CALCULO DE LA PRESION DE VAPOR PARA SUSTANCIAS PURAS
ECUACION DE ANTOINE !og10 ap = A - B 45 C C89 mmHg T= No. = Sustancia =
Constantes = a!or Ca!cu!ado"
20 107 C3H6 3H6O
°C
<---- Ingrese temperatura <---- Ingrese No. de Sustancia
acetone
A B 7.2316 1277.03 Pvap = 1#$.%& Pvap = 0.2$6&#
C 237.23 mmHg bar
Tmin -32
BASES DE DATOS 1. POLIN!" BRUCE# PRAUSNIT$" %OHN & O'CONNELL" %OHN. :5(e roperties o* ;ases and c;ra> Hi!!. Ne> ?or@. ?or@. 2001 2. UNIVERSITY OF MARYLAND. (ttp">>>.engr. (ttp">>>.engr.umd.eduAns>enc(2&0antoine.dat umd.eduAns>enc(2&0antoine.dat No. 1 2 3 $ & 6 7 # % 10 11 12 13 1$ 1& 16 17 1# 1% 20 21 22 23 2$ 2& 26 27 2#
SUSTANCIA car'on-tetrac(!oride tric(!oro*!uoromet(ane di dic(!orodi*!uoromet(ane c(!orotri*!uoromet(ane car'on-tetra*!uoride car'on-mono,ide car'on-dio,ide car'on!-su!*ide car'on-disu!*ide c(!oro*orm dic(!oro*!uoromet(ane c(!orodi*!uoromet(ane tri*!uoromet(ane triiodomet(ane isot(iocanic-acid dic(!oromet(ane c(!oro*!uoromet(ane di*!uoromet(ane diiodomet(ane *orma!de(de *ormic-acid 'romomet(ane c(!oromet(ane *!uoromet(ane iodomet(ane nitromet(ane met(!-nitrite met(!-nitrate
FORULA CC)$ CC)3+ CC)2+2 CC)+3 C+$ CO CO2 COS CS2 CHC)3 CHC)2+ CHC)+2 CH+3 CHI3 CHNS CH2C)2 CH2C)+ CH2+2 CH2I2 CH2O CH2O2 CH3/ CH3C) CH3+ CH3I CH3NO2 CH3NO2 CH3NO3
A 6.#%$1 6.##$3 6.6#61% 6.3&10% 6.%723 6.2$02 %.#106 6.%0723 6.%$1% 6.%371 6.%7&7& 6.7&77 7.0##6 6.&%&%# 0 7.0#03 6.20$&2 7.13#% 6.%$2$6 7.1&61 7.377% 6.%&%7 6.%%$$ 7.0%76 6.%## 7.0$$ 0 0
B 121%.&# 10$3.01 7#2.072 &22.061 &$0.& 230.27 13$7.7% #0$.$# 116#.62 1171.2 %%6.267 7$0.3% 70&.33 1&67.# 0 113#.%1 7$0.3% #21.7 1&67.# %&7.2$ 1&63.2# %#6.&% %02.$& 7$0.22 11$6.3$ 12%1 0 0
C 227.17 236.#6 23&.377 231.677 260.1 260.01 273 2&0 2$1.&$ 227 23$.172 231.#6 2$%.7# 20$ 0 231.$6 231.#6 2$$.7 20$ 2$3.01 2$7.07 23#.33 2$3.61 2&3.#% 236.66 20%.01 0 0
2% 30 31 32 33 3$ 3& 36 37 3# 3% $0 $1 $2 $3 $$ $& $6 $7 $# $% &0 &1 &2 &3 &$ && &6 &7 &# &% 60 61 62 63 6$ 6& 66 67 6# 6% 70 71 72 73 7$ 7& 76 77 7# 7%
