Ceton Beilstein,E IV Z (f950-9) 687-B Susie , AIfred G " USPat 2233823'' CL.2 60 : 566 , Process for Ceton oxim of Arylnitroalkenes, the Reduction Potapov, V.M. " Journal of General Chemistry of the USSR" 28(1958 )3349-53, IV, Schiff BenzyLetylami bases from optical active Leake,W.!{. " J.Am. Soc. " B1( 1959 ) 1169-72 L e v i n e , R . " J . A m . S oc . " 6 6 ( 1 9 4 9 ) 1 7 6 8 - 7 0 Smith, G. G. " J. Am.Soc ." 75 ( 1953 ) 1L34,-7 Tegn6r, C. "Acta Chemica Scandinavica" 6 ( 1952 )782-90 ,789 King,J.A. et al "J.Am.Soc."73( 195I)49II-5,4 Zettlemoyer,A.C. of Ketones "USPat 2612524"CI.264: 590 Preparation by dehydrocarboxylation Acids of Carboxyfic Beilstein, E III 7 (L930 -49 ) 1037-9 Walker, H. G. " J.Am. Soc. " 6B( 1946 ) f386-B Stoermer, " Ber. " 6B( f93 5 )2IL2-6 Ku.ki-ta, S. "C.A ." 42(7948 )6339 N e w m a n , M .S . " J . A m . S o c . " 6 7 ( L 9 4 5 ) 1 5 4 M a s o n , J . P . " J . A m . S oc . ' 6 2 ( L 9 4 0 ) 1 6 2 2 Whitmore, F.C. " J.Am. Soc. " 64 (f942 )2968-70 Hurd, C.D. " J.Am. Soc. " 5B( 1936 )1240 Beilstein, H Z (-1909)303-4 Beckh,W. "Ber. "31(1898 )3f 60-4 Metzner,H. " A."298 ( 1897 )374-90 Popoff,A. "Ber. " 5 ( fB72)500-2 L u d l a m , E . B . " S o c . " Bl , 1 1 8 5 - 9 3 , 1 1 8 6 Apitzch, "Ber. " 38 ,288-99 Acrylsyra Beil-stein, H 9, 542-3 Kipping, " Soc. " 83, 913-B Conrad,M. "A. " 204 ( 1880 ) 17 4-6 Ehrlich, F. L. "a. " t!Z( 1879 )13-30 Conrad,M. " A." 192 (1878 )153-60 C o n r a d , l t 4 a x , " B e r . " 1 1 ( 1 B 7 B) 1 0 5 5 - B Kipping, F. S. " J.Am. Soc. " B3( 1903 ) f005- 10 Beilstein, E II 2 ,357-B Jones, L.W. " J.Am. Soc. " 4B( L926 ) 169-81 Lapworth,A. "Procedj-ngs of the Chemical Soc. , London" 1B(1903 )35-6 Beilstein, E III 2 ,2472-5 Holden, " soc. " ( 1931 )2368-75 Dean, F.M. " Soc. " ( L948 )L674-7 Flisik,A.C. " U S P a t . 2 4 1 3 4 9 3 " C 1 . 2 6 0 z4 7 6 Beilstein, E III 9 ,27 64-5 Beilstein, E rI {, 409Beilstein, E I 2 , 255-6 Beilstein, H 9 , 615-6 Charles,M. " Soc." 43 ,403-9 ,406 Perkin,W.H. "Ber. " 10 ,299-300 Perkin,W.H."Soc."3T rB77 )3BB-427,660 Fittig, " A."227 (IBB5 )53-61 Posn€r, "eer.' 36, 4305- 1B Erdman, " A. " 227 ( lBBO )247 - 6I Posn€r, " Journal- fur Praktische Chemie" Nr .2 ,32 ( L9 10 ) 425-40 Stoermer, "A. " 409,36-58, 50, 358
2 -Chlor-
1 -pheny]. -propan
E rV 5,980Beilstein, ,E rrr q ,871, H q L . S o c . Schmerlj-ng, " J.Am. " 80 ( 1958 )57 6-9 N e n r t z e s c u , Costin,D. "Ber ." 66, 1100-3 Nazarova, Z. N. "C.A. " 39 ( 1945 )916
,39I
Nitro E IV 9,1360-1, Beilstein, H q ,483 B altimore'' 1B( 1953 ) 1-3 Gairaud,C.B. " J.Org.Chem. Boberg, "Ber. " 90 ( 1957 )1215-29, I22I Knoevenagel , E. " Ber ." 37 ( 190 4 ) 45 02 - 10 Erdman, Hugo" Ber ." 24,27 7 L-5 Amphetamin Beilstein,
E III
12 ,2664- 8, E II
12 ,62I-3
,E I
L2 ,493-4 ,H 12 ,LL45
Amider
,
Hofmann,Albert Wissenschaft"
Sandoz-Zeitschrift "Triangel Bd. II( 1956)Nr.3, 117-24
fur
Medizrnische
Azidfdrfarande Stoll,A. Hofmann,A. "Helv ."26(1943 )944-65 Stoll,A. Hofmann,A. "USPat.2438259" (L948 )Appf . ( 1944) StoIl-,A. Hofmann,A. "Z.physiol.Ch ."251( 1938 )155-63 Ainsworth, C. " USPat .2756235" ( 1956 )Appl . ( 1954 ) Sto1I,A. Hofmann,A. "Helv. "38 ( 1958)42 1-33 Hofmantr,A. Troxler, F. "USPat.3085092" (1963 )AppI. ( 1960 ) Hofmantr,A. Rutschmann, J. " LISPat.3239 530" ( 1966 ) Hofmantr,A. TroxIer, F. "USPat33465B0" (1967 ) M a g d , E . e t a l " U S P a t . 3 8 2 2 2 6 8 " ( 1 9 74 ) f o r f a r a n d e en1 . Briti sh Pat . 480822 Spaltning Stoll,A. Stol-f ,A.
