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CONTROL S YSTEMS ENGINEER TECHNICAL REFERENCE HANDBOOK BY CHUCK CORNELL, PE, CAP, PME
International Society of Automation P.O. Box 12277 Research Triangle Park, NC 27709
CONTROL S YSTEMS ENGINEER TECHNICAL REFERENCE HANDBOOK BY CHUCK CORNELL, PE, CAP, PME
International Society of Automation P.O. Box 12277 Research Triangle Park, NC 27709
CONTENTS
PREFACE
xiii
ABOUT THE AUTHOR ACKN CKNOWLE OWLEDG DGM MENTS ENTS ACRONYMS
xv xvii xvii
xix
COMM COMMON ON ELEC ELECTR TRIC ICAL AL DEFI DEFINIT NITIO IONS NS
xxii xxiiii
1. CSE CSE PE PE EXA EXAM M – GENE GENERA RAL L INF INFOR ORMA MATI TION ON 2. MISC MISCEL ELLA LANE NEOU OUS S REV REVIE IEW W MAT MATER ERIA IAL L
1
3
2.1 Mathematics 3 2.1.1 SI Pr Prefixes 3 2.1.2 Algebra 3 2.1.3 Trigonometry 6 2.1.4 Calculus 7 2.1. 2.1.66 Diff Differ eren enti tial al Equ quat atio ions ns 11 2.1.7 1.7 Laplace Transforms 11 2.1.8 Bode Plot 11 2.1.9 Nyquist Plot 12 2.2 Thermodynamics 14 2.2.1 Terminology 14 2.2. 2.2.22 He Heat at Ad Addi diti tion on and and Te Temp mper erat atur uree 15 2.2.3 2.3 Mollier SStteam Di Diagr agram 15 2.2.4 2.4 Psychro hrometric Ch Chart 15 2.2.5 2.2.5 Proper Propertie tiess of Water Water 17 2.2. 2.2.66 Pr Prop oper erti ties es of Satu Satura rate ted d Stea Steam m 18 2.2. 2.2.77 Prope ropert rtie iess of of Su Supe perh rhea eate ted d Ste Steam am 20 2.3 Statistics 22 2.4 2.4 Bool Boolea ean n Logi Logicc Ope pera rati tion onss 24 2.5 Conversion Fa Factors 26 2.6 2.6 Eq Equ uatio ations ns/L /Law awss/F /For orm mulas ulas 29 3. MEASUREMENT
35
Topic Hi Highlights 35 3.1 3.1 Te Temp mper erat atur uree Me Meas asur urem emen entt Se Sens nsor orss 35
V
3.1.1 3.1.2 3.1.3 3.1.4 3.1. 3.1.55 3.1.6
Thermocouple (T/C) 35 Resistanc Resistancee Temperatur Temperaturee Detector Detector (RTD) (RTD) 38 Thermistor 41 Temperature Switch 42 Temp Te mper erat atur uree Indic Indicat ator or (The (Therm rmom omet eter er)) 42 Thermowell 42
3.2 3.2 Press ressu ure Measu easure rem ment ent Sen Senso sors rs 45 3.2.1 Manometer 45 3.2.2 Bourdon Tube 46 3.2.3 2.3 Pressure Diaphragm 46 3.2. 3.2.44 Pr Pres essu sure re Tra Trans nsdu duce cer/ r/Tr Tran ansm smit itte terr 47 3.2.5 Diaphragm Se Seal 47 3.2.6 Pressure Pressure Sensor Sensor Installatio Installation n Details Details 47 3.3 3.3 Volu Volume metr tric ic Flow Flow Me Meas asur urem emen entt Sen Senso sors rs 49 3.3. 3.3.11 Se Sens nsor orss Based Based on Dif Diffe fere rent ntia iall Pres Pressu sure re (D/P (D/P Pro Produ duce cers rs)) 50 3.3. 3.3.22 Elec Electr tron onic ic Volu Volume metr tric ic Flow Flowme mete ters rs 62 3.3.3 3.3.3 Mass Mass Flowme Flowmeter terss 65 3.3. 3.3.44 Me Mech chan anic ical al Vol Volum umet etri ricc Flo Flowm wmet eter erss 67 3.3. 3.3.55 Op Open en Chan Channe nell Volu Volume metr tric ic Flow Flow Me Meas asur urem emen entt 68 3.3. 3.3.66 Flow lowmete meterr Sel Selec ecti tion on Gui Guide 71 3.4 3.4 Lev Level Measu easure reme ment nt Se Sens nso ors 72 3.4. 3.4.11 Infe Infere rent ntia iall Le Leve vell Me Meas asur urem emen entt Te Tech chni niqu ques es 72 3.4. 3.4.22 Visu Visual al Lev Level el Mea Measu sure reme ment nt Tec Techn hniq ique uess 78 3.4. 3.4.33 Elec Electr tric ical al Prop Proper erti ties es Leve Levell Measu Measure reme ment nt Tech Techni niqu ques es 80 3.4. 3.4.44 Floa Float/ t/Bu Buoy oyan ancy cy Le Leve vell Mea Measu sure reme ment nt Tec Techni hniqu ques es 82 3.4. 3.4.55 Time Time of Flig Flight ht Lev Level el Me Meas asur urem emen entt Tec Techni hniqu ques es 83 3.4. 3.4.66 Misc Miscel ella lane neou ouss Level Level Meas Measur urem emen entt (Switc (Switch) h) Tech Techni niqu ques es 85 3.5 Analytical Analytical Measurement Measurement Sensors Sensors 86 3.5. 3.5.11 Comb ombusti ustib ble Gas Gas Ana Anallyzer yzerss 87 3.5.2 Dew Point 88 3.5.3 Humidity SSeensors 89 3.5. 3.5.44 Elec Electr tric ical al Con Condu duct ctiv ivit ity y Anal Analyz yzer erss 91 3.5.5 pH/ORP An Analyzers 92 3.5. 3.5.66 Disso issollve ved d Oxy Oxyg gen Ana Anallyzer yzerss 93 3.5.7 Oxygen Co Content tent (in Ga Gas) 94 3.5.8 Turbidity An Analyzers 95 3.5. 3.5.99 TO TOC C (To (Tota tall Orga Organi nicc Car Carbo bon) n) Ana Analy lyze zers rs 97 3.5. 3.5.10 10 Ligh Lightt Wav Wavel elen engt gth h Typ Typee Ana Analy lyze zers rs 99 3.5. 3.5.11 11 Chro Chroma mato togr grap aphs hs and and Spe Spect ctro rome mete ters rs 99 3.5. 3.5.12 12 Cont Contin inuo uous us Emi Emiss ssio ion n Moni Monito tori ring ng Sys Syste tems ms (CE (CEMS MS)) 102 3.5.13 Vibrati ation An Analysis 104 104 4. SIGNA SIGNALS LS,, TRA TRANS NSMI MISS SSIO ION N AND AND NETW NETWOR ORKI KING NG
4.1 Signals/Transmission 107 4.1.1 Copper Cabling 107 4.1.2 1.2 Fiber O Opt ptiic Ca Cabling 109
VI
107 107
4.1.3 IEEE 802.11 & ISA 100.11a Wireless LAN Communication Protocols 111 4.1.4 Transducers 113 4.1.5 Intrinsic Safety (I.S.) 113 4.2 Networking 115 4.2.1 OSI Model 115 4.2.3 Protocol Stack 116 4.2.4 Network Hardware 116 4.2.5 Network Topology 119 4.2.6 Buses/Protocols 121 4.3 Circuit Calculations 134 4.3.1 DC Circuits 134 4.3.2 AC Circuits 140 4.3.3 Voltage Drop 147 4.3.4 Cable Sizing 148 4.3.5 Electrical Formulas for Calculating Amps, HP, KW & KVA (Table 4-13) 148 5. FINAL CONTROL ELEMENTS
149
5.1 Control Valves 149 5.1.1 Selection Guide 149 5.1.2 Control Valve Inherent Flow Characteristics 149 5.1.3 Control Valve Shutoff (Seat Leakage) Classifications 151 5.1.4 Control Valve Choked Flow/Cavitation/Flashing 151 5.1.5 Control Valve Noise 152 5.1.6 Control Valve Plug Guiding 156 5.1.7 Control Valve Packing 157 5.1.8 Control Valve Bonnets 159 5.1.9 Control Valve Body Styles 159 5.1.10 Common Valve Trim Material Temperature Limits 165 5.1.11 Control Valve Installation 166 5.2 Actuators 166 5.2.1 Failure State 166 5.2.2 Action 167 5.2.3 Valve Positioner 168 5.2.4 Actuator Types 168 5.2.5 Actuator Selection 170 5.3 Control Valve Sizing 171 5.4 Pressure Regulators 175 5.4.1 Pressure Reducing Regulator 175 5.4.2 Back Pressure Regulator 177 5.4.3 Vacuum Regulators & Breakers 177 5.4.4 Regulator Droop 178 5.4.5 Regulator Hunting 178 5.4.6 Pressure Regulator Sizing 178 5.5 Motors 181 5.5.1 Types of Motors 181
VII
5.5.2 5.5.3 5.5.4 5.5.5 5.5.6 5.5.7 5.5.8 5.5.9
Motor Enclosure Types 194 Nameplate Voltage Ratings of Standard Induction Motors 195 Motor Speed 195 Motor NEMA Designations 197 Life Expectancy of Electric Motors 198 Motor Positioning 199 Example Motor Elementary Diagrams 200 Motor Feeder Sizing Table 204
