Solvay Paint Additives

Additives for Paints and Coatings

Solvay Novecare Coating Additives SOLVAY Novecare, Global Expert in Additives for Coatings Applications

Solvay, a world leader in the development and production of specialty chemicals, supplies performance additives for a variety of paint and coating applications.

Solvay Novecare offers multiple products RHODOLINE® wRHODOLINE

series defoamers RHODOLINE® wRHODOLINE

dispersing agents Solvay additives deliver outstanding benefits to coating formulations, such as enhanced surface wetting, improved coating adhesion to substrate, superior dispersion stability and gloss, enhanced color development and stability, and better foam control. Solvay additives are also effective in minimizing production mixing time and improving manufacturing efficiency. efficiency. Technical support dedicated With our global technical support network, Solvay provides customers with custom-made solutions and develops formulations adapted to their needs and requirements for the paint and coatings industry. Solvay uses its expertise in safety, toxicology, environmental and regulatory affairs to provide guidance on industrial formulation compounds, thus creating additional value for paint and coatings customers.

RHODOLINE®, wRHODOLINE

IGEPAL® and GEROPON® wetting agents

RHODOLINE® wRHODOLINE

series freeze/ thaw and open time additives

FENTAMINE® and wFENTAMINE FENTACARE® specialty amines RHODIASOLV ® wRHODIASOLV

Adapted for paint and coating applications:

Waterborne wWaterborne Aqueous w

Global industrial footprint Through its world-class manufacturing operations in Europe, North America, Asia Pacic and Latin America, Solvay shares best practices within zones and benets from technology transfer. Strengthened by a worldwide R & D and tech-support network, Solvay develops strong partnerships with customers around the world and creates innovative materials focused on next-generation technologies for the p aint and coatings market.

Note: These products are pr oduced oduced at worldwide locations through the Novecare division of Solvay.

coalescent

paints

ink systems

Water-based wWater-based

adhesives

Solvay’s Sustainable Portfolio Solvay Novecare works alongside its customers to design products and solutions with reduced impact on health and the environment. As part of corporate social responsibility, Solvay uses procedures that

Solvay offers a versatile

monitor its products throughout their entire life cycles. Solvay supports customers with a broad range of sustainable solutions and services including products optimized around criteria such as biodegradability, eco-toxicity, eco-toxicity, VOC content, and percentage of renewable materials.

and coatings formulation.

toolbox for waterborne paint

Solvay VOC-f Solvay VOC-free ree defoamers and APE-free surfactants are examples of its commitment to sustainability and the environment. Solvay recognizes the difficulties in selecting the optimal surfactant system for wetting, dispersing or designing an emulsion polymer system. Formulators require surfactants that perform and are compatible with the entire formula and do not compromise the quality of the coating. Environmental concerns are also key drivers behind the reformulation of well-established systems, leaving formulators with additional challenges to overcome, such as the conversion to APE-free systems or ensuring compatibility with low to VOC-free formulations. Solvay Novecare is developing and expanding its line of industry-leading ree and APE-free APE-free paint additives to enhance the performance of VOC-f of VOC-free water-based formulations formulations while providing additional benefits such as improved freeze-thaw, open time, film appearance, defoaming and wetting characteristics. Solvay consistently develops new sustainable additives that allow formulators to address the performance challenges of newer waterborne formulations, while answering the demand for more sustainable and cost-effective products.

Solvay Coating Additives / 1

Functional Additives RHODOLINE® OTE-500: OPEN-TIME ADDITIVE RHODOLINE® OTE-500 is a novel APE and solvent free open time additive for low to VOC-free waterborne paints, coatings, inks and adhesives.

Sustainable Additives wAPE-free and VOC-free additive wLow odor solution wEnables design of low to VOC-free coating formulations wDesign sustainable coatings with RHODOLINE® OTE-500 [Green Seal (GS-11) or EU Ecolabel compliant paints]

RHODOLINE® OTE-500 improves open time for low to VOC-free waterborne paints. It could be utilized in various formulations from low to high gloss paints.

PAINT SAMPLE

RHODOLINE® OTE-500 significantly improves open time for paints made with the following resin systems: wAll-Acrylic copolymer wStyrene-Acrylic copolymer (S/A) wVinyl Acetate / Acrylic copolymer (V/AC) wVinyl Acetate / Ethylene Copolymer (EVA) wWater-based Alkyd Paints RHODOLINE® OTE-500 works in all gloss: high gloss, semi-gloss, satin and flat (matte) systems Key Features wExtends open time wExhibits excellent dispersion stability wAllows formulation of Eco-label compliant coatings wMay reduce/eliminate wetting agents

CONTROL

RHODOLINE® OTE-500

2

8

VOC-free ACRYLIC SG PAINT

Visible X shows limits

OPEN TIME

PRODUCT NAME

RHODOLINE® OTE-500

DESCRIPTION

APE-free and VOCfree additive that promotes extended open time

u Listed

2 / Solvay Coating Additives

e e r F E P A

e e r F C O V

u

u

u

s s o l G h g i H

u

0

2

2

4

4

6

6

8

8

10

10

12

12

14

14

/ s s c g n i r i e t a m o c o t f s o a o l E R

u

MIN

0

Application Guideline s s o l g i m e s o t s t n t i a l a F p

CONTROL

RHODOLINE® OTE-500

MIN

g n i k r a M c s t n ffi i a r a T P

u

OPEN TIME

International Inventory Status

s k n I

s e v i s e h d A

) A C S T ( A S U

) L S D ( A D A N A C

u

u

u

u

A E R A I O L ) K E S A P C R ) H ) O E T S T L S I C U C R N U A O E U I E E ( A ( S K (

u

u

u

) I T I M ( N A P A J

u

Low VOC Acrylic Semi-Gloss Paint A

B

C

CONTROL PAINT

RHODOLINE® OTE-500 + RHODOLINE® 5520

RHODOLINE® OTE-500

Wt. %

Wt. %

Wt. %

Water

7.75

7.75

7.75

RHODOLINE® 286N – dispersant

0.78

0.78

0.78

RHODOLINE® 643 - defoamer

0.05

0.05

0.05

RHODOLINE® 5520 – wetting agent

0.39

0.39

0.00

RHODOLINE® OTE-500

0.00

0.00

0.39

Amine

0.19

0.19

0.19

Attagel 50

0.48

0.48

0.48

Titanium Dioxide

22.29

22.29

22.29

Water

8.67

8.67

8.67

Acrylic Latex (50%)

46.52

46.52

46.52

RHODOLINE® OTE-500

0.00

1.21

0.82

RHODOLINE® 643

0.19

0.19

0.19

High Shear Builder (ICI)

2.23

1.65

1.94

Water

9.21

8.61

8.56

Low Shear Builder (Ku)

0.85

0.82

0.97

Mildewcide

0.39

0.39

0.39

Total

100

100

100

LOW VOC SEMI-GLOSS PAINT FORMULA Raw Materials

PVC = 22.2%; Weight Solids = 45.4%; Volume Solids = 32.4%

For optimum results use RHODOLINE® OTE-500 as shown in formulation C above by splitting the quantity in the grind to replace the wetting agent and in the letdown. RHODOLINE® OTE-500 increases the open time with minimal impact on dry film properties. CONTROL PAINT

RHODOLINE® OTE-500 + RHODOLINE® 5520

RHODOLINE® OTE-500

Non-Ionic Surfactant R5520 - %

0.39

0.39

0.00

RHODOLINE OTE-500 - %

0.00

1.21

1.21 (0.39 + 0.82)

21/56/91

27/61/89

23/57/89

Fail-1

16

14

2

8

8

Scrub Resistance ASTM D2486

>1000

555

>1000

Block Resistance ASTM D4946

Control

-

-

0.53

0.79

0.65

-1

4

0

Stain Resistance ASTM D4828

Control

=

=

Surfactant Leaching - O/N Dry

8

9

9

10/10

8/10

10/10

PAINT PROPERTIES TESTED

Gloss O/N 20°/60°/85 Freeze/Thaw - 5 Cycles - ∆Ku Open Time – Minutes ASTM D7488

Color Rub-up ∆E – BLK (1.6% by volume) Heat Aged – 2 wks @ 50°C – ∆ KU

Low Temp FF, 5°C – Sealed/Unsealed

Rating System: 10 = Best; 0 = Worst


Functional Additives RHODOLINE® FT-100: FREEZE-THAW STABILITY ADDITIVE Freeze-Thaw Process

RHODOLINE® FT 100 is a unique APE-free and solvent-free additive utilized to improve freeze-thaw stabilit y primarily for low Tg latex binders as well as waterborne paints formulated with these binders. RHODOLINE® FT 100 also improves gloss, pigment dispersions and stain resistance in these formulations.

Freezing of Latex Polymers (to -18°C)

No FT-100

Key Features wDelivers freeze-thaw stability wEnhances gloss wBoosts stain resistance wAPE-free and VOC-free

With FT-100

Easy to use for a wide range of polymers wAll Acrylic wVinyl / Acrylic wStyrene / Acrylic wEthylene vinyl acetate

Application Guideline

PRODUCT NAME

DESCRIPTION

APE-free and VOC-free additive RHODOLINE® FT-100 that promotes freeze-thaw stability u Listed


e e r F E P A

e e r F C O V

u

u

s s o l g i m e s o t s t t i n a l a F p

u

s s o l G h g i H

u

/ s s c g n i r i e t a m o c o t s f a o o l E R

u

g n i k r a M c s t n ffi i a a r P T

u


s k n I

s e v i s e h d A

) A C S T ( A S U


u

u

u

u

A E R A I O L ) K E S A P C R ) H ) O E T S T L S C R N U C U I U I O E E A E ( A ( S K (

u

u

u


u

Effects of RHODOLINE® FT-100 on Freeze-Thaw Stability of Low VOC Commercial PAINT Commercial all acrylic gloss paint (VOC= 50 g/l/ASTM)

RHODOLINE® FT 100 No additive Ethylene Glycol Alkyl Phenol Ethoxylate Linear Alkyl Ethoxylate

Initail Viscosity (KU) 102.4 121.1 103 88 96

1 Cycle

2 Cycle

103.8. gel gel gel gel

104.3

3 Cycle

4 Cycle

5 Usage levels in Cycle paint formulations

104.0 105.4 105.4 paint coagulated paint coagulated paint coagulated paint coagulated

1.0% — 1.0% 1.0% 1.0%


Wetting Agents SURFACTANTS

Solvay offers a comprehensive line of wetting and dispersing agents specifically designed for waterborne coatings systems and drives its

RHODOLINE® WA Series

innovation to deliver new and better performing APE-free and VOC-free solutions. RHODOLINE® and IGEPAL® dispersing and wetting agents provide excellent broad compatibility, improvement of color stability and color acceptance, improved flow and leveling and storage stability in both architectural and industrial paints, inks and adhesive systems. These workhorse additives will reduce the surface tension and improve pigment

wVery

fast Wetting

wExtremely

low foam

wFull

compatibility with water based paints

w APE-Free wVOC-free,

exible for point choice

wLow

viscosity easy to handle


wetting with minimum foaming. RHODOLINE® 200 and 300 series polymeric dispersants provide exceptional pigment dispersion, improved color acceptance and storage stability. RHODOLINE® 3000 series provides exceptional pigment wetting and color improvement for carbon black and organic pigments. RHODOLINE® 4000 series is designed for inorganic pigments. RHODOLINE® WA APE-free wetting agents provide excellent substrate wetting and low foaming for waterborne paints, coatings, adhesives and inks. RHODOLINE® WA line of products are low viscosity with low pour point for ease of handling.

RHODOLINE® WA 120 at 1.0% addition

Silicone

As is

RHODOLINE® WA 120

Benchmark


Wetting Agents Application Guideline

PRODUCT NAME

DESCRIPTION

e g n a R B L H

e e r F E P A

C O V

- s i m t n e i s a p o t s t s a l o l F g

s s o l G h g i H

/ s s c g i n r i e t a m o c o t s f a o o l E R

g n i k r a M c s t n s ffi i a a k r P n T I

s e v i s e h d A

RHODASURF® BC-420

TDA Ethoxylate

8

Yes

Yes

u

u

u

u

u

u

RHODASURF® BC-729

TDA Ethoxylate

13.8

Yes

Yes

u

u

u

u

u

u

N/A

Yes

Low

u

u

u

u

u

Yes

No

u

u

u

u

u

u

u

u

RHODOLINE® 5520

Low foam nonionic wetting agent; excellent wetting and color acceptance

RHODOLINE® WA 100

Solvent free surfactant with a good balance of wetting and low foaming properties.

RHODOLINE® WA 120

Low foaming surfactant with excellent wetting properties. Great alternative to silicone wetting agents.

10 - 13

Yes

No

u

u

u

u

RHODOLINE ® WA 200

High HLB surfactant with excellent wetting in low to high PVC paint formulations. Excellent alternate for APE, high HLB wetting agents. Improved paint stability.

17 - 19

Yes

No

u

u

u

u

RHODOLINE® 4160

Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A

Yes

Low

u

u

u

u

RHODOLINE® 4170

Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A

Yes

Low

u

u

u

u

u

RHODOLINE® 4188

Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.

N/A

Yes

Low

u

u

u

u

u

IGEPAL® CO series

Nonylphenol ethoxylates used as pigment wetters and color stabilizers

4 - 19

N0

No

u

u

u

u

u

IGEPAL® CA series

Octylphenol ethoxylates used as pigment wetters and color stabilizers

4 - 19

No

No

u

u

u

u

u

GEROPON® 99

Low Anionic surfactant for improved adhesion over chaulky and weathered surfaces

N/A

Yes

Low

u

u

u

u

u

u Listed

- Not listed


u

International Inventory Status ) A C S T ( A S U


u

u

u

u

u

u

u

u

u

u

u

u

u

A E R O K H ) T L U C O E S K (

FDA Compliance 21 CFR

) A P E S ( A N I H C


u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

E ) P S C O E R N U I E E (

A I L A R ) T S S C U I A A (

S E N I P ) P I S C L I C H I P P (

5 0 1 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

-

-

-

-

-

u

u

-

-

-

-

-

u

u

u

-

-

-

-

-

u

u

u

u

u

u

-

-

u

u

u

u

u

-

-

-

-

-

u

u

u

u

u

u

NE

NE

NE

NE

NE

u

u

u

u

u

u

u

NE

NE

NE

NE

NE

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u


Dispersants for Waterborne Systems


Dispersing Process of Pigment

Pigment

Three steps Wetting wLiquid replaces adsorbed gas on the

surface of the pigment wImmersion, adhesion, spreading, and capillary penetration

wExcellent pigment wetting wImproved

Liquid

flow

wImproved color acceptance wImproved stability

Separation wBreaking up of the aggregates and agglomerates wHigh amount energy needed Stabilization wRemaining particle size and its distribution during storage

Key Performance Features

wLow

foaming

wBroad compatibility

Wetting

Separation

Stabilization


Dispersants for Waterborne Systems

PRODUCT NAME

DESCRIPTION e g n a R B L H

e e r F E P A

C O V

RHODOLINE® 3100

Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments.

11 - 13

Yes

No

RHODOLINE® 3200

Dispersant for low HLB organic pigment including toluidine red, yellow and other organic pigments.

8 - 11

Yes

No

RHODOLINE® 3500

High HLB organic pigment wetting and dispersant agent. Works great with organic pigments as well as industrial grade carbon black pigments.

>16

Yes

No

RHODOLINE® 3700

High HLB pigment wetting and dispersant agent. It works great with high surface area pigments such as conductive carbon blacks.

>16

Yes

No

RHODOLINE® 4100

Anionic; 100 % active. Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents. Improved corrosion resistance.

N/A

Yes

Low

RHODOLINE® 4160

Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A

Yes

Low

RHODOLINE® 4170

Potassium neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance and color strength.

N/A

Yes

Low

RHODOLINE® 4188

Ammonia neutralized anionic wetting agent used in low/zero VOC colorants; best for inorganic pigments. Improved color acceptance, color development, color strength and color float resistance.