med Hydrazin et al "Helv. "33( 1950 )56-67 Hofmann,A. "He1v"26(1943 )922-B
Blandanhydrid-kopl
ing s f6r f arandet
Tri fluoriittikssyra Pioch,R. P. "USPat.27367 28" ( f 956 ) S t a d 1 e r , P . " U S P a t . 3 8 4 6 4 3 3 " ( 1 9 74 ) Svaveltrioxid Garbrecht,W. L. " J. Org.Chem ."24 ( Kenner, G. W. Stedmail , R. J. " Soc. " G a r b r e c h t , W . L . " U S P a t . 2 7 ' 74 7 6 3 " ( Garbrecht,W. L. "BDRPat.1040560"
1959 )3 68-72 ( 1952 )2069 -7 6 1956 ) ( 1956 )
Halogenider Frey, A. " USPat.30B4L64" ( 1963 ) Griot,R. Frey,A. "USPat.32B0129" (1966) Frey, A. " Frans . Pat . 1308758 " HofmanD, A. Frey, A. J. Ott, H. " Experientia" 17 (196L)206-7 Schlientz,W. et al "Helv ." 47( 1964)192I-33 Sas,I. " Ital-. Pat .67278" ( I979 ) Karbodiimider
C e r n y , A . S e m o n s k y, M . " C o l l e c t i o n C z e c h o s l o v . C h e m .C o m m u .n" 27(L962 ) 1sB5-92 P a u l , R . A n d e r s o n , G . W ." J . A m . S o c . " B 2 ( L 9 6 0 ) 4 5 9 6 - 6 0 0
PhosgenePatel1i,
dimethyl B.
formamide
Bernardi,
complex
L. " USPat.3141BB7 " ( 1964 )
Elymoclavine Choong, T. Shough, R. " Tetrahedron Nr. 19 ( 1977 )L627 -B Analogi
Letters"
University
of
Utah
fdrfarande
Mago, E. Mago,E.
et et
al " Sv. Pat .42L424" ( 198 1 ) aI"USPat.3904633" ( 1975)
Syra Jacobs,W.A. Craig, L.C. "The Journal of 104,Nr.3(f934)547-5I Smj-th, S. Tj-mmis,G.M. " Soc. " ( 1934)67 4-5 S t o l l - , A . e t a l " H e . l - v. " 2 6 ( 1 9 4 3 ) 1 6 0 2 - 1 3 L a i b a c h , R . R . " B D R . P a t . 2 6 I 0 8 5 9 ' ' ( L 9 76 ) Smith, S. Timmis, G. " Soc. " ( 1936 )I440-4
Biological
Chemistry"
Extraktion Kocjan, "DDRPat.9I665" ( L972) Sttlt Z, P. " Experient a" 29 ( I97 3 )93 6-l Czechosl-ovak Cerny , A. et al " Collecti-on 4r(1976)3415-9
C h e m j - c a l C o m m u n ."
Totalsyntes Kornfeld,E.C. "USPat.27964 19" ( L951 ) OppoLzer,W. et al- "Helv." 64, Fasc.2(1981
)Nr. 47,478-81
Ergolines Spalla,C. et aI " Folia Microbiot .u23(IglB )505-8 A hypothei= mechanisms govering the biosynthesis on the regulation pur. in Claviceps of Alkaloids Corbett, K. et al " J. Gen.Microb. " 90 (I97 5 )55-68 Metabol j-sm of the germinating scl-erotium of Cl-aviceps pur. l1 (I97O )2IL-44 Kelleher,W. J. "Advances in Apptied Microbiolgy" Ergot Alkaloid Fermentations Society SpalIa, C. " Annual Procedj-ngs of the Phytochemical of Europe Production Nr.17 , (1980 )27I-84 of Ergot Alkaloids by Fermentaton Production Taber,W.A. " Lloydia"30 (L967 )39-66 Fermentative Indole Compounds of Hallucinogenic Preparation Abe,M. Yamatodani, S. " Prog.Ind.Microbiol. " 5 (1964)203-29 E r g o t F u n g u s S a p r o p h y t i c o f A l k a l o i d s b y C u l t u r e of Arcamone,F. of the Royal Society of London, et al- "Proceedings Series B-Biological Sciences" 8155 (1,96I)26-54 Production in submerged of a new Lysergic acid derivative papsaljculture by a strain of Claviceps Taber,W.A. Vining, L.C. "Canadj,an Journal of Mj-crobiology"4 (1958 ) production 6LL-26 The influence factors on the in vitro of certain of Ergot alkaloids by CIavj-ceps purpurea Arcamone,F. Production et al "Nature"187(1960)238-9 of Lysergic Acid derivatives by a strain Clavi-ceps papsali Abe,M. " Journal Chemical Society of the Agricultural of Japan" 25(1952 )458 A preliminary report on a new water-solubl-e Ergot Alkaloid Elymocl-avine StoIl,A. et al "USPat.2809920"USCl.195:81 Process for the preparation of Ergotamine, Ergtaminine and Ergometrine by saprophytic culture of Ergot in vitro Abe,M."JournalChemical- Society of the Agricul-tural of Japan" 45 ( 197I )6- 10 Production of Al-kal-oids and Related Substances by Fungi McCred, A. " Amer. Journ. Botany. " 18 ( 1931 ) 50-7 8 The reactions of purpurea Claviceps to variations of environment Stager, Rob " Mykolog. Cental-bl . " 1 ( 1912 ) 19I - 20I Inf ectionsversuche mit uberwinterten Claviceps Conidien Engelk€, C. " Hedwigia ( Beiblatt ) " 5 1 ( 1902 )22L-2 Neue Beobachtung purpurea uber die Vegetationsformen Claviceps des Mutterkornpilzes Falck,R. "Pharm.Ztg. " 67 (1922 )Nr.73,777-9 Nr.74,786-7 Nr.75,80L-2 Nr.77,825-6 Nr.79,850-1 uber die Bekampfung und die kultur des Mutterkorn im Roggenfelde Heck€, L. " Schweizer Apother .Ztg. "Nr.4(1922 )45-51 Die Kultur des Mutterkornes Bdkdsy, N. " Ztbl. f .Bakt. Parasittenk. " IIAbt. ( 1938 )32I-32 E n g e 1 k e , E . " J a h r e s b e r . N a t u r h i s t . G e s . H a n n o v e r " 5 0 - 5 4 ( 1 90 5 ) 7 0 - 2 uber neue Beobachtungen uber die Vegetationsformen des Mutterkonpi Meyer, B. " Landwi-rtsch. Jahrbucher" I'7( lBBB )924-30 Die kunstliche Kultur der Sphacaelia- Sporen und das Vorkommen und die Keimdauer derselben in der Natur Bref eld, O. " Untersuchung aus dem Gesamtgebiete der Mykologi-e" ( 1BB9)16-7 Heft IV,Munster i W . ( 1 B B 1) 1 - 3 5 , 1 3 6 - 7 , H e f t VIII Heft x (1891)192-3
Ergolines Ernst Gdumann "Pf]-anzliche Infektionslehre" Lehrbuch der pflanzenpathologie allgemeinen ftir Biologen, Landwirte und P f l a n z e n z u c h t e r . V e r f a g B i r k h a u s e r , B a s e l ( 19 4 6 ) 7 - I 0 , 9 B- 1 00 Bekdsy, N. "Biochem .2." 302 ( 1939 )187 -97 Untersuchungen uber den Atkaloidgehalt des Mutterkornes Bekdsy, N. "Biochem .2." 303 (L940 )368-82 Untersuchungen uber den Alkaloidgehalt des Mutterkornes Blazek,Z. et al- "Pharmazle"S(1953)592-5 Uber die Menge und j-m Sl(Ierotium Verteilung der Alkaloide von Cl-aviceps purpurea Michener, H. David, Snell, N. " Amer. Journ.Botany " 37 ( f950 ) 52-9 Studies on Cultural purpurea Requirements of Claviceps and Inactivation of Ergotamine Rochelmeyer, H. "Dtsch.Apoth-Z'tg. " 94(L954 )L-4 Die biologische Synthese von Mutterkornalkaloj-de und ihre Bedeutung fUr die galenische Pharmaz:-e Hecht , W. " Pharmazie" 6 ( 195 L )29 L-6 Ertragsund Gehaltsschwankungen purpuiea bei Claviceps Tulasn. Hecht,M. Hecht,W" " Pharmaz:-e"9 (1955 )424-9 Vergleichende Untersuchungen uber Physiologie und Chemie von Leukosklerotien bei Mutterkorn Rieder,H. P. B6hmer,M. "Helv. "43 (1960)638-44 Zur Spez:_fitat der modi f:-z:-erten Kell-er-Reaktion Rieder, H. P. Bohmer, M. " Experienta" 14 ( 195B )463 -5 Zur kenntnis der Keller-Reaktion und ihre Anwendung zur spektophotometrischen bestimmung von Indolen R u r r ' . p e,I W . " P h a r m a z i e " 1 0 ( 1 9 5 5 ) 2 0 4 - 6 E i n f a c h e s e r i e n m i i s s i g e j-en des Mutterkorns Bestimmung des Alkaloidwertes von Ein zelsklerot Yamatodani, S. "Annual Report of the Takeda Research Laboratories" 19 ( 1960 )B-11 Studies on the Color Reaction of Ergot Alkaloids Reichelt, J. Kurdrndc" Journal of Chromatography"BT (7973)433-6 Analytical studies on Ergot al-kaloids and their derivatives Separatj-on of Ergot alkaloids of the Ergotoxine and Ergotamine groups by Thin- l-ayer Chromatography Mclaughlin, J. L. et al" Journal of Pharmaceutical Sciences Washington D.C. " 53 (1964 )306-10 Thin-layer Chromatography of Ergot R d d e r , K . e t a l - " P h a r m a c e u t i c a l A c t a H e l - v e t i a e " 4 2 ( L 9 6 7 ) 4 0 7- 2 2 Uber die quantitative bestimmung der mutterkornalkaloide nach dunns chi chtchromatographischer trennung Esser,K. Tudzynski, P. "Theor.Appl-.Genet. "53 ( 1978) 145-9 Genetics of the Ergot fungus SpaI1a,C. Marnati,M. P. "Antibiotics and other Secondary Metabolites (L978)Eds. Hutter,R. et aL"2I9-32 Genetics Aspects of the Formation of Ergot AIkaloids Kobel,H. Sanglier, J. J. "Antibiotics and other Secondary Metabolites (197 8 )Eds.Hutter, et aL"233-42 Formati-on of Ergotoxine Atkaloids by Fermentation and Atempts to Control Biosynthesis their Bulock , J "D. Barr, J. G. " Biotechnol. Lett . " Nr .6 ,!(1979 )261-5 The Effects of maintained Tryptophan levels on Ergot Alkaloids Production and overall Tryptophan Economy in Claviceps pur.
