This report presents the economics of large-scale Methanol production from natural gas. The process examined employs combined reforming for syngas generation similarly to the technologies de…Full description
This report presents the economics of large-scale Methanol production from natural gas. The process examined employs combined reforming for syngas generation similarly to the technologies de…Full description
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This report is a project report for engineering economy course at Sultan Qaboos University, the topic of the project to create and analyze a new business, then do some cost estimation consid…Full description
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Ab st rac t Process Economics Program Report Report 261 261 METHANOL TO OLEFINS (November 2007) Ethylene and propylene are by far the two largest volume chemicals produced by the petrochemicals industry. In 2006 about 110 million metric tons of ethylene and 70 million metric tons of propylene were produced worldwide. Global demand for light olefins (ethylene and propylene) is expected to grow at an annual rate of 5% for propylene and 4% for ethylene. Today the majority of light olefins are produced by the petrochemicals industry either from pyrolysis (steam cracking) of naphtha or from fluid catalytic cracking (FCC) of naphtha. The recent dramatic increase in oil prices is reviving a strong interest in the production of light olefins from non-petroleum source among which low-cost methanol may play a significant role. Because of the wide variety of feedstock sources and projected massive new capacity additions in the near future, methanol has promise as an economical, non-petroleum source for the production of light olefins. At present, the technologies for producing light olefins from methanol appear ready for commercialization. In this report, we evaluate one of the most promising new appli cations for low-cost methanol: the catalytic conversion of methanol to light olefins. We develop and present conceptual designs and preliminary economics of the two processes currently available for license—the UOP/Hydro MTO (methanol-to-olefins) technology based on the MTO-100 silicoaluminophosphate synthetic molecular sieve based catalyst, and Lurgi’s MTP (methanol-to-propylene) process based on MTPROP, a proprietary ZSM-5 type of catalyst supplied from Süd-Chemie.
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For detailed marketing data and information, the reader is referred to one of the SRI Consulting programs specializing in marketing research. THE CHEMICAL ECONOMICS HANDBOOK Program covers most major chemicals and chemical products produced in the United States and the WORLD PETROCHEMICALS PROGRAM covers major hydrocarbons and their derivatives on a worldwide basis. In addition the SRIC DIRECTORY OF CHEMICAL PRODUCERS services provide detailed lists of chemical producers by company, product, and plant for the United States, Western Europe, Canada, and East Asia, South America and Mexico.
U.S Market Prices for Ethylene ............................................................................. 3-8
3.2
U.S. Market Prices for Propylene .......................................................................... 3-15
3.3
U.S. Polymer-Grade Propylene to Ethylene Production and Price Ratios............ 3-16
3.4
Block Diagram of Methanol-to-Propylene Process ............................................... 3-27
3.5
Block Diagram of Coal-to-Propylene Process....................................................... 3-28
3.6
Schematic the UOP/Hydro MTO Process ............................................................. 3-30
3.7
SChematic of the DMTO Process ......................................................................... 3-31
4.1
Reaction Network from MTO Over SAPO-34........................................................ 4-13
4.2
Methanol to Olefins by the UOP/Hydro Process Flow Diagram ........................................................................................................ D-3
4.3
The UOP/Hydro MTO Process with a DME Recovery Block ................................ 4-30
4.4
Methanol to Olefins by the UOP/Hydro Process Effect of Plant Capacity on Investment Cost ......................................................... 4-36
4.5
Methanol to Olefins by the UOP/Hydro Process Effect of Methanol Price and Plant Capacity of Ethylene Product Value .............. 4-39
4.6
Methanol to Olefins by the UOP/Hydro Process Historical Pre-tax Return on Investment (ROI)...................................................... 4-40
4.7
Methanol to Olefins by the UOP/Hydro Process Production Economics at Historical Ethylene and Propylene Prices .................... 4-41
5.1
Lurgi MTP Process Carbon Product Yields, wt%.................................................. 5-5
5.2
Methanol to Propylene by the Lurgi MTP Process Flow Diagram ........................................................................................................ D-7
5.3
Methanol to Propylene by the Lurgi MTP Process Effect of Plant Capacity on Investment Cost ......................................................... 5-24
5.4
Methanol to Propylene by the Lurgi MTP Process Effect on Methanol Price on Production Cost and Product Value......................... 5-27
Comparative Economics for Production of Propylene Economic Summary .............................................................................................. 2-5
Propylene Supply/Demand Summary for 2006 ..................................................... 3-14
3.7
Yields of Co-Product Propylene from Ethylene Production .................................. 3-18
3.8
Change in Expected Propylene Feedstock Utilization .......................................... 3-20
3.9
Producers of Propylene from Propane by Dehydrogenation ................................ 3-22
3.10
Producers of Propylene from Ethylene/Butylene Metathesis ................................ 3-24
3.11
Historical and Projected World Methanol Capacity, Production and Consumption by Region ........................................................................................ 3-34
3.12
U.S. Prices and Unit Sales Values for Methanol................................................... 3-35
4.2
Methanol to Olefins by the UOP/Hydro Process Design Bases and Assumptions............................................................................ 4-19
4.3
Methanol to Olefins by the UOP/Hydro Process Stream Flows......................................................................................................... 4-20
4.4
Methanol to Olefins by the UOP/Hydro Process Major Equipment ................................................................................................... 4-25
4.5
Methanol to Olefins by the UOP/Hydro Process Utilities Summary................................................................................................... 4-28
4.6
Yields from UOP/Hydro Process MTO Conversion Zone ..................................... 4-31
4.7
Methanol to Olefins by the UOP/Hydro Process Total Capital Investment........................................................................................ 4-34
4.8
Methanol to Olefins by the UOP/Hydro Process Capital Investment by Section ............................................................................... 4-35
4.9
Methanol to Olefins by the UOP/Hydro Process Production Costs ................................................................................................... 4-37
Methanol to Olefins by the UOP/Hydro Process Production Costs ................................................................................................... 4-42
5.1
Methanol to Propylene by the Lurgi MTP Process Design Bases and Assumptions............................................................................ 5-9
5.2
Methanol to Propylene by the Lurgi MTP Process Stream Flow .......................................................................................................... 5-10
5.3
Methanol to Propylene by the Lurgi MTP Process Major Equipment ................................................................................................... 5-15
5.4
Methanol to Propylene by the Lurgi MTP Process Utilities Summary................................................................................................... 5-17
5.5
Methanol to Propylene by the Lurgi MTP Process Total Capital Investment........................................................................................ 5-22
5.6
Methanol to Propylene by the Lurgi MTP Process Capital Investment by Section ............................................................................... 5-23
5.7
Methanol to Propylene by the Lurgi MTP Process Production Costs ................................................................................................... 5-25
A.1
Conversion of Methanol to Olefins Sapo Catalysts and Reaction Conditions Patent Summary.................................................................................................... A-3
A.2
Conversion of Methanol to Olefins Zeolite Catalysts and Reaction Conditions Patent Summary.................................................................................................... A-20
A.3
Conversion of Methanol to Olefins Reactor Design and Operation Patent Summary.................................................................................................... A-25
A.4
Conversion of Methanol to Olefins Product Recovery Patent Summary.................................................................................................... A-34
A.5
Conversion of Methanol to Olefins Other Catalysts/Process Integration Patent Summary.................................................................................................... A-41