Jotun Paints Presentation

V SHIPS September 26th, 2012

Tank Coating / V Ships / September 26 th, 2012

Owner’s requirement for Chemical Resistance The requirement very much depends on the type of vessel and more so the liquids being carried. Crude Oil Carrier



Crude

Products Carrier



CPP

Chemical/Oil Carrier



CPP & Chemicals & Vegoil

Chemical Carrier



Chemicals & Vegoil

Bunker vessel



(heavy) fuels


Owner’s requirement for Chemical Resistance The requirement very much depends on the type of vessel and more so the liquids being carried. Crude Oil Carrier



Crude

Products Carrier



CPP

Chemical/Oil Carrier



CPP & Chemicals & Vegoil & Vegoil

Chemical Carrier



Chemicals & Vegoil

Bunker vessel



(heavy) fuels


Owner’s requirement for Chemical Resistance The requirement very much depends on the type of vessel and more so the liquids being carried. Crude

epoxy

CPP

pure epoxy

Vegoil

Free Fatty Acids (FFA%)

phenolic epoxy

Chemicals

wide chemical resistance

phenolic epoxy zinc silicate


Owner’s requirement for Chemical Resistance The requirement very much depends on the type of vessel and more so the liquids being carried. Tankguard CPC Tankguard HB

epoxy pure epoxy

Tankguard Special

standard phenolic epoxy

Tankguard Special Ultra Tankguard Zinc

high-end phenolic epoxy zinc silicate


Tankguard Zinc The renew zinc silicate tank coating


BUT BEFORE THAT……….. Single hull vs Double Hull Cargo temperature


BUT BEFORE THAT……….. Single hull vs Double Hull Cargo temperature Cleaning -

How, and where to get the info how to clean – who are the experts hot cleaning water vs cold wall effct organic coating vs inorganic coating absorption vs desorption


BUT BEFORE THAT……….. Single hull vs Double Hull Cargo temperature Cleaning

How, and where to get the info

Paint challenges

Blisters; detachments; pit corrosion

-

too limited time for cleaning / ventilation tank top of COT: Sulphur Reducing Bacteria ageing of coating – deckhead pit corrosion on tank top fast deterioration of zinc silicate




Paint challenges


Training

Riga

(done in the past – November 2010)

- under discussion with Neil Barnes to organise cargo tank coating training for Riga office in the near future




Paint challenges


Training

Riga

Approach of owners

Mondreas; Sonangol; Tri Star; Perosea


Tankguard Zinc The renew zinc silicate tank coating


Upgraded zinc silicate tank coating

Introduction of an upgraded zinc silicate tank coating • Substantially improved resistance to mud cracking Mud-crack Resistance over 200 microns

• Negligible spray dust • Relatively Smooth surface Easier to cleaning in between cargoes Easy inspection of possible spray-dust after application


Tankguard Special Ultra The new top-of the range epoxy phenolic tank coating


Product characteristics Tankguard Special Ultra

%FFA resistance

100%

Methanol resistance

YES

Swelling in aggressive chemicals

Negligible

General chemical resistance

Excellent 5 C

Min. application/cure temperature Post cure

°

3 days at 60 C or 2 days at 70 C or 1 day at 80 C °

°


°

Customers concerns on tank coatings Owners/Managers/Charterers CARGO Flexibility in use Chemical Resistance CLEANING Easy to clean Ventilation


Chemical Resistance Looking at the chemical resistance of the typical cargoes shipped in Tankguard Special Ultra coated tanks: -

Palm Oil Vegoils in general Oleochemicals CPP Chemicals


no limitations no limitations no limitations no limitations closer look required , but widest chemical resistance for a phenolic epoxy or alike in the market

Chemical Resistance Looking at the chemical resistance of the typical cargoes shipped in Tankguard Special Ultra coated tanks: -

Palm Oil Vegoils Oleochemicals CPP Chemicals


no limitations no limitations no limitations no limitations closer look required , but widest chemical resistance for a phenolic epoxy or alike in the market

Chemical Resistance - vegoils Vegoil (derivates) This typical reaction between an alcohol & an acid is called an ester. H2C – O – R | HC – O – R | H2C – O – R With

–R

being

– C – CxHy ||

O


Chemical Resistance - vegoils Vegoil (derivates) Vegetable (and animal) oils are a chemical reaction between fatty acids & glycerine (glycerine is also called glycerol, being an alcohol). H2C – O – R | HC – O – R | H2C – O – R