N/A

Yes

Low

uListed

- Not listed

NE Not evaluated


* Availability based on REACH status


) A C S T ( A S U


) S C E N I E ( E P O R U E

) S C I A ( A I L A R T S U A

) L C E K ( A E R O K H T U O S

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u


) A P E S ( A N I H C


) S C C I P ( S E N I P P I L I H P

5 0 1 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

u

—

—

—

—

—

u

u

—

—

—

—

—

u

u

u

u

—

—

—

—

—

u

u

u

u

u

—

—

—

—

—

u

u

u

u

u

u

—

—

—

—

—

u

u

u

u

u

u

u

—

—

—

—

—

u

u

u

u

u

u

u

u

NE

NE

NE

NE

NE

u

u

u

u

u

u

u

u

NE

NE

NE

NE

NE


Dispersants for Waterborne Systems Application Guideline

PRODUCT NAME

DESCRIPTION

e e r F E P A

e e r F C O V

c i b o h p o r d y H u

) % ( e v i t c a t n e c r e P

s s o l s g e l d e i n v m e e e L s m ) m e g % o t s t o t i n c a s t a a e o w l R d ( F p

s s o l G h g i H u

t l a S

Na

10.0

25

0.1 - 0.3

u

Na

7.0

45

1.0 - 5.0

u

Na

7.3

35

0.1 - 0.5

u

H p

RHODOLINE® 111

Most versatile hydrophobic dispersant for stabilizing TiO2 and other inorganic pigments

u

u

RHODOLINE® 207

Neutralized polyacrylated polymer with excellent chlorine and thermal stability

u

u

RHODOLINE® 226/35

Low-foaming, hydrophobic copolymer for reactive and non-reactive pigments

u

u

RHODOLINE® 230

Hydrophobic dispersant, particularly effective with high calcium carbonate pigment loadings

u

u

Na

7.9

44

0.1 - 0.5

u

RHODOLINE® 231

Water-soluble anionic dispersant used in pigment slurries and paper coatings. Suited for stabilizing inorganic pigments like TiO2, CaCO3 and MgOH slurries.

u

u

Na

7.3

44

0.1 - 0.5

RHODOLINE® 270

Low-foaming, hydrophilic polyacrylate for general pigment dispersions

u

u

Na

7.3

43

RHODOLINE® 286N

Low foaming, ammonia-neutralized copolymer, best for gloss development. Exterior paints

u

u

NH4

7.0

50

uListed

- Not listed

NE Not evaluated


u

u

* Availability based on REACH status


u

u

u

u

u

u

u

u

u

u

u

u

u

0.1 - 0.4

u

u

u

0.1 - 0.4

u

u

u

u

u

g n i k r a M c s t n s ffi i a a k r n T P I

u

FDA CLEARANCE

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

u

u

u

u

u


) A C S T ( A S U


u

u

u

u

u

u

u

u

u

u

u

u

u

u

0 8 1 . 6 7 1

0 1 2 . 6 7 1

* ) E S P C O E R I N U E E (




u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

—

u

u

u

u

u

u

u

u

u

u

—

u

u

u

u

u

u

u

u

u

u

u

u

NE

NE

NE

NE

NE

NE

u

u

—

—

—

—


RHODOLINE® Defoamers Solvay’s extensive line of RHODOLINE® defoamers is designed to provide optimal foam control in coatings, inks and adhesive formulations. RHODOLINE® defoamers provide excellent deaeration and prevent foam formation during manufacture and application of paints, coatings, emulsion polymerization, inks and adhesives. RHODOLINE® defoamers minimize foam formation during high-shear applications such as paint roll, brush, spray and high-speed ink or coating applications. RHODOLINE® defoamer portfolio includes industry workhorse products for flat to high gloss paint systems as well as printing inks and adhesive systems. The newly developed eco-friendly, APE–free and Zero-VOC defoamers, provide quick foam knockdown a nd the lasting efficiency. Wide range of use in polymers • All acrylic • Vinyl/Acrylic • Styrene/Acrylic • Vinyl Acetate Ethylene (VAE)


Key Features wQuick

bubble break and lasting efficiency in Flat to SG Paints

wExcellent

efficiency in architectural and industrial paints, adhesives and inks

wDoes

not cause fish-eyes or film defects

wExcellent

foam control in latex manufacturing of vinyl, acrylics and VAE resins

wBroad

compatibility

Initial Foam 1 Minute ■ After 2 Minutes ■

300

■ After

250 ) l m200 ( e m u l 150 o v m a o 100 F

50

0 No Defoamer

Rhodoline®

Competitor


RHODOLINE® Defoamers Application Guideline

PRODUCT NAME

DESCRIPTION

e e r F e n o c i l i S

- s i m t n e s i a p o t s t s a l o l F g

s s o l G h g i H


g n i k r a M c s t n ffi i a a r T P

s e v i s e h d A

e e r F E P A

e e r F C O V

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

s k n I

Oil Based

RHODOLINE® 622 RHODOLINE® 635 RHODOLINE® 640 RHODOLINE® 643 RHODOLINE® 646 RHODOLINE® 670

Highly recommended for exterior flat to semi-gloss waterborne coatings In-process defoaming of vinyl latexes for coatings, PSA and paints Recommended for flat to semi-gloss coatings Recommended for contractor and consumer latex paints In-process defoaming of latexes for coatings, PSA and inks In-process defoaming of latexes for coatings and PSA

u

u

RHODOLINE® 679

Recommended for adhesives and inks

u

u

u

RHODOLINE® 681F

Recommended for flat to semi-gloss coatings

u

u

u

RHODOLINE® 688

Workhorse defoamer for flat to semi-gloss waterborne coatings

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

Glycol Ester

RHODOLINE® 990

RHODOLINE® 999* u Listed

A molecular defoamer that provides excellent defoaming efficiency with minimum impact on gloss. A molecular defoamer that provides excellent defoaming efficiency in water-based inks and adhesives with minimum impact on gloss

- Not listed

NE Not evaluated


* REACH compliant

u

u

u

u

u

u

u

u

u

International Inventory Status ) A C S T ( A S U


u

u

u

u

u

u

u

u

u

u

FDA Compliance 21 CFR A E R O K H ) T L U C O E S K (


5 0 1 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

u

u

—

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

NE

NE

NE

NE

NE

u

u

u

u

u

—

—

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

NE

NE

NE

NE

NE

u

u

u

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u

u

u

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u

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u

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u

u

u

L

L

L

L

L

E ) P S C O E R N U I E E (



Coalescent DIB RHODIASOLV ® DIB is a new generation of low odor coalescent additive that meets tightening VOC regulations

in the paint industry. RHODIASOLV ® DIB helps in formulating low VOC paints without the drawbacks of plastisizers. RHODIASOLV ® DIB coalescent agent is extremely ecient for architectural, industrial coatings and inks. RHODIASOLV ® DIB does not cause film softness and provides films with improved hardness and scrub resistance. Key Features wEnables low VOC formulations wLow odor wEnhanced eciency wBiodegradability wHydrolytically stable wNonammable wTrue coalescing agent

Specialty Amines SOLVAY Novecare oers a broad portfolio of fatty and specialty amines fo r paints and coatings. FENTAMINE® and FENTACARE® products are based on specialty amines for use in paints and ink systems. FENTAMINE® and FENTACARE® products oer multi-functional performance properties such as improvement of pigment wetting and dispersions, as polyurethane catalysts, epoxy curing agents and used as neutralizing agents.

Amine Types wFatty

Alky primary amines

wFatty

Alkyl Tri & Tetra amines

w Alkyl

Ethanol/Propanol amines

wSpecialty

amines

wEthoxylated wQuaternary


amines

amines

Recommended Use

PRODUCT NAME

DESCRIPTION

CAS #

t n e g a g n i r u c y x o p E

s y l a t a c U P

r e z i l a r t u e N

International Inventor y Status

/ d t i c n a i a g t s n a r i t e d i s p n t s i i r n D g A

) A C S T ( A S U


* * ) E S P C O E R I N U E E (

) S C I A ( A I L A R T S U A



Primary Amines

FENTAMINE® A-CO

Coco amine

61788-46-3

u

u

u

u

u

u

NE

FENTAMINE® A-12

Laurylamine

124-22-1

u

u

u

u

u

u

u

FENTAMINE® A-O

Oleyamine

112-90-3

u

u

u

u

u

u

u

FENTAMINE® A-HT

Hydrogenated tallow amine

61788-45-2

u

u

u

u

u

u

FENTAMINE® A-T

Tallow amines

61790-33-8

u

u

u

u

u

u

FENTAMINE® DA-CO

N-Cocoalkyl 1,3-propanediamines

61791-63-7

u

u

u

u

u

u

u

u

u

FENTAMINE® DA-T

N-Tallowalkyl 1,3-propanediamines

61791-55-7

u

u

u

u

u

u

u

u

u

Secondary Amines

Tertiary Amines

FENTAMINE® DMA 1295

Dodecyl dimethylamine

112-18-5

u

u

u

u

u

u

u


Hexadecyl dimethylamine

112-69-6

u

u

u

u

u

u

u


Octadecyl dimethylamine

124-28-7

u

u

u

u

u

u

u


Octyl dimethylamine

7378-99-6

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

u

Specialty Amines

FENTAMINE® DMAPA

3-Dimethylamino 1-Propylamine

109-55-7

u

FENTAMINE® DEAPA

3-Diethylamino 1-Propylamine

104-78-9

u

FENTAMINE® MDEA

n-methyl diethanol amine

105-59-9

u

u

u

Specialty Amine Ethoxylates

FENTACARE® T02

Bis(2-Hydroxyethyl) tallowalkyl amine(2EO)

61791-44-4

u

u

u

u

u

u

u

u

FENTACARE® CO5

Cocoamine 5EO

61791-14-8

u

u

u

u

u

u

u

u

FENTACARE® CO2

Cocoamine 2EO

61791-14-8

u

u

u

u

u

u

u

u

RHODAMEEN® HT-50

Hydrogenated tallow amine ethoxylate

68783-22-2; 7732-18-5

u

u

u

u

u

u

—

—

RHODAMEEN® PN-430

Ethoxylated oleyl amine

58253-49-9

u

u

u

u

u

u

u

u

Ethoxylated tallow amine

61791-26-2

u

u

u

u

u

u

u

u

Di(hydrogenated Tallow) Dimethyl Ammonium Chloride

61789-80-8

u

u

u

—

u

u

u

61791-57-9

u

u

NE

u

u

u

NE

®

RHODAMEEN VP532 Quaternary Amine

FENTACARE® DHT 21 75

Fatty Alkyl Tri and Tetra Amine

FENTAMINE® DPTA- T u Listed

- Not listed

N1-Tallowalkyl dipropylenetriamines NE Not evaluated

** Availability based on REA CH registration


The way we do business Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reects our commitment to each of our stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere. Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership.

> Responsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987) > The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, Working Conditions, Respect for the environment and anti—corruption. (2003) > The International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005) > Solvay Novecare has achieved world—wide ISO—9001 Quality Management System Multi—Site Certification. (2008)

North America Solvay Novecare—504 Carnegie Center Drive, Princeton, NJ 08540—USA Phone: +1-800-973-7873—Fax: +1-609-860-0463—[email protected] Europe Solvay Novecare—40, rue de la Haie—Coq-F—93306 Aubervilliers Cedex—France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 Asia Pacific

Solvay Asia Pacific Pte. Ltd.—438B Alexandra Road—#02—09/12 Alexandra Technopark—Singapore 119968 Phone: +65-6291 1921—Fax: +65—6394 3377 Latin America Solvay Novecare—Centro Empresarial—Avenida Maria Coelho Ag uiar, 215, Bloco B-1º Andar Cep: 05804-902 —São Paulo—SP Brazil Phone: +55 11 3747-7637—Fax: +55 11 3741-8378 www.solvay.com Material Safety Data Sheets (MSDS) are available by emailing us or contacting your sales representative. Always consult the appropriate MSDS before using any of our products. Neither Solvay Specialty Polymers nor any of its aliates makes any warranty, express or implied, including merchantability or fitness for use, or accepts any liability in connection with this product, related information or its use. Some applications of which Solvay’s products may be proposed to be used are regulated or restricted by applicable laws and regulations or by national or international standards and in some cases by Solvay’s recommendation, including applications of food/feed, water treatment, medical, pharmaceuticals, and personal care. Only products designated as part of the Solviva® family of biomaterials may be considered as candidates for use in implantable medical devices. The user alone must finally determine suitability o f any information or products for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. The information and the products are for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance o r any other process. This is not a license under any patent or other proprietary right. All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners. © 2012 Solvay Specialty Polymers USA, LLC. All rights reserved.

t e n . t s a c m o c @ o e l i d a i r a m , n g i s e D c i h p a r G o e L i D — E R A C E V O N Y A V L O S 6 1 0 2 H C R A M

A N

Surfactants and Specialty Monomers

Contents

FORMULATED EMULSIFIERS ................................................................................... Page 2 SULFATES ............................................................................................................... Page 6 PHOSPHATE ESTERS................................................................................................ Page 8 SULFONATES............................................................................................................ Page 10 NONIONICS (APE FREE) ........................................................................................... Page 12 NONIONICS ............................................................................................................... Page 14 SPECIALTY MONOMERS ........................................................................................... Page 16 DEFOAMERS ............................................................................................................ Page 20

Solvay Novecare Emulsion Polymerization Working with Solvay

Solvay Novecare is the leading globalsu pplier of em ulsifiers, sp ecialty m ono m ers and specialty additives to the E m ulsion P olym erization Ind ustry.

w Extensive

portfolio of

products Fo r m ore than 4 0 years, w e have b een com m itted to p roviding lead ing ed ge so lutions to this industry. O ur portfolio has evolved into the m ost co m pre-

w S urfactants &

hensive range o f products addressing form ulation challenges and m ore

S pecialty

im portan tly ena bling cu stom ers to create tom orrow ’ s perform an ce req uire-

m onom ers dedicated to

m ents tod ay.

Em ulsion P olym ers m anufacturing

Solvay Novecare supports cu stom ers w ith a b road range o fsustainable so lutions and service s including products optim ized around criteria such

w O

as b iodeg rad ab ility, eco -toxicity, V O C co ntent, an d percentag e of

ver 40 years as m ajor

supplier to the Em ulsion

ren ew ab le m aterials.

P olym er industry O ur A P E -free surfactan t portfolio co vers allch em istries from nonionics (R H O D A S U R F ®), to an ionics like alkyl sulfonates (R H O D A C A L ®), alkylether

w G

sulfates (R H O D A P E X ®), sulfosuccinates (G ER O P O N ®), pho sp ha te esters

lobalplayer w ith local

technicalteam s to support

(R H O D A FA C ®)and form ulated blends (A B E X ®).

your develop m ents Solvay Novecare’s ded icated specialty m ono m er portfolio (S IP O M E R ) brings functionality an d boosts binder perform an ce to higher levels. W hether seeking to im prove substrate w etting, adhesion to differen t ®

substrates, em ulsion stab ility or sim ply dem an d higher film perform an ce, such as high scrub, stain or w ater resistan ce, S olvay has the solution.

Note: These products are produced at worldwide locations through the Novecare division of Solvay.

Solvay Novecare Emulsion Polymerization / 1

Formulated Emulsifiers

Description

APE/ APE-Free

Physical Form

Solids Content (%)

Critical Micelle Concentration (%)

ABEX® 18-S

Proprietary

APE-Free

Liquid

35

0.03

48

ABEX® 23-S

Proprietary

APE-Free

Liquid

60

0.10

40

ABEX® 26-S

Proprietary

APE

Liquid

33

0.02

55

ABEX® 33-S

Proprietary

APE

Liquid

30

0.12

37

ABEX® JKB

Proprietary

APE-Free

Liquid

30

0.13

40

ABEX® VA-50

Proprietary

APE

Liquid

46

0.17

44

ABEX® 2005

Proprietary

APE-Free

Liquid

30

—

—

ABEX® 2020

Proprietary

APE-Free

Liquid

30

0.01

41

ABEX® 2115-A

Proprietary

APE-Free

Liquid

33

—

—

ABEX® 8018

Proprietary

APE-Free

Liquid

31

0.05

37

ABEX® EP-100

Ammonium salt of Sulfated Nonylphenol Ethoxylate; 4 Moles EO

APE

Liquid

30

0.03

33

ABEX® EP-110


APE

Liquid

30

0.01

37

ABEX® EP-120


APE

Liquid

30

0.05

42

ABEX® EP-120 NA

Sodium Salt of Sulfated Nonylphenol ethoxylate

APE

Liquid

35

ND

ND

Product

Surface Tension at CMC (dynes/CM)

Formulated Anionics

Formulated Anionics

2 /Surfactants and Specialties

FDA Status

International Inventory Status ) S e C p E o r N u I E E (

a i l ) a r S t s C u I A A (

- ) o L K C E h K t ( u a o S e r

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

●

—

—

●

●

—

—

—

—

●

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—

—

—

—

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—

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—

—

—

—

—

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—

—

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—

—

RL

—

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—

—

—

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—

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—

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—

—

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—

—

—

—

—

—

—

—

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●

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—

—

—

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—

—

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—

—

L

—

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—

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—

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—

—

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—

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—

—

—

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—

—

—

—

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●

●

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—

—

—

—

—

—

—

—

—

●

●

●

●

●

●

FDA Listing Status Codes ●

0 3 . 1 8 1

) A C S T ( S U

0 0 4 3 . 8 7 1

Listed with no specic limits

E Extraction limitation

a d ) a L n S a D C (

n ) a T p I a M J (

International Inventory Status Codes

L Listed with limitations

R Referenced with no limitations

RL Referenced with limitations

● Listed

— Not Listed

Formulated Emulsifiers / 3

Formulated Emulsifiers

Solids Content (%)



Description

APE/ APE-Free

HLB

Physical Form

ABEX® 2515

Proprietary

APE-Free

16.3

Liquid

50

0.03

38

ABEX® 2525/40

Proprietary

APE-Free

17.4

Liquid

40

0.08

44

ABEX® 2535

Proprietary

APE-Free

18.0

Liquid

50

0.09

45

ABEX® 2545

Proprietary

APE-Free

18.3

Liquid

50

0.12

46

Product Nonionics


FDA Status

International Inventory Status ) S e C p E o r N u I E E (


- ) o L K C E h t K ( u a o e S r

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

●

—

—

●

●

—

—

—

●

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●

●

—

—

●

●

—

—

—

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—

—

●

●

R

R

—

●

●

●

●

●

●

●

●

—

—

●

●

—

—

●

●

●

●

●

●

●

●


0 3 . 1 8 1

) A C S T ( S U

0 0 4 3 . 8 7 1



a d ) a L n S a C D (

n ) a T p I a J M (





● Listed

— Not Listed

Formulated Emulsifiers / 5

Sulfates



Description

Ionic Charge

Physical Form

Solids Content (%)

