Environ nvi ronmental mental Standa Standards rds Waste Classification lassifi cation
KSA
Presidency of Meteorology and Environment
PME Reference
Kingdom of Saudi Arabia National Environmental Standard Waste Classification
Art ic le I – Pr eli mi nar y
1)
Definitions “ Agricultural Waste” is any waste from a farm or market garden and includes organic matter such as manure from livestock, slurry, silage effluent and crop residues. It also includes packaging and film, and animal treatment dips. “ Animal Waste” includes carcases or parts of animals or fish, or products of animal origin not intended for direct human consumption, with the exception of animal excreta and catering waste. This includes wastes from the preparation and processing of meat, fish and other foods of animal origin. “Asbestos” includes materials containing a naturally occurring fibrous silicate mineral popular in manufacturing and industry due to its strength, chemical and thermal stability. All waste containing greater than 0.1% asbestos is classified as hazardous waste. Types of asbestos waste are:
crocidolite (blue asbestos); actinolite; anthophyllite; chrysotile (white asbestos); amosite (brown asbestos); tremolite; products resulting from the primary crushing of asbestos ore.
“Batteries or Accumulators” are a source of electrical energy generated by direct conversion of chemical energy and consist of one or more primary (non-rechargeable) batteries or secondary (rechargeable) cells, as listed below:
containing more than 0.0005 % of mercury by weight; containing: — more than 25 mg of mercury per cell, except alkaline manganese batteries, — more than 0.025 % of cadmium by weight, — more than 0.4 % of lead by weight. Alkaline manganese batteries containing more than 0.025 % of mercury.
Batteries contain heavy metals such mercury, lead, cadmium and nickel, which can contaminate the environment when improperly disposed of.
“ Biodegradable Waste” is waste that I s capable of undergoing anaerobic or aerobic decomposition, such as food or garden waste and paper and cardboard, i.e. waste that rots. “ Bottom Ash” is ash that collects at the bottom of a combustion chamber. “By-Products” are materials that are not one the intended products of a production process and include many wastes that are not spent materials or sludges. “ Cathode Ray Tubes” are vacuum tubes, made primarily of glass, which constitute the video display component of televisions and computer monitors. These tubes are classed hazardous due to their lead constituent. “ Cement Kiln Dust” is a fine dust generated during the cement production process. ‘Competent Agency’ where referenced, refers to the Presidency of Meteorology and Environment or its designated representative. “ Construction and Demolition Waste” arises from activities such as the construction of buildings and civil infrastructure, total or partial demolition of buildings and civil infrastructure, road planning and maintenance. It mostly includes brick, concrete, hardcore, subsoil and topsoil, but it can also include quantities of timber, metal, plastics and, occasionally, hazardous materials. “Corrosivity” is the property which identifies wastes that can readily corrode or dissolve flesh, metal or other materials. “ Dredged Spoils” consist of the sediments left over from dredging aggregates (hard rock, sand and gravel) from estuaries or coastal areas. “Electrical and Electronic Equipment” (“EEE”) means equipment which is dependent on electric currents or electromagnetic fields in order to work properly and equipment for the generation, transfer and measurement of currents and fields designed for use with a voltage rating not exceeding 1000 volts for alternating current and 1500 volts for direct current. “Fly Ash” refers to particles of ash, such as particulate matter which may also have metals attached to them, which are carried up the stack of a combustion unit with gases during combustion.
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is a commercial or industrial ‘generator’ organisation which produces or stores trackable waste and arranges for this waste to be sent for storage, recycling, treatment or disposal at another location via an authorised transporter. “Green waste” is waste from gardens and parks including tree cuttings, branches, grass, leaves ( with the exception of street sweepings), sawdust, wood chips and other wood waste not treated with and free of heavy metals or organic compounds.
returnable` items used for the same purposes shall also be considered to constitute packaging. Packaging consists only of:
‘hazardous waste” is a waste with properties that make it dangerous or capable of having a harmful effect on human health and/or the environment. ‘ignitability’ is the property which identifies wastes that can readily catch fire and sustain combustion.