5.6 Variable Frequency Drives (VFDs) 205 5.6.1 Types of Variable Frequency AC Drives 205 5.6.2 VFD Applications 206 5.6.3 Harmonics Associated with VFDs 206 5.7 Pressure Safety Devices 207 5.7.1 Terminology 207 5.7.2 Types of Pressure Relief/Safety Valves 208 5.7.3 Tank Venting 209 5.7.4 Types of Rupture Disks 210 5.7.5 Rupture Disk Accessories 211 5.7.6 Rupture Disk Performance 212 5.7.7 Pressure Relief Device Sizing Contingencies 212 5.7.8 Pressure Levels as a % of MAWP 214 5.7.9 Pressure Relief Valve Sizing (per ASME/API RP520) 215 5.7.10 Rupture Disk Sizing (per ASME/API RP520) 217 5.7.11 Selection of Pressure Relief/Safety Devices 219 5.8 Relays/Switches 219 5.8.1 Relays 219 5.8.2 Switches 220 6. CONTROL SYSTEMS
223
6.1 Documentation 223 6.1.1 Instrumentation Identification Letters 223 6.1.2 Instrumentation Line Symbols 224 6.1.3 Instrumentation Location Symbols 225 6.1.4 Binary Logic Diagrams 226 6.1.5 Functional Diagram/Symbols 226 6.1.6 Loop Diagram 229 6.2 Control System - Controller Actions 231 6.2.1 Terminology 231 6.2.2 PID Control 232 6.2.3 Cascade Control 233 6.2.4 Feedforward Control 234 6.2.5 Ratio Control 235 6.2.6 Split Range Control 235 6.2.7 Override Control 236 6.2.8 Block Diagram Basics 236
VIII
6.3 Controller (Loop) Tuning 238 6.3.1 Process Loop Types: Application of P, I, D 238 6.3.2 Tuning Map – Gain (Proportional) & Reset (Integral) 240 6.3.3 Loop Dynamic Response 240 6.3.4 Loop Tuning Parameters 242 6.3.5 Manual Loop Tuning 242 6.3.6 Closed Loop Tuning 243 6.3.7 Open Loop Tuning 244 6.3.8 Tuning Rules of Thumb 246 6.4 Function Block Diagram Reduction Algebra 246 6.4.1 Component Block Diagram 246 6.4.2 Basic Building Block 247 6.4.3 Elementary Block Diagrams 247 6.5 Alarm Management 250 6.5.1 Good Guidelines for Alarm Management 250 6.5.2 Characteristics of Good System Alarms 251 6.5.3 Alarm Terms 251 6.5.4 Alarm Review Methodology 253 6.6 Types of Control System Programming 254 6.6.1 Ladder Diagram 254 6.6.2 Function Block Diagrams 264 6.6.3 Structured Text 268 6.7 Batch Control 272 6.7.1 Automation Pyramid 273 6.7.2 Physical Model 273 6.7.3 Procedural Model 276 6.7.4 Recipes 277 6.7.5 Sequential Function Chart (SFC) 278 6.8 Advanced Control Techniques 279 6.8.1 Fuzzy Logic 279 6.8.2 Model Predictive Control 280 6.8.3 Artificial Neural Networks 280 6.9 Example Process Controls 281 6.9.1 Boiler Control 281 6.9.2 Distillation Column Control 283 6.9.3 Burner Combustion Control 284 7. ISA-95
285
7.1 ISA-95 Hierarchy Model 285 7.2 ISA-88 Physical Model As It Pertains to ISA-95 286 7.3 Levels 4–3 Information Exchange 286
IX
8. HAZARDOUS AREAS AND SAFETY INSTRUMENTED SYSTEMS
287
8.1 Hazardous Areas 287 8.1.1 NEC Articles 500–504 287 8.1.2 NEC Article 505 (Class I, Zone 0, Zone 1 and Zone 2 Locations) 296 8.2 Safety Instrumented Systems (SIS) 299 8.2.1 Safety Integrity Level (SIL) 299 8.2.2 Relationship between a Safety Instrumented Function and Other Functions 300 8.2.3 Definitions 300 8.2.4 Layers of Protection 301 8.3 Determining PFD (Probability of Failure on Demand) 302 8.3.1 Basic Reliability Formulas 303 8.3.2 Architectures 304 9. CODES, STANDARDS AND REGULATIONS
307
9.1 Standards Listings 307 9.1.1 ISA 307 9.1.2 ASME 310 9.1.3 API 311 9.1.4 NFPA 311 9.1.5 IEC 312 9.1.6 CSA 312 9.1.7 UL 312 9.1.8 FM 312 9.1.9 CE 313 9.1.10 ANSI 313 9.1.11 IEEE 313 9.1.12 AICHE (American Institute of Chemical Engineers) 313 9.1.13 OSHA 313 9.2 NEC 315 9.2.1 Allowable Conduit Fill 9.2.2 Wiring Methods 315
315
9.3 NEMA/IEC-IP Enclosure Classifications 328 9.3.1 NEMA Designations (Non-Hazardous) 328 9.3.2 NEMA Designations (Hazardous) 329 9.3.3 IEC-IP (Ingress Protection) 329 9.4 NFPA 70E Electrical Safety in the Workplace: 330 9.4.1 Shock Hazard Analysis 331 9.4.2 Arc Flash Hazard Analysis 333 9.4.3 Protective Clothing Characteristics 334 9.4.4 Personal Electrical Shock Protection Equipment 335 9.4.5 Qualified Personnel 335 9.4.6 Label Requirements 336 9.5 Lightning Protection 336 9.5.1 Lightning Protection (NFPA 780; UL96 & 96A; LPI 17S; IEEE Std 487) 337 9.5.2 Facility Lightning Protection per NFPA 780 337
X
10. SAMPLE PROBLEMS
341
11. SAMPLE PROBLEMS - SOLUTIONS
351
12. MISCELLANEOUS TABLES/INFORMATION
357
12.1 Viscosity Equivalency Nomograph 357 12.2 Copper Resistance Table (Table 12-1) 358 12.3 RTD Resistance Tables 359 12.4 Thermocouple milliVolt Tables 369 12.5 Instrument Air Quality 375 12.6 Thevenin & Norton Equivalencies 376 12.6.1 Thevenin 376 12.6.2 Norton’s Theorem 380 13. UNINTERRUPTIBLE POWER SUPPLY (UPS)
387
13.1 UPS Topologies 387 13.1.1 Single-Conversion 387 13.1.2 Double-Conversion 387 13.2 Inverter Technologies 388 13.2.1 Ferro-resonant 388 13.2.2 PWM (Pulse Width Modulation) 388 13.2.3 Step-Wave 388 13.3 Mechanical Flywheel 388 14. RECOMMENDED RESOURCES
391
XI
PREFACE
The information in this book was prepared so that it can serve a dual purpose. The first purpose is to provide a study aid for the Control Systems Engineering Professional Engineering Exam that is presided over by the NCEES. The second purpose is to provide a technical reference for future use by the instrumentation / automation professional. Where the author cites any references to commercially available products, it is for reference only and is by no means an endorsement by the author of any commercially available product. Sample problems presented in this book are not meant to influence the reader on specific problems that may be on the exam, but rather to reinforce the technical material that has been presented to the reader.
XIII
2. MISCELLANEOUS REVIEW MATERIAL 2.1 MATHEMATICS This section only intends to provide a high-level overview of the various math concentrations, not specific in-depth coverage. 2.1.1 SI Prefixes
The SI prefixes are derived from a Greek, Latin, Italian and Danish names that precedes an SI unit of measure. This name indicates a decade multiplier or divider. Table 2-1. SI Prefixes Prefix
Symbol
Value
Exa
E
1018
Peta
P
1015
Tera
T
1012
Giga
G
109
Mega
M
106
Kilo
k
103
Hecto
h
102
Deca
da
101
Deci
d
10-1
Centi
c
10-2
Milli
m
10-3
Micro
µ
10-6
Nano
n
10-9
Pico
p
10-12
Femto
f
10-15
Atto
a
10-18
cgs units (centimeter, gram, second) mks units (meter, kilogram, second)
2.1.2 Algebra
The part of mathematics in which letters and other symbols are used to represent numbers and quantities in formulae and equations. Quadratic Equations ax 2 + bx + c = 0
−b ± b 2 − 4ac r1, r2 = a( x − r1 )( x − r2 ) = 0 2a
REVIEW MATERIAL – MATHEMATICS
3
The variables r1 and r2 can be real or imaginary depending on the coefficients a, b and c. • If b2–4ac > 0, then there are two different REAL roots. -
This is an indication of an over-damped system.
