Designation: B783 − 13
Standard Specification for
Materials for Ferrous Powder Metallurgy (PM) Structural Parts1 This standard is issued under the fixed designation B783; the number immediately following the designation indicates the year of original origin al adoption or, in the case of revis revision, ion, the year of last revision. revision. A number in paren parenthese thesess indicates the year of last reappr reapproval. oval. A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Sco Scope pe
Powder Metallu Powder Metallurgy rgy (PM) Prod Products ucts Using Archimedes’ Archimedes’ Principle B963 Test Met Method hodss for Oil Con Conten tent, t, Oil Oil-Im -Impr pregn egnati ation on Effficiency Ef iciency,, and Surf Surface-Con ace-Connected nected Poro Porosity sity of Sinter Sintered ed Powderr Metallu Powde Metallurgy rgy (PM) Prod Products ucts Using Archimedes’ Archimedes’ Principle E8 Test E8 Test Methods for Tension Testing of Metallic Materials E29 Pra Practic cticee for Using Sig Signifi nifican cantt Dig Digits its in Test Data to Determine Conformance with Specifications E1019 Test Methods for Determination of Carbon, Sulfur, E1019 Nitrogen, and Oxygen in Steel, Iron, Nickel, and Cobalt Alloys by Various Combustion and Fusion Techniques 2.2 MPIF Standard:3 MPIF Standa Standard rd 35 35 Mater Materials ials Sta Standa ndards rds for PM Str Struct uctura urall Parts
1.1 This specification specification covers covers a variety of ferrous ferrous PM structural materials and includes a classification system or material designation code. The classification system used in this specification ficat ion incl include udess che chemica micall com compos positio ition, n, min minimu imum m ten tensile sile;; 0.2 % offset yield strength for as-sintered materials and minimum ultimate tensile strength for heat-tr heat-treated eated materials (sinter hardened or quenched and tempered). It also contains minimum den densit sity y and max maximu imum m coe coerci rcive ve field str streng ength th req requir uireements for iron-phosphorus materials. 1.2 Materi Material al classifi classification cation is gover governed ned by the designation code which is explained in Appendix X1. X1 . The data provided display typical mechanical properties achieved under commercial manufacturing procedures. Physical and mechanical property performa performance nce cha charac racteri teristic sticss can cha change nge as a res result ult of subsequent processing steps beyond the steps designated in this standard.
3. Terminology 3.1 Definitions— Definit Definition ionss of pow powder der met metallu allurg rgy y ter terms ms can be fou found nd in Term ermino inolog logy y B243. B243. Additional Additional descr descriptive iptive information is available in the Related Materials section of Vol 02.05 of the Annual Book of ASTM Standards .
1.3 With th 1.3 thee ex exce cept ptio ion n of de dens nsity ity va valu lues es fo forr wh which ich th thee 3 g/cm unit is the industry standard, property values stated in inch-pound units are the standard. Values in SI units result from conv co nver ersio sion. n. Th They ey ma may y be ap appr prox oxim imate ate an and d ar aree on only ly fo forr information.
4. Order Ordering ing Information Information 4.1 Materia Materials ls for parts conforming conforming to this specification shall be ordered by material designation code.
2. Referenc Referenced ed Documents Documents 2.1 ASTM Standards:2 A839 Specification A839 Specification for Iron-Phosphorus Powder Metallurgy Parts for Soft Magnetic Applications B243 Terminology B243 Terminology of Powder Metallurgy B528 Test B528 Test Method for Transverse Rupture Strength of Powder Metallurgy (PM) Specimens B962 Test Methods for Density of Compacted or Sintered B962
4.2 Order Orderss for parts under this specification specification may include the following information: 4.2.1 Certific Certification ation and test repor reports, ts, if requir required ed (see Sectio Section n 11), 11 ), 4.2.2 4.2 .2 Test meth methods ods and mec mechan hanical ical pro proper perties ties oth other er tha than n strength (see 8.2 and 8.3 8.3)), 4.2.3 Densit Density y (see 7.1 7.1), ), 4.2.4 Poros Porosity ity or oil content (see 7.2 7.2), ), and 4.2.5 Specia Speciall packa packaging ging if required.
1
This specification is under the jurisdiction of ASTM Committee B09 Committee B09 on on Metal Powders and Metal Powder Products and is the direct responsibility of Subcommittee B09.05 mittee B09.05 on Structural Parts. Current edition approved Nov. 1, 2013. Published November 2013. Originally approv app roved ed in 198 1988. 8. Las Lastt pre previo vious us edi editio tion n app approve roved d in 201 2010 0 as B78 B783– 3– 10. DOI DOI:: 10.1520/B0783-13. 2 For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at
[email protected]. For Annual Book of ASTM Standards volume information, refer to the standard’s Document Summary page on the ASTM website.
5. Mater Materials ials and Manuf Manufactu acture re 5.1 Struct 5.1 Structur ural al pa part rtss sh shal alll be ma made de by co comp mpact actin ing g an and d sinter sin tering ing meta metall pow powder derss wit with h or with without out sub subseq sequen uentt hea heatt -treating. Parts may also be made by repressing or repressing and res resint interi ering ng sin sinter tered ed par parts, ts, if nec necessa essary ry,, wit with h or wit withou houtt 3
Available from MPIF, 105 College Road East, Princeton, NJ 08540.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
B783 − 13 subsequent heat treatment to produce finished parts conforming to the requirements of this specification.
strength for heat-treated materials (sinter hardened or quenched and tempered). Iron-phosphorus materials (Table ( Table 3) 3) contain an alphan alp hanume umeric ric suf sufffix and are an exc except eption ion to thi thiss rul rule. e. The iron-phosphorus suffix is related to the minimum density and maximu max imum m coe coerciv rcivee fiel field d str streng ength th and not the ten tensile sile yie yield ld strength (see X1.3 (see X1.3 a and nd X1.4 X1.4 for for details). 8.1.1 8.1 .1 Materials Materials tha thatt are hea heatt trea treated ted (si (sinte nterr-har harden dened ed or quenched and tempered) have the numeric value followed by HT in the suffix.