Ergolines Part j-e Botanique" Tulasn€,M. L. -R"Annales des Sciences Naturelles III. Sdr. Tome XX( 1853 )5-56 Planches L-4 , Lergot des Glumacees The Host-Parasite Bove, F. J. "The Story of Ergot" ( 1970 )Ref.60-61 Relatj-onship 83-6 The Laboratory 72-3 The Field Cultj-vation Cultivation IB7 -90 The Chemistry 2I0-L4 The Biosynthesis 229-33 The Chemical Assay Aj1, S. J. Toxj-ns"Eds.Kadis, S. Ciegler,A. GrOger,D. "Microbial 12,Ergot VoI. VIII( I972)32L-'73,Chapter Hofmano, A. " Deutsche Apot-Ztg. " Nr.2 2 ,I05 ( 1965 ) 7 11-3 Neuere Entwicklung auf dem Gebi-et der Mutterkornal-kal-oide Mulle,M. CI2P I7/00, C07D 5L9/02 et al "DDRPat.146620" Int.Cl. Verfahren zur Isolierung von Mutterkornalkaloide aus Trockenmycel -Adsorb . - Gemi s ch L2 /00 , CI2P L /00 Grawert,W. "DDRPat.138223" Int.Cl.CL2D Verfahren zur Isolierung von Mutterkornalkalo-ide aus Kultursuspens Marderosian , Ara Der " Lloydia" 30 ( 1967 )3 5-42 The Distribution Among Ceartin Species and Varieties of Indole Alkaloids of Ipomoea Rivea and Convolvulus Barger, G. " Ergot and Ergotism" London ( 193 1 )23L-7 4 Bibliography and Index of Authors Tschirch, " Handbuch der Pharmakognosie" Le rpzrg ( 192L-23 )Band I I I Lieferung 1 , 157-9, Secale Corntum Nr. 50, 49 (L936) 1513-7 Wochenschrift" StolI,i\. "Wiener Klinische Nr.51 , 1552-6 , Die Alkal-oide des Mutterkorns Stol-l,A. "Experientia" I (L945)250-62 Les alcaloides de lergot ( 1949 ) 5 L7 -39 Ergot Alkaloids Anderson, H. " The Plant AIkaloids" Foster,G.E. et al "Journal of Pharmacy and Pharmacology,London" Tire Assay of Ergot and j-ts preparations 7 (1955 ) 1- 15 Review Article, ( 1964 ) I-Vii Hofmano, A. "Dj-e Mutteralkaloide" Stuttgart Vorwort Floss, H. G. " Tetrahedron" 32 (L97 6 )873-912 Biosynthesis of Ergotalkaloids Compounds and related Kozikowski,A. P . " H e t r o c y c l e s ' ' 1 6 ( 1 9 8 1 -) N r . 2 , 2 6 7 - 9 L Synthesis indoles of 4-substituted and elaboration to the Ergot alkaloids S t o l l , A . " H e l v . C h i - m .A c t a " 2 8 ( 1 9 4 5 ) 1 2 8 3 - 1 3 0 8 , 1 0 . M i t t e l . E r g o t a m i n Tanret,M. "C.r "Acad" Sci. " B6( 1878 )888-90 Sur lergotinine alcali du seigfe ergot€ Tanret,M. "C.r.Acad.Sci. Sur la presence "B1( 1875 )896-7, dun nouvel alcaloide lergotinine Keller,C.C. Wochenschrift fur Chemie und Pharmacie" " Schwerzerische XXXIV( 1896 )Nr. B , 65-7 4 Neue studien S ecale cornutum uber Kraft, F. "Archiv der Pharmazre"244 ( 1906 )33 6-59 Uber das Mutterkorn Keller, C. C. " Schwelzerische Wochenschrift fur Chemie und Pharmacie XXXII ( 1894 )Nr .L2 ,12I-36 Mitteilungen uber die Wertbestimmung Barger,G. Carr, F.H. " Journal of the Chemical Society"9l( 1907 )337 -53 XXXVII-The AIkaloids of Ergot Stol-1,A. Burckhardt,E. "C.r.Acad. Sci. "200 ( 1935 )1680-2 lergobasine nouvel alcaloide de lergot Smith, S. Timmis,G.M. "Journal of the Chemical Society, London" ( 1936 ) 1L66-9 The Alkaloids of Ergot , Part VI, Ergometrinine Dudl€y,H.hl. " Pharmaceutical Journal, London" ( 1935 ) 709The preparation E r g o m e t r i n e of Smith, S. Timmis, G.M. " J.Chem. Soc. London" ( 1937 )396-401 The Al-kaloids of Erqot