• If b2–4ac = 0, then there are two identical REAL roots. -
This is an indication of a critically-damped system.
• If b2–4ac < 0, then there are two complex conjugate roots with the following: Real part:
−b 2a
Imaginary part: ± c − b a 2a -
2
This is an indication of an under-damped system.
Exponentiation x a x b = x a +b 1 x −a = a x 1 x a =
( x ) a
b x a
b
a
x
= x ab
= a xb =
( ) a
x
b
Logarithms
If bx = y, then x=log by. Example: If y = 10 x , then x = log10 y OR If ex = y, then x = loge y = ln y log100 = log10 2 log 0.01 = log10 − 2
Constants: loga 1 = 0 loga a = 1
4
REVIEW MATERIAL – MATHEMATICS
Other Identities: logb y a = (a)logb y a a x = b( x log b ) loga y = (logb y )(loga b ) logb xy = logb x + logb y log( x = jy ) = log( x 2 + y 2 ) + j (log e ) × tan−1
y x
Antilog: The antilog function is the inverse of the log function: antilog 2 = 102
antilog− 2 = 0 .01
Matrix Mathematics
A matrix is a rectangular array of numbers. Addition and Subtraction: Matrices MUST be of the same size in order for addition/subtraction to work. 0 1 2 6 5 4 0 + 6 1 + 5 2 + 4 6 6 6 9 8 7 + 3 4 5 = 9 + 3 8 + 4 7 + 5 = 12 12 12 −1 2 0 0 −4 3 −1 − 0 2 − ( −4) 0 − 3 −1 6 −3 0 3 6 − 9 −4 −3 = 0 − 9 3 − ( −4) 6 − ( −3) = −9 7 9 −3 x 4 6 1 7 2y 0 + −3 1 = −5 1 First simplify the left side of the equation:
−3 x 4 6 −3 + 4 x + 6 1 7 2y 0 + −3 1 = 2 y − 3 0 + 1 = −5 1 ∴ x + 6 = 7
so x = 1
and 2y − 3 = −5
so y = −1
Multiplication: Matrix multiplication is not commutative: the order in which matrices are multiplied is important. To multiply matrices, their ranks2 must be compatible. In the matrix example shown below a (2x3) matrix is multiplied by a (3x2). Their product is a (2x2) matrix. To check for rank compatibility simply write the ranks as (M x N) x (N x Q). The matrices may be multiplied together ONLY if the (N) values are equal. If the (N) values are indeed equal then the resultant matrix will have a rank of (M x Q).
2.
Rank of a matrix is defined as, the maximum number of linearly independent column vectors in the matrix, OR the maximum number of linearly independent row vectors in the matrix.
REVIEW MATERIAL – MATHEMATICS
5
Example: Multiply the ROWS of Matrix A by the COLUMNS of Matrix B. 0 3 1 0 −2 = (1 × 0) + (0 × ( −2)) + (( −2) × 0) (1 × 3) + (0 × ( −1)) + (( −2) × 4) = 2 1 × − − 0 3 −1 0 4 (0 × 0) + (3 × ( −2)) + (( −1) × 0) (0 × 3) + (3 × ( −1)) + (( −1) × 4)
Matrix A
Matrix B
(0 + 0 + 0) (3 − 0 − 8) 0 −5 (0 − 6 + 0) (0 − 3 − 4) = −6 −7
Division: There is NO such operation as matrix division. You MUST multiply by a reciprocal. Not all matrices may be inverted because there is no inverse of zero and you cannot divide by zero. 8 3 5 2
w Let A −1 = x
If A =
y
z
8w + 3x 8y + 3z 1 0 = 0 1 5 w 2 x 5 y 2 z + +
Then AA −1 =
The resulting equations
8w + 3 x = 1 8 y + 3z = 0 5w + 2 x = 0
5 y + 2z = 1
Have the solution w=2; x=-5; y=-3; z=8
2
−3
−5
8
∴ A−1 =
2.1.3 Trigonometry
The branch of mathematics dealing with the relations of the sides and angles of triangles and with the relevant functions of any angles. r 180 (360 ) = 2π r π
180 = 57.3 1⋅ radian = π
csc-1 1-sin
B u s e n e t p o H y
c
A
θ
b sinθ =
6
Adjacent
opposite a = hypotenuse c
e t i s o p p O
csc
c o t
sin
t a n
sin θ
1-cos
1-sec
cos
a
sec
C
csc θ =
hypotenuse c 1 = = opposite a sin A
REVIEW MATERIAL – MATHEMATICS
cos θ =
adjacent b = hypotenuse c
sec θ =
hypotenuse c 1 = = adjacent b cos A
tanθ =
opposite a sinA = = adjacent b cos A
cot θ =
adjacent b cos A = = opposite a sin A
Trigonometric Identities sin2 x + cos2 x = 1 1 + tan2 x = sec2 x 1 + cot2 x = csc2 x sin2x = 2sinx • cosx 2tan x 1 − tan2 x cos 2 x = 2cos 2 x − 1 = cos2 x − sin2 x = 1 − 2sin2 x tan2 x =
sin( x + y ) = sin x cos y + cos x sin y sin( x − y ) = sin x cos y − cos x sin y cos( x + y ) = cos x cos y − sin x sin y cos( x − y ) = cos x cos y − sin x sin y 2sin x sin y = cos( x − y ) − cos( x + y ) 2cos x cos y = cos( x − y ) + cos( x + y ) 2sin x cos y = sin( x + y ) + sin( x − y )
2.1.4 Calculus
A form of mathematics that deals with the finding and properties of derivatives and integrals of functions, by methods originally based on the summation of very small differences. The two main types are differential calculus and integral calculus. Differential Calculus
Differentiation is the procedure used to take the derivative of a function. The derivative is a measure of how a function changes as its input changes, as indicated by a tangent line to a curve on the graph (Figure 2-1). For commonly used derivative formulas, reference Table 2-2.
f(x)
f’(x 0 )= Slope of the tangent line x 0
Figure 2-1. Derivative
REVIEW MATERIAL – MATHEMATICS
7
The derivative method is used to compute the rate at which a dependent output y changes with respect to a change in the independent input x. This rate of change is called the derivative of y with respect to x (i.e. the dependence of y upon x means that y is a function of x). If x and y are real numbers, and if the graph of y is plotted against x, the derivative measures the slope of this graph at each point. This functional relationship is often denoted y = ƒ(x), where ƒ denotes the function. The simplest case is when y is a linear function of x, meaning that the graph of y against x is a straight line. In this case, y = ƒ(x) = m x + b, for real numbers m and c, and the slope m is given by: ‘m =
change in y change in x
=
∆y ∆ x
The idea is to compute the rate of change as the limiting value of the ratio of the differences ∆y/∆x as ∆x becomes: dy dx
Differentiation Rules Constant Rule: if ƒ(x) is constant, then f ′ = 0 Sum Rule: for all functions ƒ and g and all real numbers a and b. (af + bg) ′ = af ′ +bg′ Product Rule: for all functions ƒ and g. (fg) ′ = f ′g + fg′ Quotient Rule: for all functions ƒ and g where g ≠ 0. '
f f ' g − fg ' = g 2 g
Power Rule: if f ′(x)=x′′, then f ′(x) = nx(n-1) Chain Rule: If f(x) = h(g(x)), then F ′(x) = h′(g(x)) * g′(x)
Examples: Find
dy 3x + 5 if y= dx 2x − 3
dy 3(2x − 3) − 2(3x + 5) = = dx (2x − 3)2 6x − 9 − 6x − 10 (2x + 3)2
8
=
−19 (2x + 3)2
if y =
4 find y ' at (2,1) x + 2
y ' = 0( x + 2) − 1(4) 2
Find f '(3) if f ( x ) = x − 8 x + 3 f '( x ) = 2 x − 8 f '(3) = (2)(3) − 8 = −2
at (2,1); y ' =
−4 4 1 =− =− 2 (2 + 2) 16 4
REVIEW MATERIAL – MATHEMATICS
Alternate solution to the above example (right): y = 4 ( x + 2)
−1
y ' = −4 ( x + 2 )
−1−1
=
−4
( x + 2)
2
y ' (2,1) ) =
−4
(2 + 2)
2
=−1
4
Table 2-2. Table of Derivatives Power of x d d C=0 x =1 dx dx
d n x = nx ( n −1 ) dx
Exponential / Logarithmic d x d x e = ex b = b x ln(b ) dx dx Trigonometric d sin x = cos x dx d cos x = − sin x dx d tan x = sec 2 x dx
1 d ln( x ) = dx x
d csc x = − csc x cot x dx d sec x = sec x tan x dx d cot x = − csc2 x dx
Inverse Trigonometric 1 −1 d d sin−1 x = csc −1 x = dx dx x 2 − 1 x x 2 − 1 1 −1 d d cos−1 x = sec −1 x = dx dx 1 − x 2 x x 2 − 1 1 −1 d d tan−1 x = cot −1 x = 2 1+ x 1+ x2 dx dx Hyperbolic d sinh x = cosh x dx d cosh x = sinh x dx d tanh x = 1 − tanh2 x dx
d csc hx = − (coth x csc hx ) dx d sec hx = −(tanh x sec hx ) dx d coth x = 1 − coth2 x dx
Integral Calculus
A common application of integration is to find the average value of a function. For a function u, the average value from x = a to x = b is: u=
1 b−a
b
a
udx
It is defined informally to be the net signed area of the region in the xy-plane bounded by the graph of ƒ, the x-axis, and the vertical lines x = a and x = b (Figure 2-2). For commonly used integral formulas, reference Table 2-3. The term integral may also refer to the notion of the antiderivative, a function F whose derivative is the given function ƒ.
