Advanced Cleaning Product Formulations Volume 5

ADVANCED CLEANING PRODUCT FORMULATIONS

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ADVANCED CLEANING PRODUCT

FORMULATIONS Volume 4

Ernest W. Flick

NOYES PUBLICATIONS Westwood, New JOrsey, U.S.A.

Copyright 0 19% by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means. electronic or mechanical, including photocopying. recording or by any information storage and retrieval system. without permission in writing from the Publisher. Library of Congress Catalog C u d Number: 89-30274 ISBN 0-8155-1396-8 Printed in the United States Published in the United States of America by Noyes Publications 369 Fairview Avenue Weshvood, New Jersey 07675 10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publication Data (Revised for vo1.4) Flick, Ernest W. Advanced cleaning produd formulations Includes bibliographid references and index. 1. Cleaning compounds. I. Title TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4)

To Ernie and Jeanne and AIIp and Barbara

and Chris and Rachel

V


Preface This book (Volume 4) presents more than 435 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2 and 3 published earlier. Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria. The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):

I. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (26) 2. Dairy, Food and General Industrial Cleaners (15) 3. Degreasers (5) 4. Dishwashing Detergents (47) 5. General Purpose Cleaners (34) 6. Glass Cleaners/Polishes (25) 7. Hard Surface Cleaners (44) 8. Laundry Products (65) 9. Metal Cleaners and Polishes (22) 10. Oven, Grill and Hot Plate Cleaners (3) 11. Polishes, Coatings and Finishes (30) 12. Rinse Aids (4) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32) 14. Miscellaneous (32) vii

Preface

viii

11. Transportation Cleaners and Polishes

15. Auto Cleaners and Polishes (14) 16. Car and Truck Wash Compounds (27) 17. Whitewall Tire Cleaners (4) 18. Miscellaneous (8) Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader. 111. Achemical trademark section where each tradenamed raw material

included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available, in the manufacturer's own words: Description of end use and most outstanding properties. 0

The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.

0

The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.

The table of contents is organized in such a way as to serve as a subject index. My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials. Newburyport, Massachusetts August 1996

Ernest W. Flick


NOTICE To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone intending to rely on any recommendation of materials or procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards. X

Contents and Subject Index SECl'ION I HOUSEHOLD AND INDUCLEANERS AND POLISHES

.

2 1 BATHROOM CLEANERS .............................. Bathtub and Faucet Cleaner ............................ 3 Bathroom Cleaner ................................... 3 Toilet Bowl Cleaner ................................. 3 Tub and Tile Cleaner ................................ 3 Clear Liquid Bowl Cleaner ............................ 4 Thick Toilet Bowl Cleaner ............................ 4 Foamable Acid Tile Cleaner ........................... 5 Liquid Toilet Bowl Cleaner ............................ 5 Solid Automatic Toilet Bowl Cleaner Formulation ........... 6 Acid Toilet Bowl Cleaner ............................. 6 Tub. Tile and Bathroom Cleaner ........................ 6 Tile. Porcelain and Bathroom Cleaner. Acid ................ 7 Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover ....................................... 7 Soap Scum RemoverICleaner ........................... 7 Toilet Cleaner LiquidA ...................................... 8 Liquid B ...................................... 8 Medium Viscosity-A ............................. 8 Medium Viscosity-B ............................. 8 Medium Viscosity-A ............................. 9 Medium Viscosity-B ............................. 9 Powder ....................................... 9 Powder-B ..................................... 9 Toilet Cleaning Block Extruded-A ................................... 10 Extruded-B ................................... 10 Cast-A ...................................... 10 Cast-B ...................................... 10

xi

xii

.

Contents and Subject Index

DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . Dairy Milkstone Remover Acid Dilutable Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . Dairy Pipeline Cleaner-High Alkaline Low Foam Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Institutional Stainless Steel Cleaner ..................... High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . Cleaner for Milking Equipment ........................ Cleaner for Meat Plants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . Steam Cleaners Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty (for Oily Soils) . . . . . . . . . . . . . . . . . . . . . . . General Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Light Duty for Soft Metals ........................ Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

11

DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . Solvent Degreasing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

17 18 18 19

4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . Clear Liquid Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . Clear. Colorless Manual Dish Wash ..................... Dish Washing Agent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . Dishwashing Detergent Medium Viscosity Basis Marlon A-A . . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon A-B . . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon AS3-A . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon AS3-B ......................... Basis Marlon PS-A . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon PS-B . . . . . . . . . . . . . . . . . . . . . . . . . . Basis Marlon Compounds-A ..................... Basis Marlon Compounds-B . . . . . . . . . . . . . . . . . . . . Powdered Spray Mixing Process-A ...................... Spray Mixing Process B . . . . . . . . . . . . . . . . . . . . . . . Phosphate-Free. Spray Mixing. Process A . . . . . . . . . .

20 21 21 21 22 23

2

.

3

12 12 13 13 14 14 14 15 16 16 16 16 16 16

24 24 24 24 25 25 25 25 26 26 26


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Phosphate.Free. Spray Mixing. Process B . . . . . . . . . . 26 40% Solids-A .............................. 27 40% Solids-B .............................. 27 27 Hand Dishwashing Liquid ............................ Dish Wash w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS/ALES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS ...................... 28 High-Performance Hand Dish Detergent . . . . . . . . . . . . . . . . . 29 29 Mild Liquid Hand Dish Detergent ...................... Starting Formulations for Home Machine Dishwashing Detergents 8.7% Phosphorous(A) ............................ 30 8.7% Phosphorous(l3) ............................ 30 Nonphosphate ................................. 30 Light Duty Liquid Detergents Pilot Formula #LDL-010-01 ...................... 31 Pilot Formula #LDL-013-01 ...................... 31 Pilot Formula #LDL-005-01 ...................... 31 Pilot Formula #LDL-O15-01 ...................... 31 Premium Hand Dishwash ......................... 32 32 Economy Hand Dishwash ......................... Liquid Hand Dish Detergent .......................... 33 Mechanical Dishwashing Detergent. Chlorinated . . . . . . . . . . . . 34 Mechanical Dishwashing Detergent. Liquid . . . . . . . . . . . . . . . 34 Non-DDBSA Dishwashing Liquid ...................... 35 Starting Formulations for Commercial Machine Dishwashing Detergents Nonchlorine/Noncaustic .......................... 36 Noncaustic .................................... 36 ChlorineKaustic ................................ 36

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5

GENERAL PURPOSE CLEANERS ....................... 37 All Purpose Cleaner ................................ 38 Phosphate Free All Purpose Cleaner ..................... 38 Bathroom Tile Cleaner .............................. 38 All Purpose Cleaner ................................ 39 39 Hard-surface Cleaner ............................... All-Purpose Cleaner Cleaner-A .................................... 40 Cleaner-B .................................... 40 With Microbicidal Properties. Liquid-B . . . . . . . . . . . . . . . 40 Liquid-A ..................................... 41 Liquid-B ..................................... 41 With Microbicidal Properties. Liquid-A . . . . . . . . . . . . . . . 41

xiv


Pasty-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 Pasty-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 With Soap. High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . 42 With Soap. High Viscosity-B . . . . . . . . . . . . . . . . . . . . . . 42 D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43 D-Limonene All Purpose Cleaner ...................... 43 General Cleaners 44 Household . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Liquid Hand Cleaner ............................ 44 Germicidal Cleaner . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . 44 High-Performance General Purpose Cleaner Concentrate . . . . . . 45 Heavy-Duty Cleaner Powder .......................... 45 Neutral All-Purpose Cleaner. with Pearlescence Effect 46 High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 All-Purpose Cleaner With Acetic Acid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 With Acetic Acid-B ............................. 46 Non-Phosphate All Purpose Cleaner .................... 47 Oil Splitting General Purpose Cleaner . . . . . . . . . . . . . . . . . . . 47 Scouring Cleaner 48 Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

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6

GLASS CLEANERSD’OLISHES . . . . . . . . . . . . . . . . . . . . . . . . . 49 Antifog Composition For Application to Cloth . . . . . . . . . . . . . . . . . . . . . . . . . . 50 For Direct Application to Glass . . . . . . . . . . . . . . . . . . . . . 51 Anti-Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . 52 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Glass Cleaners Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Glassware and Bottle Cleaners Bottle Cleaner 54 Alkaline-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . Acid-Powder ............................... 54 Acid-Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Highly Alkaline ............................. 54 Household Window Cleaner . . . . . . . .. . . . . . . . . . . . . . . . . . 55 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . 55


Low VOC Antistat/Cleaner for Glass .................... Anti-Fog Glass Cleaner ............................. Glass Cleaner ..................................... Traditional Consumer Glass Cleaner .................... Consumer Acid Glass Cleaner .........................

.

7

xv

56 56 56 57 57

.......................... 58 Abrasive Cleaner-1 ................................ 59 59 Abrasive Cleaner-2 ................................ 59 Abrasive Cleaner-3 ................................ Concentrated Liquid Household Hard-surface Cleaner . . . . . . . 60 All-Purpose Household Spray Cleaner . . . . . . . . . . . . . . . . . . . 60 Consumer Tile Cleaner .............................. 61 Industrial Strength Chlorine Cleaner ..................... 61 D-Limonene Hard-surface Cleaners .................... 62 d'limonene Spray Cleaner ............................ 63 63 d'limonene Cleaner Concentrate ....................... General Purpose Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . 64 Alkaline Hard Surface Cleaner ........................ 64 General Purpose Hard-surface Cleaners . . . . . . . . . . . . . . . . . . 65 Unbuilt. High-Sudsing. Hard-surface Cleaner . . . . . . . . . . . . . 65 Hard Surface Cleaner ............................... 66 Non-Abrasive Cleanser .............................. 66 Hard Surface Cleaner ............................... 66 Floor Cleaner Products .............................. 68 Rug Cleaner ...................................... 68 Plastic. Vinyl and Leather Cleaner ...................... 68 Hard Surface Cleaners .............................. 69 69 Tub and Tile Cleaners ...............................

HARD SURFACE CLEANERS

Counter Top/Wall Cleaners AlIPurposeType ............................... 69 69 Ammoniated Type .............................. Hard Surface Cleaner w/Amphoteric .................... 70 Hard Surface Cleaner Concentrate w/d'Limonene ................................. 70 Alkaline All-Purpose Cleaner Concentrate . . . . . . . . . . . . . 71 All-Purpose Alkaline Cleaner for Sponge or Spray 71 Application ................................. High-Performance. Hard Surface Cleaners . . . . . . . . . . . . . . . . 72 Economical Pine Oil Hard-surface Cleaner . . . . . . . . . . . . . . . 72 73 Mild Abrasive Hard Surface Cleaner .................... Non-Phosphate Household Hard-surface Cleaner . . . . . . . . . . . 74 Non-Phosphate Concentrated Household Hard-surface Cleaner ....................................... 74

xvi

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8

Contents and Subject Index Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Super Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . .

75 75

LAUNDRY PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . Cold Water Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Colored Fabrics. Powder. Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . P~OUXS-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Curtains Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . Manual-Wash Detergent. Foaming Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . Enzymatic Heavy-Duty Laundry Detergent . . . . . . . . . . . . . . . Non-Phosphate Laundry Powder . . . . . . . . . . . . . . . . . . . . . . . Fabric Pretreatment Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low VOC Pump Fabric Antistatic Spray . . . . . . . . . . . . . . . . . Laundry Pre-Spotter and Stain Remover . . . . . . . . . . . . . . . . . Fabric Softener Process-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrate. Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . Concentrate. Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . Heavy-Duty Detergent. Powder Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Heavy-Duty Detergent. Built Type. High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . Built Formulation #1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . Liquid Laundry Detergents . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . .

76 77 78 79 79 80 80 81 81 81 81 82 82 83 83 84 84 84

85 85 85 86 86 86 86

87 87 88 88 88 89 89 90 90 91


xvii

Built Formulation #2 ................................ 91 Liquid Heavy-Duty Detergent 92 Low Viscosity-A ............................... 92 Low Viscosity-B ............................... 92 Built Type. High Viscosity-B ...................... Light-Duty Detergent. Powder 93 Spray Mixing Process-A .......................... Spray M i n g Process-B .......................... 93 Liquid Light-Duty Detergent With Incorporated Softener. Low Viscosity-A .......... 93 94 Low VisCosity-A ............................... 94 Low Viscosity-B ............................... With Incorporated Softener. Low Viscosity-B .......... 94 Industrial Laundry Two-Part Systems. Uniforms (Petroleum Greases and Oils) ........................ 95 HoteVLinen Supply (Animal and Vegetable Grease) ......... 95 Industrial Laundry Powder. Uniforms .................... 95 Laundry Liquids ................................... 96 "Fine Care" Fabric Detergents % Pilot Formula #LDY-OO3-01 ...................... Pilot Formula #LDL-003-01 ...................... 96 Heavy Duty Laundry Liquids Pilot Formula #HDL-004-01 ...................... % Pilot Formula #HDL-005-01 ...................... % Laundry Powder Detergent ........................... 97 97 Industrial Laundry One-Shot Liquid .................... 98 Liquid Heavy Duty Detergent HDLD .................... 98 Liquid Detergent "FSL" A ............................ 99 Thick Bleach-1 ................................... 99 Thick Bleach-2 ................................... Wool Detergent 100 Medium Viscosity-A ........................... Medium Viscosity-B ........................... 100

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9

METAL CLEANERS AND POLISHES ................... Aluminum CleanerDrightener ........................ Aluminum Smut Cleaner ............................ Aluminum Cleaner Concentrate ....................... Aluminum Wash ................................. Cleaners and Cleaning Solutions ...................... Metal Cleaning Alkaline .................................... Acid ....................................... Paint Removal ................................

101 102 102 103 103 104 104 104 104

xviii


Rust Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Copper Cleaning .................................. Aluminum Cleaning Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Brightening . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Aircraft-Brightener (U.S. Patent 2.687. 346) . . . . . . Electrocleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . High-Foaming Acid Scrubber ........................ Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Metal Cleaner and Degreaser ......................... Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . Stainless Steel Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cleaner-B ................................... Silver Polish Liquid-A . . . . . . . . . . . . . . . . . . . ................. Liquid-B ....................................

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10 OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . Pump Spray Oven Cleaner .......................... Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven/Grill Cleaner ................................

.

11 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . . Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . Furniture Paste Wax ............................... Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . Detergent Resistant Cream Polish ..................... Liquid Polish For Clear Coat Finishes ......................... No Solvent .................. . . . . . . . . . . . . . . . . Outer Phase Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Wax Liquid Polish (Oil-in-Water Type) . . . . . . . . . . . . Liquid Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20% Wax Emulsion-1 ............................. 20% Was Emulsion-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Water-Based Glaze .......................... Solvent Wax Glaze . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Paste Polish (Oil-in-Water Type) .....................

104 105 105 105 105 106 106 107 107 108 108 109 109 109 109 110 111 111 111 112 113 113 114 114 115 115 116 116 117 117 118 118 119 119 119 120 120 121


Spray-and-Wipe Polish ............................ Paste Polish Oil-in-Water Type Type-1 .................................. Type-2 .................................. Type-3 .................................. Outer Phase Oil ............................... Spray-and-Wipe Polish (Pump) ...................... 20% Wax Emulsion-1 ............................. 20% Wax Emulsion-2 ............................. Spray and Wipe Type Aerosol or Non-Aerosol (1) ...................... Aerosol or Non-Aerosol (2) ...................... Aerosol or Non-Aerosol (3) ...................... Liquid Wax-Solvent Furniture or Floor Polish ............

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12 RINSE AIDS ....................................... Automatic Dishwash Rinse Aid For Hard Water ............................... For Neutral or Soft Water ........................ Rinse Aid ......................................

xir

121 122 122 123 123 124 124 124 125 125 125 125 126 127 127 128

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13 RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS ANDCLEANERS ................................... Basic Floor Cleaner Liquid-A .................................... Liquid-B .................................... Floor Cleaner. for Everyday Use Liquid-A .................................... Liquid-B .................................... Carpet and Upholstery Cleaners Dry-Foam Cleaner Liquid-A ................................ Liquid-B ................................. Powder-A ................................ Powder-B ................................. Carpet Shampoo. High Foam ......................... Evaporative (No Rinse) Wax Stripper ................... Waxed Floor Cleaner .............................. Floor Cleaner .................................... Floor Polish Mor-Glo 2-457 20% Solids ...................... ML-870-389 20% Solids ........................ Liquid Carpet Cleaner ..............................

129 130 130 130 130 131 131 131 131 132 133 133 134 135 136 137


XT

Carpet Stain Remover-Liquid . . . . . . . . . . . . . . . . . . . . . . . . Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . Non-Ammoniated Floor Stripper . . . . . . . . . . . . . . . . . . . . . . Quarry Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Foam Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Special-Purpose Floor Cleaner Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wash-and-Wax Floor Cleaner Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

.

14 MISCELLANEOUS

..................................

Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dilutable Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Viscous Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Opacified Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hand and Body Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . Low Foam Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . Metal CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . . . Hot Tank Stripper/Cleaner/Derster .................... Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . Paint Brush Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . High Solids Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . Wallpaper Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

137 137 138 138 138 139 140 140 141 141 141 141 142 143 143 143 143 143 143 143 144 144 145 146 147 148 148 148 149 149 149 150 150 150 151 152 152 152 153


m-

SECTION II TRANSPORTATION CLEANERS AND POLISHES

.

15 AUTO CLEANERS AND POLISHES .................... Auto Polishlcleanser. Oil in Water Emulsion ............. Detergent Resistant Auto PolishlCleanser. Paste Wax ....... Camauba Hotwax ................................. Pressure Spray Truckwash ........................... Detergent Resistant Auto Polish. Oil in Water Emulsion ..... High Luster Auto Finish. Paste Wax ................... High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . High Gloss Auto PolishPinish ........................ Spraywax Concentrate .............................. Spraywax ....................................... Spraywax Ladder of Formulas ........................

.

155 156 156 157 157

158 158 159 159 160 160 161

16 CAR AND TRUCK WASH COMPOUNDS ................ 162 Automatic Car Wash Concentrate ..................... 163 General Purpose Car Wash .......................... 163 Auto Shampoo Concentrate .......................... 164 High Foaming Car Wash ............................ 164 Car Wash ....................................... 164 Car Wash Liquid ................................. 165 Car Wash Powder ................................. 165 Economy Truck Wash .............................. 166 Truck Wash Liquid ................................ 166 Foamy Brush Car Wash. Liquid ....................... 167 1:2 Dilutable Car Wash ............................. 167 High Oil Splitting Vehicle Wash-A .................................... 168 Wash-B .................................... 168 Liquid Car Wash ................................. 169 Spray-On Car Wash Concentrate ...................... 169 Liquid Hi@ Pressure Coocentrate ..................... 170 Tmck Wash w/varamide A-83 ....................... 170 Liquid Tmck Wash ................................ 171 Mild Car Shampoo ................................ 172 Cgrspray CW Concentrate ........................... 172 Automotive "Wash t Wax" ......................... 172 Premium Carspray 500 Concentrate .................... 173 Standard Carspray 500 Concentrate .................... 173 Premium Carspray 700 Concentrate .................... 174 Standard Carspray 700 Concentrate .................... 174

xxii


.

17 WHITEWALL TIRE CLEANERS ....................... White Wall Tire Cleaner ............................ Bug Remover Concentrate ........................... Whitewall Tire Cleaner Concentrate .................... Whitewall Tire Cleaner Liquid .......................

.

18 MISCELLANEOUS .................................. Automobile Windshield Cleaners ...................... General Purpose Liquid Boat Polish-(l) . . . . . . . . . . . . . . . . . General Purpose Liquid Boat Polish-(2) . . . . . . . . . . . . . . . . . Liquid Aluminum Engine Block Cleaner ................ Foaming Engine Cleaner ............................ SECTION Ilk TRADE-D

175 176 176 177 177 178 179 180 180 181 181

RAW MATERIAIS ........... 182

SECTION N:SUPPLIERS' ADDRESSES

....................

197

Section I Household and Industrial Cleaners and Polishes

1

1 Bathroom Cleaners

2

Bathroom Cleaners

B a t h t u b and Faucet C l e a n e r Ingredient: P e r c e n t by We1 q h t L i q u i d C i t r i c Acid-50% (Haarman & Reimer C o r p . ) 20.0 Ammoni um h y d r o x i d e s o l u t i o n 28% 3.2 5.0 Cellosolve solvent N o n i o n i c s u r f a c t a n t (Neodol 25-9) 6.0 65.8 Water F r a g r a n c e , dye

q.s.

M i x t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f w a t e r . S l o w l y add t h e ammonium h y d r o x i d e s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n i s e x o t h e r m i c . Add C e l l o s o l v e , s u r f a c t a n t , r e m a i n i n g w a t e r , f r a g r a n c e and dye. The f o r m u l a i s s u i t a b l e f o r a pump s p r a y . B a t h t u b , s i n k s , f a u c e t s and o t h e r h a r d s u r f a c e s s h o u l d be sprayed f r o m a d i s t a n c e o f about 10 i n c h e s . For maximum e f f e c t i v e n e s s , t h e d e p o s i t e d c l e a n e r f l u i d s h o u l d be e f t a t work f o r a t l e a s t f i v e m i n u t e s and t h e n r i n s e d o f f w t h w a t e r o r removed w i t h a wet c l o t h o r sponge.

SOURCE: Haarman 81 Reimer C o r p . :

Suggested Formu a t i o n

__ Bathroom_C_l e_a -n e ~r Water Sodium C i t r a t e Glucopon 425 CS P r o p y l e n e G l y c o l nButy1 E t h e r

\"rtb 79

9 9 3

T o i l e t B o w l Cleaner Wt%

79

Water Phosphoric A c i d Glucopon 425 CS

15

6 Tub 8 7 1 l e Cleaner Wt%

75

Water Sodium C i t r a t e STPP Standapol ES-2 V e l v e t e x A0-45 Standamid KD I s o p r o p y l Alcohol

SOURCE: Henkel Corp.,

4 1 12

4 1 3

CD D i v i s i o n : S t a r t i n g F o r m u l a t i o n s

3

4

Advonced Cleoning Roduct Formulotions

C l e a r L i q u i d Bowl C l e a n e r Formula BC-0001 W% .t 3.0 20.0 77.0

M i r a n o l FBS H y d r o c h l o r i c A c i d (20Be) Water

Procedure Add t h e w a t e r . S l o w l y add t h e h y d r o c h l o r i c a c i d , w i t h m i x i n g . Add t h e M i r a n o l FBS. M i x u n t i l u n i f o r m .

Phvsi -1

P r o o e r t i es

Appearance: C l e a r , l i g h t y e l l o w V i s c o s i t y : <10 cps S p e c i f i c Gravity: 1-03 pH ( a s i s ) : <1.0

Thick T o i l e t Bowl C l e a n e r Formula BC-0002

Wt.% M i r a t a i ne TM

5.0 32.0

H y d r o c h l o r i c A c i d (20Be) Water

Q.S

P r o w d ur g Add t h e h y d r o c h l o r i c a c i d t o t h e w a t e r , w i t h s t i r r i n g . add t h e M i r a t a i n e TM and mix u n t i l u n i f o r m .

Phvsi G a l P r o o e r t ies Appearance: C1e a r , ye1 1ow 1 iq u i d V i s c o s i t y : 1.035 c p s Speci f ic G r a v i t y : 1 ,037 pH ( a s i s ) : <1.0

SOURCE:

Rhone-Poulenc

Surfactants & Specialties:

Formulas

Slow Y

Bathroom Cleaners

5

Foarnable A c i d T i l e C l e a n e r Hard Foaming Hard S u r f a c e C l e a n e r f o r Soap Scum Removal

Wt.%

Inaredi ent: Dei o n i zed Water C i t r i c A c i d (50%) Mazon 98

87.00 10.00

3.00

pH ( a s i s ) : 2 . 0 - 2 . 5 Appearance: C l e a r , w a t e r - w h i t e Specific Gravity: 1.01

liquid

Procedure: To a m i x i n g v e s s e l , c h a r g e t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d above. M i x u n t i l c l e a r . Notes : T h i s f o r m u l a produces a c o p i o u s , dense foam. I t i s s u i t a b l e f o r c l e a n i n g soap scum f r o m shower s t a l l t i l e s and o t h e r b a t h room and h o u s e h o l d f i x t u r e s . Formula CH-105 L i a u i d T o i l e t Bowl C l e a n e r A L i q u i d S t a i n and Rust Remover Insredient: D e i o n i z e d Water P h o s p h o r i c A c i d (75%) Avanel S-70

Wt.% 66.00 30.00 4.00

pH ( a s i s ) : t1.5 Appearance: C l e a r , w a t e r - w h i t e l i q u i d S p e c i f i c Gravity: 1.124 Procedure: Charge t h e w a t e r t o t h e m i x i n g v e s s e l , and s l o w l y c h a r g e t h e p h o s p h o r i c a c i d under a g i t a t i o n . Use c a u t i o n d u r i n g a c i d addi t i o n t o a v o i d s p a t t e r i n g . When a l l o f t h e a c i d i s d i s s o l v e d , c o o l t o room t e m p e r a t u r e and add t h e Avanel s u r f a c t a n t . Notes: T h i s f o r m u l a t i o n i s d e s i g n e d t o be used "as i s " and i s p a r t i c u l a r l y e f f e c t i v e i n t h e removal o f s c a l e b u i l d - u p and r u s t stains. T h i s m a t e r i a l may be marketed i n an a p p r o p r i a t e squeeze b o t t l e t o f a c i l i t a t e "under t h e r i m " bowl c l e a n i n g by t h e consumer. Formula CT-101

SOURCE: Mazer Chemicals: Suggested F o r m u l a t i o n s

6

Advanced Cleaning Roabct Formulations

S o l i d A u t o m a t i c T o i l e t Bowl C l e a n e r F o r m u l a t i o n Ingredient: Macol DNP 1 5 0 I n c r o m i d e L90 Carbowax PEG 8000 Macol 27 V e r s a f l e x 207 ( d r y ) Water

-%

25.0 25.0 20.0 20.0 5.0 5.0

Procedure: 1 . M e l t t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and mix t o g e t h e r . 2. M a i n t a i n a t e m p e r a t u r e o f about 70C, and add t h e I n c r o m i d e L90 w h i l e m i x i n g . 3. Add w a t e r and V e r s a f l e x 207 ( d r y ) and m i x . 4 . Pour f o r m u l a t i o n i n t o a mold, and a l l o w t o c o o l . SOURCE: N a t i o n a l S t a r c h and Chemical Co.: R e f e r e n c e #8069:49

__ A c i d T o i l e t Bowl C l e a n e r Water, D . I . H y d r o c h l o r i c A c i d (37%) R e w o t e r i c AM TEG

% bv Weiaht 71 . O

27.0 2.0

B1e n d i ng Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i on. Typical Properties: V i s c o s i t y , cps: 135 S o l i d s : 1.0% pH: 2.8 SOURCE: W i t c o C o r p . : Formula 532 Tub,

T i l e and Bathroom C l e a n e r % bv Wei a h t

Water Sodium Carbonate T e t r a s o d i u m EDTA (40%) P h o s p h o t e r i c T-C6 Nonoxynol 1 0

81.5 5.0 10.0 1.5 2.0

Procedure: Add i n g r e d i e n t s i n o r d e r l i s t e d , a l l o w i n g s u f f i c i e n t t i m e between a d d i t i o n s . T h i s p r o d u c t may be a p p l i e d w i t h a t r i g g e r pump o r by a e r o s o l . Formulation P r operties: P h y s i c a l Appearance: C l e a r l i q u i d Cloud P o i n t : 42C SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n

Bathroom Cleaners

Tile,

7

P o r c e l a i n and Bathroom Cleaner, A c i d

% by Weiqht Water. D . 1 75.5 Rhodopol 23 0.5 Petro BAF Powder 2.0 Phosphori c Acid, 75% 12.0 Hydroxyacetic Acid, 70% 10.0 Perfume, Dye q.s. B1endi ng Procedure : Add Rhodopol 23 s l o w l y t o water w i t h h i g h speed mixing. Allow t o mix u n t i l m a t e r i a l t h i c k e n s . Add remaining i n g r e d i e n t s i n order l i s t e d . If problems develop adding Rhodopol t o water, premix t h e Rhodopol 23 i n some isopropanol b e f o r e adding t o water. Formula 529

H y p o c h l o r i t e Tub and T i l e Cleaner and Mildew S t a i n Remover % by Weiqht Water, D.I. 44.9 Sodium Hydroxide (30%) 1 .o Varox 365 1.5 Sodium H y p o c h l o r i t e (5.7%) 52.6 81 endi ng Procedure : Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each addi t i on. Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 3.8% pH: 13.5 Formula 531

Soap Scum Remover/Cleaner % by Weiaht Water, D.I. q.s. *Builder Solution 0.20 Tetrasodi um EDTA 0.25 Rewoteric AM V 1 .oo Dowanol EB 0.50 81 ending Procedure: Blend i n g r e d i e n t s i n t h e order shown, m i x i n g thoroughly between each a d d i t i o n . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 4 S o l i d s : 2.0% pH: 11-12 Comments: 4% * B u i l d e r S o l u t i o n : Sodium Carbonate (Na2C03): Potassi um Hydroxide (KOH) : 3% DI Water 93% Formula 544

SOURCE: Witco Corp.: Suggested Formulations

8

Advanced Cleaning Roabct Formulations

T o i l e t Cleaner. M a r l ip a l 013/99 Acetic acid* Balance w a t e r , f r a g r a n c e ,

Liquid-A

96 3.0 6.0 t o 100

dyestuff

A c t i v e m a t t e r : 2.7% Toi 1e t C l e a n e r

M a r l ip a l 013/99 C i t r i c acid Balance w a t e r , f r a g r a n c e ,

.

L i qui d-B

%

dyestuff

5.0 1.7 t o 100

A c t i v e m a t t e r : 4.5% T o i 1e t C1 eaner , Medi urn V i s c o s i t y - A M a r l a z i n OL 2 M a r l i p a l 013/99 C i t r i c acid Na Cumene s u l p h o n a t e 40 ( a p p r o x . ) Balance w a t e r , f r a g r a n c e , d y e s t u f f

%

1.5 0.5 5.0 1.5 t o 100

A c t i v e m a t t e r : 2.0% T o i l e t Cleaner,

Medi urn V i s c o s i t v - B

M a r l a z i n OL2 M a r l ip a l 013/99 C i t r i c acid P h o s p h o r i c a c i d , 85% KNA cumene s u l p h o n a t e 40 ( a p p r o x . ) Balance waser, f r a g r a n c e , d y e s t u f f A c t i v e m a t t e r : 2.0 * f u r t h e r p r o d u c t s o f H u l s AG

SOURCE: H u l s America, I n c . : B a s l c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents f o r Household Purposes

%

1.5 0.5 2.5 7.5 1.3 t o 100

Bathroom Cleaners

9

Toi 1e t Cleaners, Medi urn V i scosi t y - A

96 M a r l a z i n 7102 Phosphoric a c i d , 85% Sodium c h l o r i d e Balance water, fragrance,

4.0 5.0 3.5 t o 100

dyestuff

A c t i v e m a t t e r : 4.0% Toi 1e t C l eaner

.

Medi urn V i scosi t y - B

%

3.0 0.5 6.0 3.1 t o 100

M a r l a z i n OL 2 M a r l i p a l 013/99 A c e t i c Acid* KNA cumene sulphonate 40 (approx.) Balance water, fragrance, d y e s t u f f A c t i v e m a t t e r : 3.5% Toi 1e t Cleaner.

Powder

96 Marlon ARL Amidosulphonic a c i d Magnesium carbonate Sodi um b i sulphate Sodium bicarbonate, fragrance, d y e s t u f f

5.0

20.0 5.0 60.0 t o 100

A c t i v e m a t t e r : 4.0% T o i l e t Cleaner.

Powder-B

% Marlon Citric Sodi um Sodium

A 390 acid sulphate bicarbonate,

A c t i v e matter:

fragrance,

dyestuff

5.0 25.0 55.0 t o 100

4.5%

I n c . : Basic Formulations o f Detergents and Cleaning Agents for Household Purposes

SOURCE: Huls America,

10

Advanced Cleaning Roduct Formulations

T o i l e t Cleaning Block, Extruded-A

96

40.0 4.0 6.0 4.0 t o 100

Marlon ARL M a r l i p a l 1618/25 powder Marlamid M1618 V e s t i n o l C* Sodium sulphate, d y e s t u f f A c t i v e m a t t e r : 42.0% T o i l e t Cleaning Block.

Extruded-B

Marlon ARL Marlon A390 L i p o x o l 6000* Sodi um t r i p o l y p h o s p h a t e Fragrance Sodium sulphate, d y e s t u f f

ss

40.0 30.0 8.0 1 .o 5.0 t o 100

A c t i v e m a t t e r : 59.0% T o i l e t Cleanino Block. Cast-A Marl i n a t 242/70 Marlon A375 M a r l i p a l 1618/25 powder M a r l i p a l 1618/40 Marlamid M 1618 L i poxol 12000* Fragrance Dyestuff

%

3.0 13.0

30.0 24.0 15.0 10.0 4.0 1 .o

A c t i v e matter: 80.8% T o i l e t Cleaning Block. Cast-B Marl i p a l 013/90 M a r l i p a l 1618/40 M a r l i p a l M 1618 L i poxol 12000* Fragrance Dyestuff

96

12.0 60.0 10.0 13.0 4.0 1 .o

A c t i v e matter: 79.0% * f u r t h e r products o f Huls Ag

SOURCE: Huls Chemical Co.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Products

2. Dairy, Food and General Industrial Cleaners

11

12


Dai ry Mi 1kstone Remover An A c i d D i l u t a b l e Concentrate

Wt.%

Inaredient : Deionized Water G l y c o l i c A c i d (70%) Phosphoric A c i d (85%) Avanel S-150

53.40 28.60 10.00 8.00

pH (as i s ) : ~ 2 . 0 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d Procedure: Charge water t o t h e m i x i n g vessel and s t a r t a g i t a t i o n . Under a g i t a t i o n , charge t h e G l y c o l i c Acid f o l l o w e d by t h e Phosphoric Acid. Charge t h e Phosphoric A c i d s l o w l y t o a v o i d s p l a t t e r i n g . Charge t h e Avanel S-150 and cool t o room temperature. F i l l o f f . Notes : T h i s f o r m u l a t i o n i s h i g h l y e f f e c t i v e a t removing d a i r y m i 1kstone from dai r y equipment Use c o n c e n t r a t i o n i s 1 / 2 t o 1 ounce per g a l l o n o f water. Brush thoroughly, then r i n s e . Formula CD-101

.

D a i r y M i 1kstone Remover Low Cost A c i d D i l u t a b l e Concentrate

Wt.%

Inaredient : Dei oni zed Water Phosphoric A c i d (85%) Gluconic A c i d (50%) Avanel 5-70 pH (as i s ) : < 2 . 0 Appearance: Clear, water-white

55.00 37.50 3.50 4.00 liquid

Procedure: To m i x i n g vessel, charge t h e water and s t a r t a g i t a t i o n . Slowly charge t h e Phosphoric A c i d t o a v o i d s p l a t t e r i n g . Cool t o room temperature and charge t h e Gluconic A c i d and Avanel S-70. Notes: A lower c o s t s u b s t i t u t e f o r PPG/Mazers CD-101 d a i r y cleaner f o r m u l a t i o n . I t r e t a i n s t h e general performance a t t r i b u t e s o f the o r i g i n a l formulation. Use c o n c e n t r a t i o n i s 1 / 2 t o 1 ounce per g a l l o n o f water. Brush thoroughly, then r i n s e . Formula CD-102

SOURCE: Mazer Chemicals: Suggested Formulations

&ky, Food and General I

.

. Cleaners

13

D a i r y P i p e l i n e Cleaner H i g h A 1 k a l ine Low Foam H v p o c h l o r i t e C l e a n e r

W % .t 52.00 20.00 2.50 1 .50

I n n r e d ient: D e i o n i z e d Water Sodium H y d r o x i d e (50%) Avanel S-74 Sodium Cumene S u l f o n a t e (40%) Sodium H y p o c h l o r i t e (12.5%)

24.00

pH ( a s i s ) : 12.5-13.5 Appearance: C l e a r , 1 i g h t - y e 1 l o w 1i q u i d Speci f ic G r a v i t y : 1 . 1 5 Procedure: Charge w a t e r t o m i x i n g v e s s e l and s t a r t a g i t a t i o n . Add Sodium H y d r o x i d e , and c o o l t o l e s s t h a n 9OF. Add t h e Avanel 5-74 and Sodium Cumene S u l f o n a t e . Mix u n t i l c l e a r and add t h e Sodium Hypochlorite. Notes: T h i s f o r m u l a t i o n combines a c h l o r i n e c l e a n e r w i t h t h e h i g h a l k a l i n i t y o f common p i p e l i n e c l e a n e r s r e s u l t i n g i n a s i n g l e c l e a n i n g system. S h e l f s t a b i l i t y o f h y p o c h l o r i t e c l e a n e r s i s dependent on t h e absence o f t r a c e m e t a l s . Care s h o u l d b e t a k e n t o i n s u r e good q u a l i t y w a t e r and h y p o c h l o r i t e . Formula may be a d j u s t e d t o use o t h e r c o m m e r c i a l l y a v a i l a b l e c o n c e n t r a t i o n s o f Sodium H y p o c h l o r i t e . A b s o l u t e c o n c e n t r a t i o n o f a v a i l a b l e c h l o r i n e i s 3.0%. SOURCE: Mazer Chemicals:

F o r m u l a t i o n CD-103

I n s t i t u t i o n a l S t a i n l e s s S t e e l Cleaner % by Weight

Components: Water 50% C i t r i c A c i d Burcosperse LP Dequest 2000* Burco NPS 50% 45% KOH

52.75 20.00 5.00 5.00 5.00 12.25

*From Monsanto o r use e q u i v a l e n t p r o d u c t . Procedure: Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l u n i f o r m between each a d d i t i o n . SOURCE:

B u r l i n g t o n Chemical Co.,

Inc.:

Suggested F o r m u l a t i o n

14

Advanced Cleaning Product Formulations

H i g h P r e s s u r e C l e a n e r f o r I n d u s t r i a l Use Liquid, transparent, a l k a l i n e Inqredients: Genapol UD-050 Genapol UD-080 Genopur ASA KOH (85%) B Water (ca.5OC) C Sodi ummetasi 1 ic a t e x 5H20 A q u a m o l l i n 8C Powder h i g h l y conc. Manufacturing: I The components o f A a r e mixed. I 1 Then B i s added. I11 F i n a l l y t h e components o f C a r e added

A

2,50% 2,50%

3,00% 5.00% 67,00% 10,00% 10,00%

C l e a n e r f o r M i 1k i n a Eaui Dment Liquid Ingredients: A Tetrapotassiumpyrophosphate Sodi ummetasi 1 i c a t e x 5H20 Sodiumcarbonate B Water C Genopur ASA

7.00% 5,00% 3,00% 70,00% 5.00%

5,00% KOH (85%) 5,00% D Genapol UD 080 Manufacturing: I One a f t e r a n o t h e r , t h e components o f A a r e added t o 8 . I 1 S t i r one a f t e r a n o t h e r , t h e components o f c t o I. I11 A t l a s t D i s added.

-

C l e a n e r f o r Meat P l a n t s Liquid Ingredients : A

Tetrapotassiumpyrophosphate

5,00%

Potassium w a t e r g l a s ( 4 0 Be) B Water C Genopur ASA KOH (65%) D Hostapur SAS 60 Genapol UD 080 S o l v e n t GX 5 Manufacturing: I Add one a f t e r a n o t h e r , t h e components o f A t o B . I 1 C i s added t o I by c o n t i n u i n g s t i r r i n g . I11 A t l a s t t h e components o f D a r e added.

-

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Agents: Guide F o r m u l a t i o n s

2,00% 76,00%

3,50% 3,50% 5.00% 2,00%

3,00%

D e t e r g e n t s and C l e a n i n g

he,Food and General Industrial Cleaners

15

Meat Packaaina P l a n t Cleaner Concentrate An A l k a l i n e High Foaming H y p o c h l o r i t e Hard Surface Cleaner w i t h Improved S a l t Tolerance

Wt.%

Inaredient : Oei oni zed Water Hostapur SAS-60 Potassi um Hydroxide Tetrapotassium Pyrophosphate Mazon 98 Sodium Cumene S u l f o n a t e (40%) Sodium H y p o c h l o r i t e (12.5%) Oei oni zed Water

59.20 2.50 0.90 2.10 5.00

1.30 10.00 19.00

pH (as i s ) : 12.5-13.5 Appearance: C l e a r - t o - t r a n s l u c e n t , yellow l i q u i d . Speci f ic G r a v i t y : 1 .04

s l i g h t l y viscous,

light-

Procedure: Charge t h e water t o a m i x i n g vessel and s t a r t a g i t a t i o n . Charge t h e Hostapur, f o l l o w e d by t h e Potassium Hydroxide and t h e Tetrapotassium Pyrophosphate. Apply c o o l i n g and then add t h e Mazon 98 and t h e Sodium Cumene Sulfonate. When product i s l e s s than 85 degrees F. add t h e Sodium H y p o c h l o r i t e and t h e balance o f t h e water. Notes: T h i s formula i s designed t o be d i l u t e d t o 3-6 ounces per g a l l o n i n h o t water and t o be a p p l i e d as a foam t o meat packing house w a l l s and o t h e r surfaces. A f t e r an a p p r o p r i a t e time, these surfaces should be thoroughly r i n s e d . S h e l f s t a b i l i t y o f c h l o r i n e cleansers i s dependent upon t h e absence o f t r a c e metals. Care should be taken t o i n s u r e good q u a l i t y water and Sodium H y p o c h l o r i t e . Revision o f CB-102 t o p r o v i d e g r e a t e r s a l t t o l e r a n c e .