met(ane met(ano! met(anet(io! met(!amine tetrac(!oroet(ene (e,ac(!oroet(ane 112tric(!orotri*!uoroet(ane 12 1 2dic(!orotetra*!uoroet(ane c(!oropenta*!uoroet(ane tetra*!uoroet(ene (e,a*!uoroet(ane canogen tric(!oroet(ene pentac(!oroet(ane tri*!uoroet(ene acet!ene4et(ne8 1B1-dic(!oroet(ene cis-1B2-dic(!oroet(ene trans-1B2-dic(!oroet(ene 1B1B2B2-tetrac(!oroet(ane 1B1-di*!uoroet(ene cis-1B2-di*!uoroet(ene trans-1B2-di*!uoroet(ene @etene 'romoet(!ene c(!oroet(ene 1B1B2-tric(!oroet(ane acet!-c(!oride *!uoroet(ene 1B1B1-tri*!uoroet(ane acetonitri!e et(!ene 1B2-di'romoet(ane 1B1-dic(!oroet(ane 1B2-dic(!oroet(ane 1B1-di*!uoroet(ane 1B2-diiodoet(ane et(!ene-o,ide aceta!de(de acetic-acid met(!-*ormate t(ioacetic-acid t(iacc!opropane 'romoet(ane c(!oroet(ane *!uoroet(ane iodoet(ane et(!enimine nitroet(ane et(!-nitrate et(ane
CH$ CH$O CH$S CH&N C2C)$ C2C)6 C2C)3+3 C2C)2+$ C2C)+& C2+$ C2+6 C2N2 C2HC)3 C2HC)& C2H+3 C2H2 C2H2C)2 C2H2C)2 C2H2C)2 C2H2C)$ C2H2+2 C2H2+2 C2H2+2 C2H2O C2H3/ C2H3C) C2H3C)3 C2H3C)O C2H3+ C2H3+3 C2H3N C2H$ C2H$/2 C2H$C)2 C2H$C)2 C2H$+2 C2H$I2 C2H$O C2H$O C2H$O2 C2H$O2 C2H$OS C2H$S C2H&/ C2H&C) C2H&+ C2H&I C2H&N C2H&NO2 C2H&NO3 C2H6
6.6%&61 #.072$ 7.03163 7.$%6% 7.02 7.0#633 6.##03 6.#70#$ 6.#333 6.#%66 6.7%33 6.$362% 7.02#1 6.7$ &.6#71& %.1$02 6.%722 7.0223 6.%6&1 6.6317 6.3$%1# &.31$01 &.31$01 6.%&73 7.2$37% 6.$%71 6.%6&3 6.#$07 6.33%$% 6.%03# 7.073& 6.7$7&6 6.721$# 6.%#&3 7.02&3 7.03 6.%##3$ 7.2701 7.0&6& 7.2%%6 7.170$ 7.7$##% 7.0372& 6.%2 6.%$ 6.%7#& 6.%&% 7.1323 7.̉ 7.1637 6.#3$&2
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267.777 23#.#7 23#.706 2$0.2$ 221.01 1%7.0$# 227.& 232.632 2$2.2# 2$&.%$ 2$6.22 1#2.30# 230.01 1%7 227.23 2#0.% 237.2 230.6 231.% 17%.% 227.23% 227.23 227.23 23#.01 26$.021 230.01 217 217.63 2$3.111 2$3.2$ 22$.01 2&& 201.7& 22#.13 222.%$ 2$$ 201 2$$.1& 236.01 216.#2 230.&6 216.#2 232.$2 231.72 236.6# 2$6.16 22% 210.01 2$1.1#7 22$.% 2&6.$7
2% 30 31 32 33 3$ 3& 36 37 3# 3% $0 $1 $2 $3 $$ $& $6 $7 $# $% &0 &1 &2 &3 &$ && &6 &7 &# &% 60 61 62 63 6$ 6& 66 67 6# 6% 70 71 72 73 7$ 7& 76 77 7# 7%
met(ane met(ano! met(anet(io! met(!amine tetrac(!oroet(ene (e,ac(!oroet(ane 112tric(!orotri*!uoroet(ane 12 1 2dic(!orotetra*!uoroet(ane c(!oropenta*!uoroet(ane tetra*!uoroet(ene (e,a*!uoroet(ane canogen tric(!oroet(ene pentac(!oroet(ane tri*!uoroet(ene acet!ene4et(ne8 1B1-dic(!oroet(ene cis-1B2-dic(!oroet(ene trans-1B2-dic(!oroet(ene 1B1B2B2-tetrac(!oroet(ane 1B1-di*!uoroet(ene cis-1B2-di*!uoroet(ene trans-1B2-di*!uoroet(ene @etene 'romoet(!ene c(!oroet(ene 1B1B2-tric(!oroet(ane acet!