‘KSA’ refers to the Kingdom of Saudi Arabia. “ Medical Waste” refers to:
Any waste which consists wholly or partly of human or animal tissue, blood or other body fluids, excretions, drugs or other pharmaceutical products, swabs or dressings, or syringes, needles or other sharp instruments, being waste which unless rendered safe may prove hazardous to any person coming into contact with it; Any other waste arising from medical, nursing, dental, veterinary, pharmaceutical or similar practice, investigation, treatment, care, teaching or research, or the collection of blood for transfusion, being waste which may cause infection to any person coming into contact with it.
“ Mines and Quarry Waste” includes materials such as ‘overburden’, rock inter-bedded with the mineral, and residues left over from initial processing of the extracted material into saleable products. Extraction and processing waste may include:
materials such as waste rock and sandy debris, fine grained materials (tailings), derived from crushing and washing the mineral.
These materials are non-hazardous and mostly chemically inert. They are often largely identical to the geological deposits in the locality from which they are extracted. “ Ozone Depleting Substances” (ODSs) are manmade chemicals used in a variety of applications such as refrigeration, fire fighting, foam blowing and as solvents and aerosol propellants.
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sales packaging or primary packaging, that is, packaging conceived so as to constitute a sales unit to the final user or consumer at the point of purchase; grouped packaging or secondary packaging, that is, packaging conceived so as to constitute at the point of purchase a grouping of a certain number of sales units whether the latter is sold as such to the final user or consumer or whether it serves only as a means to replenish the shelves at the point of sale; it can be removed from the product without affecting its characteristics; transport packaging or tertiary packaging, that is, packaging conceived so as to facilitate handling and transport of a number of sales units or grouped packagings in order to prevent physical handling and transport damage. Transport packaging does not include road, rail, ship and air containers.
‘particulate matter’ refers to small particles emitted from combustion units.
dust-like
(polychlorinated biphenyls) PBBs “ PCBs” (polybrominated biphenyl) and PCTs (polychlorinated terphenyls) are a group of hazardous compounds used for a number of industrial purposes and in electrical products such as capacitors and transformers. ‘PME’ refers to the Presidency of Meteorology and Environment who are designated as the responsible authority for the protection of the environment and the development of environmental protection standards in the Kingdom of Saudi Arabia. “Power Station Ash” is generated from the ash in coal which amounts to abut 15% of the original coal, including pulverised fuel ash and furnace bottom ash. “ Putrescible Waste” is organic matter constituting food scraps, food preparation waste and plate scrapings and other perishable foodstuffs. ‘reactivity’ is the property which identifies wastes that readily explode or undergo violent reactions. “ Scrap Metal” is derived from two sources:
“Packaging” includes products made of any material of any nature used for the containment, protection, handling, delivery and presentation of goods, from raw materials to processed goods, from the producer to the user or the consumer. 'Non-
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new scrap metal generated from metal processing, such as off-cuts, stampings, turnings, grindings and swarf from industries carrying out metal fabrication processes; old scrap metal generated from end of life or obsolete products including heavy scrap from dismantling industrial plants, railway rolling stock and track, and light scrap from the processing of consumer goods such as scrap automobiles and radiators.
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Presidency of Meteorology and Environment
“Spent Materials” are materials that have been used and can no longer serve the purpose for which they were produced without processing. ‘toxicity’ is the property which identifies wastes that are likely to leach dangerous concentrations of toxic chemicals into groundwater. ‘TPLP’ refers Procedure.
to
Toxicity
Property
01) issued by the Presidency of Meteorology and Environment (PME).
3)
Timescales for implementation
. a) The effective date of this standard 01/05/1433H corresponds to 24/03/2012G.
Leaching
‘transporter’ means a person engaged in the offsite transportation of waste by air, rail, highway or water and is anyone who transports the trackable waste from its place of production or storage to another location.
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4)
is
Purpose a) The objective of this document is to establish a national baseline Waste Classification System within the Kingdom of Saudi Arabia. It is anticipated that this document will be employed nationally by all waste handlers to whom they apply with inspections taking place to verify their implementation progress at a regional level as outlined within the s tandards.