SOURCE: PPG I n d u s t r i e s ,

Inc.:

Formula CB-102-A

Advanced Cleaning Prodccct Formulations

16

Steam Cleaners C1 eaner-Li ght Duty Inaredients : Sodi urn Metasi 1ia t e Sodi um T r i p o l yphosphate Trisodium Phosphate Aerosol 22 S u r f a c t a n t T r i t o n CF-10

% by Weiaht 30.0 58.0 10.0 1.o 1 .o

C l eaner-Medi urn Duty % by Wei a h t Inqredients: 33.0 Sodi urn O r t h o s i 1i c a t e 20.0 Sodium Carbonate 44.0 T r i sodi urn Phosphate 1.5 Aerosol 22 S u r f a c t a n t 1.5 T r i t_o_ n CF-10 Cleaner-Heavy D u t y (For O i l y S o i l s ) % by Weiaht Inaredients: Aerosol 22 S u r f a c t a n t 7.0 35.0 Sodium M e t a s i l i c a t e 3.0 Dowanol DE 55.0 Water Cleaner-General Purpose % by Weight Inaredients: 10.0 Aerosol 0s S u r f a c t a n t 35.0 Soda Ash 15.0 Sodi urn Hydroxide 30.0 Sodium M e t a s i l i c a t e (5H20) 10.0 Sodi um T r i p o l yphosphate Use _ _ _ 0.5 t o 2.0 0 2 . t o 1 a a l l o n o f water. Cleaner-Lipht Duty f o r S o f t Metals % by Weiaht Ingredients: 7.14 Aerosol 0 s S u r f a c t a n t Sodium Sesquicarbonate 92.86 Cleaner-General Purpose Inpredients: % by Weiaht 15-20 Sodi um Metasi 1ic a t e Aerosol 0s S u r f a c t a n t 2- 3 5.0 Aerosol 22 S u r f a c t a n t Water 73-78 Cleaner-Compound % by Weiaht Inaredients : Sodi urn Hydroxide 30.0 Borax 30.0 20.0 Soda Ash D i sodi um Phosphate 15.0 Aerosol C-61 S u r f a c t a n t 5.0 Add t h e d e s i r e d amount o f cleaner t o water which has been preheated t o 140F. ~

~~~

~

~~~

SOURCE: Cytec I n d u s t r i e s I n c . : Suggested Formulations

3. Degreasers

17

18


d-Liaonene Microemulsion Cleaner/Desreaser 11 11 16 62

Burco TME Burco FAE d-Li monene Water

parts parts parts parts

Mix i n o r d e r l i s t e d ; add water s l o w l v . Product w i l l t h i c k e n , then break as water i s added. No co-solvent i s r e q u i r e d when mixed i n p r o p r o r t i o n s g i v e n above. Produces a c l e a r product. Burco FAE i m p a r t s c o r r o s i o n r e s i s t a n c e i n a d d i t i o n t o emulsion c h a r a c t e r i s t i c s . To make a more concentrated product, l e s s water can be used, b u t r a t i o s o f t h e o t h e r a c t i v e s must remain s i m i l a r t o t h e above. Exampl e : 22 22 32 24

TME FAE d-Limonene Water

High a c t i v e products can reach a g e l - l i k e v i s c o s i t y , be t h i nned w i t h Isopropanol and B u t y l Propyl s o l v.

SOURCE: B u r l i n g t o n Chemical Co.,

Inc.:

parts parts parts parts

b u t can

Suggested Formulation

Concentrated d-Limonene Biodearadable Deareaser A N a t u r a l All-Purpose Micro-Emulsion Cleaner o r Concentrate

Wt.%

I n a r e d i ent : d-Limonene. Grade M Mazclean EP Deionized Water

30.00 20.00 50.00

pH (as i s ) : 9.0-10.0 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 0.97 Odor: Sweet Orange Procedure: Charge t h e d-Limonene and Mazon 245-103 t o an apprDopriate m i x i n g vessel and s t a r t a g i t a t i o n . Under good a g i t a t i o n , s l o w l y add t h e water and mix u n t i l s o l u t i o n i s c l e a r . Notes : T h i s f o r m u l a t i o n may be used "as i s " o r d i l u t e d . For heavyduty use, product should be sprayed "as i s " onto t h e o i l y s u b s t r a t e , f o l l o w e d by a water r i n s e .

SOURCE: PPG I n d u s t r i e s , I n c . :

Formulation CS-101

Degreasers

19

S o l v e n t Deareasi rig The s o l u b i l i t y o f Aerosol OT S u r f a c t a n t i s e x t r e m e l y h i g h i n a l l s o l v e n t s used f o r d e g r e a s i n g . I t w i l l d i s s o l v e e a s i l y a t room t e m p e r a t u r e i n most cases. I f h e a t i n g i s r e q u i r e d f o r s o l u b i l i z a t i o n , t h e s o l u t i o n w i l l be s t a b l e upon r e t u r n t o room temperature. As an example, A e r o s o l OT-75% i s s o l u b l e t o o v e r 50% a t room t e m p e r a t u r e i n c a r b o n t e t r a c h l o r i d e , b u t naphtha s o l v e n t r e q u i r e s h e a t i n g . B o t h a r e c l e a r s o l u t i o n s a t room t e m p e r a t u r e . The presence o f t h e w a t e r i n Aerosol OT-75% p o r t i o n i s an a i d i n t h e removal o f any w a t e r - s o l u b l e p a r t i c l e s p r e s e n t i n t h e work b e i n g degreased. F o r m u l a t i o n s such as: A e r o s o l GPG o r OT-75% H i g h F l a s h Naphtha

0.5% 99.5%

can be used f o r l i g h t - d u t y c l e a n i n g , t h e s o l v e n t removing t h e o i l s , waxes, e t c . and t h e A e r o s o l OT a i d i n g n o t o n l y i n t h e penetration o f t h e covering material, but also i n draining. T h i s t y p e o f c l e a n e r can be sprayed on, brushed on, o r t h e work can be immersed i n t o i t f o l l o w e d by a r i n s e . Heavy-Duty Degreasing: To remove heavy l u b r i c a t i n g and p r e s e r v a t i v e o i l s and greases, many s o l v e n t s may be used t o s p e c i f i c needs. A e r o s o l GPG S u r f a c t a n t w i l l be f o u n d t o be s o l u b l e i n a l l o f t h e s e s o l v e n t s . A t y p i c a l f o r m u l a t i o n used i s : A e r o s o l GPG o r OT-75% Kerosene

1- 3% 97-99%

P r e p a r a t i o n i s by s i m p l e m i x i n g . T r i - o r t e t r a c h l o r o e t h y l e n e , h i g h f l a s h naphtha o r o t h e r s u i t a b l e s o l v e n t s can be s u b s t i t u t e d f o r t h e kerosene. Carbonaceous d e p o s i t s can be removed by d i p p i n g i n f o r m u l a t i o n s such as: Kerosene Perchloroethylene Carbon T e t r a c h l o r i d e C r e s y l ic A c i d Aerosol GPG o r OT-75%

40%

30% 16% 10% 4%

N o r m a l l y , 3 g a l l o n s o f t h e above a r e added t o 1 g a l l o n of w a t e r which, f l o a t i n g on t h e s u r f a c e , m i n i m i z e s l o s s o f s o l v e n t . The work t o be c l e a n e d i s immersed i n t h e s o l v e n t phase f o r t i m e p e r i o d s o f a few m i n u t e s t o s e v e r a l hours, i f r e q u i r e d , t o o b t a i n c l e a n l i n e s s . Upon removal f r o m t h e s o l v e n t l a y e r , and a s h o r t r i n s e i n t h e aqueous l a y e r , t h e c l e a n e d a r t i c l e s a r e rinsed, d r i e d o r c a r r i e d onto t h e next operation. SOURCE: C y t e c I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

4. Dishwashing Detergents

20

Dishwashing Detergents

C1e a r L i q u i d D i shwash W i t c o l a t e AE-3

W i t c o 1298 S o f t A c i d Sodi um H y d r o x i d e , 50% W i t c o n a t e SXS L i q u i d W i tcami de 51 95 Phosphoric A c i d Water

q.s.

B l e n d i n g Procedure B1end in g r e d i e n t s in t h e o r d e r shown, between each a d d i t i o n .

% by Weiqht 12.5 19.0 5.2 13.5 2.5 t o pH = 6.4-6.8 q . s . t o 100

m i x i ng t h o r o u g h l y

Formula 108 N o n - C h l o r i n a t e d Machine D i shwashi na Compound, L i q u i d % by Weight

Water, D.I. Sodi um T r i p o l y p h o s p h a t e Versene 220, Powder Sodium G l u c o n a t e Sodium M e t a s i l i c a t e , P e n t a h y d r a t e C a u s t i c Soda 50% P e t r o ULF L i q u i d B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r shown, between each a d d i t i o n .

79.5 2.0 1.0 1.o 7.0 8.5 1.0 mixing thoroughly

Formula 109 Clear,

C o l o r l e s s Manual D i s h Wash % b y Weiqht 57.5 31.2 5.0 3.0 3.3

Water, D.I. W i t c o l a t e ES-3 R e w o t e r i c AM 8-14 Ethanol Sodium C h l o r i d e

B l e n d i n g Procedure: B1 end in g r e d i e n t s in t h e o r d e r 1is t e d . D i s s o l v e c o m p l e t e l y between each a d d i t i o n . Comment : R e w o t e r i c AM 8-14;

Grease c u t t e r and foam b o o s t e r .

Formula 132

SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

21

22


Dish Washi na Agent Clear, l i q u i d , 25% WAS

Alkanesulphonate:ethersulfate=4.1 Ingredients: 33.36% A Hostapur SAS 60 17.90% Genapol ZRO l i q u i d 47.50% B Water 0.10% Preservative q.s. Dye 0.20% Perfume 1.00% Hoe S 3924 Manufacturi ng : One a f t e r another, t h e components o f B a r e added t o A . Tests: V i s c o s i t y (mPas) : 90 Cloud p o i n t : <-5C Dish Washin c l e a r , liquid:

A ent 2 % : WAS

alkanesulphonate:ethersulphate=4.1 Ingredients: 33.30% A Hostapur SAS 60 17.90% Genapol ZRO l i q u i d B Water 44.50% 0.10% Preservative q.s. We 0.20% Perfume 4.00% Hoe S 3924 Manufacturing: One a f t e r another, t h e components o f B are added t o A. Tests V i s c o s i t y (mPas): 410 Cloud p o i n t : <-5C D i s h Washing Aaent Clear, l i q u i d , 30% WAS

alkanesulphonate:ethersulphate=4.1 Ingredients: A Hostapur SAS 60 40.00% Genapol ZRO l i q u i d 21.40% B Water 30.30% P r e s e r v a t i ve O.\lO% Dye q.s. 01.20% Perfume Manufacturing: One a f t e r another, t h e components o f 0 a r e added t o A.

Tests: V i s c o s i t y (mPas): 330 Cloud p o i n t : <-5C

SOURCE:

Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaningal Agents: Guide Formulations


23

D i s h Washi na Agent C l e a r , l i q u i d , 30% WAS

alkanesulphonate:ethersulphate=4:1 Inaredients: A Hostapur SAS 60 Genapol ZRO l i q u i d 8

40.00% 21.40% 34.30% 0.10% q.s. 0.20%

Water Preservative Dye Perfume Hoe S 3924

Manufacturing: One a f t e r a n o t h e r ,

4.00% t h e components o f 0 a r e added t o A.

Tests: V i s c o s i t y (mPas): 610 Cloud p o i n t : <-5C Powder f o r A u t o m a t i c Dishwashina Machines Inaredients: A Genapol 2908

1;. 00%

B

S o d i u m m e t a s i l i c a t e x 5H20

52.00%

C

Sodiumcarbonate Sodi u m d i c h l o r o i s o c y a n u r a t e Thermphos NW

10.00% 2.00% 35.00%

M a n u f a c t u r i no: I Spray A on 0 . I 1 One a f t e r a n o t h e r ,

t h e components o f C a r e added t o 1.

Application: 1-2 g d e t e r g e n t / L d i s h w a s h i n g l i q u o r



24

Advanced Cleoning Product Formulations

Dishwashing D e t e r a e n t . Medium V i s c o s i t v .

B a s i s M a r l o n A-A

% M a r l o n A 350 M a r l in a t 242/70 D i o n i l OC Na cumene s u l p h o n a t e 40 Balance w a t e r , f r a g r a n c e , sodium c h l o r i d e

30.0 5.7 1. o 1 .o dyestuff,

preservative, t o 100

A c t i v e m a t t e r : 20.0% Dishwashing DeterQent. Medium V i s c o s i t v . M a r l o n A 365 M a r l in a t 242/70 Balance w a t e r , f r a g r a n c e , sodium c h l o r i d e Active matter:

B a s i s M a r l o n A-B

%

18.5 4.3 dyestuff, preservative, t o 100

15.0%

D i shwashi na Detergent,

Medi urn V i m s i t y . B a s i s M a r l o n AS3-A

% M a r l o n AS3 C a u s t i c soda, 50% ( a p p r o x . ) M a r l ip a l 013/120 Balance w a t e r , f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e

10.5 2.6 2.7 preservative, t o 100

A c t i v e m a t t e r : 14.0% D i shwashi n Q D e t e r g e n t , Medi urn V i s c o s i t y .

Bas4 s M a r l o n AS3-B

% M a r l o n AS3 C a u s t i c soda, 50% ( a p p r o x . ) M a r l i n a t 242/70 Balance w a t e r , f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e

4.5 1.1 4.5 perservative, t o 100

A c t i v e m a t t e r : 8.0% I n c . : B a s i c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents f o r Household Purposes

SOURCE: H u l s America,

M w h i n g Detergents

D i shwashi n q D e t e r g e n t , Medi um V i s c o s i t y .

M a r l o n PS 65 M a r l in a t 242/70 M a r l a m i d DF 1218 Ethanol Balance w a t e r , f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e

*

25

B a s i s M a r l o n PS-A % 49.0 11.5 3.0 4.0


A c t i v e m a t t e r : 43.0% D i shwashi ng D e t e r g e n t ,

Medi u m V i s c o s i t y ,

M a r l o n PF 40 M a r l a m i d DF 1218 Balance w a t e r , f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e

B a s i s M a r l o n PS-B % 71.3 1.5


A c t i v e m a t t e r : 30.0% f u r t h e r p r o d u c t s o f H u l s AG

*

D i shwashi n g D e t e r g e n t ,

Medi u m V i scos t y .

M a r l o n AFO 40 M a r l a m i d D 1885 Balance water, f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e Active matter:

% 46.3 1.5


20.0%

D i shwashi ng D e t e r g e n t ,

Medi um V i s c o s i t y ,

M a r l o n AFO 50 Balance w a t e r , f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e Active matter:

B a s i s M a r l o n Compounds-A

B a s i s M a r l o n Compounds-B % 30.0


15.0%

SOURCE: H u l s America, I n c . : B a s i c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents for Household Purposes

26 Advanced Cleaning Roduct Formulations

D i shwashi n Q D e t e r a e n t

. Powdered.

SDrav M i x i na Process-A %

M a r l o x FK 64 1.o Sodium t r i p o l y p h o s p h a t e 40.0 Sodium m e t a s i l i c a t e p e n t a h y d r a t e 35.0 Sodium c a r b o n a t e , d e h y d r a t e d 22.0 Sodium d i c h l o r o i s o c y a n u r a t e 2.0 A c t i v e m a t t e r : 1.0% A p p l i c a t i o n : Use 3-5 g/1 w a t e r (depending on w a t e r h a r d n e s s ) D i shwashi n g D e t e r g e n t ,

Powdered,

Spray M i x i ng Process-I3 %

M a r l o x B 24/80 1. o Sodium t r i p o l y p h o s p h a t e 25.0 Sodium m e t a s i l i c a t e p e n t a h y d r a t e 25.0 Sodium m e t a s i l i c a t e , d e h y d r a t e d 20.0 Sodium c a r b o n a t e , d e h y d r a t e d 15.0 Sodi um d i c h l o r o i s o c y a n u r a t e 2.0 Phosphonate HEDP, e . g . Sequion 10 Na 2 2.0 Sodi um h y d r o x i d e 10.0 A c t i v e m a t t e r : 1.0 A p p l i c a t i o n : Use 3 - 5 g / 1 w a t e r (depending on w a t e r h a r d n e s s ) D i shwashi ng D e t e r g e n t ,

Powder, Phosphate-Free, Process-A

Spray M i x i n g %

M a r l o x MO 154 Sodi um c i t r a t e d i h y d r a t e Sodium d i s i l i c a t e g r a n u l a t e P o l y c a r b o x y l a t e , e . g . Sokalan PA 40 g r a n u l a t e Sodium p e r b o r a t e monohydrate Tetraacetylethylenediami ne (TAED) Enzyme Esperase Sodium s e s q u i c a r b o n a t e A c t i v e m a t t e r : 2.5% Dishwashing D e t e r g e n t s ,

Powder, Phosphate-Free, Process-I3

M a r l o x MO 154 Sodium c a r b o n a t e , d e h y d r a t e d P o l y c a r b o x y l a t e , e . g . P e r m u l s i n SP Phosphonate HEDP, e . g . Sequion 10 Na 2 Sodi um m e t a s i 1 i c a t e A c t i v e m a t t e r : 2.0%

2.5 35.0 25.0 5.0 15.0 4.0 2.0 t o 100

Spray M i x i n g % 2.0 15.0 10.0 5.0 t o 100

SOURCE: H u l s America, I n c . : B a s i c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents f o r Household Purposes


DishwashtnLDeterpent (4096 Sol ids)-A % by W e i m 37.0 17.5 4.0 34.0

Witconate 1260 S l u r r y W i t c o l a t e LES-6OA W i tcami de 128T Water

Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r shown. m i x i n g thoroughly between each a d d i t i o n . Dishwashing Deteraent (40% S o l i d s ) - 8 % bv Weiqht

W i tconate W i tconate Witcolate W i tcamide Water

59.0 6.0 17.5

45LX SXS L i q u i d LES-6OA 128T

4.0 16.5

Blending Procedure: Blend i n g r e d i e n t s i n t h e order shown. m i x i n g thoroughly between each a d d i t i o n . Formula 105 Hand D i shwashi ng L i q u i d % by Weiaht W i t c o n a t e AOS

W i t c o l a t e S-1285C Witcamide 128T Water

60.0 10.0 4.0 26.0

Blending Procedure: Blend ingredi e n t s in t h e o r d e r shown, m i x i ng thorough1y between each a d d i t i o n . Formula 1 0 6


27

28

Advanced Cleaning R&t

Formulations

Dish Wash w/Ami ne Oxi de/LABS/SLES % by Weiqht

Water, D . I . Witconate 30DS Varox 1770 W i t c o l a t e SE-5

62.9 13.7 5.3 18.1

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s l v e ompl e t e l y between each a d d i t i o n . Add Ethanol as needed t o lower v i s c o s i t y . Typical Properties: V i s c o s i t y , cps: 620 S o l i d s : 16.8% pH: 9 . 1 2 Formula 117 D i s h Wash w / h i ne Oxi de/LABS/ALES % by Weiaht 70.0 13.8 3.1

Water, 0.1. W i t c o n a t e 30DS Varox 1770 W i t c o l a t e LES-6OA Ethanol

8.2 5.0

B1endi ng Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . A c i d i f y w i t h C i t r i c Acid t o pH = 6.5. Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 10.1% pH: 6 . 6 8 Formula 118 Dish Wash w/Ami ne Oxide/LABS % by Weiaht

Water, D . I . W i t c o n a t e 30DS Varox 1770 Ethanol Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical P r o p e r t i e s : V i s c o s i t y , cps: 4 S o l i d s : 7.8% pH: 9 . 1 6 Formula 119


69.8 20.3 4.9 5.0


29

High-Performance Hand D i s h Detergent Formula DW-0013

Wt.% Water SXS, 40 Caustic Soda, 50% Dodecylbenzene s u l f o n i c A c i d Rhodapex NA-61 A 1 kami de DC-212/S Rhodacal A-246/L Rhodasurf 25-9 C i t r i c A c i d (50%). t o pH 8 Ethanol SD-3A P r e s e r v a t i ve Fragrance Dye

To 100 3.0 6.6 25.0 8.0 3.0 10.0 6.0 Q.S. 2.0 0.1

-

Procedure Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h mixing. Mix u n t i l u n i f o r m a f t e r each a d d i t i o n . C i t r i c A c i d and Caustic Soda are used f o r pH adjustment. Physical ProDerties Appearance: Clear g o l d l i q u i d , dyed t o preference pH. as i s : 8 V i s c o s i t y : 400 cps S p e c i f i c G r a v i t y : 1.05 M i l d L i a u i d Hand Dish Detergent Water Caustic Soda (50%) Dodecylbenzene s u l f o n i c a c i d Miranol CS Conc. A1 kami de DC-212/S Rhodasurf 25-9 Cheel ox BF-13 C i t r i c A c i d (50%). t o pH 8 Fragrance Dye

W % .t To 100 3 12 15 3 3 0.2

Procedur e Add t h e i n g r e d i e n t s i n t h e order l i s t e d w i t h mixing. Mix u n t i l u n i f o r m a f t e r each a d d i t i o n . C i t r i c a c i d and c a u s t i c soda are used f o r pH adjustment. D i s s o l v e t h e dye i n water before a d d i t i o n . Phvsi c a l P r o p e r t i es Appearance: Clear g o l d l i q u i d , dyed t o preference pH. as i s : 8 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : 150 cps

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Formulas

Q.S.

-

-

30


S t a r t i n g F o r m u l a t i o n s f o r Home Machine Dishwashinq D e t e r g e n t s 8.7% Phosphorous(A) Compounds: BASF S u r f a c t a n t * Sodium t r i p o l y p h o s p h a t e B r i t e s i 1 H24 hydrous sodium s i 1 i c a t e * * Sodium s u l f a t e Sodium c a r b o n a t e C hl o r i n a t e d isocyanurate*** Water

?4 b y W S i ¶ h _ t .

3 34 17

15 19 2 10

8.7% Phosphorous(B1 Coflpounds : BASF S u r f a c t a n t * B r i t e s i l H24 hydrous sodium s i l i c a t e * * Sodi um s u l f a t e Sodium c a r b o n a t e C hl o r i n a t e d isocynaurate*** Sodium t r i p o l y p h o s p h a t e h e x a h y d r a t e

% -by__W!sh t 3

17 14.5 20 1.5 44

Nonphosphate Compounds2 BASF S u r f a c t a n t * Sokalan PABOCL B r i t e s i l ti24 hydrous sodium s i l i c a t e * * C h l o r i n a t e d t r i s o d i u m phosphate Sodium s u l f a t e Sodium c a r b o n a t e Sodi um c i t r a t e d i h y d r a t e

”/._ bY.

W!%bl

t 4.0

2**** 20 12.5 30 1.5 30

* P l u r o n i c , P l u r a f a c , and I n d u s t r o l s u r f a c t a n t **Other r a t i o s o f S i 0 2 can be used. L i q u i d s i l i c a t e s can a l s o be used i n p l a c e o f powders. ***Such as ACL-59. ****Active M i x i n g Procedures: T o a c h i e v e maximum c h l o r i n e s t a b i l i t y o f t h e f o r m u l a t e d d e t e r g e n t , t h e f o l l o w i n g p r o c e s s i s suggested f o r t h e m i x i n g o f raw mater ia1 s : 1 . Spray a m i x t u r e o f t h e s u r f a c t a n t and w a t e r ( o r s u r f a c t a n t , w a t e r , and l i q u i d s i l i c a t e ) o n t o t h e phosphate b u i l d e r s , soda ash, o r m i x t u r e t h e r e o f . S t i r c o n t i n u o u s l y w h i l e s p r a y i n g . T h i s process r e s u l t s i n h y d r a t i o n o f t h e b u l d e r s w i t h s i m u l taneous a d s o r p t i o n o f t h e s u r f a c t a n t . 2. Add t h e c h l o r i n e - c o n t a i n i n g compound and any f i l e r s t o t h e m i x t u r e and c o n t i n u e m i x i n g u n t i l t h e e n t i r e m i x u r e i s homogeneous. A d r y , f r e e - f l o w i n g g r a n u l a r produc s h o u l d be o b t a i n e d w i t h t h i s method. SOURCE: BASF Corp.: Suggested F o r m u l a t i o n s

-washing

Detergents

31

L i g h t Duty L i q u i d Deteraents L i q u i d d e t e r g e n t s based on P i l o t C a l s o f t , Calsuds and Calfoam s u r f a c t a n t s produce s a f e , e f f e c t i v e suds w i t h e x c e l l e n t greasec u t t i n g p r o p e r t i e s f o r hand dishwashing. D e t e r g e n t s c o n t a i n i n g Calamide C a r e e s p e c i a l l y m i l d t o s e n s i t i v e s k i n . P i l o t Formula #LDL-010-01 % bv Weipht 61 . O O 19.80 9.90 5.00 3.00 0.10 0.10 0.10 1 .oo

Water C a l s o f t L-60 C a l f a x DB-45 Cal foam EA-603 Calamide C C i t r i c Acid Perfume Dye Ammonium C h l o r i d e P i l o t Formula #LDL-013-01

% by Weiaht

70.00 10.00 20.00 Q.S. pH 7 Q.S.

Calsuds A Cal foam ES-303 Water* C i t r i c Acid Perfume and C o l o r P i 1o t Formul a #LDL-005-01

% bv Weiaht 40.00 10.00 6.00 12.50 26.50 Q.S. pH 7

C a l s o f t L-40 Cal foam EA-603 Calamide C P i l o t SXS-40 Water* C i t r i c Acid Perfume and C o l o r

Q.S. P i 1o t Formula #LDL-015-01 % b v Weight

Calsuds CD-6 Cal foam EA-603 P i l o t SXS-40 Cal s o f t LAS-99 Water* C i t r i c Acid Perfume and C o l o r

25.00 10.00 8.80 6.00 50.20 Q.S. pH 7 Q.S.

*May be o p a c i f i e d by r e p l a c i n g 1% o f w a t e r w i t h 1% l a t e x o p a c i f ie r Opaci f i e r s h o u l d be d i 1u t e d w i t h w a t e r b e f o r e addition. SOURCE: P i 1o t Chemi c a l Co. : Household C1eaner Formul a t i on8

.

32 Advanced Cleaning Promcct Formulations L i g h t D u t y Liauid.

Premium Hand Dishwash % by Weight

Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S1 u r r y W i t c a m i de 128T P e t r o LEA L i q u i d Sodium S u l f a t e Ethanol Formal i n Perfume, Dye

30.2 21.7 36.7 5.0 1.9 2.6 1.8 0.1 q.s.

B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH = 6.5-7.0 using C i t r i c Acid. T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 230 Appearance: C l e a r L i q u i d Formula 113 L i g h t D u t y L i q u i d Economy Hand D i shwash % by Weiqht 73.6 8.3 13.5 1.9 1. o 0.6 1.o 0.1 q.s.

Water, D . I. W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t c a m i de 128T P e t r o LEA L i q u i d Sodium S u l f a t e Sodium C h l o r i d e Formal in Perfume, Dye

81 e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH = 6.5-7.0 using C i t r i c Acid. T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 180 Appearance: C1e a r L i q u i d Formula 115



LXshwashing Detergents

33

L i a u i d Hand D i s h D e t e r g e n t Formula DW-0016

Wt.% Water Caustic Soda (50%) Dodecylbenzene s u i f o n i c a c i d Rhodapex NA-61 A1 kami de DC 212/S Cheelox BF-13 C i t r i c A c i d (50%), t o pH 8 Sodium c h l o r i d e Fragrance Dye Opaci f ie r (Morton )

To 100 2.5 10 4.5 1 0.5 Q.S. 1

--

Wt.%

Wt.%

To 100 To 100 3.3 4.1 13 16 5 4.5 3 2 0.5 0.5 Q.S. Q.S. 1 1

--

Procedur e Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d , w i t h mixing. Mix u n t i l u n i f o r m a f t e r each a d d i t i o n . C i t r i c a c i d and c a u s t i c soda a r e used f o r pH adjustment. Sodium c h l o r i d e b u i l d s v i s c o s i t y . D i s s o l v e i t i n water b e f o r e a d d i t i o n . D i s s o l v e t h e dye i n water b e f o r e a d d i t i o n . I f o p a c i f i e r i s used, i t should be d i l u t e d w i t h water b e f o r e a d d i t i o n . A l l pH adjustments must be completed b e f o r e t h e o p a c i f i e r i s added. Phvsical ProDertieg Appearance: L i q u i d , c o l o r e d and o p a c i f i e d t o preference pH. as i s : 8 pH, 1%: 7.2 V i s c o s i t y : 200-400 cps Speci f ic Gravi t y : 1 .02+-0.05

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Formula

34


Mechanical D i shwashi ng Detergent Chlorinated Formula DW-0009

Wt.% Sodium Carbonate ( L t . Density) Antarox BL-330 Sodium Tripolyphosphate. Powder Sodium M e t a s i l i c a t e Pentahydrate Clearon CDB (FMC)

41 . O 2.0 34.0 20.0 3.0

ProcedurQ Add t h e sodium carbonate t o t h e mixer. Spray on t h e Antarox EL 330. Add t h e remaining i n g r e d i e n t s i n t h e order l i s t e d . Mix u n t i 1 uniform. Phvsi c a l P r o D e r t i eg Appearance: White, f r e e - f l o w i n g powder pH ( 1 % ) : 11.2 S p e c i f i c G r a v i t y : 0.70 Uechani c a l D i shwashi ng DeterQent L i sui d Formula DW-0010 Igepal CO-730 Gantrez AN-149 Potassium Hydroxide (45% A c t i v e ) Sodium S i l i c a t e (46% A c t i v e ) Antarox BL-330 Tetrapotassium Pyrophosphate (60% A c t i v e ) Water

Wt% . 0.5 1. o

3.0 17.0 3.0 63.3 12.2

Proctndur e 1. Add Gantrez AN-149 t o I g e p a l CO-730/water m i x t u r e and s t i r a t room temperature u n t i l d i s s o l v e d . Heat t o 45-50C i f n o t t o t a l l y i n solution. 2. M a i n t a i n heat a t 45C and add r e s t o f i n g r e d i e n t s i n d i v i d u a l l y . Physical P r o m r t i eg pH (as i s ) : 13.2 pH (1%): 10.4 V i s c o s i t y : 1060 cps S p e c i f i c G r a v i t y : 1.14

SOURCE: Rhone-Poulenc S p e c i a l t i e s 6 S u r f a c t a n t s : Formulas


35

Liauid Formula DW-0008

Wt.% 60.0 10.0 5.0 4.0 1.0 20.0 Q.S. P.S.

Rhodacal A-246/L Rhodapex MA-460 Alkamide DC-212/S Sodium X y l e n e S u l f o n a t e (40%) O p a c i f i e r (Morton) Water C i t r i c A c i d t o pH 6.5-7.5 Perfume and C o l o r

Procedure 1. Charge w a t e r and sodium x y l e n e s u l f o n a t e t o v e s s e l equipped with agitation. 2. Add Rhodacal A-246/L and Rhodapex MA-360 t o v e s s e l and m i x u n t i 1 uniform. 3 . Add Alkamide DC-212/S and mix as above. 4. A d j u s t pH 6.5-7.5 w i t h c i t r i c a c i d . 5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and c o l o r a n t , as d e s i r e d . Physical P r o m r t i e s : Appearance: C l e a r g o l d l i q u i d , dye and o p a c i f y t o p r e f e r e n c e . pH, as i s : 6.5-7.5 S p e c i f i c G r a v i t y : 1.02-1.04 V i s c o s i t y : 200-300 cps SOURCE: Rhone-Poulenc S u r f a c t a n t s EL S p e c i a l t i e s :

Formula

36 Advanced Cleaning Product Formulations

S t a r t i n a Formulations f o r Commercial Machine Dishwashing Deteraents Nonchlori ne/Noncaustic % by Weight

BASF S u r f a c t a n t *

Sodium Sodium Sodium Sodium Water

tripolyphosphate carbonate sulfate m e t a s i l i c a t e pentahydrate

3 34 22 11

25 5

Noncaustic BASF S u r f a c t a n t * Sodium t r i p o l y p h o s p h a t e Sodium carbonate Sodium m e t a s i l i c a t e pentahydrate C h l o r i n a t e d isocyanurate** Water

% bv Weiaht 3 31.5 20 31.5 1.5 12.5

ChlorineKaustic % bv Weiqht

BASF S u r f a c t a n t * Sodium t r i p o l y p h o s p h a t e Sodium carbonate Sodium m e t a s i l i c a t e pentahydrate C h l o r i n a t e d isocyanurate** Sodium hydroxide (90%) Water *Pluronic, Plurafac, **Such as ACL-59

3 34 18 22.5 2.5 15 5

Industrol surfactant

M i x i ng Procedures : 1. Thoroughly mix t h e phosphate and carbonate. 2 . I n a separate c o n t a i n e r , mix t h e s u r f a c t a n t and water. Next, spray th'is l i q u i d onto t h e phosphate/carbonate m i x t u r e . Mix c o n t i n u o u s l y w h i l e spraying, and continue mixing u n t i l t h e l i q u i d i s completely adsorbed and t h e m i x t u r e i s homogeneous. 3. Add t h e m e t a s i l i c a t e , s u l f a t e , and/or c a u s t i c and mix. 4. F i n a l l y , add t h e c h l o r i n a t e d cyanurate and mix thoroughly. Note: The m i x i n g sequence given above i s necessary f o r m a i n t a i n i n g maximum c h l o r i n e s t a b i l i t y .

SOURCE:

BASF Corp.:

Suggested Formulations

5. General Purpose Cleaners

37

38

Advanced Cleaning Roduct Formulatioiu

A 1 1 Purpose Cleaner Weight.% 10.0 5.0 5.0 4.0 10.0 66.0

Mackam 2CSF T e t r a p o t a s s i um Pyrophosphate T r i sodium Polyphosphate KOH (45%) Low Rosin T a l l O i l F a t t y Acid Dei oni zed Water

Procedure: 1. D i s s o l v e Tetrapotassi um Pyrophosphate and T r i sodi um Po Yphosphate a t 70C. 2. Add KOH. 3. Disperse T a l l O i l F a t t y Acid. 4. Cool t o 50C and s l o w l y add Mackam 2CSF. PhosDhate Free A l l PurDose Cleaner Sodium M e t a s i l i c a t e Pentahydrate Mackami ne C-10 Caustic Soda (50%) Mackam 2CYSF Tetrasodium EDTA (40%) Dei oni zed Water

Weight .% 22.0

9.0 2.0 4.0 1. o 62.0

Procedure: 1. Add Sodium M e t a s i l i c a t e and Tetrasodium EOTA t o water and heat t o 60C. 2. Add Mackamine C-10 and Caustic Soda (50%). 3. Add Mackam 2CYSF and blend u n t i l c l e a r . Bathroom T i l e Cleaner Wei a h t .% 4.7 5.0 1 .o

Sodium H y p o c h l o r i t e (35%) Mackamine LO Tetrasodi um EDTA Dei oni zed Water

89.3

Procedure: Add components t o water and blend u n t i l c ear.

SOURCE: M c I n t y r e Qroup L t d . :

Suggested Formu a t i one

39

General Purpose Cleaners

A l l Purgose C l e a n e r % b v Weiqht

61.2

Water Sodi um Carbonate T e t r a s o d i u m EDTA, 40% W i t c o l a t e 7031 Sodium C h l o r i d e W i t c o n a t e SXS L i q u i d C i t r i c A c i d , 50%

5.0

6.0 15.0 10.8 2.0 9 . s . t o pH=11.0-11.5

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Typical Properties: V i s c o s i t y , c p s : Water t h n S o l i d s : 25.6% p H , as i s : 1 1 . 2 SOURCE: W i t c o Corp.:

Formula 518 All-PurDose Cleaner % bv Weisht

3.2 2.7 2 3 1 5 90 3

Eastman E 8 s o l v e n t Na4EDTA* Nonionic s u r f a c t a n t * * Isopropyl alcohol Water * T e t r a s o d i u m e t h y l enedi ami n e t e t r a c e t a t e **Such as Neodol 23-7 a l c o h o l e t h o x y l a t e N-95 e t h o x y l a t e d n o n y l p h e n o l ( T e x a c o ) .

39%) Shell) o r Sulfon

C

Hard-surface Cleaner % bv Weiaht

Eastman DB s o l v e n t Anionic surfactant*** N a 4 EDTA* Ammonium H y d r o x i d e (28%) Water

***

7.0 1.o

1.25 2.0 88.75

***Such as Rhodapex CO-433 (Rhone-Poulenc) * * * * T e t r a s o d i u m ethylenediaminetetraacetate (39%)

SOURCE:

Eastman.Chemica1 Co.: Eastman EB and D 0 S o l v e n t s f o r C l e a n e r s : Suggested F o r m u l a t i o n s

40 Advanced Cleaning Product Formulations A1 1-Purpose C1eaner-A

% Marl i p a l 24/90 Methoxypropanol Sodium carbonate N i t r i l o t r i a c e t a t e , 40% Balance water, fragrance, sodium c h l o r i d e

7.5

6.0 3.0 0.4 dyestuff,


A c t i v e m a t t e r : 7.5% Viscosity: Liquid A11-PUrDOSe C l e a n e r 4

%

M a r l i p a l 1012/6 M a r l i n a t 242/28 Sodium carbonate Sodium c i t r a t e d i h y d r a t e Sodium t a r t r a t e Balance water, fragrance, sodium c h l o r i d e

1 .o 10.0 3.0 1.5 1.5 dyestuff,


A c t i v e m a t t e r : 3.8% V i s c o s i t y : Low Al1-PUrDOSe Cleaner. w i t h Y i c r o b i c i d a l P r o o e r t i e s . Liauid-B Marl ip a l 013/99 Warlazin KC 21/50 N it r i1o t r iacetate, 40% Sodium carbonate Balance water, fragrance,

% 8.0 5.0 0.5

3.0 dyestuff

t o 100

A c t i v e m a t t e r : 9.7%


I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

41


A-Jl-Purpose Cleaner,

Liquid-A %

M a r l o n PS 65 M a r l ip a l 01 3/69 Coconut f a t t y a c i d C i t r i c terpene Methoxypropanol Sodium c a r b o n a t e Sodium c i t r a t e d i h y d r a t e E t h y l e n e d i a m i n e t e t r a a c e t a t e , 40% Balance w a t e r , f r a g r a n c e , d y e s t u f f , Active matter:

3.0 1 .o 0.2

2.0

preservative

3.0 3.0 3.0 0.2 t o 100

3.1% A l l -Pu_rpose C1eaner

, L i q u i d-6 '16

M a r l ip a l 01 3/69 C i t r i c terpene Methoxypropanol Sodi um c a r b o n a t e C i t r i c acid N i t r i l o t r i a c e t a t e , 40% KNA cumene s u l p h o n a t e 40 Balance w a t e r , f r a g r a n c e ,

5.0

0.2 5.0

dyestuff,

preservative

3.0 1 .o 0.2 1.o t o 100

A c t i v e m a t t e r : 4.5% All-Purpose

CleaKer,

with-Microbicidal

Properties,

Liquid-A %

M a r l ip a l 01 3/99 N i t r i l o t r i a c e t a t e , 40% Lonzabac 12.30 Sodium c a r b o n a t e KNA cumene s u l p h a t e 40 Balance w a t e r , f r a g r a n c e , d y e s t u f f

7.5

2.0 3.0 3.0 2.0 t o 100


SOURCE:

Huls America, I n c . : B a s i c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents f o r Household Purposes

42

Advanced Cleaning product Formulations

All-Purpose

C l e a n e r , Pastv-A

96

10.0 2.6 15.5 3.0 4.0 0.1 2.0 t o 100

M a r l o n AS3 C a u s t i c soda, 50% ( a p p r o x . ) M a r l in a t 242/28 M a r l ip a l 013/30 T y l o s e CBR 10000 Titanium dioxide Sodium c h l o r i d e ( a p p r o x . ) Balance w a t e r , f r a g r a n c e , p r e s e r v a t i v e A c t i v e m a t t e r : 18.0% A 1 1-Purpose

Cleaner

, Pastv-B %

M a r l o n PF 40 M i l ip a l 01 3/30 Marlamid DF 1218 T y l o s e CBR 10000 Titanium dioxide Sodium c h l o r i d e ( a p p r o x . ) Balance w a t e r , f r a g r a n c e , A c t i v e m a t t e r : 22.0%

45.0 2.0 2.0 4.0 0.1 8.0 t o 100

preservative

A l l - P u r p o s e C l e a n e r , W i t h Soap,

High Viscosity-A %

M a r l o n PF 40 Oleic acid C a u s t i c p o t a s h , 50%* ( a p p r o x . ) Potassium c a r b o n a t e * E t h y l e n e d i a m i n e t e t r a a c e t a t e , 40% Balance w a t e r , f r a g r a n c e , d y e s t u f f , A c t i v e m a t t e r : 12.8% A l l - P u r p o s e Cleaner.

preservative

W i t h Soap.

