NITRIC ACID, 69-71% 1. Product Identification Synonym! Aqua Fortis; Azotic Acid; Nitric Acid 50%; Nitric Acid 65%; nitric acid 69-70% CAS No.! 7697-37-2 "o#ecu#ar $ei&t! 63.01 C&emica# 'ormu#a! HNO3 Product Code!
(. Com)oition*Information on Inredient
Ingredient Hazardous ---------------------------------- -----------------------------------------------------------Nitric Acid Yes Water No
CAS No
Percent
------------
7697-37-2
69 - 71%
7732-1-!
29 - 31%
+. aard Identification merency /0er0ie -------------------------P/IS/N2 DAN3R2 STR/N3 /4IDI5R. C/NTACT $IT /TR "ATRIA "A CA8S 'IR. C/RR/SI. I:8ID AND "IST CA8S SR ;8RNS T/ A ;/D TISS8. "A ; 'ATA I' S$A/$D /R INAD. INAATI/N "A CA8S 8N3 AND T//T DA"A3.
---------------------------------------------------------------------------------------------------------Heat! "atin#$ - &'tre(e )*oison+ Fa((a,iit "atin#$ 0 - None
"eactiit "atin#$ 3 - /eere )O'idizer+ ontact "atin#$ - &'tre(e )orrosie+ a, *rotectie &qui$ O&/ 4 /H&; A OA8 4 A*"ON; &N8 HOO; *"O*&" O&/ /tora#e oor ode$ :!ite )orrosie+ ---------------------------------------------------------------------------------------------------------Potentia# ea#t& ffect ----------------------------------
Nitric acid is e'tre(e !azardous; it is corrosie reactie an o'idizer and a oison. In&a#ation! orrosie< n!aation o= aors can cause ,reat!in# di==icuties and ead to neu(onia and u(onar ede(a >!ic! (a ,e =ata. Ot!er s(to(s (a incude cou#!in# c!o?in# and irritation o= t!e nose t!roat and resirator tract. Inetion! orrosie< />ao>in# nitric acid can cause i((ediate ain and ,urns o= t!e (out! t!roat eso!a#us and #astrointestina tract. S or eo>-,ro>n coor. ye Contact! orrosie< aors are irritatin# and (a cause da(a#e to t!e ees. ontact (a cause seere ,urns and er(anent ee da(a#e. C&ronic =)oure! on#-ter( e'osure to concentrated aors (a cause erosion o= teet! and un# da(a#e. on#-ter( e'osures sedo( occur due to t!e corrosie roerties o= t!e acid. Ara0ation of Pre-e=itin Condition! *ersons >it! re-e'istin# s?in disorders ee disease or cardiou(onar diseases (a ,e (ore susceti,e to t!e e==ects o= t!is su,stance.
>. 'irt Aid "eaure ((ediate =irst aid treat(ent reduces t!e !eat! e==ects o= t!is su,stance. In&a#ation! "e(oe to =res! air. = not ,reat!in# #ie arti=icia resiration. = ,reat!in# is di==icut #ie o'#en. a a !sician. Inetion! O NO8 N@& O8N< ie ar#e quantities o= >a ter or (i? i= aaia,e. Neer #ie ant!in# , (out! to an unconscious
erson. et (edica attention i((ediate. Sit! ent o= >ater =or at east 15 (inutes >!ie re(oin# conta(inated cot!in# and s!oes. :as! cot!in# ,e=ore reuse. 8!orou#! cean s!oes ,e=ore reuse. et (edica attention i((ediate. ye Contact! ((ediate =us! ees >it! ent o= >ater =or at east 15 (inutes i=tin# o>er and uer eeids occasiona. et (edica attention i((ediate.
?. 'ire 'i&tin "eaure 'ire! Not co(,usti,e ,ut su,stance is a stron# o'idizer and its !eat o= reaction >it! reducin# a#ents or co(,usti,es (a cause i#nition. an react >it! (etas to reease =a((a,e !dro#en #as. =)#oion! "eacts e'osie >it! co(,usti,e or#anic or readi o'idiza,e (aterias suc! as$ aco!os turentine c!arcoa or#anic re=use (eta o>der !dro#en su=ide etc. "eacts >it! (ost (etas to reease !dro#en #as >!ic! can =or( e'osie (i'tures >it! air. 'ire =tinui&in "edia! :ater sra (a ,e used to ?ee =ire e'osed containers coo. o not #et >ater inside container. S)ecia# Information! ncreases t!e =a((a,iit o= co(,usti,e or#anic and readi o'idiza,e (aterias. n t!e eent o= a =ire >ear =u rotectie cot!in# and NO/H-aroed se=-contained ,reat!in# aaratus >it! =u =aceiece oerated in t!e ressure de(and or ot!er ositie ressure (ode.
