High Performance Surfactants for Emulsion Polymerization Typical Technical Data
Product Name
Description
e n t o T a i g t i R e r d g n @ g o A C
r e t t a M ] e % v [ i t c A
] % m [ e u d i d i r o l o S h C
] m % u [ e i t d f a o l S u s
e u l a v H p
Features and Benefits
Ani oni c su rfac tant s Alk yl Su lfat es ®
Texapon EHS *
Na-2-Ethylhexyl sulfate (iso-C8)
liquid
42.5 - 49.0
0-2
0 - 0.5
10.0 - 11.5
Disponil ® ALS 33
NH4-lauryl sulfate (C8/14)
liquid
32.0 - 34.0
0 - 7 a)
0 - 1.5 a)
6.0 - 7.0 5)
®
Disponil SDS 15
Na-n-dodecyl sulfate (C12)
liquid
14.5 - 15.5
0 - 0.8
0 - 0.3
8.0 - 9.0
1)
Disponil SDS 30
®
Na-n-dodecyl sulfate (C12)
liquid
29.0 - 31.0
0 - 1.0
0 - 0.1
7.5 - 8.5
5)
®
Na-n-dodecyl sulfate (C12)
granules
95.0 - 99.0
0 - 2.5
0 - 1.0
8.5 - 10.5
®
Triethanolamin lauryl sulfate (C12/14)
liquid
40.0 - 43.0
0 - 3.0
®
Disponil SLS 103
Na-lauryl sulfate (C12/16)
liquid
27.5 - 28.5
0 - 1.0
®
Na-lauryl sulfate (C12/18)
paste like
28.0 - 30.0
0 - 2.0
Disponil SDS G Disponil TLS 42
Disponil SLSK 30 ®
Na-oleyl-cetyl sulfate (C16/18')
Disponil OCS 27
b)
b)
2)
7.2 - 7.5
5)
0 - 0.1
7.5 - 8.5
5)
0 - 1.0
10.5 - 11.5
0 - 1.0
solid
26.0 - 28.0
0 - 0.6
0 - 0.3
8.3 - 11.5
2)
- basic surfactants - excellent particle size control - foaming foaming agents, e.g. for carpet backing, backing, textile suitable for all types of monomers, styrene acrylics, pure acrylics, E-PVC
5)
5)
* characteristic foaming behavior
Alk yl-ar yl Su lfo nates ®
linear Dodecyl benzene sulfonate, Na-salt
liquid
18.5 - 19.5
0 - 1.0
0 - 0.1
7.0 - 8.5
5)
®
linear Dodecyl benzene sulfonate, Na-salt
liquid
24.5 - 25.5
0 - 1.0
0 - 0.1
7.0 - 8.5
5)
®
linear Dodecyl benzene sulfonate, Na-salt
paste like
54.0 - 56.0
0 - 1.0
-
9.0 - 10.0
Disponil FES 27
®
Fatty alcohol ether sulfate, Na-salt (2 EO)
liquid
26.5 - 27.5
0 - 0.5
0 - 0.1
6.4 - 7.5
5)
®
Fatty alcohol ether sulfate, Na-salt (4 EO)
liquid
30.0 - 32.0
0 - 0.8
-
7.0 - 8.5
5)
Disponil LDBS 19 Disponil LDBS 25 Disponil LDBS 55
3)
- basic surfactants - especially for seed latex - stable against hydrolysis - suitable for all types of monomers, commonly use in E-PVC and NB Latex
Alk yl Et hers ulf ates
Disponil FES 32
- alternatives to APEO-sulfates - improved stabilization properties in the latex over alkyl sulfates - lower ethoxylated products more suitable for all acrylics - medium ethoxylated products more suitable for styrene acrylics, mulsifiers for alkyd resins - higher ethoxylated products more suitable for VAc's, emulsifiers for alkyd resins.