5.0 10.0 3.9 1.o 0.2 t o 100

High Viscositv-B

96 M a r l ip a l 24/79 M a r l ip a l 242/28 Oleic Acid C a u s t i c p o t a s h , 50%* ( a p p r o x . ) Sodi um c i t r a t e d i h y d r a t e E t h y l e n e d i amine t e t r a a c e t a t e , 40% Ethanol Balance w a t e r , f r a g r a n c e , d y e s t u f f , A c t i v e m a t t e r : 11.8%

*

preservative

2.0 5.0 8.0 3.1 1.5 0.2 1.5 t o 100

I n c . : Basic Formulations o f Detergents and C l e a n i n g Agents f o r Household P r o d u c t s

SOURCE: H u l s America,


D-Lilnonene E m u l s i f i a b l e Concentrate Formul a HS-0094

Wt.%

Component D-Li monene Rhodacal I PAM I g e p a l CQ-720 T r i ethanol ami ne

80.0 15.0 4.0 1 .o

Procedure Blend i n g r e d i e n t s i n order l i s t e d and m i x u n t i l uniform. Phvsical P r o o e r t i es Appearance: Clear, y e l l o w l i q u i d S p e c i f i c G r a v i t y : 0.9 V i s c o s i t y : t 1 0 cps pH, as i s : 10.0 Note: Product forms m i l k y w h i t e emulsions when d i l u t e d w i t h water. D-Limonene All-PurDose Cleaner Formula HS-0033

Wt.%

Comoonent: Water Sodium Metasilicate-Pentahydrate Miranol FBS Rhodasurf 91-6 Cheelox BF-13 A1 kamide DC-212/M D-Li monene

73.5 2.0 10.0 3.5 5.0

3.0 2.0

Procedur e Blend i n g r e d i e n t s i n order l i s t e d and m i x u n t i l uniform. Phvsicsl Pronerties Appearance: S l i g h t l y hazy, y e l l o w l i q u i d pH, as i s : 1.25 S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y :
SOURCE: Rhone-Poulenc S u r f a c t a n t s 81 S p e c i a l t i e s :

Formulas

43

44

Advanced Cleaning Rorluct Formulations

General C1 eaners Cleaner-Household I n s r e d ie n t s : Tetrapotassium Pyrophosphate Dodecyl benzene Sul f o n a t e T r i ethanol ami ne S a l t Aerosol A-103 S u r f a c t a n t L a u r i c Diethanolamide Sodium Xylene S u l f o n a t e

% by Weiaht 8.0 4.0 4.0 2.0 76.0

Mix a l l o f t h e above t o g e t h e r a t one time.

A1 k a l ine Cleaner % bv Wei a h t

I n s r e d ie n t s : Aerosol 0 s S u r f a c t a n t Sodi um Metasi 1ic a t e Caustic Soda Tetrasodi um Pyrophosphate T r i sodi um Phosphate

5.0 50.0 5.0 7.0 33.0

L i a u i d Hand Cleaner % by Weiaht 60.0 10.0 5.0 5.0

Insredients: Aerosol A-102 S u r f a c t a n t Mineral O i l Coconut O i l n-Propanol o r Isopropanol Triethanolamine Germicide Water

0.5 0.1 19.4

Germicidal C1eaner I n a r e d i ents: Aerosol 22, Aerosol 0 s . Aerosol A-102 S u r f a c t a n t or mixture Tetrapotassium Pyrophosphate Dowicide 32 Isopropanol Water

SOURCE: Cytec I n d u s t r i e s I n c . :

% bv Weiaht


10.0 7.0 5.0 3.0 75.0


45

Hiph-Performance General Purpose Cleaner Concentrate Formula HS-0038

Wt.% 65.0 6.0 13.0 5.0 5.0 4.0 2.0

Water STPP (Anhydrous Granular) Rhodapon UB Rhodapon BOS A1 codet HSC-1000 Butoxyethanol Miranol FBS

Procedur e Blend i n g r e d i e n t s i n order 1 s t e d and mix u n t 1 uniform. Phvsi c a l P r o D e r t l es Appearance: Clear, l i g h t ye1 ow 1 q u i d pH, as i s : 9 . 4 Specific Gravity: 1.06 V i s c o s i t y : t 1 0 cps Heavy-Dutv Cleaner Powder Formula HS-0039

Wt.96 40 10 20 30 Q.S

Trisodium Phosphate o r Sodium Carbonate Sodi um S i 1ic a t e Rhodacal DS-10 Sodium S u l f a t e Fragrance Procedur g Add i n g r e d i e n t s i n o r d e r l i s t e d t o powder blender uniform.

Mix u n t i l

Physical ProDerti es Appearance: Whi t e , f r e e - f 1owi ng powder pH, 1% S o l u t i o n : 10.8

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s :

Formulas

46

Advanced Cleaning Pr&t

Formulations

N e u t r a l A 1 1 -PurDose C1 eaner, w i t h P e a r l escence E f f e c t , High V i scosi t y - A

96 M a r l o n PS 65 M a r l in a t 242/28 Marlamid DF 1218 M a r l a m i d PG 20 C e l l o b o n d HEC l O O O O O A Balance w a t e r , f r a g r a n c e , A c t i v e m a t t e r : 7.2%

dyestuff,

preservative

7.5 4.5 1 .o 2.0 0.7 t o 100

N e u t r a l All-PUrDOSe C l e a n e r , w i t h Pearlescence E f f e c t . H i ah V i s c o s i t y - B

96 M a r l i n a t OFK 30 M a r l in a t 242/28 Marlamid DF 1218 M a r l ip a l 24/90 Marlamid PG 20 C e l l o b o n d HEC l O O O O O A Balance w a t e r , f r a g r a n c e , A c t i v e m a t t e r : 5.0%

5.0 2.0 1 .o

I

dyestuff,

A1l-PUrDOSe Cleaner,

preservative

.o

1. o 0.9 t o 100

w i t h Acetic Acid-A

M a r l i p a l 1012/6 M a r l i n a t 242/28 Sodium c i t r a t e d i h y d r a t e Acetic acid* Sodi um c h l o r i d e ( a p p r o x . ) Balance w a t e r , f r a g r a n c e , d y e s t u f f A c t i v e m a t t e r : 5.7% V i s c o s i t y : low

96

1.5 15.0 1 .o 2.0 6.5 to 100

A11-PUrDOSe C l e a n e r . w i t h A c e t i c Acid-B M a r l o n PS 65 Acetic acid* Balance w a t e r , f r a g r a n c e , d y e s t u f f A c t i v e m a t t e r : 3.3% V i s c o s i t y : 1i q u i d * f u r t h e r p r o d u c t s o f H u l s AG

s6

5.0 6.0 t o 100



47

Non-PhosDhate A l l PurDose Cleaner % by Weight 77.15 0.75 3.00 3.40 1 .oo 1.75 6.00

Components: Water 45% KOH Burcosperse AP L i q u i d Sodium Xylene Sulfonates 40% Sodi um C i t r a t e Dodecylbenzene S u l f o n i c Acid Burco TME B u t y l Propasol Varsol o r M i n e r a l S p i r i t s

6.00 0.95

Procedure: Add components i n t h e order l i s t e d . between each a d d i t i o n .

Blend u n t i l u n i f o r m

O i l S D l i t t i n s General PurDose Cleaner

Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burco ADS-40 Burco TME Burco LAA-38 Burco EHS

% by Wei Qht 82.5

5.0 2.5 5.0 2.5 2.5

Procedure: Add components i n t h e o r d e r l i s t e d . Blend u n t i l f u l l y d i s s o l v e d between each a d d i t i o n . T h i s i s a use as i s f o r m u l a t i o n f o r heavy duty c l e a n i n g . For l i g h t e r d u t y a p p l i c a t i o n s , d i l u t i o n w i t h water may be p o s s i b l e . T h i s f o r m u l a t i o n w i l l suspend o i l t o a s s i s t w i t h removal. The suspended o i l w i l l then f l o a t f o r easy removal.

SOURCE: B u r l i n g t o n Chemical C o . ,

I n c . : Suggested Formulations

48


Scouri ng Cleaner,

Medi urn V i scosi tv-A

Marlon PS65 Marl ip a l 01 3/30 Sodium sulphate Calcium carbonate, e.g. Durcal 40 Balance water, d y e s t u f f , fragrance,

%

4.3

preservative

2.7 1.5 50.0 t o 100

A c t i v e m a t t e r : 5.5% Scouring Cleaner. Medi urn V i scosi t y - B

%

Marlon PS 65 M a r l i p a l 013/30 Marl inat 242/28 Sodium carbonate Calcium carbonate, e.g. Durcal 40 Balance water, d y e s t u f f , fragrance, p r e s e r v a t i v e

3.5 3.0 2.0 1.5 50.0 t o 100

A c t i v e m a t t e r : 5.8% Scouring Cl-eaner. Powder-A

%

5.0 5.0

Marlon ARL Sodium carbonate, dehydrated Sodi um d i c h l o r o i socyanurate C a l c i um carbonate powder (abrasive)

1.o t o 100

A c t i v e m a t t e r : 4.0% Scouring Cleaner, Marlon ARL Sodium carbonate, dehydrated Sodium t r i p o l y p h o s p h a t e Calcium carbonate powder ( a b r a s i v e )

Powder-B


SOURCE:

%

5.0 5.0 2.0 t o 100

Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

6. Glass Cleaners/Polishes

49

50


A n t i f o g Compositions f o r A p p l i c a t i o n t o C l o t h

S p e c i a l w i p i n g c l o t h s impregnated w i t h A e r o s o l OT S u r f a c t a n t a r e used t o c l e a n and t o p r e v e n t f o g g i n g o f eye g l a s s e s , b i n o c u l a r s , goggles, e y e p i e c e s i n gas masks, and a u t o m o b i l e , t r a i n , p l a n e , and b o a t w i n d s h i e l d s . Such w i p i n g c l o t h s a r e p r e p a r e d by i m p r e g n a t i n g c o t t o n f l a n n e l w i t h A e r o s o l OT S u r f a c t a n t s o l u t i o n s f o l l o w e d by a r u n t h r o u g h squeeze r o l l s t o remove t h e excess 1iquor . Three s u c c e s s f u l f o r m u l a t i o n s c o n t a i n i n g A e r o s o l OT S u r f a c t a n t a t 25% s o l i d s and one f o r m u l a t i o n a t 50% s o l i d s a r e as f o l l o w s : Ingredients-1 : A e r o s o l OT-75% S u r f a c t a n t ( l b . ) V a r s o l No. 2 P e t r o l e u m S o l v e n t ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . )

25% S o l u t i o n 113 15 3 19

I n a r e d i ents-2 : A e r o s o l OT-75% S u r f a c t a n t ( l b . ) V a r s o l No. 2 P e t r o l e u m S o l v e n t ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . )

25% S o l u t i o n 113 6 6 25

In~redients-3: A e r o s o l OT-75% S u r f a c t a n t ( l b . ) V a r s o l No. 2 P e t r o l e u m S o l v e n t ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . )

25% S o l u t i o n 113

Inqredients-4: A e r o s o l OT-75% S u r f a c t a n t ( l b . ) V a r s o l No. 2 P e t r o l e u m S o l v e n t ( g a l . ) Isopropyl Alcohol ( g a l . ) Water ( g a l . )

50% S o l u t i o n

-

8 29

66 2

-

3

The s o l v e n t s and w a t e r a r e mixed a t 80F t o 1OOF. The A e r o s o l OT-75% S u r f a c t a n t i s added s l o w l y w i t h c o n t i n u e d m i x i n g . A f t e r t h e A e r o s o l OT has d i s s o l v e d , a l l s o l u t i o n s w i l l remain c l e a r and l i q u i d a t t e m p e r a t u r e s as l o w as 5OF. No scumming o f t h e s u r f a c e w i l l o c c u r because o f e v a p o r a t i o n d u r i n g a normal r u n o f c l o t h t h r o u g h t h e b a t h . The s o l u t i o n s t h a t a r e a l l o w e d t o s t a n d s h o u l d be c o v e r e d t o p r e v e n t l o s s o f s o l v e n t . The optimum amount o f A e r o s o l OT S u r f a c t a n t t o be l e f t on t h e c l o t h i s 40-50%, based on t h e w e i g h t o f t h e c l o t h . However, a range o f 25-50% w i l l g i v e s a t i s f a c t o r y r e s u l t s .

SOURCE:

Cytec I n d u s t r i e s I n c . :


Glass CleanerslPolishes 51

A n t i f o g Compositions f o r D i r e c t A p p l i c a t i o n t o Glass Aerosol OT S u r f a c t a n t i s used i n s p e c i a l f o r m u l a t i o n s t h a t are a p p l i e d d i r e c t l y t o g l a s s surfaces t o prevent fogging under adverse weather c o n d i t i o n s . Some o f these f o r m u l a t i o n s g i v e dura b l e f i l m s t h a t stand up under severe t e s t s . An example o f an excel l e n t " A n t i fog" paste i s as f o l l o w s : 10.7 l b . 2.0 l b . 2.0 l b . 85.3 l b .

Aerosol OT-75% S u r f a c t a n t Gum Tragacanth Petrolatum Water

Heat t h e water t o 18OF and add t h e Aerosol OT-75% s l o w l y w i t h mixing. S i f t i n powdered gum tragacanth. Continue m i x i n g u n t i l a l l gum i s dispersed, cool t o 105F, and add petrolatum. A p p l i c a t i o n o f A n t i f o g Paste: Dampen t h e corner of a p i e c e o f c l o t h w i t h paste and rub over e n t i r e g l a s s surface. Before f i l m becomes d r y , p o l i s h w e l l w i t h clean p o r t i o n o f th e c l o t h . A spray bomb o f A n t i f o g may be prepared as f o l l o w s :

10 p a r t s 10 p a r t s 80 p a r t s

Aerosol OT-75% S u r f a c t a n t B u t y l C e l l o s o l v e Solvent Propel 1ant

Aerosol OT S u r f a c t a n t may a l s o be c a s t i n t o s t i c k form. S o f t e n i n g agents such as g l y c e r i n e o r ethylene g l y c o l a r e i n c o r p o r a t e d t o s i m p l i f y a p p l i c a t i o n t o t h e g l a s s surface. Such s t i c k s , u s u a l l y two t o f o u r inches l o n g and one-half i n c h i n diameter, a r e s o l d i n k i t s f o r a p p l i c a t i o n t o goggles, w i ndshi e l d w i pes and bthroom m i r r o r s .

SOURCE: Cytec I n d u s t r i e s , I n c . :


52

Advonced Cleoning product FormulotiOnr

Anti-Foggina.

A n t i - S t a t i c Glass Cleaner % bv We

sht 0.0 9.0 0.1 0.5 0.4

Water, D . I . Isopropanol Adogen 66 Varox 365 Emcol 4500

Blending Procedure: Combine i n g r e d i e n t s i n t h e order shown and mix thorough Y . I f product i s hazy, a d d i t i o n a l Isopropanol can be used t o c l a r i f y t h e s o l u t i o n . Gentle h e a t i n g can be used t o f a c i l i i t a t e m i x i n g o f t h e Emcol 4500. Use I n s t r u c t i o n s : Apply f i n i s h e d product t o a t o w e l l e t e (Kimwipe, e t c . ) wipe o n t o t h e g l a s s . A l l o w t o d r y .

and

Product I n f o r m a t on : Benefit: Product: Wetting agent, degreaser. and detergent Varox 365 Adogen 66 A n t i - s t a t i c agent Wetting agent, coupler, and detergent Emcol 4500 T h i s f o r m u l a t on presents a t h i n b a r r i e r between t h e water vapor ( i . e . , fog, steam, e t c . ) and t h e g l a s s which w i l l prevent fogging. The a b i l i t y t o lower t h e s u r f a c e t e n s i o n o f t h e water prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o t h e glass; t h e r e f o r e l i g h t i s not s c a t t e r e d as much as i t i s when passing through i n d i v i d u a l d r o p l e t s . Formula 708 Annoniated Glass Cleaner % by Weight 94.0

Water W i t c o l a t e 231 0 B u t y l Cel l o s o l v e Aqua Ammonia, 26 Be'

3.0 2. 0

2.0

Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g thoroughly between each a d d i t i o n . Formula 704

SOURCE: Witco Corp.:


Glass CleanersfPolbhes 53

Glass C1eaners Ammon ia Formula GC-0017 Economical

Wt.%

94.60 0.15 5.00 0.25

Water Rhodacal DSB Butoxyethanol Ammonium Hydroxide (28%) Dye

-

Heavy-Duty

Wt.%

88.70 ~~

0.30 10.00 1 .oo

-

ProcedurQ Blend i n g r e d i e n t s i n order l i s t e d and mix u n t i l uniform. Phvsi ca 1 P r o o e r t i e s Appearance: Clear l i q u i d , dye t o preference 10.5 pH (as i s ) : pH (1%): 9.0 Specific Gravity: 0.99 Viscosity: t10 cps

10.8 9.7 0.99 t10 cps

G1ass C1 eaners Vinegar Formula GC-0018 Economical Water Rhodacal DSB Butoxyethanol Acetic Acid Dye

Heavv-Duty

Wt.%

94.85 0.15 5.00 To pH=4

-

Wt.%

89.70

0.30 10.00 To pH=4

-

ProcedurQ Blend i n g r e d i e n t s i n order l i s t e d and mix u n t i l uniform. Physical P r o o e r t i eg Appearance: Clear l i q u i d , pH (as i s ) : pH (1%): Speci f ic G r a v i t y : V i scosl t y :

dye t o preference 4.0

3.5 0.99 t 1 0 cps

SOURCE: Rhone-Poulenc S u r f a c t a n t s 6 S p e c i a l t i e r : Formulas

4.0 3.5 0.99 t 1 0 cps

54


Glassware and B o t t l e Cleaners B o t t l e Cleaner (Alkaline-Powder) % by Weiaht 2.0 20.0 5.0 8.0 65.0

Inaredients: Aerosol OT-8 S u r f a c t a n t Sodium NTA Powder Cyanamer A-100L Polyacrylamide Sodi um Metasi 1ic a t e Tetrasodium Pyrophosphate B o t t l e Cleaner (Acid-Powder)

% by Weiaht

Inaredients: Aerosol OT-0 S u r f a c t a n t NTA Acid Sodium Dihydrogen Phosphate Sodium Hydrogen S u l f a t e

2.0 20.0 58.0 20.0

B o t t l e Cleaner (A1 k a l ine-Powder) % bv Weiaht 5-1 0 1- 2 20.0 8.0 60-66

Inaredients: Aerosol 0 s S u r f a c t a n t Aerosol OT-8 S u r f a c t a n t Sodium NTA Powder Sodi um Metasi 1ic a t e Tetrasodi um Pyrophosphate B o t t l e C1 eaner ( A c i d-Li q u i d) Inaredients: Aerosol GPG S u r f a c t a n t Phosphoric A c i d (85%) NTA Acid Water

% by Weiaht 5.0 t o pH 3.0 o r l e s s 20.0 75.0

B o t t l e C1eaner (Acid-Liqui d l Inaredients: Aerosol 0 s S u r f a c t a n t NTA Acid Phosphoric Acid (85%)

Water

% bv Weight 1. 0.0 .

20.0 t o pH 3.0 o r l e s s 70.0

B o t t l e Cleaner ( H i a h l y A l k a l i n e ) Inaredi e n t s : % bv Weiaht Aerosol 0 s Surfactant 10.0 Aerosol 22 S u r f a c t a n t 2.0 Sodium NTA 20.0 Sodi um Hydroxi de ( 1 0%) 68.0 SOURCE: Cytec I n d u s t r i e s I n c . : Suggested Formulations

Glass CleanerslPolishes 55 Household Window Cleaner % by Weight

89.3 10.0 0.7

Water, D . I . Isopropanol Varox 365 Methyl ene B1ue

q.s.

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 0.2% pH: 7.4 Formula 706 Prerni urn Household W i ndow C 1eaner Water, D . I . Isopropanol Varox 1770 Methyl ene 81 ue

% by Weight 89.4 10.0 0.6 q.s.

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 0.23% pH: 6 . 2 Formula 707


56


Low VOC A n t i s t a t / C l e a n e r

f o r Glass

%w/w

Inqredient: V e r s a f 1ex 7000 Isopropanol Ammonium H y d r o x i d e (30%) Neodol 25-35 (58%) Water, F r a g r a n c e , and P r e s e r v a t i v e

1 .oo 5.00

0.50 0.15 q.s.

Procedure: 1 . D i s s o l v e V e r s a f l e x 7000 i n w a t e r . 2 . Add ammonium h y d r o x i d e and Neodol 25-35, 3. Add i s o p r o p a n o l and m i x . 4. Add f r a g r a n c e and p r e s e r v a t i v e .

SOURCE:

N a t i o n a l S t a r c h and Chemical Co.:

and m i x .

R e f e r e n c e : #8069:32

A n t i -Fog G1ass C1g a s % by W e -

I n q r e d ients:_ Water Monawet MO-70R IPA

93.0 2.0

5.0

Procedure: B l e n d i n o r d e r l i s t e d and package.

SOURCE: Mona I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n G1a s s C1eaner % by W e -

Eastman EB s o l v e n t Isopropyl alcohol Noni on ic s u r f a c t a n t * Water

3.0

5.0 0.1 91.9

*Such as T e r g i t o l 15-S-7, C l l - C 1 5 secondary a l c o h o l e t h o x y l a t e ( U n i o n C a r b i d e ) o r Genapol 24-L-60 l i n e a r a l c o h o l e t h o x y l a t e (Hoechst C e l a n e s e ) .

SOURCE:

Eastman Chemical Co.: Eastman EB and DB S o l v e n t s f o r C l e a n e r s : Suggested F o r m u l a t i o n

Glass CleaturslPolisks

57

T r a d i t i o n a l Consumer Glass Cleaner Ammoni a t e d Anionic Non-Streaki na G1ass C1eaner Inaredient : Wt.% Deionized Water 94.05 2-Butoxyethanol 5.70 Avanel S-70 0.25 C . I . D i r e c t Blue #86 Q.S. Monoethanol ami ne t o pH 10.5-11.5 pH (as i s ) : 10.5-11.5 Appearance: Clear, l i g h t - b l u e l i q u i d Odor: Sweet, e t h e r e a l Procedure: Charge under a g i t a t i o n most o f t h e water, t h e 2-butoxyethanol. and t h e Avanel S-70 i n t o t h e m i x i n g vessel. I n a separate vessel, under a g i t a t i o n , d i s s o l v e t h e dye i n t h e balance of t h e water. Add t h e dye s o l u t i o n t o t h e batch. A d j u s t p H t o 10.5-11.5 w i t h Monoethanolamine. Notes : T h i s f o r m u l a t i o n i n c o r p o r a t e s a novel a n i o n i c s u r f a c t a n t i n t o a t r a d i t i o n a l ammoniated g l a s s cleaner. On prolonged storage, g l y c o l e t h e r s have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n g l a s s cleaners. Morpholine, Ammonia, o r o t h e r v o l a t i l e amines may be used i n p l a c e o f t h e Monoethanolamine. Formula CG-101

-

Consumer Aci d G1ass C 1 eaner A c i d Anionic Non-Streaking Glass Cleaner I n s r e d ie n t : Wt.% Dei oni zed Water 89.70 2-Butoxyethanol 10.00 Avanel S-70 0.30 Color Q.S. Acetic Acid t o p H 3.5-4.0 pH (as i s ) : 3.5-4.0 Appearance: Clear 1i q u i d Odor: Sweet, e t h e r e a l Procedure: Charge under a g i t a t i o n most o f t h e water, t h e 2-butoxyethanol, and t h e Avanel S-70 i n t o t h e m i x i n g vessel. I n a separate vessel, under a g i t a t i o n , d i s s o l v e t h e dye i n t h e balance o f t h e water. Add t h e dye s o l u t i o n t o t h e batch. A d j u s t p H t o 3.5-4.0 w i t h A c e t i c Acid. Notes: T h i s f o r m u l a t i o n i s p a r t i c u l a r l y e f f e c t i v e a t removing o i l . greases and o t h e r atmospheric contaminants from g l a s s surfaces. On prolonged storage, g l y c o l e t h e r s have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n g l a s s cleaners. Dyes should be thoroughly screened f o r s h e l f s t a b i l i t y i n t h e f i n i s h e d product p r i o r t o adoption i n t o t h e f i n i s h e d f o r m u l a t i o n . Formula CG-102


7. Hard Surface Cleaners

58

Hard swface Cleaners

59

A b r a s i v e Cleaner-1 Inaredients: Hostapur SAS 60 Genapol UD-030 B Water (40-5OC) C Preservative Perfume D C a l i b r i t e SL Tests: V i s c o s i t y (mPas): pH: 1 0 , O

4.50% 5.40% 59.00% 0.10% 0.20% 30.00%

A

1700 ( B r o o k f i e l d R V T )

A b r a s i v e C1eaner-2 1n . q r e d ient s : Hostapur SAS 60 Genapol UD-030 B Water (40-50C) C Preservative Perfume D C a l i b r i t e SL

4.50% 5.40% 49.00% 0.10% 0.20% 40.00%

A

Tests: V i s c o s i t y (mPas): pH: 1 0 , O

2800 ( B r o o k f i e l d RVT)

A b r a s i v e C1eaner-3 Insredients: Hostapur SAS 60 Genapol UD-030

A

4.50% 5.40% 39.00%

B

Water (40-5OC)

C

Preservative Perfume

0.10% 0.20%

D

C a l i b r i t e SL

50.00%

Tests: V i s c o s i t y (mPas) : 6400 ( B r o o k f ie l d R V T ) pH: 1 0 , O O Manufacturing(l,2,3): I One a f t e r a n o t h e r , t h e components o f A a r e added t o 0. I1 A t 30C t h e components o f C a r e added t o I. I 1 1 A t l a s t , s t i r D to 11. A b r a s i v e powders, based on s i l i c i u m d i o x y d e a r e n o t common any l o n g e r . Modern l i q u i d p r o d u c t s a r e based on c a l c i u m carbonate. SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Agents: Guide F o r m u l a t i o n s


60 Advanced Cleaning product Forrnulaiions

Concentrated L i q u i d Household Hard-surface Cleaner P i ne O i 1 A1 1-Purpose D i l u t a b l e Concentrate Inaredient : Dei oni zed Water Macol TD-12 Macol TD-3 Mazamide 80 Macol 40 Pine O i l Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Sodium Xylene S u l f o n a t e (40%)

Wt.96 79.30 5.00 2.50 0.50 4.00 0.20

3.00 2.00 3.50

pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d Speci f ic G r a v i t y : 1 .03 Procedure: Charge t h e water t o a m i x i n g vessel and s t a r t a g i t a t i o n . Charge t h e Macol TD-12, Macol TD-3. and Macol 48 and m i x u n t i l product i s c l e a r and f r e e o f " f i s h eyes." Charge t h e Pine O i l and mix 5 minutes. Charge t h e remaining i n g r e d i e n t s and mix u n t i l clear. Notes: T h i s i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per g a l l o n . Formula CH-103 All-PurDose Household Spray Cleaner Ready t o Use A l k a l i n e Hard Surface Spray Cleaner Ineredient : Dei o n i zed Water Macol TD-12 Sodi um C i t r a t e Tetrapotassium Pyrophosphate Macol 48

Wt.96 95.15 1 .oo 0.25 0.60 3.00

pH (as i s ) : 9.5-10.5 Appearance: Clear, water-white l i q u i d S p e c i f i c G r a v i t y : 0.99 Procedure: Charge t h e water t o a m i x i n g vessel and s t a r t a g i t a t i o n . Charge t h e Macol TD-12 and mix u n t i l d i s s o l v e d and f r e e o f " f i s h eyes.'' Charge t h e remaining i n g r e d i e n t s and m i x u n t i l clear. Notes : T h i s i s an a l l - p u r p o s e household cleaner designed t o be used "as i s " from a spray b o t t l e . Formula CH-104


Hard Surface Cleaners

Consumer T i 1e C1 eaner A Hard Surface H y p o c h l o r i t e Spray Cleaner Inpredient: Dei oni zed Water Sodium Hydroxide (50%) Sodium H y p o c h l o r i t e (12.5%) Avanel S-70 pH (as i s ) : Appearance:

Wt.% 81 .OO 2.00 18.00 1 .oo

>12.5 Clear, water-white t o l i g h t - y e l l o w l i q u i d

Procedure: Charge t h e i n g r e d i e n t s w i t h a g i t a t i o n i n t h e order l i s t e d . Notes : T h i s formula i s s u i t a b l e f o r pump spray a p p l i c a t i o n . I t can be used on shower t i l e s and l i k e surfaces. S h e l f s t a b i l i t y o f c h l o r i n e cleaners i s dependent on t h e absence o f t r a c e metals. Care should be taken t o i n s u r e good q u a l i t y water and Sodium H y p o c h l o r i t e . Formula may be a d j u s t e d t o use o t h e r commercially a v a i l a b l e c o n c e n t r a t i o n s o f Sodium H y p o c h l o r i t e . Absolute c o n c e n t r a t i o n o f a v a i l a b l e c h l o r i n e i s 2.0%. Formula CC-101 I n d u s t r i a l S t r e n a t h C h l o r i n e Cleaner A Hard Surface I n d u s t r i a l S t r e n g t h H y p o c h l o r i t e Spray Cleaner Inaredient: Deionized Water Sodium Hydroxide (50%) Sodium H y p o c h l o r i t e (12.5%) Avanel S-70

Wt.Sb 56.00 3.00 40.00

1 .oo

pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d Odor: C h l o r i n e Procedure: Charge t h e i n g r e d i e n t s w i t h a g i t a t i o n i n t h e order l i s t e d . Notes : T h i s f o r m u l a t i o n can be used i n high-pressure spray washing cleaners, d i l u t e d f o r hard-surface c l e a n i n g o r used as i s f o r an enhanced consumer household bleach. S h e l f s t a b i l i t y o f c h l o r i n e cleaners i s dependent on t h e absence o f t r a c e metals. Care should be taken t o i n s u r e good qua1 it y water and Sodi um Hypochlori t e . Formula may be adjusted t o use o t h e r commercially a v a i l a b l e c o n c e n t r a t i o n s o f Sodium Hypochlorite. Absolute c o n c e n t r a t i o n of a v a i l a b l e c h l o r i n e i s 5.0%. Formula CC-102 SOURCE: Mazer Chemicals: Suggested Formulations

61

62


D-Limonene H a r d - s u r f a c e C l e a n e r s Formula HS-0093

D-Limonene Concentrate Component D-Li monene A l c o d e t HSC-1000 I g e p a l CO-720 M i r a n o l FBS Triethanolamine Water

Wt.%

All-Purpose Spray C1eaner Heavy-Duty Degreaser Type Type (1:9 D i l u t i o n ) (1:3 D i l u t i o n )

20.0

30.0 30.0 19.0 1.o

---

Wt.%

Wt.%

2.0 3.0 3.0 1.9 0.1 90.0

5.0 7.5 7.5 4.75 0.25 75.0

Procedur e A. C o n c e n t r a t e

B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i 1 uniform. B. SDrav Cleaner D i l u t e c o n c e n t r a t e 1 : 9 w i t h w a t e r or c h a r g e "Vessel A" w i t h D-Limonene, A l c o d e t HSC-1000, and t h e n I g e p a l CQ-720. M i x u n t i l u n i f o r m . Charge a s e p a r a t e "Vessel B" w i t h w a t e r , t r i e t h a n o l a m i n e and M i r a n o l FBS. M i x u n t i l u n i f o r m . F i n a l l y , add t h e c o n t e n t s o f "Vessel A" t o "Vessel B" and m i x u n t i l u n i f o r m . C.DeQreaSer D i l u t e c o n c e n t r a t e 1:3 w i t h w a t e r or b l e n d i n g r e d i e n t s i n t h e same manner as s p e c i f i e d i n t h e spray c l e a n e r procedure. Phvsi c a l P r o o e r t i es Appearance Specific Gravity Viscosity pH. as i s

SOURCE:

Rhone-Poulenc

Concentrate Clear, g o l d liquid 1.02 110 cps 10.0

S w a y Cleaner Clear, l i g h t yellow l i q u i d 1 .oo <10 cps 9.5

Surfactants & Specialtlea:

DegreaSer Clear, yellow l i q u i d 1 .oo <10 cps 9.5 Formulas


63

d ' l i a o n e n e SDrav C l e a n e r % bv Weiaht

Phase A : Water, D . I . T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous P e t r o LBA L i q u i d W i t c o n a t e AOS Phase B: DeSonic 9N W i tcami de 128T d ' L i monene*

68.0 6.0 2.0 10.0 3.0 5.0 3.0 3.0

* S u n k i s t Growers,

I n c . o r Union Camp

B l e n d i n g Procedure: B l e n d Phase A and Phase B s e p a r a t e l y . W i t h m i x e r a t h i g h speed, add Phase B t o Phase A. Use D i l u t i o n :

use as i s .

Formula 802 ~d'Lirnonene

Cleaner Concentrate % by Weiaht

Phase I: Isopropanol Oleic Acid V a r o n i c K205 d ' L i monene

10.0 8.8 5.0 12.0

Phase 11: Water, D . I . Potassium H y d r o x i d e , 87%

62.2 2.0

B l e n d i n g Procedure: Combine Phase I i n g r e d i e n t s and mix t h o r o u g h l y . Combine Phase I 1 i n g r e d i e n t s and mix t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 11. Typical Properties: V i s c o s i t y , cps: 75 S o l i d s : 13.8% pH: 10.2 Formula 808 SOURCE: W i t c o Corp.:


64 Advanced Cleaning product Formulations General Purpose Hard Surface Cleaner T h i s general purpose cleaner i s a v e r s a t i l e product. The combination o f Sandoxylate SX-408 and Sandoxylate SX-424 p r o v i d e e x c e l l e n t s u r f a c e a c t i v i t y and s o i l removal a l l o w i n g i t t o be used i n many a p p l i c a t i o n s . % bv W t

Inaredients: Water Sodi urn S i 1 ic a t e Sodium Hydroxide (20% S o l u t i o n ) B u t y l C e l l osol ve Sandoxylate SX-408 Sandoxylate SX-424 Sodium Xylene S u l f o n a t e Drimarine Turquoise XB

79.9

1 .o 0.5 0.5 5.0 11.5 1.5 0.1

Procedure: Charge vessel w i t h water. Add sodium s i l i c a t e , sodium hydroxi d e (20%), B u t y l C e l l o s o l v e , Sandoxylate SX-408. Sandoxylate SX-424, Sodium Xylene S u l f o n a t e and Drimarine Turquoise XB. Suggested Use: 4 t o 6 ounces per g a l l o n o f water.

SOURCE: Sandoz Chemical s Corp. : Formul a t i on HHG-11 A l k a l i n e Hard Surface Cleaner % by Weiaht 34.0 8.0 12.0 40.0 6.0

Water, D.I. Sodium M e t a s i l i c a t e Varami de A-83 Witconate 30DS W i t c o n a t e SXS L i q u i d

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 205 S o l i d s : 34.4% pH: 12.5

SOURCE: Wltco Corp.:

Formula 5 1 6


65

General Puroose H a r d - s u r f a c e C l e a n e r s Formula HS-0034 Solvent-Free Solvent-Free Non-Phosphate Phosphate

Heavy-Duty Sol vent

Comoonent

IYPe

Wt.%

m Wt.%

IYPS

Water Sodi um M e t a s i 1ic a t e Pentahydrate Rhodasurf 91-6 Cheelox BF-13 M i r a n o l FBS Rhodaf ac RA-600 Butoxyethanol

83.5

85.5

83.0

2.0 7.5 3.0 4.0

2.0 7.5 3.0

-

Wt.% I

.o

6.0 2.0 2.0

-

-

2.0

-

6.0

Procedure B l e n d i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m . Phvsi c a l P r o o e r t i 8s Appearance Specific Gravity Viscosity pH, as i s

C1 e a r , It. yellow 1.035
C1e a r , water-white 1.012
C1e a r , water-white 0.994
U n b u i l t . Hiah-Sudsina. H a r d - s u r f a c e C l e a n e r Formula HS-0036

W% .t 79.7 5.3 3.0 5.5

Comoonent Water C a l s o f t F-90 M i r a n o l FBS Sodi um S i 1i c a t e I g e p a l CO-710 A1 kami de DC-212/S M-Pyrol, N - m e t h y l - 2 - p y r r o l i d o n e

1 .o 2.0 3.5

Procedure 81 end i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l u n i f o r m .

TvDi c a l P r o D e r t i 88 Appearance: C1e a r , ye1 1ow 1iq u i d V i s c o s i t y : t 1 0 cps pH, as i s : 9.85 S p e c i f i c G r a v i t y : 1.07

SOURCE:

Rhone-Poulenc S u r f a c t a n t s h S p e c i a l t i e s :

Formulas

66


Hard-surface Cleaner P e r c e n t b y Wei q h t Inqredient: 4.0 L i q u i d C i t r i c Acid-50% (Haarman & Rei mer C o r p l - j 2.5 Sodium h y d r o x i d e s o l u t i o n 50% 0.0 N o n i o n i c s u r f a c t a n t (Neodol 25-9) 7.0 Methyl C a r b i t o l solvent 5.0 Sodi um x y l ene s u l f o n a t e 3.0 Sodium c a r b o n a t e 0.3 Pine o i 1 70.2 Water M i x t h e L i q u i d C i t r i c Acid-50% s o l u t i o n w i t h an e q u a l volume o f w a t e r and n e u t r a l i z e b y a d d i n g sodium h y d r o x i d e . The n e u t r a l i z a t i o n r e a c t i o n s h o u l d be done s l o w l y and c a u t i o u s l y u n d e r a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exothermic. Blend t h e neutr a l i z e d s o l u t i o n w i t h t h e nonionic s u r f a c t a n t , Methyl C a r b i t o l , sodium x y l e n e s u l f o n a t e and sodium c a r b o n a t e . Add p i n e o i l l a s t . Mn-Abrasive Cleanser P e r c e n t b y Wet q h t -~ 6.0 L i q u i d C i t r i c Acid-50% (Haarman & Reimer Corp. ) 3.7 Sodium h y d r o x i d e s o l u t i o n 50% 25.0 Xanthan gum 2.5 V e g e t a b l e gum (Veegum HS) 3.0 Amphoteric s u r f a c t a n t 1.5 Noni o n i c s u r f a c t a n t 45.0 C a l c i u m c a r b o n a t e (100 mesh) 13.3 Water

I n g r ed ien t :

P r e p a r e a 1% s o l u t i o n o f x a n t h a n gum w i t h t h e i n c l u s i o n o f a p r e s e r v a t i v e . S l o w l y add t h e v e g e t a b l e gum t o w a t e r and s t i r u n t i l t h o r o u g h l y h y d r a t e d . Add t h e c a l c i u m c a r b o n a t e , f o l l o w e d by t h e a m p h o t e r i c s u r f a c t a n t , t h e n o n i o n i c s u r f a c t a n t and t h e x a n t h a n gum s o l u t i o n . SOURCE: Haarman 8, Reimer C o r p . : Hard-Surf

Suggested F o r m u l a t i o n s ace C l e a n e r

Yo b y W t . 7.0 1 .o 1.25 2.0 00.75

Eastman DB s o l v e n t Anionic surfactant* Na4 EDTA* Ammoni um h y d r o x i d e (28%) Water

*

*Such a s Rhodapex CO-433 (Rhone-Poulenc) * * T e t r a s o d i u m ethylenediaminetetracetate (39%) SOURCE: Eastman Chemical Co.:



67

Hard-surface Cleaner A l l - S u r f a c e Bathroom A c i d Type Formula BC-0005

3

>W

4.0

M-Pyrol, N-Methyl-2-Pyrrolidone (ISP) I g e p a l CO-630 Hydroxyethylcel l u l o s e Phosphori c A c i d Water Perfume and c o l o r a n t s may be added.

1

.o

0.2 9.5 85.3

Procedure 1 D i sperse hydroxyethylcel 1u l o s e i n water. 2. I n a separate vessel, mix M-pyrol, Igepal CO-630 t o g e t h e r . Add hydroxyethylcellulose/water m i x t u r e . 3 . Add a c i d and mix thoroughly.

.

Phvsi c a l P r w e r t i gg pH (as i s ) : 2.0 pH (1%): 2.4 V i s c o s i t y : 30 cps Speci f ic G r a v i t y : 1 .02 --Surface Cleaner A l l - S u r f a c e Bathroom Type Formula BC-0006

Wt.% Water I gepal CO-630 Cheel ox NTA-Na3 Sodi um Xylene Sul f o n a t e Sodi um Hydroxide Perfume and c o l o r a n t s added, as desired,

70.5 2.5 20.0 5.5

1.5 r e p l a c i n g water.

Procedure 1 . D i s s o l v e I g e p a l CO-630 i n water. Add Cheelox NTA-Na3. 2 . Add sodium-xylene s u l f o n a t e and sodium hydroxide, m i x i n g w e l l a f t e r each a d d i t i o n .