6. Accidenta# Re#eae "eaure entiate area o= ea? or si. :ear aroriate ersona rotectie equi(ent as seci=ied in /ection B. soate !azard area. Cee unnecessar and unrotected ersonne =ro( enterin#. ontain and recoer iquid >!en ossi,e. Neutraize >it! a?aine (ateria )soda as! i(e+ t!en a,sor, >it! an inert (ateria )e. #. er(icuite dr sand eart!+ and ace in a c!e(ica >aste container. o not use co(,usti,e (aterias suc! as sa> dust. o not =us! to se>er< @/ "e#uations )&"A+ require reortin# sis and reeases to soi >ater and air in e'cess o= reorta,e quantities.
7. and#in and Storae /tore in a coo dr entiated stora#e area >it! acid resistant =oors and #ood draina#e. *rotect =ro( !sica da(a#e. Cee out o= direct suni#!t and a>a =ro( !eat >ater and inco(ati,e (aterias. o not >as! out container and use it =or ot!er uroses. :!en diutin# t!e acid s!oud a>as ,e added so> to >ater and in s(a a(ounts. Neer use !ot >ater and neer add >ater to t!e acid. :ater added to acid can cause uncontroed ,oiin# and sas!in#. ontainers o= t!is (ateria (a ,e !azardous >!en e(t since t!e retain roduct residues )aors iquid+; o,sere a >arnin#s and recautions isted =or t!e roduct.
@. =)oure Contro#*Perona# Protection Airorne =)oure imit! -O/HA *er(issi,e &'osure i(it )*&+$ 2 ( )8:A+ ( )/8&+ -AH 8!res!od i(it aue )8+$ 2 ( )8:A+; ( )/8&+ enti#ation Sytem! A sste( o= oca andDor #enera e'!aust is reco((ended to ?ee e(oee e'osures ,eo> t!e Air,orne &'osure i(its. oca e'!aust entiation is #enera re=erred ,ecause it can contro t!e e(issions o= t!e conta(inant at its source reentin# disersion o= it into t!e #enera >or? area. *ease re=er to t!e AH docu(ent Industrial Ventilation, A Manual of Recommended Practices (ost recent edition =or detais. Perona# Re)irator BNI/S A))ro0ed! = t!e e'osure i(it is e'ceeded >ear a suied air =u-=aceiece resirator airined !ood or =u-=aceiece se=-contained ,reat!in# aaratus. Nitric acid is an o'idizer and s!oud not co(e in contact >it! cartrid#es and canisters t!at contain o'idiza,e (aterias suc! as actiated c!arcoa. anister-te resirators usin# sor,ents are ine==ectie. S!ere sas!in# is ossi,e. aintain ee >as! =ountain and quic?-drenc! =aciities in >or? area.
9. P&yica# and C&emica# Pro)ertie A))earance! ooress to eo>is! iquid. /dor! /u==ocatin# acrid. So#ui#ity! n=inite sou,e. S)ecific 3ra0ity! 1.1 )! 1.0 )0.1 soution+ % o#ati#e y 0o#ume (1C B7E'! 100 )as >ater and acid+ ;oi#in Point! 122 )252F+ "e#tin Point! -2 )-F+ a)or Denity BAirF1! 2-3 a)or Preure Bmm ! B E 20 )6BF+ 0a)oration Rate B;uAcF1! No in=or(ation =ound.
1E. Stai#ity and Reacti0ity Stai#ity! /ta,e under ordinar conditions o= use and stora#e. ontainers (a ,urst >!en !eated. aardou Decom)oition Product! :!en !eated to deco(osition e(its to'ic nitro#en o'ides =u(es and !dro#en nitrate. :i react >it! >ater or stea( to roduce !eat and to'ic and corrosie =u(es. aardou Po#ymeriation! :i not occur. Incom)atii#itie! A dan#erous o>er=u o'idizin# a#ent concentrated nitric acid is inco(ati,e >it! (ost su,stances esecia stron# ,ases (etaic o>ders car,ides !dro#en su=ide turentine and co(,usti,e or#anics. Condition to A0oid! i#!t and !eat.
11. To=ico#oica# Information Nitric acid$ n!aation rat 50$ 2 ( )NO2+D30; nesti#ated as a (uta#en reroductie e==ector. Ora )!u(an+ o$ 30 (#D?#. --------"Cancer #ists"--------------------------------------------------------N$P Carcinogen--Ingredient no&n Antici'ated Categor) -------------------------------------------------------------Nitric Acid *7697-37-2+ No No None Water *7732-1-!+ No No None
1(. co#oica# Information n0ironmenta# 'ate! No in=or(ation =ound. n0ironmenta# To=icity! No in=or(ation =ound.