-c(!oride *!uoroet(ene 1B1B1-tri*!uoroet(ane acetonitri!e et(!ene 1B2-di'romoet(ane 1B1-dic(!oroet(ane 1B2-dic(!oroet(ane 1B1-di*!uoroet(ane 1B2-diiodoet(ane et(!ene-o,ide aceta!de(de acetic-acid met(!-*ormate t(ioacetic-acid t(iacc!opropane 'romoet(ane c(!oroet(ane *!uoroet(ane iodoet(ane et(!enimine nitroet(ane et(!-nitrate et(ane
CH$ CH$O CH$S CH&N C2C)$ C2C)6 C2C)3+3 C2C)2+$ C2C)+& C2+$ C2+6 C2N2 C2HC)3 C2HC)& C2H+3 C2H2 C2H2C)2 C2H2C)2 C2H2C)2 C2H2C)$ C2H2+2 C2H2+2 C2H2+2 C2H2O C2H3/ C2H3C) C2H3C)3 C2H3C)O C2H3+ C2H3+3 C2H3N C2H$ C2H$/2 C2H$C)2 C2H$C)2 C2H$+2 C2H$I2 C2H$O C2H$O C2H$O2 C2H$O2 C2H$OS C2H$S C2H&/ C2H&C) C2H&+ C2H&I C2H&N C2H&NO2 C2H&NO3 C2H6
6.6%&61 #.072$ 7.03163 7.$%6% 7.02 7.0#633 6.##03 6.#70#$ 6.#333 6.#%66 6.7%33 6.$362% 7.02#1 6.7$ &.6#71& %.1$02 6.%722 7.0223 6.%6&1 6.6317 6.3$%1# &.31$01 &.31$01 6.%&73 7.2$37% 6.$%71 6.%6&3 6.#$07 6.33%$% 6.%03# 7.073& 6.7$7&6 6.721$# 6.%#&3 7.02&3 7.03 6.%##3$ 7.2701 7.0&6& 7.2%%6 7.170$ 7.7$##% 7.0372& 6.%2 6.%$ 6.%7#& 6.%&% 7.1323 7.̉ 7.1637 6.#3$&2
$0&.$2 1&7$.%% 101&.&$7 107%.1& 1$1&.$% 1626.%$& 10%%.% %$2.336 #02.%7 6#3.#$ 6&7.06 &76.&7% 131&.1 137# $%1.3&% 1232.6 10%%.$ 120&.$ 11$1.% 122#.1 $%1.3&% $%1.3&% $%1.3&% #03.1 121%.30# 7#3.$ 13&1 1062.#6 &%3.&&1 7##.21 127%.2 &#& 12#0.#2 1171.$2 1271.2& %10 16$7.1 111&.1 1070.6 1$7%.02 112&.2 1$7%.02 11%$.37 10%0.#1 1012.7# #&$.21 1232 1133.7 1671.266 133#.# 663.7
267.777 23#.#7 23#.706 2$0.2$ 221.01 1%7.0$# 227.& 232.632 2$2.2# 2$&.%$ 2$6.22 1#2.30# 230.01 1%7 227.23 2#0.% 237.2 230.6 231.% 17%.% 227.23% 227.23 227.23 23#.01 26$.021 230.01 217 217.63 2$3.111 2$3.2$ 22$.01 2&& 201.7& 22#.13 222.%$ 2$$ 201 2$$.1& 236.01 216.#2 230.&6 216.#2 232.$2 231.72 236.6# 2$6.16 22% 210.01 2$1.1#7 22$.% 2&6.$7
#0 #1 #2 #3 #$ #& #6 #7 ## #% %0 %1 %2 %3 %$ %& %6 %7 %# %% 100 101 102 103 10$ 10& 106 107 10# 10% 110 111 112 113 11$ 11& 116 117 11# 11% 120 121 122 123 12$ 12& 126 127 12# 12% 130