Physical P r w e r t i e s pH, as i s : 12.9 pH (1%): 1 1 . 4 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.05

SOURCE: Rhone-Poulenc S u r f a c t a n t s 6 S p e c i a l t i e s :

Formulas

68

Advanced Cleaning Product Formulotiotu

Hard S u r f a c e C l e a n e r s Calsuds, C a l s o f t and Calamide c o n c e n t r a t e s can be f o r m u l a t e d t o c r e a t e p o w e r f u l , non-corrosive, n o n - f i l m i n g c l e a n e r s f o r f l o o r s , woodwork, w a l l s , windows, c o u n t e r t o p s , t u b s , t i l e and s i m i l a r h a r d s u r f a c e s . Use l e v e l s : 1-4 o z . / g a l o f w a t e r . F l o o r Cleaner Products P i 1o t Formula #HSC-003-01 % b y Weiaht 81 .OO 10.00 4.00 2.00 3.00

Water Na4EDTA C a l s o f t F-90 Cal o x y l a t e N-9 Butyl Cellosolve P i l o t Formula #HDC-003-01

% bv Weight 5.00 7.80 10.00 77.20

Calsuds 81 TKPP P i l o t SXS-40 Water

Rua C l e a n e r P i l o t Formula #CPT-003-01 % by Weiqht 40.09 4.04 20.11 35.76

Cal foam SLS-30 Calamide C P r o p y l ene G1y c o l Water P l a s t i c , V i n y l and L e a t h e r Cleaner P i l o t Formula #UPC-001-01 C a l o x y l a t e N-9 Dowanol D (PnB) P r o p y l ene G1y c o l Butyl Cellosolve Water SOURCE:

by Weight 10.10 5.02 2.56 1.13 81.19

P i l o t Chemical Co. : Household C1eaner Formu a t ions


69

Hard S u r f a c e C l e a n e r s C a l s u d s , C a l s o f t and Calamide c o n c e n t r a t e s can be f o r m u l a t e d t o c r e a t e powerful, non-corrosive, non- f i l m i n g c l e a n e r s f o r f l o o r s , woodwork, w a l l s , windows, c o u n t e r t o p s , t u b s , t i l e and s i m i l a r h a r d s u r f a c e s . Use l e v e l s : 1 - 4 o z . / g a l . o f w a t e r . Tub and T i l e C l e a n e r s P i l o t Formula #APC-004-01 % bv Weiqht 65.00 1 .oo 25.00 5.00 3.00 1 .oo

Water Versene 100 Calsuds A I s o p r o p y l Alcohol P r o p y l ene G1 y c o l Pine O i 1 P i 1o t Formula #HDC-006-01

?&by D-1 imonene Cal i m u l se PRS C a l o x y l a t e N-9 Water C a l s o f t L-40 P i l o t sxs-40 Calamide 0

Wei a h t 30.00 5.00 5.00 26.50 16.50 10.00 7.00

Counter Top/Wall C l e a n e r s P i l o t Formula #HDC-003-01 A l l Purpose Type % b y Weight

77.20 7.80 5.00 10.00

Water TKPP Calsuds 81 P i l o t sxs-40 P i l o t Formula #HSC-008-01 Ammoniated -T Water Ammonia (29%) Na4EDTA B u t y l C e l l o s o l ve Calsuds 81

% by Weiaht 86.50

SOURCE: P i lot Chemical Con: Household C1 eaner F o r m u l a t i o n s

3.00 0.50 5.00 5.00

70


Hard Surface Cleaner w/AmDhoteric % by Weinht 75.0

Water, 0.1. Sodium Carbonate Rewoteric AM KSF-40 Oowanol DPM Versene 100 Witconate SXS (40%)

4.0 10.0 5.0 2.0 4.0

Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e completely between each a d d i t i o n . Typi c a l Propert ies : V i s c o s i t y , cps: 4 S o l i d s : 10.2% pH: 10.8 Formula 507 Hard Surface Cleaner Concentrate w/d'Lilnonene % by Weiciht Phase I: Isopropanol O l e i c Acid Varonic K205 d ' L i monene Phase 11: Water, 0.1. Potassium Hydroxide (87%)

10.0 8.8 5.0 12.0 62.2 2.0

B1endi ng Procedure : Combine Phase I i n g r e d i e n t s and mix thoroughly. Combine Phase I 1 i n g r e d i e n t s and mix thoroughly. While mixing, add Phase I t o Phase 11. Typical Properties: V i s c o s i t y , cps: 75 S o l i d s : 13.8% pn: 10.2 Formula 508



Hard Swface Cleaners

71

Hard-surface Cleaner Concentrate A l k a l i n e All-Purpose Cleaner Concentrate Inaredient : Deionized Water Sodium Hydroxide (50%) Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Avanel S-150 Sodium Cumene S u l f o n a t e (40%)

W% .t

76.00 2.00 12.00 1 .oo 6.00 3.00

pH (as i s ) : 10.5-11.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.13 Procedure: Charge t h e water t o an a p p r o p r i a t e m i x i n g vessel and s t a r t a a i t a t i o n . I n t h e sequence l i s t e d above, charge t h e remaining i n g r e d i e n t s and mix u n t i l t h e s o l u t i o n i s c l e a r . Notes : T h i s i s a hard-surface cleaner concentrate which i s e f f e c t i ve on many d i f f e r e n t s o i l s and surfaces. For concrete s u r aces, use "as i s . " For w a l l s , f l o o r s , and o t h e r surfaces, d i u t e 1O:l w i t h water. Formula CH-101 Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge o r Spray Apt I ic a t ion Inaredient : Deionized Water Sodium Laureth ( 3 ) S u l f a t e Mazamide 00 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Macol 40 Deionized Water, Dye, e t c .

Wt.% 80.00 2.50 0.50 1 .oo 2.00 4.00 Q.S.

pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d ( w i t h o u t dye) S p e c i f i c G r a v i t y : 1.01 Procedure: Charge t h e f i r s t p o r t i o n o f water t o a m i x i n g vessel and s t a r t a g i t a t i o n . I f product i s t o be colored, d i s s o l v e dye i n t h e reserved p o r t i o n o f t h e water i n a separate vessel. Charge a l l remaining i n g r e d i e n t s , i n c l u d i n g t h e dye s o l u t i o n , t o t h e m i x i n g vessel and mix u n t i l c l e a r . Notes : T h i s f o r m u l a t i o n i s designed as a general purpose household cleaner. The product may be used w i t h a sponge o r may be used i n a spray b o t t l e . Formula CH-102


72


Hiah-Performance. Hard-surface Cleaners Formula HS-0035 Solvent-Free Solvent-Free Non-Phosphate Phosphate

Heavy-Duty Solvent

Component

IYPe Wt.%

Wt.%

IYIzz

TYDe Wt.%

Water Sodi um Metasi 1ic a t e Pentahydrate Miranol FBS A1codet HSC-1 000 Cheelox BF-13 Rhodafac RA-600 Butoxyethanol 6.0

88.0

87.0

85.0

2.0 3.0

2.0

4.0 3.0

4.0 3.0 3.0

2.0 2.0 3.0 2 .0

-

1.o

-

-

Procedur e Blend i n g r e d i e n t s i n o r d e r l i s t e d and mix u n t i l uniform. Physical P r o D e r t i e s Appearance pH, as i s Viscosity Speci f ic G r a v i t y

Clear, l i g h t y e l l o w l i q u i d 12.6 11.5 12.55
Econoai c a l P i ne O i 1 Hard-surface C 1 eaner Formula HS-0037 Component Pine O i l Rhodasurf 0C-840 Water

Wt.% 5.0 10.0 85.0

Procedur e 1 . Add Rhodasurf BC-840 t o p i n e o i l . Mix w e l l . Heat t o approxi m a t e l y 35-40C t o o b t a i n homogeneous s o l u t i o n . 2. Add water and mix thoroughly. Physical P r o o e r t i e s Appearance: Clear, water-white l i q u i d pH. as i s : 3.08 S p e c i f i c G r a v i t y : 0.99 V i s c o s i t y : <10 cps



73

M i l d A b r a s i v e Hard S u r f a c e Cleaner A m i l d a b r a s i v e c l e a n e r f o r consumer use. E f f e c t i v e on S t a i n l e s s S t e e l , P o r c e l a i n and o t h e r h a r d s u r f a c e s . Part: A

B

Inqredients: Dei o n i zed Water C a l c i t e ( t 1 0 0 mesh) Mazox LDA P o t a s s i um C i t r a t e

W% .t 30.00 50.00 6.70 1 .oo

3.30 9.00

C a l s o f t F-90 D e i o n i z e d Water

Appearance: W h i t e p a s t y 1iq u i d p H (as i s ) : 7.0-8.0 S p e c i f i c G r a v i t y : 1.47 Procedure: To a m i x i n g v e s s e l w i t h sweep and s c r a p e ype a g i t a t i o n , c h a r g e t h e w a t e r and s t a r t a g i t a t i o n . Do n o t m i x a i r i n t o t h e p r o d u c t . S l o w l y add t h e C a l c i t e f o l owed by t h e Mazox LDA and t h e Potassium C i t r a t e . I n a s e p a r a t e v e s s e l , d i s s o l v e t h e C a l s o f t F-90 i n t h e r e m a i n i n g w a t e r . When c o m p l e t e l y d i s s o l v e d , add t h e f i r s t p a r t o f t h e m i x . A g a i n a v o i d m i x i n g excess a i r i n t o t h e system. Notes : T h i s f o r m u l a t i o n i s d e s i g n e d t o be used as i s b y t h e consumer. I t i s a m i l d abrasive hard surface cleaner e f f e c t i v e a g a i n s t mast common s o i l s . I t can be used on s t a i n l e s s s t e e l , p o r c e l a i n and o t h e r h a r d s u r f a c e s . I n t h e m a n u f a c t u r e o f t h i s p r o d u c t , c a r e s h o u l d be t a k e n t o a v o i d m i x i n g a i r i n t o t h e f i n i s h e d p r o d u c t . Being a p a s t y l i q u i d , once a i r i s e n t r a i n e d i n t o t h e system, i t i s d i f f i c u l t and t i m e consuming t o remove.

SOURCE:

Mazer Chemicals:

F o r m u l a t i o n CH-109

74


Non-Phosphate Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge o r Spray A p p l i c a t i o n I n a r e d i ent : INt.% Dei o n i zed Water 79.75 Sodi um Laureth S u l f a t e 2.50 0.50 Mazamide 80 1.25 Sodi um C i t r a t e Sodium M e t a s i l i c a t e Pentahydrate 2.00 Macol 40 4.00 a.s. Deionized Water, Dye, e t c . pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d ( w i t h o u t dye) S p e c i f i c G r a v i t y : 1. O l Procedure: Charge t h e f i r s t p o r t i o n o f water t o a m i x i n g vessel and s t a r t a g i t a t i o n . I f product i s t o be colored, add t h e dye t o reserved p o r t i o n o f t h e water i n a separate vessel. Charge a l l remaining i n g r e d i e n t s , i n c l u d i n g t h e dye s o l u t i o n , t o t h e m i x i n g vessel and mix u n t i l c l e a r . Notes : T h i s f o r m u l a t i o n i s a non-phosphate v e r s i o n o f f o r m u l a t i o n CH-102. T h i s f o r m u l a t i o n i s designed as a general purpose household c l e a n e r . The product may be used w i t h a sponge o r may be used i n a spray vessel. Formula CH-106 Won-Phosphate Concentrated Household Hard-surface Cleaner Concentrated Pine O i l All-Purpose Cleaner Wt.% I n q r e d i ent : Dei oni zed Water 78.05 Macol TD-12 5.00 Macol TD-3 2.50 Mazamide 00 0.50 4.50 Macol 40 Pine O i 1 0.20 3.75 Sodi um C i t r a t e Sodium M e t a s i l i c a t e Pentahydrate 2.00 3.50 Sodium Xylene S u l f o n a t e (40%) pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.02 Procedure: Charge t h e water t o a m i x i n g vessel and s t a r t a g i t a t i o n . Charge t h e Macol TD-12, Macol TD-3, Mazamide 80 and Macol 48 and c o n t i n u e a g i t a t i o n . Charge t h e Pine O i l and mix 5 minutes. Charge t h e remaining i n g r e d i e n t s and mix u n t i l c l e a r and f r e e o f " f ish eyes. I' Notes : T h i s f o r m u l a t i o n i s a non-phosphate v e r s i o n o f f o r m u l a t i o n CH-103. T h i s i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per g a l l o n . Formula CH-107



75

Pine O i l Cleaner Concentrate % by W t .

I n g r e d i en.Lsl P i n e 01 I N i n o l 11-CM Makon 1 2 Ammonyx LO B i o - S o f t S-100 Isopropanol Water, D.I. ~~

20.0 9.0 5.0 0.5 2.0 10.0 53.5

M i x i n g Procedure: Combine p i n e o i l , s u r f a c t a n t s and I P A . M i x u n t i l c l e a r . Add water s l o w l y w h i l e under a g i t a t i o n . Mix u n t i l c l e a r . Properties: Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y C 25C, c p s : 50 pH ( a s i s ) : 8 . 1 Density lbs/gal: 8.06 Freeze/Thaw ( 3 c y c l e s ) : Pass 50C oven ( 1 week): Pass Use I n s t r u c t i o n s : D i l u t e 1 - 2 ozs i n t o one g a l l o n Performance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Above f o r m u l a t i o n : 7 3 . 0 % s o i l removed f r o m t i l e s Commercial p r o d u c t : 55.5% s o i l removed f r o m t i l e s SOURCE: S t e p a n Co.:

F o r m u l a t i o n No. 208 L i q u i d Super C o n c e n t r a t e

Water, D . I . T e t r a p o t a s s i u m P y r o p h o s p h a t e (60%) Butyl Cellosolve W i t c o n a t e SXS L i q u i d Varamide A-83

%_by Wei ght 30.0 25.0

5.0 10.0 30.0

Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each add1 t ion. Typical Properties: S o l i d s : 49.0%

SOURCE: W i t c o Corp. : F o r m u l a 502

8. Laundry Products

76

Laundry Products

77

Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0042

Wt.% Water C a l s o f t F-90 Rhodasurf 25-7 Rhodacal A-246/L Sodi um C i t r a t e Brightener Fragrance Dye

63 5 7 15 10 Q.S. Q.S. Q.S.

Procedur g Heat water t o 60C. Add Rhodasurf 25-7 s l o w l y , w i t h moderate a g i t a t i o n . Then, add Rhodasurf A-246/L and C a l s o f t F-90. Begin c o o l i n g and add remaining i n g r e d i e n t s s i n g l y , w i t h a g i t a t i o n t o o b t a i n u n i f o r m mixture, b e f o r e making n e x t addition. Phveical ProDert 1 ea Appearance: C1 ear 1iquid, dyed t o preference pH. as i s : 7 . 4 S p e c i f i c G r a v i t y : 1.09 V i s c o s i t y : 200 cps Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0043 Part A Water Na C i t r a t e C a l s o f t F-90

l!artJ!

Rhodasurf 25-7 MEA

sxs

30.0 8.0 17.0

8.0 2.0 6.0

Part C Colorant 0.02-1 Perfume 0.1-0.5 Water Q.S. Procedur g D i s s o l v e Sodi um C i t r a t e i n water by s t i r r i n g a t 45-50C and add C a l s o f t F-90. Mix P a r t llgll i n t h e order l i s t e d . Add "A" t o "B" Add c o l o r a n t , perfume and water. A d j u s t pH t o 11.0.

.

Phvsf ca 1 P r o o e r t i e s pH: 11.0 pH (1% S o l u t i o n ) : 9.50 S p e c i f i c G r a v i t y : 1.120 V i s c o s i t y : 75 cps

SOURCE: Rhone-Poulenc S u r f a c t a n t s 6 S p e c i a l t i e s : Formulas

78


Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0044

Wt.%

Part A Water Na C i t r a t e C a l s o f t F-90

30.0 8.0 17.0

Part B

8.0

Rhodasurf 25-7 MEA

2.0

sxs

6.0

Part C Colorant Perfume Water

0.02-1 0.1- 0.5 Q.S.

Procedure D i s s o l v e sodium c i t r a t e i n water by s t i r r i n g a t 45C-5OC. add C a l s o f t F-90. Mix P a r t " B " i n t h e order l i s t e d . Add "A" "8" Add c o l o r a n t , perfume and water. Adjust pH t o 11.0.

.

to

Nonionic/Amphoteric Heavy-Duty Laundry L i q u i d Formula LY-0045 W% .t

Water G1ycosi des Miranol FBS MEA Colorant ' P e r f ume

Q.S. 20.0 7.0 2.0

0.02-1 0.1 -0.5

Procedure Add t h e i n g r e d i e n t s i n t h e order l i s t e d . M i x w e l l a f t e r each a d d i t i o n . Adjust pH t o 11.0. Phvsi c a l P r o m r t ieg pH: 11.0 pH (1% S o l u t i o n ) : 9.50 S p e c i f i c G r a v i t y : 1 .lo0 V i s c o s i t y : 300 cps


Laundry Products

79

Cold Water Deterpent JFor W o o l and D e l i c a t e F a b r i c s ) Formula LY-0040

Wt.% Water Miranol CS Conc. Rhodapex ES-2 A1 kami de DC-212 Fluorescent Whitening Agent

55.9 10.0

30.0 4.0 0.1

Procedur Q Add i n g r e d i e n t s i n order l i s t e d . Heat t o 50C and mix u n t i l clear. Phvsi c a l P r o n e r t i 8s Appearance: Clear, y e l l o w l i q u i d pH. as i s : 8.16 S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y : 700 cps

F i ne F a b r i c Deterpent Formula LY-0041 Rhodacal DS-10 Sodium Hexametaphosphate Sodium Bicarbonate Optical Brightener

Wt.% 32.0 30.0 38.0 P.S.

Procedure Add t h e sodium bicarbonate and t h e sodium hexametaphosphate t o t h e blender. Mix f i v e minutes. Add t h e Rhodacal DS-10 w i t h mixing. Add t h e o p t i c a l b r i g h t e n e r w i t h mixing. Mix u n t i l uniform. Phvaical Prooert i e s Appearance: White, f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 8 . 5


Formulas

80


Deteraent f o r Colored Fabrics.

Powder, Spray M i x i n Q Process-A %

Spray M i x : M a r l i p a l 24/939 o r 013/939 Fragrance Optical brightener

10.0 0.2 0.2

Builder Mix: Zeolite A Sodium m e t a s i l i c a t e p e n t a h y d r i t e Sodium c a r b o n a t e , d e h y d r a t e d Carboxymethyl c e l l u l o s e P o l y c a r b o x y l a t e , e . g . Sokalan CP 5 powder Sodi um s u l p h a t e 1 ig h t

35.0 5.0 15.0 2.0 4.0 t o 100

A c t i v e m a t t e r : 9.0% Detergent f o r Colored Fabrics,

Powder,

% 2.0 4.0 0.2 0.2

Spray M i x : M a r l i p a l 24/30 M a r l ip a l 24/90 Fragrance Optical brightener Builder Mix: M a r l o n ARL Zeolite A Sodium soap powder Sodium m e t a s i l i c a t e p e n t a h y d r a t e Sodium c a r b o n a t e , d e h y d r a t e d P o l y c a r b o x y l a t e , e . g . Sokalan CP 5 powder P o l y v i n y l p y r r o l i d o n e , e . g . Sokalan HP 50 Sodium s u l p h a t e l i g h t Active matter:

Spray M j x i n ~Pro_cess-B

10.0 40.0 4.0 5.0 15.0 4.0 2.0 t o 100

14.0%


Laundry Products

81

D e t e r g e n t f o r C u r t a i n s , Medium V i s c o s i t v - A

% M a r l i n a t DFK 30 M a r l ip a l 24/70 Coconut f a t t y a c i d , p o t a s s i u m s a l t E t h y l e n e d i ami ne t e t r a a c e t a t e 40 Balance w a t e r , f r a g r a n c e , d y e s t u f f , p r e s e r v a t ive

20.0 15.0 5.0 0.2 o p t i c a l brightener, t o 100

A c t i v e m a t t e r : 26.0% D e t e r g e n t f o r C u r t a i n s , Medium V i s c o s i t v - 8 M a r l o n PS 65 M a r l o x M 606/1 E t h y l e n e d i a m i n e t e t r a a c e t a t e 40 Balance w a t e r , f r a g r a n c e , d y e s t u f f , preservative

%

10.0 15.0 0.2 o p t i c a l brightener, t o 100

A c t i v e m a t t e r : 20.7% Manual -Wash D e t e r g e n t , F o a m i n g Medi um V i s c o s i t y - A M a r l o n PS 65 M a r l i p a l 013/70 Marlamid DF 1218 Na cumene s u l p h o n a t e , 40% Ethanol Balance w a t e r , f r a g r a n c e , d y e s t u f f , sodium c h l o r i d e

%

10.0 15.0 2.5

1

*

.o

1.5 preservative, t o 100

A c t i v e m a t t e r : 24.0% Manual-Wash D e t e r g e n t . M a r l o n A 365 M a r l in a t 242/28 Balance w a t e r , f r a g r a n c e , sodium c h l o r i d e Active matter:

F o a m i n g Medium V i s c o s i t y - B

%

18.5 12.0 dyestuff,


15.3%


82


Detergent f o r F i n e Fabrics-1 Liquid I n redients: i?Fatty a c i d (Cocos + O l e i n . KOH (85%) H20 (40-50C)

P r i f a c 7976)

3.00% 0.60% 41.90%

B

Hostapur SAS 60 Genapol ZRO l i q u i d Genapol UD-080

23.30% 25.00% 6.00%

C

C i t r i c a c i d x 1H20

0.20%

Manufacturing: I One a f t e r a n o t h e r , t h e components o f B a r e added t o A . I 1 A t l a s t C i s added. Deteraent f o r F i n e Fabrics-2 mredients: Fatty acid

A

(Cocos + O l e i n ,

P r i f a c 7976)

4.00% 0.80%

KOH (85%)

H20 (40-5OC)

63.00%

8

Hostapur SAS 60 Genapol UO-080

a. 00% 24.00%

C

C i t r i c a c i d x 1H20

0.20%

Manufacturing: I One a f t e r a n o t h e r , t h e components o f B a r e added t o A . I 1 A t l a s t C i s added.

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Agents:

Guide F o r m u l a t i o n s


Laundry Products

83

Enzymatic Heavy-Duty Laundry D e t e r a e n t Formula LY-0046

Part A

Wt.%

Water Citrate C a l s o f t F-90

10.0 5.0 8.0

Part Rhodasurf 25-7 M EA TEA

6.0 2.0 2.0 3.0

Rhodapex NA 61 Part C Na Formate Calcium C h l o r i d e Enzymes Colorant Perfume Water

8.0

sxs

1.2 0.2 0.4 0.02-1 0.1 - 0 . 8

Q.S.

Procedure D i s s o l v e sodium c i t r a t e i n w a t e r b y s t i r r i n g a t 45-5OC. add C a l s o f t F-90. M i x P a r t "B" i n t h e o r e r l i s t e d . Add "A" t o " B " . Add sodium f o r m a t e and c a l c i u m chlOP e. Cool t o room tempera t u r e . Add t h e enzymes. Add c o l o r a a t , perfume and w a t e r . A d j u s t pH t o 10.0. Phvsi c a l P r o o e r t i pH: 10.0 pH (1% S o l u t i o n ) : 8.8 Speci f ic G r a v i t y : 1 . l o 0 V i s c o s i t y : 100 cps

&

Won-Phosphate Laundry Powder Formula LY-0048

Wt.% Sodium Carbonate I g e p a l CO-630 Sodi um S i 1ic a t e Sodium S u l f a t e Carboxymethyl c e l l u l ose Optical Brightener

50.0

12.0 12.0 24.5 1 .o 0.5

Procedur g Add t h e sodium c a r b o n a t e t o t h e m i x e r . Spray t h e I g e p a l 02-630 o n t o t h e sodium c a r b o n a t e . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . M i x u n t i l a homogeneous, f r e e - f l o w i n g product r e s u l t s . Phvsi c a l P r o m r t 1os Appearance: White, f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 11.0

SOURCE: Rhone-Poulrnc S u r f a c t a n t a & S p e c i a l t i e s : Formulas

84


F a b r i c Pretreatment S p r i t z Ingredients: Neodol 25-7 Neodol 25-3 V e r s a f l e x 207 (25%) Sodium Xylene S u l f o n a t e (40%) EDTA, Disodium S a l t Water, Dye, Perfume, and Enzymes

9.75 5.25 20.00 15.00 0.50

4.s.

Procedure: 1. Mix m e l t e d Neodol 25-7 and Neodol 25-3. 2 . Add sodium x y l e n e s u l f o n a t e and mix. 3. Add water and V e r s a f l e x 207, mix, and c o o l . 4. Add EDTA. dye, perfume, and enzymes. Reference #8069:21 Low VOC Pump F a b r i c Antist%%.

Insredients: Versaf 1ex 2004 (30%) Ethanol P r o p y l ene G1y c o l P r e s e r v a t i v e , Water, and Fragrance

5.00 10.00 0.50 Q.S.

Procedure: 1. M i x V e r s a f l e x 2004 and water. 2. Add e t h a n o l and mix. 3. Add p r o p y l ene g l y c o l , p r e s e r v a t i v e , and f r a g r a n c e .

and mix.

Reference #8069:97

SOURCE:

N a t i o n a l S t r a c h and Chemical Corp.: tions

Suggested Formula-

Laundrv P r e - S p o t t e r and S t a i n Remover % by Weiaht

83.0

Water Sodium Meta S i l i c a t e (Anhydrous) Detergent Concentrate 840 Procedure: Blend i n g r e d i e n t s i n o r d e r l i s t e d . Add c o l o r , p r e s e r v a t i v e as r e q u i r e d . SOURCE: Mona I n d u s t r i e s ,

Inc.:

2.0 15.0 f r a g r a n c e and


Laundry Products

85

F a b r i c Softener-1 Ingredients: H20 (50-6OC)

ad 100.00%

B

Prapagen WK

6.70%

C

MgC12 (10% b . w . )

0.10%

D

Perfume Dye

0.20%

A

q.s.

F a b r i c Softener-2 Ingredients: Genamin S-250 H3P04 ( 1 M; 9 , 5 % b . w . ) H 2 0 (50-60C)

2.00% 1.00% ad 100.00%

A

17.30%

8

Prapagen WK

C

MgClP (10% b . w . )

3.00%

D

Perfume Dye

0.60% Q.S.

F a b r i c Softener-3 Inqredients: Genamin 5 - 2 5 0 H3P04 ( 1 M; 9 , 5 % b . w . ) H20 (50-6OC)

0.90% 0.45% ad 100.00%

A

8

13.80%

Prapagen WK P o l y g l y k o l 400

3.70%

C

MgClZ (10% b . w . 1

1 .OO%

0

Perfume Dye

0.60% q.s.

Manufacturing: I One a f t e r a n o t h e r , t h e components o f B a r e added t o A. I 1 A t 40C, a d j u s t t h e v i s c o s i t y w i t h C ( c a . 100-150 mPas). I11 A t 30C the-components o f D a r e added. Appl ic a t ion : 1.0-2.0 g active ingredient/kg t e x t i l e


D e t e r g e n t s and C e a n i ng

86

Advanced Cleaning Product Formulatiom

F a b r i c Softener. M a r l o s o f t IQ 90 Balance water, fragrance,

Low V i scosi tv-A

%

5.6 t o 100

dyestuff

A c t i v e m a t t e r : 5.0% F a b r i c Softener.

Low V i scosi ty-B

%

M a r l o s o f t IQ 90 Balance water, fragrance, d y e s t u f f A c t i v e matter:

8.3 t o 100

7.5%

F a b r i c Softener Concentrate.

Low Viscosity-A

%

M a r l o s o f t IQ 90 Calcium c h l o r i d e , 25% (approx.) Balance water, fragrance, d y e s t u f f

11.1 0.1 t o 100

A c t i v e m a t t e r : 10.0% Formulation A : double concentrate F a b r i c Softener Concentrate. M a r l o s o f t IQ 90 Calcium c h l o r i d e , 25% (approx.) Balance water, fragrance, d y e s t u f f

Low V i s c o s i t y - B

%

16.7 1.1 t o 100

A c t i v e matter: 15.0% Formulation 8: t r i p l e concentrate

SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

Laundry Products

Heavy-dutv D e t e r g e n t , Powder, Spray M i x : M a r l i p a l 24/70 o r 013/70 Optical brightener Ethylenediamine t e t r a a c e t a t e . Fragrance

87

SDrav Y i x i n a Process-A

%

4.0 0.2 0.8 0.2

40%

Builder Mix: M a r l o n ARL Sodium soap powder Zeolite A Sodium m e t a s i l i c a t e p e n t a h y d r a t e Sodium p e r b o r a t e t e t r a h y d r a t e T e t r a a c e t y l e t h y l e n e d i ami ne (TAED) Sodium c a r b o n a t e P o l y c a r b o x y l a t e , e . g . Sokalan CP 5 powder Carboxymethyl c e l l u l o s e Sodium s u l p h a t e l i g h t , enzymes

8.0 2.8 25.0 5.0 20.0 3.0 10.0 4.0 1.o t o 100

A c t i v e m a t t e r : 13.2% Heavy-Duty D e t e r g e n t . Powder, Soray M i x i n g Process-8 Spray Mix: M a r l i p a l 24/70 o r 013/70 Optical brightener Ethylenediamine t e t r a a c e t a t e , Fragrance

%

40%

B u i l d e r Mix: M a r l o n ARL Sodium soap powder Sodium t r i polyphosphate Sodium d i s i l i c a t e Sodi um p e r b o r a t e t e t r a h y d r a t e Tetraacetyethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium s u l p h a t e l i g h t , enzymes

4.0 0.2 0.8 0.2

8.0

3.0 30.0 9.0 20.0 3.0 1.o t o 100

A c t i v e m a t t e r : 13.4% SOURCE: H u l s America, I n c . : B a s i c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents f o r Household Purposes

88 Advanced Cleaning Roduct Formulations

Heavy-Duty Deteraent. Powder. Sprav M i x i n g Process-A Spray Mix: M a r l i p a l 013/939 o r 24/939 Fragrance Ethylenediamine t e t r a a c e t a t e . Optical brightener

E!

10.0 0.2 1 .o 0.2

40%

B u i l d e r Mix: Zeolite A Sodium m e t a s i l i c a t e pentahydrate Magnesi um s i lic a t e Sodium p e r b o r a t e t e t r a h y d r a t e T e t r a a c e t y l e t h y l e n e d i ami ne (TAED) Sodi um carbonate Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes

30.0 5.0 1 .o 25.0

3.0 15.0 1.5 t o 100

A c t i v e m a t t e r : 9.0% Heavy-Duty Deteraent. Powder. Sprav M i x i n g Process-8

E!

Spray Mix: M a r l i p a l 013/939 o r 24/939 Fragrance Optical brightener B u i l d e r Mix: Sodium t r i p o l y p h o s p h a t e Sodi um d i s i 1ic a t e Magnesi um s i 1ic a t e Sodium p e r b o r a t e t e t r a h y d r a t e Tetraacetylethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes A c t i v e matter:

10.0 0.2 0.2

28.0 5.0 1 .o 25.0 3.0 1 .o t o 100

9.0%

L i a u i d Heavy-Duty Deteraent. B u i l t Tvoe. Hieh V i s c o s i t y - A Marlon PS 65 M a r l i p a l 013/30 1,2-Propylene g l y c o l * C i t r i c acid Z e o l i t e A, 50% s l u r r y Balance water, fragrance, d y e s t u f f , enzymes, p r e s e r v a t i v e

%

10.0 5.0 5.0 2.0 45.0 optical brightener,

t o 100

A c t i v e m a t t e r : 11.5% + f u r t h e r products o f Huls AG SOURCE: Hula America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

Laundry Products

89

Heavy D u t y L i a u i d Laundry D e t e r q e n t Type DN I n q r e d ients: Stepan B i o S o f t D-62 ( a n i o n i c s u r f a c t a n t ) Neodol 25-7 ( n o n i o n i c s u r f a c t a n t ) P r o p y l ene g l y c o l Ethyl alcohol Sodium C i t r a t e (Haarman & Reimer) Sodium x y l e n e s u l f o n a t e Sodium b o r a t e ( b o r a x ) T r i e t h a n o l ami ne (TEA) o r s o d i um h y d r o x i d e

P a r t s b y Weiqht 7.0 16.0 7.0

5.0 5.0 10.0 1. o t o pH 9 . 5

D i s s o l v e t h e Sodium C i t r a t e and sodium b o r a t e i n approxima t e l y 20 m l w a t e r . Apply h e a t i f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , p r o p y l e n e g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e and sodium b o r a t e s o l u t i o n t o t h e s u r f a c t a n t s m i x t u r e . Add t h e sodium x y l e n e s u l f o n a t e . A d j u s t t h e pH t o 9 . 5 u s i n g TEA o r d i l u t e sodium h y d r o x i d e . B r i n g t h e volume o f t h e m i x t u r e t o 100 m l u s i n g w a t e r . I f an enzyme d e t e r g e n t i s d e s i r e d , t h e f o l l o w i n g s h o u l d be added : Sodium b o r a t e ( b o r a x ) add an a d d i t i o n a l 2.0 Calcium c h l o r i d e 0.1 Protease 0.6 D i s s o l v e t h e Sodium C i t r a t e , sodium b o r a t e and c a l c i u m c h l o r i d e i n w a t e r . A p p l y h e a t i f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , p r o p y l e n e g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e , sodium b o r a t e and c a l c i u m c h l o r i d e s o l u t i o n t o t h i s m i x t u r e . Add sodium x y l e n e s u l f o n a t e . A d j u s t t h e pH t o 8 . 0 w i t h TEA o r d i l u t e sodium h y d r o x i d e . Add t h e P r o t e a s e . B r i n g t h e volume o f t h e m i x t u r e t o 100 m l u s i n g w a t e r . The a d d i t i o n o f f r a g r a n c e , dye, o p t i c a l b r i g h t e n e r , a n t i r e d e p o s i t i o n agent, c o r r o s i u m i n h i b i t o r , e t c . , i s o p t i o n a l .

SOURCE: Haarman & Reimer C o r p . :


B u i l t F o r m u l a t i o n #1 I n a r e d ient : Water Na3NTA Na G l u c o n a t e 45% KOH 42 S i l i c a t e N Glycol Ether Non ion ic S u r f a c t a n t Amphoteric

Weight .% 68%

-

1%

1% 10% 10%

5% 2% 3%

'

B o t h t h e Amphoteric SC and t h e c o m p e t i t i v e i m i d a z o l i n e c o u p l e d t h e f o r m u l a t i o n t o g e t h e r w i t h 3% o f a m p h o t e r i c .

SOURCE: Tomah P r o d u c t s ,

Inc.:

Suggested F o r m u l t i o n


Heavy D u t y L i q u i d Laundry D e t e r g e n t Type TA P a r t s Ia L ! W s h t I n q r e d ie n t s : 5.0 Neodol 25-7 ( n o n i o n i c s u r f a c t a n t ) 10.0 Neodol 25-35 ( a n i o n i c s u r f a c t a n t ) 12.0 Sodium l a u r y l s u l f a t e ( a n i o n i c s u r f a c t a n t ) 8.0 Stepan B i o S o f t D-62 ( L A S - a n i o n i c s u r f a c t a n t ) 5.0 T r i e t h a n o l a m i ne (TEA) 7.0 Propylene g l y c o l 6.0 Potassium C i t r a t e (Haarman & Reimer C o r p . ) 7.0 Ethyl alcohol 0.1 Calcium c h l o r i d e 3.0 Sodium b o r a t e ( b o r a x ) 0.6 Protease t o 100 p a r t s Water q.s D i s s o l v e t h e Potassium C i t r a t e , c a l c i u m c h l o r de and sodium b o r a t e i n a p p r o x i m a t e l y 2 0 m l w a t e r . Apply h e a t f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , TEA, propy ene g l y c o l and e t h y l a l c o h o l . Add t h e Potassium C i t r a t e , c a l c i u m c h l o r i d e and sodium b o r a t e s o l u t i o n . A d j u s t t h e pH o f t h e s o l u t i o n t o 8 . 0 w i t h T E A o r d i l u t e sodium h y d r o x i d e . Add t h e P r o t e a s e . B r i n g t h e volume o f t h e m i x t u r e t o 100 m l u s i n g w a t e r . The a d d i t i o n o f f r a g r a n c e , dye, o p t i c a l b r i g h t e n e r , a n t i r e d e p o s i t i o n agent, c o r r o s i o n agent, c o r r o s i o n i n h i b i t o r , e t c . , i s optional.

SOURCE: Haarman & Reimer C o r p . :


!&Md Laundry_ D_etergents InQ r e d j.=ts: Water Glucopon 6OOCSUP (50%) E t hano 1 T r y c o l 5963

We 1 g h t % 72 10

I n redients.; iaFer Sodi um C i t r a t e S u l f o t e x SXS Glucopon 6OOCSUP (50%) Ethanol S u l f o t e x 6040 S (59%)

Weight% 32 5 5 15 5 38

3 15

Add i n t h e o r d e r l i s t e d , d i s s o l v i n g each i n g r e d i e n t comp l e t e l y . Use moderate a g i t a t i o n and i n c o r p o r a t e c o l o r s and f r a g r a n c e s as r e q u i r e d .

SOURCE: Henkel C o r p . : CD D i v i s i o n : Glucopon S u r f a c t a n t s : Suggested F o r m u l a t i o n s

Laundry Products

91

Heavv D u t v L i q u i d Laundry D e t e r q e n t Type WA I n a r e d ie n t s : __ P a r t s b y Weiaht Stepan B i o S o f t D-62 ( L A S - a n i o n i c s u r f a c t a n t ) 28.0 7.0 Neodol 25-7 ( n o n i o n i c s u r f a c t a n t ) Sodium x y l e n e s u l f o n a t e 12.0 T r i e t h a n o l a m i ne (TEA) 2.0 Sodium C i t r a t e (Haarman & Reimer C o r p . ) 12.0 Water 9 , s . t o 100 p a r t s D i s s o l v e Sodium C i t r a t e i n a p p r o x i m a t e l y 20 m l w a t e r . Combine t h e s u r f a c t a n t s , sodium x y l e n e s u l f o n a t e and TEA. Add t h e Sodium C i t r a t e . A d j u s t t h e pH o f t h e s o l u t i o n t o 11 u s i n g d i l u t e sodium h y d r o x i d e . B r i n g t h e volume o f t h e m i x t u r e t o 100 m l u s i n g w a t e r . I f an enzyme d e t e r g e n t i s d e s i r e d , t h e f o l l o w i n g s h o u l d be added : Sodi um b o r a t e ( b o r a x ) 3.0 Cal c i um c h l o r i d e 0.1 7.0 Propylene g l y c o l Protease 0.6 D i s s o l v e t h e sodium b o r a t e , c a l c i u m c h l o r i d e and Sodium i Citrate w a t e r . A p p l y h e a t i f necessary t o d i s s o l v e . Combine t h e s u r f s t a n t s , sodium x y l e n e s u l f o n a t e , TEA and p r o p y l e n e g l y c o l . Add t h e sodium b o r a t e , Sodium C i t r a t e and c a l c i u m c h l o r i d e s o l u t i o n t o t h i s m i x t u r e . A d j u s t t h e pH t o 8 . 0 w i t h T E A o r d i l u t e sodium h y d r o x i d e . Add t h e P r o t e a s e . B r i n g t h e volume o f t h e m i x t u r e t o 100 m l u s i n g w a t e r . The a d d i t i o n of f r a g r a n c e , dye, o p t i c a l b r i g h t e n e r , a n t i r e d e p o s i t i o n agent, c o r r o s i o n i n h i b i t o r , e t c . , i s o p t i o n a l .

SOURCE: Haarman & Reimer Corp.:


B u i l t F o r m u l a t i o n #2 Inaredient: Water Na M e t a s i l i c a t e p e n t a h y d r a t e STPP Nonionic s u r f a c t a n t Amphoteric s u r f a c t a n t

Weight .% 7 9% 1% 10% 5% 5%

B o t h t h e Amphoteric SC and t h e c o m p e t i t i v e a m p h o t e r i c c o u p l e d t h e f o r m u l a t i o n t o g e t h e r w i t h 5% o f a m p h o t e r i c .

SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n

92

Advanced CIeaning Roduct Formulations

L i a u i d Heavv-Duty Detergent. Marlon PS 65 Marl ip a l 013/89 Caustic potash, 50% (approx.)* Coconut f a t t y a c i d T r i ethhnol ami ne R* 1.2-Propylene g l y c o l * Ethanol Phosphonate, e.g. Dequest 2060 S Sodi um formi a t e * Balance water, fragrance, d y e s t u f f , enzymes, p r e s e r v a t i v e

Low V i s c o s i t v - A

%

20.0 17.2 3.9 10.0 5.0 3.0 8.0 1.5 1. o

*

optical brightener, t o 100

A c t i v e m a t t e r : 45.0% L i a u i d Heavy-Dutv Detergent.

Low V i s c o s i t v - B

s6

Marlon PS 65 20.0 M a r l i p a l 013/129 3.9 12.0 Marlox FK 64 Caustic potash, 50% (approx.)* 3.9 10.0 Coconut f a t t y a c i d Triethanolamine R * 5.0 3.0 1,P-Propyl ene g l y c o l 8.0 Ethanol Phosphonate, e.g. Dequest 2060s 1.5 Sodi urn formi a t e * 1 .o Balance water, fragrance, d y e s t u f f , o p t i c a l b r i g h t e n e r , enzymes, p r e s e r v a t i v e t o 100

*

*

A c t i v e m a t t e r : 45.0% L i a u i d Heavy-Duty

Deteraent.

Marlon PS 65 Marl ip a l 01 3/30 C i t r i c acid Z e o l i t e A, 50% s l u r r y Balance water, fragrance, enzymes, p r e s e r v a t i v e A c t i v e matter:

*

B u i l t Type.

H i g h Viscositv-B % 10.0 5.0 1. o 45.0

dyestuff,

o p t i c a l brightener, t o 100

11.5%

f u r t h e r products o f Huls AG


Laundry Products

Light-Duty Deterqent.

93

Powder. Spray M i x i n q Process-A %

Spray M i x : M a r l i p a l 013/939 o r 24/939 M a r l a m i d DF 1218 Fragrance

5.0 1.0 0.2

Builder Mix: Zeolite A Sodi um d i s i 1 ic a t e Carboxymethyl c e l l u l o s e Sodium s u l p h a t e l i g h t

40.0 3.0 1.o 34.8

Post Mix: M a r l o n ARL

15.0

Active matter: L i ght-Duty

17.5% Deterqent

~

Powder,

Spray M i x : M a r l i p a l 013/939 o r 24/939 Fragrance

Spray M i x i ng Process-€3 %

3.0

0.2

Builder Mix: Zeolite A Sodi u m d i s i 1 i c a t e Carboxymethyl c e l l u l o s e Sodium s u l p h a t e l i g h t

45.0 5.0 1.o 22.8

Post M i x : M a r l o n ARL

18.0

Active Matter:

17.1%

L i q u i d L i g h t - D u t y Detergent, w i t h I n c o r p o r a t e d Softener, Low V i s c o s i t y - A

9b M a r l i p a l 24/99 M a r l o x FK 64 M a r l o s o f t I0 90 Ethanol Balance w a t e r , f r a g r a n c e , d y e s t u f f

*

15.0 5.0 5.0 10.0 t o 100

A c t i v e M a t t e r : 23.0% * f u r t h e r p r o d u c t s o f H u l s AG



L i Quid L i ght-Duty Detergent.

