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1- Klorofilin
a.noa.l;i.zi %2. 68 lliA9nez}~.im ihtiva
ettigini
göstermisti::: .1.00
....
klorofilde
ne kadar
2- Bir .ntimon
%24173
oksitte
3- 0.90 ~tom-gram tiva\eden
2. tO!!l:U n:;.';
vardir.
nesapla-yxi:::i:i.z.
Ampirik
i.445xi024 atom hidrojen
~rbon,
bir
oksijen
bilesigin
basit
ç .:'i;/:.
f
bulunduSunu
formülü
,':..
formülünü
bulunuz.
ve 4.8 9 oksijen
ih-
medir?
\
4-
Ag~r1ik
~9.7
~3B.7 karbon,
yüzdesi
hidrojen,
%51,6
oksijen
olan
bile-
-I
~~~in:bGsit olduguna
formülü
nedir?
Çlüre moleküi
Bu biie~i9in
formülü
nedir?
.malekül
Bu bilesigin
mo1ekiil vardir?
62,0 g/mo~
ag~rl~gi
<:f;=amiri~ kaç ..
1,00
_.
"
- .. ~~;
.-:'~ :.,'
"',;
~5- yaliin •
hidrojen
ve k4rbondan
kildigi -zai:ian0,660 .
nasildir?
9 CO
yapilins
meydana
2
B~ hidrokarbonun
,.. "'-'7"'.'
273.1~K
.
'-"
.••..
...
muamele
ediliyor
iüyor.Europyum'un 7- Bir A,elementi, yor.
0,359
atom
agirligini
8- 1,60
~tom
klorür
1,28
9 AgCl
=
formülü,,<.!.,,\jf .
'.. c'
q •••
~:
1',87 g/1
,,_o
••
,.;
.' ...
",'·;~~~1:11~t' ..
•• :',;
··Ç?~~~~~f~\;~::~'~
nitra.~ ..;_r •• --r "' .•.•. ;y•••••.• h4ilinde .Çoktü....-ü.. , ;-'.;' ~-~.i:",i
...•..:
i
4igirligi ne kadardir.
oksijenle
9 A ele~enti
ggelen
ve bütün
ampirik
ve 1 at~~.deki yogunlugu
..... ;.cfi~'.'B.~iesi~i~·"moieküi f~rmüiü~~~:,~:~~r?,>?o':'.~~ .. :.,.' . 6- ·i,oo.? ~uropyum dikJ.orür(:EUCI2;,'OOl~tar~ sulu' ~üs tisiyle
'>i'<)~'f:; , •..,..•.
bir:~bIi';;sigin·O,210..g'i.. ya'·.?'-.i-l: :
geliyor::-::BÜesigin
. .~.~.~: ~~~~~:
basit 0,559
formülü
9 bilesik
A30S
olan
bir
verdigine
bilesik.veri-
göre
A elementinin • '-t.
hesaplayini..z •
bir
demir
oksid
örneg~,
t~jyle
1,12
9 metalik
demir ...•.......
:...:,~"' ~= ::,~=-:':..;.~~--:=:.~ l-:::~, oksidin 9- Baryum
ampirik bromür ,
hidrojen
.9azi akiminda
~si tiliyor.
Demir
formülünasildir?
BaBr 2' klor.
'...i::~:":;
9.azJ. akiminda
isitilirsa,
tamamen,
BaC12
baryum Idorllre dönüsür. -1,5() ~ BaBr; ~-den tam 1,05 9 BaCI2, elde baryumun atom agirli..çini edilmektedir. Bu verilerden. faydalanarak hesaplayiniz.
10- 0,578 9 saf kalnYe dar fIuor ün ampirik - 11-
Sadece grami
gazi
ile reaksiyona
formülü
kükürt,
nas~ldir?
hidrojen
klor gazinda
dür. Bilesigin
SVL. ~~iinün agi..rligi sabit
sokuluyor. Sentezin
ve karbon
yaki1iyor.
ampirik
")
/-
.J.'