6. Chem Chemical ical Compositi Composition on 6.1 The material material shall conform to the requiremen requirements ts of Table Table 1. 6.2 Che Chemic mical al ana analys lysis, is, if req requir uired, ed, sha shall ll be per perfor formed med by methods agreed upon by the producer and the user. 6.3 Variou ariouss analyt analytical ical test method methodss are used to determ determine ine the chemical compo composition sition (see ASTM standards for the appro appro-priate test metho methods) ds) of PM materia materials. ls. Combu Combustionstion-infra infra-red -red absorption and inert gas fusion methods (Test Methods E1019 E1019)) are used for the specific elements carbon, nitrogen, oxygen, and sulfur.
8.2 The producer and the user should agree upon upon the method to be used to verify the minimum strength characteristics of the finished finish ed parts. Since it is usually impossible to machine tensile test specimens from these parts, alternative strength tests are advisable. advisa ble. An example would be measuring the force needed to break teeth off a gear with the gear properly fixtured.
6.4 The Chemical Composition Composition Requirements Table Table (Table (Table 1) designates the limits of metallurgically combined carbon for each eac h al allo loy y. Th Thee co comb mbin ined ed ca carb rbon on lev level el can be es estim timate ated d metallographically for sintered PM steels. When a clear pearlite to ferri ferrite te ratio cannot be estimate estimated d metallog metallographic raphically ally,, total carbon carb on can be dete determi rmined ned usi using ng ana analyti lytical cal meth methods ods (T (Test est Methods E1019 E1019). ). This would include very low carbon levels (<0.08 %), heat treated steels and materials made from prealloyed loy ed bas basee pow powder derss or dif diffus fusion ion allo alloyed yed pow powder ders. s. Whe When n reporting repor ting carbon levels, the repor reportt shoul should d identi identify fy wheth whether er the carbon is metallu metallurgic rgically ally combined carbon or total carbon and the test method should be identified. While total carbon will approx app roxima imate te the com combin bined ed car carbon bon in man many y mate materia rials, ls, fre freee graphite and other carbonaceous material will raise the total carbon carb on lev level el abo above ve the lev level el of com combin bined ed car carbon bon,, pos possib sibly ly causing the total carbon content to exceed the combined carbon level specified for the material.
8.3 If the tensile tensile pro proper perties ties of the materials materials are req requir uired, ed, standard test bars shall be compacted from the same mixed powder lot, at the density of a critical region in the part, and processed along with the parts. When a PM part has a larger ruling section than the test bar being used, the test bar may not be rep repres resent entativ ativee of the par part. t. The fol follow lowing ing pro proced cedure uress are listed with the preferred method first. 8.3.1 Tra Transver nsverse se ruptu rupture re streng strength th (see Test Method B528) B528) can be related to the minimum tensile strength by the ratio of typicall trans typica transverse verse rupture strength to typical tensile strength at the same density as the part, as shown in, or interpolated from the tables contained in Appendix X1. X1 . 8.3.2 For as-sintered as-sintered material, flat unmachined unmachined tension test specimens (see Test Methods E8 Methods E8)) should be used for determination of 0.2 % offset yield strength. 8.3.3 8.3 .3 For det determ ermini ining ng the tens tensile ile str streng ength th of hea heat-tr t-treate eated d (sinter-ha (sinte r-hardene rdened d or quenc quenched hed and temper tempered) ed) materia material, l, roun round d testt ba tes bars rs sh shou ould ld be ma mach chin ined ed fr from om sp spec ecial ially ly co comp mpac acted ted,, as-sintered bars because heat-treated, unmachined specimens yield lower values. The machined tension test specimens (see Test Metho Methods ds E8 E8)) shall be hea heat-tr t-treate eated d wit with h the pro produc ductio tion n parts.
7. Physical Propertie Propertiess 7.1 Density: 7.1.1 7.1 .1 The user and pro produc ducer er may agree upon a min minimu imum m average density for the part or minimum densities for specific regions of the part, or both, except soft magnetic materials, whic wh ich h re requ quir iree a mi mini nimu mum m av aver erag agee de dens nsity ity as pa part rt of th thee material specification. 7.1.2 Density shall be determined in accordance accordance with Test Method B962 Method B962..
9. Sampl Sampling ing 9.1 Chemical Analys When req reques uested ted on the pur purcha chase se Analysis— is— When order, at least one sample for chemical analysis shall be taken from each lot. The analysis shall be performed by a mutually agreed upon method.
7.2 Porosity: 7.2. 7. 2.1 1 Th Thee pr prod oduc ucer er an and d th thee us user er ma may y als also o ag agre reee up upon on a minimu min imum m vo volu lume me oi oill co cont nten entt fo forr pa part rtss th that at ar aree to be sel selfflubricating. 7.2.2 Poros Porosity ity or oil content, or both, shall be determined in accordance with Test Method B963 B963.. 7.2.3 7.2 .3 The produce producerr and the user may agree agree upo upon n a fun funcctional test for porosity in parts that are to be self-l self-lubrica ubricating, ting, or for permeability where fluid flow must be restricted.
Mechanical Tests— The 9.2 Mechanical T he pr prod oduc ucer er an and d th thee us user er sh shal alll agree on the number of specimens for mechanical tests.
10. Reje Rejectio ction n and Rehe Rehearin aring g 10.1 Par 10.1 Parts ts tha thatt fai faill to conform conform to the require requiremen ments ts of thi thiss specification may be rejected. Rejection should be reported to the producer or supplier promptly and in writing. 11. Certificatio Certification n and Test Reports
8. Mechanical Propertie Propertiess
11.1 Whe 11.1 When n spe specifie cified d in the purchase purchase order or con contra tract, ct, a producer’s certification shall be furnished to the user that the parts par ts wer weree man manufa ufactu ctured red,, sam sampled pled,, test tested, ed, and ins inspec pected ted in accordance with this specification and have been found to meet the req requir uireme ements nts.. Whe When n spe specifi cified ed in the pur purcha chase se ord order er or contract, a report of the test results shall be furnished.
