Se>elum Se>elum $%hun $%hun &B.,5 &B.,5 poses poses pem>u%$ pem>u%$%n %n Polie$i Polie$ilen len Tee1$% ee1$%l%$ l%$ (PET) (PET) s%n#%$l%h suli$5 n%mun se%%n# $e%p%$ >e>%#%i m%@%m poses pem>u%$%n Poli Polie$i e$ilen len Tee1$% e1$%l%$ l%$ (PET (PET)) semu% semu% i#un% i#un%%n %n un$u un$u memp mempo ous usii PET PET inus$i5 se%%n# uni% m%sih >%n*% %pli%si' Me$oe ini men@%up u% l%n#%h l%n#%h *%i$u *%i$u *%n# pe$%m% pe$%m%55 ime$il ime$il $ee1$% $ee1$%l%$ l%$ (DMT) (DMT) i@%mpu i@%mpu en#%n en#%n e$ile e$ilen% n% #li #liol ol %$%u %$%u &53 &53 ? >u$%ne >u$%neio ioll en#% en#%n n %%n* %%n*%% %$%l %$%lis is un$u un$u e%s e%sii $%nses$ei1i%si es$ei1i%si $ese>u$' K%$%lis *%n# umum i#un%%n %%l%h sen#5 sen#5 o>%l$5 o>%l$5 m%n#%n m%n#%n %se$%$5 %se$%$5 %$%u @%mpu%n @%mpu%nn*% n*% en#%n en#%n $iosi $iosi% % %n$imon %n$imon %l%m ee%si
%n $e@%mpu %%n $e>en$u Bishydro"yethyl $e>en$u Bishydro"yethyl Terepthalate Terepthalate (9HET) (9HET) en#%n pou s%mpin# me$%nol me$%n ol ' Re%si ini %p%$ i mul%i p%% &-::75 $e$%pi %l%m >%n*% h%l i l%u%n p%% 0:::7 %$%u le>ih un$u menin#%$%n l%el%n#sun# me$%nol men#u%p %n u$ i l%u%n %l%m se>u%h %u$ol%15 #%s *%n# i h%sil%n i in#in%n %n %%n men#em>un%n E;' %n# emui%n i em>%li%n e %u$ol%1' ;%s *%n# $e$i $e$in# n##%l #%l55 *%n# *%n# $ei $eii i %i %i me$%n me$%nol ol55 i in#in in#in%n %n le>ih le>ih l%nun >un
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0'3 Kl%si1i%si Kl%si1i%si p%% Polie$h*lene Polie$h*lene Teep Teeph$%l%$e h$%l%$e (PET) A%pun l%si1i%si %$%u m%@%m?m%@%m %h%n Polie$h*lene Teeph$%l%$e (PET)5 *%i$u
Tes$il?Polie$h*lene Tes$il?Polie$h*lene Teeph$%l%$e Teeph$%l%$e (PET) Resin5 9o$ol C A?Polie$h*lene Teeph$%l%$e Teeph$%l%$e (PET) ( PET) Film?Polie$h*lene Teeph$%l%$e (PET)
( h$$p!CC+iipei%'o#C+iiCpolie$ilen?$ee1$%l%$C h$$p!CC+iipei%'o#C+iiCpolie$ilen?$ee1$%l%$C ) )
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sehin##% %p%$ i#un%%n un$u men#em%s pou s%i >u%h Ti% $%h%n $eh%%p %s%m u%$5 1enol5 %n >en*l %lohol' Ku%$5 $i% mu%h us%' 9o$ol pl%s$i *%n# men##un%%n Polie$h*lene Teeph$%l%$e Teeph$%l%$e (PET) m%mpu men%h%n $e%n%n *%n# >e%s%l %i minum%n >e%>on%si'
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;%m>% 0 Di%#%m %li %li pem>u%$%n pem>u%$%n Polie$h*lene Polie$h*lene Tee Teeph$%l%$e ph$%l%$e (PET) (PET) en#%n poses es$ei1i%si es$ei1i%s i l%n#sun# 0'. Apli%si %i Polie$h*l Polie$h*lene ene Teep Teeph$%l%$e h$%l%$e (PET) (PET) Polie$h Polie$h*le *lene ne Teeph$ eeph$%l%$ %l%$ee (PET) (PET) >%n*% >%n*% ipou ipousi si %l%m %l%m inus$i inus$i imi% %n i#un%%n %l%m se%$ sin$e$is5 >o$ol minum%n (>o$ol pl%s$i *%n# o$ol mine%l5 >o$ol o$ol minum%n l%inn*%5 %n +%%h m%%n%n5 %pli%si $hemo1omin#5 %n io iom> m>in in%s %si i%n %n en# en#%n %n se% se%$$ %@% %@% %l% %l%m m esi esin n $en $eni i'' Poli Polie$ e$h* h*le lene ne Teeph$%l%$e (PET) %h%n men$%h $epen$in# %l%m e% e% pem>u% u%$% $%n n %in %in'' Sel% Sel%in in i$u i$u u%$%n 1ilm 1o$o#%1i %n u%$%n >o$ol *%n# >eoe “&” ieomen%si%n h%n*% un$u se%li p%%i5 >u%n un$u ip%%i >e%li?%li %n <%n#%n ip%%i un$u %i h%n#%$ %p%l%#i p%n%s'
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DAFTAR PUSTAKA
9%sse$ 56 ' &BB3 ' Kimia ' Kimia Analisis K!antitatif Anorganik Anorganik ' 6%%$% ! E;7' H%<%i5 ='5 &BB:' Ilm! &BB:' Ilm! Kimia Analitik %asar %asar ' 6%%$%! ;%mei% Hen%*%n%5 Sum%5 ' &BB3' Kimia &BB3' Kimia Analitik Instr!men' Instr!men' Sem%%n# ! IKIP Pess Im%n5 M'5 Kim5 9o?K*un#'5 H%n5 M*un#+%n'5 7ho5 9on# ;*oo'5 Kim5 Do H*un' 0:&:' &!b' and &!percrit &!percritical ical Glycolysis Glycolysis of $olyethylen $olyethylenee Tereph Terephthala thalate te ($ET) ($ET) Into Into The *onome *onomerr Bis(+' Bis(+'Hyd Hydro ro"yet "yethyl hyl)) Terepht rephthal halate ate (BHET) (BHET) $olymer %egradation and &tability &tability55 955 &.".?&.B, ' Khop%' &BB:' Konsep &BB:' Konsep %asar Kimia Analitik Analitik ' 6%%$%! UI Pess' Sil4e Sil4es$ei s$ein' n' 0::0' 0::0' Identification of Organic Organic ,omp!nd- .rd Edition' Edition ' Ne+ o! 6ohn =ile* Sons L$'