REVIEW MATERIAL – MATHEMATICS
9
y = f(x) area
a
=
b
a
f ( x )dx
b
Figure 2-2. Average Value of a Function
Product Rule:
d (uv ) = udv + vdu
Quotient Rule:
u vdu − udv d = v 2 v
Chain Rule:
(u × v )' = (u '× v )v '
Table 2-3. Table of Integrals
f ( x)dx = F( x) + C kf ( x)dx = k f (x)dx kdx = kx + C sin xdx = − cos x + C sec xdx = tan x + C sec x tan xdx = sec x + C 2
tan xdx = − ln cos x + C sec xdx = ln sec x + tan x + C e xdx = e x + C
dx
x
a2 − x 2 dx
= sin−1
x 2 − a2
=
x +C a
[f (x ) ± g (x )]dx = f (x )dx ± g (x )dx x ( n −1) x dx = + C; n ≠ 1 n +1
cos xdx = sin x + C csc dx = − cot x + C csc x cot xdx = − csc x + C n
2
dx = ln x + C x
cot xdx = ln sin x + C csc xdx = −ln sec x + tan x + C a
2
dx 1 x = tan−1 + C 2 +x a a
1 x sec−1 + C a a
Examples:
−8dx = −8x + C 3 x dx = x + C 2
10
3
(6 x 2 + 5 x − 3)dx =
6 x 3 5 x 2 + − 3 x + 2 = 2 x 3 + 2.5 x 2 − 3 x + C 3 2
REVIEW MATERIAL – MATHEMATICS
2.1.6 Differential Equations
A differential equation is a mathematical expression combining a function and one or more of its derivatives. First Order (Linear): A first order differential equation is an equation that contains a first, but no higher, derivative of an unknown function. It can be written as a sum of products of multipliers of the function and its derivatives. If the multipliers are scalar then the differential equation is said to have constant coefficients. If the function or one of its derivatives is raised to some power the equation is said to be non-linear. The form for the first order linear equation is y’ + p(x)y = q(x) where p and q are continuous functions of x. Second Order (Linear): A second order differential equation is an equation that involves the second derivative of an unknown function, but no derivative of a higher order:
y” + p(x)y’ + q(x) = r(x) where p, q and r are continuous functions of x. Homogeneous: The sum of the derivatives terms is equal to zero. Non-Homogeneous: The sum of the derivative terms is equal to non-zero. 2.1.7 Laplace Transforms
The Laplace transform3 is an important tool for solving systems of linear differential equations with constant coefficients. The strategy is to transform the more difficult differential equations into simple algebra problems where solutions are more easily obtained. This book will not attempt to teach Laplace transforms, but rather just provide a table of commonly used transforms (Table 2-4).
2.1.8 Bode Plot A Bode plot (Figure 2-3)4 is a graphical representation of a system, used to evaluate its stability and performance. It is a combination of two graphs (plots) on log (logarithmic) paper and consists of a Bode phase plot and a Bode magnitude (gain) plot. They are both drawn as functions of frequency where each cycle represents a factor of ten in frequency. The Bode magnitude plot is a graph where the frequency is plotted along the x-axis and the resultant gain (represented as decibels – dB) at that frequency is plotted along the y-axis. The Bode phase plot is a graph where the frequency is again plotted along the x-axis and the phase shift of that frequency is plotted along the y-axis. A “passband” is the range of frequencies or wavelengths that can pass through a circuit without being attenuated. A “stopband” is a band of frequencies, between specified limits, through which a circuit does not allow signals to pass. 3. 4.
Named for French mathematical astronomer Pierre-Simon Laplace. Image derived from Wikipedia.
REVIEW MATERIAL – BODE & NYQUIST PLOTS
11
Table 2-4. Laplace Transforms (t)
(t)]
1
1 s
e at
1 s −a
sin at
a s2 + a2
cos at
s s2 + a2
t sin at
2as
( s 2 + a2 ) t cos at
s 2 − a2
(s eat sin bt
2
2
+ a2 )
2
b 2
(s − a) + b2 e at cos bt
s −a 2
(s − a) + b2 t n n! at
e ×
; n ∈ N t n n!
; n ∈ N
1 s n +1 1
(s − a )
n +1
2.1.9 Nyquist Plot
A Nyquist5 plot (Figure 2-4) exhibits a relationship to the Bode plots of the system. If the Bode phase plot is plotted as the angle θ, and the Bode magnitude plot is plotted as the distance r, then the Nyquist plot of a system is the polar representation of the Bode plot.6 Nyquist Stability Criteria
This is a test for system stability. The criteria states that the number of unstable closed-loop poles (zeroes) is equal to the number of unstable open-loop poles (zeroes) plus the number of encirclements of the origin of the Nyquist plot of the complex function D(s) (aka the Argument Principle7).
5. 6. 7.
12
Named after Harry Theodore Nyquist of Bell Labs. Image derived from www.math.uic.edu. Developed by Augustin Louis Cauchy.
REVIEW MATERIAL – BODE & NYQUIST PLOTS
Cutoff Frequency ) B d ( e d u t i n g a M
Slope: –20 dB/decade
Passband
) g e d ( e s a h P
Passband
Stopband
Stopband
Frequency (rad/sec)
Figure 2-3. Bode Plot Imaginary G
(contour) ΓF (s)
F(S) Plane Real G
Figure 2-4. Nyquist Plot
• A feedback control system is stable if, and only if, the contour Γ F(s) in the F(s) plane does not encircle the (-1, 0) point when P (number of poles) is 0 (i.e. the point –(1, 0) is used because that is where a unit circle drawn with its center at the origin (0,0) crosses the realaxis which means that point is -180° from the origin). Therefore, the feedback control system is stable when the unit circle crossing point is at a frequency lower than -180°. • A feedback control system is unstable when the same unit circle crossing point on the real-axis is at a frequency higher than -180°.
REVIEW MATERIAL – BODE & NYQUIST PLOTS
13
2.2 THERMODYNAMICS Thermodynamics is the study of the effects of work, heat, and energy on a system. There are three laws: First Law (Law of Conservation): Energy can be changed from one form to another, but it cannot be created or destroyed. ∆U = Q – W (U = internal energy; Q = heat added to system; W = work done by system). Second Law (Law of Entropy): Energy spontaneously disperses from being localized to becoming spread out if it is not hindered from doing so (i.e., heat is transferred from high temperature to low temperature regions). Third Law: This law is an extension of the second law: as temperature approaches absolute zero, the entropy of a system approaches a constant.
2.2.1 Terminology Exothermic: A type of chemical reaction that releases energy in the form of heat, light, or sound. This type of reaction may occur spontaneously. Endothermic: A type of chemical reaction that must absorb energy in order to proceed. This type of reaction does not occur spontaneously because work must be done in order to get this reaction to occur. Entropy (s): Entropy is a measure of how much heat must be rejected to a lower temperature receiver at a given pressure and temperature (measured in BTU/lbm–°R). Heat Q released by a system into its surroundings is indicated by a negative quantity (Q°<°0); when a system absorbs heat from its surroundings, Q is indicated by a positive value (Q°>°0). An example of this heat rejection is to place a glass of hot liquid into a colder environment, this results in a flow of heat from the glass to the environment’s surrounding atmosphere until an equilibrium is reached. s=
Q T
Q = heat content of the system
T = Temperature of the system (°R)
Enthalpy (h) (inherent heat): Enthalpy is measured in British thermal units per pound (mass), or BTU/lbm, and represents the total energy content of the system (the enthalpy SI unit is J/kg). It expresses the internal energy and flow work, or the total potential energy and kinetic energy contained within a substance. h = U + PV (U = internal energy; P
= pressure; V = volume)
Adiabatic process : A thermodynamic process in which there is no transfer of heat between the process and the surrounding environment. An adiabatic process is generally obtained by surrounding the entire system with a strong insulating material or by carrying out the process so quickly that there is no time for significant heat transfer to take place. Isothermal process : A thermodynamic process in which no temperature change occurs (∆T = 0). Note that heat transfer can occur without causing a change in temperature of the working fluid.