‘TSD Facility’ refers to a treatment, storage and/or disposal facility. “Tyres” are composed of vulcanised rubber in addition to the rubberised fabric with reinforcing textile cords, steel or fabric belts and steel-wire reinforcing beads. Waste tyres are those which have been permanently removed from vehicles without the possibility of being remounted for further road use.
b) The Standard for Waste Classification has effect for purposes connected with the regulation of waste and in particular for the purposes of providing: i)
A national classification system that may be employed within KSA by all waste generators, transporters, facility operators and the relevant competent agencies and other interested parties;
ii)
A classification, coding and defining of all waste types so they can be handled, treated or disposed of accordingly;
iii)
A classification methodology to ensure that waste is dealt with appropriately to ensure the protection of human health and the environment.
“ Used Oil Fuel” is any oil that has been refined from crude oil, or any synthetic oil, that has been used and, as a result of such use, is contaminated by physical or chemical impurities. “ Waste Electrical and Electronic Equipment” (“WEEE”) means electrical or electronic equipment which is waste within the meaning of including all components, subassemblies and consumables which are part of the product at the time of discarding. ‘waste handler’ is a generator, transporter and receiver of waste who has waste responsibilities. “ Waste Oils” are any mineral-based lubrication or industrial oils which have become unfit for the use for which they were originally intended, and in particular used combustion engine oils and gearbox oils, and also mineral lubricating oils, oils for turbines and hydraulic oils. (see also Used Oil Fuel). ‘waste tracking’ is the recording of information from the waste generator about the quantity and type of waste produced; recording information about who transported the waste and when; recording information from the waste receiver about the quantity and type of waste received; and matching information about the waste from both the generator and the receiver.
2)
5)
Scope a) These Standards guide those generating, storing and handling wastes in assessing their classification in terms of: i)
The origin of the waste: whether waste is industrial, commercial or municipal;
ii)
The physical form of the waste: whether waste is a liquid or a solid (gaseous waste is outside the scope of this standard);
iii)
The character of the waste: whether waste is hazardous, non-hazardous or inert.
iv)
The type of hazardous waste: whether it is a listed hazardous waste, contains a hazardous constituent or displays a hazardous property.
Citation a) This document may be cited as the Waste Classification Standard for KSA. This standard revises the current General Standards for the Environment (specifically document number 1423-
b) The assessment of waste will enable Waste Handlers to determine the overall manageability of the waste to ascertain the level of control necessary
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Presidency of Meteorology and Environment
and allow for responsible practice to meet any associated environmental obligations.
i) to give the Competent Agency all such assistance; and
c) This Standard defines and classifies waste to be managed in KSA with respect to the form of the waste material and its associated impact on human health or the environment.
6)
ii) to provide the Competent Agency with all such information, as that may reasonably be required for the purpose of carrying out an investigation
d) This Standard is relevant to all waste types currently produced within KSA as well as any other waste streams which may be produced throughout the period of operation of this Standard.
d) The Competent Agency or appointed individual for the purpose of waste classification may:
e) This standard does not apply to the following waste streams:
i) Enter any premises for the purpose of carrying out any investigation.
i)
Discharges of industrial and municipal wastewater to central treatment works or directly to the environment – The Industrial and Municipal Wastewater Discharges and Ambient Water Quality Standards control and manage wastewaters discharges.
ii) carry out such inspections, measurements and tests on premises entered, articles or records found on any such premises, and take away such samples of waste or articles, as may be considered appropriate for the purpose of enabling such investigation; or
ii)
Radioactive waste, other than that produced in the course of healthcare treatment procedures.
iii) at any reasonable time require any relevant party to supply him with copies of, or of extracts from, any records kept for the purpose of demonstrating compliance with the waste classification standard. e) This standard enables the issue of regulations and technical memoranda which are enforceable by the Competent Agency who hold delegated authority under the General Environmental Regulations.
Exemptions a) Specific exemptions may be specified within this standard at any point where relevant to the Article that they are common to.
7)
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8)
Powers of Authority a) Within the scope of these standards the Competent Agency may: i)
Prescribe specific requirements as to the classification of individual wastes that may be present in or absent within the Kingdom;
ii)
authorise such relaxations or departures from, the waste classification standards and make any such authorisation subject to the prescribed conditions, and to modify or revoke any such authorisation or condition; and
iii)
a) Failure to comply with the requirements of these standards may lead to prosecution by the Competent Agency and those convicted of such failure may be subject to fines or periods of imprisonment as laid out in the General Environmental Regulations. b) It is anticipated that the requirements of this standard will be enforced nationally with inspections taking place to verify their implementation at a regional and local level.