RHODAPON® UB STD

Sodium Lauryl Sulfate

Anionic

Liquid

30

0.06

29

RHODAPON® L-22EP

Ammonium Lauryl Sulfate

Anionic

Liquid

28

0.06

33

Sodium Lauryl Sulfate

Anionic

Liquid

30

0.06

29

RHODAPEX EST-30*

Sodium Tridecyl Ether Sulfate; 3 Moles EO

Anionic

Liquid

30

0.08

33

RHODAPEX® LA-40S

Sodium Salt of Sulfated Linear Alcohol Ethoxylate; 4 Moles EO

Anionic

Liquid

31

0.02

32

RHODAPEX® LA-120S

Sodium Salt of sulfated linear Alcohol Ethoxylate, 12 Moles EO

Anionic

Liquid

30

0.02

34

RHODAPEX® LA-300S

Sodium Salt of sulfated linear alcohol ethoxylate, 30 Moles EO

Anionic

Liquid

30

0.03

44

RHODAPEX® AB-20**

Ammonium Salt of Sulfated Alcohol Ethoxylate; 9 Moles EO

Anionic

Liquid

29

0.03

33

RHODAPEX® OPS-253

Sulfate of Alkyl Phenol Ethoxylate Sodium Salt

Anionic

Liquid

36

0.09

36

Ammonium Salt of Sulfated Alkylphenol Ethoxylate; 4 Moles EO

Anionic

Liquid

58

0.03

33

Product ALKYL SULFATES

RHODAPON® LX-28 AEP ETHER SULFATES

RHODAPEX® CO-436 * North America Only, **Europe- Asia


FDA Status

International Inventory Status ) A C S T ( S U

) L S D ( a d a n a C

) S e C p E o r N u I E E (


a e r o K ) L h t C u E o S K (

) T I M ( n a p a J

d n a l e Z w e N

s e n i p p i l i h P

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

0 0 4 3 . 8 7 1

●

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L

—

—

L

L

—

—

L

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—

L

L

—

—

L

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L

L

—

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L

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L

●

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—

●

●



E Extraction L Listed with limitation limitations




● Listed

— Not Listed

Sulfates / 7

Phosphate Esters

Product

Description

Ionic Charge

Physical Form

Solids Content (%)



PHOSPHATE ESTERS RHODAFAC® RS-410

Aliphatic Phosphate Ester; 3 Moles EO

Anionic

Liquid

100

0.002

—

RHODAFAC® RS-610


Anionic

Liquid

100

0.002

—

Aliphatic Phosphate Ester; 6 Moles EO; Ammonium Salt Solution

Anionic

Liquid

25

0.01

30

RHODAFAC® RS-710


Anionic

Liquid

100

0.002

36

RHODAFAC® RS-710 D


Anionic

Liquid

30

0.002

36

RHODAFAC® RS-960


Anionic

Liquid

80

—

—

RHODAFAC® RE-410

Aromatic Phosphate Ester; 3 EO

Anionic

Liquid

100

—

—

RHODAFAC® RE-610

Aromatic Phosphate Ester; 9 Moles EO

Anionic

Liquid

100

0.01

37

RHODAFAC® RK-500 A

Aliphatic Phosphate Ester; 3.5 Moles EO

Anionic

Liquid

74

—

—

RHODAFAC® RS-610A-25


FDA Status

International Inventory Status a e r o K ) L h t C u E o S K (

) T I M ( n a p a J

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

0 0 4 3 . 8 7 1

) A C S T ( S U

—

—

—

—

—

—

—

—

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—

—

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—

—

—











● Listed

— Not Listed

Phosphates Esters / 9

Sulfonates

Ionic Charge

Physical Form

Solids Content (%)


Sodium Alpha Olen Sulfonate

Anionic

Liquid

40

0.07

29

RHODACAL® 330

Isopropyl Amine Dodecyl Benzene Sulfonate

Anionic

Liquid

90

0.1

32

RHODACAL® DS-10

Sodium Dodecyl Benzene Sulfonate

Anionic

Flake

98

0.1

32

RHODACAL® DS-4

Sodium Dodecyl Benzene Sulfonate

Anionic

Liquid

23

0.1

32

RHODACAL® DSB

Disodium Alkyl Diphenyloxide Sulfonate

Anionic

Liquid

45

0.08

32

RHODACAL® LDS-22

Sodium Dodecyl (linear) Benzene Sulfonate

Anionic

Liquid

23

0.1

32

GEROPON® SS-OIP

Disodium Salt of Monoalkyl Ether Sulfosuccinate

Anionic

Liquid

40

0.1

30

GEROPON® ACR-4

Disodium Sort 4 Monoalkyl ether Sulfosuccinate

Anionic

Liquid

31

0.01

29

Aqueous Dioctyl Sodium sulfosuccinate

Anionic

Liquid

75

0.35

27

Product

Description


SULFONATES

RHODACAL® A-246/L

SULFOSUCCINATES

Geropon® 99


FDA Status





) T I M ( n a p a J

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

●

●

●

●

●

●

●

L

●

●

●

●

●

●

●

—

—

—

—

—

●

—

●

●

●

—

—

—

L

L

●

●

●

—

—

—

●

●

●

●

●

●

L

L

●

●

●

—

—

—

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

—

—

—

●

●

●

●

●

●

—

—

—

●

R

—

—

L

●

●

●

●

●

—

●

—

—

—

—

—

—

●

●

●

●

●

●

—

●

●

—

●

●

—

●

—

●

●

●

●

●

●

R


0 0 4 3 . 8 7 1

) A C S T ( S U








● Listed

— Not Listed

Sulfonates / 11

Nonionics (APE Free)

Physical Form

Solids Content (%)


3

Liquid

100

—

TDA Ethoxylate

6

Liquid

100

—

—

11.4

RHODASURF® BC-720

TDA Ethoxylate

9-10

Paste

100

—

—

13.8

RHODASURF® BC-729

TDA Ethoxylate

9-10

Liquid

90

—

—

13.8

RHODASURF® BC-840

TDA Ethoxylate

15

Paste

100

—

—

15.4

RHODASURF® TLA 3040

TDA Ethoxylate

30

Liquid

40

0.08

44

17.4


TDA Ethoxylate

40

Liquid

50

0.09

45

18


TDA Ethoxylate

50

Liquid

50

0.12

46

18.3

RHODASURF® TR 4070*

TDA Ethoxylate

40

Liquid

70

—

—

—

RHODASURF® L-4

LA Ethoxylate

4

Liquid

100

—

—

9.7

RHODASURF® LA-9/85

LA Ethoxylate

9

Liquid

85

—

13.1

RHODASURF® LA-12/80

LA Ethoxylate

12

Liquid

80

—

14.4

RHODASURF® ON-870

OA Ethoxylate

20

Solid

100

0.015

37

15.4

RHODASURF® ON-877

OA Ethoxylate

20

Liquid

70

Proprietary

—

Liquid

65

0.08

41

17

RHODASURF® L-7/90

LA Ethoxylate

7

Liquid

90

—

30

12.5

RHODASURF® S25 28

TSP Ethoxylate

25

Liquid

28

—

ANTAROX® L-61

EO/PO

—

Flakes

100

—

Insoluble

3.0

ANTAROX® L-62

EO/PO

Liquid

100

—

Soluble

7.0

ANTAROX® L-64

EO/PO

Liquid

100

—

43.2

15.0

Description

Moles of Ethylene Oxide

RHODASURF® BC-420

TDA Ethoxylate

RHODASURF® BC-610

Product


HLB

ALIPHATIC ALCOHOL ETHOXYLATES

RHODASURF® 6530

8

14.5

BLOCK CO-POLYMERS

*Europe- Asia


—

FDA Status


) T I M ( n a p a J

5 0 1 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

0 0 4 3 . 8 7 1

0 3 . 1 8 1

) A C S T ( S U

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

—

—

—

●

●

●

●

●

●

●

●

●

●

—

—

—

●

●

●

●

●

●

●

●

●

●

—

—

—

●

●

●

●

●

●

●

●

●

●

—

—

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

●

—

●

●

—

—

—

●

●

●

●

●

●

●

—

●

●

—

—

—

●

●

●

●

●

●

●

●

—

—

●

—

●

●

●

●

●

●

●

●

●

●

●

●

—

●

●

●

●

●

●

●

—

—

—

—

—

—

—

●

●

●

●

●

●

●

●

●

●

●

—

—

●

●

●

●

●

●

●

—

●

●

●

—

—

●

●

●

●

●

●

●

●

●

●

●

—

—

●

●

●

●

●

●











● Listed

— Not Listed

Nonionics (APE Free) / 13

Nonionics

Product

Description

Moles of Ethylene Oxide

Ionic Charge

Physical Form

Solids Content (%)


Surface Tension at CMC (dynes/ CM)

HLB

ALKYLPHENOL ETHOXYLATES

IGEPAL® CA-210

Octylphenol Ethoxylate

1.5

Nonionic

Liquid

100

—

Insoluble

4.8

IGEPAL® CA-630


9

Nonionic

Liquid

100

0.005

31

13

IGEPAL® CA-877


23

Nonionic

Liquid

70

—

—

16.6

IGEPAL® CA-887


30

Nonionic

Liquid

70

0.03

38

17.4

IGEPAL® CA-897


40

Nonionic

Liquid

70

0.04

44

18

IGEPAL® CA-407


40

Nonionic

Liquid

70

0.04

44

18

IGEPAL® CO-210

Nonylphenol Ethoxylate

1.5

Nonionic

Liquid

100

-

IGEPAL®CO-430


4

Nonionic

Liquid

100

-

IGEPAL® CO-530


6

Nonionic

Liquid

100

0.03

32

10.8

IGEPAL® CO-630


9

Nonionic

Liquid

100

0.005

32

13

IGEPAL® CO-720


12

Nonionic

Liquid

100

0.007

36

14.2

IGEPAL® CO-730


15

Nonionic

Liquid

100

0.008

39

15.0

IGEPAL® CO-858


20

Nonionic

Liquid

80

0.01

41

16.0

IGEPAL® CO-887


30

Nonionic

Liquid

70

0.02

45

17.2

IGEPAL® CO-897


40

Nonionic

Liquid

70

0.04

44

17.8

IGEPAL® CO-977


50

Nonionic

Paste

70

0.05

44

18.2

IGEPAL® CO-987


70

Nonionic

Paste

70

0.05

48

18.6

IGEPAL® DM-430

Dinonylphenol Ethoxylate

7

Nonionic

Liquid

100

—

—

9.5


FDA Status

International Inventory Status ) L S D ( a d a n a C


) T I M ( n a p a J

5 0 1 . 5 7 1

0 0 3 . 5 7 1

0 2 3 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

0 0 4 3 . 8 7 1

) A C S T ( S U

●

—

—

●

—

—

●

—

●

●

●

●

●

●

●

R

R

R

●

R

R

●

●

●

●

●

●

●

●

—

—

—

●

—

—

—

●

●

●

●

●

●

●

—

—

●

●

—

—

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

—

●

—

●

—

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●



●

R

R

R

●

R

●

●

●

●

●

●

●

●

●

R

R

R

●

R

●

●

●

●

●

●

●

●

●

—

—

—

●

—

●

—

●

●

●

●

●

●

●

—

—

—

●

—

●

—

●

●

●

●

●

●

●

—

—

—

●

—

—

●

●

●

●

●

●

●

●

R

—

R

●

R

R

●

●

●

●

●

●

●

●

R

R

R

●

R

R

●

●

●

●

●

●

●

●

—

—

—

●

—

R

●

●

●

●

●

●

●

—

—

—

—

●

—

—

—

●

●

●

●

●

●

—

—

—

—

—

—

—

—

●

●

●

●

—

●


FDA Listing Status Codes ● Listed

with no specic limits

E Extraction L Listed with R Referenced limitation limitations with no limitations


● Listed

— Not Listed

APE Nonionics / 15

Specialty Monomers

% of Solid

Tg (°C)

% Water

Inhibitor ppm

Speci�c gravity

SIPOMER® PAM-100

100

-18

<1

MEHQ/~5000

1.2

SIPOMER® PAM-200

100

0

<1

MEHQ/~5000

1.1

SIPOMER® PAM-300

100

-40

<1

MEHQ/~5000

1.1

SIPOMER® PAM-4000

100

ND

<0.25

MEHQ/~400

1.2

SIPOMER® PAM 5000

100

NA

1.0 max

none

1.25

SIPOMER ® COPS-1

40

NA

60

none

1.17

SIPOMER® COPS-3*

25

NA

75

none

—

SIPOMER ® AES-100

97

NA

<2.0

none

1.0

SIPOMER ® AAE-10

99

NA

<0.3

none

—

Trade Name PAM Technology Adhesion and Much More

Polymerizable Stabilizers

* Asia - Latin America - MEA * ** *** ****

Remainder consists of acrylic acid (~20%) and higher adducts (~50%) Sipomer® BEM contains ~25% methacrylic acid Sipomer® SEM-25 contains ~20% methacrylic acid Sipomer® WAM II-25 contains ~25% methacrylic acid



) S a e C d ) p a L o E n S r N a u I D E E C ( (

a e r o a i l ) K ) a L r S h t C t s C u u I o E A S K A ( (

) T I M ( n a p a J

s e ) i n ) C p S a S i p C n C l i i C h E h I P C J ( P (

d n a l a ) e Z C o I w e Z N N (

Performance Features and Application

w Improved ●

—

●

●

●

—

●

—

●

adhesion on metal, glass, and other inorganic substrates w High mono/di alkyl phosphate ratio and low residual acid w Improved latex stability w Improved

●

—

●

●

●

—

●

—

—

adhesion on metal, glass, and other inorganic substrates compatibility with most common organic systems w Excellent compatibility w High mono/di alkyl phosphate ratio and low residual acid w Improved anti-corrosion anti-corrosion properties properties w Polymerizable surfactant w Improved

●

—

●

—

—

—

●

—

—

●

●

●

●

●

—

●

●

●

●

—

●

—

—

—

adhesion on metal, glass, and other inorganic substrates w Excellent compatibility with most common o rganic systems w High mono/di alkyl phosphate ratio and low residual acid w Improved anti-corrosion properties w Polymerizable surfactant w Improved

●

●

—

—

●

●

—

●

●

●

●

Improved scrub resistance when formulated into vinyl binders for high PVC paints

●

●

●

●

●

●

—

—

—

●

—

—

—

●

—

●

—

●

adhesion on metal substrate w Improved latex stability w Improved gloss

—

●

—

●

—

●

Reactive co-stabilizer providing: foaming latexes w Better latex stability at low surfactant dosage w Coatings with improved water and bleach resistance w Low

Reactive co-stabilizer providing scrub/washability for high PVC coating formulation Reactive co-stabilizer providing: foaming latexes Better latex stability at low surfactant dosage w w Coatings with improved water and bleach resistance w Low

Nonionic reactive co-stabilizer: w Low foaming latexes w Better latex stability at low surfactant dosage w Coatings with improved water and bleach resistance

International Inventory Status Codes ● Li Listed

— Not Listed

Specialty Monomers / 17

Specialty Monomers

% of Solid

Tg (°C)

% Water

Inhibitor ppm

Speci�c gravity

SIPOMER® IB I BOA

100

94

<0.05

MEHQ/112

0.985

SIPOMER® IB IBOMA

100

110

<0.05

MEHQ/108

0.983

SIPOMER® B B-CEA

30*

37

0.5

MEHQ/1000

1.2

SIPOMER® BEM

50**

ND

25

MEHQ/1000

1.06

SIPOMER® SEM-25

60***

ND

20

MEHQ/600

1.07

SIPOMER® HP H PM 100

50

ND

50

MEHQ/1000

1.06


50

ND

50

MEHQ/1000

1.06


50

ND

50

MEHQ/1000

1.06

90

NA

10

none

1.15

50***

87

30

HQ/1800

1.11

50

ND

50

TEMPO 250 and HQ 750 ppm

1.100

Trade Name Resin Modi�ers

Rheology

Wet Adhesion

SIPOMER® WA WAM SIPOMER® WA WAM II SIPOMER® WAM E W50 * Asia - Latin America - MEA * ** *** ****

Remainder consists consists of acrylic acid (~20%) and higher adducts (~50%) Sipomer® BEM contains ~25% methacrylic acid Sipomer® SEM-25 contains ~20% methacrylic acid Sipomer® WAM II-25 contains ~25% methacrylic acid



●

●

) S a e C d ) p a L o E n S r N a u I C D ( E E (

●

●

●

●

a e r o a i l K ) ) a L r S h t C t s C u u I o E A A ( S K (

●

●

●

●

) T I M ( n a p a J

●

●

s e ) i n ) C p S a S i p C n C l i i C E h h I C J ( P P (

●

●

●

●

d n a l a ) e Z C o I w Z e N N (

●


High Tg hydrophobic monomer providing: w Improved chemical and water resistance w Better gloss and better mar resistance w An excellent radiation curable reactive diluent High Tg hydrophobic monomer providing: chemical and water resistance w Better gloss and better mar resistance w Lower viscosity in high solid solvent based resin systems