8.1 The gua guaran ranteed teed pro proper perties ties sho shown wn in Tables Tables 2-12 are include incl uded d in the suf sufffix of the mat materia eriall des design ignatio ation n cod code. e. The code is adopted from MPIF Standard 35. All tensile strengths are read as 10 3 psi, and are defined as the 0.2 % offset yield strengt stre ngth h for asas-sin sintere tered d mate material rialss and the ulti ultimate mate ten tensile sile 2
B783 − 13 subsequent heat treatment to produce finished parts conforming to the requirements of this specification.
strength for heat-treated materials (sinter hardened or quenched and tempered). Iron-phosphorus materials (Table ( Table 3) 3) contain an alphan alp hanume umeric ric suf sufffix and are an exc except eption ion to thi thiss rul rule. e. The iron-phosphorus suffix is related to the minimum density and maximu max imum m coe coerciv rcivee fiel field d str streng ength th and not the ten tensile sile yie yield ld strength (see X1.3 (see X1.3 a and nd X1.4 X1.4 for for details). 8.1.1 8.1 .1 Materials Materials tha thatt are hea heatt trea treated ted (si (sinte nterr-har harden dened ed or quenched and tempered) have the numeric value followed by HT in the suffix.
6. Chem Chemical ical Compositi Composition on 6.1 The material material shall conform to the requiremen requirements ts of Table Table 1. 6.2 Che Chemic mical al ana analys lysis, is, if req requir uired, ed, sha shall ll be per perfor formed med by methods agreed upon by the producer and the user. 6.3 Variou ariouss analyt analytical ical test method methodss are used to determ determine ine the chemical compo composition sition (see ASTM standards for the appro appro-priate test metho methods) ds) of PM materia materials. ls. Combu Combustionstion-infra infra-red -red absorption and inert gas fusion methods (Test Methods E1019 E1019)) are used for the specific elements carbon, nitrogen, oxygen, and sulfur.
8.2 The producer and the user should agree upon upon the method to be used to verify the minimum strength characteristics of the finished finish ed parts. Since it is usually impossible to machine tensile test specimens from these parts, alternative strength tests are advisable. advisa ble. An example would be measuring the force needed to break teeth off a gear with the gear properly fixtured.
6.4 The Chemical Composition Composition Requirements Table Table (Table (Table 1) designates the limits of metallurgically combined carbon for each eac h al allo loy y. Th Thee co comb mbin ined ed ca carb rbon on lev level el can be es estim timate ated d metallographically for sintered PM steels. When a clear pearlite to ferri ferrite te ratio cannot be estimate estimated d metallog metallographic raphically ally,, total carbon carb on can be dete determi rmined ned usi using ng ana analyti lytical cal meth methods ods (T (Test est Methods E1019 E1019). ). This would include very low carbon levels (<0.08 %), heat treated steels and materials made from prealloyed loy ed bas basee pow powder derss or dif diffus fusion ion allo alloyed yed pow powder ders. s. Whe When n reporting repor ting carbon levels, the repor reportt shoul should d identi identify fy wheth whether er the carbon is metallu metallurgic rgically ally combined carbon or total carbon and the test method should be identified. While total carbon will approx app roxima imate te the com combin bined ed car carbon bon in man many y mate materia rials, ls, fre freee graphite and other carbonaceous material will raise the total carbon carb on lev level el abo above ve the lev level el of com combin bined ed car carbon bon,, pos possib sibly ly causing the total carbon content to exceed the combined carbon level specified for the material.
8.3 If the tensile tensile pro proper perties ties of the materials materials are req requir uired, ed, standard test bars shall be compacted from the same mixed powder lot, at the density of a critical region in the part, and processed along with the parts. When a PM part has a larger ruling section than the test bar being used, the test bar may not be rep repres resent entativ ativee of the par part. t. The fol follow lowing ing pro proced cedure uress are listed with the preferred method first. 8.3.1 Tra Transver nsverse se ruptu rupture re streng strength th (see Test Method B528) B528) can be related to the minimum tensile strength by the ratio of typicall trans typica transverse verse rupture strength to typical tensile strength at the same density as the part, as shown in, or interpolated from the tables contained in Appendix X1. X1 . 8.3.2 For as-sintered as-sintered material, flat unmachined unmachined tension test specimens (see Test Methods E8 Methods E8)) should be used for determination of 0.2 % offset yield strength. 8.3.3 8.3 .3 For det determ ermini ining ng the tens tensile ile str streng ength th of hea heat-tr t-treate eated d (sinter-ha (sinte r-hardene rdened d or quenc quenched hed and temper tempered) ed) materia material, l, roun round d testt ba tes bars rs sh shou ould ld be ma mach chin ined ed fr from om sp spec ecial ially ly co comp mpac acted ted,, as-sintered bars because heat-treated, unmachined specimens yield lower values. The machined tension test specimens (see Test Metho Methods ds E8 E8)) shall be hea heat-tr t-treate eated d wit with h the pro produc ductio tion n parts.
7. Physical Propertie Propertiess 7.1 Density: 7.1.1 7.1 .1 The user and pro produc ducer er may agree upon a min minimu imum m average density for the part or minimum densities for specific regions of the part, or both, except soft magnetic materials, whic wh ich h re requ quir iree a mi mini nimu mum m av aver erag agee de dens nsity ity as pa part rt of th thee material specification. 7.1.2 Density shall be determined in accordance accordance with Test Method B962 Method B962..
9. Sampl Sampling ing 9.1 Chemical Analys When req reques uested ted on the pur purcha chase se Analysis— is— When order, at least one sample for chemical analysis shall be taken from each lot. The analysis shall be performed by a mutually agreed upon method.
7.2 Porosity: 7.2. 7. 2.1 1 Th Thee pr prod oduc ucer er an and d th thee us user er ma may y als also o ag agre reee up upon on a minimu min imum m vo volu lume me oi oill co cont nten entt fo forr pa part rtss th that at ar aree to be sel selfflubricating. 7.2.2 Poros Porosity ity or oil content, or both, shall be determined in accordance with Test Method B963 B963.. 7.2.3 7.2 .3 The produce producerr and the user may agree agree upo upon n a fun funcctional test for porosity in parts that are to be self-l self-lubrica ubricating, ting, or for permeability where fluid flow must be restricted.
Mechanical Tests— The 9.2 Mechanical T he pr prod oduc ucer er an and d th thee us user er sh shal alll agree on the number of specimens for mechanical tests.