14
REVIEW MATERIAL – THERMODYNAMICS
2.2.2 Heat Addition and Temperature
When heat is added to a material, one of two things will occur: the material will change temperature or the material will change state. When a substance is below the temperature at a given pressure required to change state, the addition of sensible heat will raise the temperature of the substance. Sensible heat applied to a pot of water will raise its temperature until it boils. Once the substance reaches the necessary temperature at a given pressure to change state, the addition of latent heat causes the substance to change state. Adding latent heat to the boiling water does not get the water any hotter, but changes the liquid (water) into a gas (steam). One can state that a certain amount of heat is required to raise the temperature of a substance one degree. This energy is called the specific heat capacity ( ∆Q=mc∆T). The specific heat capacity of a substance depends upon the volume and pressure of the material, except for water, the specific heat capacity is 1 BTU/lbm-°F (1kcal/kg-°C in SI units) and remains constant. This means that if we add 1 BTU of heat to 1 lbm of water, the temperature will rise 1°F. The specific heat value and the specific heat capacity value for water are equal. 2.2.3 Mollier Steam Diagram
A Mollier diagram (Figure 2-5) can be used to determine enthalpy versus entropy of water and steam with the pressure identified on the y-axis in a log scale, and enthalpy identified on the xaxis. Other properties identified on the Mollier diagram are constant temperature, density and entropy lines. The Mollier diagram 8 is useful when analyzing the performance of adiabatic steady-flow processes.9 How To Read A Mollier Diagram Example: Superheated steam at 700psi and 680°F is expanded at constant entropy to 140psi.
1. Locate point 1 at the intersection of the 700psi and 680°F line – then read h (h = 1333 BTU/lbm). 2. Follow the entropy line downward vertically to the 140psi line and read h (h = 1178 BTU/lbm) h = 1178 – 1333 = –155 BTU/lbm. 2.2.4 Psychrometric Chart
A psychrometric chart (Figure 2-6) is graphical representation of the thermodynamic properties of moist air. The chart is used to determine the state of an air-water vapor mixture when at least two properties are known. How to Use a Psychrometric Chart Example: Assume dry bulb temperature = 78°F and wet bulb temperature = 65°F. 8. 9.
Mollier diagrams are named after Richard Mollier, a professor at Dresden University who pioneered the graphical display of the relationship of temperature, pressure, enthalpy, entropy and volume of steam and moist air. Reference www.chemicalogic.com for a blank example of this Mollier Diagram.
REVIEW MATERIAL – THERMODYNAMICS
15
v = specific volume
Entrpoy s=1.0 s=1.1
s=1.2 s=1.3
s=1.4
s=1.5
s=1.6 s=1.7
s=1.8
s=1.9
s=2.0
s=2.1
s=2.2
s=2.3
s=2.4
s=2.5
s=2.6
s=2.7
s=2.8
Figure 2-5. Mollier Diagram (based upon the Scientific IAPWS-95 formulation)
V o S p lu e c i m f ic e Intersection Point
Dewpoint
78°F
Figure 2-6. Psychrometric Chart (Linric Company )
16
REVIEW MATERIAL – THERMODYNAMICS
• First locate 78°F on the DB Temperature Scale at the bottom of the chart. • Then locate 65°F WB on the saturation curve scale. • Extend a vertical line from the 78°F DB point and a diagonal line from the 65°F WB point to intersect the vertical DB line. • The point of intersection of the two lines indicates the condition of the given air. As a result: -
Enthalpy of air = 30 BTU/lb Specific volume of air = 13.7 ft3/lb Dewpoint = 57.5°F
2.2.5 Properties of Water Table 2-5. Properties of Water Specific Temperature Saturation Of Water °F Pressure psia Volume ft3 /lb
Weight Density lb/ft
Weight lb/gal
3
32
0.08859
0.016022
62.414
8.3436
40
0.12163
0.016019
62.426
8.3451
50
0.17796
0.016023
62.410
8.3430
60
0.25611
0.016033
62.371
8.3378
70
0.36292
0.016050
62.305
8.3290
80
0.50683
0.016072
62.220
8.3176
90
0.69813
0.016092
62.116
8.3037
100
0.94924
0.016130
61.996
8.2877
110
1.2750
0.016165
61.862
8.2698
120
1.6927
0.016204
61.7132
8.2498
130
2.2230
0.016247
61.550
8.2280
140
2.8892
0.016293
61.376
8.2048
150
3.7184
0.016343
61.188
8.1797
160
4.7414
0.016395
60.994
8.1537
170
5.9926
0.016451
60.787
8.1260
180
7.5110
0.016510
60.569
8.0969
190
9.340
0.016572
60.343
8.0667
200
11.526
0.016637
60.107
8.0351
210
14.123
0.016705
59.862
8.0024
212
14.696
0.016719
59.812
7.9957
220
17.186
0.016775
59.613
7.9690
240
24.968
0.016926
59.081
7.8979
260
35.427
0.017098
58.517
7.8226
280
49.200
0.017264
57.924
7.7433
300
67.005
0.01745
57.307
7.6608
REVIEW MATERIAL – THERMODYNAMICS
17
350
134.604
0.01799
55.586
7.4308
400
247.259
0.01864
53.684
7.1717
450
422.55
0.01943
51.467
6.8801
500
680.86
0.02043
48.948
6.5433
550
1045.43
0.02176
45.956
6.1434
600
1543.2
0.02364
42.301
5.6548
650
2208.4
0.02674
37.397
4.9993
700
3094.3
0.03662
27.307
3.6505
Saturation Pressure: P = 10
B A− (C +T )
A, B and C are the values of the Antoine constants A, B and C for the temperature T from NIST.
Density: ρ = P/RT (P in Pascal; T in Kelvin) Specific Volume: 1/ρ Linear Interpolation in Tables
Linear interpolation is a convenient way to fill in holes in tabular data. The formula for linear interpolation is: g − g1 ( d2 − d1 ) g g − 2 1
d = d1 +
Example: Find the saturation pressure for water at 575°F.
From Table 2-5: d1 = 1045.43 psia d2 = 1543.2 psia g = 575°F g1 = 550°F f2 = 600°F 575 − 550 (1045.43 − 1543.2 ) = − 550 600
∴ d = 1045.3 +
1045.3 + ( −0.5 ) ( −497.77) = 1045.3 + 248.89 = 1294.19ps ia
2.2.6 Properties of Saturated Steam
Saturated steam occurs when steam and water are in equilibrium. Once the water’s boiling point is reached, the water’s temperature ceases to rise and stays the same until all the water is vaporized. As the water goes from a liquid state to a vapor state it receives energy in the form of “latent heat of vaporization.” As long as there is some liquid water left, the steam’s temperature is the same as the liquid water’s temperature. This type of steam is called saturated steam. Industries normally use saturated steam for heating, cooking, drying and other processes.