Low V i scosi t y - A

%

Marlon PS 65 Marl in a t 242/28 Marlamid DF 1218 Coconut f a t t y a c i d Caustic potash, 50% (approx.)* Ethylenediamine t e t r a a c e t a t e , 40% Balance water, fragrance, d y e s t u f f , sodium c h l o r i d e

20.0 12.0 3.0 4.0 1.4 0.2 preservative, t o 100

A c t i v e m a t t e r : 23.5% Formulation A f o r machine-wash L i a u i d L i ght-Duty Detergent, Low V i scosi ty-B M a r l i n a t 242/28 Marlamid DF 1218 Marlamid PG 20 Balance water, fragrance, d y e s t u f f , sodium c h l o r i d e

%

40.0 3.0 3.0


A c t i v e m a t t e r : 16.2% Formulation B f o r manual-wash L i q u i d Light-Duty Detergent, w i t h I n c o r p o r a t e d Softener, Low V i scosi t y - B Marl i p a l 24/99 Marlox FK 64 Ampholyt JB 130 M a r l o s o f t I Q 90 Balance water, fragrance, d y e s t u f f A c t i v e m a t t e r : 21.5%

*

f u r t h e r products o f Huls AG I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes


%

5.0 5.0 25.0 5.0 t o 100

Laundry Products

I n d u s t r i a1 Laundry Two-Part Formula LY-0052

Systems

Uniforms (Petroleum Greases and O i l s ) Part A I g e p a l CO-660 C a l s o f t F-90 Water

2 90

Part B Sodium S i l i c a t e (Si02/Na20 1.6-2.5)

100

H o t e l / L i nen S U D D ~ Y(Ani ma1 and Vegetable Greaser

Wt.%

Part A I g e p a l CO-660 C a l s o f t F-90 Water

10 2 88

Part B Potassi um Hydroxide (45%) STPP, TKPP o r KTPP

85 15

I n d u s t r i a l Laundry Powder Uniforms Formula LY-0050

Wt.% 52.5 15 20 12 0.5

Sodium Carbonate I g a p a l CO-660 Sodi um Tripolyphosphate Sodium M e t a s i l i c a t e O p t i c a l B r i ghtener

Procedure Add t h e sodi um carbona t o t h mixer. S r a y on t h e Igepal CO-660. Add t h e remaining i n g r e d i e n t s i n t h order 1isted. Mix u n t i l uniform. Phvsi c a l ProDert i8s Appearance: White, f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 11.4


Formulas

95


Laundry L i a u i d s Calsuds o r C a l s o f t based p r o d u c t s remove g r o u n d - i n d i r t and grease i n heavy f a b r i c s and g e n t l y c l e a n d e l i c a t e k n i t s i n c o l d water. They i n h i b i t s t a t i c b u i l d - u p and p r o v i d e l u b r i c i t y , f u l l i n g and s o f t e n i n g . " F i n e Care" F a b r i c D e t e r g e n t s P i l o t Formula ULDY-003-01 % bv Weipht

Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water

19.90 15.15 10.20 4.96 49.79 P i l o t Formula ULDL-003-01 % by Weiqht

20.00 15.00 10.00 5.00 50.00 Q.S. pH 7 Q.S.

Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water C i t r i c Acid Perfume and C o l o r Preservative

Q.S. Heavy Duty Laundry L i q u i d s P i 1o t Formula #HDL-004-01 % by Weiqht

Water 50% NaOH D i e t h a n o l ami ne Propylene G l y c o l Cal s o f t LAS-99 Cal o x y l a t e N-9

36.60 6.40 7.00 5.00 40.00 5.00 P i l o t Formula #HDL-005-01 % bv Weiqht

Water 50% NaOH D i e t h a n o l ami ne P i l o t SXS-40 C a l s o f t LAS-99 Cal o x y l a t e N-9

30.40 4.60 5.00 25.00 30.00 5.00

SOURCE: P i l o t Chemical Co. : Household C1eaner Formul a t i ons

Laundry Products

97

Laundry Powder Deteraent Formula LY-0047

Wt.% 44.0 14.0

Sodium Carbonate C a l s o f t F-90 Rhodapex NA-61 Rhodasurf 25-7 Sodium M e t a s i l i c a t e Pentahydrate Sodi um S u l f a t e Zeol it e Sodi um Perborate Enzymes can be added Dye Perfume

6.0

2.0 4.0 10.0 18.0

2.0

Procedure Add t h e sodium carbonate t o t h e mixer. Spray on t h e Rhodapex NA-61 and t h e Rhodasurf 25-7. Add t h e remai n i ng i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l uniform. Physical ProDerties Appearance: White, f r e e - f l o w i n g powder, dyed t o preference. pH, 1 % S o l u t i o n : 11 I n d u s t r i a l Laundry One-Shot L i a u i d Formula LY-0049

Wt.% 69 3 3 10 10

Water I g e p a l CO-630 I g e p a l CO-710 Cheelox BF-13 Potassi urn Hydroxide (45%) M i r a n o l FBS

5

Procedur e Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d . Mix u n t i l uniform. Phvsi c a l P r o v e r t i ea Appearance: Clear l i q u i d pH. as i s : 13.0 pH, 1% s o l u t i o n : 11.8 S p e c i f i c G r a v i t y : 1.06 V i s c o s i t y :
SOURCE:

Rhone-Poulenc S u r f a c t a n t s

a

S p e c i a l t i e s : Formulas

98

Advanced Cleaning Product Formulafions

L i q u i d Heavy Duty Detergent HDLD Soap based Ingredients: A Genapol OA-080 F a t t y a c i d ( 2 / 3 o l e i c , 1 / 3 COCO) KOH (85%) 1,2 Propyleneglycol 8 Tinopal CBS-X Water (50-6OC) C Hostapur SAS 60 T r i sodi um-ci t r a t e x 2H20 D Ethanol Savi nase Alcalase Termamyl P a r f um Farbstoff

12.00% 14.00% 3.50% 5 .OO% 0.10% 39.40% 17.00% 5.00% 3.00% 0.50% 0.20% 0.30% 0.20% 0.10%

Manufacturing: I Dissolve 8 i n A. 11 One a f t e r another, t h e components o f C a r e added t o I I11 A t 25C, t h e components o f D t o 11. L i q u i d Detergent "FSL" A I ngr ed ie n t s I CIA-080 F a t t y a c i d ( P r i f a c 7976) KOH (85%) T r i ethanolami ne 1.2 Propyleneglycol 8 Tinopal CBS-X Water (50-6OC) C Hostapur SAS 60 T r i sodi um-ci r a t e x 2H20 Dequest 2066 D Ethanol Savi nase A1 c a l ase Termamyl P e r f ume Dye

r - Genapol

12.00% 14.00% 2.60% 2.00% 5.00% 0.20% 34.20% 17.00% 5.00% 4.00% 3.00% 0.50% 0.20% 0.30% q.s. q.s.

Manufacturing: I D i s s o l v e 8 i n A. I 1 One a f t e r another, t h e components o f C are added t o I. I11 A t 25C, t h e components o f D t o I.

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Detergents and Cleaning Agents:

Guide Formulations

Laundry Products

99

T h i c k Bleach-1 L iqui d Ingredients.; Genaminox MY Medialan LD NaOH (100%)

12.000%

A

2.500% 1 .OOO%

B

Water

34.475%

C

Sodiumhypochlorite - s o l u t i o n (150 g/L a c t i v e c h l o r i n e )

50.000%

D

Perfume (e.g.

0.025%

Hypofresh)

Manufacturing: I B i s added t o A. I 1 S t i r C t o I. I11 A t l a s t D i s added. Viscosity

( B r o o k f i e l d RVT,

sp.4, 22C, mPas): 4800

m g k Bleach-2 Ingredients: A Genaminox MY M e d i a l a n LD NaOH (100%)

6.000% 1.000%

1.000%

B

Water

41.975%

C

Sodiumhypochlorite - s o l u t i o n ( 1 5 0 g/L a c t i v e c h l o r i n e )

50.000%

D

Perfume ( e . g .

Hypofresh)

0.025%

Manufacturing: I B i s added t o A. I 1 S t i r C t o 1. 111 A t l a s t D i s added. V i s c o s i t y ( B r o o k f i e l d RVT,

sp.4,


22C. mPas): 600 D e t e r g e n t s and C l e a n i n g

100

Advanced Cleaning R&ct

Formulotions

Wool DeterQent,

Medium Viscosity-A

%

Marlon PS 65 Marl in a t 242/28 Marlamid DF 1218 Balance water. d y e s t u f f , sodium c h l o r i d e

18.0 28.0 1 .o fragrance,

preservative. t o 100

A c t i v e m a t t e r : 20.5% Wool Detergent. Medium V i s c o s i t y - B

%

Marlon PS 65 M a r l i n a t SRN 30 D i o n i l OC Balance water, d y e s t u f f , sodium c h l o r i d e

20.0 20.0 1 .o fragrance,


A c t i v e m a t t e r : 20.0% Wool Detergent. Medi um V i scosi tv-A

%

Marlon AS3 Marl in a t 242/28 Ammonium hydroxide, 25% Urea Balance water, fragrance, d y e s t u f f , sodium c h l o r i d e

12.0 18.0

3.0 3.0 preservative.

to 100

A c t i v e m a t t e r : 19.0% Wool Detergent. Medium V i s c o s i t y - B

%

Marlon A 375 Marl in a t 242/28 Marlamid DF 1218 Balance water, fragrance, sodium c h l o r i d e

15.6 28.0 1. o dyestuff,


A c t i v e m a t t e r : 20.5%


9. Metal Cleaners and Polishes

101

102

Advanced Cleoning Product Formulations

A l u m i nun C1e a n e r / B r i s h t e n e r A c i d Cleaner for Aluminum Wheels and T r a i l e r s

Inqredient : D e i o n i z e d Water Phosphoric A c i d (85%) C i t r i c A c i d (50%) N i t r i c A c i d (70%) Avanel S-70 pH ( a s i s ) : <2.0 Appearance: C l e a r , w h i t e - w a t e r

Wt.% 83.00 6.00 8.00 1 .oo 2.00 liquid

Procedure: Charge t h e w a t e r t o an a p p r o p r i a t e m i x i n g v e s s e l . Charge remaining in g r edients i n t h e order l i s t e d w h i l e continuing agitation. WARNING: Use a l l m a n u f a c t u r e r p r e c a u t i o n a r y s a f e t y measu r e s when hand1 ing c o n c e n t r a t e d a c i d s o l u t i o n s . Formula CM-101 A1 urni num Smut C1eaner H i g h Temperature D i l u t a b l e A c i d C o n c e n t r a t e Insredi ent : Dei o n i zed Water C i t r i c A c i d (50%) G l u c o n i c A c i d (50%) Avanel N-1525-90 Avanel S-70 Ammoni um B i f 1u o r i de

Wt.% 19.00

50.00 25.00 3.00 1.50 1.50

pH ( a s i s ) : < 2 . 0 Appearance: C l e a r , w a t e r - w h i t e t o l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .18 Procedure: Charge t h e w a t e r and two a c i d s under a g i t a t i o n . C o n t i n u e a g i t a t i o n and add t h e Avanel s u r f a c t a n t s ; m i x u n t i l d i s s o l v e d . Add Ammonium B i f l u o r i d e and mix u n t i l d i s s o l v e d . Use D i r e c t i on8 : Use i n p r e s s u r e wash a t a r a t e o f 2-4 ounces p e r g a l l o n . Use t e m p e r a t u r e o f d i l u t i o n i s n o r m a l l y 140-15OF. Notes: T h i s f o r m u l a was developed t o remove stamping o i l smut f r o m aluminum cans. Cans s h o u l d be t h o r o u g h l y r i n s e d a f t e r c l e a n i n g Formula CM-104

SOURCE: Mazer Chemicals: SUQQeSted F o r m u l a t i o n s

Metal Cleaners and Polishes

103

Alumcnum C l e a n e r C o n c e n t r a t e % by Weiqht

75 10 5 10

Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u m Pyrophosphate (Powder) Mona NF-10

Procedure: D i s s o l v e sodium m e t a s i l i c a t e and t e t r a p o t a s s i u m pyrophosphate i n w a t e r w i t h m i x i n g , t h e n add Mona NF-10. Typical Properties: Appearance: C l e a r l i q u i d Cloud P o i n t : 88C Recommended Use D i l u t i o n : 1 t o 4 oz/gal. Formula F-498 A1 umi num Wash Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a s o d i u m Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona NF-10

% by Weight 88

Procedure: D i s s o l v e sodium m e t a s i l i c a t e and t e t r a s o d i u m pyrophosphate i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10. T y p i c a l P r o p e r t ies : Appearance: C l e a r l i q u i d pH: 1 2 . 8 Recommended Use D i l u t i o n : 1 : l O w i t h water Formula F-499


Inc.:


2 3 2

5

104

Formulations

Advanced Cleaning R&t

Cleaners and Cleanina S o l u t i o n q Metal Cleani na-A1 k a l ine % by Weiaht

Inaredients: Aerosol 22 S u r f a c t a n t Sodium Carbonate Sodi um Metasi 1ic a t e Sodium Hydroxide

10.0 40.0 20.0 10.0

G r i n d t h e powders t o g e t h e r and add t h e Aerosol 22 s l o w l y w h i l e grinding. Metal C1eani na-Aci d % by Wei a h t

Inqredients: Dowanol EB Phosphoric Acid ( 8 5 % ) Aerosol 22 S u r f a c t a n t Water

6.0 7.0 0.3 86.7

Metal C l eani na-Pai n t Removal % by Wei a h t

I n s r e d i ents: Aerosol C-61 S u r f a c t a n t Sodium Carbonate Sodium M e t a s i l i c a t e Sodi um Hydroxide

20.0 40.0 30.0 10.0

G r i n d t h e powders t o g e t h e r and add t h e Aerosol C-61 s l o w l y w h i l e mixing. Metal Cleaning-Rust Removal I n e r e d i ents: Aerosol 0 s S u r f a c t a n t Sodium B i f l u o r i d e Sodium Tetraphosphate Sodium B i s u l f i t e SOURCE: Cytec I n d u s t r i e s I n c . :

% by Weight

10.0 75.0 10.0 15.0 Suggested Formulations


105

Comer C l eani ng % bv Weiaht

Inaredients: Aerosol A-102 S u r f a c t a n t Sodium C h l o r i d e C i t r i c Acid Eentoni t e Water

2.0 5.0 5.0 22.0 66.0

Aluminum Cleaning

-

Acid % bv Wei Qht 15.0 2.0

Inaredients: Phosphoric Acid (65%) H y d r o f l u o r i c A c i d (48%) Glacial Acetic Acid Aerosol 0s S u r f a c t a n t Water

3.0 5.0 75.0

A1 u n i n u m C 1 eani na-Bri a h t e n i ng % by Wei Qht

Ingredients: Phosphoric A c i d (85%) Aerosol 22 S u r f a c t a n t Aerosol 0 s S u r f a c t a n t Butyl Cellosolve Water

47.2 1.o

1. o

16.0 34.8

Aluminum A i r c r a f t - B r i g h t e n e r Ingredients: Aerosol 0s S u r f a c t a n t Aerosol 22 S u r f a c t a n t C i t r i c Acid Arnmoni urn B i f 1u o r i de Benzenesul f o n i c Acid Phosphoric A c i d (85%) Water


(U.S.

Patent 2.68Y.3461 % bv Weiaht

3.0 9.0 5.0

3.0 10.0 2.4 26.4-52.6 Suggested Formulatlons

lo6


E l e c t r o c l eaner

% by Weiaht 2-0 1-4 0.75-3 0.25-1 To 100% T o t a l

Components: Water Burco BSGH-400 Burco NPS-225 Burco TME 50% NaOH

Basic f o r m u l a t i n g g u i d e l i n e s : 1) R a t i o o f Burco NPS-225/Burco TME should be 3 / 1 . 2 ) The l e v e l o f Burco BSGH-400 i s p r e f e r a b l y equal t o t h e sum o f Burco NPS-225 and Burco TME. 3 ) The water charge should be equal t o t h e sum o f Burco BSGH-400, Burco NPS-225 and Burco TME. 4) Premix a l l components b u t NaOH. then add NaOH w i t h s t i r r i n g . T h i s f o r m u l a t i o n w i l l p r o v i d e moderate foam l e v e l s and i s s u i t a b l e f o r use as an e l e c t r o c l e a n e r , food p l a n t cleaner o r o t h e r a p p l i c a t i o n s where h i g h c a u s t i c concentrates a r e used. For reduced foam l e v e l s as i n an a l k a l i n e spray cleaner, r e p l a c e Burco NPS-225 w i t h Burco HCS-50NF. Moderate A1 k a l in i t y , Soi 1 So1 it t i n a Soak Cleaner ComDonents: Water Sodium M e t a s i l i c a t e (Pentahydrate) Trisodium Phosphate ( C r y s t a l s ) Burco ADS-40 Burco EHS Burco TME

% bv Weiaht 70 5 10 5 5 5

Procedure: Add components i n t h e order l i s t e d . S t i r u n t i l homogeneous between each a d d i t i o n .



Metal Cleaners and Polirhes

107

Hiah-Foaming A c i d Scrubber* Formula BC-0003 W % .t

5.0

M i r a n o l FBS I g e p a l CO 630 Sulfamic A c id G1y c o l ic ( H y d r o x y a c e t i c ) A c i d (70%) Butoxyethanol Water

2.0 4.0 4.0 3.0 82.0

Procedure Add t h e w a t e r , s u l f a m i c and g l y c o l i c a c i d s . M i x u n t i l d i s s o l v e d . Add t h e r e m a i n i n g i n g r e d i e n t s , w i t h m i x i n g . M i x u n t i l uniform. Physical ProDerties Appearance: Clear l i q u i d . . pH, as i s : 1 . 5 S p e c i f i c G r a v i t y : 1 027 V i s c o s i t y : t 1 0 cps * S u i t a b l e f o r a p p l i c a t ons w i t h a t r i g g e r - t y p e

sprayer.

A c i d Cleaner Formula BC-0004 W % .t Rhodafac RE-61 0 I g e p a l CO-630 Phosphoric A c i d , Water

3.0

4.0 75%

10.0

83.0

Procedure Add p h o s p h o r i c a c i d t o w a t e r and h e a t w i t h a g i t a t i o n t o 50C. w i t h r a p i d b u t smooth a g i t a t i o n . S l o w l y b l e n d i n Rhodafac RE-610 and I g e p a l CO-630. Once system i s c o m p l e t e l y u n i f o r m , c o o l w i t h s t i r r i n g t o 40-45C, and package. Physical ProDertiea Appearance: S l i g h t l y hazy l i q u i d pH, as i s : 1.6 Speci f i c G r a v i t y : 1 .03 V i s c o s i t y : 20 cps

SOURCE: Rhone-Poulenc S u r f a c t a n t s 8 S p e c i ' a l t i e s : Formulas

108

Advanced Cleaning Product Fotmulations Metal C 1 eaner and Deereaser % bv Weight

InQredi e n t s : Monoethanolamine Sodium DDBSA, 35% Sandoxylate SX 400 Sodium EDTA Water Oleic Acid D-Li monene Butyl Cellosolve

5.0 12.0 5.0 0.5 50.5 10.0 3.0 6.0

Procedure: Charge monoethanolamine and water t o vessel. With s t i r r i n g . add DDBSA. Mix i n Sandoxylate SX 400, and EDTA. Warm t o 50C, add t h e o l e i c a c i d s l o w l y , w h i l e i n c r e a s i n g t h e a g i t a t i o n . When t h e o l e i c a c i d has completely reacted, add D-Limonene and B u t y l C e l l o s o l v e . Cool w i t h s t i r r i n g t o 40C. B o t t l e . Properties: pH (as i s ) : 10.0 V i s c o s i t y : Approx. 100 cps B r o o k f i e l d LVT, Spindle #2 @ 12 rpm % S o l i d s : 26%

SOURCE: Sandoz Chemicals Corp.:

Formulation HHG-10

Thickened Clear Deareaser Concentrate % by Weight

42.5 25.0 12.5 20.0

Water, D . I . DeSonic 9N Varonic DM55 d ' L i monene

Blend1 ng Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 363 S o l i d s : 37.5% pH: 5.9


Formula 805


109

S t a i n l e s s S t e e l Cleaner-A M a r l i p a l KF Marlophor CS a c i d Solvent BG* Balance water, fragrance,

%

dyestuff,

preservative

1. o 10.0 5.0 t o 100

A c t i v e m a t t e r : 1.0 V i scosi t y : 1iq u i d S t a i n l ess S t e e l C 1 eaner-B Mar 1ip a l 013/99 Aluminum o x i d e FPTO I s o p a r a f f i n . e.g. S h e l l s o l T Balance water, fragrance, d y e s t u f f ,

%

preservative

6.0 25.0 40.0 t o 100

A c t i v e m a t t e r : 5.4 V i s c o s i t y : medi um Formulation B w i t h abrasive S i l v e r Polish, M a r l i p a l KF Thiourea Phosphoric acid, Isopropanol* Balance water

Liauid-A

%

0.5 6.0 2.0

85%

3.0 t o 100

A c t i v e m a t t e r : 0.5% S i l v e r Polish. M a r l a z i n L 10 Marlophor CS a c i d Thiourea Phosphoric acid, 85% Balance water A c t i v e matter:

Liauid-B

%

1.5 5.0 2.5 20.0 t o 100

1.5%



10. Oven, Grill and Hot Plate Cleaners

110

Oven, Grill and Hot Plate Cleaners

111

Pump Sprav Oven C l e a n e r -. Percent

Ingredient;

b v Wei q h t

Part A: V e g e t a b l e gum (Veegum T) Xanthan gum Water

1.2 0.4 78.9

P a r t B: L i q u i d C i t r i c Acid--50% (Haarman & Reimer C o r p . ) Sodium h y d r o x i d e s o l u t i o n 50%

7.0 4.5

P a r t C: Amphoteric s u r f a c t a n t

8.0

P r e p a r e P a r t A b y s l o w l y a d d i n g v e g e t a b l e gum and x a n t h a n gum t o t h e w a t e r . C o n t i n u e a g i t a t i n g u n t i l smooth d i s p e r s i o n i s obtained. Prepare P a r t B ( t r i s o d i u m c i t r a t e ) by adding t h e c i t r i c a c i d t o a s e p a r a t e t a n k and n e u t r a l i z i n g i t w i t h t h e sodium h y d r o x i d e s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d b e done s l o w l y and c o n t i n u o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y e x o t h e r m i c . Add P a r t B t o P a r t A , and f i n a l l y P a r t C . The f o r m u l a t i o n has t h e c o n s i s t e n c y o f a f l u i d g e l . I t may be used i n e i t h e r warm o r c o l d ovens. The s p r a y i n g s h o u l d be done a t a d i s t a n c e o f f r o m 10 t o 15 i n c h e s . Clean b y w i p i n g a f t e r a t l e a s t 10 m i n u t e s o f r e a c t i o n t i m e . SOURCE: Haarman & Reimer C o r p . : Suggested F o r m u l a t i o n C a u s t i c Oven C 1 e a n e r

% by Weight I n g r e d i egt_s_: (1) Korthix H 2.0 (2) Kelzan 0.3 ( 3 ) D e i o n i z e d Water 86.7 ( 4 ) Sodium H y d r o x i d e (50%) 10.0 ( 5 ) Avanel S-74 1.o Procedure: Add ( 1 ) t o ( 3 ) and mix a t h i g h speed. A f t e r ( 1 ) i s w e l l d i s p e r s e d , add ( 2 ) and ( 5 ) . Reduce speed and add ( 4 ) c a r e f u l l y and slowly. F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s o f each p r o d u c t used. SOURCE: K a o p o l i t e , I n c . : Suggested F o r m u l a t i o n Oven/Grill

Cleaner

Wt% Water T e t r a s o d i u m EDTA Sodium H y d r o x i d e (50%) Glucopon 425 CS SOURCE: Henkel C o r p . , CD D i v i s i o n : Suggested F o r m u l a t i o n

78 2 15 5

11 Polishes, Coatings and Finishes

112

Polishes, Coatings and Finishes

113

Aerosol F u r n i t u r e P o l i s h (Carbon D i o x i d e P r o p e l l a n t l Part/Wt(%) M a t e r i a1 s: P a r t A: 22.5 Isopar E 0.5 Hoechst Wax A 3 CS 2.3 SF 96 (100) 0.5 V i s c a s i l (10,000) 0.3 Span 80 P a r t 8: 73.9 Water Procedure: 1 . ) Heat P a r t A t o 8 5 C . 2 . ) Heat P a r t 8 t o 70C. 3 . ) Add P a r t 8 t o P a r t A w i t h h i g h shear m i x i n g . 4 . ) Cool t o room t e m p e r a t u r e when homogeneous. Preparation o f Aerosol: Part/Wt(%) Loadi ng : 97.5 P o l i s h Concentrate 2.5* Carbon D i o x i d e * T h i s w i l l g i v e a can p r e s s u r e o f a p p r o x i m a t e l y 105 p s i g . Aerosol V a l v e : P r e c i s i o n V a l v e P a r t Numbers: B u t t o n : P a r t No. 01-5843 (0.020" MBFT RS) Stem: P a r t No. 04-1215 (0.016") Gasket: P a r t No. 05-0310 (BUNA) Body: P a r t No. 07-1901 ( 0 . 0 8 0 " ) 5 . ) Package i n s u i t a b l e c o n t a i n e r s . General Purpose L i a u i d P o l is h ( O i l - I n - W a t e r Type)

Part/Wt (%l Mater ia1 s : P a r t A: SF 96 (350) 2.50 V i s c a s i l (10,000) 1 .oo 1.50 Hoechst Wax E Oleic Acid 1.50 Isopar M 10.00 P a r t 8: Water 70.05 Carbopol 934 0.25 Morphol ine 1.60 0.10 Kathon CG P a r t C: Isopar M 2.00 SF 1706 1.50 P a r t D: K a o p o l i t e SF 8.00 Procedure: 1 . ) Heat P a r t A t o 95C. ( 2 . ) Heat P a r t B t o 85C. ( 3 . ) Add P a r t A t o P a r t 8 w i t h h i g h shear m i x i n g . ( 4 . ) When homogeneous, c o o l t o 60C and add P a r t C w i t h h i g h shear m i x i n g . ( 5 . ) Add P a r t D w i t h moderate m i x i n g . ( 6 . ) Cool and package i n s u i t a b l e containers. SOURCE: GE Si14cones: Formula FP 3003/Formula AP 1000

114

Advanced Cleaning Roduct Formulatiom

Aerosol F u r n i t u r e P o l i s h IHydrocarbon P r o D e l l a n t ) Materials: P a r t A: Isopar E Hoechst Wax A3 CS S F 96 ( 1 0 0 ) V i s c a s i 1 ( 10,000) Span 80 Tween 81 P a r t B: Water Procedure: 1 . ) Heat P a r t A t o 85C. 2 . ) Heat P a r t B t o 70C. 3 . ) Add P a r t B t o P a r t A w i t h h i g h shear m i x i n g . 4 . ) Cool t o room t e m p e r a t u r e when homogeneous. Preparation o f Aerosol: i o a d i ng : P o l i s h Concentrate A 46 P r o p e l l a n t Aerosol Valve : P r e c i s i on V a l v e P a r t Numbers : B u t t o n : P a r t No. 01-5843 (0.020" MBFT RS) Stem: P a r t No. 04-1240 (0.024") Gasket: P a r t N o . 05-0310 (BUNA) Body: P a r t No. 07-1901 (0.080") 5 . Package i n s u i t a b 1 e c o n t a i n e r s .

Part/ W t

1%)

14.75 0.50 2.30 0.50 0.25 0.08 81.62

Part/WtC%) 90.0 10.0

Furniture P a s t e m M a t e r i a1 s : P a r t A: 7.0 V i s c a s i 1 (30,000) 7.0 Hoechst Wax E 3.0 Hoechst Wax F 6.0 Ross M i c r o Wax 1135/15# 1 .o Ross O z o k e r i t e Wax 77Y P a r t B: 76.0 Isopar L Procedure: 1 . ) Heat P a r t A t o 1OOC. 2 . ) Heat P a r t B t o 9%. 3 . ) Add P a r t 8 t o P a r t A w i t h g e n t l e m i x i n g . 4 . ) Cool t o 50-52C w i t h g e n t l e m i x i n g and pour i n t o c o n t a i n e r s . A l l o w c o n t a i n e r s t o c o o l b e f o r e capping. A f l o w o f a i r across s u r f a c e o f c o n t a i n e r w i l l improve c o o l i n g p r o c e s s . M u l t i p l e p o u r c y c l e s can be used f o r deep c o n t a i n e r s . A l t e r n a t e Method: 1 . ) Heat P a r t A t o 100C. 2 . ) Add P a r t B (unheated) s l o w l y w h i l e b l e n d i n g . 3 . ) Reheat P a r t AB u n t i l a c l e a r s o l u t i o n i s o b t a i n e d . F o l l o w above p r o c e d u r e f r o m h e r e .

SOURCE:

GE S i l i c o n e s :

Formula FP 3002/Formula

FP 3004


I15

D e t e r g e n t R e s i s t a n t . Cream C l e a n e r P o l i s h Ingredients: ( 1 ) Deodori zed Kerosene ( 2 ) Hoechst Wax S ( 3 ) GP-7104 ( S i l i c o n e F l u i d ) ( 4 ) GP-10-1,000 c s t k ( D i m e t h y l S i l i c o n e F l u i d ) (5) Oleic Acid ( 6 ) S o f t Water ( 7 ) Morphol ine ( 8 ) S o f t Water ( 9 ) M i n e r a l S p i r i t s (Low Odor) ( 1 0 ) K a o p o l i t e SF

% b y Weight

10.0 8.0 3.0 4.0 1.o 2.4 0.8 38.8 20.0 12.0

Procedure: Combine ( 1 ) t h r o u g h ( 5 ) and h e a t t o 212F w i t h l o w t o moderate m i x i n g . Remove h e a t , i n c r e a s e m i x i n g and add ( 6 ) t h r o u g h ( 1 0 ) as i n s t r u c t e d below. Heat ( 6 ) t o 21OF, s t i r i n ( 7 ) , t h e n p o u r i n t o t h e b a t c h . Heat ( 8 ) t o 210F and add t o t h e b a t c h . Add ( 9 ) t h e n ( 1 0 ) s l o w l y t o t h e b a t c h , a l l o w i n g c o m p l e t e m i x i n g o f each. M i x s l o w l y u n t i l t e m p e r a t u r e o f b a t c h reaches l l O F . Package. Formula 4-2 Non-Abrasive,

Detergent R e s i s t a n t , Glaze Emulsion

% b y Weight Ingredients: ( A ) ( 1 ) GP-10-1,000 c s t k ( D i m e t h y l S i l i c o n e F l u i d ) 3.0 ( 2 ) GP-7104 ( S i l i c o n e F l u i d ) 3.0 ( 3 ) Hoechst Wax S 1.5 ( 4 ) Carnauba Wax #3 1. o (5) Oleic Acid 1.5 ( 6 ) Mineral S p i r i t s 4.6 (B)

(7) (8) (9) (10)

S o f t Water Carbopol 934 T r i e t h a n o l a m i n e 99% Morphol ine

83.6 0.2 0.2 1.4

Procedure: ( A ) Combine ( 1 ) t h r o u g h ( 6 ) and h e a t t o 150F w i t h m i x i n g . ( B ) Heat ( 7 ) t o 1OOF. W i t h h i g h shear m i x i n g add ( 8 ) t o ( 7 ) . Once ( 8 ) i s d i s s o l v e d add ( 9 ) and t h e n add ( 1 0 ) . Add ( A ) t o ( B ) s l o w l y , w i t h h i g h shear m i x i n g . C o n t i n u e m i x i n g u n t i l e m u l s i o n reaches 70F. Package. Formula 8-1

SOURCE: Genesee Polymers C o r p . :


I16


H i ah G1oss. D e t e r e e n t R e s i s t a n t . S o f t P a s t e P o l ish Inqredients: (A) ( 1 ) Hoechst Wax OP (2) Hoechst Wax E (3) Ozokeri t e (B)

(4) (5) (6) (7) (8) (9) (10)

% bv Weight

7.0 8.0 1.5

GP-7104 ( S i l i c o n e F l u i d ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) GP-10-12,500 c s t k (Dimethyl S i l i c o n e F l u i d ) M i n e r a l S p i r i t s (Low Odor) Deodorized Kerosene K a o p o l i t e SF M i n e r a l S p i r i t s (Low Odor)

3.0 3.0 2.0 36.0 9.5 12.0 18.0

Procedure: ( A ) Combine ( I ) , (2), and (3), h e a t t o 230F t o m e l t waxes. ( B ) S e p a r a t e l y mix and h e a t ( 4 ) , ( 5 ) , ( 6 ) , ( 7 ) , and ( 8 ) t o 160F. S l o w l y add ( B ) t o ( A ) w i t h m i x i n g . Temperature o f b a t c h a f t e r adding (B) t o ( A ) s h o u l d be 195F. Add ( 9 ) t h e n ( 1 0 ) t o b a t c h w i t h m i x i n g . Remove h e a t and mix w e l l u n t i l temperature reaches 140F. Package. Formula 5-2 D e t e r g e n t R e s i s t a n t Cream P o l i s h Inqredi ents: ( 1 ) W i t c o n o l 14 (2) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) ( 3 ) Carnauba Wax #3 (4) Isopar L ( 5 ) Morphol ine ( 6 ) GP-7104 ( S i l i c o n e F l u i d ) ( 7 ) S o f t Water ( 8 ) K a o p o l i t e SF

% b y Wei a h t

1.5

3.0 10.0 25.0 0.4

3.1 47.1 10.0

Procedure: Combine ( I ) , (2), (3). and 50% o f ( 4 ) i n a c o n t a i n e r and h e a t t o 195F w i t h m i x i n g t o m e l t wax. Once wax i s melted, add ( 5 ) w i t h m i x i n g . Add ( 6 ) t o m i x t u r e f o l l o w e d by t h e r e s t o f (41, k e e p i n g t h e t e m p e r a t u r e a t 175F. Remove f r o m h e a t and mix u n t i l t e m p e r a t u r e reaches 130F. Package. Formula 3-2 SOURCE: Genesee Polymers Corp.:

Suggested FormulatSons


117

L i q u i d P o l i s h F o r C l e a r Coat F i n i s h e s Part/Wt(%) Mater ia1_s ; P a r t A: SF 96 (350) 3.50 1 .oo Hoechst Wax S Hoechst Wax E 1.60 Oleic Acid 1.50 5.00 Isopar M P a r t 0: Water 77.75 Carbopol 934 0.20 1.60 Morphol ine Kathon CG 0.10 P a r t C: Isopar M I.oo SF 1706 0.75 P a r t D: Kaopol it e 1152 6.00 Procedure: 1 . ) Heat P a r t A t o 95C. 2 . ) Heat P a r t B t o 8%. 3 . ) Add P a r t A t o P a r t B w i t h h i g h shear m i x i n g . 4 . ) When homogeneous, c o o l t o 60C and add P a r t C w i t h h i g h shear m i x i ng. 5 . ) Add P a r t D w i t h moderate m i x i n g . 6 . ) Cool and package i n s u i t a b l e c o n t a i n e r s . L i q u i d Polish-No S o l v e n t Mater ia1 s : Part/Wt(%) P a r t A: SF 96 (350) 5.00 Hoechst Wax E 1.50 Oleic Acid 1.50 Part 8: Carbopol 934 0.25 Morphol ine 1.50 Water 74.15 Kathon CG 0.10 Part C: SF 96 (100) 2.00 SF 1706 2.00 P a r t D: Kaopol it e 1152 7.80 Snow F l o s s 4.20 Procedure: 1 . ) Heat P a r t A t o 95-IOOC. 2 . ) Heat P a r t B t o 85C. 3 . ) Add P a r t A t o P a r t B w i t h h i g h shear m i x i n g . 4 . ) When homogeneous, c o o l t o 60-70C and add P a r t C w i t h c o n t i n ued h i g h shear m i x i n g . 5 . ) When homogeneous, reduce m i x i n g t o medium speed and s l o w l y b l e n d i n P a r t D. 6 . ) Cool and package i n s u i t a b l e c o n t a i n e r s .

SOURCE: GE S i l i c o n e s : Formula APlOOl/Formula AP1002

I18 Advanced Cleaning Product Formulations

L i a u i d P o l i s h (Outer Phase O i l l Part/Wt (%l Materials: P a r t A: 1.50 V i s c a s i l (10,000) 1 .oo W i tcamide 51 1 0.15 Tween 81 1.30 Hoechst Wax OP Ross O z o k e r i t e 77Y 0.20 20.00 Isopar M P a r t 9: 55.85 Water 4.50 Kaopol it e 1152 4.50 K a o p o l i t e SF Part C: 6.00 Isopar L 3.00 SF 1705 2.00 SF 1706 Procedure: 1 . ) Heat P a r t A t o 90-95C. 2 . ) Heat P a r t B t o 80C. 3 . ) Add P a r t B t o P a r t A w i t h h i g h shear mixing. 4 . ) When homogeneous, cool t o 50-60C and add P a r t C w i t h continued h i g h shear m i x i ng. 5 . ) Cool and package i n s u i t a b l e c o n t a i n e r s . Formula AP 1003 Non-Wax L i a u i d P o l i s h (Oil-Pn-Water

Tvoe)

M a t e r i a1 s : Part/Wt C%l P a r t A: SF 96 (350) 4.00 V i scasi 1 (10,000) 1 .oo Isopar L 11 .oo Oleic A c i d 1.50 Part 0 : Water 65.95 Carbopol 934 0.25 Morpholine 1.70 Kathon CG 0.10 P a r t C: Isopar M 4.00 SF 1706 1.50 P a r t D: Kaopol it e 1152 6.00 Snow F l o s s 3.00 Procedura: 1. ) Add P a r t A t o P a r t B w i t h h i g h shear mixing. 2 . ) When AB i s homogeneous, add P a r t C . a l s o w i t h h i g h shear m i x i ng. 3 . ) Add P a r t D w i t h moderate m i x i n g u n t i l homogeneous. 4.) Package i n s u i t a b l e c o n t a i n e r s . Formula AP 1004 SOURCE: BE S l l l c o n e a : Suggested Formulations


L i sui d F u r n i t u r e P o l is h Part/Wt

Materials: SM 2133 sm 2135 20% Wax Emulsion Carbopol 934 Triethanolamine Water B i o c i de

119

(%I 4.0 2.0 2.5 0.2

0.2 91.1 q.s

20% Wax Emulsion-1 Materials: P a r t A: C a r d i s 36 Wax Hoechst Wax A3 CS Oleic Acid Morpholine P a r t B: Water B i o c i de 20% Wax Emulsion-2 Materials: P a r t A: C a r d i s 36 Wax Hoechst Wax A3 CS Oleic Acid D i e t h y l ami n o e t h a n o l (DEAE) P a r t 8: Water B i o c i de

Part/Wt(%) 10.0 10.0 3.0 4.0 73.0 q.s.

Part/Wt (%) 10.0 10.0 3.0 2.5 74.5 q.s.

P r e p a r a t i o n o f Wax Emulsion: 1 . ) Add C a r d i s 36 wax, Hoechst wax A 3 CS, and o l e i c a c i d t o a v e s s e l , and w i t h m i l d s t i r r i n g b r i n g t h e t e m p e r a t u r e up t o 96-1 OOC. 2 . ) When c o m p l e t e l y melted, add e i t h e r t h e m o r p h o l i n e o r DEAE u n t i l m i x t u r e i s homogeneous. 3 . ) Add P a r t B, p r e h e a t e d t o 95C, s l o w l y s t i r r i n g t h e wax/soap m i x t u r e , m a i n t a i n i n g t e m p e r a t u r e between 93 t o 98C d u r i n g t h i s addition. 4 . ) C o n t i n u e s t i r r i n g u n t i l t e m p e r a t u r e reaches 45C. 5 . ) Cool t o room t e m p e r a t u r e . Preparation of Polish: 1 . ) Add w a t e r , b i o c i d e , and Carbopol 934 t o a v e s s e l , and d i s s o l v e t h e Carbopol w i t h good m i x i n g . Warm w a t e r w i l l improve t h i s p r o c e s s . 2 . ) Add t r i e t h a n o l ami ne and mix u n t i 1 homogeneous. 3 . ) Add o t h e r i n g r e d i e n t s . 4 . ) Combine w i t h m i l d m i x i n g , and when homogeneous, package in s u i t a b 1 e c o n t a i n e r s . SOURCE: GE S i l i c o n e s : Formula FP 3000

120

Advanced Cleaning Roduct Formulatiotu

L i a u i d Water-Based G l a z e Part/Wt(%)

Mater ia1 s : P a r t A: SF 96 (350) O l e i c Acid Hoechst Wax OP C a r d i s 36 Wax Isopar M

3.50 1.50 1 .oo 1.50 6.00

P a r t B: Water Carbopol 934 Morpholine Kathon CG

82.55 0.25 1.60 0.10

P a r t C: Isopar M SF 1706

1 .so 0.50

Procedure: 1 . ) Heat P a r t A t o 95-1OOC. 2 . ) Heat P a r t B t o 90-95C. 3 . ) Add P a r t A t o P a r t B w i t h h i g h shear m i x i n g . 4 . ) Cool t o 60-70C and add P a r t C w i t h h i g h shear m i x i n g . 5 . ) Cool w i t h c o n t i n u e d moderate m i x i n g . 6 . ) Package i n s u i t a b l e c o n t a i n e r s . Formu la AP 1005

Sol v e n t Wax G l aze Materials: P a r t A: SF 96 (1000) Hoechst Wax OM Hoechst Wax F Deodorized Kerosene P a r t B: Odorless M i n e r a l S p i r i t s S R 107

Part/Wt

(%l 3.0

0.6 1.4 10.0 84.0 1.0

Procedure: 1 . ) Heat P a r t A to 95C. Be s u r e a l l wax i s c o m p l e t e l y m e l t e d and d i spersed. 2 . ) Add P a r t B w i t h moderate m i x i n g . 3 . ) C o n t i n u e m i x i n g and c o o l t o room t e m p e r a t u r e . 4.) Package i n s u i t a b l e c o n t a i n e r s . Formula AP 1008

SOURCE: GE S i l i c o n e s : Suggested F o r m u l a t i o n s


Paste P o l i s h (Oil-In-Water

121

Type1

Materi a1 s: Part/Wt (%l P a r t A: Hoechst Wax S 5.0 1. o Hoechst Wax OP 4.5 SF 96 (350) V i s c a s i l (10,000) 2.0 Stearic Acid 1 .o 8.0 Isopar M 18.0 Isopar L P a r t 0: 42.8 Water 0.7 Morpholine 8.0 Kaopol it e 1168 Super F l o s s 2.0 P a r t C: Isopar M 5.0 2.0 SF 1706 Procedure: 1 . ) Heat P a r t A t o 90-95C. 2 . ) Heat P a r t 8 t o 80-85C. 3.) Add P a r t A to P a r t B w i t h good mixing. 4 . ) When homogeneous, cool t o 60C and add P a r t C w i t h continued mixing. 5 . ) Cool t o s u i t a b l e pour temperature (<50C). 6 . ) Package i n s u i t a b l e c o n t a i n e r s . Comments : The pour temperature w i l l depend on equipment and r a t e and degree o f c o o l i n g a v a i l a b l e on t h e f i l l i n g l i n e . With slow c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done w i t h o u t covers t o prevent condensation i n s i d e c o n t a i n e r s . Spray-And-Wipe

Polish

Mat e r ia1 s : Part/Wt(%) SM 2109 8.00 AF 9020 0.05 Veegum Pro 0.80 Proxcel GXL 0.15 K a o p o l i t e SF 5.00 Water 86.00 Procedure: 1 . ) Add water, Proxcel GXL. and Veegum Pro t o a m i x i n g vessel, and, u s i n g h i g h shear, disperse u n t i l uniform. 2 . ) Add K a o p o l i t e SF and continue m i x i n g w i t h h i g h shear u n t i l a u n i f o r m f i n e d i s p e r s i o n i s obtained. 3 . ) Reduce m i x i n g t o low t o moderate and add AF 9020 and SM 2109 emulsions. Do Not Overmix. These m a t e r i a l s e a s i l y disperse i n a very s h o r t t i m e p e r i o d . 4 . ) Package i n s u i t a b l e sprayable c o n t a i n e r s .