met(!-et(er et(!-a!co(o! et(!ene-g!co! met(!-su!*ide et(anet(io! met(!-disu!*ide et(!amine dimet(!amine acr!onitri!e a!!ene4propadiene8 propne4met(!acet!ene8 acr!ic-acid 3-'romo-1-propene 3-c(!oro-1-propene 1B2B3-tric(!oropropane 3-iodo-1-propene propionitri!e propene cc!opropane 1B2-di'romopropane 1B2-dic(!oropropane 1B3-dic(!oropropane 2B2-dic(!oropropane 1B2-diiodopropane prop!ene-o,ide a!!!-a!co(o! propiona!de(de acetone t(iacc!o'utane 1-'romopropane 2-'romopropane 1-c(!oropropane 2-c(!oropropane 1-*!uoropropane 2-*!uoropropane 1-iodopropane 2-iodopropane 1-nitropropane 2-nitropropane prop!-nitrate isoprop!-nitrate propane et(!-met(!-et(er prop!-a!co(o! isoprop!-a!co(o! et(!-met(!-su!*ide 1-propanet(io! 2-propanet(io! prop!amine trimet(!amine octa*!uorocc!o'utane
C2H6O C2H6O C2H6O2 C2H6S C2H6S C2H6S2 C2H7N C2H7N C3H3N C3H$ C3H$ C3H$O2 C3H&/ C3H&C) C3H&C)3 C3H&I C3H&N C3H6 C3H6 C3H6/2 C3H6C)2 C3H6C)2 C3H6C)2 C3H6I2 C3H6O C3H6O C3H6O C3H6O C3H6S C3H7/ C3H7/ C3H7C) C3H7C) C3H7+ C3H7+ C3H7I C3H7I C3H7NO2 C3H7NO2 C3H7NO3 C3H7NO3 C3H# C3H#O C3H#O C3H#O C3H#S C3H#S C3H#S C3H%N C3H%N C$+#
7.316$ #.2133 #.7%$& 6.%$#7% 6.%&206 6.%77%2 7.3#62 7.063% 6.%163 &.7137 6.7#$#& 7.1%26 7.0&1#7 6.%3## 7.002# 6.%6%3 6.%301 6.#1%6 6.##7% 6.#%10& 6.%6&$ 6.%71#6 6.%$#2 6.076& 6.6&$6 7.3$2$ 7.0$%3 7.2316 7.01667 7.03766 7.00$63 6.%311 6.%6&$ 6.%&33 7.07$&1 7.22121 7.0167 7.11$6 7.$#6&$ 7.7371% 6.$2006 6.#03%# &.##1% 7.61%2 #.11#2 6.%3#$% 6.%2#$6 6.#773$ 6.%$6# 6.%70$ 6.#1&3
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'utadine4'iacet!ene8 1'uten3ne4in!acet!ene8 *uran t(iop(ene 1B2-'utadiene 1B3-'utadiene 1-'utne4et(!acet!ene8 2-'utne4dimet(!acet!ene8 cc!o'utene acetic-an(dride 'utronitri!e iso'utronitri!e 1-'utene 2-'uteneBcis 2-'uteneBtrans 2-met(!propene cc!o'utane 1B2-di'romo'utane 2B3-di'romo'utane 1B2-diiodo'utane 'utra!de(de 2-'utanone p-dio,ane et(!-acetate t(iacc!opentane 1-'romo'utane 2-'romo'utane 2-'romo-2-met(!propane 1-c(!oro'utane 2-c(!oro'utane 1-c(!oro-2-met(!propane 2-c(!oro-2-met(!propane 2-iodo-2-met(!propane prro!idine 1-nitro'utane 2-nitro'utane 'utane 2-met(!propane4iso'utane8 et(!-et(er met(!-prop!-et(er met(!-isoprop!-et(er 'ut!-a!co(o! sec-'ut!-a!co(o! tert-'ut!-a!co(o! et(!su!*ide isoprop!-met(!-su!*ide met(!-prop!-su!*ide 1-'utanet(io! 2-'utanet(io! 2-met(!-1-propanet(io! 2-met(!-2-propanet(io!