18
REVIEW MATERIAL – THERMODYNAMICS
Table 2-6 lists the properties of saturated steam at different pressures. Table 2-6. Properties of Saturated Steam 10 Specific Volume V Pressure psig
Saturated Temperature ºF
0
3
ft /lb
Heat Content BTU/lb
Latent Heat of Vaporization (hfg) BTU/lb
Saturated Liquid (Vf)
Saturated Vapor (Vg)
Saturated Liquid (hf)
Saturated Vapor (hg)
212
0.0167
26.8
180
1150
970
1
215
0.0167
24.3
183
1151
967
2
218
0.0167
23.0
186
1153
965
3
222
0.0168
21.8
190
1154
963
4
224
0.0168
20.7
193
1155
961
5
227
0.0168
19.8
195
1156
959
6
230
0.0168
18.9
198
1157
958
7
232
0.0169
18.1
200
1158
956
8
235
0.0169
17.4
203
1158
955
9
237
0.0169
16.7
205
1159
953
10
239
0.0169
16.1
208
1160
952
11
242
0.0169
15.6
210
1161
950
12
244
0.0170
15.0
212
1161
949
13
246
0.0170
14.5
214
1162
947
14
248
0.0170
14.0
216
1163
946
15
250
0.0170
13.6
218
1164
945
16
252
0.0170
13.2
220
1164
943
17
254
0.0170
12.8
222
1165
942
18
255
0.0170
12.5
224
1165
941
19
257
0.0171
12.1
226
1166
940
20
259
0.0171
11.1
227
1166
939
25
267
0.0171
10.4
236
1169
933
30
274
0.0172
9.4
243
1171
926
35
281
0.0173
8.5
250
1173
923
40
287
0.0173
7.74
256
1175
919
45
292
0.0174
7.14
262
1177
914
50
298
0.0174
6.62
267
1178
911
55
302
0.0175
6.17
272
1179
907
60
307
0.0175
5.79
277
1181
903
65
312
0.0176
5.45
282
1182
900
70
316
0.0176
5.14
286
1183
897
75
320
0.0176
4.87
290
1184
893
80
324
0.0177
4.64
294
1185
890
85
327
0.0177
4.42
298
1186
888
90
331
0.0178
4.24
301
1189
887
95
334
0.0178
4.03
305
1189
884
100 105
338 341
0.0178 0.0179
3.88 3.72
308 312
1190 1191
882 877
110
343
0.0179
3.62
314
1191
877
115
347
0.0180
3.44
318
1192
872
120
350
0.0180
3.34
321
1193
872
REVIEW MATERIAL – THERMODYNAMICS
19
125
353
0.0180
3.21
324
1193
867
130
355
0.0180
3.12
327
1194
867
135
358
0.0181
3.02
329
1194
864
140
361
0.0181
2.92
332
1195
862
145
363
0.0181
2.84
335
1196
860
150
366
0.0182
2.75
337
1196
858
155
368
0.0182
2.67
340
1196
854
160
370
0.0182
2.60
342
1196
854
165
373
0.0183
2.53
345
1197
852
170
375
0.0183
2.47
347
1197
850
175
378
0.0183
2.40
350
1198
848
180 185
380 382
0.0184 0.0184
2.34 2.29
352 355
1198 1199
846 844
190
384
0.0184
2.23
357
1199
842
200
388
0.0185
2.14
361
1199
838
210
392
0.0185
2.05
365
1200
835
220
396
0.0186
1.96
369
1200
831
230
399
0.0186
1.88
373
1201
828
240
403
0.0187
1.81
377
1201
824
250
406
0.0187
1.75
380
1201
821
260
410
0.0188
1.68
384
1201
817
270
413
0.0188
1.63
387
1202
814
280
416
0.0189
1.57
391
1202
811
290
419
0.0190
1.52
394
1202
807
300
421
0.0190
1.47
397
1202
805
2.2.7 Properties of Superheated Steam
As opposed to saturated steam, when all the water is vaporized any subsequent addition of heat will raise the steam’s temperature. Steam heated beyond the saturated steam level is called superheated steam. Superheated steam is used almost exclusively for turbines. Turbines have a number of stages. The exhaust steam from the first stage is directed to a second stage on the same shaft, and so on. This means that saturated steam would get wetter and wetter as it went through the successive stages. This is due to the fact that saturated steam has a greater volume of water in it as the pressure gets lower. Not only would this situation promote water hammer11, but the water particles would cause severe erosion within the turbine. There is a good reason why superheated steam is not as suitable for process heating as is saturated steam. Superheated steam has to cool to saturation temperature before it can condense to release its enthalpy of evaporation. The amount of heat given up by superheated steam as it cools to saturation temperature is relatively small in comparison to its enthalpy of evaporation. Thus, if the steam has a large degree of superheat, it may take a relatively long time to cool, during which time the steam will release very little energy. 10. There are many free online tools available to calculate these values based upon the pressure in psig, www.spiraxsarco.com is just one example of a website that makes one of these calculation tools available free of charge. 11. Water hammer (aka fluid hammer) is a pressure surge that occurs when the fluid in motion is suddenly stopped or forced to change directions abruptly. This pressure wave then propagates throughout the equipment causing noise and vibration.
20
REVIEW MATERIAL – THERMODYNAMICS
Table 2-7 lists the properties of superheated steam at various pressures. Table 2-7. Properties of Superheated Steam 12 Pressure
Sat. Temp psia psig . 15
0.3
Total Temperature ºF 350
400
500
600
700
800
900
1000
1100
1300
1500
213.03 V 31.939 33.963 37.985 41.986 45.978 49.964 53.946 57.926 61.905 69.858 77.807 hg 1216.2 1239.9 1287.3 1335.2 1383.8 1433.2 1483.4 1534.5 1586.5 1693.2 1803.4
20
5.3
227.96 V 23.900 25.428 28.457 31.466 34.465 37.458 40.447 43.435 46.420 52.388 58.352 hg 1215.4 1239.2 1286.9 1334.9 1383.5 1432.9 1483.2 1534.3 1586.3 1693.1 1803.3
30
15.3 250.34 V 15.859 16.892 18.929 20.945 22.951 24.952 26.949 28.943 30.936 34.918 38.896 hg 1213.6 1237.8 1286.0 1334.2 1383.0 1432.5 1482.8 1534.0 1586.1 1692.9 1803.2
40
25.3 267.25 V 11.838 12.624 14.165 15.685 17.195 18.699 20.199 21.697 23.194 26.183 29.168 hg 1211.7 1236.4 1285.0 1333.6 1382.5 1432.1 1482.5 1533.7 1585.8 1692.7 1803.0
50
35.3 281.02 V
9.424 10.062 11.306 12.529 13.741 14.947 16.150 17.350 18.549 20.942 23.332
hg 1209.9 1234.9 1284.1 1332.9 1382.0 1431.7 1482.2 1533.4 1585.6 1692.5 1802.9 60
45.3 292.71 V
7.815
8.354
9.400
10.425 11.438 12.446 13.450 14.452 15.452 17.448 19.441
hg 1208.0 1233.5 1283.2 1332.3 1381.5 1431.3 1481.8 1533.2 1585.3 1692.4 1802.8 70
55.3 302.93 V
6.664 7.133
8.039
8.922
9.793 10.659 11.522 12.382 13.240 14.952 16.661
hg 1206.0 1232.0 1282.2 1331.6 1381.0 1430.9 1481.5 1532.9 1585.1 1692.2 1802.6 80
65.3 312.04 V
5.801 6.218
7.018
7.794
8.560
9.319
10.075 10.829 11.581 13.081 14.577
90
hg 1204.0 1230.5 1281.3 1330.9 1380.5 1430.5 1481.1 1532.6 1584.9 1692.0 1802.5 75.3 320.28 V 5.128 5.505 6.223 6.917 7.600 8.277 8.950 9.621 10.290 11.625 12.956 hg 1202.0 1228.9 1280.3 1330.2 1380.0 1430.1 1480.8 1532.3 1584.6 1691.8 1802.4