SOURCE: GE S i l i c o n e s :

Formula BP 2001/Formula AP 1010

122

Advonced Cleaning Product Formulations

Paste P o l i s h (Oil-In-Water

TYDe)-(l)

M a t e r i a1 s : P a r t A: SF 96 ( 3 5 0 ) V i s c a s i l (10,000) Hoechst Wax S Hoechst Wax OP Stearic Acid Isopar M Isopar L P a r t 0: Water Morpholine K a o p o l i t e SF Snow F1oss Kathon CG P a r t C: Isopar M SF 1706 Paste P o l i s h (Oil-In-Water M a t e r i a1 s : P a r t A: SF 96 (350) v i s c a s i 1 (i0,ooo) Hoechst Wax S Hoechst Wax OP Stearic Acid Isopar M Isopar L P a r t 0: Water Morpholine K a o p o l i t e 1152 Snow F1oss Kathon CG P a r t C: Isopar M SF 1706

Part/Wt (%) 4.5

2.0 5.0

1

.o

1 .o 8.0 18.0

42.7 0.7 8.0 2.0 0.1 5.0 2.0 Tyoe)-(Zl Part/Wt(%l 4.5

2.0 5.0 1 .o

1 .o 8.0 18.0

41.7 0.7 7.8 4.2 0.1

4.0 2.0

Procedure: 1.) Heat P a r t A t o 90-95C. (2.) Heat P a r t B t o 80-8512. 3.) Add P a r t A t o P a r t 0 w i t h good m i x i n g . ( 4 . ) When homogeneous, c o o l t o 60C and add P a r t C w i t h c o n t i n u e d m i x i n g . ( 5 . ) Cool t o s u i t a b l e p o u r t e m p e r a t u r e , e . g . , >50C. 6.) Pour i n t o s u i t a b l e c o n t a i n e r s . Comments : The p o u r t e m p e r a t u r e w i l l depend on equipment, r a t e and degree o f c o o l i n g a v a i l a b l e on t h e f i l l i n g l i n e . W i t h s l o w c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done w i t h o u t c o v e r s t o p r e v e n t condensation i n s i d e c o n t a i n e r s . SOURCE: GE S i l i c o n e s : Formula AP 1008


123

Paste P o l i s h ( O i p Meteri a1 s: Part/Wt t % l P a r t A: SF 96 (350) 4.5 V i scasi 1 (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1.o S t e a r i c Acid 1. o Isopar M 8.0 Isopar L 18.0 P a r t B: Water 42.7 Morphol ine 0.7 Kaopol it e 1152 7.5 Snow F l o s s 2.5 Kathon CG 0.1 P a r t C: Isopar M 5.0 SF 1706 2. 0 1 . ) Heat P a r t A t o 90-95C. 2 . ) Heat P a r t 8 t o 80-85C. 3 . ) Add P a r t A t o P a r t B w i t h good mixing. 4 . ) When homogeneous, cool t o 60C and add P a r t C w i t h continued m i x i ng 5 . ) Cool t o s u i t a b l e pour temperature, e.g., >5OC. 6. ) Pour in t o s u i t a b l e c o n t a i ners. Comments : The pour temperature w i l l depend on equipment, r a t e and degree o f c o o l i n g on t h e f i l l i n g l i n e . With slow c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done w i t h o u t covers t o prevent condensation in s i de c o n t a i ners. Paste P o l i s h (Outer Phase O i l 2 Materials: Part/Wtt%) P a r t A: V i s c a s i l (10,000) 2.50 Hoechst Wax S 1.80 Hoechst Wax E 2.00 Ross Ozokerite 77Y 0.15 Span 80 2.00 Tween 81 0.15 Isopar L 17.00 Isopar M 5.00 P a r t B: Water 52.40 Kaopol it e 1152 6.00 Snow Floss 3.00 Part C : Isopar M 2.00 SF 1705 4.00 SF 1706 2.00 1. Heat P a r t A t o 95C. ( 2 . ) Heat P a r t B t o 8OC. ( 3 . ) Add P a r t B t o P a r t A w i t h h i g h shear mixing. ( 4 . ) Cool t o 60-65C and add Part C w i t h good mixing. ( 5 . ) Cool t o 55C and pour i n t o s u i t a b l e containers. SOURCE: GE S i l i c o n e s : Formula AP 1006(3)/AP 1007

.

124


Spray-And-Wipe

P o l i s h (Pump) Part/Wt(%) 3.0 2.0 2.5 92.5 q.s.

Mater ia1 s 1 SM 2133 SM 2135 20% Wax Emulsion Water B i o c i de 20%Wax .Emu 1s ionr--l )

Sartf W t f U

Materials Part A: C a r d i s 36 Wax Hoechst Wax A3 CS Oleic Acid Morpholine

10.0 10.0 3.0 4.0

P a r t B: Water B i o c i de

73.0 q.s 20% Wax EmulKion-.(a

Mateyjal s : P a r t A: C a r d i s 36 Wax Hoechst Wax A3 CS Oleic Acid Diethylaminoethanol

(DEAE)

P a r t B: Water B i o c i de

10.0 10.0 3.0 2.5

74.5 q.s.

P r e p a r a t i o n o f Wax Emulsion: 1 . ) Add C a r d i s 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a v e s s e l and, w i t h m i l d s t i r r i n g , b r i n g t e m p e r a t u r e up t o 98-1ooc. 2 . ) When c o m p l e t e l y m e l t e d , add e i t h e r t h e m o r p h o l i n e o r DEAE u n t i l m i x t u r e i s homogeneous. 3.) Add P a r t B, p r e h e a t e d t o 95C, s l o w l y s t i r r i n g t h e wax/soap m i x t u r e , m a i n t a i n i n g t e m p e r a t u r e between 93 and 9BC d u r i n g the addition. 4 . ) C o n t i n u e s t i r r i n g u n t i l t e m p e r a t u r e reaches 45C. 5 . ) Cool t o room t e m p e r a t u r e . Preparation o f Polish: Blend a l l i n g r e d i e n t s t o g e t h e r w i t h m i l d s t i r r i n g , package i n s u i t a b l e c o n t a i n e r s .

SOURCE:

GE S i l i c o n e s : Formula FP 3001

and


Spray 8 Wipe Type-Aerosol Concord Co-Wax E m u l s i o n , 12% S i 1 icone ( U n i o n C a r b i d e LE-461) D i s t i 11ed Water Spray 8 Wipe- Type-Aerosol

o r Non-Aerosol(1) % by Weiaht 4.1 7.0 88.9

o r Non-Aerosol(E] Weisht 7.5 12.5 2.5 77.5

Concord Co-Wax E m u l s i o n , 12% S i l i c o n e ( U n i o n C a r b i d e LE-461) S i l i c o n e ( U n i o n C a r b i d e LE-462) D i s t i 11ed Water Spray & Wipe Type-Aerosol Concord Co-Wax E m u l s i o n , 12% S i 1 icone ( U n i o n C a r b i d e LE-461) S i l i c o n e ( U n i o n C a r b i d e LE-462) T r i e t h a n o l ami ne L a u r y l S u l f a t e D i s t i 1 l e d Water

125

o r Non-Aerosol(3) % by Weiqht 7.5 12.5 2.5 1.5 76.0

The f o r m u l a s l i s t e d above a r e suggested f o r m u l a s . Every e f f o r t has been made t o o p t i m i z e a l l p r o p e r t i e s t o g e t t h e b e s t p o l i s h w i t h r e g a r d t o s p e c i f i c amounts o f i n g r e d i e n t s . Formula #1 i s t h e b e s t a l l around p o l i s h . I t f e a t u r e s e x c e l l e n t g l o s s , a p p l i c a t i o n ease and economy. Formula #3 i s an example o f l i g h t foam-type p o l i s h , and o f f e r s b e t t e r removal o f s o i l and emulsi f i c a t i o n o f p r o p e l l e n t s . Formula #2 i l l u s t r a t e s a h i g h g l o s s formula w i t h excellent p r o t e c t i v e q u a l i t i e s . L i q u i d Wax-Solvent

Furniture o r Floor Polish

Concord Wax #1600 S i l i c o n e General E l e c t r i c SF 96-100 Safety Solvent (Stoddard Solvent)

% by Weight 6.0 1.o 93.0

Procedure: M e l t wax and s i l i c o n e t o g e t h e r a t a t e m p e r a t u r e o f 195-200F i n one h a l f o f t h e s o l v e n t . The b a l a n c e o f t h e c o l d s o l v e n t i s t h e n added t o t h i s s o l u t i o n a f t e r t h e waxes a r e m e l t e d .

SOURCE: Concord Chemical Co.,

Inc.:


12. Rinse Aids

126

RinseAids

127

Automatic Dishwash Rinse A i d (For Hard Water1 A c i d Hard Water T o l e r a n t Formulation

Wt.%

Inaredient : Oeioni zed Water Mazawet 36 G l y c o l i c Acid (57%) I s o p r o p y l Alcohol pH, 1%: 2.0-3.0 Appearance: Clear, s l ight y viscous, S p r c i f i c G r a v i t y : 1.01

30.00 55.00 10.00 5.00 light-yellow

iqui d

Procedure: Charge t h e water and Mazawet 36 t o t h e m i x i n g vessel and s t a r t a g i t a t i o n . Charge t h e G l y c o l i c A c i d and I s o p r o p y l Alcohol and mix u n t i l c l e a r and f r e e o f " f i s h eyes." Notes : Formulated f o r areas w i t h hard water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e c y c l e . Conce n t r a t i o n s o f use s o l u t i o n s may be adjusted t o meet l o c a l needs o r v a r t a t i o n s i n equipment. Formula CR-101 Automatic Dishwash Rinse A i d
Wt.% 55.00 40.00 5.00

P . S . t o pH 6.0-7.0 light-yellow l i q u i d

Procedure: Charge t h e i n g r e d i e n t s i n t h e sequence g i v e n above and mix u n t i l c l e a r and f r e e o f " f i s h eyes." Notes : Formulated f o r areas w i t h n e u t r a l o r s o f t water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e c y c l e . Conce n t r a t i o n s o f use s o l u t i o n s may be a d j u s t e d t o meet l o c a l needs o r v a r i a t i o n s i n equipment. The f o r m u l a t o r may a d j u s t t h e c l o u d - p o i n t o f t h i s system by u s i n g a d d i t i o n a l a l c o h o l t o increase i t o r Sodium Hydroxide t o decrease i t . Formula CR-102


128


Rinse A i d Formula DW-0011 W % .t 50.0 9.0 41 . O

Antarox BL-240 Urea Water Dye

Procedure 1. D i s s o l v e urea i n water. 2. Add Antarox BL-240 t o water/urea s o l u t i o n . Mix thoroughly. Physical PrpDertiea pH (as i s ) : 7.5 pH (1%): 8.1 V i s c o s i t y : 50 cps S p e c i f i c G r a v i t y : 1.01 Rinse A i d Formula DW-0012 W % .t

70.0 20.0 10.0

Antarox BL-225 Isopropanol Water Dye Procedure 1 . D i s s o l v e Antarox BL-225 2 . Add isopropanol.

-

i n water. Mix thoroughly.

Physical P r o p e r t i e s pH (as i s ) ; 6.1 pH (1%): 8 . 3 V i s c o s i t y : 30 cps S p e c i f i c G r a v i t y : 0.99

SOURCE:

Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s :

Formulas

13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

129

130

Advanced Cleaning product Formdations

Basic F l o o r Cleaner.

Liauid-A

% 7.0 3.0 3.0 5.0 5.0 10.0 1 .o t o 100

Marlon A 360 o r A 365 Marl ip a l 013/99 Solvent BG* Tetrapotassium pyrophosphate Sodi um metasi 1i c a t e pentahydrate KNA cumene sulphonate 40 Ammonia, 25% Balance water, fragrance, p r e s e r v a t i v e A c t i v e m a t t e r : 7.0% Basic F l o o r C1eaner,

L i a u i d-B

M a r l i p a l 013/99 Marl owet 5622 Solvent BG* Tetrapotassium pyrophosphate Ammonia, 25% Balance water, fragrance, p r e s e r v a t i v e

!%

3.0 4.0 20.0 3.0 1 .o t o 100

A c t i v e m a t t e r : 6.7% F l o o r Cleaner. f o r Everyday Use. Liauid-A

% 5.0 6.0

Marlon PS 65 L i poxol 12000* Marlamid DF 1218 Isopropanol* Fragrance Balance water, d y e s t u f f

1.5 20.0 0.5 t o 100

A c t i v e m a t t e r : 4.7% F l o o r Cleaner. M a r l i p a l KF C i t r i c acid Isopropanol* Fragrance Balance water,

f o r Everyday Use. Liauid-B

!%

3.0 0.2 25.0 0.5 dyestuff

t o 100




&g,

Floor, Catpet, UpholsteryShampOchF and Cleaners

131

CarDet and UDhols t e w C1 e a n e r s Dry-Foam C 1 eaner. L i aui d-A % M a r l i n a t SRN 30 M e t h a c r y l a t e copolymer, e . g . S y n t r a n 6520 N i t r i l o t r i a c e t a t e powder Balance w a t e r , f r a g r a n c e , p r e s e r v a t i v e

30.0 20.0 1 .o t o 100

A c t i v e m a t t e r : 9.0% Dry-Foam C 1 eaner M a r l i n a t SRN 30 N i t r i l o t r i a c e t a t e powder Balance w a t e r , f r a g r a n c e ,

.

L i aui d-B

%

preservative

40.0 0.5 t o 100

A c t i v e m a t t e r : 12.0% Dry-Foam Cleaner. M a r l i n a t SRN 30 Methoxypropanol T e c h n o c e l l 90 DU Balance w a t e r , f r a g r a n c e , Active matter:

%

preservative

5.0 5.0 50.0 t o 100

1.5% Dry-Foam Cleaner,

M a r l i n a t DFK 30 Methoxypropanol T e c h n o c e l l 90 DU Balance w a t e r , f r a g r a n c e , Active matter:

Powder-A

Powder-B

%

preservative

5.0 5.0 50.0 t o 100

1.5%

SOURCE: H u l s America, I n c . : B a s i c F o r m u l a t i o n s o f D e t e r g e n t s and C l e a n i n g Agents f o r Houaehold Purposes

132


C a r p e t Shampoo,

H i a h Foam %__byWeigh2 10.0 15.0 75.0

Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d .

P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t freeze/thaw p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e . Formula 9 1 1 Carpet. Shampoo,

H i &h -Foam ?4 by Weight 78.3

Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA

5.0 16.7

B1 endi ng P r o c e d u r e : Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t freeze/thaw p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e . Formula 908



Rug Floor, Carper, Uphktety Shampoos and Cleaners

133

Evaporative (No Rinse) Wax S t r i p p e r Formula FC-0056

Wt.% Miranol JEM Concentrate Monoethanol ami ne Butoxyethoxypropanol Isopropanol Water

0.5 6.5 2.5 19.0 '72.5

Procedure Add t h e i n g r e d i e n t s and mix u n t i l uniform. Phvsi c a l ProDerti es Appearance: Clear s o l u t i o n pH, as i s : 1 1 . 4 V i s c o s i t y : t 1 0 cps S p e c i f i c G r a v i t y : 0.97 Waxed F l o o r Cleaner Formula FC-0055

Wt.% Rhodaf ac RA-600 A1 kami de DC 212/S Tetrapotassium Pyrophosphate (60% A c t i v e ) Water

5.0 1.o 25.0 69.0

Q=

Add i n g r e d i e n t s one by one, a f t e r each a d d i t i o n .

i n order l i s t e d above,

mixing well

Phvsi c a l ProDerti es pH. as i s : 8 . 6 pH (1%): 8.6 V i s c o s i t y : 10 cps Specific Gravity: 1.04


Formulas

134


F1oor C l eaner Formula FC-0053

Wt.% 6.0 3.0

Rhodafac LO-529 Sodi um T r i p o l y p h o s p h a t e T e t r a s o d i u m Pyrophosphate Water

3.0 88.0

Procedure 1. D i s s o l v e s o l i d s i n t h e t o t a l amount o f w a t e r . 2. Add Rhodafac LO-529. M i x t h o r o u g h l y . Phvsi c a l P r o D e r t ies pH, as i s : 13.9 pH (1%): 8.9 V i s c o s i t y : 60 cps S p e c i f i c G r a v i t y : 1.09 F l o o r Cleaner Formula FC-0054 Rhodafac LO-529 A1 kami de DC-212/S T e t r a s o d i u m Pyrophosphate (65% A c t i v e ) T r i s o d i um Phosphate D i e t h y l e n e G l y c o l Monoethyl E t h e r Water Perfume and C o l o r a n t s added, as d e s i r e d , r e p l a c i n g w a t e r

Wt% . 5.0 1 .o 2.0 1 .o 1 .o 90.0

Procedur e 1. D i s s o l v e T e t r a s o d i u m Pyrophosphate i n w a t e r . Add T r i s o d i u m Phosphate. D i s s o l ve thorough1 y . 2. Add Rhodafac LO-529 and Alkamide DC-212/S. 3 . Add s o l v e n t .

1 pH. as i s : 11.0 pH ( 1 % ? : 9 . 0 V i s c o s i t y : 290 cps S p e c i f i c G r a v i t y : 1.01


Formulas

Rug, Floor, Carpet, Upholsfery Shampom and Cleaners

135

Floor Polish Mor-Glo 2-457 20% S o l i d s Use w i t h l o w speed s p r a y b u f f i n g and h i g h speed maintenance programs u s i n g p l u g - i n e l e c t r i c b u r n i s h e r s and s y n t h e t i c pads. Produces h i g h e r i n i t i a l g l o s s t h a n t h e 442 f o r m u l a t i o n . Can be b u r n i s h e d d a i l y o r on an i n t e r m i t t e n t s c h e d u l e w i t h o u t p r o d u c i n g e x c e s s i v e amounts o f d u s t . M u l t i p l e r e c o a t s o f 4 - 5 c o a t s p e r a p p l i c a t i o n a r e recommended w i t h 30-45 min. d r y i n g t i m e depending on s o l i d s . W i t h t h e s e m a i n t a i n a n c e p r o c e d u r e s a c o n s i s t e n t h i g h l e v e l o f appearance can be s u s t a i n e d o v e r an extended p e r i o d o f time.

___ Item: 1 2 3 4 5 6 7 8 9 10

Components: Water D i e t h y l e n e G l y c o l Monoethyl E t h e r T r i b u t o x y e t h y l Phosphate F l u o r a d FC-129 ( 1 % a c t i v e s o l u t i o n ) A n t i foam Emu1s i on* P r o x e l GXL Mor-Glo 2 L a t e x (38%) M o r t o n Conrez 510 ( 2 5 % s o l u t i o n ) AC-325 A n i o n i c (35%) E-43 N o n i o n i c (40%)

Wei Q h t P e r c e n t 47.07 3.37 2.95 0.50 0.02 0.10 39 4 9 1 .oo 2.51 2.19 9

Procedure: W i t h good a g i t a t i o n add t h e components i n t h e o r d e r l i s t e d . A f t e r t h e a d d i t i o n o f i t e m #6, a l l o w t o mix f o r 3 0 min. b e f o r e c o n t i n u i n g . Add t h e r e m a i n i n g components s l o w l y . F o r m u l a t i o n Constants: Polymer/Resin/Wax R a t i o : 9 0 / 0 / 1 0 T y p i c a l pH: 8 . 5 Formulation Density: 8.54 l b s . / g a l . S p e c i f i c G r a v i t y : 1.026 TvDi c a l Densi t y Val ues: __Solids: Pounds/Qal. 2 5% 8.60 20% 8.54 15% 8.49

Specific Gravity 1.032 1.026 1.019

*SAG 1010 f r o m Union C a r b i d e Corp., S i 1 i c o n e s Corp.

o r SWS 211 f r o m Wacker

SOURCE: M o r t o n I n t e r n a t i o n a l , I n c . : Formula Mor-Glo 2-457 20% Sol i d s

136


Floor Polish

ML-870-389 20% S o l i d s Use w i t h low speed spray b u f f i n g and h i g h speed maintenance programs. T h i s product maintains a h i g h i n i t i a l g l o s s and can be burnished on an i n t e r m i t t e n t schedule. With these maintenance procedures, a c o n s i s t e n t h i g h l e v e l o f appearance can be sustained over an extended p e r i o d o f time. Up t o f i v e coats per a p p l i c a t i o n may be a p p l i e d w i t h 30-45 min. d r y i n g t i m e depending on s o l i d s and c o n d i t i o n s .

Item: 1 2 3 4 5 6 7 8 9 10 11 12

W_eiqht Percent

Components: Water D i e t h y l e n e G l y c o l Monoethyl Ether T r i b u t o x y e t h y l Phosphate D i b u t y l Phthalate I g e p a l CO 977 F l uorad FC-129 (1% s o l u t i o n ) A n t i foam* Proxel GXL ML-870 Latex (38%) Morton Conrez 510 (25% s o l u t i o n ) AC-325 Noni oni c (35%) E-43 Nonionic (40%)

42.36 4.97 1.24 0.65 0.20 0.60 0.02 0.10 34.89 7.45 4.01 3.51

Procedure: With good a g i t a t i o n , add t h e components i n t h e order l i s t e d . A f t e r t h e a d d i t i o n o f i t e m #8, a l l o w t o mix f o r 30 minutes b e f o r e c o n t i n u i n g . Add t h e remaining components s l o w l y . Formulation Constants: Polymer/Resin/Wax R a t i o : 74/10/16 T y p i c a l pH: 8.0 Formulation Density: 8.52 l b s . / g a l . Speci f ic G r a v i t y : 1 .023 T y p i c a l D e n s i t y Values: Sol i d s : Pounds/Gal

25% 20% 15%

.

Speci f ic G r a v i t y

8.57 8.52 8.47

*SAG 1010 from Union Carbide Corp., S i 1icones Corp.

1.029 1.023 1.017 o r SWS 211 from Wacker

SOURCE: Morton I n t e r n a t i o n a l : Formulation ML-870-389 20% S o l i d s

Rug, Floor, Carpet, Upholsfery Shampom and Cleaners

137

L i a u i d Carpet Cleaner % bv W e -

Water SXS-40% Sodi um Bicarbonate STPP Burcosperse AP-Liq Burco LAF-6

72.5 10.0

5.0 5.0 5.0 2.5 Carpet S t a i n Remover-Liauid % by Weight To 100

Water Burcoterge DG-40 Burcosperse AP-Liq Propylene G l y c o l S o r b i t o l 70% Burcotase SL-80

40

10 20

15 0.5-1

.o

Carpet Cleaner/Booster-Dry Destai ner

96 bv Weipht Burco LAF-6 Soda Ash FB-Sodi um Percarbonate

2.0-6.0 40-60 40-60

Above a l s o e l i m i n a t e s odors such as those caused by pet u r i n e . O x i d i z e s s t a i n s such as c o f f e e , wine, j u i c e , e t c . G e n e r a l l y 5 ounces o f above added t o 5 g a l l o n s o f detergent s o l u t i o n i s s u f f i c i e n t f o r good performance.


Inc.:


138


Low Cost E x t r a c t i o n CarDet Cleaner % bv Weight 91 . o 5.0 4.0

Water, D . I . P e t r o 22 Powder EDTA Powder Perfume

Q.S.

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . Use D i l u t i o n : 1-2 o t / g a l

o f water

Formula 901 Medium Cost Steam E x t r a c t i o n Carpet Cleaner Water, D . I . P e t r o 22 Powder Sodi um T r i p o l yphosphate Sodium S i l i c a t e 42 Be' ( S t a r ) * T r i sodi um Phosphate, C r y s t a l DeSonic 9N Perfume *Pa Corp.

% bv Weight 76.5

3.5 5.0 9.0 2.0 4.0 q.s.

01 end1 ng Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d Use D i l u t i o n :

1-2 oz/gal

.

o f water

Formula 902 Premium. Heavy Duty Steam E x t r a c t i o n Carpet Cleaner Sodium Tripolyphosphate, L i g h t Density Sodium M e t a s i l i c a t e , Pentahydrate P e t r o 22 Powder Optical Brightener 01 endi ng Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . Use D i l u t i o n :

1-2 oz/gal

Formula 906



% by Weight 40.0 54.5 5.0 0.5

Rug, Floor, Carper, Upholsteryshonrpocrs and Cleaners

139

Non-Ammaniated F l o o r S t r i m e r %-by Water Sodium M e t a s i l i c a t e , Pentahydrate Monoethanolamine Potassium Hydroxide, 45% Witcamide S-771 Butyl Cellosolve Witconate SXS L i q u i d

Weight 65.44 1 .oo 16.25 3.25 8.00 4.06 2.00

Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g thoroughly between each a d d i t i o n . Typical Properties: S o l i d s : 13.3% pH, as i s : 13.3 Formula 924 Non-Ammoniated F l o o r S t r i m e r 9b bv Weiaht

40.0 20.0 40.0

Monoethanolamine Witcamide S-771 Butyl Cellosolve 81endi ng Procedure: Blend i n g r e d i e n t s i n t h e o r d e r shown, mixing thoroughly between each a d d i t i o n . Typical Properties: S o l i d s : 20.0% pH, as i s : 11.4 Formula 923



I40

Advanced Cleaning R h t FormJatiotu

Quarry T i l e Cleaner % bv WeiQht 88.0

Inqredients: Water B i o - S o f t S-1 0 0 Makon 10 Hydroxy A c e t i c A c i d (70%) HC1 (37%)

4.0 3.5 3.0 1.5

M i x i ng Procedure : Mix t h o r o u g h l y i n o r d e r g i v e n . Typical Properties: Appearance: L i g h t y e l l o w , c l e a r l i q u i d p H , as i s : 1 . 8 7 S p e c i f i c G r a v i t y , g/ml: 1.01 V i s c o s i t y , @ 25C, c p s : 15 Stability: 40F ( 7 d a y s ) : Pass 75F ( 7 d a y s ) : Pass 120F ( 7 d a y s ) : Pass Freeze/Thaw ( 3 c y c l e s ) :

Pass

Use I n s t r u c t i o n s : One t i m e o n l y : H e a v i l y s o i l e d f l o o r : wet f l o o r w i t h w a t e r and p o u r c o n c e n t r a t e d i r e c t l y on. Spread w i t h mop and l e a v e f o r t e n m i n u t e s . Scrub and squeegee, r i n s e w i t h w a t e r . D r y w i t h c l e a n mop. D a i l y C l e a n i n g : 4 oz/l g a l w a t e r d i l u t i o n . Apply w i t h mop and l e a v e f o r f i v e m i n u t e s , t h e n s c r u b , r i n s e , and d r y .

SOURCE: Stepan Co.:

F o r m u l a t i o n No. 582

L o w Foam Floor C l e a n e r Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u m Pyrophosphate Mona NF-10

% by Weisht 70 5 14 11

Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . T y p i c a l P r o p e r t ies : Cloud P o i n t : 93C K r a f t P o i n t : COC Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .

SOURCE: Mona I n d u s t r i e s , I n c . : F o r m u l a t i o n F-545

Rug, Floor, Carpet, Uphoktery Shampoos and Cleaners

SDeci a1-PurDose F l o o r C1eaner

.

141

L i a u i d-A

%

Marlon A 365 Marlophor ND-DEA-salt Marlowet T o r 5622 Na cumene sulphonate 40 T r i ethanol ami ne* Tetrapotassium pyrophosphate Balance water, fragrance, p r e s e r v a t i v e

10.0 5.0 5.0 10.0 4.0 6.0 t o 100

A c t i v e matter: 16.5% Formulation A w i t h a n t i s t a t i c p r o p e r t i e s Special-Purpose F l o o r Cleaner. Marlon PS 65 Isopropanol* Lonzabac 12.30 N i t r i l o t r i a c e t a t e , 40% Balance water, fragrance,

Liauid-6

%

5.0 25.0 3.0 0.5 t o 100

preservative

A c t i v e m a t t e r : 3.3% Formulation B w i t h m i c r o b i c i d a l p r o p e r t i e s Wash-and-Wax

F l o o r Cleaner.

L i a u i d-A

M a r l i p a l 013/79 Marlox FK 64 Marlowet 5622 N i t r i l o t r i a c e t a t e powder C i t r i c acid Wax emulsion. 15%. b a s i s Vestowax AW 1060* Balance water, fragrance, p r e s e r v a t i v e

% 5.0 3.0 2.0 0.2 0.3 10.0 t o 100

A c t i v e m a t t e r : 9.5% Wash-and-Wax

F1o o r Cleaner, L i a u i d-B

Marl ip a l 01 3/60 Marlowet 5622 N i t r i l o t r i a c e t a t e powder C i t r i c acid Wax emulsion, 15%, b a s i s Vestowax AW 1060* Balance water, fragrance, p r e s e r v a t i v e A c t i v e matter: 10.0%

%

8.0 2.0

0.2 0.3 10.0 t o 100


14. Miscellaneous

142

Miscellaneous

143

Condensate TL: T y p i c a l F o r m u l a t i o n s

A l l Purpose C l e a n e r 5.0% 50.0% 1-2% To 100%

Condensate TL Harco 20% Soap STPP Water Bubble Bath D i e t h a n o l a m i n e L a u r e l S u l f a t e (35% A c t i v e ) Stepanol DEA Condensate TL Water D i l u t a b l e Shampoo(l:8) D i e t h a n o l a m i n e L a u r e l S u l f a t e (35% A c t i v e ) Stepanol DEA Condensate TL (TO pH 7.0-7.5) H2S04 ( c o n c . ) Isopropanol

30.0% 5.0% 65.0%

60.0% 35.0% 1.15% 4%

V i scous F l o o r C l e a n e r

9.0% 4.0% 4.0% 20.0%

Condensate TL TSPP STPP Harco 20% Soap Water

63.0%

D i shwashi ne L i a u i d Sodium Xylene S u l f o n a t e 4.0% Dodecylbenzene S u l f o n i c A c i d 12.5% Noni o n i c D e t e r g e n t 6.0% 3.0% Condensate TL 50% C a u s t i c Soda A d j u s t t o pH o f 7 . 0 + - 0 . 5 SDA 3A A l c o h o l 2.0 Dye 8 Perfume Water To 100% O D a c i f i e d Hand SoaD Opaci f ie r Water S o l u b l e L a n o l i n Condensate TL Conc. Coconut/Veg. O i l Potash Soap Perfume 8 Dye Water SOURCE: Concord Chemical Co.,

0.70% 1.25% 12.5% 20.0% To 100%

I n c . : Suggested F o r m u l a t i o n s

I44


d' Limonene Waterless Hand Cleaner % by Weight

Phase I: Water, D.I. T r i sodi um Phosphate Sodium C i t r a t e G1y c e r i ne

81 .o 1. o 2.0 2.0

Phase 11: d ' L i monene DeSonic 9N Varonic T202

7.0 5.0 2.0

Blending Procedure: I n vessel #1 combine Phase I i n g r e d i e n t s and mix thoroughly. Heat t o 140F. Combine Phase I1 i n g r e d i e n t s i n separate vessel and mix thoroughly. Heat t o 140F. While m i x i n g r a p i d l y , add Phase I1 t o Phase I. Cool q u i c k l y t o s t a b i l i z e emulsion. Typical Properties: Appearance, Room Temp.: Heavy Cream S o l i d s : 12.0% pH: 10.4 Formula 1120 Water1ess Hand C1 eaner Emphos PS-220 Kerosene, deodorized Stoddard Solvent, deodorized T r i ethanol ami ne, 99% Water

% by Weight 8.7 37.9 15.4 2.2 35.8

81ending Procedure: 01end ingredi e n t s in t h e o r d e r shown, m i x i ng thorough1y between each a d d i t i o n . Formula 1119



Miscellaneous

145

D r y Cleanina By u s i n g Aerosol OT-100% S u r f a c t a n t i n d r y c l e a n i n g s o l v e n t a t a c o n c e n t r a t i o n o f ca. 0.1 o z . / g a l . t h e soaps used as a i d s i n w a t e r - s o l u b l e s t a i n removal can be replaced i n t h e d r y c l e a n i n g i n d u s t r y . I n c o n t r a s t t o many soaps, Aerosol OT does n o t o x i d i z e w i t h consequent development o f undesirable odor upon aging. Aerosol OT-100% d i s s o l v e d i n a s u i t a b l e s o l v e n t , such as t r i c h l o r o e t h y l e n e . naphtha, carbon t e t r a c h l o r i d e , o r combi n a t i o n s o f these, can be used t o remove s o l v e n t - s o l u b l e s t a i n s a f t e r f a b r i c s have become wet w i t h water. The m i x t u r e can then be f l u s h e d o u t w i t h a d d i t i o n a l water. As a whitener f o r k i d gloves, i t i s recommended t h a t 4 oz. o f Aerosol OT-100% be d i s s o l v e d i n a g a l l o n o f Stoddard solvent, t o which may be added from 4 t o 8 oz. o f z i n c s t e a r a t e . A water brushing f o r r e t a i n i n g p l e a t s i s made by d i s s o l v i n g 4 oz. o f Aerosol OT-100% S u r f a c t a n t i n one-half g a l l o n o f Stoddard s o l v e n t , t o which i s added one p i n t o f wet s p o t t e r and one-half p i n t o f water. The p l e a t e d items should be brushed thoroughly w i t h t h e m i x t u r e , then simply hung i n t h e a i r t o d r y , t o e l i m i n a t e water. The i t e m should be re-cleaned w i t h s o l v e n t t o dispose o f t h e o t h e r agents p r e s e n t . I t w i l l come out without wrinkles o r disturbed p l e a ts.

S a t i s f a c t o r y s p o t t i n g m i x t u r e s can be made as f o l l o w s : 1 . Aerosol MA-80 S u r f a c t a n t * To1u o l Perch1o r o e t h y l ene Water

*

1 lb. 3 qt. 1 qt. 1/2 p t .

I f Aerosol OT i s used i n s t e a d o f Aerosol MA, becomes t u r b i d when water i s added.

2. Aerosol OT-100% S u r f a c t a n t Stoddard Solvent Water

the mixture

1 lb. 2 gal. 3 pt.

I n o r d e r t o increase t h e w e t t i n g o u t (reduce t h e break t i m e ) o f e x c e p t i o n a l l y greasy a r t i c l e s , t h e use o f 0.25% to 1.0% of a 10% aqueous s o l u t i o n o f Aerosol OT S u r f a c t a n t (based upon t h e weight o f t h e water) i s r e s o r t e d t o o c c a s i o n a l l y i n laundry p r a c t i c e s . During e x c e p t i o n a l l y busy periods, t h e use o f 10% aqueous Aerosol OT s o l u t i o n s w i l l reduce t h e treatment t me and t h u s i n c r e a s e e f f i c i e n c y , although i t i s t r u e t h a t a k a l i t o g e t h e r w i t h h o t water over a longer treatment p e r i o d w 11 accomplish t h e same r e s u l t s . A l k a l i w i t h h o t water f i x e s egg albumin whereas Aerosol OT S u r f a c t a n t does n o t .



146


Dust C o n t r o l Areas o f Use: Dust r e s u l t i n g f r o m o p e r a t i o n s such as m i n i n g c o a l , p r o d u c t i o n o f t a l c o r f a c e powder, m i l l i n g g r a i n and sawing wood a r e a l l f i r e , e x p l o s i o n a n d / o r h e a l t h hazards. Such d u s t y c o n d i t i o n s can be a l l e v i a t e d o r c o n t r o l l e d by w a t e r s p r a y s c o n t a i n i n g s m a l l amounts o f A e r o s o l GPG S u r f a c t a n t . Reasons f o r U s i n g A e r o s o l GPO S u r f a c t a n t : Most d u s t s a r e r e s i s t a n t t o w e t t i n g by w a t e r a l o n e . Concentr a t i o n s o f o n l y 0.01% t o 0.05% o f A e r o s o l GPG S u r f a c t a n t i n w a t e r p r o v i d e e f f i c i e n t and economical w e t t i n g . Areas t o be Sprayed: Work s u r f a c e s may be w e t t e d w i t h a f i n e s p r a y t o p r e v e n t c r e a t i o n o f d u s t . Dusty m a t e r i a l s b e i n g conveyed may a l s o be sprayed. T h i s p r a c t i c e n o t o n l y m i n i m i z e s t h e p r o b l e m o f a i r b o r n e d u s t , b u t s i m u l t a n e o u s l y reduces p r o d u c t l o s s . Spray heads may be l o c a t e d a t as many l o c a t i o n s as have d u s t problems because t h e equipment r e q u i r e d i s moderate i n c o s t and t h e r e i s no h a z a r d t o p e r s o n n e l f r o m Aerosol GPG S u r f a c t a n t . C o n c e n t r a t i o n s o f Aerosol GPG S u r f a c t a n t

c We1 h t

1% Inoredi ents: 1.43 Aerosol GPG S u r f a c t a n t none Ethanol t o make 100 p a r t s Water 5% Inaredients : 7.15 A e r o s o l GPG S u r f a c t a n t Ethanol 10-20 t o make 100 p a r t s Water 10% Inaredients: 14.3 A e r o s o l GPG S u r f a c t a n t 15-20 Ethanol Water t o make 100 D a r t s 25% Ingredients: 35.7 A e r o s o l GPG S u r f a c t a n t 10-15 Ethanol t o make 100 D a r t s Water 50% Ingredients: 71.5 A e r o s o l GPG S u r f a c t a n t 15-20 Ethanol t o make 100 p a r t s Water Procedure: The s t o c k s o l u t i o n may be i n t r o d u c e d i n t o t h e main w a t e r stream by a p r o p o r t i o n i n g .DumD . o r an e d u c t o r . The s t r e n a t h o f t h e f i n a l s o l u t i o n may be a d j u s t e d by changing t h e amount o r s t r e n g t h o f t h e s t o c k s o l u t i o n b e i n g added. The range o f s t r e n g t h c o n c e n t r a t i o n s shown i n t h e t a b l e above w i l l a l l o w any o r d i n a r y method o f m e t e r i n g . F u r t h e r c o n t r o l may be p r o v i d e d by use o f a d j u s t a b l e s p r a y heads. SOURCE: Cytec I n d u s t r i e s I n c . :


Miscellaneous

147

Hand and Body Cleanser 96 by Weight

Phase I: Water, D . I . Witconate AOS Varonic LI-48 Varonic LI-67 Ethylene Glycol Monostearate Varamide ML-1 Phase 11: Glycerine Lanoquat 50

67.0 20.0 3.7 1.3 1.6 2.5

0.2 0.5

EDTA

Rewoteric AM 8-15

0.1 3.1

Phase 111: C i t r i c Acid

q.s.

Phase I V : Sodium C h l o r i d e

q.s.

Phase V : Preservat ive

q.s.

Blending Procedure: Heat Phase I water t o 8OC. Blend i n Witconate AOS w i t h good a g i t a t i o n . When t h i s i s blended completely, add t h e remaining Phase I i n g r e d i e n t s , m e l t i n g them f i r s t b e f o r e adding. Cool t o 45C and add Phase 11, i n t h e o r d e r l i s t e d . Cool t o 35C and a d j u s t pH = 7.0-7.7 w i t h c i t r i c a c i d . Add sodium c h l o r i d e t o desired v i s c o s i ty. Typical Properties: S o l i d s : 19.5% pH: 7.3


Formula 1125

148


Heavv Dutv Deareaser Butoxyethanol Mac kam JS Sodium M e t a s i l i c a t e Pentahydrate Sodi um T r i p o l yphosphate T r i sodi urn Phosphate T a l l O i l Fatty Acid KOH (45%) EDTA (40%) Deionized Water

Weiqht,% 8.0

3.5 3.0 1.5 2.5 2.0 2.1 0.3 77.3

Procedure: 1. Add components t o water and heat t o 40C. 2 . Blend u n t i l c l e a r . Burni s h i na Colnpound Wei qht .%

93.0 1.5 2.7 2.7

Mackamide CD (Cocami de DEA) TKPP Glycerin Mackadet 40K (Potassium Coconut Soap) Procedure: 1. Disperse TKPP i n G l y c e r i n and add Mackadet 40K. 2. Then b l e n d i n Mackamide CD.