9)
Penalty fines
10)
a) Maximum fines that may be imposed for exceeding the applicable standard, breach of permit and failure to comply with an abatement notice are set out in the General Environmental Regulations. Appeals
authorise a local Competent Agency to exercise any power conferred by these regulations by paragraphs i) - iii) above.
b) The Competent Agency may, for the purposes of this Standard, appoint persons to act on their behalf as technical assessors and monitors in relation to the powers and duties conferred on him by this standard and/or its subsequent amendments.
Enforcement procedur es
a) A right of appeal exists for any organisation or individual who is required to take action as a consequence of the implementation of the revised standard.
c) In addition to the responsibilities conferred by other sections contained within this standard, it shall be the duty of a relevant party;
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11)
Presidency of Meteorology and Environment
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b) The right of appeal against conviction or sentence is available through the appropriate judicial system as set out in the General Environmental Regulations.
viii) chemicals and other substances which no longer perform satisfactorily such as contaminated solvents and acids;
c) All appeals should be fully supported with a documented case containing as a minimum, the information required under the appeals process of the General Environmental Regulations.
ix)
slags, still bottoms and other industrial process residues;
x)
scrubber sludges, spent filters, baghouse dusts and other residues from pollution abatement processes;
xi)
residues from machining or finishing such as lathe turnings and mill scales;
Periodic Review
a) As a minimum, the Competent Agency shall undertake a periodic review of this standard every 5 years.
xii) residues from the extraction and processing of raw materials, such as mining residues;
b) Where new information suggests that adjustments are required to this standard, all changes will be subject to the appropriate consultation and will be notified to facilities by the Competent Agency. Appropriate implementation time will be allowed.
xiii) materials which have been adulterated such as oil contaminated with greater than 50 ppm of polychlorinated biphenyls (PCBs); xiv) banned substances that require disposal; xv) products which the holder no longer requires (including agricultural, household, office, commercial and shop waste); and
Art ic le II – Def in in g Was te
1)
What is Waste?
xvi) contaminated substances, materials and products which result from the remediation of contaminated land.
a) Treatment, storage or disposal operators of waste need to ensure uniformity in defining and classifying the type of waste they handle. A material or substance will be considered a waste which the holder; i)
discards;
ii)
intends to discard; or
iii)
are required to discard.
c) Once it is established that a substance or material constitutes a waste, the following further classification is required by Waste Handlers to ensure that unknown wastes are handled appropriately and in accordance with the requirements as specified, to include; i)
identification of the waste origin of the waste, that is, is it produced by an industrial, commercial or municipal waste Generator;
ii)
establish the physical form of the waste, that is, is it a liquid or a solid;
iii)
analysis of the waste to ascertain its character, that is, whether it is hazardous, non-hazardous or inert; and
iv)
if the waste is hazardous, it will be subject to additional classification according to the type of waste stream and/or risk it presents to human health or the environment.
b) Examples of waste that generators discard include; i)
residues from production or consumption;
ii)
off-specification products;
iii)
products which have passed their ‘use-by’ date;
iv)
materials which have been spilled and any other materials or items which have been contaminated by the spillage;
v)
contaminated materials which have been used in cleaning up a spillage such as residues from cleaning operations, containers or packaging;
vi)
reject batteries;
vii)
exhausted catalysts;
Art ic le III – Was te Or ig in s
1)
Industr ial, Commercial and Municipal Origins
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Waste
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Presidency of Meteorology and Environment
a) The origin of the waste needs to be ascertained so that compliance with the regulatory control measures can be met and the information supplied for the purposes of Waste Tracking, as required under the Waste Regulatory Control and Compliance Standard which provides a breakdown of waste origins with codes for industrial and commercial waste.
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x)
waste from premises used for the purposes of breeding, boarding, stabling or exhibiting animals;
xi)
automotive and lubricant waste oil, waste solvent or scrap metal, other than household waste;
xii) waste imported into KSA; 2)
xiii) tank washings or ships’ waste landed in KSA;
Industr ial Waste a) To assist Waste Handlers in identifying their waste, the following is an exemplary list of the type of waste that can be cl assified as industrial; i)
waste from business premises used for maintaining vehicles, vessels or aircraft (except waste from small private garages , etc);
xiv) waste from works of construction or demolition, other than those carried out by private individuals at their own properties.