100
85.3 327.82 V
4.590
4.935
5.588
6.216
6.833
7.443
8.050
8.655
9.258
10.460 11.659
hg 1199.9 1227.4 1279.3 1329.6 1379.5 1429.7 1480.4 1532.0 1584.4 1691.6 1802.2 120 105.3 341.27 V 3.7815 4.0786 4.6341 5.1637 5.6813 6.1928 6.7006 7.2060 7.7096 8.7130 9.7130 hg 1195.6 1224.1 1277.4 1328.2 1378.4 1428.8 1479.8 1531.4 1583.9 1691.3 1802.0 140 125.3 353.04 V
-
3.4661 3.9526 4.4119 4.8588 5.2995 5.7364 6.1709 6.6036 7.4652 8.3233
hg
-
1220.8 1275.3 1326.8 1377.4 1428.0 1479.1 1530.8 1583.4 1690.9 1801.7
160 145.3 363.55 V
-
3.0060 3.4413 3.8480 4.2420 4.6295 5.0132 5.3945 5.7741 6.5293 7.2811
hg
-
1217.4 1273.3 1325.4 1376.4 1427.2 1478.4 1530.3 1582.9 1690.5 1801.4
180 165.3 373.08 V
-
2.6474 3.0433 3.4093 3.7621 4.1084 4.4508 4.7907 5.1289 5.8014 6.4704
hg
-
1213.8 1271.2 1324.0 1375.3 1426.3 1477.7 1529.7 1582.4 1690.2 1801.2
200 185.3 381.80 V
-
2.3598 2.7247 3.0583 3.3783 3.6915 4.0008 4.3077 4.6128 5.2191 5.8219
hg
-
1210.1 1269.0 1322.6 1374.3 1425.5 1477.0 1529.1 1581.9 1689.8 1800.9
220 205.3 389.88 V
-
2.1240 2.4638 2.7710 3.0642 3.3504 3.6327 3.9125 4.1905 4.7426 5.2913
hg
-
1206.3 1266.9 1321.2 1373.2 1424.7 1476.3 1528.5 1581.4 1689.4 1800.6
240 225.3 397.39 V
-
1.9268 2.2462 2.5316 2.8024 3.0661 3.3259 3.5831 3.8385 4.3456 4.8492
hg
-
1202.4 1264.6 1319.7 1372.1 1423.8 1475.6 1527.9 1580.9 1689.1 1800.4
260 245.3 404.44 V
-
-
2.0619 2.3289 2.5808 2.8256 3.0663 3.3044 3.5408 4.0097 4.4750
hg
-
-
1262.4 1318.2 1371.1 1423.0 1474.9 1527.3 1580.4 1688.7 1800.1
280 265.3 411.07 V
-
-
1.9037 2.1551 2.3909 2.6194 2.8437 3.0655 3.2855 3.7217 4.1543
hg
-
-
1260.0 1316.8 1370.0 1422.1 1474.2 1526.8 1579.9 1688.4 1799.8
300 285.3 417.35 V
-
-
1.7665 2.0044 2.2263 2.4407 2.6509 2.8585 3.0643 3.4721 3.8764
hg
-
-
1257.7 1315.2 1368.9 1421.3 1473.6 1526.2 1579.4 1688.0 1799.6
320 305.3 423.31 V
-
-
1.6462 1.8725 2.0823 2.2843 2.4821 2.6774 2.8708 3.2538 3.6332
hg
-
-
1255.2 1313.7 1367.8 1420.5 1472.9 1525.6 1578.9 1687.6 1799.3
REVIEW MATERIAL – THERMODYNAMICS
21
340 325.3 428.99 V
-
-
1.5399 1.7561 1.9552 2.1463 2.3333 2.5175 2.7000 3.0611 3.4186
hg
-
-
1252.8 1312.2 1366.7 1419.6 1472.2 1525.0 1578.4 1687.3 1799.3
360 345.3 434.41 V
-
-
1.4454 1.6525 1.8421 2.0237 2.2009 2.3755 2.5482 2.8898 3.2279
hg
-
-
1250.3 1310.6 1365.6 1418.7 1471.5 1542.4 1577.9 1686.9 1798.8
380 365.3 439.61 V
-
-
1.3606 1.5598 1.7410 1.9139 2.0825 2.2484 2.4124 2.7366 3.0572
hg
-
-
1247.7 1309.0 1364.5 1417.9 1470.8 1523.8 1577.4 1686.5 1798.5
400 385.3 444.60 V
-
-
1.2841 1.4763 1.6499 1.8151 1.9759 2.1339 2.2901 2.5987 2.9037
hg
-
-
1245.1 1307.4 1363.4 1417.0 1470.1 1523.3 1576.9 1686.2 1798.2
3
V = specific volume, ft /lb h g = total heat of steam, BTU/lb
2.3 STATISTICS Degrees of Freedom (df)
df is the number of values that are free to vary in the final calculation of a statistic: df = n – 1 where n = number of samples. Standard Deviation ( ) is a measure of the spread of the data about the mean value. Reference Figure 2-7 for the normal distribution curve between standard deviations.
σ =
Σ ( x − x ) n −1
2
x = sample value; x = mean value; n = # of samples; n − 1= df
Example: Consider a population consisting of the following values:
2, 4, 4, 4, 5, 5, 7, 9 There are eight data points in total, with a mean (or average) value of 5: 2+ 4+ 4+ 4 +5 +5 +5 +7 +9 8
=
40 8
=5
To calculate the population standard deviation, we compute the difference of each data point from the mean, and square the result: (2 – 5)2 = (–3)2 = 9 (4 – 5)2 = (–1)2 = 1 (4 – 5)2 = (–1)2 = 1
12. There are many free online tools available to calculate these values based upon the pressure and superheat temperature, www.spiraxsarco.com is just one example of a website that makes one of these calculation tools available free of charge.
22
REVIEW MATERIAL – STATISTICS
(4 – 5)2 = (–1)2 = 1 (5 – 5)2 = (–0)2 = 0 (5 – 5)2 = (–0)2 = 0 (7 – 5)2 = (–2)2 = 4 (9 – 5)2 = (–4)2 = 16 Next we average these values and take the square root, which gives the standard deviation: 9 + 1+ 1 + 1 + 0 + 0 + 4 + 16 = 8 −1
32 = 2.138 7
34.1% 34.1%
0.1% –3σ
2.1%
2.1% 13.6% –2σ
–1σ
Mean
13.6% +1σ
+2σ
0.1% +3σ
Figure 2-7. Percentages in Normal Distribution between Standard Deviations
Six Sigma
Six Sigma comes from the notion that if one has six standard deviations between the process mean and the nearest specification limit, there will be practically no items that fail to meet specifications. To achieve Six Sigma, a process must not produce more than 3.4 defects per one million opportunities. 1.5 Sigma Shift
It has been shown that in the long term, processes usually do not perform as well as they do in the short term. As a result of this performance, the number of sigmas that will fit between the process mean and the nearest specification limit is likely to drop over time, as compared to an initial short-term study. To account for this real-life increase in process variation over time, an empirically-based 1.5 sigma shift is introduced into the calculation. According to this concept, a process that fits Six Sigmas between the process mean and the nearest specification limit in a short-term study will, in the long term, only fit 4.5 sigmas. Either the process mean will move over time, or the long-term standard deviation of the process will be greater than that observed in the short term, or possibly both. Therefore, the widely accepted definition of a Six Sigma process is one that produces 3.4 Defective Parts per Million Opportunities (DPMO).
REVIEW MATERIAL – STATISTICS
23
This definition is based on the fact that a process that is normally distributed will have 3.4 defective parts per million beyond a point that is 4.5 standard deviations above or below the mean. So the 3.4 DPMO of a “Six Sigma” process corresponds in fact to 4.5 sigmas, that is, 6 sigmas minus the 1.5 sigma shift introduced to account for long-term variation. This is done to prevent underestimation of the defect levels likely to be encountered in real-life operation. Table 2-8 gives long-term DPMO values corresponding to various short-term sigma levels. Table 2-8. Long-Term DPMO Values Level