●

w Improved

Low Tg acidic monomer: adhesion promoter for resins used in coatings and adhesives w Improved peel strength for adhesives

●

●

●

●

●

●

●

●

●

w Effective

●

●

●

—

●

—

●

●

●

Specialty monomer design for low shear HASE polymer

●

●

●

—

—

—

●

—

●

Specialty monomer design for mid to high shear HASE polymer

●

●

●

●

●

—

●

●

●

Specialty monomer design for mid shear HASE polymer

●

●

●

●

—

●

—

●

—

Spec Specia ialt lty y mon monom omer er desi design gn for for newt newton onia ian n HAS HASE E poly polyme merr

●

●

●

—

●

—

●

●

●

Specialty monomer design for low to mid shear HASE polymer

●

●

●

—

—

—

—

—

●

Wet adhesion monomer for latex paints

●

●

●

●

●

●

●

●

●


●

—

—

●

—

●

●

—

●

Wet adhesion monomer for paint applications

International Inventory Status Codes ● Li Listed

— Not Listed

Specialty Monomers / 19

Rhodoline® Defoamers

Product uses

e e r F E P A

e e r F C O V

l i s O n e i a n o t c n i o l i C S

E A V , s c c i i l l l y y y r n r c i c A V a

Product

Description

RHODOLINE® DF 540*

Zero VOC white oil defoamer for in-process latex processing. BfR compliant

●

●

Yes

●

●

RHODOLINE® 635

Zero VOC oil defoamer for in-process foam control

●

●

No

●

●

RHODOLINE® 646

Zero VOC oil defoamer for in-process vinyl and natural latex foam control

●

●

Yes

●

●

RHODOLINE® 670

Zero VOC oil defoamer for in-process vinyl latex processing

●

●

No

●

●

RHODOLINE® 990

Oil-free defoamer for latex systems, minimum impact on gloss

●

●

No

●

●

RHODOLINE® 999*

Oil-free defoamer for latex systems, minimum impact on gloss

●

●

No

●

●

*REACH Compliant


R B S

●

FDA Status


) T I M ( n a p a J

5 0 1 . 5 7 1

0 7 1 . 6 7 1

0 8 1 . 6 7 1

0 0 2 . 6 7 1

0 1 2 . 6 7 1

) A C S T ( S U

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

L

L

L

L

L

●

●

●

●

●




a i l ) a r S t s I C u A A (

— ●

—







● Listed

— Not Listed

Rhodoline® Defoamers / 21

The way we do business Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reects our commitment to each of our stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere. Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership.

> Responsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987) > The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, Working Conditions, Respect for the environment and anti—corruption. (2003) > The International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005) > Solvay Novecare has achieved world—wide ISO—9001 Quality Management System Multi—Site Certication. (2008)

North America Solvay Novecare—504 Carnegie Center Drive, Princeton, NJ 08540—USA Phone: +1-800-973-7873—Fax: +1-609-860-0463—[email protected] Europe Solvay Novecare—40, rue de la Haie—Coq-F—93306 Aubervilliers Cedex—France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 Asia Pacific Solvay Asia Pacic Pte. Ltd.—438B Alexandra Road—#02—09/12 Alexandra Technopark—Singapore 119968 Phone: +65-6291 1921—Fax: +65—6394 3377 Latin America Solvay Novecare—Centro Empresarial—Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar Cep: 05804-902 —São Paulo—SP Brazil Phone: +55 11 3747-7637—Fax: +55 11 3741-8378 www.solvay.com Material Safety Data Sheets (MSDS) are available by emailing us or contacting your sales representative. Always consult the appropriate MSDS before using any of our products.

t e n . t s a c m o c @ o e l i d a i r a m , n g i s e D c i h p a r G o e L i D — E R A C E V O N Y A V L O S 6 1 0 2

Neither Solvay Specialty Polymers nor any of its afliates makes any warranty, express or implied, including merchantability or tness for use, or accepts any liability in connection with this product, related information or its use. Some applications of which Solvay’s products may be proposed to be used are regulated or restricted by applicable laws and regulations or by national or international standards and in some cases by Solvay’s recommendation, including applications of food/feed, water treatment, medical, pharmaceuticals, and personal care. Only products designated as part of the Solviva® family of biomaterials may be considered as candidates for use in implantable medical devices. The user alone must nally determine suitability of any information or products for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. The information and the products are for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process. This is not a license under any patent or other proprietary right.

H C R A M

All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners. © 2012 Solvay Specialty Polymers USA, LLC. All rights reserved.

A N

SIPOMER® Specialty Monomers

For enhanced performance

Solvay Novecare Coatings

Novecare Coatings is a global leader in surfactant and specialty monomers committed to emulsion and specialty polymers. With over 40 years serving this industry, we have developed one of the most extensive portfolios of specialty monomers (SIPOMER® ) dedicated to improve architectural, industrial coatings and adhesives. Leveraging our portfolio of chemistries and local application expertise, we continue designing structures that will help you solve today’s challenges and define tomorrow’s standards.

Novecare Coatings / 1

CONTENTS Process / Adhesion / Surface Properties ...........................................................Page 4 wSIPOMER® PAM 100 wSIPOMER® PAM

200 wSIPOMER PAM 300 wSIPOMER® PAM 4000 wSIPOMER® PAM 5000 ®

Polymerizable Stabilizers .................................................................................... Page 16 wSIPOMER® COPS-1 wSIPOMER® COPS-3 wSIPOMER® AES-100 wSIPOMER® AAE 10 Wet Adhesion, Alkyd / Wood Adhesion ............................................................. Page 20 wSIPOMER® WAM wSIPOMER® WAM II wSIPOMER® WAM E W50 Resin Modifiers..................................................................................................... Page 28 wSIPOMER® IBOMA • Hardness wSIPOMER® IBOA • Hardness wSIPOMER® ß-CEA • Cohesive strength Rheology ...............................................................................................................Page 29 wSIPOMER® BEM wSIPOMER® SEM 25 wSIPOMER® HPM series

Note: These products are produced at worldwide locations through through the Novecare division of Solvay.

2 / Specialty Monomers

SIPOMER® “So little delivers so much” SIPOMER®s are very efficient. In most application, addition of 0.5 to 3% of these monomers deliver significant performance and bring functionality to your polymers. By leveraging our diverse chemistry platforms, Solvay designs solutions adapted to both monomer systems and formulation performance. Whether your formulation is waterborne, solventborne or you seek support in transitioning towards waterborne, SIPOMER® will deliver in the following properties:

From Technology to Solutions

Process

Surface Properties

• Clean EP Process • Improved mechanical, thermal & salt stability • Limit foaming

Adhesion

• High Scrub • Gloss • Low water sensitivity • EZ Clean • Scratch resistance

Mechanical Properties

• Wet Adhesion • Metal & Inorganic • Wood • Interaction with Pigments

• Tg depletion • Tg Increase • Peel Strength

SIPOMER®s / 3

SIPOMER® PAM “Adhesion and Much More” Performance Benefits Phosphate group 0H

Polymerizable group

Extender

0

P

wImproves binder

robustness 0

0H

Adhesion w

to metal

Adhesion w

to inorganic

substrate

SIPOMER® PAM 100

Reactive Group

Nature of Extender

Application

Methacrylate

Hydrophilic

Industrial

Methacrylate

Hydrophobic

Industrial/ Architectural / Adhesive

SIPOMER® PAM 300

Acrylate

Hydrophobic

UV/EB Cure

SIPOMER® PAM 4000

Methacrylate

~

Architectural

SIPOMER® PAM 5000

Allyl Ether

Slightly Hydrophilic

Architectural

Applications 0.5 to 1 wt% PHM

Concrete

0.5% PAM200

Concrete

After 2000 scrub cycles


to glass

wScrub resistance

SIPOMER® PAM 200

control

w Adhesion

wColor

development

wGloss

enhancement

Uses SIPOMER ® PAMs are available in a variety of structures compatible with most coatings chemistries, technologies and applications.

Effective in Different Polymer Systems

Effective on a Variety of Substrates

w Acrylic

w Aluminium

wStyrene/acrylic

wCold

rolled steel

wVeoVa/acrylic

wZinc

phosphated steel

wVinyl

wIron

phosphated steel

VeoVA

wPolyurethane

(via acrylic polyols)

wGalvanized wStainless

(plain and chromated)

steel

steel

wGlass wConcrete

SIPOMER® PAM / 5

SIPOMER® PAM “Adhesion and Much More” Technologies for different markets SIPOMER® PAM in various resins by either emulsion or solution polymerization. SIPOMER® PAM-100

SIPOMER® PAM-200

SIPOMER® PAM-300

SIPOMER® PAM-4000

SIPOMER® PAM-5000

> You want to add the phosphate monomer with no other modication to an existing latex recipe.

SIPOMER® PAM-100 can be added to the monomer feed in acidic form or to a separate feed in neutralized form.

Due to its surfactantcy properties, SIPOMER® PAM-200 may generate problems such as secondary nucleation.

Due to its surfactantcy properties, SIPOMER® PAM-300 may generate problems such as secondary nucleation.

SIPOMER® PAM 4000 is perfectly suited to be used in monomer mix

SIPOMER® PAM 5000 is perfectly suited to be used in monomer mix

> You want to minimize or or eliminate the primary surfactant.

*reduce the total amount of surfactant needed * cannot be used as a primary surfactant.

Reduce Reduce *reduce the total drastically the use drastically the use amount of of surfactant or of surfactant or surfactant needed may be used as may be used as *cannot be the sole surfactant the sole surfactant used as a primary in emulsion in emulsion surfactant. polymerization. polymerization.

*reduce the total amount of surfactant needed *cannot be used as a primary surfactant.

Not Surface active

SIPOMER® PAM-200 may be used as a sole emulsifer to stabilize pre-emulsion.

SIPOMER® PAM-300 may be used as a sole emulsifer to stabilize pre-emulsion.

Due to poor solubility in water, using SIPOMER® PAM-200 may lead to micellar polymerization.

Due to poor solubility in water, using SIPOMER® PAM 300 may lead to micellar polymerization.

EMULSION POLYMERIZATION

> You want to stabilize a pre-emulsion without any conventional surfactant.

Not Surface active Not Surface active

SOLUTION POLYMERIZATION

SIPOMER® PAM-100 is more hydrophilic and totally soluble in water when neutralized.

> Water soluble

> Solventborne (Polyacrylate Polyols…)

SIPOMER® PAM-100 can be used to make resins but might have compatibility issues with some polymers.

®

SIPOMER PAM-200 is soluble in a broad range of monomers and solvents.

SIPOMER® PAM-300 is soluble in a broad range of monomers and solvents and suitable for UV/EB applications.

UV/EB Cure

The acrylic functionality of SIPOMER® PAM-300 provides a higher reactivity in radiation cure application

UV/EB cure

n

Best

n

Possible


n

Not suitable

Water Soluble

Water Soluble

Example: Car Refinish: More cars coated with fewer problems Direct-to-metal substrates represent a significant field for innovation yielding process simplification and environmentally friendly solutions such as: wDirect-to-metal priming that consolidates a complex process into one step wShift from solventborne to waterbor ne resin systems

Thanks to their superior MAP/DAP ratio, SIPOMER ® PAM-100 and SIPOMER® PAM-200 are easily incorporated into polyurethane systems with minimum impact on

Standard primers for car refinishing are based on 2K polyurethane solventborne resin systems. Either SIPOMER® PAM-100 or SIPOMER® PAM-200, based on the formulation and technology used, will be effective in improving metal ad hesion of such systems.

viscosity. SIPOMER® PAM 200 can be used in polyurethane waterborne systems where it provides improved adhesion with system and stabilization features.

Adhesion Data in 2K Polyurethane Solventborne Systems SIPOMER® PAM-200 can significantly improve the dry and wet adhesion on both aluminum and cold-rolled steel. SIPOMER® PAM is used to make acrylic polyols. ALUMINUM

IMMERSION HOURS

DRY

2

4

1B

0B

0B

1% PAM

3-4B

0B

0B

4% PAM

5B

0B

0B

Control

Adhesion is evaluated according to ASTM D3359 test: OB poor adhesion - 5B perfect adhesion.

COLD-ROLLED STEEL

IMMERSION HOURS

DRY

2

4

8

24

48

Control

5B

4-5B

2B

0B

0B

0B

1% PAM

5B

2B

2B

1B

0B

0B

4% PAM

5B

5B

5B

5B

4-5B

4-5B

SIPOMER® PAM / 7

SIPOMER® PAM “Adhesion and Much More” Automotive Refinish: Direct-to-Metal (DTM) Benefits Ready-to-apply top coat with DTM primer in 30 minutes instead of 12 hours with standard systems

Coating Cost ($) 100%

92%

100%

Clear coat

Clear coat

Top coat Top coat

Primer Pre-treatment

Treating Primer

Metal

Metal

75%

50%

25%

0

Standard System

St and ar d S y st em

Direct to Metal

Example: Coil Coating: Improved efficiency and environmentally friendly Coil coating is a continuous and highly automated process whereas the metal coil is unwound and both the top and bottom sides are cleaned, chemically treated, primed, oven cured, top coated, oven cured again, and rewound for shipment. Thanks to this process, large coils can be coated at high speed before fabrication. Resins incorporating SIPOMER® PAMs will boost primer adhesion and anti-corrosion properties eliminating the need for pre-treatment step(s) translating into less waste, energy & process time.

D i r ect t o Met al

Benefits : wProcess savings: one step vs. two steps wEliminate

waste treatment and reporting/regulation requirements Linked to the use of heavy metals such as chrome and phosphorous.

Coil-Coating Cost ($) 100%

89%

Standard

Removal of Pre-treatment

100%

Top coat Top coat


Treating Primer

Metal

Metal

75%

50%

25%

0

Standard System


Removal of Pre-treatment

Example: Maintenance Coatings: An environmental solution that works! Organic coatings play an important role in corrosion protection. One of the key c hallenges to convert solventborne systems to more sustainable, water-based formulation resides in significant loss in adhesion and anticorrosion performances. Thanks to it’s excellence in metal adhesion, SIPOMER® PAM-200 boosts the performance of acrylic waterborne resins enabling matching performance versus solventborne anticorrosion coatings, allowing low VOC coa tings formulations and consumers who are demanding new products that meet or exceed the requirements for lower VOC coatings. Good Adhesion Results SIPOMER® PAM-200 was used to modify a waterborne styrene/acrylic resin. An anticorrosion paint was formulated and tested for adhesion and corrosion-resistance properties. Compared with a control paint formulated without SIPOMER® PAM-200, the results are below:

PAINT-BASED ON S/A LATEX WITH 1%

PAINT-BASED ON S/A CONTROL LATEX

CROSSHATCH RESULTS AFTER WATER IMMERSION

CROSSHATCH RESULTS AFTER WATER IMMERSION

24 hrs

520 hrs

24 hrs

520 hrs

> Cold-rolled steel

5B

5B

4B

2B

> Iron phosphate steel

5B

5B

1B

1B

> Zinc phosphate steel

3B

3B

0B

0B

S/A: Styrene/Acrylic

Adhesion is evaluated according to ASTM D3359 test: 0B poor adhesion –

5B perfect adhesion. Adhesion is evaluated after 24 hours and after 520 hours of immersion in water.

Good Anti-Corrosion Results

SIPOMER® PAM / 9

SIPOMER® PAM “Adhesion and Much More” Special-Purpose Coatings: Improved performance and efficiency This segment includes coatings for various metal substrates mainly applied by Original Equipment Manufacturers. This market ranges from coatings for large vehicles, such as trucks, farm tractors and cranes to house appliances. Different technologies compete in this market with the objective of a single, multipurpose coating applied directly to metal. The result is elimination of pre-treatment and fewer steps in the p rocess! Either SIPOMER® PAM-100 or SIPOMER® PAM-200, based on the formulation and technology used, can boost acrylic resin performances in terms of adhesion and corrosion resistance and offer a viable solution for directto-metal applications.