Remarks : The f i n a l product w i l l form an almost water c l e a r product. The product upon d i l u t i o n w i t h water w i l l form a cloudy emulsion which r e q u i r e s shaking b e f o r e use. Corrosion I n h i b i t i n g Coating O i 1- E m u l s i f i a b l e Mackazoline 0 ( O l e y l Hydroxyethyl I m i d a z o l i n e ) L i g h t Mineral O i l G l a c i a l A c e t i c Acid Oleic Acid Procedure: 1. Blend Mackazol i n e 0 and Mineral O i 1 . 2. Add A c e t i c Acid and O l e i c Acid. 3. Blend u n t i l c l e a r .

SOURCE: M c I n t y r e Group L t d . :

I n d u s t r l a l Formulary

Wei a h t .% 16.5 75.0 1.5 7.0

Miscellaneous

149

Heavy D u t y I n d u s t r i a l Spray M e t a l C l e a n e r C o n c e n t r a t e % by Weiaht

65 10 10 5 10

Water P o t a s s i um H y d r o x i d e Sodium M e t a s i l i c a t e (Anhydrous) Sodium Carbonate Mona NF-25 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Cloud P o i n t : 43C K r a f t Point: COC Recommended Use D i l u t i o n : 6 t o 8 o z . / g a l . F o r m u l a t i o n F-544 L o w Foam H y p o c h l o r i t e C l e a n e r

I n redients;. water Sodium H y p o c h l o r i t e (5.25%) Mona NF-10

% bv Wei q h t

79.0 19.0 2.0

Procedure: B l e n d i n g r e d i e n t s i n o r d e r l i s t e d . A d j u s t pH t o 13-14 w i t h 45% KOH

.

F o r m u l a t i o n F-655


Inc.:


Metal CleanerJBri nhtener % by WeixhL

Eastman EB s o l v e n t C i t r i c acid P h o s p h o r i c a c i d (85%) Nonionic s u r f a c t a n t * Water

4.5 4.0 2.5 3.0 86.0

*Such as Neodol 91-8 a l c o h o l e t h o x y l a t e ( S h e l l Chemical Co.) o r Rhodasurf LA-9 a l c o h o l e t h o x y l a t e (Rhone-Poulenc).

SOURCE:

Eastman Chemical Co.: Eastman EB and DB S o l v e n t s f o r C l e a n e r s : Suggested F o r m u l a t i o n

150


H o t la n k StripperjCleaner/Deruster Component: C a u s t i c Potash C r y s t a l Anhydrous Sodium M e t a s i l i c a t e Burco BSGH-270 o r BSGH-Crystals Burco ADS-100 Burco TME D o d e c y l b e n z e n e s u l f o n a t e Powder

10.0 15.0 5.0 2.5

5.0

Procedure: B l e n d C a u s t i c Potash and Sodium M e t a s i l i c a t e . Spray Burco TME o n t o m i x t u r e and b l e n d u n t i l f u l l y absorbed. Add 8 u r c o ADS-100, G l u c o n a t e o r Glucoheptonate and Dodecylbenzenesulfonate. B l e n d u n t i 1 uniform. Each component has a s p e c i f i c f u n c t i o n . The M e t a s i l i c a t e w i l l increase p a i n t s t r i p p i n g e f f i c i e n c y provided s u f f i c i e n t a l k a l i n i t y i s p r e s e n t . The G l u c o n a t e o r Glucoheptonate p r o v i d e t h e d e r u s t i n g . Burco TME and 8 u r c o ADS-100 p r o v i d e removal and d i s p e r s i o n o f p a r t i c u l a t e s o i l s w h i l e t h e Dodecylbenzenesulfonate adds w e t t i n g and o i l y s o i l d e t e r g e n c y . Each component can be a d j u s t e d a c c o r d i n g t o t h e improvement needed.

Low Foam _Heavy D u t y A1 k a l in e C l eaner-A

~~

CommDonent: Water Sodium M e t a s i l i c a t e , Burcene 100 B u r c o s o l v TM Burco TME Burcowet TM-LF

%.

bx_Wei.&t

58

Pentahydrate

5

2 10 20 5

Procedure: Add a l l components i n t h e o r d e r l i s t e d . S t i r u n t i l homogeneous between each a d d i t i o n . F o r m u l a t i o n A i s l o w foaming a t t e m p e r a t u r e s above 160F.

Low Foam Heavy-Duty Component: Water Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Sodi um X y l e n e S u l f o n a t e s 40% B u r c o s o l v TM Burco TME Burco LAF-125

A1 k a l ine. C l e a n e r - 6 % by Weight

55 5 8.5 10 20 5

Procedure: Add a l l components i n t h e o r d e r l i s t e d . S t i r u n t i l homogeneous between each a d d i t i o n . F o r m u l a t i o n B i s low foaming above 1OOF. SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s

Miscelloneous

151

Pai n t Brush C1eaners Aerosol C-61 S u r f a c t a n t i s a c a t i o n i c reagent t h a t w i l l a c t i v a t e s t r o n g l y t h e v o l a t i l e s o l v e n t s commonly used f o r removing p a i n t . B r i s t l e brushes and r o l l e r s , glass, p o r c e l a i n , metal, p l a s t i c , and c l o t h i n g have been t r e a t e d s u c c e s s f u l l y . A 5 1 0 % s o l u t i o n o f Aerosol C-61 i n a s o l v e n t , o r mixed s o l v e n t s is recommended. Extremely r a p i d sedimentation o f p a i n t pigment has been obtained w i t h t h e f o l l o w i n g composition: Inaredients: Aerosol C-61 S u r f a c t a n t B u t y l C e l l o s o l v e Solvent Xyl ene

% by Weight o r Volume 5 5 90

Brushes and r o l l e r s may be cleaned immediately a f t e r use by b e i n g suspended i n t h i s m i x t u r e . I n a few hours p r a c t i c a l l y a l l o f t h e p a i n t pigment s e t t l e s i n a l a y e r beneath t h e b r i s t l e s . The s o l v e n t m i x t u r e may be reused repeatedly. When t h e pigment has s e t t l e d t h e brush may be removed and hung i n c i r c u l a t i n g a i r t o d r y . For b e s t r e s u l t s , t h e brush then should be washed i n soapy water and r i n s e d . I f t h e brush i s t o be used again immediately, i t may be r i n s e d i n s o l v e n t i n s t e a d o f d r y i n g and waterwashi ng. For r e n o v a t i n g brushes t h a t have been allowed t o become caked w i t h hard, d r y p a i n t , t h e f o l l o w i n g f o r m u l a t i o n has proved sucessf u l

.

Ingredients: Aerosol C-61 S u r f a c t a n t Xyl ene Butanol Mineral Spi r i t s

?4 by Weight o r Volume 10 45

5 40

The brush i s soaked i n t h e m i x t u r e f o r a time, then worked up and down t o a i d t h e p e n e t r a t i o n i n t o t h e caked p a i n t . The soaking and working may be repeated several times i f t h e p a i n t i s very hard and d r y . When t h e o l d p a i n t has soaked o u t o f t h e brush, t h e brush i s r i n s e d i n clean, warm water and f i n a l l y washed i n soapy water and r i n s e d again, then hung up t o d r y . A f t e r b e i n g d r i e d t h e b r i s t l e s have t h e appearance and f e e l of those o f a new brush.

SOURCE:

Cytec I n d u s t r i e s I n c . :


I52


Steam C l e a n e r % by WeiQht

65 3 10 10 12

Water P o t a s s i um H y d r o x i d e Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u m Pyrophosphate Mona NF-15 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Cloud P o i n t : 75C K r a f t P o i n t : >OC Recommended Use D i l u t i o n : 4 t o 6 o z . / g a l . F o r m u l a t i o n F-541 Helvy D u t y Indus-ray

c l e a n e r Concentrate % by Weigh% 40 50 10

Water Sodium H y d r o x i d e (50%) Mona NF-25

Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Cloud P o i n t : 75C K r a f t P o i n t : >5C Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l . F o r m u l a t i o n F-543 H i g h Sol i d s A 1 k a l ine C1 eaner Water Potassium H y d r o x i d e Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u m Pyrophosphate Mona NF-25

% bv Weiclht 45.0 10.0 10.0 25.0 10.0

Procedure: Mix i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F o r m u l a t i o n F-555


Inc.:


Miscellaneous

153

W a l l DaDer Removal A s t o c k s o l u t i o n o f Aerosol OT-75% S u r f a c t a n t , o r a powder c o n t a i n i n g A e r o s o l OT-B S u r f a c t a n t can be p r e p a r e d f o r use as a w a l l p a p e r remover. D i l u t e d w i t h w a t e r by t h e u s e r t o a conc e n t r a t i o n o f 0.025% Aerosol OT, t h e s o l u t i o n i s h i g h l y e f f e c t i v e i n s o a k i n g o f f o l d w a l l p a p e r , and o f t e n r e n d e r s t h e use of an e x p e n s i v e and b u l k y steamer unnecessary.

A t y p i c a l l i q u i d c o n c e n t r a t e w a l l p a p e r remover can be p r e p a r e d as f o l l o w s . Inqredi ents: A e r o s o l OT-75% S u r f a c t a n t I s o p r o p y l Alcohol Water

% by Weisht 15.0 15.0 70.0

Directions: Use one t a b l e s p o o n o f t h e above f o r m u l a t i o n p e r g a l l o n o f warm w a t e r . A p p l y t o a l a r g e s e c t i o n o f w a l l p a p e r and w a i t a few m i n u t e s . I f necessary, a p p l y a g a i n . The f o l l o w i n g powdered c o n c e n t r a t e may be p r e p a r e d u s i n g A e r o s o l OT-B S u r f a c t a n t : % by Weiqht

Inqredients: Sodium S u l f a t e (Powder) A e r o s o l OT-B S u r f a c t a n t

90.0 10.0

Directions: Use one t e a s p o o n f u l p e r g a l l o n o f warm w a t e r and a p p l y as recommended above.

SOURCE:

Cytec I n d u s t r i e s ,

Inc.:


Section II Transportation Cleaners and Polishes

154

15. Auto Cleaners and Polishes

155

156


A u t o P o l ish/Cl eanser O i l i n Water Emulsion % by Weiqht

Phase A: 1 D e i o n i z e d Water 2 668 P o l i s h i n g Powder 3 V o l c l a y NF-BC Phase 0: 4 PEG-10 Carnauba 5 SF96-350 6 Montan Wax "S" 7 Oleic Acid 8 Morpholine Phase C: 9 Odorless M i n e r a l S p i r i t s

40.5 15.0 1. o 7.0 4.0 2.5 1.5 1 .o 27.5

Procedure: Combine Phase A under a g i t a t i o n and a l l o w t h e V o l c l a y t o h y d r a t e f o r 15 m i n u t e s . B r i n g t e m p e r a t u r e up t o 75C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t e m p e r a t u r e up t o 85C t o m e l t t h e waxes. G e n t l y h e a t t h e m i n e r a l s p i r i t s t o 65C and add t o Phase 0. Once u n i f o r m and a 75C tempe r a t u r e i s reached, s l o w l y add t h i s t o Phase A, m a i n t a i n i n g good a g i t a t i o n . C o n t i n u e m i x i n g u n t i l e m u l s i o n c o o l s t o 40C. Pour i n t o a p p r o p r i a t e c o n t a i n e r s . The PEG-10 Carnauba i n t h i s f o r m u l a h e l p s t o c r e a t e a s t a b l e e m u l s i o n , w h i l e p r e s e r v i n g t h e s t r e n g t h and i n t e g r i t y o f a n a t u r a l carnauba f in i sh. D e t e r g e n t R e s i s t a n t A u t o P o l ish/Cleanser P a s t e Wax 1 2 3 4 5 6 7 8

O d o r l e s s M i n e r a l Spi r i t s 787 P o l i s h i n g Alumina P-10 F e i n s t O z o k e r i t e 170 #3 Carnauba S y n t h e t i c Carnauba SF1706 Hexanedi o l Behenyl Beeswax V i s c a s i l 12M

% by WeiQht 57.0 12.0

8.0 6.0 6.0 5.0 4.0 2.0

Procedure: Combine a l l i n g r e d i e n t s , l e a v i n g o u t t h e alumina, and h e a t t o 8OC. M i x u n t i l homogeneous. Add t h e a l u m i n a w h i l e m i x i n g , and c o o l t o 35c. The #1 Y e l l o w Carnauba i n t h i s f o r m u l a has been r e p l a c e d b y equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba. T h i s s u b s t i t u t i o n has no e f f e c t on t h e f i n i s h e d p r o d u c t and w i l l y i e l d t h e same r e s u l t s . The o n l y d i f f e r e n c e i s a r e d u c t i o n i n c o s t .

SOURCE: K o s t e r Keunen I n c . :


Auto Cleaners and Polishes

157

Carnauba Hotwax Carnauba spraywax w i t h e x c e l l e n t performance and s t a b i l i t y i s produced using: Inaredient : Mineral seal o i l Tomah Emu1s i f ie r Four 9-10 mole ethox. n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Water (70-9OF) Emulsion C-340

Wei aht%

9.0 6.9 0.3 1.3 67.5 15.0

Add i n g r e d i e n t s s e q u e n t i a l l y and mix completely p r i o r t o each a d d i t i o n . The carwash w i l l use t h e "hotwax" by d i l u t i n g 1:lO w i t h water and then i n j e c t i n g 6-8 0 2 . o f t h e d i l u t e product onto each c a r . The product w i l l n o t separate o r g e l l . Pressure Spray Truckwash Wei aht% Water Sodium M e t a s i l i c a t e Pentahydrate EDTA ( l i q u i d 46%) Tomah Q-17-2 Tomah AO-14-2 Texstim 0741 45% Caustic Potash Tomah A l k a l i S u r f a c t a n t

05.7 4.2 1.8 1 .o 1 .o 2.0 2.6 1.7

Texstim 0741 i s a n o n i o n i c s u r f a c t a n t which performs as a " s e l f - d e m u l s i f y i n g " detergent. T h i s i s extremely useful i n truckwash a p p l i c a t i o n s . I n most o i l / w a t e r separators, t h e f o r m u l a t i o n " s p l i t " t h e o i l and water i n t o two phases w i t h o u t f u r t h e r treatment. The o i l phase can then be skimmed o f f f o r recovery o r disposal and n o t be sent t o t h e sewage treatment plant.

SOURCE: Tomah Products,

Inc.:


158


Deterqent Resistant Auto P o l i s h O i l i n Water E m u l s i o n % b v Weight Phase A : 1 D e i o n i z e d Water 44.3 8.0 2 678 P o l i s h i n g Powder 3 V o l c l a y NF-BC 1.o 4 Morpholine 0.7 Phase B: 18.0 5 Isopar L 8.0 6 Isopar M 7 PEG-I0 Carnauba 6.0 8 S i l i c o n y l Beeswax 6.0 9 SF96-350 3.0 10 S t e a r i c A c i d 1.o Phase C : 11 I s o p a r M 5.0 12 SF1706 2.0 Procedure: Combine Phase A under a g i t a t i o n and b r i n g t e m p e r a t u r e up t o 85C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t h e t e m p e r a t u r e up t o 9OC. Once b o t h phases a r e up t o t e m p e r a t u r e , add Phase B t o Phase A and m a i n t a i n moderate a g i t a t i o n . S l o w l y c o o l and a t 60C add Phase C . The S i l i c o n y l Beeswax p e r f o r m s w h i l e a p p l y i n g t h e p o l i s h b y c r e a t i n g a smooth, even c o a t i n g on t h e s u r f a c e o f t h e a u t o m o b i l e . The PEG-10 Carnauba t o g e t h e r w i t h t h e amine f u n c t i o n a l s i l i c o n e , g i v e s t h e p o l i s h e d s u r f a c e a deep g l o s s and an e x t r e m e l y d u r a b l e finish.

High L u s t e r Auto F i n i s h P a s t e Wax % b y Weight 49.0 1 Odorless Mineral S p i r i t s 14.0 2 Isopar L 10.0 3 Isopar M 8.0 4 SF96-350 5 #3 Carnauba 6.0 6.0 6 S y n t h e t i c Carnauba 7 O z o k e r i t e 170 3.0 8 W h i t e Beeswax 2.0 9 V i s c a s i l 12M 2.0 Procedure: Combine a l l waxes and s i l i c o n e s . Heat t o 85C. W h i l e m i x i n g , s l o w l y add t h e s o l v e n t s . C o n t i n u e m i x i n g and c o o l t o 40C. Equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba a r e used w i t h t h e i n t e n t i o n s o f these b e i n g a d i r e c t s u b s t i t u t e f o r #1 Y e l l o w Carnauba. The #3 Carnauba and S y n t h e t i c Carnauba w i l l y i e l d t h e same r e s u l t s as #1 Y e l l o w Carnauba, b u t a t a s i g n i f i c a n t cost savings.

SOURCE: K o s t e r Keunen I n c . :


Auto Cleoners ond P o l i s h

H i g h Gloss,

159

Detergent Resis t a n t P o l i s h

F o r m u l a t i o n 20-6 i s a w a x - f r e e p o l i s h , w h i c h p r o v i d e s a h i g h g l o s s , d e t e r g e n t r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . Simple a p p l i c a t i o n , w i t h o u t h a r d r u b b i n g o r b u f f i n g r e s u l t s i n b o t h d e p t h o f g l o s s and d e t e r g e n t r e s i s t a n c e f o r extended properties. Ingredients: ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-10-1,000 S i l i c o n e F l u i d ( 3 ) Stoddard S o l v e n t ( 4 ) Mineral S p i r i t s (Odorless) ( 5 ) Witcamide 511 ( 6 ) K a o p o l i t e SF (7) S o f t Water ( 8 ) Giv-Gard DXN

% by weight

13.0 2.0 5.5 5.5 1.4 5.0 67.5 0.1

,

Combine i n o r d e r shown w i t h h i g h shear m i x i n g u n t 1 t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package. Formul a t i on P r o p e r t i e s : * C o n t a i n s no wax *High g l o s s *Detergent r e s i s t a n t *Easily applied

*Non-smeari ng *Cost e f f i c i e n t *Cold b l e n d ( 0 n l y mix ng r e q u i r e d ) * R e s i s t a n t t o wash-o f

Formula 20-6 High Gloss Auto P o l i s h f F i n i s h Ingredients: ( 1 ) GP-121 ( S i l i c o n e P o l i s h A d d i t i v e ) ( 2 ) Witcamide 511 (3) K a o p o l i t e SF ( 4 ) S o f t Water ( 5 ) Giv-Gard DXN

% by. Weight

26.0 1.4 5.0 67.5 0.1

Combine i n o r d e r shown w i t h h i g h shear m i x i n g u n t i l t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package. Formulation Properties: * C o n t a i n s no wax *High g l o s s *Detergent r e s i s t a n t *Easi 1y appl i e d *Non-smeari ng *Cost e f f ic i e n t *Cold b l e n d Only m i x i n g r e q u i r e d Formula 20-5

SOURCE: Genesee Polymers C o r p . :


160


Spravwax Concentrate The f o l l o w i n g formula should produce a c l e a r , s t a b l e spraywax concentrate. Comonent: Kerr-McGee Mineral seal o i 1 Emul s i f ie r 827 Ethylene g l y c o l monobutyl e t h e r Water (70-9OF)

Grams 18.0 15.0 4.0

63.0

D i r e c t ions : Charge t h e mineral seal o i l , E m u l s i f i e r 827, ethylene g l y c o l monobutyl e t h e r and m i x u n t i l c l e a r . Add water s l o w l y w h i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f d e s i r e d . A d d i t i o n o f a fragrance may r e q u i r e a s l i g h t f o r m u l a t i o n change. The f i n a l product w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e 5 g a l l o n s o f concentrate w i t h 50 g a l l o n s o f water and then i n j e c t about 6 0 2 s . o f t h e d i l u t e spraywax through a DEMA system onto each c a r . Spraywax The f o l l o w i n g t y p i c a l f o r m u l a t i o n i s h i g h l y e f f e c t i v e , problem f r e e , and s t a b l e i n b o t h concentrate and d i l u t e form. Inaredient : Kerr McGee Mineral Seal O i l Emul s i f ie r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Tap Water

Weiaht % 20.0 15.0 1 .o 3.0 61 . O

Directions: Charge t h e mineral seal o i 1, E m u l s i f i e r Four-HF, e t h o x y l a t e d n o n i o n i c , ethylene g l y c o l monobutyl e t h e r and mix u n t i l c l e a r . Add water s l o w l y w h i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f d e s i r e d . A d d i t i o n o f a f r a g rance may r e q u i r e a s l i g h t f o r m u l a t i o n change. The f i n a l product w i l l be c l e a r and i s normally packaged i n 5 g a l l o n p a i l s . The carwash should d i l u t e 5 g a l l o n s o f concentrate w i t h 50 g a l l o n s o f water and then i n j e c t about 6 0 2 s . o f t h e d i l u t e spraywax through a DEMA system onto each c a r .

SOURCE: Tomah Products, I n c . : Suggested Formulations

Auto Cleaners and Polishes

161

Spravwax Ladder of Formulas Because mineral seal o i l s a c t e r i s t i c s , i t i s necessary achieve optimum performance. mined by r u n n i n g a ladder o f

d i f f e r i n e m u l s i f i c a t i o n chart o modify t h e f o r m u l a t i o n t o The best formula can be d e t e r formulas. T y p i c a l examples are:

Comonent: Mineral seal o i l Emul s i f ie r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Water

Grams-B 40.0 31 . O 1 .o 6.0 122.0

Component: M i n e r a l seal o i l Emul s i f ie r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl ether Water

Grams-C 40.0 30.5 1.5 6.0 122.0

Comoonent: Mineral seal o i l E m u l s i f i e r Four-HF 9-1 0 mole e t h o x y l a t e d noni oni c Ethylene g l y c o l monobutyl e t h e r Water

Grams-D 40.0 30.0 2.0 6.0 122.0

Components: Mineral seal o i l Emul s i f i e r Four-HF 9-10 mole e t h o x y l a t e d n o n i o n i c Ethylene g l y c o l monobutyl e t h e r Water

Grams-E 40.0 29.5 2.5 6.0 122.0

Check a l l formulas f o r : 1 . 1 : l O d i l u t i o n i n water. 2 . 120F s t a b i l i t y ( 3 hours i n sealed c o n t a i n e r i n water b a t h a t 120F). 3 . Freeze/thaw-24 hour recovery ( s e a l e d c o n t a i n e r ) . The optimum formula w i 11 : 1. D i l u t e c l e a r and e a s i l y a t 1:lO d T l u t i o n . 2. Not c l o u d a t . 120F. 3. Recover completely from freeze/thaw c y c l e ( w i t h o u t shaking).

SOURCE: Tomah Products, I n c . : E m u l s i f i e r Four-HF:

Formulas

16. Car and Truck Wash Compounds

162

Car and Truck Wash Compounds

163

Automatic Car Wash Concentrate A High A l k a l i n e D i l u t a b l e Concentrate

Wt.% Inaredient : Oeioni zed Water 50.00 Maphos 60-A 6.00 Potassi um Hydroxide 3.00 Tetrapotassium Pyrophosphate 2.00 Sodium M e t a s i l i c a t e , Anhydrous 2.00 Macol LF-120 2.00 Mazamide 80 2.00 Sodium Xylene S u l f o n a t e (40%) 3.00 Macol 48 3.00 27.00 Oei oni zed Water pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.06 Procedure: Charge t h e f i r s t water p o r t i o n t o t h e m i x i n g vessel and s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e given sequence and mix u n t i l c l e a r . Notes : T h i s i s a h i g h l y a l k a l i n e cleaner designed t o be used i n commercial automatic c a r washes a t a d i l u t i o n r a t e o f 1-2 ounces per g a l l o n . Do n o t use d i r e c t l y on automotive f i n i s h e s . Formula CA-102 General Purtmse Car Wash High Foami ng A1 1-Purpose D i 1u t a b l e Concentrate W% .t Ineredi ent : Deioni zed Water 50.00 Mazon 98 9.50 Macol TD-3 1.50 SLS (Sodi um Lauryl S u l f a t e ) 2.50 Mazamide 80 3.00 1 .oo Macol 48 Triethanolamine (85%) 1.50 Deionized Water 31 .OO pH (as i s ) : 8 . 5 - 9 . 5 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.02 Procedure: Charge t h e f i r s t p o r t i o n o f water t o t h e m i x i n g vessel and s t a r t slow a g i t a t i o n . Excessive a g i t a t i o n w i 11 produce a foami ng problem. Add t h e remaining i n g r e d i e n t s i n t h e g i v e n sequence and mix u n t i l c l e a r . Notes: T h i s i s a copious-foaming, a l l - p u r p o s e c a r wash formulated t o be s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f road grime and o t h e r s o i l s . Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm water. Formula CA-103

SWRCE: Mazer Chemicals: Supposted Formulations

164

Advanced Cleaning R h c t Formulations

Auto Shampoo Concentrate % by Weight

80.0 15.0 5.0

Water, D.I. Rewoteric AM KSF-40 W i t c o l a t e SE-5 Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4.0 S o l i d s : Q.O% pH: 9 . 5 Formula 628 High Foaming Car Wash

% by Weight 65.0 5.0 15.0 10.0 1. o 1.o

Water, D.I. D i ethanol ami ne Witco 1298SA Varox 1770 Butyl Cellosolve Sodi urn Metasi 1i c a t e Sodium Tripolyphosphate

3.0

01endi ng Procedure: Add DEA t o water and mix thoroughly. Slowly d i s s o l v e Witco 1298 i n t o s o l u t i o n . Next, add remai n i ng i n g r e d i e n t s a1 l o w i ng t o d i s s o l v e completely between a d d i t i o n s . T y p i c a l Propert ies : V i s c o s i t y . cps: 77.0 S o l i d s : 27.5% pH: 9.3 Formula 631 Car Wash % by Wei aht

Water Witcolate A W i t c o l a t e S-l285C Emcol NA-30 Preservative Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Typi c a l Propert ies : S o l i d s : 28.4% pH: 6.9 V i s c o s i t y , cps: Gel Formula 623 SOURCE: Witco Corp.: Suggested Formulations

34.9 25.0 25.0 15.0 0.1

Car and l h c k Wash Compowrds

165

Car Wash L i q u i d Formula TR-0023 W t .% 6.0

A1 k y l benzene s u l f o n i c a c i d Sodium x y l e n e s u l f o n a t e I g e p a l CO-710 T e t r a p o t a s s i u m p y r o p h o s p h a t e (60% a c t i v e ) Potassium h y d r o x i d e (45% a c t i v e ) Water

11.5 3.0 25.0 2.5 52.0

Procedure 1 D i s s o l ve a1 k y l benzene s u l f o n i c a c i d i n w a t e r . 2 . A d d sodium x y l e n e s u l f o n a t e , I g e p a l CO-710, t e t r a p o t a s s i u m p y r o p h o s p h a t e and p o t a s s i u m h y d r o x i d e , m i x i n g w e l l a f t e r each a d d i t i o n . 3. F i l t e r p r o d u c t .

.

Physical Properties pH ( a s i s ) : 9 . 5 pH ( 1 % ) : 9 . 9 V i s c o s i t y : 1 0 cps S p e c i f i c G r a v i t y : 1 .05 Car Wash Powder Formula TR-0022 W t .%

Igepal Sodi um Sodium Sodium

10.0 50.0 5.0 35.0

CO-710 tripolyphosphate m e t a s i l i c a t e pentahydrate carbonate ( L t . d e n s i t y )

Procedure: 1 . M i x I g e p a l CO-710 w i t h sodium t r i p o l y p h o s p h a t e . 2 . Add sodium m e t a s i l i c a t e p e n t a h y d r a t e and sodium c a r b o n a t e Physical Properties: Appearance: W h i t e , f r e e - f l o w i n g powder pH ( 1 % ) : 1 1 . 2 Specific Gravity: 0.73


Formulas

166

Advanced Cleaning Product Formulotiom

Economy T r u c k Wash H i g h - p r e s s u r e Spray (Formula TR-0024) W t .% 3.0 1.o 1.5 84.5

I g e p a l CO-660 Cheel ox BF-13 Sodi um Xylene Sul f o n a t e Water Procedure 1 . D i s s o l v e sodium xy ene s u l f o n a t e n w a t e r . 2. Add I g e p a l CO-660. M i x t h o r o u g h l y . Add Cheelox BF 13. P h y s i c a l Properti-eg pH ( a s i s ) : 1 0 . 3 DH ( 1 % ) : 10.1 V i s c o s i t y : 10 c p s Speci f ic G r a v i t y : 1 . 0 2 T r u c k Wash L i q u i d Formula TR-0025

W t .%

3.0 3.5 2.0 3.5 3.0 85.0

I g e p a l CO-630 Rhodapex CO-436 A1 kami de DC-212/S Cheelox BF-13 E t h y l e n e G l y c o l Monobutyl E t h e r Water Procedure 1 . D i s s o l v e s u r f a c t a n t s I g e p a l GO-630, Rhodapex CO-436 and A1 kami de DC-212/5 in w a t e r . 2 . Add Cheelox BF-13. M i x w e l l . 3. Add e t h y l e n e g l y c o l monobutyl e t h e r . P h y s i c a l PrQpe-rti 8 9 pH ( a s i s ) : 9 . 9 pH ( 1 % ) : 9 . 6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.01

SOURCE:

Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s :

Formulas

Gar and h

Foamy Brush Car Wash.

k Wash Compounds

167

Liquid % by Weight

Water, D . I . * Caustic Soda, 50% Witco 1298SA W i t c o l a t e SE-5 Petro BAF L i q u i d W i tcami de 128T Formal i n Sodium C h l o r i d e

79.75 1.40 5.00 7.00 3.00 3.00 0.10 0.75

Blending Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Sodium C h l o r i d e i s used t o a d j u s t v i s c o s i t y o f t h e product. T y p i c a l Propert ies: S p e c i f i c G r a v i t y : 1.015 Wt./Gal. l b s . : 8.46 pH, as i s : 9.8 V i s c o s i t y , cps: 410 D i l u t i o n R a t i o a t Wand = 1:40 * I f unsoftened t a p water i s used, 40% t o counteract hardness.

add 0.25% l i q u i d EDTA,

Formula 621

1:2 D i l u t a b l e Car Wash Water Sodium Hydroxide, 50% Witconate SXS (40%) Witco 12988 W i tcami de 128T W i tcami de CDA Blend4 ng Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Typi c a l P r o p e r t ies : S o l i d s : 54.0% pH. as i s : 8.5 V i s c o s i t y , as i s , cps: 580 V i s c o s i t y , 1:2. cps: 440 Formula 622


Sugueated Formulations

% by Weight 33.71 5.96 14.90 25.88 16.76 2.79

I68


High O i l S p l i t t i n g V e h i c l e Wash-A % by Weiqht 71.5 10.0 2.5

Components: Water Sodium M e t a s i l i c a t e Pentahydrate TKPP Sodi um Xylene Sul fonates 40% Burco TME

6.0 10.0

Add i n t h e o r d e r l i s t e d . Blend u n t i l d i s s o l v e d between each addition. High O i l S D l i t t i n g V e h i c l e Wash-B Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burcosol ADS-40 G l y c o l Ether Burco TME Burcotrope 1250

% by Weiqht 73.5 10.0

5.0 5.0 10.0 As Required

Add i n t h e order l i s t e d . Blend u n t i l d i s s o l v e d between each addition.



Car and Truck Wosh Cornpout&

169

L i aui d Car Wash Formula TR-0020 Formula A

WtT%

Rhodapon SB Alcodet SK Rhodasurf 25-9 Tetrapotassium pyrophosphate Sodi um metasi 1i c a t e Water Perfume Dye

18.0 8.0

---

3.0 2.0 69.0 Q.S. Q.S.

Formula

B

wtT% 18.0

----

8.0 3.0 2.0 69.0 Q.S. Q.S.

Procedure D i s s o l v e t e t r a p o t a s s i u m pyrophosphate and sodium m e t a s i l i c a t e i n water. Add Rhodapon SB. A g i t a t e u n t i l c l e a r . Add Alcodet SK and Rhodasurf 25-9 and mix u n t i l u n i f o r m and c l e a r . Add perfume and dye, as d e s i r e d . Physical ProDertiea Appearance: Clear l i q u i d , pH: 12.0 S p e c i f i c G r a v i t y : 1.03 V i s c o s i t y : t 5 0 cps

dyed t o preference

Spray-On Car Wash Concentrate "Grease and Grime" Remover Formula TR-0021

Wt.% 5.0 20.0 3.3 5.0

Rhodacal A-246/L Rhodacal 330 Rhodapon BOS Alcodet SK Water

66.7

Procedure: 1. Charge water t o a vessel equipped w i t h a g i t a t i o n . 2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l u n i f o r m (5-10 minutes). 3. Add Rhodacal 330 and Alcodet SK t o ( 2 ) above. Mix u n t i l u n i f o r m (15-30 minutes). Phvsi ca 1 P r o p e r t i g p Appearance: Viscous, gel -1 ike 1i q u i d pH. as i s : 9.0 S p e c i f i c G r a v i t y : 1.02-1.04 V i s c o s i t y : t50 cps

SOURCE: Rhone-Poulenc S p e c i a l t i e m

a

S u r f a c t m t m : Formulas

I70 Advanced Cleaning Product Formulotions L i q u i d Hiah Pressure Concentrate % by Weiaht

46.0

Water, D.I. Oowanol EB Witconate SXS L i q u i d Sodium Benzoate Sodium M e t a s i l i c a t e Tetrapotassium Pyrophosphate Varion AM-KSF-40%

2.0 1 .o 1 .o

10.0 20.0 20.0

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 1 5 S o l i d s : 39.4% pH: 13.4 Formula 605 Truck Wash w/Vararide A-83 % by Weight

Water, D . I . Sodium Tripolyphosphate T r i sodi um Phosphate Sodium M e t a s i l i c a t e Varami de A-83 B u t y l C e l l osol ve Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 1 2 S o l i d s : 16.0% pH: 11.0 Formula 608



81 . o 3.0

3.0 1 .o 9.0 3.0

Car and Truck Wash Compounds

171

L i q u i d T r u c k Wash Formula TR-0029

Wt.% Water M i r a n o l FBS I g e p a l CA-630 Dowanol EB (Dow Chemical ) P o t a s s i um H y d r o x i d e (45%) Tall O i l T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e , P e n t a h y d r a t e

73.6 6.0 3.0 2.0 4.0 3.4 4.0 4.0

Procedure Premix t h e t a l l o i l and Dowanol EB. Add t h e w a t e r t o t h e m i x e r . Add t h e sodium m e t a s i l i c a t e , t h e p o t a s s i u m h y d r o x i d e and t h e TKPP. Add t h e M i r a n o l FBS and I g e p a l CA-630. Add t h e t a l l o i l / D o w a n o l EB p r e m i x . M i x u n t i l u n i f o r m . Physical ProDerties Appearance: C l e a r , amber l i q u i d pH, as i s : 12.7 S p e c i f i c G r a v i t y : 1.08 V i s c o s i t y : 6 0 cps L i q u i d T r u c k Wash Formula TR-0030 Water M i r a n o l FBS Rhodafac RA-600 I g e p a l CA-720 Cheel ox BF-13 T e t r a p o t a s s i um Pyrophosphate P o t a s s i um H y d r o x i d e (45%) Sodium M e t a s i l i c a t e P e n t a h y d r a t e A r c o s o l v PTB

Wt% . 63.0 4.0 2.0 2.0 17.5 1.o 6.0 2.0 2.5

Procedure Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l u n i f o r m . Phvsl c a l P r o o e r t i es Appearance: C1e a r , ye1 1ow 1 iq u i d pH, as i s : 12.9 S p e c i f i c G r a v i t y : 1.10 V i s c o s i t y :
SOURCE:

Rhone-Poulenc S u r f a c t a n t s & Spec a1t i 8s : Formu as

172


M i l d Car Shampoo A m i l d r i c h foaming c a r shampoo w i t h e x c e l l e n t d e t e r g e n c y and sheeting a c t i o n , I n a r e d ients: % ComDosi t o n W / W Sandobet SC 4.5 DDBSA, 60% 10.8 S a n d o x y l a t e SX-424 3.6 Triethanolamine 0.8 Dye, F r a g r a n c e , P r e s e r v a t i v e , Water Q.S. Procedure: Charge w a t e r t o m i x i n g v e s s e l w i t h moderate a g i t a t i o n . H o l d o u t s m a l l p o r t i o n o f t h e w a t e r t o d i s s o l v e dye. Charge t h e r e m a i n i n g components i n sequence, m i x i n g a f t e r each a d d i t i o n . D i s s o l v e t h e dye w i t h a g i t a t i o n i n t h e w a t e r p r e v i o u s l y h e l d o u t and add t o t h e p r o d u c t . Properties: Appearance: C1 e a r 1 iq u i d pH: 7 . 0 - 8 . 0 A p p l i c a t i o n : Use 1 t o 2 o z p e r 5 g a l l o n b u c k e t SOURCE: Sandoz Chemicals Corp. : F o r m u l a t i o n HHA-01

C a r s p r a y CW C o n c e n t r a t e % b y Weight 80.0 Water, D . I . Carspray CW 20.0 B l e n d i n g Procedure: Add C a r s p r a y t o w a t e r w h i l e m i x i n g . C o n t i n u e m i x i n g u n t i l s o l u t i o n i s homogeneous. Typical Properties: S o l i d s : 11.6% Formula 632

A u t o m o t i v e "Wash 8 Wax" % by Weiqht Witcamine AL42-12 6.9 Isopropanol 1.o Glacial Acetic Acid 2.1 Water 65.0 Witcamide 5195 25.0 B l e n d i n g Procedure: M i x a l l i n g r e d i e n t s e x c e p t Witcamide 5195 i n t h e o r d e r l i s t e d . Heat t h e m i x t u r e t o 70C and t h e n add Witcamide 5195. C o n t i n u e mixing u n t i l solution i s clear. T h i s f o r m u l a t i o n l e a v e s a w a t e r " b e a d i n g " f i l m on t h e a u t o mobile f i n i s h , Formula 636



Car and Truck WaFh Compounds

I73

Premium CarsDrav 500 C o n c e n t r a t e ?6 b y Weight

20.0 5.0 25.0

C a r s p r a y 500 B u t y l C e l l o s o l ve M i n e r a l Seal O i l * Water, D . I .

50.0

*Kermac 600 S o l v e n t : K e r r McGee O i l Co. D i a l a A O i 1 : Shel 1 Chemical I s o p a r V : Exxon Chemical B1e n d i ng Procedure : Combine Carspray, B u t y l C e l l o s o l v e and O i l i n v e s s e l and mix t h o r o u g h l y . I n a s e p a r a t e v e s s e l weigh i n t h e w a t e r . W h i l e m i x i n g t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s homogeneous. Use D i l u t i o n : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r . Comments: C a r s p r a y 500: Beading Agent w i t h s i l i c o n e . Formula 687 S t a n d a r d C a r s p r a y 500 C o n c e n t r a t e % b y Weipht

16.0

C a r s p r a y 500 B u t y l Cel l o s o l v e M i n e r a l Seal O i l * Water, D . I .

3.0 20.0 61 .O

*Kermac 600 S o l v e n t : K e r r McGee O i l Co D i a l a A O i 1 : Shel 1 Chemical I s o p a r V : Exxon Chemical 81 e n d i ng P r o c e d u r e : Combine Carspray, B u t y l C e l l o s o l v e and O i l i n v e s s e l and m i x t h o r o u g h l y . I n a s e p a r a t e v e s s e l weigh i n t h e w a t e r . W h i l e m i x i n g t h e water, pour i n t h e b l e n d . Mix u n t i l s o l u t i o n i s homogeneous. Use D i 1u t i on : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r . Comments : C a r s p r a y 500: Beading Agent i n s i l i c o n e Formula 688

SOURCE: W i t c o Corp.:


174


Premium Carspray 700 C o n c e n t r a t e %_by Wei q h t 25.0 25.0 50.0

Carspray 700 M i n e r a l Seal O i l * Water, D . I . *Kermac 600 S o l v e n t : K e r r McGee O i l Co. D i a1 a A O i 1 : She1 1 Chemical I s o p a r V : Exxon Chemical

B l e n d i n g Procedure: I n v e s s e l #1, combine Carspray 700 and M i n e r a l Seal O i l and h e a t t o l l O F w i t h t h o r o u g h m i x i n g . I n v e s s e l #2, weigh i n t h e w a t e r and mix u n t i l a v o r t e x i s formed. W h i l e m i x i n g t h e w a t e r , p o u r t h e b l e n d i n t o t h e v o r t e x . M i x u n t i l s o l u t i o n i s homogeneous.

Use D i l u t i o n : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r .

Comments : Carspray 700:

Foaming b e a d i n g agent

Formula 685 S t a n d a r d Carspray 70-0 C o n c e n t r a t e

%uYA ! h t

16.0 16.0 68.0

Carspray 700 M i n e r a l Seal O i l * Water, D . I . *Kermac 600 S o l v e n t : K e r r McGee O i l Co. D i a l a A O i l : S h e l l Chemical I s o p a r V : Exxon Chemical

B l e n d i n g Procedure: I n v e s s e l #1, combine Carspray 700 and M i n e r a l Seal O i l and h e a t t o l l O F w i t h t h o r o u g h m i x i n g . I n v e s s e l #2, weigh i n t h e w a t e r and mix u n t i l a v o r t e x i s formed. W h i l e m i x i n g t h e w a t e r , p o u r t h e b l e n d i n t o t h e v o r t e x . M i x u n t i l s o l u t i o n i s homogeneous.

Use D i l u t i o n : 5 g a l l o n s C o n c e n t r a t e t o 50 g a l l o n s w a t e r .

Comments : Carspray 700:


Formula 686

SOURCE: W i t c o Corp.:


17. Whitewall Tire Cleaners

175

176


W h i t e Wal 1 T i r e C l e a n e r

%by.Wt.