Ergolines Stol-1 , A. Hofmann , A. " HeIv. Chim. Act a" 2 6 ( 1943 ) f 570- 1601 Die Alkaloide der Ergotoxingruppe Kobel ,H. et al "Hel-v."47(1964 )1052-64 Ein neues Ergolinderivat Mary, N. Y. " Lloydia " 28 ( 1965 )2I8-29 Production of Lysergic Acid Derivatives in Submerged Culture Ami-ci,A.M. "Experient ia"22 (1966 )4I5-6 Production of Ergotamine purpurea by a Strain of Claviceps Arcamone, F. et al "Canadian Journal- of Microbiology" 16 (L97 0 )923-3L Ergotamine production and metabolism of Clavi-ceps purpurea Chaifl ,E.B. "Osterr. Pat .239966"K1. 30L,2 Verfahren zuT biosynthetisch Herstellung von Lysergsdure-Abk6mmlingen Chain , E. B. " 0sterr. Pat .251198 " Kl .3 0I ,2 Int . Ct . C 07 d Verfharen zur biosynthetischen herstellung eines neuen D-Lysergsyr Bekdsy, N. " PharmazLe" l l ( 1956 )339-50 uber die technischen und agrotechnischen fragen der Mutterkornkultur Kirchoff, Heinrich" Zentralbl I I " . Bakt . Parasit . Infektionskrankh. Abt .77 (L929 )310-69 Beitrage zur Biologie und Physiologie des Mutte StolI,A. Brack,A. " Pharm.Acta.Helv. " 19 (1944)LIB-23 Zum feldmassigen Anbau von Mutterkorn Brack,A. "Ber. Schweiz.Botan.Ges. " 54 (L944)252-4 Stoll,A. uber die Entstehung von Skleroti-en des Mutterkornpilz es an den obersten purpurea ) Halmknoten des Rogens ( Claviceps Hecht,W. " Pharm.Acta.HeIv. " 19 (1944 ) 1L2-B Zur frage des feldmeissigen Anbaues von Mutterkorn Bekdsy,M. "Acta Agronomica" 2(1952)I25-30 Die landwirtschaftlichen probleme der parasitischen und industriellen Mutterkornkultur Freudenberg-Rosendahl, G. " Pharmazie" 8 ( f953 )4 16-2L Feldversuche zur Mutterkorngewinnung H e c h t , W" " O e s t e r r . A p o t h e k e r . Z t g . " 9 ( 1 9 5 5 ) 7 5 - 9 u b e r M u t t e r k o r n z u c h t u n Fuchs, L. " Scientia Pharm. " l9 ( 1950 )93-104 Eine vereinfachte methode zur photometrischen bestiffiung des gehaltes an wasserloslichen und wasserunloslichen Alkaloiden im Mutterkorn Hecht , W. " Osterreisches A p o t h e k e r - Z t g . " 3 ( 1 9 4 9 ) 6 3 0- 2 Versuche mit der Mutterkornimpfung Bonns,W.W. "Amer. Journ. of Botany" Nr .7,2(1922)339-53 Plate XVI,XVII,XVIII,XIX,XX,XXI purpurea A prelimj-nary study of Claviceps in Culture
Grignard Houben-Wey1 "Methoden der Organischen Chemie" Ed, Eugen MUI-l-er XIII /2a(I973 )54-85 Metallorganische Verbindungen, Organo-Magnesum Verbindungen, Herstellung House , H. O. " Modern Synthetic R e a c t i o n s " 2 n d e d ( L 9 72 ) B I 7 - 9 Ashby,E.C. "Quarterly Reviews. London"21 ( 1967 )259-85 Grignard Reagents, Composition and Mechanism of Reaction A s h b y , E . C . " J . A m . S oc . " 9 4 ( L 9 7 2 ) 5 4 2 L - 3 4 Detailed deskriptj-on of the mechanism Grignard, V. "C.r. " 130 ( 1900 )L322-4 Wakefield,B. J. "Orffiometal-.Chem.Rev. " 1( Lg66 )131-56 Recent advances in the chemistry of organomagnesium compounds A s h b y , E . C . " A c c t s . C h e m . R e s . " 7 ( L 9 74 ) 2 7 2 - 8 0 The Mechan j,sm o f Grignard Reagent Chlortoluene Beilstei-n, E III 5,685-90, E II 5,227-3L, Wohl , A. "C" ( 1905 )II,727 -B Beilstein , F. " A. " 139 ,331-42 Silberrad, C . A . " S oc . " L 2 - 7 , 2 4 4 9 - 5 0 Silberrad, O. " Soc ." I27 L724-3I Firth, J.B. " Soc. " ( 1936 )337-9 Schramil, J. "Ber. " 18, 606-9 S o r s , P . " C h e m. Z t g . 57 (L933 )32L-3 LorgesrB.
ttC. t',
E I
5,150-1,
H 5,292-5
I 12655
Coen€fl , " Ullmanns" 5 ( 1954 ) 458-61 B a n c r o f t , W .D . " P r o E e e d i n g s o f t h e N a t i o n a l Academy of o f U S A "I 7 ( 1 9 3 1 ) 1 Br - 3 C a nr z z a r o , S . " A n n a l e s d e C h i m i - e " N r . 3 , 4 5 , 4 6 8 - 7 5 Zelinsky, N. " Fort. Teer. " L6 ,335-6 Benzaldehyd Beilstein, E IV 7 ,505-6, E rrr E I 7,113-9, H 17 4-9 Schenderowi t s ch , F.S."C."(1930)r Jewdokimow, I . P. c."(1930)r,B20Schorygin , P. et al "C."(1930)II ( 1933)r,3 442 SinkowrS.E."C.tt Berkenheim,A.M. c."(1935)rr,510
7 tl
Z, 8 0 5 - 7 ,
E rr
, 3551I , 3 3 97
lt