Coating Cost ($)

100%

84%

St and ar d S y st em

Si ngle coat D i r ect t o Met al

100%

Top coat

75%

Single coat Direct to Metal


Metal

Metal

50%

25%

0

Standard System

Single coat Direct to Metal

Good results without pre-treated substrate SIPOMER® PAM-100 was used to modify a waterborne styrene/acrylic resin. The resin was formulated in a clearcoat and tested for adhesion on untreated, coldrolled steel. Wet adhesion was evaluated under different test conditions: wWater-spots

test wImmersion test w After 24 hours recovery

or special purpose coatings, the benefits of using the SIPOMER ® PAMs include:

Control 2%

PAM-100

4-hour spot test

0B (0%)

4B (95%)

4-hour immersion test

0B (0%)

3B (92%)

24-hour recovery test

0B (0%)

5B (100%)

Anticorrosion is evaluated according to ASTM D3359 OB: poor adhesion 5B: perfect adhesion


Conclusions SIPOMER® PAM-100 and SIPOMER® PAM-200 specialty monomers enable process simplification and cost savings for the industrial coatings market. Whether your application is automotive refinishing, coil coatings,maintenance

wElimination

of costly metal pre-treatment step wReduction of layers in the coating system wCost saving of labor required for the coating application A shift from heavy metals-based w conversion coatings to organic A shift from solventborne to w waterborne systems

SIPOMER® PAM-4000 – Metal Adhesion Promoter

Monomer Ratio (BOTM)

BLANK

SIPOMER® PAM 4000

Cross-hatched Tape Adhesion Test - Cold Steel

MMA

51.5

BA

46.5

MAA

1

SIPOMER® PAM-4000

1

Surfactant Charge (BOTM) Rhodapex RS-610 A25

0.5 in Kettle 1.0 in Pre-emulsion

Initiator System: Thermal, Ammonium Persulfate

Seed: 20% Initiator Solution / 4% Pre-Emulsion

Particle Size : 126 nm

Latex Stability : Freeze/Thaw Stability - 5+ cycles Heat Stability (60C) - 30+ days

SIPOMER® PAM / 11

SIPOMER® PAM “Adhesion and Much More” High Scrub for high PVC binders in Architectural coatings with SIPOMER® PAM-5000

Number of cycles DIN scrub resistance at 85 % PVC

Latex Property Results Benchmark

SIPOMER® PAM 5000

119

126

50.30%

50.10%

92

22

Clean

Clean

Viscosity @ 20 rpms (mPa)

548

494

Viscosity @ 50 rpms (mPa)

386

252

Particle size (nm) Solids content (%) Grit / 120mesh (ppm) Coagulum

Matte Paint Application Data Scrub Resistance Results (PVC = 82)

Scrub Resistance Measurement ISO test rst serial (µ) DIN scrub resistance (cycles)

Benchmark

1 % SIPOMER® PAM 5000

36

17

1050

4000

Improve Scrub Resistance in High PVC Paints SIPOMER® PAM-5000 – Styrene/Acrylic Starting Point Recipe

Monomer Ratio (BOTM) Styrene

49.5

BA

47.5

AA

2

SIPOMER® PAM-5000

1.0 (in Kettle Charge)

Surfactant Charge (BOTM)

High PVC Vinyl VeoVA paint formulation Ingredients

Parts per weigh

Demineralised water Rhodafac® RS 710-E (10%aq. Sol. At pH 7-8) Potassium persulphate

399 25

Demineralised water Rhodafac® RS 710-E (10%aq. Sol. At pH 7-8) Sodium bicarbonate Vinyl VeoVA* 2-Ethylhexyl acrylate Pre-emulsion SIPOMER® COPS-1 (40% aq. Sol.) Acrylic acid Vinyl acetate SIPOMER® PAM 5000 (30% aq. Sol. At pH 5) Silquest A 171

393 45

Initial Reactor Charge

3 200 70 9.4 1.5 730 33.2 2.5

Demineralised water Potassium persulphate

120 1

Line one

Demineralised water Ter-butyl hydroperoxyde (70% aq. Sol.)

20 1.4

Seed: 20% Initiator Solution / 4% Pre-Emulsion

Line two

Demineralised water Bruggolite FF6M

20 1.2

Particle Size: 120 nm

Neutralisation AMP 95 until pH of 8-8.5

Latex Stability: 5 cycles of Freeze/Thaw Stability

Biocide

Rhodapex® LA-40S

0.1 in Kettle Charge 0.9 in Pre-emulsion

Rhodafac® RS-610A25

1.0 in Pre-emulsion

Initiator solution

1

Other

Initiator System: Thermal, Ammonium Persulfate


Parmetol K40

8.3 2

General Guidance for use of SIPOMER® PAM Monomers

> Storage –Feedings tanks

> High reactivity

DO

DON’T

Do use stainless steel or plastic containers to store solutions of SIPOMER® PAM.

Don’t use iron containers that can be corroded by acidic SIPOMER ® PAM releasing metal ions that could trigger the polymerization.

Do follow the order of introduction of our starting recipes. Put SIPOMER® PAM in the kettle when the reaction temperature is met. Do feed separately or in the monomer mixture/pre-emulsion.

Don’t introduce SIPOMER® PAM in the initial charge before heating. Don’t mix with the solution of the initiator. This would rapidly polymerize even without heating.

Do neutralize the polymer before heating at elevated temperature ( > 140° C).

> Heat stability of polymer

> Hydrolytic stability

> Corrosion

Copolymers are more stable and can be handled above 200° C. This is strongly dependent on the nature of the polymer and must be checked case by case.

Don’t heat acidic homopolymers to temperatures above 140° C.

Do keep between pH = 5 and pH = 9 for long time storage or when using at temperatures above 60° C.

Don’t use diluted SIPOMER ® PAM very acidic (pH < 3) or basic (pH > 10) conditions. This would hydrolyze the ester linkage and the phosphate group.

Do neutralize with a non volatile base and add corrosion inhibitor. Keep the coating at pH > 9 for good anticorrosion properties.

Don’t use SIPOMER® PAM in acidic form when post neutralization is not possible.

SIPOMER® PAM / 13

SIPOMER® Polymerizable Stabilizer Key Features w Improve mechanical stability

Stabilizers

Improve thermal stability w Improve salt stability w Decrease need in surfactant w Reduce foaming & water sensitivity w

Covalent Bound

Reactive Group Nature of Extender SIPOMER® COPS SIPOMER® AAE10 SIPOMER® AES-100

« Head » group

Allyl ether

Hydrophobic

Sodium Sulfonate

Allyl ether

Hydrophilic

Ethoxylate

Allyl ether

Hydrophilic

Ammonium Sulfate

SIPOMER® COPS-1 is a 40% aqueous solution of sodium 1-allyloxy-2-hydroylpropyl sulfonate:

CH2 = CH - CH2 - O - CH2 - CH(OH) - CH2 - SO3Na Even at levels as low as 0.5 - 1.0% (based on total monomer), SIPOMER® COPS-1 provides latex stability, such as shelf life, freeze/thaw and mechanical and chemical stability. It also provides block resistance for the final polymer. With SIPOMER ® COPS-1, the levels of conventional can be reduced significantly. Surfactants are key component in providing stability to latex. However their migration to the interface causes water sensitivity to the dry polymer film. SIPOMER® COPS-1 reacts with other reacts with other c omonomers through the chemical (covalent) bond. The sulfonate group will remain at the surface of the particle providing very good stability to the latex. Since the functionality is anchored to the polymer backbone, it will not migrate after film formation and thus cannot modify interfacial properties. As a result of the reduction of conventional surfactant, the foaming tendency of the latex and the water sensitivity of the polymer film are both reduced.


Applications w Use 0.5 Wt% based on total monomer (BOTM) w All

acrylic, styrene acrylic, vinyl acrylic, vinyl VeoVA

SIPOMER® COPS-1 Polymerizable Stabilizer Reactivity Ratio Data for SIPOMER® COPS-1 (M1)

The reactivity ratio data show that the r1 values for SIPOMER® COPS-1 are close to 0, suggesting that homopolymerization of this monomer is unlikely. There is no need for adding an inhibitor to this monomer. As shown on the Mayo representation below, the most favorable reactivity ratios were found for SIPOMER® COPS-1 with vinyl acetate and VeoVA 10. However, SIPOMER® COPS-1 can also work very effectively in acrylic and styrene/acrylic systems.

Mayo Curves for SIPOMER ® COPS-1

SIPOMER® Polymerizable Stabilizer / 15

SIPOMER® COPS-1

Polymerizable Stabilizer Addition of SIPOMER® COPS-1 SIPOMER® COPS-1 improves Freeze/Thaw Stability Latexes

Acrylic control

Acrylic with COPS-1

Styrene/acrylic control

Styrene/acrylic with COPS-1

Surfactant % BOTM

Rhodacal® DS4 1

Rhodacal® DS4 1

Rhodapex® LA40S 1.5

Rhodapex® LA40S 1.5

SIPOMER® COPS-1 % BOTM

0

0.5

0

0.5

Particle size (nm) Solids (%)

17.9 49.8

186 49.9

175 51.1

149 51.1

Freeze thaw cycles

0

5

0

5

Rhodacal DS4: Sodium dodecylbenzene sulfonate (23%) Rhodapex LA40S: Sodium dodecyl ether sulfate; 4 EO (32%) Freeze/thaw test

Procedure: Latex was placed in -15C conditions for 12 hours and thawed back to RT for 8 hours. Cycles were repeated 5 times.

SIPOMER® COPS-1 improves mechanical stability Latexes

Acrylic control

Acrylic with SIPOMER® COPS-1

Surfactant % BOTM

Rhodacal® DS4 1

Rhodacal® DS4 1

SIPOMER® COPS-1 % BOTM

0

0.5

Particle size (nm) Solids (%)

179 49.8

186 49.9

Waring blender 5 minutes at 20,000 rpm

Failed

Passed

Mechanical test procedure: Pour 200 mL of latex into a Waring blender. Mix latex at 20,000 rpm under high shear for 5 minutes. If the latex does not completely coagulate after 5 minutes of mixing, it “passes.” If it coagulates within 5 minutes of mixing, it fails.


SIPOMER® COPS-1 improves chemical stability Latexes

Acrylic Control 1

Acrylic Control 2


Acrylic with nonionic surfactant

Anionic surfactant Rhodapex® LA40S (%BOTM)

1.0

1.5

1.0

1.5

Nonionic surfactant (% BOTM)

0

0

0

1.0

SIPOMER® COPS-1 (% BOTM)

0

0

0.5

0

% CaCl2 added to latex for immediate coagulation

3

6

5

5

Substitution of surfactant by SIPOMER® COPS-1 in a latex formulation

Latexes

Acrylic control


Surfactant % BOTM

Rhodacal® DS4 1.0

Rhodacal® DS4 0.5

SIPOMER® COPS-1 Particle size (nm)

0 179

0.5 196

Solids (%) Wet coagulum (% BOTL)

49.8 0.7

50.6 0.7

Freeze/Thaw cycles Mechanical stability

1 Passed

5 Passed

Foaming height (mL)

200

120

Latex Chemical Stability: The ability of latex to resist coagulation in the presence of salts. (Salt used is Calcium chloride) Procedure: Add CaCl2 at dierent levels to the latex until i mmediate coagulation is observed. The data above should be read as follows: CaCl2 was added (in term of weight % compared to total latex -% BOTL): «3%» means that the system was stable at 2% of CaCl2 «6%» means that the system was stable at 5% of CaCl2 Comments: By adding COPS-1, the chemical stability results are improved. To have the same eect in terms of chemical stability, normally non ionic surfactant is used. COPS-1 improves chemical stability without increasing the amount of free surfactant.

Mechanical test procedure: Pour 200 mL of latex into a Waring blender. Mix latex at 20,000 rpm under high shear for 5 minutes. If the latex does not completely coagulate after 5 minutes of mixing, it “passes.” If it coagulates within 5 minutes of mixing, it fails.


SIPOMER® COPS-3

Polymerizable Stabilizer Features: w Good pigment binding power w High PVC paints system w Anti-corrosion properties w Improved color acceptance w Good stain and block resistance

SIPOMER® COPS-3

Product Specications Appearance

Transparent liquid

Active content

39.0-42.0

Color APHA

200 Max

pH (10% aqueous solution)

6.0 - 9.0

Ionic type

Anionic

Improve adhesion to dierent inorganic substrate w Applicable to most of monomers systems: SA, FA, VA, VeoVA, etc. w

Improve Water-Resistance & Corrosion Inhibition 50wt% SA latex: 1% of Rhodapex® LA 40S; 0.5% of BOTM COPS-3 Without COPS-3

With COPS-3

Without COPS-3

• Glass substrate: 100 um lm • Soaking into water for 24 hrs

• Substrate: Iron phosphate panel Curing @ room temperature, 60-70% RH

COPS-3 in Vinyl VeoVA System

55% Vinyl VeoVA System: VAM/VeoVA-10:70:30 w 1% BOTM of COPS-3 w 0.3% BOTM of RS610-A25 & 2% BOTM of Rhodasurf ® 6530 w

Particle size (nm)

Commercial SA

Without COPS-3

COPS-3

~150

262.2

238.7

405

1168

75 PVC paints Scrub resistance *Only available in China


550

With COPS-3

SIPOMER® AES 100

Copolymerizable Stabilizer Key Benefits w Reduce Grit w Increase stability (mechanical, FT, chemical )

SIPOMER® AES-100 Latex

MMA

52

BA

47

MAA

1

Particle Size: 150 nm

Surfactant

Type

Rhodapex® LA40S

Amount in Kettle:

0.10%

Amount in Feed:

0.90%

In situ-seeded pre-emulsion

Amount of AES-100

0%

1%

1%

Way of Addition of AES-100

Feed

Kettle

Dry Grit

130 ppm

10 ppm

70 ppm

Mechanical Stability

3'

9'

9'

F/T stability

0

>5

>5

Calcium Stability

2%

5%

6%

Dry Grit: Filtration on 100 micron net Mechanical Stability: Waring Blender 22.000 rpm ( time to coagulation ) Calcium Stability: CaCl2*2H2O/Dry latex ratio ( concentration to coagulate a 30 % diluted latex )


SIPOMER® WAM

Wet Adhesion Monomers “The 1% that makes the difference”

SIPOMER® WAM SIPOMER® WAM II SIPOMER® WAM E W50

Reactive Group

Binders

Allyl Ether

Both acrylic & vinyl copolymers

Methacrylamide

Acrylics

Methacrylate Ester

Acrylics

SIPOMER® WAM into the Superior wet-adhesion properties SIPOMER® WAM was custom designed to combine the benefits of amine and ureido functionalities in a single monomer. The Table below shows the synergistic effects of this combination.

polymer backbone greatly improves wet-adhesion of both all-acrylic and vinyl-acrylic latex paint systems for both interior

®

SIPOMER WAM is incorporated into all-acrylic and vinyl-acrylic polymer systems through its allylic functionality. It provides wet adhesion in two ways: w The

ureido ring promotes interaction with the substrate via its high polarity and hydrogen bonding. The amine functionality provides an additional site for interaction w with substrate and pigment. SIPOMER® WAM modifies the latex binder, enabling it to wet the pigment particles more effectively, due to reduced interfacial tension. Eects of Amine and Ureido Functionalities, Alone and In Combination


and exterior applications.

Lab tests demonstrate exceptional wet adhesion Test after test has proven that all-acrylic and vinyl-acrylic polymers containing SIPOMER® WAM provide latex paints with the be st and most cost-effective wet-adhesion properties available. In a Wet Pick Adhesion Test, latex with SIPOMER® WAM showed greater wet adhesion as indicated by the substantially smaller area of peeling. And in a Wet Adhesion Abrasion Test, the latex paint containing SIPOMER® WAM demonstrated outstanding wet-scrub performance. Results of Wet Pick Adhesion Test

Results of Abrasion Test

SIPOMER® WAM-based paints compared to commercial products As shown in the Table below, polymers containing SIPOMER® WAM were evaluated against commercial wet adhesion systems. Paints based on SIPOMER® WAM exhibited superior wet-adhesion properties as well as greater shelf stability and improved color stability. When effective use levels were measured, SIPOMER® WAM also proved to be the most cost-effective wet-adhesion promoting system available. Gardner Scrub Test Results with SIPOMER ® WAM-Based Paints Versus Commercial Standards

Control

Control

SIPOMER® WAM / 21

SIPOMER® WAM II

Wet Adhesion Monomer Innovative chemical structure

SIPOMER® WAM II provides

With SIPOMER® WAM II, emulsion polymerization producers can formulate products with an easy-to-use wet-adhesion monomer which is effectively

enhanced wet-adhesion,

polymerized in both redox and thermal processes.

wet-scrub resistance and solvent resistance in a wide range of latex systems.

MAEEU The MAEEU advantage is its ability to easily copolymerize in all-acrylic, vinyl-acrylic and styreneacrylic latex systems.

SIPOMER® WAM Il’s improved performance is the result of MAEEU (methacrylamidoethylethyleneurea), an advanced ureido-based adhesion promoting monomer.

SIPOMER® WAM II in Latex Blends


Dramatically improved wet-scrub resistance Wet-Scrub Resistance Test

Similar results with SIPOMER® WAM II in semi-gloss paint When all-acrylic latexes containing SIPOMER® WAM II were formulated into a semi-gloss paint at 23% PVC, improved wet-scrub resistance was demonstrated. The paint formulated without SIPOMER® WAM II began lifting from the substrate at 95 cycles. The paint formulated with SIPOMER® WAM II exhibited outstanding scrub resistance, completely covering the substrate after 2000 cycles.