Meydana
denklemini
ihtiva
Ürünler,
formülünü
(0,944 g) kalincaya
eden 21,9
gelen
kalay
ka-
fIuorür-
yaziniz.
bir bilesigin 9 HCl
ve 30,8
~~ZO 9 C
C14
bulunuz.
~ ,
•.
.J,"
li'
12- Belli bir metalden, içlerinde S85,2 ve ~5,8 klorür elde ediliyor. gun olduklarini
~t~
buiun~n
iki
(a) 'Bu bilesiklerin kat oranlari k.:.uiununa uy-
gösterin.
(b) Bilesiklerin en basit formülleri na-
sildir ve metalin bu formüller e göreatom
agirligi ne k~dardir?
(c) Diger mümkün formüller e göre, hangi atom .girliklari mümkündür? (d) \Periyodik sistemden faydalanarakmetalin
atom ~giriigini t~yin
'.
ediniz. 13- van.dium ve kükürt, uygiin,sartlar -altinda farkli bilesikler meydan .• getirebilirler.Asag:'..daki konbinasyonlara gö:-ebilesiklerin basit nelerdir? a') 0,15 a,tom-gram vanadi~
formuileri
kükürt, b) Agir1ikÇ4%38.9
~e 9.1'03x1022atom
vanadium ve ~6l,1 kükürt, c) 5,094 g
vanadill,!It ve 0,,15 a~om-gram kükürt.
14- As~gidaki izoto~ k~~~-le~i,ve, ~ll~arindan faydalanilarak, magnez~ a~om --g~r?-i~i~_.i7rini~, •. :. Izotop Çokluk Kütle 24
//
%78,60
23,993
25
~lO,11
24,994
26
%11,29
25,991
15- Dogal bakir Cu63 ve eu65 den meyda.i-ia gelmistir. Bu i'zotop.1arinkütleIeri sirasiyla 62,929 __.k.b. ve 64y28 a.k.b. dir. Ba..1a.rin atom agirligi 63,54 a.k.b. olduguna göi:.~
/
-' .
//
'
16- 7,380 g gelen bir metal oksi~ tamamen bozunar-.k6,840 9 saf metal
/
veriyor.
Metalin özgülisisi
0,0332 cal/gl dir. Metalin duyar atom
agirligini ~esaplayin ve oks~ ampirik formülünü bulun. 17- Bir metalin özgül isisi 0,110 Cal/g derece olarak biliniyor •. Bu ' / metalin 1.000 gramini.n seyreltik asit ile rea.k.Myonundan meydana gelebilecek
hidrojen gazinin hacmi NS. alti..nda ne bdardir?
IB- Belli bir ~le:~n~€l gazin çesitli basinçlard-.kiyogunluklari
ölçül~
müs ve 1 atm ve 273,ioK deki ideal yogunluk için 17787 g/litre degeii ri elde edi!;m.istir. /Oksijen gazinin ayni sartlar altindaki ideal
/
yogunlugu
1,428 g/litredir? Bilinmeyen gazin molekül agirligi'oe
ka-
dardir? Bu molekül agirliginin tam kesirleri için periyodik.sistemdeki "yer" ler~.. g~ôl.ki bu elementin iki vey.•çok atomlu bir moleküle sahip olamiyacagi h-.kki..nda bir kanit arayin. Bu molekü1 agi..r1igimidir?
-2 .~
19- Esit
a9i~likta çir~o ile iyod karistirilmis ve iyodun tamani znl 2
baline dÖnüsmüstür.
Bastaki çinkonun, agirlik yüzdesi ol~ak
neka-
dari reaksiyona girmeden kalmistir? 20- Gümüs molibden ve kükürt elementleri bir araya geler~k A92MoS4 bilesigini
meydana getiriyorlar. 8.63 g Ag, 3,36 9 Ho ve 4.Si.gS'den
basliyarak elde edebilecek maksimum Ag2HoS4 bilesiginin miktarini i hesap,layiniz. \
2l-~~,~~~~~~u bir CaC12 ve NaCl 'karisimindaki bütün kalsiyum Cac03 halinde çöktürülüyor ve bu çökelek isitilinca. '0,959 9 S~ C&O elde ediliyor. CaC12'ün bastaki karisimindaki agirlik yüzdesini bulu~uz. 22- Basit formüliei'i Cus Fe S4 ve Cu 2S OLan iki mineraiden hangisi .. agirlik -Yüzdesi·olarak. baS.{a::'i-~-daha zengindir? ~
23- Bir 'alimin~m
ve bakir alasim,
Al üi:iri.n yum
Al .•..3 H~Al+~'..