3)
Commercial Waste a) To assist Waste Handlers in identifying their waste, the following is an exemplary list of the type of waste that can be classified as commercial;
ii)
waste from a laboratory;
iii)
waste from a workshop or similar premises (not including factories or premises at which the principal activities are computer operation or the copying of documents by photographic or lithographic means);
i)
waste from an office or showroom;
ii)
waste from a hotel;
iii)
waste from the ‘business’ part of a building which is used for both domestic and trade purposes;
iv)
waste from premises occupied by a club, society or association;
v)
waste from premises occupied by a: Court; Government department or Municipality authority; Body corporate or an individual appointed to discharge any public functions.
vi)
waste from a tent pitched on land other than a camp site;
vii)
waste from a souk, market or fair; and
viii)
waste from open land collected by a contractor on behalf of the relevant Municipality or PME.
iv) waste from premises occupied by an approved scientific research association; v)
vi)
medical waste other than medical waste from a domestic property, caravan or residential home, or from a moored vessel which is only used as living accommodation; waste arising from any aircraft, vehicle or vessel which is not occupied for domestic purposes;
vii) waste which has previously formed part of any aircraft, vehicle or vessel and which is not classified as municipal waste; viii) harmful or hazardous leachate from a deposit of waste; ix)
poisonous or noxious waste arising from any of the following processes undertaken on business or trade premises; -
-
mixing or selling paints; sign writing; laundering or dry cleaning; developing or printing photographs; selling petrol, diesel fuel, paraffin, kerosene, heating oil or similar substances; selling pesticides, herbicides or fungicides.
4)
Municipal Waste a) To assist Waste Handlers in identifying their waste, the following is an exemplary list of the type of waste that can be classified as municipal and constitutes waste from a domestic property, caravan, residential home, educational establishment, hospital or nursing home which includes; i)
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waste from any land associated with domestic property, including a caravan or residential home;
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Presidency of Meteorology and Environment
ii)
c) Liquid waste may be classified into the following five groups;
waste from a garage which is used wholly or mainly to accommodate a private motor vehicle;
iii)
waste from private storage premises used wholly or mainly for the storage of domestic articles;
iv)
waste from a moored vessel which is used only for living accommodation;
v)
waste from a place of worship, which is exempted from business rates;
vi)
waste from premises occupied by a charity and used for charitable purposes;
i)
water containing larger quantities of filterable or non-filterable solids. Examples are: dredge spoil, mine tailings, and slurries, provided that they are not contaminated with suspended or dissolved chemicals to an extent that requires them to be disposed of in a controlled manner;
ii)
water containing larger quantities dissolved chemical substances;
of
iii)
water containing larger quantities nutrients, that is, wastewater effluent;
of
iv)
non-aqueous liquids. Examples are: oils, solvents and solvent containing liquids such as coatings and paints; and
v)
combinations of two or more of the above groups.
vii) waste from a camp site; viii) waste from institution; ix)
x)
a prison
or
other penal
waste from a hall or other premises used wholly or mainly for public meetings;
d) The following liquids shall not be deemed as wastes for the purposes of t his Standard;
waste arising from street cleaning for which the Competent Agency is responsible;
i)
domestic sanitary waste water and other wastes passing through the sanitary drainage network to the treatment facility. This exclusion does not cover sludge resulting from the sanitary waste water treatment facility or wastewaters being collected, stored or treated before discharge;
ii)
final discharge of treated industrial wastewater. This exclusion does not cover wastewater prior to discharge;
iii)
agricultural drainage runoff and irrigation return flows; and
iv)
mining residual matter remaining at their natural location in the mine during excavation.
xi) municipal waste delivered to municipal recycling points; xii) municipal parks and garden wastes; xiii) civic amenity site waste.
Art ic le IV – Ph ys ic al Fo rm s o f Was te
1)
Liqui d Waste a) Waste in liquid form should be regarded as; i)
ii)
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any waste that near instantaneously flows into an indentation void made in the surface of the waste; or any waste load containing free draining liquid substance in excess of 250 litres or 10% of the load volume, whichever represents the lesser amount. “Free draining” means a liquid as defined in i), irrespective of whether that liquid is in a container.
b) The second interpretation should be used where liquids are known to be present in small amounts in a generally solid waste, for example, cartons of milk or juice in mixed commercial waste or are adventitious in a waste, for example, liquid that has drained or been squeezed from components of the waste.
