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U.S. Department of Energy Office of Fossil Energy Hydrogen Production from Natural Gas June 2, 2003 Hydrogen Coordination Meeting Arthur Hartstein Program Manager Natural Gas and Oil Processing/Hyd Processing/Hydrogen rogen
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Introduction •
•
•
Natural gas is currently the lowest cost alternative to produce hydrogen Natural gas provides 95% of the hydrogen used to supplement refinery and chemical industry needs Steam methane reforming (SMR), the most widely used method to produce hydrogen, is near its
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Program Goal and Benefits •
•
Goal: Reduce the cost of producing hydrogen from natural gas by 25 percent Benefits: Provide the earliest transitional source of hydrogen for the FreedomCAR FreedomCA R program and the hydrogen −
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History of the FE Hydrogen from Natural Gas Program
Past
Present
Future
GTL
Syngas Production
Emphasis on H2 Production
•
Platform Technology
•
Membranes to separate O2 from air and to
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Gas-to-Liquids (GTL) Process Overview Air
Air Separation
Natural Gas +/+/- Stea Steam m
Oxygen
Syngas Generation
Syngas (Carbon Monoxide + Hydrogen)
FischerTropsch Synthesis (F-T)
About 40% of Capital Cost is Associated With the
Jet Fuel, Diesel, Naphtha
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History of the FE Hydrogen from Natural Gas Program Past
Present
Future
GTL
Syngas Production
Emphasis on H2 Production
• •
Platform Technology Membranes to separate O2 from air
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Revolutionary Platform Technology for Syngas Generation •
Ion Transport Membranes (ITM) Non-porous, multi−
Oxygen-depleted Air
Multilayer Membrane
Syngas Products
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History of the FE Hydrogen from Natural Gas Program Past
Present
Future
Syngas
Emphasis on
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Hydrogen from Natural Gas Program Major Technical Milestones 2005: 0.5 MM ft 3/day H2 Ion Transport Membrane Reactor (ITM) production unit demonstrating conversion of air and natural gas to H2 and synthesis gas
Develop advanced-technology, advanced-technology, low-cost, small-footprint plant for
2010: Pre-commercial ITM technology unit producing 15MM ft 3/day of H2 demonstrated By 2013: Modules to reduce cost of H2 (and synthesis gas) production from natural gas by 25% available 2015: RD&D natural gas program
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Barriers to Hydrogen Production from Natural Gas •
Steam reforming and pressure swing adsorption are mature mat ure tech technolo nologie gies s – the there re is limited potential for cost improvements
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Technology Gaps for Hydrogen Production from Natural Gas •
Novel hydrogen production that combines air separation and partial oxidation in one step [ion transport membrane (ITM) syngas reactor]
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Mission
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Four UCF Projects in Oil and Gas
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FE Hydrogen from Natural Gas
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