·sulu HCl ile reaksiyona sokulu~r .•..3/2
•.
"H2
reCLksiyona göre çözünüyor ~f.;"'kat ·.boua.r saf ~tal. olara.kk.iii.liyor .0,3.50 9 alasimdan 415 cc.H2 gazi (273,ioK ve 1 atm'de) ·elde ediliyor.Al'nin alasiinda.-ki agirlik yüzdesi ne kadirdir? 24- 2,07 9 saf kursun, nitra.t asidinde çözillerekkursun nitrat çözeltisi elde ediliyor. Bu çözelti klorür asidi, klor gazi ve amon}~
klorür
ile reaksiyona sokuluyor. Sonunda amonyum heksa.kloroplumha.t(NH4)2 PbC16 çökele§i elde ·ediliyor. 2,07 9 kxur.~un~~ en fazla ne~dar ürün elde edilebilir? 25- 2.00 9 C3HS ile 7 ~00 9 02 ::2.ksimummi~tarda CO ve H20 elde etmek üzere reaksiyona sokuluyor. Kaç gram CO meydana gelire = -3 ..•... -3 26- 1,00 x 10 :mol Ag ile 1,00 x 10 mol Cr04 karis~irildiginda ne kadar Ag2CrO 4. çöker? 27- Bor ve hidrojenin bir gaz bilesiginden 0,596gram~ 273,ioK ve 1 atm de484 cc yer kAplama.ktadi~. Bilesik bol oksijenle yakilinca. içindeKi bütün hidrojen 1,17 9 su halinde geçmekte ve borun tamami B~O_ ~
.::>
sekline dönüsmektedir. Borhidrojen bilesiginin ampirik formülünü. molekü1 formülünü, molekül agirligini bulunuz. Yanma sonunda ne kadar B203 meydana geiir? 28- Baryumun bili~yen oksijen gazi
bjr
c~~idi isitilinca 5,00 9 saf BaO ve 366
CC"
(273,ioK ve 1 at~'de) elde ediliyor. Bilinmeyen oksidin
ampirik formülü nasildir? Baslangiçtaki oksi t ne kadardir?
-3.J-" .. '. ·'-1-0'
-r.~
t,
r
i
+
29- 0,560
! .~
sokuç gelen bir:KBr ve NaBr k.aris.imisulu Aç; ile re;Ucsiyon;i.
luyor ve bromürÜn t~
0,970
ç
saf AçBr h~linde ayriliyor.Bast~(i
karisimda F~r' in agir'.ik kesri ne kadardir? 30- Demir ticari olarak, hema~itin (Fe203) indirçenaesi :le elde e~ilir. Demir üretmek için gerekli CO, kok kömürünün Ciksijenle re~ksiyona sokulmasindan elde edilir. Reaksiyo~ denklemlerini y~zip denklestirerek, 1,47 9 karbondan ne ~dar
Fe elde edilebilecegini hesaplayiniz.
-4-...~ ..~
.~
AT01>'UNYAPiSi 1- Asagidaki
ILE ILGILI
PROBL5..}.{LER
tabloyu tam=-.mlayiniz.
i A 202temel alan 82 34 114 Proton 10 N olan 209126 7 Elektron Z"dtron 80 -~F atomunu atomik Sembol 2)Halen 29 kütle birimi. -;0 Bi 7 48 e gaha büyüktür? 1) Kütiesi tam olarak a.k.b.
ku1ianilan·standart·ato~k .topuvardir.
o.da
gd'
kütle birimi.
(~gada
dir.)'
fl?run birtek
'-':,
izo~
_,
3- imbidyumun 'iki dogal izotopu vardir. Biri kütlesi 84.91 •.• k.b. olan' 85Rb.~geri
kütlesi 86.92 a.k.'b•.olan 87Rb dir. Rubidyumwi atom agir-
ligi 85,47 dir. HerbiL izotopun yüzdebolluk
degerini hesaplayiniz.