Phenyltittikssyra Beilstein, E rrr 9,2170, E rr 9,294, H 9,43I Kinney,C.R. " J.Am.5oc. " 53 ( 1931 )T90-9 Houb€o , " Ber . "35 ,2523 Zelinsky , N. "Ber. " 352692-4 GiIman,H."J .Am. Soc. " 45 ( L923 )2462-6 Gj-lman,H."J .Am. Soc. " 45 (L923 ) 159-65 Morton,A.A. " J. Am.Soc. " 5B L936)2599-60s Morton,A.A. "J.Am.Soc."58 r936)1697-L701 Morton , A. A. " J.Am. Soc. " 65 1943)1339-46
7,I45-7
Sciences
Natriumacetat G m e l i n , 2 1 - ,N a . E r g . L 4 ) , 2 - 5 Cadj-an El-ectro "C. " (1929 )II,3068 Franklin,M.C. " Soc. " ( 1928 ) 59 1-5 Acetanhydrid Beilstein, E r 2,75-8,
E IV 2,386-90, H 2,166-9
E III
2,37L-9,
E II
2,L70-4
Nitroglycerin L,2328-32, E II 1,59L-2 Bei-Istein, E IV L,2762, E III H I,5T6-7 E I I,272_3, Foulon,A. "Ze:_tschrift fUr das gesamte Schiess ( 1933 )B-11 und Sprengstoffwesen"2S S y m m e S, E . M . " C h e m i c a l - a n d M e t a l l u r g i c a l Engj-neering" New York 25(1949)831-4 Bresser, A. " Industrial London" Chemist and Chemical Manufacturer, 25 ( 1949 )92-B Stettbacher,A. " Schwerzer Chemiker Zettung" 26(L943 ) 181-7 Acetaldehyd Gatterman-Wieland, " Praxis 40th ed. ( L96I )180-4
des
Organischer
Chemikers"
Diethyleter Himml-er, K. " Ullmanns " 5 ( I95 4 )7 72-82 Nitroethane Giral,H. "C.A. "49 ( 1955 )836 Beilstein, H I,99,Syst.Nr.8-9 McCombie, H. " J. Chem.Soc. " ( 1944 )24-5 Formamid Beilstei-n, E IV 2,45,8 III 2,54-5,8 II 2,36-,E I 2,20,H Cherbulie Z,E. "HeIv ." 29 ( 19 AOjtq31 -46, I44O Phelps, I. K. "American Journal of Sci-ence" Nr .4 ,24 , L73-5 Slobodin, "C. A. " ( 1945 )7 02-3 DMF Brown, D. J. " J.Appl.Chem. London" 1. supp. Nr.2 , (1951 ) 159-60 Mitchell, J.A. " J.Am. Soc. " 53 ( 1931 ) 1B79-83 Alkylklorid Farbenind, I. G. " Fort. Teer. " L7 (L930 ) 113-5 F a r b e n i n d , I . G . " C . " ( L 9 2 9 ) I , 1 0 4 5 , D R P 46 7 L B 5 , F r d I . 1 6 , 1 1 5 Treptow Anil-infab. " Fort. Teer. " 12 ,22-3
2,26
Diethylamin Hofmann, A.W. " Proc. Royal. Soc. London" 11, 66-8 Journal-" 13 (1861)331-3 Groves,C.E. "Chemical Society Quaterly Hofmanil,A.hl. "Annalen der Chemie"73 ( 1850)9L-2 Hofmantr,A.W. "Ber. " 3 ( 1870 ) 109-12 Duvj-I1i€r, "A. ch. "Nr .5 ,23 ,345 ,352 Werner, E.A. " Soc. " 113899 -902 GarnerrW.E. "Soc. " 109 ,174-5 Hofmann, A.!V. " Ber . " 1,1 76-9 Wa11ach, " A. " 2I4 ,266-9 Wall-ach, "A. " 184, 62-5 Gaudion , G. " Annales de Chemie et de Physiqe" Nr .B ,2 5 , 135 Lea,"J."(lB6L)493-5 Heintz,W. "A. " 127 ,43-55 ,46
Ally]-klorid Beilstein,
H 1,198-9,Syst.Nr.ll
B en z ylmagn e s iumk lori
d
Greenwood, F. L. " J.Am. Soc. " 60 ( 1938 )2028-30 p- Toluol
sul fochlorid
Beilstein,
H 11,103,
Syst.Nr.L52L
Ameisensdure Beil-stej-n E IV 2,3-, E III 2,3-7,8 II 2,3-9,8 Hempel , G. A. " Fort . Teer. " 10 , 55 - 6 Meister, LuciuS, & Bruning" Fort. Teer. " 10 ,5 1-3 Hanel,M. "C. " ( 1905 )I ,L7AL Othmer,D. F. "C.A. " 34 (1940 ) 116, USPat.2L70B34 Farbwerke, "C. " ( 1909 ) II, 1095 Nitri-tfabrik, " c. " ( 1907 ) I,L469 -70 Hamef ,M. "C. " ( 1906 )I,1584,DRP.169730 Paraldehyd-
I
2,7-9,H
2,8-10
Acet a]-dehyd
Beilstein, E IV 1,3 094-I02 ,E III I ,26L7 -4I ,E II L ,654-7 I E r 1,32I-'/,H 1,594-603 Baer, D. H. " USPat .2864827 "CI . 260: 340, Process f or polyme rLzing aldeh-ydes W e r t h e i m , E . " J . A m . S oc . " 4 4 ( L 9 2 2 ) 2 6 5 8 - 9 Fricke, R. "Angew.Chemie'' 36 ( 1923 )546-7 Vogel,A. I. " Practj-cal- Org.Cfrem. " Longmans, London, ( 1959 )31B-25 Kekule,A. "A. " L62 ( 1872)125-50 Figot , P. P. " acta pharmacol . Toxicol. " B( 1952 )290-304 Ethers Luri€,A.
P. "Kirk-Othmer"
B( 1965 )470-98 ,2nd
ed.