DPMO
% Defective
% Yield
1
691,462
69%
31%
2
308,538
31%
69%
3
66,807
6.7%
93.3%
4
6,210
0.62%
99.38%
5
233
0.023%
99.977%
6
3.4
0.00034%
99.99966%
2.4 BOOLEAN LOGIC OPERATIONS13 AND Gate: All inputs must be true for output to be true In1
In2
Out
0
0
0
0
1
0
1
0
0
1
1
1
In1 In2
Out
NAND Gate: All inputs must be false for output to be true In1
In2
Out
0
0
1
0
1
1
1
0
1
1
1
0
In1 In2
Out
13. Developed by George Boole (1815-1864).
24
REVIEW MATERIAL – BOOLEAN LOGIC
OR Gate: Any input can be true for output to be true In1
In2
Out
0
0
0
0
1
1
1
0
1
1
1
1
In1
Out
In2
NOR Gate: If any input is true the output will be false In1
In2
Out
0
0
1
0
1
0
1
0
0
1
1
0
In1
Out
In2
XOR Gate: All the inputs must be different for the output to be true In1
In2
Out
0
0
0
0
1
1
1
0
1
1
1
0
In1
Out
In2
S-R Flip-Flop: Latch Circuit S
R
Q
Q
0
0
Keep output state
Keep output state
0
1
0
1
1
0
1
0
1
1
Unstable condition
Unstable condition
S
NAND
Q
S R
NAND
SET
Q
Q
R
CLR
Q
Equivalent Circuit
REVIEW MATERIAL – BOOLEAN LOGIC
25
2.5 CONVERSION FACTORS Table 2-9. Common Conversion Factors Unit
=
Gallon
8.34
Density of Water
62.4 Lbs/Ft3
Density of Air
0.07649 Lbs/Ft3
SG Water @ 60°F
1
MW of Air
29
SG of Liquid
MW of Liquid ÷ 18.02
SG of Gas
MW of Gas ÷ 29
Unit Lbs Water @ 60°F
Table 2-10. Distance Factors Multiply Inch
By 2.54
To Obtain Centimeter
Centimeter
0.3937
Inch
Foot
0.3048
Meter
3.28083
Foot
Meter
Table 2-11. Volume Factors Multiply
By
To Obtain
Gallon
0.13368
Ft 3
Gallon
0.003754
M3
Gallon
3.7853
Liter
Liter
0.2642
Gallon
Liter
0.03531
Ft3
Liter
0.001
M3
Ft3
7.481
Gallon
Ff3
28.3205
Liter
Ft3
0.028317
M3
M3
35.3147
Ft3
M3
3.28083
Gallon
M3
1000
Liter
Table 2-12. Mass Factors
26
Multiply
By
To Obtain
Pound
0.4536
Kilogram
Kilogram
2.2046
Pound
REVIEW MATERIAL – CONVERSION FACTORS
Table 2-13. Force Factors Multiply
By
To Obtain
Newton
0.22481
Pound-Force
Pound-Force
4.4482
Newton
Table 2-14. Energy Factors Multiply
By
To Obtain
BTU
778.17
Ft-Lbf
BTU
1.055
KJoules
BTU/Hr
0.293
Watt
HP
0.7457
Kilowatt
HP
2545
BTU/Hr
Table 2-15. Temperature Factors Unit
Use Equation
To Obtain
°F
(°F – 32)*1.8
°C
°F
(°F + 459.67)/1.8
°K
°F
(°F + 459.67)
°R
°C
(°C × 1.8) + 32
°F
°C
°C + 273.15
°K
°C
(°C × 1.8) + 32 + 459.67
°R
°K
(°K × 1.8) – 459.67
°F
°K
°K - 273.15
°C
°K
°K × 1.8
°R
°R
°R – 459.67
°F
°R
(°R – 32 – 459.67)/1.8
°C
°R
°R/1.8
°K
REVIEW MATERIAL – CONVERSION FACTORS
27
Table 2-16. Pressure Factors Multiply
By
To Obtain
Atmosphere
1.01295
Bar
Atmosphere
29.9213
Inches Hg
Atmosphere
760
mm Hg
Atmosphere
406.86
Inches WC *
Atmosphere
14.696
PSI
Atmosphere
1.01295 x 105
N/M2 or Pa
Bar
0.9872
Atm
Bar
29.54
Inches Hg
Bar
750.2838
mm Hg
Bar
401.65
Inches WC
Inches WC
0.03612
PSI
Inches WC
0.07354
Inches Hg
Inches WC
1868.1
mm Hg
Inches WC
248.9
N/M2 or Pa
Inches WC
0.001868
Micron or mtorr
PSI
27.68
Inches WC
PSI
2.036
Inches Hg
PSI
51.71
mm Hg
PSI
0.068046
Atm
PSI
0.068948
Bar
PSI
6892.7
N/M2 or Pa
Micron or mtorr
0.0005353
Inches WC
N/M2 or Pa
0.004018
Inches WC
N/M2 or Pa
0.00014508
PSI
* WC indicates water column
Table 2-17. Viscosity Multiply
By
To Obtain
cSt
0.999g/cm3
cP
cP
1/0.999g/cm3
cSt
Kinematic viscosity (stoke) = Absolute viscosity (poise)/S.G. Dynamic viscosity (cP) = 0.001 Pa-s
28
REVIEW MATERIAL – CONVERSION FACTORS
2.6 EQUATIONS /LAWS /FORMULAS Pressure P =
F A
F = Force applied A = Area Boyle’s Law PV 1 1 = P2V2
Boyle’s law states that at constant temperature , the absolute pressure and the volume of a gas are inversely proportional. The law can also be stated in a slightly different manner: that the product of absolute pressure and volume is always constant. P = Pressure in PSIA V = Volume in Ft 3 Charles’s Law V1 T1
=
V 2 T 2
OR V1T2 = V2T1
These expressions may be combined into the form of PV/T = constant for a fixed mass of gas. Charles’s law states that at constant pressure , the volume of a given mass of an ideal gas increases or decreases by the same factor as its temperature on the absolute temperature scale (i.e., the gas expands as the temperature increases, the temperature is the average of molecular motion, therefore, the molecular motion will increase with a corresponding temperature increase, thus causing the gas to expand.). T = Temperature in °R (Note the absolute temperature scale) V = Volume in Ft 3 Gay-Lussac's Law P 1 T 1
=
P 2 T 2
OR
PT 1 2 = P2T1
The pressure of a fixed mass and fixed volume of a gas is directly proportional to the gas's temperature. T = Temperature in °R P = Pressure in PSIA
REVIEW MATERIAL – EQUATIONS /LAWS
29
Ideal Gas Law (for compressible fluids) PV = RT
R = Gas Constant (Value = 1544/MW) P = Pressure in PSIA V = Volume in Ft 3 T = Temperature in °R MW = Molecular Weight Pascal’s Law
Pascal’s Law states that a change in the pressure of an enclosed incompressible fluid is conveyed undiminished to every part of the fluid and to the surfaces of its container. Note: this is the principle used in the pressure factor table (Table 2-16) to convert between pressure and inches-WC, mm Hg, etc.
∆ P = ρ g (∆h) ∆P = Hydrostatic pressure ρ = Mass density
g= Gravitation constant ∆h = Difference in elevation between the two points within the fluid column Bernoulli’s Equation
The Bernoulli equation states that as the speed of a moving fluid increases, the pressure within the fluid decreases: PV 1 1 T1
=
P2V2 T 2
P + ½ ρv2 + ρgh = Constant P = Pressure in PSIA ρ = Mass Density g = Gravitation constant h = Height above reference level v = Velocity This form of the Bernoulli equation ignores viscous effects. If the flow rate is high, or the flowing material has a very low viscosity, Bernoulli’s equation should not be used. For example, liquid flowing in a pipe may be more accurately described with Poiseuille’s equation14 to account for flow rate, viscosity and pipe diameter. Poiseuille’s equation states:
14. Also known as the Hagen-Poiseuille Law that states that the volume flow of an incompressible fluid through a circular tube is equal to π/8 times the pressure differences between the ends of the tube, times the fourth power of the tube's radius divided by the product of the tube's length and the dynamic viscosity of the fluid.
30
REVIEW MATERIAL – EQUATIONS /LAWS
∆Pπ r 4 Q= 8 µ
Q = Volumetric flow rate, in3/sec = Tube length, inches r = Tube radius, inches µ = Viscosity, lb•sec/in2 Volumetric Flow Rate Q = AV
Q(gpm) = 3.12 A(sq in) x V(ft/sec)
Q = Volumetric Flow Rate A = Cross Sectional Area of the Pipe V = Velocity of the Fluid Darcy’s Formula (general formula for pressure drop) h=
fLV 2 2Dg
h = Pressure drop in feet of fluid L = Length of pipe (feet) V = Velocity of the fluid (ft/sec) g = Acceleration of gravity (32.2 ft/sec2) D = Pipe ID (feet) f = The Darcy-Weisbach friction factor f = 16 ÷ Re (Re = Reynolds Number) Velocity of Exiting Fluid
h A
V=
2gh
Q = A 2gh
V = Velocity of the fluid (ft/sec) g = Gravitation constant (32.2 ft/sec2) h = Height above reference level (in feet) A = Area of opening (in sq ft) (the smaller the area, the greater the fluid velocity) Q = Volumetric flow rate (ft3/sec) Convert Actual Cubic Feet per Minute (ACFM) to Standard Cubic Feet per Minute (SCFM) 14.7
ACFM = SCFM
P a
×
519.67 T a
REVIEW MATERIAL – EQUATIONS /LAWS
equivalent to
P 1V 1 T 1
=
P 2V 2 T 2
31
Pa = Actual pressure (PSIA) Ts = Standard temperature (519.67°R) NOTE: °R =60°F+459.67 (convert from °F to °R) Ta = Actual temperature (°R) Joule-Thomson (Kelvin) Effect/Coefficient
When the pressure of a non-ideal (real) gas changes from high to low (such as through a valve), a change of temperature occurs, proportional to the pressure difference across the restriction. The Joule-Thomson coefficient (µ JT) is the change of temperature per unit change of pressure. The rate of change of temperature T with respect to pressure P in a Joule-Thomson process (that is, at constant enthalpy H) is the Joule-Thomson (Kelvin) coefficient. This coefficient can be expressed in terms of the gas's volume V, its heat capacity at constant pressure Cp, and its coefficient of thermal expansion α as: V ∂T = (α T − 1) ∂P H C P
µJT ≡
Where: V = Volume of gas Cp = The gas’ heat capacity at constant pressure α = The gas’ coefficient of thermal expansion H = Enthalpy constant ∂ T = Rate of change of temperature ∂ P = Rate of change of pressure The value of µ JT is typically expressed in °C/bar (SI units: °K/Pa) Table 2-18 defines when the Joule-Thomson effect cools or warms a real gas: Table 2-18. Joule-Thomson Effect µJT is:
Gas Temperature
sign of
P
sign of T
The gas
< Inversion Temperature (1)
Positive
Negative (2)
Negative
COOLS
> Inversion Temperature (1)
Negative
Negative (2)
Positive
WARMS
(1) Inversion Temperature: The critical temperature below which a non-ideal (real) gas that is expanded (with a constant enthalpy) will experience a temperature decrease. (2) When a gas expands the pressure is always lower; therefore ∂ P is always negative.
Mass Flow – Gas Equations
Substitute Q for V/t: w =
32
m t
=
V p 103 R t T M
Substitute for Q: w =
MQ p 103 R T
Q = k D ; k =
Mk f 103 R
REVIEW MATERIAL – EQUATIONS /LAWS