2)
Solid Wastes a) For waste to be considered solid, it must meet all of the following criteria: i)
it has an angle of repose of greater than five degrees (5°);
ii)
it has no free liquids in excess of 10% of the load volume, when tested in accordance with the USEPA Paint Filter Liquids Test – Method 9095 (USEPA 1986);
iii)
it liberates transported;
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no
free
liquids
when
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iv)
v)
it does not become free flowing at or below 60°C or when transported; and
i)
asbestos waste; and
it is spadeable.
ii)
waste classified as hazardous from a hospital, clinic, doctor’s office or a nursing or dental establishments.
b) All other waste that is not gaseous is considered to be liquid waste.
3)
4)
Sludge
Inert Waste a) Waste is inert if:
a) A sludge will be defined as a liquid or solid waste depending on whether its particular characteristics meet the criteria set out in Section (1), liquid Waste, or Section (2), Solid Waste, of this Article respectively.
i)
it does not undergo physical, chemical transformations;
ii)
when in contact with other matter, it does not react in any way which would cause environmental pollution or harm to human health (for example, by dissolving, burning or biodegrading); and
iii)
it produces only an insignificant quantity of leachate, which would not cause pollution or endanger the quality of surface or groundwater.
Art ic le V – Ch arac ter of Wast e
1)
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Waste Characteristic s a) Industrial, commercial or municipal waste origins may comprise liquid and solid waste types which may be hazardous, non-hazardous or inert, ranging from the most harmful to the environment to the least harmful.
any or
significant biological
Art ic le VI –Hazard ou s Was te 2)
Hazardous Waste a) Hazardous waste is waste which presents a hazard to human health or the environment because it contains dangerous substances. A waste is hazardous if; i)
3)
it is included in the Hazardous Waste List, Appendix A, Table 1; and/or
ii)
it contains one of the hazardous constituents listed in Appendix B, Table 2; and/or
iii)
it displays one of the hazardous properties listed in Appendix C, Table 3, for example, toxic, corrosive or dangerous to the environment; and/or
iv)
the waste is a mix of hazardous and nonhazardous materials; or
v)
if the Competent Agency decides consider them specifically hazardous.
to
Non-Hazardou s Waste a) Non-hazardous waste is waste which is not classified as either hazardous or inert. It comprises non-hazardous industrial and commercial waste streams.
1)
Classific ation of hazardous waste a) To establish whether a waste is classified as hazardous, it must be determined if the waste is Listed on the Hazardous Waste List (Appendix A, Table 1). b) If a waste is identified as one of the waste streams in the Hazardous Waste List then it must be classified and treated as hazardous, irrespective of whether a hazardous waste constituent or property is present or not in the waste. The Table lists wastes from generic industrial processes, wastes from certain sectors of industry and unused pure chemical products and formulations. Any waste fitting a narrative listing description is considered a listed hazardous waste. c) If the waste is not listed, a waste Generator must then establish whether the waste contains any of the hazardous constituents listed in Appendix B, Table 2. These constituents pose a threat to human health and the environment. d) If the waste is not listed in the Hazardous Waste List or does not contain one of the hazardous waste constituents, the assessor of the waste must determine the waste’s composition to establish whether it contains a hazardous property, as listed in Appendix C, Table 3, according to either: i)
b) All municipal waste is classified as nonhazardous except:
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its physical property, flammability; or
for
example,
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ii)
2)
the concentration substance(s).
of
dangerous
3)
a) The composition of the waste can be identified using: chemical analysis of the waste;
ii)
knowledge of the process or activity that produced the waste;
iii)
safety data sheets;
iv)
previous analyses of the waste.
i)
-
ii)
ii)
2)
liquid wastes (other than those aqueous waste containing less than 24% alcohol by volume) that have a flash point less than 60°C (140°F). The flash point test determines the lowest temperature at which the fumes above a waste will ignite when exposed to flame; solid wastes that, under standard temperature and pressure, are capable of causing fire through friction, absorption of moisture, or spontaneous chemical changes and, when ignited, burn so vigorously and persistently that they create a hazard.