Toluen E II 5,210-5,222-3, E I 5,144-5,148-9 E III 5,65I-75, Beilste-in, H 5,280-3 Coulson,E.A. "J. of the Soc. of Chem.Ind.London"63( 1944)329-33 Birch, S. F. " Ind.Eng.Chem.Ind.Ed. "24( 1932)49-50 Benedict,M."Transaction of the American Institute of Chemical Engineers" 4 1 ( 1945 ) 353 -70 Lak€,G.R."Transactions of the American Institute of Chemical Engineers" 4 1 ( 1945 )327 -52 G l a s g o w , A . R . e t a l " I n d . E n g . C h e m . I n d . E d . " 4 1 ( 1 94 9 ) 2 2 9 2 - 7 Components of Gasoline Isobe,C. "C.A. " ( L947 )37 69, Jap. Toluene Clark,C. R. " USPat . 2388040"CI. 202: 42,Recovering Bureau of Standards Mair, B. J. " Journal of Researcfr of the National Washington D.C ." 27 (L941 )39 -63,5L,Azeotropic Distillation Foster,A. L. "The Oif and Gas Journal"Nr .49,42(L944) 130-2 Toluene Recovering Plant Mair,B. J. " J.Res. Natl.Bur. Standards" 34 (L945 )435-5 I B e n e d i c t , M . " T r a n s . A m . I n s t . C h e m .E n g . " 4 l ( L 9 4 5 ) 3 7 L - 9 2 Brandt, P. L. " Ind. Eng.Chem. " 39 (L947 )L0 10-B Column Assembly and Testing Laboratory Adsorption of 52-foot " Ind. Eng. Chem." 39 (L9 47 )I072-82 L e e , R . " U S P a i u . 2 31 9 6 9 4 " C L . 2 0 2 ' . 4 2 , S e p a r a t i o n s BenzoI Bei-lstein, E III E II 5,120-3,I44-6, 5,469-5L7, E I 5,96-LO7 H 5,174-BL,L96-7 Griswold, J. " Ind. Eng.Chem. " 38 ( 1946 )509 -12 W i l m i n g t o n , E . F . " U S P a t . 2 2 L 2 8 I 0 " C L . 2 0 2 z4 2 W oj c i e c h o w s k i , M . " J . R e s . B u r . of Standards" 19 ( L937 )347 -52 ,348 Vinsyra Beilstein E IV 3,12I8-36, E III E r 3,169-83, H 3,48r-92,508-31 Methyl
3 ,994- 1033 , E II
3,308-40
Iodi-de
"Org.Synth."399-405 Propylene
O
H L7 ,6, Syst. Nr .2362 Beilstein Horsley, L.H. "Kirk-Othmer" B( 1965 )47 0-9B,2nd ed Gurme, G. O. Johnson, F. Eds. "ACS Monograph Series New York( 1952)250-61
no.1 \4 ,Gl-ycols
Hydrazine Audrieth, L.F. Ogg,B.A. "The Chemistry of Hydrazine"New York( 1951 ) Formation and Preparation 13-4L, Preparation of Hydrazine of Concentrated and Anhydrous HydrazLne 42-54, Explosive Charact 94-9 Raschig, F. "Ber. " 43 ( 1910 ) f927 ,Anhyd. Hydrazine Charmandarian, M. O. "Bul-1. de 1a Societe Chimique de France"
( re5r)325-7
Argyl€,C. S. " Eng. Pat .L07329 2 " Recovery Gme1in,lAC D1 366-7I H e r m a n t r, B . " B D R P a t . 2 0 5 6 3 5 7 " V e r f a h r e n Reaktionsprodukten aus Hydrazrn Potassium
of
Hydrazt-ne
zur
Herstellung
von
Azid
MilIer,M.W. " Inorg. Syntheses" 2 (L946 ) 139-4I Browne,A.W. " Inorg. Syntheses'' 1 ( 1939 ) 79-B1 Jiirntriklorid Pray,A.R.
" Inorg. Syntheses"5 ( 1957 ) 153-65,Anhydrous
Metal
Chlorides
Fos for Davy , H. " Philosoph j-cal Transactions of the Royal Society of ( 1818 )316-37 ,36, New Experi-ments on some of the Combinations of Phosphorus Marchand, R. F. " Journal fur Praktische Chemie" 16 ( 1839 )3 72-5
London "
Ammonium Acetate Zuff anti, Sulfur
S. " J.Am. Soc. " 63 ( 194L)3I23-4
Dioxide
Gmelin, 9,S Erg. 8d.3,70-3 Gmelin , 9 , S, B ,202-3 Darst. im Laboratorium Marchand, R. F. " Poggendorfs Annalen der Physik und Chemie" 118 ( 1937 ) L44 ,Darst. Reiner Schwef f ichter Seiure Stolba"J.pr.Ch. "99 ( 1866)54-6 N e u m a n n ,G . " B e r . " 2 0 ( 1 B B 7) L 5 8 4 - 5 , U e b e r d i e E n t w i c k l u n g von schwefliger Saure und Saurestoff mit Hulfe des Kippschen Aparat Nitric
O:
Jones, K. "Comprehensive 2(L973)323-34
Inorganic
Chemistry"Bailar
tithium Bach,R.O. "Kirk-Othmer" Nitric
L2(1967 )529 -56
Acid
Stern, S.A. "Chem.Rev. " 60 ( 1960 )185-207 Forsythe,W.R. " J.Am.Chem. Soc ." 64(L942)48-61 Kay,W.B. " Ind. Eng.Chem." 47 ( 1955 ) 1463-9
et
al- Ed.
Ammonia Gmelin 4 N (1935)365-7 im Laboratorium ,Darst. Gmeli-n 4 N 366-7 Technische Darst. R o b e r t s o n e t a l " P r . R o y . S o c . " A 1 2 0 ( 1 9 2 8 ) 15 7 - 8 , P r e p . o f A m m o n i a Richards, T.W. " Z.Annorg.Ch" " 61( 1909 )322-7 Moser, L. "Monatsh.'44(1923 von Reinem Ammoni )115-22 Die Darstellung Schwe fel chloride Gmelin,9 S,Erg. -Bd . 2 ,219-72, Schwefel_chloride Gmelin,9 S B,l748-9I,Schwefel und Chlor Gmelin,9 S B, 179I- 1802 , Thionylchlorid Edwards , J. P. " USPat .2362057 " CL.23:203, Process for of Thionylchloride Kirk-othmer,2nd. Ed ., 19 ( L969 ) 398-401 M i c h a e l i s , A . " A . u2 7 4 ( 1 8 9 3 ) L 7 3 - 8 6
Production
Koldioxid GmeIin ,14 C C,285-9,Darst. im Laboratorium Tucker, S.H. "Analysts" 64(L939 )4 10-5.Generator for Air-Free Carbon Dioxide P o t h , E . J . " I n d . E n g . C h e m .A n a I . E d . " 3 ( 1 9 3 I ) 2 0 2 - 3 Poth, E. J. " Ind. Eng.Chem.AnaI. Ed. "2 (t930 )250- I Lowe, E.W. " Ind.Eng.Chem.AnaI. Ed. "4 ( 1932)440-1 Poth, E. J. " Ind.Eng.Chem.Anal.Ed. " 11 ( 1939 )518 Rauscher,W.H. " Ind. E.g:Chem.Anal. Ed ." 12 ( L940 ) 694-5 PageI,H.A. " Ind.Eng.Chem.AnaI. Ed. " 16 ( 1944)344-5 Natrium Wallac€,T.