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et(!-disu!*ide 'ut!amine sec-'ut!amine tert-'ut!amine diet(!amine pridine 2-met(!t(iop(ene 3-met(!t(iop(ene 1B2-pentadiene 1B3-pentadieneBcis 1B3-pentadieneBtrans 1B$-pentadiene 2B3-pentadiene 3-met(!-1B2-'utadiene 2-met(!-1B3-'utadiene 1-pentne 2-pentne 3-met(!-1-'utne cc!opentene spiropentane 1-pentene 2-penteneBcis 2-penteneBtrans 2-met(!-1-'utene 3-met(!-1-'utene 2-met(!-2-'utene cc!opentane 2B3-di'romo-2-met(!'utane a!era!de(de 2-pentanone t(iacc!o(e,ane cc!opentanet(io! 1-'romopentane 1-c(!oropentane 1-c(!oro-3-met(!'utane 2-c(!oro-2-met(!'utane pentane 2-met(!'utane4isopentane8 2B2-dimet(propane met(!-tert-'ut!-et(er pent!-a!co(o! tert-pent!-a!co(o! 'ut!-met(!-su!*ide et(!-prop!-su!*ide 2-met(!-2-'utanet(io! 1-pentanet(io! (e,ac(!oro'enene (e,a*!uoro'enene o-dic(!oro'enene m-dic(!oro'enene p-dic(!oro'enene
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C11H22 C11H22 C11H2$ C11H2$O C11H2$S C11H2$S C11H2$S C11H2$S C11H2$S C12H10 C12H12 C12H12 C12H12 C12H12 C12H12 C12H12 C12H12 C12H12 C12H12 C12H12 C12H12 C12H1# C12H1# C12H1# C12H1# C12H1# C12H22 C12H2$ C12H2$ C12H2$ C12H26 C12H26O C12H26S C12H26S C12H26S C12H26S C12H26S C12H26S C12H26S2 C13H1$ C13H1$ C13H1$ C13H1$ C13H1$ C13H20 C13H2$ C13H26 C13H26 C13H26 C13H2# C13H2#O
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'ut!-non!-su!*ide dec!-prop!-su!*ide dodec!-met(!-su!*ide et(!-undec!-su!*ide 1-tridecanet(io! 1-'ut!nap(t(a!ene 2-'ut!nap(t(a!ene 1-p(en!octane 1B2B3B$-tetraet(!'enene 1B2B3B&-tetraet(!'enene 1B2B$B&-tetraet(!'enene 1-tetradecne 1-tetradecene 1-cc!opent!nonane 1-cc!o(e,!octane tetradecane 1-tetradecano! 'ut!-dec!-su!*ide dodec!-et(!-su!*ide (ept!-su!*ide met(!-tridec!-su!*ide prop!-undec!-su!*ide 1-tetradecanet(io! (ept!-disu!*ide 1-pent!nap(t(a!ene 2-pent!nap(t(a!ene 1-p(en!nonane 1-pentadecne 1-pentadecene 1-cc!opent!decane 1-cc!o(e,!nonane pentadecane 1-pentadecano! 'ut!-undec!-su!*ide dodec!-prop!-su!*ide et(!-tridec!-su!*ide met(!-tetradec!-su!*ide 1-pentadecanet(io! 1-p(en!decane pentaet(!'enene 1-(e,adecne 1-(e,adecene 1-cc!opent!undecane 1-cc!o(e,!decane (e,adecane 1-(e,adecano! 'ut!-dodec!-su!*ide et(!-tetradec!-su!*ide met(!-pentadec!-su!*ide oct!-su!*ide prop!-tridec!-su!*ide
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