®
Fatty alcohol ether sulfate, Na-salt (8 EO)
liquid
28.0 - 30.0
0 - 0.8
-
7.0 - 8.5
5)
®
Fatty alcohol ether sulfate, Na-salt (12 EO)
liquid
29.0 - 31.0
0 - 0.8
-
7.0 - 8.5
5)
®
iso-Tridecyl alcohol ether sulfate, Na-salt (20 EO)
liquid
28.0 - 30.0
0 - 1.0
-
7.0 - 8.5
5)
®
Disponil FES 77
Fatty alcohol ether sulfate, Na-salt (30 EO)
liquid
32.0 - 34.0
0 - 0.8
-
7.0 - 8.5
5)
®
Fatty alcohol ether sulfate, Na-salt (50 EO)
liquid
31.0 - 33.0
0 - 0.8
-
7.0 - 8.5
5)
Fatty alcohol ehter sulfate, Na-salt (30 EO)
liquid
30.0 - 34.0
max. 1.5
-
7.5 - 9.0
®
Nonyl phenol ether sulfate, Ammonium salt (4 EO)
liquid
68.0 - 71.0
-
-
6.0 - 7.5
Disponil AES 60
®
Nonyl phenol ether sulfate, Na-salt (10 EO)
liquid
34.0 - 36.0
0 - 1.0
-
7.0 - 8.5
5)
®
Nonyl phenol ether sulfate, Na-salt (25 EO)
liquid
31.0 - 33.0
0 - 0.5
-
7.0 - 9.0
1)
®
Nonyl phenol ether sulfate, Na-salt (25 EO)
liquid
28.5 - 32.5
0 - 0.3
-
7.0 - 9.0
®
Octyl phenol ether sulfate, Na-salt (25 EO)
liquid
~ 34
0 - 2.0
-
7.0 - 9.0
Sulfosuccinic acid monoester, Di-Na-salt
liquid
28.0 - 32.0
0 - 1.0
-
5.0 - 6.0
5)
®
Di-isooctyl-sulfosuccinate, Na-salt (iso-C8)
liquid
73.0 - 76.0
0 - 1.0
-
5.5 - 7.5
5)
®
Di-isooctyl-sulfosuccinate, Na-salt (iso-C8)
liquid
~ 60
-
®
Di-isodecyl-sulfosuccinate, Na Na-salt (i(iso-C10)
liquid
63.0 - 66 66.0
0 - 1. 1.0
-
6.0 - 8.0
5)
®
Modified Di-isooctyl sulfosuccinate (iso-C8)
liquid
83.0 - 86.0
0 - 1.0
-
5.5 - 7.5
2)
®
Modified Di-isooctyl sulfosuccinate (iso-C8)
liquid
84.0 - 87.0
0 - 1.0
-
5.5 - 7.5
5)
®
Di-isodecyl-sulfosuccinate, Na Na-salt (i(iso-C10)
liquid
48.0 - 51 51.0
0 - 1. 1.0
-
5.0 - 7.0
5)
partly crystallized
34.0 - 36.5
-
-
7.5 - 9.5
4)
>98
-
-
<2.5
liquid
~ 100
-
-
-
liquid
29.0 - 31.0
-
-
1.0 - 3.0
5)
- Corrosion protection - VAc-homo polymers
partly crystallized
49.0 - 51.0
-
-
8.5 - 9.0
5)
- suitable for micro-suspension PVC
6.0 - 7.0
5)
Disponil FES 430 Disponil FES 993 Disponil BES 20
Disponil FES 61 ®
Emuphor FES 30
Alk ylp heno l Et hers ulf ates Disponil AES 48
Disponil AES 25 Emulphor NPS 25 Emulphor OPS 25
- based on Alkylphenol Alkylphenol ethoxylates (APEO'S). Alternatives see Disponil FES types types
Sulfosuccinates / Sulfossuccinamates Sulfossuccinamates Disponil ® SUS 87Special Disponil SUS IC 875 Lutensit A-BO Disponil SUS IC 10 Hydropalat 885 * Hydropalat 886 * Hydropalat 88 * ®
Disponil ODSLS
Di-Na-Sulfosuccinamate (C18')
- suitable for manufacturing of small particle latices (hydrosols)