"Chem. and
Ind. " (1953 )876-82
The Castner
Sodium Process
Stickstoff GmeI:-n,4 N,(1934)71-80 Dars. im Laboratorium Pfordten, O. " Liebigs Ann ."228 ( fB85 ) 112-26, Neues Adbsorptionsmittel fur Sauerstoff Moser, L ." Z .Anorg.Chem. " 110 (1920 ) 13I-2 Brunt,c" " J.Am. soc. "36(1914)1448-50,A Nitrogen Generator Badger,W. L. " J. Ind.Eng.Chem. " 11( f919 ) 1052-5,A Nitrogen Generator for Laboratory Use Threlf al-l , R. " London, Edi-nburg and Dublin PhilosophicalM a g a zj - n e ( and Journal of Science" 35 , Nr.5 fB93 ) l-35 , Pl. 1 Carbon
tvlonoxide
Weinhouse, S. " J.Am. Soc. " 70 (L948 )442-3, Prep. Sulfur
of
Carbon
Monoxide
Trioxide
EvanS, H. S. " Pharm. J. " B( 1849 )L27 -B VEB Farbenfabrik"BDP 1 0 B 2 B B B "I n t . C I . Schwef eI silureanhydrid Waser et al" J.Am. Soc. "B7 (7965 )3333-9
C01b Stabifisieren
von
ChIor 1-30, B0-1, Im Laboratorium GmeIin,6 Cl,Erg.A, GmeIin,6 C1,5 -7 ,Darst. im Laboratorium I v l c C o n n e l - l -W , . H . , L e w i s , K . S . " C h e m. E n g . P r o g r e s s " 5 6 ( 1 9 6 0 ) N r . 2 , 4 3 - 5 T h e C h l o r - A l - ka l i I n d u s t r y Diamond Alkali Co. "C. " ( 1952)2565 ,AP .2553557 Gewinnung von Trockenem Chlor Kl-emenc,A. "Die Behandlung und Reindarstellung von Gasen" Viennd,2 nd.Ed. ( 1948 ) 153-5 F y e , P . M . B e a v e r , J . J . " J . A m .C h e m .S o c . " 6 3 ( 1 9 4 L ) 1 2 6 8 - 9 The Rigid Purificaton of Chlorine Winkler, C. "Ber ." 20, IB4-5, Bequeme Methode zur Entwj-cklung von Chlorgas aus Chlorkalk unter Anwendung des Kippschen Apparates Foran,B. "Chem. Ind. London" ( 1954)14L6, An Improved Chlorine Gener. Graebe,C. "Ber. "35 ( 1902)43-5,Uber Darstellung von Chlor Mittels SaIze ubermangansaurer Ul-lmanns , 3 ed. 5 ( 1964 )298, Herstellung Bunsen,R. Roscoe,H. " Pogg.Ann. " 100( fB57 )43-BB, 52 II I . Photochemische Untersuchungen O h m a n n ,O . " Z e t - t s c h r i f t f i i r d e n P h y s i k a l i s c h e n und Chemischen 7 ( Unterricht 2 7 1 9 1 4 1 I D i e C h l o r e n t w i c k l u n g 6 7 mittels Kaliumperm " ) , Solvay Process Co. "C. " ( L946)I ,169 ,Can. P.431538 Elektrolyse von Kaliumsalzen Motulevich"C.A. " ( 1958 )5891, A Gas Drying System F i n e , I . " J . C h e m .E d u c a t i o n , E a s t o n , P d . " 1 3 ( 1 9 3 6 ) 5 B B- 9 An Automatic Gas Generator S o l v a y P r o c e s s C o . " C . " ( 1 9 34 ) f , 1 2 3 1 , A . P . 1 9 3 0 5 2 6 Trocknen von Eeuchtem Chlor Farbwerke Hoechst "C."(1954)2895, DBP B7B196, Trocknen von Chl-or Jannasch, Jilk€, "Ber. " 40 ( 1907 )3606, Kaliumpermagnat Sanders,H. J. " Ind. Eng.Chem. "45 ( 1953 ) 1824-35 Mercury Cell Chlorine and Caustic Ullmanns, 3 Ed. 5 ( 1954 )3 13- 4 ,Phy siologische und Toxikofogische Kemmerich, W.E. " USPat . 1 66837I" Apparatus Suitable for the Gradual Production of Gases Kemmerich, W.E. " USPat . 1729043 " Process for the Gradual Production Natriumnitrit Cook€,W. T. "Australi-an Chem.Inst. J. Proc. " 11 (1944)49-5 I The Laboratory Preparation of Sodium Nitrite Hayes , J. W. " USPat.2032699" Collins et al- "Ind.Eng.Chem.Anal .Ed."4(1932)347 -50,Assay Gmeli-n, 2I Na Erg.(1960)960-3 Phosphorus
Pentachloride
Maxson,R. N. " Inorganic Phosphorus
Syntheses'' 1( 1939 )99-100
Trichloride
Forbes,M. C. " Inorganic Syntheses" 2 ( 1946 ) I45-7 Graebe,C. "Ber. "34, 645-52,651, ueber Darstellung von Chlor aus Natriumchlorat und uber Gewinnung von Phosphortrichlorid
Testes