lab5-y-6

[LAB.INORGANICA AIII]

PREPARACIÓN, PURIFICACIÓN Y CARACTERIZACIÓN DE 1,1-DIETIL-3-BENZOILTIOUREA

UNIVERSIDAD NACIONAL MAYOR DE SAN MARCOS FACULT FACULTAD AD DE QUÍMICA, INGENIERÍA QUÍMICA E INGENIERÍA AGROINDUSTRIAL ESCUELA ACADÉMICO PROFESIONAL DE QUÍMICA

LAB. 5 y 6 “PREPARACION “PREPARACION PURIFICACION Y CARACTERIZACION DE 1,1DIETIL! BENZOILTIOUREA"  ALUMNOS# 

ZAP ZAPATA FERN FERNAN ANDE DEZ, Z, EUG EUGEN ENIO IO

05 0507 0701 0119 19



Rodri!"# P"$%, &"'d( E)%**

09070079

PROFESOR:  Dr. MARIO CERONI GALLOSO

- LIMA, CIUDAD UNIVERSITARIA, JUNIO 2012 +UN EAP .UIICA

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TABLA DE CONTENIDO O$%&'()*+



D&+-(/-(0 y 2(+-3+(0



1. . !. 9.

P&/44-(0 P3((-4-(0 y -44-'&(4-(0 C47-37* 2&7 &2(8(&'* D(+-3+(0 2& &+37'42*+

   2

C*-73+(*&+



S3:&&-(4+

9

B($7(*:4;4

10

+UN EAP .UIICA

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OB
O4*"'"r !' i%'do, "6*!di%r 6! 6o!4iid%d ( %r%*"ri#%ro8 C%r%*"ri#%r % i%'do or %6 *:'i%6 "6"*ro6;i%68

DESCRIPCI=N Y DISCUSI=N

R&4-'()*+ *"r "*?io Di="*i6!@;ido

M4'&(47&+ Ai*%dor =%':*io oor*" U'i)"r6% N!""6 R"@ri"r%'*" d" 6"r"'*i' B%;' d" do6 4o%6 d" 50=L %6o6 d" 100 ( 0 =L B%!"*% E6/*!% E=4!do B!'"r L!'% d" R"o, roi"*% P%" @i*ro Bo=4% d" )%i;

1. PREPARACI=N# E' " 4%;' 6" ooo 7,2 0,1=o d" &CN ( 6" %r"o 30=L d" %"*o'%8 " i'6"r*o " r"@ri"r%'*", ( 6" i'iio % %i*%i;' %i*%dor =%':*io @i81 ( or % 4o% 6!"rior o' !'% i"*% %diio'%=o6 ,7=L 0,1=o d" or!ro d" 4"'#oio o' 6!=o !id%do8 A @i'% 6" %diio'o 30=L d" %"*o'%8 " =%'*!)o "' r"@!o % 52C d!r%'*"  or%68 " o46"r)o % @or=%i;' d" !' oor o'6*%'*" d" r"ii*%do8 E r"%r%do 6" "'@r?% ( !"o 6" " %r"o o*% % o*% 13 =L 0,15=o d" di"*i%=i'% @i88 D"%=o6 %i*%'do d!r%'*" 30 =i'!*o6 @i8 38 Tr%6)%6%=o6 % ="#% % !' )%6o d" 00 =L H!" o'*"'?% 10=L d"
Fi81


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Fi8 

Fi8 3

Fi8 

@i8 5

Fi8 2


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. PURIFICACI=N Y CARACTERIZACI=N# Pro4%=o6 o' "H!"$%6 %'*id%d"6 d" di@"r"'*"6 6o)"'*"6 o=o "*%'o, T
!. C>LCULO DEL RENDIMIENTO# L% roori;' "6*"H!io=:*ri% @!" d" 11, %r% *odo6 o6 %6o68

O

O

&CN

K

Cl

K

K &C N S

782 9M=o

87=L 10M=o

 123M=o

Co' % i'@or=%i;' d" % d"'6id%d 6" !"d" %!%r % =%6% d" or!ro d" 4"'#oio

Por o *%'*o, " r"%*i)o i=i*%'*" " "6 &CN, or o H!" 6" !"d" o4*"'"r, % =%6% d" rod!*o8


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L!"o

O

S

K

HN

N

CH3

S

1807 123M=o

NH

CH3

N C

?

982=L  = 287 73M=o

07M=o

E r"%*i)o i=i*%'*" d" % r"%i;' "6 C <5 NO, @i'%="'*" 6" o4*i"'" " "6o *";rio d" % r"%i;'8 18078 123M=o8807M=o   1583 *";ri% 

D4'*+ &@/&(8&'47&+#  /*23-'*  1385


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9. DISCUSI=N DE RESULTADOS L% r"%i;' H!?=i% "6 SH O

+

K

N

S

-

O

+

+

H3C

N H

Cl

PCO-C K <CN K < NC<5

CH3

A 7 " *o ' % E r " @ 5! Do F

H3C

N

H3C

N

H

P-CO-N-N-C-NC<5

D" %!"rdo o' % r/@i% d" "6"*ro6oi% IR, " i%'do r"6"'*% o6iio'"6 4%'d%6 4i"' d"@i'id%6, d" %6 4%'d%6 d" %46ori;' d" =%(or i'*"r:6 6"J' " 6i!i"'*" !%dro