Ingredients: Sodium M e t a s i 1 i c a t e Sodium T r i p o l y p h o s p h a t e Tetrapotassium Pyrophosphate Sodium L a u r y l E t h e r S u l f a t e S o l i n (35%) Sandopan B Water (warm)

2.00 2.00 2.00 4.00 2.30 5.00

83.00

Procedure: Charge t h e w a t e r t o a v e s s e l w i t h good a g i t a t i o n . Charge t h e f i r s t t h r e e components and m i x t i l l d i s s o l v e d . Charge t h e r e m a i n i n g p r o d u c t s and m i x t i l l comp e t e l y d i s s o l v e d and f r e e o f g e l particles. Physical Properties: Appearance: C l e a r w a t e r whi e t o l i g h t y e l l o w l i q u i d p H ( a s i s ) : >9.0 T o t a l S o l i d s : 11.0-12.0% Use L e v e l s : F o r f i n a l use,

d i l u t e between 4:l and B : l w i t h w a t e r

SOURCE: Sandoz C h e m i c a l s C o r p . :

F o r m u l a t i o n HHA-03

Bug Remover C o n c e n t r a t e % by W e i . a

17.14 42.86 17.14 22.86

T r i e t h a n o l a m i ne (TEA) Butyl Cellosolve Isopropanol R e w o t e r i c AM 8-15

81 e n d i n g P r o c e d u r e : B l e n d t h e components i n t h e o r d e r shown. M i x u n t i l homogeneous D i l u t i o n Rates: 1 : 2 E x t r a Heavy D u t y 1 : 4 Heavy D u t y 1 : 16 Medi um D u t y 1 :32 L i g h t D u t y

D i 1 u t i on I n s t r u c t i o n s : Add Bug Remover C o n c e n t r a t e t o w a t e r w h i l e m X i n g ; m i x i n g u n t i l homogeneous. Comments: Appearance @ 7 7 F : C r y s t a l c l e a r , SOURCE: W i t c o C o r p . :

Formula 677

yellow l i q u d

continue

Whitewall Ere Cleaners

177

Whitewall T i r e Cleaner Concentrate Formula TR-0031

Wt.% Water M i r a n o l FBS Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Potassium H y d r o x i d e (45%) Butoxyethanol

48.0 22.0 25.0

3.0 2.0

Procedure Add i n g r e d i e n t s i n o r d e r l i s t e d . M i x u n t i l u n i f o r m . Physical ProDerties Appearance: C l e a r , y e l l o w l i q u i d pH, as i s : 12.7 V i s c o s i t y : <50 cps S p e c i f i c G r a v i t y : 1.16

W h i t e w a l 1 T i r e C1eaner L i aui d Formula TR-0027

Wt.% 2.0

I g e p a l CA-630 Rhodafac RA-600 M-Pyrol N - M e t h y l - 2 - P y r r o l i d o n e ( I S P ) Sodium M e t a s i l i c a t e , Anhydrous Sodi um T r i p o l y p h o s p h a t e P o t a s s i um H y d r o x i d e Water

6.0 2.0 3.0 5.0 1.5 80.5

ProceduPQ 1. D i s s o l v e sodium m e t a s i l i c a t e , anhydrous, sodium t r i p o l y phosphate and p o t a s s i u m h y d r o x i d e i n t o w a t e r . 2. Add I g e p a l CA-630, Rhodafac RA-BOO, and M-Pyrol s e p a r a t e l y , m i x i n g w e l l a f t e r each a d d i t i o n . Physical ProDertiea pH ( a s i s ) : 13.3 pH (1%): 10.7 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.03

SOURCE;

Rhone-Poulenc S u r f a c t a n t s

a

Specialties:

Formulas

18. Miscellaneous

178

Miscellaneous

179

Automobi 1e W i n d s h i e l d C l e a n e r s % by Weiaht

Inaredients: A e r o s o l MA-80 S u r f a c t a n t S u r f o n i c N-95 Isopropanol Water

3.5 0.5

51 .o 45.0

The above i s d i l u t e d 5 oz. t o 1 g a l l o n o f w a t e r f o r use. I n w i n t e r t i m e , t h e recommended d i l u t i o n i s 10 oz. p e r g a l l o n . Thi s f o r m u l a t i o n leaves F r e e z i ng i s p r e v e n t e d by t h e isopropanol a s m a l l amount o f r e s i d u e on t h e unwiped p o r t i o n o f t h e winds h i e l d upon d r y i n g . There a r e s e v e r a l ways o f p r e v e n t i n g t h e s e v i s i b le residues.

.

1 . Use a m i x t u r e o f v o l a t i l e s o l v e n t s w i t h o r w i t h o u t s u r f a c t a n t s . A suggested f o r m u l a t i o n i s :

Inaredients: 2 - E t h y l Hexanol A e r o s o l OT-75% S u r f a c t a n t Isopropanol Water

% by Weiaht 5.0 1. o 47.0 47.0

The above i s d i l u t e d 5-10 0 2 . p e r g a l l o n o f w a t e r , not freeze a t t h e higher l e v e l o f concentration.

and w i l l

2. U s i n g s u r f a c t a n t s , b u t i n c l u d i n g s m a l l amounts o f nonv o l a t i l e s o l v e n t s which g i v e a t r a n s p a r e n t f i l m on t h e g l a s s w i t h t h e s u r f a c t a n t . N o n - v o l a t i l e s o l v e n t s having approximately t h e same r e f r a c t i v e i n d e x o f g l a s s s h o u l d be s e l e c t e d . A suggested f o r m u l a t i o n i s : Innredients: A e r o s o l MA-80 S u r f a c t a n t A e r o s o l OT-75% S u r f a c t a n t Diethylene Glycol Isopropanol n-Butyl-p-Hydroxy Benzoate Methyl-p-Hydroxy Benzoate Water

% by Weight 2.5

3.3 4.4 40.0 0.1 0.1 49.78

The above c o n c e n t r a t e i s used a t 5 02. p e r g a l l o n ( 1 0 0 2 ' . p e r g a l l o n i n w i n t e r ) . The b a c t e r i c i d e s a r e p r e s e n t t o keep t h e window c l e a n i n g s o l u t i o n f r e e o f s l i m e and t u r b i d i t y due t o bacteria. % by Weight Inaredients: A e r o s o l OT-75% S u r f a c t a n t 3.5 Dibutyl phthalate 0.5-2.0 Isopropanol 40.0 Water 46-48 The above s o l u t i o n i s d i l u t e d 5-10 02. p e r g a l l o n o f w a t e r and w i l l n o t f r e e z e a t t h e h i g h e r l e v e l o f c o n c e n t r a t i o n .



180


General PurDose L i q u i d B o a t P o l i s h - ( 1

1

Materials: P a r t A: SF 96 (350) V i s c a s i 1 (10,000) Oleic acid Isopar M Hoechst Wax E P a r t B: Water Morphol ine Carbopol 9 3 4

Part/Wt

(%Z

3.50 1 .oo 1.50 10.00 1.50 65.65 1.60 0.25

P a r t C: Isopar M S F 1706

3.00 2.00

P a r t D: Snow Floss Super F l o s s

7.50 2.50 General Purpose L i q u i d Boat P o l i s h - ( 2 )

M a t e r i a1 s : P a r t A: S F 96 (350) V i s c a s i 1 ( 10,000) Oleic acid Isopar M Hoechst Wax E

Part/Wt(%)

P a r t B: Water Morphol ine Carbopol 934 Part C: Isopar M SF 1706 P a r t D: Kaopol it e 1 1 68 Procedure: 1.) Heat P a r t A t o 90-95C. (2.) Heat P a r t B t o 60-85C. 3.) Add P a r t A t o P a r t B w i t h good m i x i n g . 4 . ) When homogeneous, c o o l t o 60-65C and add P a r t C w i t h c o n t i n u e d h i g h shear m i x i n g . 5.) Add P a r t D w i t h good m i x i n g . 6.) When u n i f o r m , c o o l and package i n s u i t a b l e c o n t a i n e r s

SOURCE: GE S i l i c o n e s : Formula BP 2000

3.50 1 .oo 1.50 10.00 1.50 63.65 1.60 0.25 3.00 2.00 12.00

Miscellaneous

181

L i a u i d Aluminum Engine B l o c k C l e a n e r Formula TR-0032 Water Sodium M e t a s i 1 i c a t e , Anh M i r a n o l FBS M i r a n o l JEM Conc. A l c o d e t HSC-1000 D-Limonene

W t .% 82.5 4.5 5.0 2.0 4.0 2.0

Procedure C o m p l e t e l y d i s s o l v e t h e sodium m e t a s i l i c a t e i n t h e w a t e r Add t h e r e m a i n i n g components, w i t h a g i t a t i o n , i n t h e o r d e r l i s t e d . Premix t h e 0-Limonene w i t h t h e A l c o d e t HSC-1000 and add t o g e t h e r . T y p i c a l P r o p e r t J es Appearance: C l e a r , y e l l o w t o amber l i q u i d pH, Conc.: 1 2 . 7 5 pH, 10%: 12.15 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : t50 cps Foami ng Engi ne C1eaner Formula TR-0019 W t .%

A l c o d e t 260 Rhodacal 330 Water I s o p a r " K " (Exxon)

2.0 8.0 80.0 10.0

Procedure 1 . Add A l c o d e t 260 and Rhodacal 330 t o w a t e r a t ambient tempe r a t u r e , s t i r u n t i l d i s s o l v e d (10-15 m i n u t e s ) . 2 . Add I s o p a r K a t ambient t e m p e r a t u r e . S t i r u n t i l d i s s o l v e d (30 minutes)

.

Physi c a l P r o e e r t i es Appearance: C l e a r l i q u i d pH, as i s : 7 . 5 Speci f ic G r a v i t y : 0 . 9 9 V i s c o s i t y : 10 cps


Section 111 Trademarked Raw Materials

182

Trademarked Raw Materials

183

SOURCE

RAW MATERIALS AC-325 N o n i o n i c

CHEMICAL DESCRIPTION Polymer

Allied

ACL-59

Chlorinated isocyanurate

Monsanto

A c r y s o l ICS-1

Water-soluble a c r y l i c r e s i n

Rohm&

Aerosol A-102

Mono-ester s u l f o s u c c i n a t e surfactant

Cytec

Aerosol A-1 03

Mono-ester s u l f o s u c c i n a t e surfactant

Cytec

A e r o s o l C-61

A1 k y l ami ne-guani d ne e t h o x y l a t e

Cytec

A e r o s o l GPG

Sodium d i o c t y l su f o s u c c i n a t e

Cytec

A e r o s o l MA-80

Sodium d i h e x y l su f o s u c c i n a t e

Cyt ec

A e r o s o l 0s

A1 k y l n a p h t h a l a n e o x i d e s u l f o n a t e

Cytec

A e r o s o l OT

Sodium d i o c t y l su f o s u c c i n a t e

Cytec

A e r o s o l OT-B

Sodium d i o c t y l s u l f o s u c c i n a t e

Cytec

A e r o s o l OT-75%

Sodi um d i o c t y l s u l f o s u c c i n a t e ( 75%) Cytec

A e r o s o l OT-100%

Sodi um d i o c t y l s u l f o s u c c i n a t e

Cytec

A e r o s o l 22

Sul f o s u c c i namate

Cytec

A l c o d e t HSC-1000

Tertiary thioether surfactant

Rhone-

A l c o d e t SK

Cleaning s u r f a c t a n t

Rhone-

A l c o d e t 260

Cleaning s u r f a c t a n t

Rhone-

A1 kami de DC-212

F a t t y a1 kanolamide

ISP

A1 kami de DC-212/M

F a t t y a1 kanolamide

ISP

A1 kamide DC-212/S

F a t t y a1 k a n o l a n i d e

ISP

Laurami ne o x i d e

Stepan

AF 9020

Aluminum Oxide FPTO Ammonyx LO

184


RAW MATERIALS Amphol y t JB130

CHEMICAL DESCRIPTION Coconut f a t t y a c i d amidopropyl b e t a i ne

SOURCE Huls

A n t a r o x BL-225

Aliphatic polyether nonionic

Rhone-


A l i p h a t i c p o l y e t h e r non o n i c

Rhone-


A l i p h a t i c p o l y e t h e r non o n i c

Rhone-

A r c o s o l v PTB

Sol v e n t

Arco

Avanel N-1525-90

Surfactant

PPG

Avanel S-70/5-74/ S-l50/590

Sodi urn 1 inear a1 k y l p o l y e t h e r sulfonate surfactant

P PG

BASF S u r f a c t a n t s

Pluronic,

BASF

B r i t e s i l H24

Hydrous s o d i um s i 1ic a t e

Aquamoll i n BC Powder

Plurafac,

Industrol

PQ

B u r l ng-

Burcene 100 Burco ADS-40

Surfactant

B u r l ng-

Burco ADS-100

Surfactant

B u r l ng-

Burco BSGH-270

Surfactant

Bur1 ing-

Burco BSGH-Crystals

Surfactant

B u r l ing-

Burco BSGH-400

Surfactant

B u r l ing-

Surfactant

B u r l ing-

Burco FAE

P r o p r i e t a r y t e x t i l e aux l i a r y

Burl ing-

Burco LAA-38

Surfactant

B u r l ing-

Burco LAF-6

Surfactant

B u r l ing-

Burco LAF-125

P r o p r i e t a r y t e x t i l e aux 1ia r y

B u r l ing-

Burco NPS-225

Surfactant

B u r l ing-

Burco

EHS


185

RAW MATERIALS Burco NPS 50%

CHEMICAL DESCRIPTION Proprietary t e x t i l e a u x i l i a r y

SOURCE B u r l ing-

Burcosolv TM

Water s o l u b l e s o l v e n t m i x t u r e

B u r l ing-

Burcosperse AP

L i q u i d detergent polymer

B u r l ing-

Burcosperse LP

P r o p r i e t a r y detergent polymer

B u r l ing-

Burcotase SL-80

P r o p r i e t a r y detergent enzyme

B u r l ing-

Burco TM€

Nonionic t h i o e t h e r s u r f a c t a n t

B u r l ingB u r l ing-

Burcotrope 1250 Burcowet TM-LF

Surfactant

Burl ing-

B u t y l Carbit07

I n d u s t r a7 s o l v e n t

UnCarb

Butyl Cellosolve


UnCarb

B u t y l Propasol


UnCarb

Calamide C

Foam s t a b i 1iz e r 8 emu1s i f ie r

P i 1o t

Calamide 0

Super amide

Pilot

Calfax DB-45

D i sul fonate

Pilot

Cal foam €A-603

L i q u i d detergent

Pil o t

Cal foam ES-303

L i q u i d detergent

Pil o t

Cal foam SLS-30

Sodium l a u r y l s u l f a t e 30%

Pi l o t

Emu1s i f ie r

Pil o t

C a l i b r i t e SL Cal irnul se PRS C a l o x y l a t e N-9

Pil o t

C a l s o f t F-90

Sodi um 1inear a1 k y l benzene s u l f o n a t e 90%

P i 1o t

C a l s o f t L-40

Linear sodium dodecylbenzene sul fonate

Pilot

186

Advanced Cleaning Product Formulationr

R A W MATERIALS C a l s o f t L-60

CHEMICAL DESCRIPTION SOURCE Sodium a l k y l b e n z e n e s u l f o n a t e ( 6 0 % ) P i l o t

Cal s o f t LAS-99

Dodecylbenzene s u l f o n i c a c i d ( 6 0 % )

Pilot

Calsuds A

L i q u i d detergent blend

Pilot

Calsuds CD-6

Coconut o i 1 amide w/sul f o n a t e

Pilot

Calsuds 81

Concentrated d e t e r g e n t b l e n d

Pilot

Carbopol 934

A c r y l i c a c i d polymer.MW:3,000,000

Goodri ch

C a r d i s 36 Wax

O x i d i z e d m i c r o c r y s t a l l i n e wax

Petrol-

C a r s p r a y 500

Beadi ng agent w i t h s i 1 i c o n e

W i tco

Carspray 700


Witco

Sodi um d i c h l o r o i s o c y a n u r a t e

FMC

C e l l o b o n d HEC 1OOOOOA Cheel ox BF-13 Cheelox NTA-Na3 C l e a r o n CDB

Concord Co-Wax Emulsion,

12%

Concord

Concord Wax #1600

Concord

Condensate TL

Concord

Cyanamer A-100L

Polyacrylamide

Cyt ec

Dequest 20605

Organophosphorous p r o d u c t

Monsant o

Dequest 2066

Organophosphorous p r o d u c t

Monsanto

Desonic 9N

Nonionic s u r f a c t a n t

DeSoto

Diala A O i l

Mineral seal o i l

She1 1

D i o n i c OC

F a t t y a c i d methanolamide polyglycol ether

nuis


187

RAW MATERIALS Dowanol D

CHEMICAL DESCRIPTION Glycol ether

SOURCE Dow

Dowanol DE

Glycol ether

Dow

Dowanol DPM

D i p r o p y l e n e g l y c o l methyl e t h e r

Dow

Dowanol EB

Ethylene g l y c o l n-butyl

Dow

Dowanol PnB

Glycol ether

ether

Dow

Dow C o r n i n g EP-1-14

DowCorn

Dowfax 2A-1

Anionic surfactant

Dow

D o w i c i d e 32

A n t i m i c r o b i a l agent

Dow

D u r c a l 40

Cal c i um c a r b o n a t e

Durer R e s i n 15546

Sodium s i l i c a t e 40 Be'

PQ

Emcol NA-30

S u r f a c e a c t i v e agent

W itco

Emcol 4500

S u r f a c e a c t i v e agent

Witco

Emersol 213

Fatty acid

Henkel

E

E-43 Noni o n i c

Emphos PS-220 Emu1s i f i e r Four-HF

W itco D i a1 k y l q u a t e r n a r y

Tomah

E m u l s i f i e r 827

Tomah

E m u l s i o n C-340

Toma h

F7 uorad FC- 129

F7uorochemica7

surfactant

3M

I88


RAW MATERIALS G a n t r e z AN-149

CHEMICAL DESCRIPTION V i n y l e t h e r polymer

SOURCE ISP

Genagen LAB

Hoechst

Genami n 5-250

Hoechst

Genaminox MY

Hoechst

Genapol OA-80

Hoechst

Genapol UD-030

Hoechst

Genapol UD-050

Hoechst

Genapol UD-080

Hoechst

Genapol ZRO L i q u i d

Hoec h st

Genapol 2908

Hoechst

General E l e c t r i c SF96-100

GESi 1 i-

S i 1 icone

Genopur ASA

Hoechst

Giv-Gard DXN GP-10-1.000

Dimethyl s i l i c o n e f u i d

Genesee

Dimethyl s i l i c o n e f u i d

Genesee

GP-121

S i l i c o n e p o l i s h add t i v e

Genesee

GP-7104

Silicone f l u i d

Genesee

GP-10-12,500

cstk cstk

Harco 20% Soap Hoe S 3924

Hoechst

Hoechst Wax A3 CS

Hoechst

Hoechst Wax E

E s t e r t y p e wax.

Drop p o i n t : 1 7 5 F

Hoechst

Hoechst Wax F

Hoechst

Hoechst Wax OM

Hoechst

nademarked Raw Materials

RAW MATERIALS Hoechst Wax OP

CHEMICAL DESCRIPTION

189

SOURCE Hoechst

Hoechst Wax S

Hoechst

Hostapur SAS 60

Hoechst

Hypof r e s h

Perfume

I g e p a l CA-630

Alkyl ethoxylate nonionic

ISP

I g e p a l CA-720

A1 k y l phenol e t h o x y l a t e n o n i o n i c

I SP

I g e p a l C0-630/C0-660/ CO-710

Alkylphenol ethoxylate

ISP

I g e p a l CO-977

Water s o l u b l e s u r f a c t a n t (70%)

ISP

I s o p a r E/K/L/M/V

I s o p a r a f f in i c s o l v e n t

Exxon

Lanoquat 50

Quaternary product

Henkel

L i poxol

Hul s

L i p o x o l 6000 & 12000

Hul s

Lonzabac 12.30

Lonza

L y t r o n 295 L a t e x

P o l y s t y r e n e emu1s i on

Morton

K a o p o l i t e SF/1152/ 1168

Anhydrous a umi num s i 1ic a t e

Kaopol-

Kathon CG

Fungi c i de ( B i o c i de)

Rohm&

K e l zan

Xanthan gum

Kelco

Kermac 600

Mineral seal o i l

Kerr-Mc

Korthix Thixotropic Agent

Refined w h i t e b e n to n i t e

Kaopol-

190


RAW MATERIALS Mackadet 40K

CHEMICAL DESCRIPTION Potassium c o c o n u t soap

SOURCE

Mackam JS

Low foam s u r f a c t a n t

McI nt y r e

Mackam MEJ

Amphoteric w e t t i n g agent

M c I nt y r e

Mackam 2CSF

Surfactant

McI n t y r e

Mackam 2CYSF

Low foaming s u r f a c t a n t

Mc I ntyr e

Mackam 35

Cocami d o p r o p y l b e t a i ne

McI nt y r e

Mackamide CD

Cocamide DEA

Mc Int y r e

Mackami ne C-10

Amine o x i d e s u r f a c t a n t

McI n t y r e

Mackamine LO


McI nt y r e

Mackazol ine 0

01 e y l h y d r o x y e t h y l im i d a z o l ine

McI nt y r e

M a c k s t a t DM

DMDM h y d a n t o i n

McIntyre

Macol 48

Block p o l y o l

PPG

Macol LF-120

R i n s e a i d . MW:

Macol TD-3

N o n i o n i c s u r f a c t a n t . HLB: 8 . 0

PPG

Macol TD-12

N o n i o n i c s u r f a c t a n t . HLB: 14.1

PPG

Maphos 60-A

Phosphate e s t e r

PPG

M a r l ami d s

F a t t y a c i d a1 k a n o l ami des

Hul s

M a r l a z i ns

F a t t y amine p o l y g l y c o l e t h e r s

Hul s

M a r l in a t s

F a t t y alcohol ether sulphates

Hul s

M a r l ip a l s

Fatty alcohol polyglycol ethers

Hul s

Marlons

A1 k y l b e n z e n e s u l p h o n a t e s , sodium salts

Hul s

Marlophors

P a r t i a l phosphate e s t e r s

Huls

1,000

M c In t y r e

PPG

TrademarkedRmu Materials

191

RAW MATERIALS M a r l o s o f t IQ 90

CHEMICAL DESCRIPTION Quaternary im i dazol ines

SOURCE Huls

Mar 1owets

Emu1s i f ie r s

Hul s

Mar 1ox I s

F a t t y a1coho1 a1 k y l ene o x i d e a d d i t i o n products

Hul s

Mazamide 80

Speci a1t y a1 kanol ami de

PPG

Mazawet 36

Surfactant

PPG

Mazclean EP Mazon 98

PPG

Proprietary surfactant

P PG

Medialan LD UnCarb

Methyl C a r b i t o l Solvent Metso Pentabead 20

Sodium m e t a s i l i c a t e ,

Miranol CS Conc.

Cocoamphopropylsulfonate

pentahydrate

PQ M i ranol

amphoteric s u r f a c t a n t Miranol FBS

Surfactant

M i ranol

M i r a n o l JEM Conc.

Mixed C8 amphocarboxylate amphoteric

M i ranol

M i r a t a i n e TM

D i hydroxyethyl t a l l ow g l y c i n a t e amphoteric s u r f a c t a n t

M i ranol

ML-870 Latex

A c r y l i c polymer emulsion

Morton

Mont an Wax "S'I

Stroh-

Mor-Glo 2 Latex

F l o o r p o l i s h l a t e x (38%)

Morton

Morton Conrez 510

Polymer emu1s i on

Morton

M- Py 1-01

N-Methyl-2-Pyrrolidone

ISP

192

Advanced Cleaning Product Formulotions

RAW M A T E R I A L S CHEMICAL DESCRIPTION Neodol 25-3 E t h o x y a t e L i n e a r p r i m a r y a l c o h o l

SOURCE Shel 1

Neodol 25-3s

Shel 1

E t h o x y s u l f a t e . Sodium c a t i o n

Neodol 25-7 E t h o x y a t e A l c o h o l e t h o x y l a t e . Neodol 91-8

MW:

519

Ethoxy a t e L i n e a l p r i m a r y a l c o h o l . MW: 529

Shel 1 Shel 1

O z o k e r i t e 170

Koster

PEG-10 Carnauba

Koster

P e r m u l s i n SP

Pol y c a r b o x y l a t e

P e t r o BAF L i q u i d

Anionic surfactant & dispersant

DeSoto

B e t r o BAF Powder


DeSoto

P e t r o LBA/ULF/22


DeSoto

P e t r o SXS-40

Sodium x y l e n e s u l f o n a t e 40%

DeSoto

P r i f a c 7976

Fatty acid

Unichema

P r o x e l GXL

Chemical b i o c i de

ICI

Prapagen WK

R e f i n e d Concord Wax #407

Concord

R e w o t e r i c AM B-15

wi tCO

R e w o t e r i c AM KSF-40

w itco

R e w o t e r i c AM V

Surfactant

witco

Rhodacal A-246/L

Rhone-

Rhodacal DS-10

Rhone-

Rhodacal DSB

Rhone-

Trademarked Rcmt Materials

R A W MATERIALS Rhodacal I PAM


RhonePhosphate e s t e r nonioni c

Rhodafac RA-600 Rhodaf ac RE-61 0

SOURCE Rhone-

Rhodacal 330 Rhodafac LO-529

193

RhoneRhone-

PhosDhate e s t e r a n i o n i c

Rhone-

Rhodapex GO-436

Rhone-

Rhodapex ES-2

Rhone-

Rhodapax MA-460

Rhone-

Rhodapex NA-61

Rhone-

Rhodopol 23

Rhone-

Rhodapon BOS

Rhone-

Rhodapon S 0

Rhone-

Rhodapon U 0

Rhone-

Rhodasurf 0C-840

Ethoxylated t r i d e c y l a l c o h o l

Rhone-

Rhodasurf 25-7

Rhone-

Rhodasurf 25-9

Rhone-

Rhodasurf 91 -6

Rhone-

Ross M i c r o Wax 1133/15W

Ross

Ross O z o k e r i t e Wax 77Y

Ross

SAG 1010

S i l i c o n e a n t i foam

Sequi on 1ONa2

Phosphonate HEDP

SF96(100)/SF96(350)/ Polydimethyl s i l i c o n e f l u i d SF96(1OOO)/SF 1705/SF 1706 Shellsol T SM 2109

I s o p a r a f f in i c s o l v e n t

UnGarb

GESi 1 She1 1 GESi 1

194


SOURCE GESi 1

RAW MATERIALS SM 2133/SM 2135


Snow F l o s s S i l i c a

Processed diatomaceous s i l i c a

Sokalan CP 5

Polycarboxylate

Manvi 11e

Sokalan HP 22 Sokalan HP 50

P o l y v i n y l p y r r o l idone

Sokalan PA 40

Polycarboxylate

S o l v e n t BG S o l v e n t GX 5 Surfactant

ICI

Sodium s i l i c a t e 42 Be’

PQ

D i e t h a n o l ami ne 1a u r y l s u l f a t e

Step n

Super F l o s s

Mineral f i l l e r

Manvi 11e

S u r f o n i c N-95

N o n i o n i c s u r f a c t a n t . HLB:

SWS 211 S i l i c o n e

A n t i foam

Wac k e r

S y n t r a n 6520

A c r y l ic emu1s i on

Inter-

Nonionic s u r f a c t a n t

Tomah

F1 u o r e s c e n t w h i t e n i n g agent

C i ba-

Span 80 SR 107

Star Stepano

DEA (35%)

12.9

Texaco

T e c h n o c e l l 90 DU T e x s t i m 8741 Thermphos NW T i n o p a l CBS-X

Amphoter c (35% A c t i v e )

Tomah

E t h e r amine o x i d e s u r f a c t a n t

Tomah


Tomah

Tomah A l k a l i S u r f a c t a n t : Tomah AO-14-2 Tomah A0-728

Special

Trademarkmi Raw Materials

195

R A W MATERIALS CHEMICAL DESCRIPTION Tomah E m u l s i f i e r Four D i a l k y l q u a t e r n a r y s u r f a c t a n t

SOURCE Tonah

Tomah Q-17-2

Tomah

Triethanolamine R T r i t o n CF-10

A l k y l a r y l polyether nonionic

UnCarb

Tween 81

Surfactant

ICI

T y l o s e CBR 10000

Ucon

1

Propel 1a n t

UnCarb

Ucon

2

Propel l a n t

UnCarb

Union C a r b i d e L-45,

100 c s t k s .

Silicone

Union C a r b i d e L-45,

30,000 c s t k s . S i l i c o n e

UnCarb UnCarb

Union C a r b i d e L-46

S i 1 icone

UnCarb

Union C a r b i d e LE-461

S i 1icone

UnCarb

Union C a r b i d e LE-462

S i 1icone

UnCarb

Varami de A-83

D e t e r g e n t a1 kanolamide

W itco

Varamide ML-1

D e t e r g e n t a1 kanolamide

W itco

V a r i o n AM-KSF-40%

Surfactant

Wi tco

V a r o n i c K205/LI-48/ LI-67

N o n i o n i c w e t t i n g agent

W itco

Varox 365

W e t t i n g agent,degreaser,detergent

W itco

Varox 1770

Amine o x i d e

W itco

V a r s o l 81 V a r s o l No.2

M i n e r a l s p i r it s

Exxon

Veegum Pro

Complex c o l 1o i d a l magnesi urn aluminum s i l i c a t e

Vander-

1%


R A W MATERIALS Versene 100/220

CHEMICAL DESCRIPTION Solution o f tetrasodium s a l t o f

SOURCE Dow

EDTA

Huls

Vestinol C 15% b a s i s

Hul s

Vestowax AW 1060

Wax e m u l s i o n ,

Viscasil lO,OOO/ 12,000/30,000

Silicone f l u i d

GESi 1

Vol c l ay NF-BC

Western b e n t o n i t e

AmColl

Wessalith P

Zeolith A

W i t c a m i de CDA/ 5-771 /128T/511/5195

A1 k a n o l ami de s u r f a c t a n t

W i tco

W i t c o 1298 S o f t A c i d W i tcolate A

Sodium l a u r y l s u l f a t e . A n i o n i c

W i t c o l a t e AE-3/

Sulfated surfactants ES-3/LES-60A/S-1285C/SE-5/WAC-LA/2310/7031

W i t c o n a t e AOS/ SXS/3ODS/45LX

Witco

Sul f o n a t e s u r f a c t a n t

W itco W itco W itco

W i t c o n a t e 1260 S l u r r y C-12 LAS (60%)

W itco

W i t c o n o l 14

Witco

Noni o n i c

Zeolith A

#3 Carnauba

Koster

668 P o l i s h i n g Powder

Whi t t C D

678 P o l is h i ng Powder

Whi t t C D

787 P o l i s h i n g Alumina P-10 F e i n s t

Whi t t C D

Section IV Suppliers' Addresses

197

198


A1 1ied-Si g n a l I n c . P.O. Box 2332R M o r r i s t o w n , NJ 07962

(201)-455-2000/(800)-526-0717

Dow C o r n i n g Corp. Box 0994 M i d l a n d , M I 48686 ( 5 1 7)-496-4000

American C o l l o i d Co. 1500 W. Shure D r . A r l i n g t o n H e i g h t s , I L 60004 (312)-392-4600

Eastman Chemical Co. P.O. Box 431 K i n g s p o r t , TN 37662

A r c 0 Chemical Co. 3801 West C h e s t e r P i k e Newtown Square, PA 19073 (215)-359-2000

Exxon Chemica? Americas 13501 K a t y Frwy Houston, TX 77079

BASF Corp. 100 C h e r r y H i l l Rd. P a r s i ppany, NJ 07054

FMC Corp. 2000 M a r k e t S t . P h i l a d e l p h i a , PA 19103

(201)-316-3000/(800)-526-1072

(215)-299-6000/(800)-526-3649

BP O i l I n c . 200 P u b l i c Square C l e v e l a n d , OH 44114

ISP/GAF Corp. 1361 A l p s Road Wayne, NJ 07470

(216)-586-6364/(800)-321-8598

(201)-628-3000/(800)-848-7659

B u r l in g t o n Chemical C o . P.O. Box 111 615 Huffman M i l l Rd. B u r l i n g t o n , NC 27215

,

(615)-229-2318/(800)-327-8626

(713)-870-6000/(800)-231-6633

Inc.

(919)-584-0111/(800)-672-5888

Genesee Polymers Corp. Fenton Rd. P.O. Box 7047 F l i n t , M I 48507 (31 3 ) -238-4966

Concord Chemical C o . 1 7 t h and F e d e r a l S t s . Camden, NJ 08105 (609)-966-1526

GE S i 1i c o n e s

Cytec I n d u s t r i e s , I n c . F i v e G a r r e t Mountain Plaza West P a t e r s o n , N J 07424 (908)-B62-6000/(800)-253-4078

BF G o o d r i c h Co. 991 1 B r e c k s v i 11e Rd. B r e c k s v i l l e , OH 44141

DeSoto, I n c . 1700 S. M t . P r o s p e c t Rd. Des P l a i n e s , I L 60018 (312)-391-9000

Haarman & Reimer Corp. P . O . Box 175 70 Diamond Rd. S p r i n g f i e l d , NJ 07081

260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188

(518)-237-3330/(800)-255-8886

(216)-447-5000/(800)-332-1144

(201)-467-5600/(800)-422-1559 Dow Chemical Co. M i d l a n d , M I 48674 (800)-258-CHEM

Suppliers' Addresses

Henkel Corp. 5325 S. N i n t h Ave. LaGrange, I L 60525 (708)-530-7300/(800)-543-7370

Miranol Inc. P.O. Box 436 Dayton, NJ 08810 (201)-329-3900

Hoechst-Celanese Corp. 26 Main S t . Chatham, NJ 07960 (201)-635-2600/(800)-526-4960

Mona I n d u s t r i e s I n c . 76 E. 24 S t . P.O. Box 425 Paterson, NJ 07544 (201)-345-8220/(800)-553-6662

H u l s America I n c . T u r n e r P1. P i scataway, NJ 08855 (201)-981-5000/(800)-526-0339 I n t e r p o l y m e r Corp. 330 P i n e S t . Canton, MA 02021 (617)-828-7120/(800)-444-1281 Kaopolite, Inc. 2444 M o r r i s Ave. Union, N J 07083 (908)-769-0609 Kelco Div. Merck & Co., I n c . 8355 Aero D r i v e San Diego, CA 92123 (619)292-4900/(800)-535-2656 Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. Box 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911 K o s t e r Keunen I n c . P.O. Box 447 90 Bourne B l v d . S a y v i l l e , NY 11782 (51 6)-589-0456

Monsanto Chemical Co. 800 N. L i n d b e r g h B l v d . S t . L o u i s , MO 63167 (314)-694-1000/(800)-325-4330 Morton I n t e r n a t i o n a l I n c . 100 N. R i v e r s i d e P l a z a Chicago, I L 60606 (312)-807-2000/(800)-367-3318 P e t r o l i t e Corp. 6910 E. 14 S t . T u l s a , OK 74112 (918)-838-1601 P i l o t Chemical Co. 11756 Burke S t . Santa Fe S p r i n g s , CA 90670 (310)-723-0036 PPG Chemical s 3938 P o r e t t D r i v e Gurnee, I L 60031 (708)-244-3410/(800)-323-0856 PQ Corp. P.O. Box 840 V a l l e y Forge, PA 19482 (215)-293-7200

Johns-Manville Ken C a r y l Ranch Denver, CO 80217

Rhone-Poulenc CN 7500 P r o s p e c t P l a i n s Rd. Cranbury, NJ 08512 (609)-860-4000/(800)-620-2613

M c I n t y r e Group L t d . 4851 S. S t . L o u i s Ave. Chicago, I L 60513 (312)-927-2401

Rohm & Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 (215)-592-3000

199

200


Ross Chemical I n c . 303 D a l e O r . F o u n t a i n I n n , SC 29644 (803)-862-4474

Union C a r b i d e Corp. 39 O l d R i d g e b u r y R d . Danbury, CT 06817 (203)-794-2000

Sandoz Chemical s Corp. 4000 Monroe Rd. C h a r l o t t e , NC 28205

RT V a n d e r b i l t Co., P.O. Box 5150 30 W i n f i e l d S t . N o r f o l k , CT 06856

(704)-331-7078/(800)-631-6077

Inc.

(203)-853-1400/(800)-243-6064 S h e l l Chemical Co. P . O . Box 2463 Houston, TX 77252 (713)-241-6161

Wacker S i l i c o n e s C o r p . 3301 S u t t o n Rd. A d r i a n , M I 49221

(517)-264-8500/(800)-246-0063 Stepan Co. 22 W . F r o n t a g e Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837 Strohmeyer & Arpe Co., 89 M i 1b u r n Ave. M i l b u r n , N J 07041 (201)-761-7600

Whittaker, Clark & Daniels, 1000 C o o l i d g e S t . S. P l a i n f i e l d , NJ 07080 (201)-561-6100

Inc.

Inc.

Texaco Chemical Co. 3040 P o s t Oak B l v d . Houston, TX 77056 ( 7 1 3)-961-3711 Tomah P r o d u c t s , I n c . 1012 T e r r a D r i v e M i l t o n , W 1 53563 (608)-868-6811/(800)-441-0708

3M 3M C e n t e r S t . P a u l , MN 55144 (612)-733-5454 Unichema Chemicals, I p c . 4650 S. R a c i n e Ave. /' Chicago, I L 60609 (312)-376-9000/(800)-833-2864

W i t c o Chemical Co. 5777 F r a n t z Rd. P.O. Box 646 D u b l i n , OH 43017

(614)-765-6500/(800)-366-6500 W i t c o Corp. 520 Madison Ave. New Y o r k , NY 10022 (212)-605-3941/(800)-634-4010

Other Noyes Arblications

ADVANCED CLEANING PRODUCT FORMULATIONS Volume 3 by Ernest W. Flick This book (Volume 3) presents more than 630 up-to-date advanced cleaning product formulations for household, industrialand automotive applications.It istheresultofinformationreceived from numerous industrial companies and other organizations. The data represent selections madeatnocostto, norinfluencefrom,themakers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1 published in 1989 and Volume 2 publishedin 1994. Formulation in the cleaning product industry hasgradually beenundergoingsignificant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass alongthese increases. Environmentalconsiderations have also played a part. By changing formulationsto improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presentsmanufacturers' suggestedformulations which might meet new performance criteria. The formulations in this book are divided into the following sections and chapters, with the number of formulations indicatedin (): 1. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (14) 2. Dairy Food and General Industrial Cleaners (52)

13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (41) 14. Miscellaneous (49)

II. Transportation Cleaners andPolishes 15.

17. Whitewall Tire Cleaners (11) 18. Miscellaneous

Eachformula is locatedinthe chapter which is most applicable. The reader, seeking a formula for aspecific end use, should check eachchapter which could possibly apply. In addition to the above, there are two other sections which will be helpfulto the reader. 111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical descriptionandthe supplier's name. The specifications which each raw material meets are included, if applicable. IV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available, in the manufacturets own words: 0 Description of end use and most outstanding

properties. 0 The percent by weight orvolume of each raw

3. Degreasers (25)

material included intheformula, rounded toa decimal figure.

4. Dishwashing Detergents (70)

5. General Purpose Cleaners (29)

6. Glass CleanarsPolishes (18) 7. Hard Surface Cleaners (59) 8. Laundry Products (100) 9. Metal Cleaners and Polishes (52) 10. Oven, Grill and Hot Plate Cleaners (11) 11. Polishes, Coatings and Finishes (19) 12. Rinse Aids (5)

ISBN 0-8155-1382-8

Auto Cleaners and Polishes (32)

16. Car and Truck Wash Compounds (34)

(1995)

0

Key propertii of the formula, which are the featuresthatthesource considentobemore outstanding than other formulations of the same type.

0 The formula source, which is the company

or

organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. Aformula number is included, if applicable.

6" x9'

280 pages

Other Noyes Publications

ADVANCED CLEANING PRODUCT FORMULATIONS Volume 2 by Ernest W. Flick

This book (volume 2) presents more than

800 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influencefrom, the makers ordistributorsof these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1, which was published in 1989. Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost-performance characteristics. manufacturers have been able to control costs but still enhance performance. This book presents supplier's suggested formulations which might meet new performance criteria. Theformulations inthis bookaredivided into the following sections and chapters, with the number of formulations indicated in (): 1. Household and industrial Cleaners and

12. Rug, Carpet and Upholstery Shampoos and Cleaners (21) 13. Miscellaneous Cleaners (96)

/I.Transportation Cleaners and Polishes (76) 14. Auto Cleaners and Polishes (9) 15. Car and Truck Wash Compounds (38) 16. Whitewall Tire Cleaners (10) 17. Miscellaneous (19)

In addition to the above, there are two other sections which will be helpful to the reader. 111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.

lV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available:

Polishes (733)

1. Description of end use and most

outstanding properties.

1. Bathroom Cleaners (29) 2. Dairy and Food Industry Cleaners (15) 3. Degreasers (20)

2. The percent by weight or volume of each raw material included in the formula.

4. Dishwashing Detergents (67) 6. General Purpose Cleaners (47)

3. Key properties of the formula, which are the features that the source considers to be more outstandingthan other formulations of the same type.

7. Hard Surface Cleaners (60)

4. The formula source, which is the

5. DetergentsDisinfectants (36)

company or organization that supplied the formula. The secondary source maybe theoriginatingcompany and/or the primary source's publication title. or both. A formula number is included, if applicable.

8. Laundry Products (217) 9. Metal Cleaners (87) 10. Polishes, Coatings and Sealers (32) 11. Rinse Aids (6)

ISBN 0-8155-1346-1 (1994)

f64

6" x9"

394 pages

Advanced Cleaning Product Formulations Volume 5

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