SIPOMER® WAM II / 23

SIPOMER® WAM Ester

Wet Adhesion Monomers SIPOMER® WAM E Technologies wWet

adhesion monomers for emulsion polymerization • Based on N-(2-Methacryloyloxyethyl) ethylene urea chemistry • Typical usage levels between 0.5 and 2.0 BOTM

wPrimarily

recommended for waterborne acrylic and styrene acrylic binder systems • Improve wet adhesion • Improve scrub resistance

Also w

used in polymerizations and co-polymerizations in bulk, suspension and solution with polymers for use in plastics, leather, paper and textile industries

SIPOMER® WAM Ester wSIPOMER® WAM

E W50 50 % Active in Water

O O N

NH

O wMethacrylate

polymerizable group wUreido ring functionality for wet adhesion wChoice of activity and diluents

Typical Properties Property

Appearance

SIPOMER® WAM E W50

Yellowish Liquid

Gardner Color

5 max

Solids, %

48 – 52

Viscosity, cPs

50 max

Density at 25 ºC, g/mL MMA, %


1.00 – 1.20 2.0 max

Features: wExcellent wet adhesion improvement wSignificant

scrub resistance improvement

wReadily

incorporated into most polymer systems

wExcellent

binder conversion rate

Application Testing SIPOMER® WAM E W 50 & WAM E MMA 50 products in all-acrylic latex binder system

wEvaluated

wPaint

application test were conducted in a semi gloss all-acrylic paint system

Tested w

for wet adhesion, scrub, gloss, viscosity, stability and all other paint properties

SIPOMER® WAM Ester / 25

SIPOMER® WAM Ester

Wet Adhesion Monomers All-Acrylic Emulsion Polymerization Formula Materials

BOTM

Monomers

Property Resin Solids

Target 50%

MMA*

52

Seed Particle Size

40 max

BA

46

Final Particle Size

130 nm

MAA

1

pH

9.0 – 9.5

Wet Adhesion Monomer**

1

Dried Coagulum, %

0.25 max

Surfactant – Rhodacal DS-4

1

Resin Viscosity, cPs

< 500

Kettle

0.15

Monomer Emulsion

1.25

Initiator System (2 % in water)

Thermal

Ammonium Persulfate 2% Monomer Emulsion

Seed 25 % Initiator Solution Temperature during Monomer Addition

80 ºC

Monomer Addition

3h

Post-Monomer Addition Temperature

85 ºC

Emulsion Polymerization Results Binder Property

No WAM Added

SIPOMER® WAM E W50

Seed Particle Size, nm

37

36

pH before neutralization

2.2

1.9

pH after neutralization

9.2

9.3

Solids, %

49.7

49.8

Conversion, %

100

100

Dried coagulum, %

0.05

0.03

Resin Viscosity, cPs

123

125

Resin Particle Size, nm

133

126


S/G Acrylic Paint Test Formula Materials

PARTS

GRIND

Property

Target

Gloss

45 - 55

Water

6.0

PVC

25

Propylene Glycol

2.0

KU Viscosity

95 - 97

Rhodoline® 111

1.0

ICI Viscosity

0.8 – 1.3

Rhodoline® 681F

0.2

Rhodoline® WA 100

0.2

Ti-Pure R-826

27.0

LETDOWN Latex

40.0

Rhodoline® 681F

0.1

Texanol

2.0

Acrysol RM-8W

0.5

Acrysol 2020 NPR

0.4

Water

20.6

Paint Test Results Property

Blank

SIPOMER® WAM E W50

Viscosity, ON, KU

95.4

96.3

Viscosity, ON, ICI

0.84

1.13

Gloss, 20/60/85 º

13.3/50.9/78.7

11.4/47.6/76.4

97.3

97.9

500

4752

100 %

497 %

Contrast Ratio Scrub Test* # cycles to breakthrough Wet Adhesion Test** * Scrub test results on vinyl scrub panel ** Wet adhesion Scrub Test ASTM D6900-10

SIPOMER® WAM Ester / 27

SIPOMER®

Resin Modifiers SIPOMER® IBOA Radiation curing resins application w Improves toughness, chemical and abrasion resistance w Reactive Diluent w Radcure polymerizable

“Improved peel strength” 100% Acrylic Pressure Sensitive Adhesive 15

180° horizontal peel test

12

SIPOMER® IBOMA Clear coat application w Improves toughness, chemical and abrasion resistance w Easily incorporated in resins (methacrylate) SIPOMER® ß-CEA Adhesives application w Lowers Tg w Improves adhesion

) m m 5 2 9 / N ( h t g n e r t s l 6 e e P

3

0

0% B - CEA


■ After

3 min, adhesion

■ After

1 hr. adhesion

0.5 % B-CEA

6.0

8.5

10.0

13.0

SIPOMER® BEM – SIPOMER® SEM – SIPOMER® HPM series

Rheology By combining its experience in specialty monomers and emulsion polymerization, Solvay extended the available range of specialty methacrylic esters monomer for HASE thickeners. SIPOMER® BEM SIPOMER® BEM delivers low shear eciency.

PSEUDOPLASTIC

SIPOMER® HPM 400 SIPOMER® HPM 400 delivers low to mid shear eciency. SIPOMER® HPM 400 allows to easily match cellulosic thickeners profles. SIPOMER® HPM-100 SIPOMER® HPM 100 delivers mid shear eciency. SIPOMER® SEM 25 SIPOMER® SEM 25 delivers mid to high shear eciency. SIPOMER® HPM 200 SIPOMER® HPM 200 delivers high shear eciency. SIPOMER® HPM 200 allows to easily match Newtonian thickeners profles.

NEWTONIAN

Solvay SIPOMER® HPMs are 50 Wt% active specialty methacrylic monomers designed to easily acce ss desired rheology profiles. Working with SIPOMER® HPMs provides choice in profile and significant cost saving versus “generic” HASE. Properties Solvay SIPOMER® HPMs were incorporated in standard HASE polymer recipes and benchmarked versus well known “generic” HASE at equal viscosity (95KU) in 30 Wt% solid latex (table 1) as well as at equal use level in flat paints (table 2). While the HPM 200 based thickener presents a very perfor mant solution as Newtonian ICI builder, the HPM 100 based HASE combines KU building and improved ICI viscosity. Whereas cellulosic replacement is targeted, HPM 400 based system offers matching profile with higher efficiency. Active HASE Wt%

Brookfield (cP)

ICI (P)

HPM 200 based hase - A

1.87

1400

2.55

Benchmark 1

3.17

1350

2.25

HPM 100 based hase - B

0.56

6800

0.6

Benchmark 2

0.57

4600

0.5

HPM 400 based hase - C

0.42

7600

0.25

Benchmark 3

0.36

7200

0.22

HEC

0.76

7600

0.25

Table 1: All paint latex system were adjusted to 95 (±2) KU stormer viscosity

HPM 400 based HASE

Benchmark 3

HPM 100 based HASE

Benchmark 2

Usage ( Wt% Active)

0.5

0.5

0.5

0.5

1.6

1.6

Equilibrium Stormer Viscosity (KU)

78.6

83.5

100.6

94.6

100.3

113.4

0.7

0.6

1

1

2.05

1.5

1.3/2.4/5.9

1.3/2.3/5.5

1.3/2.4/6.1

1.3/2.5/7.1

1.3/2.6/7.8

1.3/2.5/7.0

Equilibrium ICI (P) Gloss, 20° / 60° / 85°

Used as KU builders

HPM 200 Benchmark 1 based HASE

Used as ICI builders

®

Table 2: SIPOMER HPMs based HASE bench marked at equal use level in a at paint formula

Rheology / 29

SIPOMER® Product Performance Internati % of Solid

Tg (°C)

% Water

Inhibitor ppm

Specific gravity

US (TSCA)

SIPOMER® PAM-100

100

-18

<1

MEHQ/~5000

1.2

●

—

●

●

SIPOMER® PAM-200

100

0

<1

MEHQ/~5000

1.1

●

—

●

●

SIPOMER® PAM-300

100

-40

<1

MEHQ/~5000

1.1

●

—

●

—

SIPOMER® PAM-4000

100

ND

<0.25

MEHQ/~400

1.2

●

●

●

●

SIPOMER® PAM 5000

100

NA

1.0 max

none

1.25

●

—

●

—

SIPOMER® COPS-1

—

NA

60

none

1.17

●

●

●

●

SIPOMER® COPS-3*

25

NA

75

none

—

—

—

SIPOMER® AES-100

97

NA

<2.0

none

1.0

●

—

●

—

SIPOMER® AAE-10

99

NA

<0.3

none

—

●

●

●

●

SIPOMER® IBOA

100

94

<0.05

MEHQ/112

0.985

●

●

●

●

SIPOMER® IBOMA

100

110

<0.05

MEHQ/108

0.983

●

●

●

●

SIPOMER® B-CEA

30*

37

0.5

MEHQ/1000

1.2

●

●

●

●

Trade name

Canada Europe + Australia (DSL) (EINECS) (AICS)

Adhesion and Much More

Polymerizable Stabilizers

—

Resin Modifiers

+ Availability is based on REACH status ND – not determined NA – not applicable


* Asia - Latin America - MEA * Remainder consists of acrylic acid (~20%) and higher adducts (~50%) ** SIPOMER® BEM contains ~25% methacrylic acid *** SIPOMER® SEM-25 contains ~20% methacrylic acid **** SIPOMER® WAM II-25 contains ~25% methacrylic acid

onal Inventory Status South Korea (KECL)

●

Japan China Philippines (MIT) (JECSC) (PICCS)

New Zealand (NZIoC)

—

●

—

●

●

—

●

—

—

—

—

●

—

—

●

—

●

●

●

—

—


— Improved adhesion on metal, glass, and other inorganic substrates — High mono/di alkyl phosphate ratio and low resididual acid — Improved latex stability — Improved adhesion on metal, glass, and other inorganic substrates — Excellent compatibility with most common organic systems — High mono/di alkyl phosphate ratio and low resididual acid — Improved anti-corrosion properties — Improved adhesion on metal, glass, and other inorganic substrates — Excellent compatibility with most common organic systems — High mono/di alkyl phosphate ratio and low resididual acid — Improved anti-corrosion properties — Polymerizable surfactant — Improved adhesion on metal substrate — Improved latex stability — Improved gloss Improved scrub resistance when formulated into vinyl binders for high PVC paints

●

●

●

●

●

—

—

●

—

—

—

—

—

—

—

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

●

Reactive co-stabilizer providing: — Low foaming latexes — Better latex stability at low surfactant dosage — Coatings with improved water and bleach resistance Reactive co-stabilizer providing scrub/washability for high PVC coating formulation Reactive co-stabilizer providing: — Low foaming latexes — Better latex stability at low surfactant dosage — Coatings with improved water and bleach resistance Non ionic reactive co-stabilizer — Low foaming latexes — Better latex stability at low surfactant dosage — Coatings with improved water and bleach resistance High Tg hydrophobic monomer providing: —Improved chemical and water resistance — Better gloss and better mar resistance — An excellent radiation curable reactive diluent High Tg hydrophobic monomer providing: — Improved chemical and water resistance — Better gloss and better mar resistance — Lower viscosity in high solid solvent based resin systems Low Tg acidic monomer: — Eective adhesion promoter for resins used in coatings and adhesives — Improved peel strength for adhesives

International Inventory Status Codes ● Listed

— Not Listed

SIPOMER® Product Performance / 31

SIPOMER® Product Performance continued

Internati

% of Solid

Tg (°C)

% Water

Inhibitor ppm

Specific gravity

US (TSCA)

Canada (DSL)

Europe + (EINECS)

Australia (AICS)

SIPOMER® BEM

50**

ND

25

MEHQ/1000

1.06

●

●

●

—

SIPOMER® SEM-25

60***

ND

20

MEHQ/600

1.07

●

●

●

—

SIPOMER® HPM 100

50

ND

50

MEHQ/1000

1.06

●

●

●

●

SIPOMER® HPM 200

50

ND

50

MEHQ/1000

1.06

●

●

●

●

SIPOMER® HPM 400

50

ND

50

MEHQ/1000

1.06

●

●

●

—

10

none

1.15

●

●

●

—

Trade name Rheology

Wet Adhesion

SIPOMER® WAM

90 50***

87

30

HQ/1800

1.11

●

●

●

●

SIPOMER® WAM E W50

50

ND

50

TEMPO 250 and HQ 750 ppm

1.100

●

—

—

●

+ Availability is based on REACH status

* * ** *** ****

SIPOMER® WAM II

ND – not determined

Asia - Latin America - MEA Remainder consists of acrylic acid (~20%) and higher adducts (~50%) SIPOMER® BEM contains ~25% methacrylic acid SIPOMER® SEM-25 contains ~20% methacrylic acid SIPOMER® WAM II-25 contains ~25% methacrylic acid

Recommended product formulations >SIPOMER® COPS-1

>SIPOMER® PAM-100

>SIPOMER® PAM-200 >SIPOMER® WAM

>SIPOMER® WAM-II


nal Inventory Status South Korea (KECL)

Japan China Philippines (MIT) (JECSC) (PICCS)

New Zealand (NZIoC)


●

—

●

●

●

Specialty monomer design for low shear HASE polymer

—

—

●

—

●

Specialty monomer design for mid to high shear HASE polymer

●

—

Specialty monomer design for mid shear HASE polymer

—

●

Specialty monomer design for newtonian HASE polymer

●

—

Specialty monomer design for low to mid shear HASE polymer

—

—

—

—

●


●

●

●

●

●


—

●

●

—

●


International Inventory Status Codes ● Listed

— Not Listed

For technical data sheets and other products, visit our website: www.solvay.com

SIPOMER® Product Performance / 33

The way we do business Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reects our commitment to each of our stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere. Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self—assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and p artnership.

> Responsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987) > The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, Working Conditions, Respect for the environment and anti—corruption. (2003) > The International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005) > Solvay Novecare has achieved world—wide ISO—9001 Quality Management System Multi—Site Certication. (2008)

North America Solvay Novecare—504 Carnegie Center Drive, Princeton, NJ 08540—USA Phone: +1-800-973-7873—Fax: +1-609-860-0463—[email protected] Europe Solvay Novecare—40, rue de la Haie—Coq-F—93306 Aubervilliers Cedex—France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 Asia Pacific Solvay Asia Pacic Pte. Ltd.—438B Alexandra Road—#02—09/12 Alexandra Technopark—Singapore 119968 Phone: +65-6291 1921—Fax: +65—6394 3377

Latin America Solvay Novecare—Centro Empresarial—Avenida Maria Coelho Ag uiar, 215, Bloco B-1º Andar Cep: 05804-902 —São Paulo—SP Brazil Phone: +55 11 3747-7637—Fax: +55 11 3741-8378 www.solvay.com Material Safety Data Sheets (MSDS) are available by emailing us or contacting your sales representative. Always consult the appropriate MSDS before using any of our products.

t e n . t s a c m o c @ o e l i d a i r a m , n g i s e D c i h p a r G o e L i D — E R A C E V O N Y A V L O S 6 1 0 2

Neither Solvay Specialty Polymers nor any of its aliates makes any warranty, express or implied, including merchantability or tness for use, or accepts any liability in connection with this product, related information or its use. Some applications of which Solvay’s products may be proposed to be used are regulated or restricted by applicable laws and regulations or by national or international standards and in some cases by Solvay’s recommendation, including applications of food/feed, water treatment, medical, pharmaceuticals, and personal care. Only products designated as part of the Solviva® family of biomaterials may be considered as candidates for use in implantable medical devices. The user alone must nally determine suitability of any information or products for any contemplated use in compliance with applicable law, the manner of use and whether any patents are infringed. The information and the products are for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance o r any other process. This is not a license under any patent or other proprietary right.

H C R A M

All trademarks and registered trademarks are property of the companies that comprise the Solvay Group or their respective owners. © 2012 Solvay Specialty Polymers USA, LLC. All rights reserved.

A N

Rhodoline® 4188 Specialty Additive for Improved Color Stability

Color Solutions Applications

Key features

wFlat to high gloss architectural paints

wImproved wetting of pigments

wPigment slurries

wImproved color

wGrind or letdown

wBetter general dispersion stability

wExcellent co-dispersant

wImproved resistance to color floating

wStabilizing agents

wEnhanced gloss

wWetting agents

wExcellent wetting

acceptance/development

wImproved adhesion

Committed to your Coatings Success

wBetter corrosion inhibition wImproved water resistance wNo impact on other paint properties

Control

Rhodoline® 4188

Semi-Gloss Acrylic Paint Formulation

North America Phone: + 1-800-973-7873

Europe, Middle East, Africa Phone: +33 01 53 56 50 00

Asia Pacific Phone: +65 62 91 19 21

Latin America Phone: +55 11 3747-7637

www.solvay.com www.solvay.com

Color Solutions Rhodoline® 3000/4000 Series Dispersants for Pigment Concentrates

The Solvay Group is committed in sustainably recreating the chemical industry, focusing on innovation and operational excellence

INNOVATIVE SOLUTIONS FOR AN INCREASINGLY DEMANDING MARKET Solvay, a world leader in the development and production of specialty chemicals, supplies performance additives for a variety of paint and coatings pplications. To meet market demands, Solvay’s global technical support network provides customers with custom-made solutions, and develops formulations adapted to their needs and requirements for the paint and coatings industry. These are surface-active solutions and functional monomers for the production of polymers in emulsion, meeting performance and sustainability requirements, such as zero VOC, biodegradability and low ecotoxicity. Solvay coatings also provides paint additives solutions, providing benefits in formulation and application. Solvay shares its best practices throughout its world-class manufacturing operations in North America, Latin America, Europe and the Asia Pacific region and benefits from technology transfer to create innovative materials focused on next-generation technologies for the paint and coatings market.