10. Reje Rejectio ction n and Rehe Rehearin aring g 10.1 Par 10.1 Parts ts tha thatt fai faill to conform conform to the require requiremen ments ts of thi thiss specification may be rejected. Rejection should be reported to the producer or supplier promptly and in writing. 11. Certificatio Certification n and Test Reports
8. Mechanical Propertie Propertiess
11.1 Whe 11.1 When n spe specifie cified d in the purchase purchase order or con contra tract, ct, a producer’s certification shall be furnished to the user that the parts par ts wer weree man manufa ufactu ctured red,, sam sampled pled,, test tested, ed, and ins inspec pected ted in accordance with this specification and have been found to meet the req requir uireme ements nts.. Whe When n spe specifi cified ed in the pur purcha chase se ord order er or contract, a report of the test results shall be furnished.
8.1 The gua guaran ranteed teed pro proper perties ties sho shown wn in Tables Tables 2-12 are include incl uded d in the suf sufffix of the mat materia eriall des design ignatio ation n cod code. e. The code is adopted from MPIF Standard 35. All tensile strengths are read as 10 3 psi, and are defined as the 0.2 % offset yield strengt stre ngth h for asas-sin sintere tered d mate material rialss and the ulti ultimate mate ten tensile sile 2
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8 8 0 0 2 2 0 - 0 C C F F
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B783 − 13 r e h t O
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l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B n x n x n x n x n x n x n x n x n x n x n x n x n x n x n x n x n x n x i a i a i a i a i a i a i a i a i a i a i a i a i a i a i a i a i a i a M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M M
n l i o a t i r a e n t g a i M s e D
0 0 0 0 0 0 1 - 1 C C F F
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5 5 0 0 0 0 4 - 4 C C 4 4 N N L L F F
B783 − 13 r e h t O n e g y x O m m u i u l o b C o n r t i e N g
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n l i o a t i r a e n t g a i M s e D
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B783 − 13 r e h t O n e g y x O m m u i u l o b C o n r t i e N g
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n o r I
l . l . l . l . l l . l . l . a a a a a a a a B B B B B B B B
l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . l . a a a a a a a a a a a a a a a a a a a a a a a a a a B B B B B B B B B B B B B B B B B B B B B B B B B B
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n l i o a t i r a e n t g a i M s e D
8 8 0 0 8 8 8 8 8 8 8 8 9 9 0 0 0 0 0 0 8 5 5 0 0 8 8 4 8 1 1 1 l 2 2 0 0 5 5 8 8 0 0 5 5 8 8 4 y 0 0 0 8 1 0 0 – – 4 8 8 8 r ) 8 9 9 5 5 0 0 0 0 0 0 0 0 0 0 0 0 2 6 8 8 4 – – – – e 4 2 2 2 2 2 4 4 4 4 4 4 N 2 8 4 - 4 - 4 - 2 2 4 - 4 4 - 4 - 4 - 2 2 2 N 0 0 - 0 - 0 - 0 - 0 - 0 - 0 - 0 - 0 - 0 - 0 - D D C C C C C C C N m r N 0 N C C C C L L L L L L L L f o L 6 L L L L L D D D D D D D D D D D D L L F F F F F F F F ( F 4 - F F F F F F F F F F F F F F F F F F F
6
5 5 0 0 9 9 4 4 – – 2 2 C C 4 4 N N D D L L F F
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B783 − 13 r e h t O
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0 . 0 . 0 1
0 . 0 . 0 1
0 . 0 . 0 1
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0 . 0 . 0 1
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0 . 0 . 0 2
0 . 0 . 0 2
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0 . 0 . 0 1
0 . 0 . 0 1
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0 . 0 . 6 8 1 1
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0 0 5 . 5 . 1 1 3 1
0 0 5 . 5 . 1 1 3 1
0 0 5 . 5 . 1 1 3 1
0 0 0 . 0 . 6 8 1 1
0 0 0 . 0 . 6 8 1 1
0 0 0 . 0 . 6 8 1 1
0 0 0 . 0 . 6 8 1 1
n e g y x O m m u i u l o b C
- s s u 4 o r o 0 . h h P p 0 r u 3 f l . u 0 S 0 n o 0 c . i l 1 i S - - e n a 0 a g s e . M n 2 o r m . u 0 h i 0 C m 2
d e u n i t n o C
1 E L B A T
% s s a M , n o i t i s o p m o C l a c i m e h C
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l . l . l . l . l . l . l . l . l . l . l . a a a a a a a a a a a B B B B B B B B B B B
l . l . l . l . l . l . l . l . l . l . l . l . a a a a a a a a a a a a B B B B B B B B B B B B
x n x n x n x n x n x a i a i a i a i a i a M M M M M M M M M M M
n x n x n x n x n x n x i a i a i a i a i a i a M M M M M M M M M M M M
2 N , 1 N 4 0 3 S S
0 0 1 1 4 - 4 S S S S
n l i o a t i r a e n t g a i M s e D
L , L , H H 4 4 0 0 3 - 3 S S S S
2 2 N , N , 1 1 N N 6 6 1 1 3 - 3 S S S S
L , L , H H 6 6 1 1 3 - 3 S S S S
L L 9 9 0 0 4 - 4 S S S S
F F
E E L L 9 9 0 0 4 - 4 S S S S
7
L L 0 0 1 1 4 - 4 S S S S
2 2 N N 0 0 3 3 4 - 4 S S S S
L L 0 0 3 3 4 4 - S S S S
2 2 N N 4 4 3 3 4 - 4 S S S S
L L 4 4 3 3 4 - 4 S S S S
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B783 − 13 TABLE 2 Minimum Tensile Strength for Iron and Carbon Steel A Minimum Strength Material Designation Code
Yield
Ultimate 3
B
10 psi F-0000-10 -15 -20 F-0005-15 -20 -25 F-0005-50HT -60HT -70HT F-0008-20 -25 -30 -35 F-0008-55HT -65HT -75HT -85HT
10 15 20 15 20 25 ... ... ... 20 25 30 35 ... ... ... ...