1+. Di)oa# Conideration :!ateer cannot ,e saed =or recoer or reccin# s!oud ,e (ana#ed in an aroriate and aroed >aste =aciit. At!ou#! not a isted ""A !azardous >aste t!is (ateria (a e'!i,it one or (ore c!aracteristics o= a !azardous >aste and require aroriate anasis to deter(ine seci=ic disosa require(ents. *rocessin# use or conta(ination o= t!is roduct (a c!an#e t!e >aste (ana#e(ent otions. /tate and oca disosa re#uations (a di==er =ro( =edera disosa re#uations. isose o= container and unused contents in accordance >it! =edera state and oca require(ents.
1>. Tran)ort Information Dometic Band, D./.T. ----------------------Pro)er S&i))in Name! N8" A ):8H NO8 O"& 8HAN 70% N8" A+ aard C#a! B
IA(C
8N*NA! @N2031 *ac?in# rou$ Information re)orted for )roduct*ie! 150 Internationa# B$ater, I."./. ----------------------------Pro)er S&i))in Name! N8" A ):8H NO8 O"& 8HAN 70% N8" A+ aard C#a! B 8N*NA! @N2031 *ac?in# rou$ Information re)orted for )roduct*ie! 150 Internationa# BAir, I.C.A./. ----------------------------Pro)er S&i))in Name! N8" A ):8H NO8 O"& 8HAN 70% N8" A+ aard C#a! B 8N*NA! @N2031 *ac?in# rou$ Information re)orted for )roduct*ie! 150
1?. Reu#atory Information --------"C,eica. In/entor) Status - Part 1"--------------------------------Ingredient Austra.ia ------------------------------------------------------Nitric Acid *7697-37-2+ Yes Water *7732-1-!+ Yes --------"C,eica. In/entor) Status - Part 2"-------------------------------- Ingredient P,i. --------------------------------------------------Nitric Acid *7697-37-2+ Yes Water *7732-1-!+ Yes
$SCA
0C
a'an
----
---
-----
Yes
Yes
Yes
Yes
Yes
Yes
orea
--Canada-S# NS#
-----
---
----
Yes
Yes
No
Yes
Yes
No
--------"4edera.5 State Internationa. (egu.ations - Part 1"----------------SA(A 32------SA(A 313------
Ingredient C,eica. Catg -----------------------------------------------------Nitric Acid *7697-37-2+ No Water *7732-1-!+ No
(8
$P8
#ist
---
-----
----
1
1
Yes
No
No
No
--------"4edera.5 State Internationa. (egu.ations - Part 2"--------------- -(C(A-$SCAIngredient C0(C#A 26133 *d+ ----------------------------------------- ---------------Nitric Acid *7697-37-2+ 1 No Water *7732-1-!+ No No
C,eica. Wea'ons Con/ention No $SCA 12*:+ No C$A No SA(A 311;312 Acute Yes C,ronic Yes 4ire Yes Pressure No (eacti/it) No *uid+
Autra#ian ac&em Code! 2*& Poion Sc&edu#e! /6 $"IS! 8!is // !as ,een reared accordin# to t!e !azard criteria o= t!e ontroed *roducts "e#uations )*"+ and t!e // contains a o= t!e in=or(ation required , t!e *".
16. /t&er Information N'PA Ratin! Heat!$ + Fa((a,iit$ E "eactiit$ E Ot!er$ /=idier ae# aard $arnin! *O/ON< AN&"< /8"ON OG&". ON8A8 :8H O8H&" A8&"A A A@/& F"&. O""O/&. I@ AN /8 A@/& /&&"& @"N/ 8O A O 8//@&. A & FA8A F /:AO:& O" NHA&. NHAA8ON A A@/& @N AN 8OO8H AA&. ae# Precaution! o not #et in ees on s?in or on cot!in#. o not ,reat!e aor or (ist. @se on >it! adequate entiation. :as! t!orou#! a=ter !andin#. Cee =ro( contact >it! cot!in# and ot!er co(,usti,e (aterias. o not store near co(,usti,e (aterias. /tore in a ti#!t cosed container.
No No
"e(oe and >as! conta(inated cot!in# ro(t. ae# 'irt Aid! n case o= contact i((ediate =us! ees or s?in >it! ent o= >ater =or at east 15 (inutes >!ie re(oin# conta(inated cot!in# and s!oes. :as! cot!in# ,e=ore reuse. = s>ao>ed O NO8 N@& O8N. ie ar#e quantities o= >ater. Neer #ie ant!in# , (out! to an unconscious erson. = in!aed re(oe to =res! air. = not ,reat!in# #ie arti=icia resiration. = ,reat!in# is di==icut #ie o'#en. n a cases #et (edica attention i((ediate. Product 8e! a,orator "ea#ent. Re0iion Information! // /ection)s+ c!an#ed since ast reision o= docu(ent incude$ 3.