DISPERSANT MECHANISM Wetting: Liquid that replaces air on the surface of the pigment

particle by reducing the interfacial tension Dispersant: Product that maintains fine solid particles in a

Electrostatic Stabilisation

suspended state and inhibits aggregation or sedimentation in a liquid medium Stabilization: Prevents re-agglomeration by electrostatic and/or

steric repulsion Steric Stabilisation

PIGMENT STABILIZATION Challenges:

• Maintain storage stability of pigment concentrates over longer time periods • Compatibility of these pigment concentrates with different coating systems after enduring longer storage time • Color acceptance/development in tinted systems Performance:

• Anchoring of dispersant over the pigment’s surface - Improved compatibility - Improved color acceptance - Preventing flocculation and sedimentation

Pigment Properties: Inorganic vs. Organic Property

Inorganic

Organic

Solubility

Generally insoluble

Slightly soluble

Tint strength

Low

High

Hiding power

High, opaque

Low, more transparent

Fairly easy to disperse

Difficult

Specific gravity

High

Low

Heat resistance

High

Low

Excellent

Poor

Low

High

Ease of dispersion

Weathering Brightness (Intensity)

The Rhodoline 3000 and Rhodoline 4000 lines are high efficiency dispersants for water-based pigments concentrates, without VOCs and alkylphenols. ®

®

RHODOLINE 3000 SERIES ®

Product

Active %

HLB

Recommendation

Rhodoline® 3100

85

11 - 13

Rhodoline® 3200

90

8 - 11

Rhodoline® 3500

70

> 16

Dosage

Workhorse dispersant for low to medium HLB organic pigments including medium grade carbon black and lampblack pigments. Dispersant for low HLB organic pigment including toluidine red, 5 - 30% yellow and other organic pigments. of the pigment High HLB organic pigment wetting and dispersant agent. weight. Works great with organic pigments as well as industrial grade carbon black pigments.

Rhodoline® 3700

97

High HLB pigment wetting and dispersant agent. Works great with high surface area pigments such as conductive carbon blacks.

-

RHODOLINE 4000 SERIES ®

Product

Ion Nature

Active %

Recommendation

Dosage

Rhodoline® 4100

Anionic

100

Used in low/zero VOC colorants; best for inorganic and organic pigments that require mid HLB range wetting agents.

Rhodoline® 4160

Anionic (ammonium salt)

25


Rhodoline® 4170

Anionic (potassium salt)

25


Rhodoline® 4188

Anionic (ammonium salt)

87


0.1 - 0.5% (active) as paint wetting agent; 1 - 2% (active) as pigment wetting; 5 - 20% (active) based on total pigment weight as dispersant for concentrates.

% of additive on the

Colour Index

Rhodoline®

PR 112

3100

8 - 15%

PY 74

3100

11 - 15%

PBK 7

3500

15 - 30%

Improved stability

PB 15:0

3500

15 - 20%

APE and VOC free

PB 15:1

3500

20 - 30%

PG 7

3500

15 - 25%

PO 5

3500

8 - 15%

ATTRIBUTES High performance with less dispersant

pigment total

Exceptional color strength development Exceptional color acceptance upon tinting

The way we do business Solvay puts into practice a sustainable development policy called Solvay Way because we are convinced our future is dependent upon the responsible way in which we conduct our current activities — a way that reects our commitment to

each of our stakeholders. Solvay Way encompasses three interlinked, equally important spheres: the Environment Sphere, the People Sphere and the Economic Sphere. Based on a framework of responsibilities, Solvay Way allows Solvay sites and businesses to conduct self-assessments of their practices and establish action plans that promote continuous progress. At Solvay, the way we do business creates sustainable value for all our stakeholders through innovation and partnership. > Responsible Care is the chemical industry’s voluntary continuous improvement initiative to promote safe handling of products. (1987) > The UN’s Global Compact aims to ensure that heads of companies promote and uphold 10 universal principles concerning human rights, working conditions, respect for the environment and anti-corruption. (2003) > The International Federation of Chemical, Energy, Mine and General Workers’ Unions. (2005) > Solvay Novecare has achieved world wide ISO-9001 Quality Management System Multi-Site Certifcation. (2008)

North America

Solvay Novecare – 504 Carnegie Center – Princeton, NJ 08540 – USA Phone: +1-800-973-7873 – Fax: +1-609-860-0463 – [email protected] Europe

Solvay Novecare – 40, rue de la Haie-Coq – F-93306 Aubervilliers Cedex – France Phone: +33 (0) 1 53 56 50 00 – Fax: +33 (0) 1 53 56 53 90 – [email protected] Asia Pacific

Solvay Novecare – 1, Biopolis Drive – #05-01/06 AMNIOS – Singapore 138 622 Phone: +65 - 6291 1921 – Fax: +65 - 6394 3376 – [email protected] Latin America

Solvay Novecare – Centro Empresarial – Avenida Maria Coelho Aguiar, 215, Bloco B-1º Andar Cep: 05804-902 – São Paulo-SP Brazil Phone: +55 11 3747-7637 – Fax: +55 11 3741-8378 – [email protected] www.solvay.com While the information herein is believed to be reliable, we do not guarantee its accuracy. Customers (direct and indirect) are urged to make their own tests with products described herein. Various patents owned by Solvay or others may be pertinent to their use and to compositions containing them. Nothing contained herein is intended as a recommendation to use our products so as to infringe any patent. We assume no liability for any intellectual property rights violation by customers (direct or indirect). Customers (direct and indirect) should make their own patent investigation related to the freedom to operate for any specific intended use. If a relevant patent is identified, customers (direct and indirect) should secure a license from the patent owner. Customers (direct and indirect) should evaluate the products to determine notably their strength, performance and safety. All applicable laws and regulations should be consulted. All the names mentioned are registered trademarks of Solvay, its subsidiaries or affiliates.

®

AEROSOL Surfactants

Specialty Additives

AEROSOL® Surfactants

Biodegradability

Flash Point °F/°C (Pensky Martens Closed Cup)

Solubility (as is) AEROSOL Surfactants

Type & Form (approx. conc.)

Chemical Name

Water @ 25°C g (as is) /100ml

Organic Solvent

Diester Sulfosuccinates

* ** ***

TR-70

Sodium bistridecyl sulfosuccinate

Anionic 70% solution in ethanol and water

0.1

Very Soluble

Not readily Biodegradable2

77 / 25

TR-70 HG


Anionic 70% solution in hexylene glycol and water

0.1

Very Soluble


>212 / >100

TR-60 I


Anionic 60% solution in isopropanol and water

0.1

Very Soluble


91 / 33

OT-75

Sodium dioctyl sulfosuccinate


2.0

Very Soluble

Readily Biodegradable1

85 / 29

OT-75 E OPV



2.0

Very Soluble


85 / 29

GPG



2.2

Very Soluble


81 / 27

OT-70 PG


Anionic 70% solution in propylene glycol and water

2.2

Very Soluble


>212 / >100

OT-70 PG OPV



2.2

Very Soluble


>212 / >100

OT-75 PG



2.0

Very Soluble

Readily Biodegradable#

>212 / >100

OT-100


Anionic 100% waxy solid

1.5

Very Soluble


Not Applicable

OT-B


Anionic 85% powder in 15% sodium benzoate

1.0

Partially Soluble


Not Applicable

OT-A (ND)


Anionic 70% solution in Solvesso 150****

—

Very Soluble


158 / 70

OT-S


Anionic 70% solution in light petroleum distillate

—

Very Soluble


131 / 55

OT-SE ULA


Anionic 70% solution in light petroleum distillate

—

Very Soluble


169 / 76

OT-85 AE

Proprietary sulfosuccinate blend

Anionic 85% solution in water

2.0

Very Soluble


>212 / >100

AEROSOL 22N is the European version of this product KRUSS -K12 Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300

**** Aromatic Solvent from Exxon Methods for assessment of biodegradation: 1: 301A DOC (dissolved organic carbon) die-away test 2: 301B Modified Sturm test

3: 301D Closed Bottle test 4: 301E Modified OECD screening 5: 302B: Zahn Wellens Inherent #: Based on evaluation of components

Surface Tension in Water (min. mN/m)**

Ca Tolerance ppm CaCO3 at 0.5%

CMC %/wt**

27

<60***

0.001

Extremely hydrophobic surfactant with excellent solubility in organic media, as well as very low critical micelle concentration and equilibrium surface tension. High oil solubility and limited water solubility. Imparts some surface water resistance in coatings and films.

27

<60***

0.001

High flash point analogue of AEROSOL TR-70 in hexylene glycol and water. Same features and benefits as AEROSOL TR-70.

27

<60***

0.001

General purpose grade of AEROSOL TR-70, commonly used in ePVC polymerizations.

Features & Benefits

26

540

0.12

Excellent wetting, rewetting and levelling agent. Also good emulsifying and dispersing properties. Has very low dynamic surface tension, and migrates to interfaces very rapidly. Used to reduce surface tension and to increase absorbency and penetration. AEROSOL OT also has some antistatic and softening properties.

26

540

0.12

Low DEHM (Diethylhexyl maleate) content specifically for over print varnish (OPV) applications.

26

540

0.12

General purpose grade of AEROSOL OT.

26

540

0.12

High flash point analogue of AEROSOL OT-75 in propylene glycol and water. Same features and benefits as AEROSOL OT-75.

26

540

0.12

Low DEHM (Diethylhexyl maleate) content specifically for OPV applications.

26

540

0.12

Higher solids version of AEROSOL OT-70 PG.

26

540

0.12

Solid version of AEROSOL OT. For use when no water can be tolerated. Same features and benefits as AEROSOL OT-75.

26

540

0.12

Powder version of AEROSOL OT that is easier to handle than the AEROSOL OT-100.

28

540

0.12

Solution of AEROSOL OT in an aromatic solvent. Same features and benefits as AEROSOL OT-75. Suitable for organic, oil based systems that can not tolerate water. Used in Agrochemical formulations.

26

540

0.12

Solution of AEROSOL OT in high purity petroleum distillate. Superior detergent for oily stains. Used in organic, oil based systems. Higher flash point grade used in oil spill dispersants.

26

540

0.12

Solution of AEROSOL OT in high purity petroleum distillate. Superior detergent for oily stains. Used in organic, oil based systems. Higher flash point grade used in oil spill dispersants. Food grade product approved for paper chemicals.

29

>2250

0.02

Low VOC and high solids version of AEROSOL OT. Same features and benefits as AEROSOL OT-75. Allows a lower coalescing agent requirement in formulations.

N.B. Not all products may be offered for sale in all regions. Please check with your local Sales Manager. N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe.

AEROSOL® Surfactants Solubility (as is) AEROSOL Surfactants


Chemical Name


Organic Solvent

Flash Point °F/°C Biodegradability

(Pensky Martens Closed Cup)

Diester Sulfosuccinates (continued)

OT-NV


Anionic Anion ic 85% 85% solution solution in water

2.5

Very Soluble


>212 / >100

LF-4


Anionic 80% Anionic 80% solution solution in isopropanol and water

10

Soluble


110 / 43

WA-300


Anionic Anion ic 75% 75% solution solution in propylene glycol and water

2.5

Soluble


>212 / >100

MA-80

Sodium dihexyl sulfosuccinate

Anionic 80% Anionic 80% solution solution in ethanol and water

34

Soluble


97 / 36

MA-80 I

Sodium dihexyl sulfosuccinate

Anionic 80% Anionic 80% solution solution in isopropanol and water

34

Soluble


101 / 38

A-196 40

Sodium dicyclohexyl sulfosuccinate


25

Soluble warm


>212 / >100

A-196 97

Sodium dicyclohexyl sulfosuccinate

Anionic 97% Anionic 97% flaky solid

10

Soluble warm


Not Applicable

AY-65

Sodium diamyl sulfosuccinate

Anionic 65% Anionic 65% solution solution in ethanol and water

62

Insoluble


77 / 25

AY-100

Sodium diamyl sulfosuccinate

Anionic 100% Anionic 100% waxy solid

40

Soluble


Not Applicable

IB-45

Sodium diisobutyl sulfosuccinate


Infinite

Insoluble


>212 / >100

Cationic 70% viscous solution in isopropanol, ethylene glycol and water

Forms Dispersions

Soluble in the presence of alcohol


85 / 29

Alkylamine-Guanidine Ethoxylate

C-61

* ** *** ****

Alkylamine-guanidine polyoxyethanol

AEROSOL 22N is the European version of this product KRUSS -K12 Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300 Aromatic Solvent from Exxon

Methods for assessment of biodegradation: 1: 301A DOC (dissolved organic carbon) die-away test

2: 301B Modified Sturm test 3: 301D Closed Bottle test 4: 301E Modified OECD screening

5: 302B: Zahn Wellens Inherent #: Based on evaluation of components



CMC %/wt**

29

>1000

0.02

Low VOC and high solids version of AEROSOL OT. Same features and benefits as AEROSOL OT-75.

24

>2250

0.02

Wetting, dispersing, levelling, and emulsifying agent specially designed for applications requiring good dynamic wetting with low and unstable foam generation.

24

500***

0.02

Excellent wetting agent designed for use in the production of pressure sensitive adhesives (PSA). Product is functional at low concentrations and has a high flash point.

28

700

1.5

Good dynamic wetting properties with unstable foam generation. Emulsifying, dispersing and solubilizing agent. High electrolyte stability.

28

700

1.5

Good dynamic wetting properties with unstable foam generation. Emulsifying, dispersing and solubilizing agent. High electrolyte stability.

38

>2250

3.0

Imparts high surface tension, high filler loading capacity, good mechanical stability and reduced water sensitivity. Excellent low foaming surfactant. Produces dispersions with excellent electrolytic stability. Liquid at approximately 40°C.

38

>2250

3.0

Flaky solid form of AEROSOL A-196 40 with same features and benefits.

30

>1125

1.8

Wetting and dispersing agent for hydrophilic systems. Imparts good electrolytic and mechanical stability. It has a high tolerance for electrolytes.

30

>1125

1.8

Solid version of AEROSOL AY-65 used in water free systems. Same features and benefits as AEROSOL AY-65.

Features & Benefits

30

>2250

3.5

Very hydrophilic surfactant which is an extremely efficient wetting agent in high concentrations of electrolytes. Imparts good electrolytic and mechanical stability and reasonably high surface tension.

40

>2250

0.05

Combines cationic and non-ionic features. Good wetting, dispersing and flushing agent. Allows anionic systems to be compatible with cationic systems. Excellent acid and alkali stability.


AEROSOL® Surfactants

Biodegradability

Flash Point °F/°C (Pensky Martens Closed Cup)

Solubility (as is) AEROSOL Surfactants


Chemical Name


Organic Solvent

Mono-ester Sulfosuccinates

EF-800

Proprietary sulfosuccinate composition


Infinite

Insoluble

Inherently Biodegradable5

>212 / >100

EF-810



Infinite

Insoluble

Inherently Biodegradable5

>212 / >100

A-102

Disodium ethoxylated alcohol half ester of Sulfosuccinic acid


Infinite

Sparingly soluble in polar solvents


>212 / >100

A-103

Disodium ethoxylated nonyl phenol half ester of Sulfosuccinic acid


Infinite

Partially soluble in polar solvents


>212 / >100

501



Infinite

Insoluble


>212 / >100

Sulfosuccinamates

18P

Disodium N-octadecyl sulfosuccinamate

Anionic 30% semi-paste in water

18 at 40°C

Insoluble


195 / 91

22 / 22N*

Tetra sodium N-(1,2 dicarboxy ethyl)- N-octadecyl sulfosuccinamate

Anionic 35% solution in water with ethanol/ methanol residuals

Infinite

Insoluble

Not readily Biodegradable#

129 / 54 156 / 70

22 Special

Tetra sodium N-(1,2 dicarboxy ethyl)- N-octadec(en)yl sulfosuccinamate


Infinite

Insoluble


129 / 54

Nonyl Phenol Ether Sulfates

NPES-458

Ammonium salt of sulfat sulfated ed nonylphenoxy poly (ethyleneoxy) ethanol


Infinite

Partially soluble

Not readily Biodegradable

NPES-930 P

Ammonium salt of sulfated nonylphenoxy poly (ethyleneoxy) ethanol

Anionic 30% solution in water

Infinite

Insoluble


>212 / >100

Anionic 75% powder in odium sulfate

>20

Partially soluble


Not Applicable

83 / 28

Alkyl Naphthalene Sulfonate

OS

* ** *** ****

Sodium diisopropyl naphthalene sulfonate

AEROSOL 22N is the European version of this product KRUSS -K12 Calcium Tolerance at 0.05% for AEROSOL TR products and 0.25% for AEROSOL WA-300 Aromatic Solvent from Exxon

Methods for assessment of biodegradation: 1: 301A DOC (dissolved organic carbon) die-away test

2: 301B Modified Sturm test 3: 301D Closed Bottle test 4: 301E Modified OECD screening

5: 302B: Zahn Wellens Inherent #: Based on evaluation of components



CMC %/wt**

Features & Benefits

31

>2250

0.03

Versatile, APE free, primary or sole emulsifier enabling easy design of new latexes while meeting regulatory requirements. Can reduce the number of raw material required, simplifying formulations. Also highly effective, functioning at low concentrations. High tolerance for water-sensitive monomers.

0.03

Versatile, APE free primary or sole emulsifier. Highly effective, functions at low concentrations, making it extremely cost effective. The product imparts outstanding pre-emulsion stability, giving robust reaction kinetics, high conversions and minimizes final latex grit and coagulum in emulsion polymerization reactions. High tolerance for water-sensitive monomers.