4)
Potentially explosive; Reacts violently; or Generates toxic gases or vapours.
iii)
If a cyanide or sulfide-bearing waste is exposed to pH conditions between 2 and 12.5, it can generate enough toxic gases, vapours, or fumes to present a danger to human health or the environment.
i)
It is normally unstable and readily undergoes violent change without detonating or becomes unstable if resulting from decomposition from shock or impact.
Ignitability a) Wastes that display the ignitability property are those that can readily catch fire and sustain combustion. Wastes that are hazardous because they may ignite include the following:
At standard temperature and pressure; If subjected to a strong ignition source; or If heated under confinement.
When mixed with water, it is: -
Art ic le VII – Hazar do us Wast e Pro per ti es
i)
It is capable of detonation or explosive decomposition or reaction; -
b) If the composition of the waste is not known, the waste assessor is still responsible for determining whether it displays a hazardous property.
1)
Reactivity a) The reactivity property identifies wastes that readily explode or undergo violent reactions or react to release toxic gases or fumes. A waste is considered reactive if it meets any of the following conditions;
The Composi tion of Hazardous Waste
i)
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Toxicity a) Toxic compounds or elements can leach into underground drinking water supplies and expose users of the water to hazardous chemicals and constituents. A waste is toxic if it is likely to leach dangerous concentrations of toxic chemicals into groundwater. The Toxicity Property Leaching Procedure (TPLP) requires that a liquid leachate is created from a hazardous waste sample. It must then be determined whether the leachate contains any of the toxic chemicals in amounts above the specified levels listed in Appendix D, Table 4.
Corrosivity a) Corrosive wastes can readily corrode or dissolve flesh, metal or other materials. Corrosive hazardous wastes include the following; i)
aqueous wastes with a pH of 2 units or below or of 12.5 units or above; and
ii)
liquid wastes that corrode steel at a rate greater than 6.35 mm (0.250 inches) per year.
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Ap pendi x A – Table 1 Hazardous Waste Lis t
Y1
Clinical wastes from medical care in hospitals, medical centres and clinics
Y2
Wastes from the production and preparation of pharmaceutical products, drugs and medications
Y3
Wastes from the production, formulation and use of biocides and phytopharmaceuticals
Y4
Wastes from the manufacture, formulation and use of wood preserving chemicals
Y5
Wastes from the production, formulation and use of organic solvents
Y6
Wastes from heat treatment and steel tempering operations containing cyanides
Y7
Waste mineral oils unfit for their originally intended use
Y8
Waste oils/water, hydrocarbons/water mixtures, emulsions
Y9
Waste substances and articles containing (greater than 50 ppm) polychlorinated biphenyls (PCBs) and/or polychlorinated terphenyls (PCTs) and/or polybrominated biphenyls (PBBs)
Y10
Waste tarry residues arising from refining, distillation and any pyrolysis treatment
Y11
Wastes from production, formulation and use of inks, dyes, pigments, paints, lacquers, varnish
Y12
Wastes from production, formulation and use of resins, latex, plasticizers, glues and adhesives
Y13
Waste chemical substances arising from research and development or teaching activities which are not known and are new and whose effects on human health and the environment are not yet known
Y14
Wastes of an explosive nature not subject to other regulations or standards
Y15
Wastes from production, formulation and use of photographic chemicals and processing materials
Y16
Wastes resulting from surface treatment of metals and plastics
Y17
Residues arising from industrial waste disposal operations
Y18
Petroleum refinery wastewater treatment sludges
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PME Reference
Ap pendi x B – Table 2 Hazardous Waste Constituents
Y19 Y20 Y21 Y22 Y23 Y24 Y25 Y26 Y27 Y28 Y29 Y30 Y31 Y32 Y33 Y34 Y35 Y36 Y37 Y38 Y39 Y40 Y41 Y42 Y43 Y44