... ... ... ... ... ... 50 60 70 ... ... ... ... 55 65 75 85
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2 )
TABLE 3 Minimum Density and Maximum Coercive Field Strength for Iron-Phosphorus A Material Designation Code
B
FY-4500 -20V -20W -17W -20X -17X -20Y -17Y FY-8000-17V -17W -15W -17X -15X -15Y
Minimum Density
Maximum Coercive Field Strength
g/cm3
Oe
6.7 6.9 6.9 7.1 7.1 7.3 7.3 6.7 6.9 6.9 7.1 7.1 7.3
2.0 2.0 1.7 2.0 1.7 2.0 1.7 1.7 1.7 1.5 1.7 1.5 1.5
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B These materials are frequently used in magnetic applications and are specified with minimum density and maximum coercive field strength. One oersted is equal to 79.6 A/m in SI units. Typical magnetic properties can be found in Specification A839.
microindentation; PM steel; Poisson’s Ratio; prealloyed; sinter-hardened; stainless; tensile strength; Young’s Modulus
12. Keywords 12.1 compressive strength; diffusion-alloyed; ductility; elastic; endurance; fatigue; hardness; hybrid; impact; low-alloy;
8
B783 − 13 TABLE 4 Minimum Tensile Strength for Copper-Infiltrated Iron and SteelA Minimum Strength Material Designation Code
Yield
Ultimate 10
FX-1000-25 FX-1005-40 FX-1005-110HT FX-1008-50 FX-1008-110HT FX-2000-25 FX-2005-45 FX-2005-90HT FX-2008-60 FX-2008-90HT
3
B
psi
25 40 ... 50 ... 25 45 ... 60 ...
... ... 110 ... 110 ... ... 90 ... 90
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
TABLE 5 Minimum Tensile Strength for Iron-Copper and Copper SteelA Minimum Strength Material Designation Code
Yield
Ultimate 10
FC-0200-15 -18 -21 -24 FC-0205-30 -35 -40 -45 FC-0205-60HT -70HT -80HT -90HT FC-0208-30 -40 -50 -60 FC-0208-50HT -65HT -80HT -95HT FC-0505-30 -40 -50 FC-0508-40 -50 -60 FC-0808-45 FC-1000-20
15 18 21 24 30 35 40 45 ... ... ... ... 30 40 50 60 ... ... ... ... 30 40 50 40 50 60 45 20
A
3
B
psi
... ... ... ... ... ... ... ... 60 70 80 90 ... ... ... ... 50 65 80 95 ... ... ... ... ... ... ... ...
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29 B 10 3 psi = 6.895 MPa (6.895 N/mm2)
9
B783 − 13 TABLE 7 Minimum Tensile Strength for Prealloyed Steel A
TABLE 6 Minimum Tensile Strength for Iron-Nickel and Nickel SteelA
Minimum Strength
Minimum Strength Material Designation Code
Yield 15 20 25 20 25 30 35 ... ... ... ... ... 30 35 40 45 50 ... ... ... ... ... 25 35 45 ... ... ... ... ... 35 45 55
Yield
Ultimate 10
FN-0200-15 -20 -25 FN-0205-20 -25 -30 -35 FN-0205-80HT -105HT -130HT -155HT -180HT FN-0208-30 -35 -40 -45 -50 FN-0208-80HT -105HT -130HT -155HT -180HT FN-0405-25 -35 -45 FN-0405-80HT -105HT -130HT -155HT -180HT FN-0408-35 -45 -55
Material Designation Code
3
Ultimate 3
B
10 psi
psiB
FL-4205-35 -40 -45 -50 FL-4205-80HT -100HT -120HT -140HT FL-4405-35 -40 -45 -50 FL-4405-100HT -125HT -150HT -175HT FL-4605-35 -40 -45 -50 FL-4605-80HT -100HT -120HT -140HT FLN-5208-65 -76 -80 -85 FL-5305-75 -90 -105 -120
... ... ... ... ... ... ... 80 105 130 155 180 ... ... ... ... ... 80 105 130 155 180 ... ... ... 80 105 130 155 180 ... ... ...
A
35 40 45 50 ... ... ... ... 35 40 45 50 ... ... ... ... 35 40 45 50 ... ... ... ... 65 75 80 85 75 90 105 120
... ... ... ... 80 100 120 140 ... ... ... ... 100 125 150 175 ... ... ... ... 80 100 120 140 ... ... ... ... ... ... ... ...
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
10
B783 − 13 TABLE 8 Minimum Tensile Strength for Hybrid Low-Alloy Steel A
TABLE 9 Minimum Tensile Strength for Sinter-Hardened Steel A
Minimum Strength Material Designation Code
Yield
Minimum Strength
Ultimate 3
Material Designation Code
Yield
10 psi FLN2C-4005-60 -65 -70 -75 FLN2C-4005-105HT -140HT -170HT -220HT FLN4C-4005-70 -75 -80 -85 FLN4C-4005-115HT -135HT -170HT -210HT FLN-4205-40 (Formerly low-alloy-45 steel)-50 -55 FLN-4205-80HT (Formerly low-alloy-105HT steel)-140HT -175HT FLN2–4405-45 (Formerly low-alloy-50 steel)-55 -60 FLN2-4405-90HT (Formerly low-alloy-120HT steel)-160HT -190HT FLN4-4405-55 -70 -85 -100 FLN4-4405-90HT -120HT -165HT -195HT FLN4-4405 (HTS)-70 -80 -85 -90 FLN4-4405 (HTS)-75HT -80HT -85HT -90HT
60 65 70 75 ... ... ... ... 70 75 80 85 ... ... ... ... 40 45 50 55 ... ... ... ... 45 50 55 60 ... ... ... ... 55 70 85 100 ... ... ... ... 70 80 85 90 ... ... ... ...
Ultimate 3
B
B
10 psi ... ... ... ... 105 140 170 220 ... ... ... ... 115 135 170 210 ... ... ... ... 80 105 140 175 ... ... ... ... 90 120 160 190 ... ... ... ... 90 120 165 195 ... ... ... ... 75 120 160 200
FLNC-4408-60HT -85HT -105HT -130HT FLC-4608-60HT -75HT -95HT -115HT FLC-4805-70HT -100HT -140HT -175HT FLC2-4808-70HT -85HT -110HT -145HT FLC-48108-50HT -70HT -90HT -110HT FLC2-5208-85HT -95HT -110HT -120HT FLC-48108-105HT -7120HT -135HT -150HT A
... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ...