0.1

Excellent APE free primary emulsifier for acrylic, styrene acrylic, vinyl acrylic and EVA latexes. Imparts both steric and charge stabilization giving systems with very good electrolytic and mechanical stability. Excellent acid stability and low surface and interfacial tension values make it a useful stabilizer/dispersant in a variety of aqueous systems. Good tolerance for cationic surfactants and polyvalent cations. Non-dermatitic.

31

29

>2250

>2250

34

>2250

0.01

Excellent primary emulsifier for acrylic, styrene acrylic and vinyl acrylic latexes especially high gloss systems. Imparts both steric and charge stabilization giving systems with very good electrolytic and mechanical stability. Outstanding compatibility with divalent and trivalent cations as well as quaternary ammonium surfactants. Non-dermatitic.

28

>2250

0.03

Emulsifier for generation of small particle size acrylic latexes. Also dispersing and wetting agent.

40

102

0.06

Emulsifying, dispersing, and foaming agent exhibiting good stability in acid and alkali solutions. Also has excellent lubricating properties.

36

200

0.04

Surfactant combining high hydrophilic and hydrophobic moieties with excellent acid and alkali compatibility. Emulsifier, dispersant and hydrotrope solubilizer. Non-dermatitic.

36

200

0.04

Same as for AEROSOL 22 but can have some additional grafting properties.

30

>2250

0.02

High foaming surfactant, also used as an emulsifier.

31

>2250

0.02

Emulsifier which is effective at low usage levels.

35

>2250

1.0

Stable wetting and dispersing agent in relatively high concentrations of acid or alkali. Highly effective in the manufacture of wettable powders.


Commercial Uses AEROSOL Surfactants

Emulsion Polymer Applications

Other Applications

Diester Sulfosuccinates

TR-70

TR-70 HG

Used as an emulsifier in acrylic, styrene acrylic and vinyl systems. In vinyl systems it modifies surface active properties which can make the finished film water resistant. It has an excellent synergy with primary emulsifiers to generate and stabilize fine latex dispersions as well as improving preemulsion stability in all acrylic and styrene acrylic systems.

Highly hydrophobic wetting agent. Dispersing agent for resins, pigments, polymers and dyes in organic systems. Particularly effective in flushing pigments from aqueous press cakes to solvent media. Used for the preparation of printing inks, rust inhibitors and anti-misting coatings. Dispersing dyes and pigments into plastics.

TR-60 I

A version of AEROSOL TR designed specifically for VCM polymerization. Due to its hydrophobic nature it stabilizes the VCM droplet very well. Offering the opportunity to generate bimodal and high solid latexes by allowing secondary nucleation. Polymer can be easily recovered.

OT-75

Used in a wide variety of emulsion and suspension polymerizations as a primary or co-emulsifier. It can produce latexes with low levels of coagulum, very low particle size and narrow distribution. As a post additive it lowers surface tension, improving flow and levelling characteristics.

Wetting and levelling agent for a wide range of industries: inks and OPVs, paint, adhesives, textile, paper, petroleum, rubber, metal, agricultural, mining, detergent compounding. Additionally used as dewatering aid and mould-release agent.

OT-75 E OPV

–

Specifically for OPV applications, ultra low levels of diethyl hexyl maleate (DEHM).

–

Used by a variety of industries as a wetting agent, e.g. in fire fighting foams, dust control, lubricants and coolants, degreasing, dry cleaning, cleaning solutions for glass etc.

GPG

OT-70 PG

OT-70 PG OPV

OT-75 PG

A high flash point version of AEROSOL OT

–

A high flash point version of AEROSOL OT

–

Same uses as for AEROSOL OT-75 but when a higher flash point is required. Compatible in paint formulations. Used in oil spill dispersants. Specifically for OPV applications, ultra low levels of diethyl hexyl maleate (DEHM). Same uses as for AEROSOL OT-75 but when a higher flash point is required. Compatible in paint formulations. Used in oil spill dispersants.

OT-100

–

Used in solvent and non-aqueous systems. Mould release for poly methyl methacrylate (PMMA). Used in inks, photographic products, dyes, textile, leather, scintillation fluid, agrochemical applications and fibre production. Wetting agent and antistat for polyethylene manufacture. Dispersing aid for dyes and pigments in plastics such as polyethylene and polypropylene.

OT-B

–

Used in agrochemicals for wettable powders and water dispersible granules.

N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe

AEROSOL Surfactants


Other Applications

Diester Sulfosuccinates (continued)

OT-A (ND)

–

Used in agrochemical formulations, where it wets out active ingredients aiding their spread on to and penetration of the plant structure.

–

Very compatible and effective as a wetting/solubilizing/ dispersing agent in a wide variety of organic/hydrocarbon/ oilbased systems. Designed for instant solubility in all organic systems, such as rust inhibitors, degreasers, lubricants, dry cleaning solvents, pre-wash spot removers. Also used as a wetting and dispersing agent in plastics, lacquers and varnishes. Used in oil spill dispersants. Wetting and antistat agent for polyethylene manufacture.

OT-S

OT-SE

OT-85 AE OT-NV

LF-4

WA-300

MA-80 MA-80 I

A-196 40

A-196 97

AY-65 AY-100

IB-45

Primary or co-emulsifier for a wide variety of latex types for effective small particle generation at low usage levels.

Used in low VOC systems as a wetting agent, emulsifier and dispersant. Low surface tension and rapid dynamic wetting for a range of applications including printing inks, OPVs, paint, coatings, textiles and all types of cleaning formulations.

Co-emulsifier to enhance wetting properties of a dispersion with limited foam generation. Produces low surface tension latexes for adhesives, paints, floor polishes, printing inks, etc. Reduces or eliminates the need for post-addition of wetting agents to latexes.

Post addition wetting agent for OPVs, printing inks, paints, textile, paper, adhesives and coating applications. Gives excellent wetting and low foam. Also gives improved adhesion, gloss and color resolution.

Co-emulsifier providing enhanced stability and wetting properties of latex. Also reduces the need for non-ionic cosurfactants.

Post addition wetting and levelling agent for PSA applications.

Effective in all monomer systems. Yields complete conversion, coagulum-free latexes with good mechanical stability. Imparts good adhesion on porous substrates. Polymer can be easily recovered. Also reduces the need for non-ionic co-surfactants.

Wetting agent for OPVs, PSAs, paints, inks, textiles, battery separators, strong electrolyte solutions, electroplating, leaching operations, etc.

Emulsifier for modified styrene-butadiene and styrene-acrylic latexes. Unsurpassed for manufacturing styrene butadiene latexes. Imparts excellent water resistance and adhesion. Produces high surface tension latexes with good mechanical stability and high filler loading capacity. Imparts good adhesion of deposited film to its substrate.

Excellent low foaming surfactant. Produces dispersions with excellent electrolytic stability.

Surfactant for emulsion polymerization systems, especially where polymer recovery is desirable.

Extremely effective wetting agent in concentrated salt solutions. Used in electroplating as a wetting and dispersing agent. Additive for agricultural chemical applications. Effective dispersant for hydrophilic resins and pigments. Very effective wetting agent for leather coatings.

Used in emulsion polymerization and stabilization of styrene, styrene butadiene and other styrene based systems. Imparts high surface tension and good mechanical stability to latexes.

Extremely stable in concentrated electrolyte solutions for leaching, wetting, electroplating and dispersion applications. Highly hydrophilic surfactant.

Commercial Uses AEROSOL Surfactants


Other Applications

Alkylamine-Guanidine Ethoxylate

C-61

–

Cationic dispersing and fixing agent for pigments, dyes and fillers. Emulsifying agent used alone or with AEROSOL OT. Used in the manufacturing of glass fiber matting. Softening agent for textiles. Used in acid or alkali cleaning formulations.


EF-800

APE free primary or sole emulsifier for acrylic, vinyl acryli c, styrene acrylic and styrene butadiene latex systems. High tolerance for water-sensitive monomers facilitates easy development of high performance systems. Yields high solids/low viscosity latexes, enabling solids > 60% in final latexes. Yields excellent mechanical, electrolytic and freeze/ thaw stability, low coagulum and grit, hence increasing operational efficiencies. Produces latex films with high optical clarity and excellent heat stability.

APE free surfactant for variety of industries providing excellent emulsification, low surface tension and good stability.

EF-810

APE free primary or sole emulsifier for acrylic, vinyl acryli c, styrene acrylic and styrene butadiene latex systems. High tolerance for water-sensitive monomers facilitates easy development of high performance systems. Yields high solids/low viscosity latexes, enabling solids >60% in final latexes. Excellent pre-emulsion stability giving increased manufacturing flexibility. Also produces latexes with excellent mechanical, electrolytic and freeze/thaw stability, low coagulum and grit hence increasing operational efficiencies. Produces latex films with high optical clarity and excellent heat stability.

APE free surfactant for variety of industries providing excellent emulsification, low surface tension and good stability.

A-102

APE free primary emulsifier for acrylic, vinyl acryl ic, styrene acrylic and EVA latexes. Can be used with N-methylolacrylamide without modifying performance requirements. Generates small to intermediate particle size emulsions, effective as a post stabilizer. Provides good adhesion in combination with AEROSOL MA-80 and 22. Gives low-coagulum levels, clear film formation and resistance to yellowing on heating. Films also have good water resistance.

Surfactant or foaming agent for personal care and cleaning applications, suitable for use in shampoos, bath and shower gels as well as germicidal cleaners. Additionally used in foaming cement, wallboard and adhesives. Also a good solubilizer and dispersant for medium HLB resin systems and other aqueous systems.

A-103

Used in emulsion polymerization as either the sole or primary emulsifier for the preparation of high gloss vinyl acetate and acrylic latexes. Produces small particle size emulsions with good film clarity as well as mechanical stability. Can be used with AEROSOL’s 22, MA-80 and A-102 to modify particle size. Gives good water resistance of the latex film and is resistant to yellowing on heating. Effective as a post-additive stabilizer.

Surfactant or foaming agent for personal care and cleaning applications, suitable for use in shampoos, bath and shower gels as well as germicidal cleaners. Additionally used in foaming cement, wallboard and adhesives. Also a good solubilizer and dispersant for medium HLB resin systems.

Used in emulsion polymerization of acrylic systems especially at low surfactant concentrations. High tolerance for water soluble monomers. Yields high solids/low viscosity latexes with freeze/thaw stability, mechanical stability and high optical clarity.

Provides low surface tension and good stability in printing ink, textile and paper applications. Used in the production of fire fighting foams.

501

N.B. The E suffix on paperwork such as Labels and MSDSs denotes material produced in Europe

AEROSOL Surfactants


Other Applications

Sulfosuccinamates

18P

Imparts excellent rheological properties to pigmented latexes. Used in emulsion and suspension polymerizations. Foaming agent for latexes especially in carpet backing and textile applications.

Used as a foaming agent in foamed insulation, carpet backing, cement, wallboard and resins. Excellent stability in acid and alkali solutions, therefore also used in cleaning formulations and lubricants.

22/22N

Imparts small particle size for all latexes except vinyl acetate. In combination with AEROSOL’s MA-80 or A-102 produces highly stable high solids latexes. Excellent as a post-additive for mechanical stabilization, especially in paint applications giving high water resistance. Imparts excellent rheological properties in pigmented latexes.

Excellent pigment dispersant. Used in agrochemical formulations, industrial, household and metal cleaners. Excellent solubilizing agent for soaps and other surfactants in soluble salt solutions. Excellent lime soap dispersant.

22 Special

Same as for AEROSOL 22 but can have some additional grafting properties.

–


NPES-458

Emulsion polymerization of vinyl acetate, acrylic and styrene acrylic systems giving very small particle size emulsions.

Used in textile scouring agents and detergents. Also used in iodine based germicidal cleaners.

NPES-930 P

Produces very fine particle size vinyl acetate, acrylic and styrene acrylic latexes with low levels of coagulum and good mechanical stability. Latexes also have good freeze/thaw stability. Superior emulsifier for Zn cross-linking latexes for floor finishes. Extremely low surfactant levels needed that result in superior water resistance and high optical clarity.

Used in detergents and rosin dispersions.

Alkyl Naphthalene Sulfonate

OS

Surfactant for emulsion polymerization and additive for latexes.

Dispersant for pigments and dyes in paints and plastics. Used in agrochemical wettable and dispersible powders. Used in metal cleaning, bottle washing, paint strippers, brick and tile cleaning, pickling, acid etching agents and hard surface cleaners due to its excellent acid and alkali stability.

Cytec Solvay Group 5 Garret Mountain Plaza Woodland Park, NJ 07424 [email protected] Tel: +1.973.357.3100 Fax: +1.973.357.3100

www.cytec.com

Disclaimer: Cytec Industries Inc. in its own name and on behalf of its affiliated companies (collectively, “Cytec”) decline any liability with respect to the use made by anyone of the information contained herein. The information contained herein represents Cytec’s best knowledge thereon without constituting any express or implied guarantee or warranty of any kind (including, but not limited to, regarding the accuracy, the completeness or relevance of the data set out herein). Nothing contained herein shall be construed as conferring any license or right under any patent or other intellectual property rights of Cytec or of any third party. The information relating to the products is given for information purposes only. No guarantee or warranty is provided that the product and/or information is adapted for any specific use, performance or result and that product and/or information do not infringe any Cytec and/or third party intellectual property rights. The user should perform its own tests to determine the suitability for a particular purpose. The final choice of use of a product and/or information as well as the investigation of any possible violation of intellectual property rights of Cytec and/ or third parties remains the sole responsibility of the user. All trademarks are the property of their respective owners. © 2015 Cytec Industries Inc. The ® indicates a Registered Trademark in the United States and the ™ indicates a trademark in the United States. The mark may also be registered, subject of an application for registration, or a trademark in other countries.

®

AEROSOL Surfactant Selection Guide

Specialty Additives

AEROSOL® Surfactants Diester Sulfosuccinates

O T -7 5 ( E )

O T -7 0 / 7 5 P G

Acrylics

E

Styrene & Styrene / Acrylics

Applications

T R -7 0

Polymer

T R -7 0 H G

T R 6 0 I

O T -A ( N D )

O T 8 5 A E

O T -N V

L F -4

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E E

E

D

D

D

D

W

W

G P G

O T -1 0 0

O T -B

O T S ( E )

Emulsion Polymerization

Styrene / Butadiene Styrene / Acrylonitrile Vinyl Acetate & Vinyl Acetate / Acrylics Vinyl Chloride & Vinylidene Chlorides (micro)Suspension Polymerization

E

E

E

E

E

E

E

D

D

D

D

D

D

D

D

W

W

W

W

E

Latex Post Stabilization Foaming Rubber or Plastic Pigment & Color Dispersing Polymer Processing Aids

D

D

D

W

Coatings & Inks Pigments Dispersing & Wetting

D

D

D

D

D

D

Color / Tint Development

W

W

W

W

W

W

Paint & Coating Formulation

X

X

X

X

D

X

X

X

Printing Ink Formulation

X

X

X

X

D

X

X

X

OPV

W

W

W

W

W

W

W

PSA

W

W

W

W

W

W

W

Sealant

W

W

W

W

W

W

W

W

W

W

W

W

W

W

W

W

W

X

X

X

X

S

S

S

S

S

S

S

S

S

S

W

Adhesives

General Adhesives Construction / Building Materials

W

W

W

W W

Textile / Non Woven

D

D

W

W

W

Agrochemical

X

X

X

X

X

Oil Spill Dispersants

S

S

Drilling / Production / Stimulation

S

S

Remedial Cleaning

S

S

W

W

X

Oil Industry

S

Mining, Paper & Pulp Dust Control Dewatering Aids

W W

W

Electronics & Electrical

W

W W

W

W

W

Cleaning Automotive Dry Cleaning Germicidal Glass & Bottle Metal - Etching, Plating

D - Dispersing

W

W

X

X

X

S

D

S

W

W

W

W

W

W

X

E - Emulsification

X

X

X

D

D

W

X

W

F - Foaming

S - Dete (Wetting, Dispersin

The E sufx on paperwork such as Labels and MSDSs denotes material produced in Europe.


W A -3 0 0

M A 8 0 ( I )

A -1 9 6 4 0

A -1 9 6 9 7

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

D

D

E

E

D

D

W

W

A Y 6 5

A Y -1 0 0

I B -4 5

E

Sulfo Succinamates


2 2 S p e c i a l

N P E S 4 5 8

N P E S 9 3 0 P

E F 8 1 0

E F 8 0 0

A -1 0 2

A -1 0 3

5 0 1

1 8 P

2 2 / 2 2 N

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E

E E

E E

E

E

E

D

Others

O S

C 6 1

E

D E

E

E

E

D

E

E F

F

D

D

D

D

D

D

D

D

D

D

D

X

W

D W

D

X

X

X

X

X

D

D

D

W

D

D

D

D

W

W

W W

W

X

W Z

W

W

X

X

X

X

W

X

F

E

E

E

X

Z

Z

Z

E

X

E

D

S

X

D W

F

S

W W W

W

W

W

X

W

W

D

W

W

X

D

D

S

D W

D

W

gency g, Emulsification)

W

W - Wetting

W

D

X

X - Wetting & Emulsification or Dispersing

D

W

D

X

X

D

X

D

Z - Wetting & Foaming

X

Solvay Paint Additives

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