4- Bir x elementi kütlesi 24,0 a.k.b. olan atomdan %78.7, kütlesi 25,0 a.k.b. olan atc:mdan%10,1, kütlesi 26,0 a.k.b.olan ihtiva ettigine göre,xtin _. b.C'nin a~om
-i ..,
riia.
enerjisi
u! l'esi t~
kOO
atomelan %11,2
atom agirligi nedir? o 1arak
12 a ••. k .b dir. 12 o,C o
atomunun baglan-
(kalori cinsinden) ne kadardir? Önemli parçaciklarin
küt-
leIeri söyledir: Elektron, 0,0005 a.k.b., proton 1.0073 a.k.b. ve nötron 1.0086 a.k.b.~
i
~~, ,,:-
a.k.b., 1.49 x 10-3 ergte esdegerdir ve 1 kalori 4.18 x 107 ergte
esdegerdir. o 5.00 x 102m 4500 AO boylu mavi isik kuvantum basina enerjileri nelerdir? Asagidakilerin 1.50 Ao dalga xisini 5500 A 6- dalga boylu sari isik (5.00 xfrekanslari~~e 1012 AO) dalga boylu radyo dalgalari.
b) d) c)
a)
o
-J-
~
'.. : ..
~. o i p ..•..
()
i
7- 4000 AA dalga boylu pir isik sodyum.meta1inin yüzeyi üzerine düserse, .J:..
hizlari 5.37 x 10
cm/sn olan elektranlar yayilir.
a) 4000 Aa dalga boylu fotonlarin enerjisi
(erg cinsinden)
nedir? b} Y.yilanelektronlarin
kinetik enerjisi
(erg cinsinden)
nedir? c) SodyumdAnbir frekansi
ele~ron çikar~
ve buna karsili~ gelen dAlgA
sAbiti. h,.6.63 cm/sn;
için gerekli, minimum
x
10-27 erg. sn.;
isik
isik Pla.nck
boyu nedir?
hizi,
x
c, 3:00
1010
2
elektran kütlesi, 9.11 x 10.28 g ; 1 erg, 1 gcm /sn
2
dir. 8•.Hidrojenip görünür bölgedeki spektra çizgileri
(Balmer serisi) daha
.yükse~ seviyelerden n=2 seviyesine geçisini gösterir. Hangi e~ektron .geçisi, 6563 AO dalga boyundaki spektra çizgilerine '~silik .
gelir?
9-a) Bohr teorisine göre, temel haldeki hidrojen _t~munun y~içapi . . . . _...•. 13 cm) Aformulu 1/3 b) Birçok çekirdegin yariçapiarir=(1.3x10
h~?~p1a~~~~li~.Eu=ada A
'
ne~r1~ . ile
kütle sayisidir. :Brinagöre H çekirdeginin
yariçapi ne :olur? c}a.
treb- deki cevapla.rikullanarak
Bohr B a.toiminuntoplam hacminin
çekirdek tarafindan .isgal edilen yüzdesini nesaplayiniz. 10- a) Isik hizinin onda biribir:hizla
hareket eden elektronunBroglie
dalga boyu nedir?
-
\
.n••..i'=~'=•.. ""CcD protonun 'Broglie dalga bo~S ·nedir? Bir b) Ayniniz:t.i:l
..1 e1 ek tronun k ut
g
esi.
1 9'.
ixio -28,9
. protonun ' k' -. 1 ve bir ,ut
esi. '1 •67XLO-24
dir.
11- Biratomdaki
herbir elektron 4 kuvantum sayisi ile karekterize
edilir.
Asagidakilerin herbiri için,-kaç takim kuvantum sayisi mümkündür? takimlarin herbiri listelenen bütün degerleri içermelidir.
a)n=
d) n=2,1~O, g) ri=
b) n= 4,
5,- 1=4, m=
+2~)
1=1,
c) n= 1=2,
5.
-10 -
m=
4, 1=0, m=O
+1f---n-~
Bu
...~ ; '.".
.