5.5 - 7.0 - highly efficient wetting agents - strong reduction of dynamic surface tension - recommended as post add f or PSA-applications - applicable for viscosity adjustment of PVC-paste
- characteristic foaming behavior
* product is free of volatile organic solvents
Phosphoric Acid Esters ®
Alkyl polyglycol polyglycol ether phospate, acid form (3 EO)
®
Alkyl phenol ether ether phosphate, acid ester (10 EO)
Disponil FEP 6300 Disponil AEP 5300 ®
Hydropalat 7003
Fatty alcohol ether phosphate, acid ester (12 EO)
paste, liquid
- based on Alkylphenol Alkylphenol ethoxylates (APEO's)
Soaps ®
Disponil OXS 970 ®
Disponil OSS 50 KS
Di-hydroxy stearic acid, NH4-salt Di-K-oleic acid sulfonate (C18')
a) Ammonium sulfate/chloride
b) Triethanol amine amine sulfate/chloride c) Potassium Potassium sulfate
1) as in
4) 5% in demi. water
2) 1 % in d em emi. wa te ter
5) 1 0% 0% in de demi. wate r
3) 3% in demi. water
liquid
49.0 - 53.0
0 - 3.0
c)
-
Rev ised date: March 12, 2012
High Performance Surfactants for Emulsion Polymerization Typical Technical Data
Product Name
Description
r e t t a M ] e % v [ i t c A
e n t o a i g t i T e r d R g n g o @ A C
t n i o ] P C r o u [ o P
e u l a v H p
B L H
Features and Benefits
Nonionic surfactants Fatty Alcohol Ethoxylates ®
Fatty alcohol ethoxylate (C12/14) (50 EO)
solid flakes
®
Fatty alcohol ethoxylate (C16/18) (11 EO)
®
Disponil LS 500 Lutensol AT 11 Lutensol AT 18 ®
Lutensol AT 25 ®
Disponil TA 400
6.0 - 7.0
43 - 47
18.4
solid
100.0
5.0 - 8.0
-
13
Fatty alcohol ethoxylate (C16/18) (18 EO)
solid
100.0
5.0 - 8.1
-
15
Fatty alcohol ethoxylate (C16/18) (25 EO)
powder/ flakes
100.0
5.0 - 8.0
-
16
42 - 47
17.4
Fatty alcohol ethoxylate (C16/18) (40 EO)
®
Fatty alcohol ethoxylate (C16/18) (50 EO)
®
Oleyl-cetyl ethoxylate (C16/18') (5 EO)
®
Oleyl-cetyl ethoxylate (C16/18') (25 EO)
Lutensol AT 50 Disponil OC 5 Disponil OC 25
1)
99.5 - 100.0
solid
1)
99.0 - 100.0
6.0 - 7.5
100.0
5.0 - 8.0
98.0 - 100.0
6.5 - 7.5
1)
10 - 20
9.5
solid
99.5 - 100.0
6.0 - 7.5
1)
~ 40
16.5
liquid
79.0 - 81.0
6.0 - 7.5
1)
< 10
14
powder/ flakes partly crystallized
- basic non-ionic surfactants - alternatives to Alkylphenol ethoxylates (APEO's) - emulsifiers for alkyd resins
19
Modified Fatty Alcohol Ethoxylates ®
Disponil A 1080
mod. Fatty alcohol ethoxylates (10 EO)
®
mod. Fatty alcohol ethoxylates (15 EO)
liquid
79.0 - 81.0
6.0 - 7.5
1)
< 15
15
®
mod. Fatty alcohol ethoxylates (30 EO)
liquid
64.0 - 66.0
6.0 - 7.5
1)
< 10
16.5