Metal carbonyls Beryllium and beryllium compounds Hexavalent chromium compounds Copper compounds Zinc compounds Arsenic and arsenic compounds Selenium and selenium compounds Cadmium and cadmium compounds Antimony and antimony compounds Tellurium and tellurium compounds Mercury and mercury compounds Lead and lead compounds Inorganic fluorine compounds excluding calcium fluoride Inorganic cyanides Acidic solutions or acids in solid form Basic solutions or bases in solid form Asbestos (dust and fibres) Organic phosphorus compounds Organic cyanide compounds Phenols and phenol compounds, including chlorophenol compounds Ether compounds Halogenated organic solvents Organic solvents other than halogenated solvents Any congener of polychlorinated dibenzo-furan Any congener of polychlorinated dibenzo-p-dioxin Organic halogen compounds other than substances referred to in this Table
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Presidency of Meteorology and Environment
PME Reference
Ap pendi x C – Tabl e 3 Hazardous Property List H1 Explosive H2 Oxidising H3 Highly Flammable
H3B Flammable H4 Irritant
H5 Harmful H6 Toxic
H7 Carcinogenic H8 Corrosive H9 Infectious H10 Toxic for Reproduction
H11 Mutagenic
H12 Toxic Gas Release H13 Ecotoxic H14
Substances and preparations which may explode under the effect of flame or which are more sensitive to shocks or friction than dinitrobenzene Substances and preparations which exhibit highly exothermic reactions when in contact with other substances, particularly flammable substances (a) liquid substances and preparations having a flashpoint below 21°C (b) substances and preparations which may become hot and finally catch fire in contact with air at ambient temperatures without any application of energy (c) solid substances and preparations which may readily catch fire after brief contact with a source of ignition and which continue to burn or to be consumed after removal of the source of ignition (d) gaseous substances and preparations which are flammable in air at normal pressure (e) substances and preparations which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities Liquid substances and preparations having a flashpoint >=21°C and <=55°C Non-corrosive substances and preparations which, through immediate, prolonged or repeated contact with the skin or mucous membrane, can cause inflammation Substances and preparations which, if they are inhaled or ingested or if they penetrate the skin, may involve limited health risks Substances and preparations (including very toxic substances and preparations) which, if they are inhaled or ingested or if they penetrate the skin, may involve serious, acute or chronic health risks and even death Substances and preparations which, if they are inhaled or ingested or if they penetrate the skin, may induce cancer or increase it s incidence Substances and preparations which can readily corrode or dissolve flesh, metal or other materials Substances containing viable micro-organisms or their toxins which are known or reliably believed to cause disease in man or living organisms Substances or preparations which, if they are inhaled or ingested or if they penetrate the skin, may produce or increase the incidence of non-heritable adverse effects in the progeny and/or of male or female reproductive functions or capacity Substances and preparations which, if they are inhaled or ingested or if they penetrate the skin, may induce hereditary genetic defects or increase their incidence Substances or preparations which release toxic or very t oxic gases in contact with water, air or an acid Substances or preparations which present or may present immediate or delayed risks for one or more sectors of the environment Substances and preparations capable by any means, after disposal, of yielding another substance, for example leachate, which possesses any of the characteristics H1 to H13
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Presidency of Meteorology and Environment
PME Reference
Ap pendi x D – Tabl e 4
Toxicity Property Leaching Procedure Regulatory Levels
Contaminant Arsenic Barium Benzene Cadmium Carbon Tetrachloride Chlordane Chlorobenzene Chloroform Chromium o-Cresol* m-Cresol* p-Cresol* Total Cresols 2,4-D 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,1-Dichlorobenzene 2,4-Dichlorobenzene Endrin Heptachlor (and its epoxide) Hexachlorobenzene Hexachlorobutadiene Hexachloroethane Lead Lidane Mercury Methoxychlor Methyl ethyl ketone Nitrobenzene Pentachlorophenol Pyridine Selenium Silver Tetrachloroethylene Toxaphene Trichloroethylene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4,5-TP (Silvex) Vinyl Chloride
Concentration mg/l 5.0 100.0 0.5 1.0 0.5 0.03 100.0 6.0 5.0 200.0 200.0 200.0 200.0 10.0 7.5 0.5 0.7 0.13 0.02 0.0008 0.13 0.5 3.0 5.0 0.4 0.2 10.0 200.0 2.0 100.0 5.0 1.0 5.0 0.7 0.5 0.5 400.0 2.0 1.0 0.2
* if 0-, m- and p-cresols cannot be individually measured, the level for total cresols is used.
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