60 85 105 130 60 75 95 115 70 100 140 175 70 85 110 145 50 70 90 110 85 95 110 120 105 120 135 150
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29 B 10 3 psi = 6.895 MPa (6.895 N/mm2)
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
11
B783 − 13 TABLE 10 Minimum Tensile Strength for Diffusion-Alloyed Steel A Minimum Strength Material Designation Code
Yield
Ultimate 3
B
10 psi FD-0205-45 -50 -55 -60 FD-0205-95HT -120HT -140HT -160HT FD-0208-50 -55 -60 -65 FD-0405-55 -60 -65 FD-0405-100HT -130HT -155HT FD-0408-50 -55 -60 -65 FLDN-09082-70 -80 -90 -100 FLDN4C2-4905-50 -60 -70 -80
45 50 55 60 ... ... ... ... 50 55 60 65 55 60 65 ... ... ... 50 55 60 65 70 80 90 100 50 60 70 80
... ... ... ... 95 120 140 160 ... ... ... ... ... ... ... 100 130 155 ... ... ... ... ... ... ... ... ... ... ... ...
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
APPENDIX (Nonmandatory Information) X1. USE OF THIS SPECIFICATION
material designation coding system is intended for use only with such materials and should not be used to create nonstandard materials. Nevertheless, the use of designations such as FC-0208 or FN-0205 to denote materials of a specified composition is permitted. The explanatory notes, property values, and other contents of this standard have no application to any other materials.
X1.1 PM Material Designation Code X1.1.1 The PM material designation code or identifying code for structural PM parts defines a specific material as to chemical composition and minimum strength expressed in 103 psi (6.895 MPa). For example, FC-0208-60 is a PM copper steel material containing nominally 2 % copper and 0.8 % combined carbon possessing a minimum yield strength of 60 × 10 3 psi (60 000 psi) in the as-sintered condition.
X1.1.4 In the coding system, the prefix letters denote the general type of material. For example, the prefix FC represents iron (F) and copper (C), which is known as iron-copper and copper steel. The prefix letter codes are as follows:
X1.1.2 The system offers a convenient means for designating both the chemical composition and minimum strength value of any standard PM material. The density is given for each standard material as one of the typical values and is no longer a requirement of the specification, with the exception of the iron-phosphorus materials as detailed in Table X1.3 and Table X1.4.
X1.1.4.1 C—Copper. X1.1.4.2 F—Iron. X1.1.4.3 FY—Iron-phosphorus. X1.1.4.4 FC—Iron-copper and Copper Steel.
X1.1.3 Designation codes in this specification and revisions thereof apply only to PM materials for which specifications have been adopted. In order to avoid confusion, the PM
X1.1.4.5 FN—Iron-nickel and Nickel Steel. X1.1.4.6 FX—Infiltrated Iron or Steel. 12
B783 − 13 TABLE 11 Minimum Tensile Strength for Austenitic-300 Series Stainless SteelA
NOTE 1—For the Stainless Steels: N1—Nitrogen alloyed. Good strength, low elongation. N2—Nitrogen alloyed. High strength, medium elongation. L—Low carbon. Lower strength, highest elongation. Minimum Strength Material Designation Code Yield
Ultimate 10
SS-303N1-25 SS-303N2-35 SS-303N2-38 SS-303L-12 SS-303L-15 SS-304N1-30 SS-304N2-33 SS-304N2-38 SS-304L-13 SS-304L-18 SS-304H-20 SS-316N1-25 SS-316N2-33 SS-316N2-38 SS-316L-15 SS-316L-22 SS-316H-20 SS-316L-15 SS-316L-22
3
psiB
25 35 38 12 15 30 33 38 13 18 20 25 33 38 15 22 20 15 22
FIG. X1.1 Illustration of PM Ferrous Material Designation Coding
Minimum Elongation
X1.1.4.7 FL—Prealloyed Ferrous material except Stainless Steel. X1.1.4.8 FLN, FLNC, or FLC Prealloyed Low Alloy Steel Powder, with Elemental Additions. X1.1.4.9 FD—Diffusion Alloyed Steel. X1.1.4.10 N—Nickel. X1.1.4.11 SS—Stainless Steel.
(in 1 in.) %
... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ...
0 3 6 12 15 0 5 8 15 18 7 0 5 8 12 15 5 12 15
X1.1.5 For an illustration of PM ferrous material designation coding, see Fig. X1.1. X1.2 Prefix and Four-Digit Code X1.2.1 In ferrous materials, the major alloying elements (except combined carbon) are included in the prefix letter code. Other elements are excluded from the code but are represented in the chemical composition that appears with each standard material. The first two digits of the numeric code indicate the percentage of the major alloying constituent present. In the case of PM stainless steels and PM prealloyed steels, the numeric code is replaced with a designation derived from modifications of the American Iron and Steel Institute alloy coding system, e.g., SS-316L-15, FL-4605-100HT. When a prealloyed steel powder is modified with elemental additions to create a hybrid low-alloy steel or a sinter-hardened steel, an alpha-numeric designator is used, e.g. FLN-4205-40, FLN24405-120HT or FLN4C-4005-60. In the iron-phosphorus material, the first two digits represent the percentage of phosphorus multiplied by 100 to indicate the nominal amount of phosphorus.
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
TABLE 12 Minimum Tensile Strength for Ferritic and Martensitic400 Series Stainless SteelA
NOTE 1—For the Stainless Steels: N1—Nitrogen alloyed. Good strength, low elongation. N2—Nitrogen alloyed. High strength, medium elongation. L—Low carbon. Lower strength, highest elongation. HT— Martensitic grade, heat treated. Highest strength. Minimum Strength Material Designation Code Yield
Ultimate 10
SS-410-90HT SS-410L-20 SS-430N2-28 SS-430L-24 SS-434N2-28 SS-434L-24
... 20 28 24 28 24
3
psiB
X1.2.2 Combined carbon content and the chemical composition limits in ferrous materials are designated in Table 1.