+ H2O

Fatty acid glycerol ester


water



Chemical Resistance - vegoils Vegoil (derivates) Vegetable (and animal) oils are a chemical reaction between fatty acids & glycerine (glycerine is also called glycerol, being an alcohol). H2C – O – R | HC – O – R | H2C – O – R

+ H2O water



H2C – O – H | HC – O – R | H2C – O – R

+ HO-R free fatty acid

The amount of fatty acids being freed is expressed in a percentage: % FFA free fatty acid


Chemical Resistance - vegoils Vegoil (derivates) Vegetable (and animal) oils are a chemical reaction between fatty acids & glycerine (glycerine is also called glycerol, being an alcohol). Zinc silicate

can handle

1½ ~ 2½ %

Tankguard Zinc

Pure Epoxy

can handle

10 ~ 15 %

Tankguard HB

10 ~ 50 %

Tankguard Special

Phenolic Epoxy High-end Phenolic


100 %

Tankguard Special Ultra

Chemical Resistance – bio-fuels Bio-fuels - Bio fuel - Bio diesel


addition of ethanol addition of FAME

to petrol to diesel

Chemical Resistance – bio-fuels Bio-fuels - Bio fuel

addition of ethanol

to petrol

Resistance to ethanol (may) require(s) a phenolic epoxy esp. for long term performance of the coating system.


Chemical Resistance – bio-fuels Bio-fuels - Bio diesel

addition of FAME

to diesel

The addition of FAME to diesel. This is basically not a challenge, provided that the FFA-% is not too high (but this is probably not allowed within the specifications). Fatty Acid Methyl Ester


Chemical Resistance – bio-fuels Biodiesel The addition of FAME to diesel. This is basically not a challenge, provided that the FFA-% is not too high (but this is probably not allowed within the specifications). H2C – O – R | HC – O – R + 3 HOCH3 | Methanol H2C – O – R



H2C – O – H | HC – O – H | H2C – O – H

+ 3 H3CO-R fatty acid methyl ester

This process is called transesterfication and is predominantly done to lower the viscosity. Tank Coating / V Ships / September 26 th, 2012

Chemical Resistance Often the main deciding factor when selecting a tank coating. Extensive exposure testing has been performed - comparison with bench mark product - wide range of curing conditions including varying post-curing - a long list of chemicals tested - cyclic testing

Adhesion, blisters, discolouration, etc have been evaluated


Product Resistance List The new Product Resistance List is a web based solution. It is possible to download the program to a PC or CD – for use when not connected to the internet. The resistance list is found as a link in Coatings, Products at www.jotun.com and the direct address is www.jotunprl.com


www.jotunprl.com Tank Coating / V Ships / September 26 th, 2012

What's new in the Resistance list? Products: – – – – –

Tankguard Tankguard Tankguard Tankguard Tankguard

Zinc CPC HB Special Special Ultra

Advanced search function with MARPOL, IMO classes or IBC codes


A "basic search" for methanol

Click anywhere on this line…


..and the resistance for all our coatings to methanol is listed The Notes-text appear when pointing at them …



Changed to 6 months

Changed to 5 days






Tailor made advice – SEA based owner


Chemical Resistance required ----- Far East / Arab Gulf & Red Sea Chemicals; CCP; Palm Oil Chemicals CPP Palm Oil

depends on type of chemicals, but would suggest Tankguard Special Ultra Tankguard HB would suffice depending on the pretreatment, resulting in a certain level of FFA, probably Tankguard Special Ultra would be best suggested

Tankguard HB Tankguard Special Ultra Tank Coating / V Ships / September 26 th, 2012

pure epoxy high quality phenolic epoxy

Chemical Resistance required -------------

Far East / Europe Far East / Arab Gulf & Red Sea Straits / Pakistan / India & China

FFAs & Chemicals zinc silicate pure epoxy common phenolic epoxy high end phenolic epoxy


Tankguard Zinc < 2% Tankguard HB < 15% Tankguard Special < 40% Tankguard Special Ultra 100%

Chemical Resistance required -------------

Far East / Europe Far East / Arab Gulf & Red Sea Straits / Pakistan / India & China

FFAs & Chemicals We need to have a closer look at what chemicals are actually shipped, & checked with the Chemical Resistance of Tankguard Special Ultra


Chemical Resistance required Tankguard Special Ultra Acetic Acid

NR

Cyclohexanol

R

Nonyl Alcohol

R

Acetone

R

Cyclohexane

R

Octane ( all isomers )