N -81 30

CO -81 120 1253 1595

B424+ 2& 4$+*-(0 2& 74 '(*3&4 I II III IV 159 130 12 97 1577 135 2

CS -81 117

L%6 4%'d%6 "'*r" 30-310 = -1 orr"6o'd"' % r!o N<8 L%6 4%'d%6 o=r"'did%6 "'*r" 1291-1579 = -1 "r*"'""' % %6 )i4r%io'"6 d" r!o CO8 E r!o C 6" !4i% "'*r" 11971111 =-18 L%6 o6iio'"6 d" % 4%'d% I !4i%d% "'*r" 157-13 = -1 "6 %6i'%d% % % *io!r"% o' o'*ri4!i;' C-N ( C-<8 i"'*r%6 H!" %6 4%'d%6 II ( III "'*r" 1323 ( 107 = -1 6o' %6i'%d%6 % %6 *io!r"%6 C, C-N ( C-<8 L% 4%'d% I or o "'"r% 6o' do6 6o' %6i'%d%6 % %6 o'*ri4!io'"6 C ( C-N ( %6 !%"6 6" !"d"' !4i%r "'*r" 1109-00 = -1

•

AN>LISIS ELMENTAL


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E %'/i6i6 ""="'*% d" i%'do "6 6"J' " 6i!i"'*" !%dro

E7&8&'*

•

 T&0(-*

C%r4o'o C

2180Q

285Q

Ni*r;"'o6 N

11893Q

A6!@r" 

13832Q

To*%

100Q

PUNTO DE FUSI=N A %"r " %'/i6i6 d" !'*o d" @!6i;' d" i%'do 6" d"*"r=i'o H!" 6" "'!"'*r% "' " r%'o d" 99-101C8


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CONCLUSIONES

L% d"*"r=i'%i;' d" !'*o d" @!6i;' 'o6 i'di% % !r"#% d" '!"6*ro rod!*o, "6 d"ir, 6i % d"*"r=i'%r " !'*o d" @!6i;' d" '!"6*ro rod!*o "6*" r"6!*o "6*%r =!( %"%do d" 6! )%or *";rio, "'*o'"6 od"=o6 6!o'"r H!" " i%'do o'*i"'" i"r*%6 i=!r"#%6 %6 !%"6 =odi@i%' 6!6 roi"d%d"68 D!r%'*" " ro"6o d" @or=%i;' d" i%'do, "6*" 6" !%rdo, 6" d"d!" H!" "6*o 6" r"%i#o %r% =%'*"'"r " o=!"6*o 6i' %*"r%io'"6 (% H!" o6i4"="'*" %J' %=4io i=/*io "' "6"i% " %!="'*o d" % *"="r%*!r% %=4i"'*% !"d" d"6o=o'"ro8 E i%'do o4*"'ido *i"'" @or=% d" ri6*%"6 %%r%do6 !%'do 6" @or=%' ( *i"'" !'*o d" @!6i;' d" 99101 C, d"6!:6 d" 6! !ri@i%i;'8


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SUGERENCIAS

O4*"'"r o6 ri6*%"6 d" i%'do "' @r?o %r% !'% ="or ( r/id% ri6*%i#%i;' d" =i6=o, "6*o 6"r?% d"/'doo r"o6%r "' i"o % 6i 6" %""r%r?% " ro"6o d" r"ii*%i;'8 " r"o=i"'d% !6%r !' r"ii"'*" o6!ro d" 4o% %'% %r% od"r r"*ir%r *o*%="'*" " o="o r"ii*%do " r"o=i"'d% do4%r 4i"' " %" @i*ro "' " "=4!do o' !'% 4%!"*% %r% !'% 4!"'% 6!i;'8 U6%r " "H!io %d"!%do o=o !%'*"6, =%6%r% ( "'*"6 "' %6o d" 6"r '""6%rio (% H!" %( r"%*i)o6 H!" 6o' *;io6 ( orro6i)o68


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BIBLIOGRAFÍA

NTEI DE LIGANDO TIPO N-ACETILTIOUREA Y COPLESO DE COBRE8 AGUILAR GARCIA8Li*%8 UN8 Li=% 1998 P%i'%6 13-8

GUA DE PRCTICA DE LABORATORIO DE .UICA INORGNICA AIII8 F%!*%d d" .!?=i%, I'"'i"r?% .!?=i% " I'"'i"r?% Aroi'd!6*ri%8 D"%r*%="'*o %%d:=io d" .!?=i% I'or/'i%8 "="6*r" 010-I8 P/i'%6 10, 11, 1, 158 P%6o 1

8r"%(68o= !*i=% )i6i*% -05-01 C"d"r Co'diio'"6

R"@"r"'i%6

18 D" %"*o'%, r"@!oV R"'di=i"'*o *&(:, 47&(H 437, L*'4H 3:&, M4';, S-3+'&, M(-4&7 d%do8 D" )%rio6 %6o6 d" r"%i;'V Li"4i6 A''%"' d"r C"=i", 1JK , P/8 1115 - 1112 T?*!o M A46*r%* T"*o Co="*o o6*r%r d"*%"6

& %"*o'%

G34+&44, N4%4//4H 4)&8$3, R484+48y, R48&+, P42(4H P*3+48y, M*2(47(/323 N4%4//4 G*32& D%*o' Tr%'6%io'"6, 11 , o8 0, W 2 /8 1519 % 152 T?*!o M A46*r%* T"*o Co="*o o6*r%r d"*%"6

& %"*o'%

G34+&44, N.H <&0(8*, P.H 4)&8$3, R.H N:, S&( &:H T(&(, E2342* RT Di%rio d" !'% %*/i6i6 =o"!%r H!?=i%, 1 , o8 353-35, P/8 152 % 12 T?*!o M A46*r%* T"*o Co="*o o6*r%r d"*%"6


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lab5-y-6

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