Minimum Elongation
X1.3 Suffix Digit Code X1.3.1 The two- or three-digit suffix represents the minimum strength value, expressed in 10 3 psi (6.895 MPa (6.895 N/mm2 )) that the user can expect from the PM material possessing that chemical composition. In the as-sintered condition the strength is tensile yield; in the heat-treated condition, it is ultimate tensile (see Minimum Value in Tables X1.1–X1.22). An exception to this is found in the soft magnetic “FY” material in which the suffix represents the minimum density and maximum coercive field strength. The suffix number represents the maximum coercive field strength (ten times the value in oersteds) instead of the yield or tensile strength. For example FY-4500-20W would represent an iron.45-% phosphorus alloy with a minimum density of 6.9 g/cm 3 and a maximum coercive field strength of 2.0 oersteds.
(in 1 in.) %
90 ... ... ... ... ...
0 10 3 14 4 10
A
For the purpose of determining conformance with this specification, measured values shall be rounded “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. B 103 psi = 6.895 MPa (6.895 N/mm2)
13
B783 − 13 y t i s n e D e t l a u i % i v g i i m 0 v t a L 9 r u F S
3
1 m . 7 . 3 . 1 . 6 . 9 . 6 . 8 . 0 . 8 . 2 . 6 . 0 . 3 . 6 . 9 . 1 . c 6 6 7 6 6 6 6 6 7 5 6 6 7 6 6 6 7 / g
i s p 0 4 2 5 3 7 2 1 4 7 5 6 0 4 8 7 9 0 1 1 1 1 2 2 3 1 1 1 2 2 3 3 3 1
3
n ) o d e C C - i t t o t R 8 8 R 0 0 0 a r r D D D e / / / c n v H 6 6 6 i 5 5 N N H N e n 8 0 M d o l l s 5 6 s c e n ( i e w n k d c r ) o a t R F B B H o n C C e r R 0 0 R 0 5 R 2 5 R 0 0 0 R 8 2 5 c r H 6 8 H 4 5 H 2 2 H 5 6 7 H 2 3 3 a a p 0 5 5 0 2 M p 4 2 3 2 2 a ( s h ) i t e d g % s r e l p 6 8 9 8 3 8 3 2 1 8 1 1 6 0 0 0 0 p i v i e n e . 0 1 1 1 1 2 2 4 5 6 2 3 3 3 7 8 9 0 1 m s Y t r 1 0 o S ( 1 C 3
. n o i t i d n o c . d s n e i o t a t i e d r n t - o t a c e g h i n e r u h t t c n a i f e u t a n a m m i t l l a u i d c n r a e n m o m i t i o d c . n r e l s o c d a n i d u r e e t r d e a e r t n t e m i s n d i e s s t a s a r e n e h e t t t m a i n e i c h d e l r p e s f o i y t . e ; s i F e s t ° m p d 0 a 5 s r 3 e 0 e h i e t a t 1 p : s h s t a g n r 5 8 4 2 8 0 0 0 9 5 2 7 5 5 5 5 i n p 8 e l a l y m i 1 2 3 2 3 3 6 7 8 2 3 4 5 6 7 8 9 i e r t t r 0 s p e t e l 1 e t y a a U S u r l o m i m a v t x a r ) o T h r o t e t H g b ( p p a a n l 0 0 . . . . 5 5 5 5 e d a . . . . . . . . . . . . . . . . . . 0 m 5 6 7 . . . . . . . . 5 6 7 8 t r m t i e t e C l i r s o A m r a a U s f e u h r h p m d t t t u g m i n t e m i n e v a g A i 0 i r e n r s M t e 1 n i r e h t e S d d u r s l m . . . . . . . l 0 5 0 5 0 5 0 5 0 5 . . . . . . . e o t a i a f l 1 1 2 1 2 2 . . . 2 2 3 3 . . . . n t e i V Y a r e s e d s m u n e e y t u r t t a r p r e m i e e t 0 5 0 5 0 5 T T T 0 5 0 5 T T T T r p e n p a i 1 H H 2 H H H s - 1 - 2 - 1 - 2 - 2 - H - 2 - 3 - 3 - H r m i M n r o m 0 0 0 5 5 5 5 0 5 8 p t t e l l i o e l 5 5 0 0 - 6 - 7 - 0 - 6 - 7 - 8 - b a t e u 0 0 0 i 5 8 a a r d g d 0 0 0 m i 0 0 e n o n n i t u c 0 0 g F F F r n i a C n a e a 0 0 M s x h p d e i F F f c l f D e u e m e i S M T Y
- e t i r h s s s e u g 0 1 4 0 0 5 0 5 s t e n r 0 5 8 4 6 5 0 n p 6 2 4 1 0 0 1 3 4 p a u 3 5 9 4 6 7 0 e l r e 1 1 1 5 6 7 1 1 1 1 1 r 0 u v t a V T R S 1 l a c i p t y y d e y T - h p c r f a g n c r b 3 6 5 a p e l 3 3 4 5 3 3 4 2 3 4 5 3 4 4 5 • U t h n f t o C I m E n s e i t r e s ’ p n i o o r 5 5 8 5 5 7 5 7 7 5 5 5 7 5 5 7 7 o t 2 s P . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . 2 . a s R l i 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a o i r P e t a M i s s ’ u s 0 5 5 0 5 5 5 5 5 5 0 5 5 5 5 5 5 M g l . . . . . . . . . . . . . . . . . P u p 5 n d 3 5 6 9 6 8 0 2 6 6 0 6 6 9 1 u o 0 1 7 1 2 1 1 1 1 1 2 1 1 1 2 1 1 1 2 o Y M 1 s e i t r n e o ) . p i t n o r a i 1 1 1 1 1 1 1 1 1 1 P g % 1 2 7 1 < 1 1 < < < < < < 1 < < < < n 1 n e o l l i i s E ( n e T h t ) i d % s l g p 3 8 5 8 3 8 5 0 5 0 e n D i e 2 . 0 1 1 2 1 2 2 D 2 3 3 4 r Y t 0 S ( 1 B
3
l e e t S n o b r a C d n a n o r I 1 . 1 X E L B A T
6