Disponil A 1580 Disponil A 3065 ®
mod. Fatty alcohol ethoxylates (40 EO)
liquid
64.0 - 66.0
6.0 - 7.5
1)
< 15
16.5
®
mod. Fatty alcohol ethoxylates (9.5 EO)
liquid
79.0 - 81.0
6.0 - 7.5
1)
< 10
13.7
®
mod. Fatty alcohol ethoxylates (10 EO)
liquid
79.0 - 81.0
6.0 - 7.5
2)
< 10
14.5
®
mod. Fatty alcohol ethoxylates (20 EO)
liquid
74.0 - 76.0
6.0 - 7.5
2)
< 15
17
®
mod. Fatty alcohol ethoxylates (30 EO)
liquid
69.0 - 71.0
6.0 - 7.5
2)
< 15
17.5
2)
<5
18
Disponil A 4065 Disponil AFX 9580 Disponil AFX 1080 Disponil AFX 2075 Disponil AFX 3070 ®
Disponil AFX 4030
mod. Fatty alcohol ethoxylates (40 EO)
liquid
29.0 - 31.0
6.0 - 7.5
- alternatives to alkylphenol ethoxylates (APEO's) - co-emulsifiers for improvement of stabilization properties - emulsifiers for alkyd resins
- alternatives to alkylphenol ethoxylates (APEO's) - co-emulsifiers for improvement of stabilization properties - emulsifiers for alkyd resins
Alk ylp heno l Eth oxy lates Letensol AP 9
Alkyl Phenol Polyglycolether (9 EO)
liquid
>99
5.0 - 8.0
-
13
Letensol AP 10
Alkyl Phenol Polyglycolether (10 EO)
liquid
>99
5.0 - 8.0
-
13.5
Lutensol AP 14
Alkyl Phenol Polyglycolether (14 EO)
liquid
>99
5.0 - 8.0
-
14.5
Lutensol AP 20
Alkyl Phenol Polyglycolether (20 EO)
paste
>99
5.0 - 8.0
-
16
<5
17.9
<5
16
-
-
<0
17.2
®
Disponil OP 4070
Octyl phenol ethoxylate (40 EO)
liquid
69.0 - 71.0
6.0 - 7.5
2)
®
Nonyl phenol ethoxylate (20 EO)
liquid
79.0 - 81.0
6.0 - 7.0
2)
Octyl phenol ethoxylates (25 EO)
paste
>99
5.0 - 8.0
Disponil NP 2080 ®
Emulan OP25 ®
Disponil NP 3070
Nonyl phenol ethoxylate (30 EO)
liquid
69.0 - 71.0
6.0 - 7.0
2)
- based on alkylphenol ethoxylates - (APEO's) (Alternatives see, modified and non-modified fatty alcohol ethoxylates)
Alk yl Po lyg lyc olet her ®
C13 - Oxo alcohol Ethoxylate (8 EO)
liquid
>99.0
5.0 - 8.0
-
13
®
C13 - Oxo alcohol Ethoxylate (10 EO)
pastes
>99.0
5.0 - 8.0
-
13.5
®
C13 - Oxo alcohol Ethoxylate (12 EO)
solid
>99.0
5.0 - 8.0
-
14.5
®
Lutensol TO 15
C13 - Oxo alcohol Ethoxylate (15 EO)
solid
>99.0
5.0 - 8.0
-
15.5
®
C13 - Oxo alcohol Ethoxylate (20 EO)
liquid
80
5.0 - 8.0
-
16
®
C13 - Oxo alcohol Ethoxylate (30 EO)
liquid
70
5.0 - 8.0
-
17
®
C13 - Oxo alcohol Ethoxylate (40 EO)
liquid
70
5.0 - 8.0
-
18
Alkyl polyglycosid (C8/C10)
liquid
62.0 - 65.0
11.5 - 12.5
-
-
-
-
-
-
Lutensol TO 8 Lutensol TO 10 Lutensol TO 12
Emulan TO 2080 Emulan TO 3070 Emulan TO 4070
- basic non-ionic surfactans - alternative to Alkylphenol ethoxylate (APEO) - co-emulsifiers to impeove stabilization properties