R

Acid oil mixture

R

Cyclohexanone

R

Olefin Oil

R

Alcohol – various grades

R

Dodecane ( all isomers)

R

Paraffin wax

R

Alkanes

R

Ethylene Glycol

R

Phenol

NR

Alkyl Benzenes

R

Formic Acid

NR

Propylene Glycol

R

Aniline

R

Glycerine

R

Propylene Tetramer

R

Butyl Acetate

R

Hexanol

R

Rapeseed Oil

R

Butyl Acrylate

R

Lauric Acid

R

Propylene Trimer

R

n-Butyl Alcohol

R

Linseed Oil

R

Pyrolysis Gasoline ( containing benzene )

R

tert-Butyl Alcohol

R

Methyl tert Butyl Ether

R

Styrene Monomer

R

Butylene Glycol

R

Methyl Ethyl Ketone

R

Toluene

R

n-Butyl Ether

R

Molasses

R

Urea solution

R

Chloroform

R

Nitric Acid

NR

Xylenes

R

Citric Acid

R

Nonane

R

White spirit

R


Chemical Resistance required Tankguard Special Ultra Acetic Acid

NR

Cyclohexanol

R

Nonyl Alcohol

R

Acetone

R

Cyclohexane

R

Octane ( all isomers )

R

R Cyclohexanone R Olefin Oil For 4 chemicals Tankguard Special Ultra does Alcohol – various grades R Paraffin wax Dodecane ( all isomers) R not have sufficient chemical resistance Acid oil mixture

Alkanes

Alkyl Benzenes Aniline Butyl Acetate Butyl Acrylate n-Butyl Alcohol tert-Butyl Alcohol Butylene Glycol

R R

R

Ethylene Glycol

R

Phenol

NR

R

Formic Acid

NR

Propylene Glycol

R

However , feedback from owner: R Glycerine R Propylene Tetramer 1. Based on the acetic Hexanol certificate R of fitness R Rapeseed Oil acid , nitric formic acid shall only R Lauricacid and Acid R Propylene Trimer R Oil R STEEL Pyrolysis Gasoline ( containing benzene ) be loaded Linseed in STAINLESS tanks R Methyl tert Butyl Ether R Monomer 2. Most suppliers/receivers prefer Styrene STAINLESS R Methyl Ethyl Ketone R Toluene STEEL tanks when shipping phenol

R R R R R R

n-Butyl Ether

R

Molasses

R

Urea solution

R

Chloroform

R

Nitric Acid

NR

Xylenes

R

Citric Acid

R

Nonane

R

White spirit

R


Chemical Resistance Required Certain owners active the SEA region are typically having the requirement out-bound: Palm Oil products, including Palm Fatty Acid Distillates in-bound: methyl alcohol ; MEG; Caustic Soda; pygas; luboil & others In case the cargo tanks are coated with Tankguard Special Ultra, there are no limitations from the coatings point of view.


Chemical Resistance Required Pre-wash after carriage of aggressive cargoes and bio-fuels: this can be accepted for all cargoes that require this pre-wash This includes executing pre-wash after carriage of methanol .

Note: the pre-wash procedure needs to be discussed.


Chemical Resistance Required In general in cargo tank coating, care regarding subsequent cargoes, since risk of: -

Cargo contamination

-

Negative effect of sequence of chemicals

But these risks are not applicable when back-2-back shipment. Hence, any cargo can be shipped back-2-back.


Chemical Resistance required by European owner 50% of the cargoes understood to be FAME Ethanol Caustic soda Gasoil Methanol Crude vegoil


Chemical Resistance required by European owner 50% of the cargoes understood to be FAME Ethanol Caustic soda Gasoil Methanol Crude vegoil

R R R R R R

1B, 10 5 days ventilation for R1, R2, R16 & R18

4,18

5 days ventilation for R1, R2, R16 & R18

Tankguard Special Ultra has resistance for the above cargoes


Chemical Resistance required by 75% of the cargoes also including MTBE Aromatics Urea’s Xylenes Styrene Molasses Isomerates Cyclo-hexane Refined vegoils


Chemical Resistance required by 75% of the cargoes also including MTBE Aromatics Urea’s Xylenes Styrene Molasses Isomerates Cyclo-hexane Refined vegoils

R R R R R R R R R

Tankguard Special Ultra has resistance for the above cargoes


Jotun Paints Presentation

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