Alk yl Po lyg lyc osi des ®
Disponil APG 215 ®
Disponil APG 425 ®
Disponil APG 600
Alkyl polyglycosid (C8/14) Alkyl polyglycosid (C12/14)
liquid
48.0 - 52.0
7.0 - 9.5
3)
4)
liquid
50.0 - 53.0
11.5 - 12.5
3)
-100% renewable base surfactant
EO/PO Block Copolymers Pluronic PE 3100
®
PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 1000g/mol)
liquid
>99.0
4.0 - 8.0
-
-
Pluronic PE 3500
®
PO/EO-Blockpolymer (ca.50 EO, molar mass ca. 1900g/mol)
liquid
>99.0
4.0 - 8.0
-
-
®
Pluronic PE 4300
PO/EO-Blockpolymer (ca.30 EO, molar mass ca. 1750g/mol)
liquid
>99.0
4.0 - 8.0
-
-
Pluronic PE 6100
®
PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 2000g/mol)
liquid
>99.0
4.0 - 8.0
-
-
®
Pluronic PE 6120
PO/EO-Blockpolymer (ca.12 EO, molar mass ca. 2100g/mol)
liquid
>99.0
4.0 - 8.0
-
-
®
Pluronic PE 6200
PO/EO-Blockpolymer (ca.20 EO, molar mass ca. 2450g/mol)
liquid
>99.0
4.0 - 8.0
-
-
®
Pluronic PE 6400
PO/EO-Blockpolymer (ca.40 EO, molar mass ca. 2900g/mol)
liquid
>99.0
6.0 - 8.0
-
-
®
Pluronic PE 6800
PO/EO-Blockpolymer (ca.80 EO, molar mass ca. 8000g/mol)
powder
>99.0
5.0 - 8.0
-
-
®
Pluronic PE 8100
PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 2600g/mol)
liquid
>99.0
4.0 - 8.0
-
-
Pluronic PE 9200
®
PO/EO-Blockpolymer (ca.20 EO, molar mass ca. 3650g/mol)
liquid
>99.0
4.0 - 8.0
-
-
Pluronic ® PE 9400
PO/EO-Blockpolymer (ca.40 EO, molar mass ca. 4600g/mol)
solid
>99.0
5.0 - 8.0
-
-
®
PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 3500g/mol)
liquid
>99.0
4.0 - 8.0
-
-
®
PO/EO-Blockpolymer (ca.30 EO, molar mass ca. 4950g/mol)
paste
>99.0
5.0 - 8.0
-
-
Pluronic PE 10100 Pluronic PE 10300
plur onic ® PE 6100, PE6200, PE 6400, PE 6800 - Low foam genration emulsifiers (depending on ratio EO/PO and interactions with anionic surfactants present in the latex formulation) - provide latexs with high stability high shear stability high elctrolytic stability high freeze-thaw stability low water sensitivity (depending on ratio EO/PO and interactions with anionic surfactants present in the latex formulation) → → →
®
PO/EO-Blockpolymer (ca.40 EO, molar mass ca. 5900g/mol)
solid
>99.0
5.0 - 8.0
-
-
®
Pluronic PE 10500
PO/EO-Blockpolymer (ca.50 EO, molar mass ca. 6500g/mol)
solid
>99.0
5.0 - 8.0
-
-
1) 1% in 0,03% KCl-solution
2) 10% in 0,03% KCl-solution 3) 10% in 15% IPA-dilution 4) 20% in 15% IPA-dilution
Pluronic PE 10400
Revised date: March 12, 2012