. d r a d n a t s s i h t f o s e s . ) o p r m u m p / e N h t 5 r 9 o 8 f . 6 d ( e a n i P . m M . J r m 6 e t 5 e 5 9 m 3 D 8 . . 1 t 6 4 . o = N = 5 2 f i s = b — p . l • t D n f i / 0 1 1 1 N — 2 — 3 — 4 — 1
2
3
E T O
E T O
E T O
E T O
N N N N
3
3
3
,
3
A B C D
14
B783 − 13 y t i s n e D
3
1 m . 7 . 3 . 1 . 6 . 9 . 6 . 8 . 0 . 8 . 2 . 6 . 0 . 3 . 6 . 9 . 1 . c 6 6 7 6 6 6 6 6 7 5 6 6 7 6 6 6 7 / g
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. n o i t i d n o c . d s n e i o t a t i e d r n t s ’ - o t n i o a c 5 5 7 5 7 5 5 7 5 5 7 5 5 7 5 5 7 s o t t e 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 s s g . . . . . . . . . . . . . . . . . a n i h i e t n 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 i a s t o R e r r s u h t P e t n c p o n a o i f r C e u P i c s i t s l ’ l u s 5 5 0 0 0 5 5 0 0 0 0 5 5 0 0 0 0 a n a a t s g i . . . . . . . . . . . . . . . . . u p 5 m m r n d a i l 6 0 7 0 5 6 0 7 7 0 5 6 0 7 7 0 t e E u o 0 1 1 2 1 2 1 1 2 1 1 2 1 1 2 1 1 2 l l t o a u i a Y M 1 d c M n r a e M P n m n ) o m o . i i t t n i o c a i d 1 0 7 0 1 0 1 0 3 3 6 0 3 8 1 g 1 % < 5 1 1 2 < 1 1 1 2 2 < 1 1 7 1 2 n r e n n o o ( i c d l . d n E d e u s e e r d i s t t e r r u e i h ) e n t e t i s e p d g s % n l n p 2 2 5 7 4 8 0 5 5 8 6 4 9 5 5 0 0 b - i o r i e e 2 s s 3 4 4 1 2 3 4 4 2 1 2 3 3 4 2 2 3 d . P l a r Y t 0 0 . s u 1 ( d e n e S l o r i h e c t a s m n d s i i e n n n c T a o d e i t e h t t i t i l s s e p s i g a d p 9 5 8 9 8 3 7 0 0 3 7 1 0 0 5 1 7 s y t n n i m e 3 5 6 3 4 4 5 7 4 4 5 4 6 7 3 4 5 ; s i o i h t r e 0 l t 1 c s t t U S r p d f e o . h 0 e r t n s o 1 a o e i , t . s ) n p e n ) a i r n a o t . o . m 2 i n p o g p a s i n t u t n r i e d o m y . i 0 3 6 2 5 0 5 8 7 5 8 0 5 8 5 2 5 a l o n u u r m a t g l i 1 % 1 1 1 1 1 1 g e o m p o a n n t / s a n e t i i n g v o i a e e A o . m a n ( r N l M l h s h a a h E o e o t i u i g t t l i e 5 b n n n g e d u e r a 9 w l o o o t n l . t o a A o m e m l 8 a e l f e n s . r t r m m V h e , e e . 6 e t , m h g h s o d ( h . a t m r a h g o i m t e g g m n n t a i e m f { { { { { { { { { { { { { { { g a r u u m n n o h g i d d g h i n i i i d d u t P e t u l n , m e e r s e t e t h y , c p t e . m r m U p r o i v t h h n t J a t r i a t M i r t a i S s i v o g n r e g d c c s i s m l e M m 6 t 5 n % n e d o o 0 a b d e m 9 h s e e o s m 5 u r 0 t 1 t a s r i 3 g i t t t 8 s s u r o D a i i 0 . . d s m l a n s n i 6 4 . 1 t 5 5 8 2 5 0 3 8 0 3 8 5 3 8 0 5 2 G d H d r 1 s a e r e n r p e i 2 3 3 1 1 3 3 3 2 1 1 2 3 3 2 1 2 o 5 i . . d s n n e n g e = 2 = N d i d i w i e n o t e i M Y y r i f w e e e r t F t m p r o F s y F o F i b — ° y ° L ° L l e e p = ° o o n . 0 0 0 l l r • a p l 0 l 5 . 0 . 0 d r t D n f 3 o i a a n 5 s / i n a 1 3 1 r 0 o 2 o 3 o p r n 2 2 p 5 5 8 0 3 8 5 3 8 n n e 1 1 1 N b 2 v l i o b t t t l 2 3 3 3 3 3 0 2 3 3 0 e e r b 2 5 - - - 2 3 8 - - - 2 5 2 g a g a a a r t a g t a a i e 1 1 1 1 1 2 a n — — — — a r 1 2 2 1 2 2 1 2 2 a m i c - - - - r o d r o d c d c t o s u i 1 2 3 4 e n d N N N L L N N N H L L N N N H L L t t t d o i r e i r e w r e w e d s n n g 3 3 3 3 3 4 4 4 4 4 4 6 6 6 6 6 6 i E E E E a a C o t 0 0 0 0 0 0 0 0 0 0 0 1 1 1 1 1 1 N t T T T T e N t e L e o r x h e e c i M s e l e 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 f O O O O L c t o f — n — n n o i — D n o r u e 2 i — N N N N S S S S S S S S S S S S S S S S S 1 i i S S S S S S S S S S S S S S S S S N S * N S * H S * L S C P * S M 6
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h ) s t e d g % a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 r e l p i v i P 2 2 4 0 6 2 2 7 5 9 5 0 2 7 5 0 e n 1 e . M 6 2 3 3 1 2 2 3 3 1 1 1 2 3 3 1 1 2 r 0 m s Y t o ( S C
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. n o i t i d h e n t r s e o g a u 0 0 0 0 0 0 0 0 0 0 s t n P 9 8 / D 7 / D 7 8 / D 9 / D / D 4 6 / D 9 5 / D c n r B p a e d 5 6 5 7 8 5 7 8 5 5 N N N N N N N s r e r M u e e T v R t t S u a l e a r V t l d y t y t a a c e p g c e i n h r a r 5 6 7 4 5 5 4 5 7 1 8 7 8 5 7 7 8 h . p 2 4 5 7 3 7 2 6 0 3 6 2 4 8 a p e J c h y U t 1 n e s m T o h n n C I E t i o n t i i d e n s t ’ a o n i o 5 5 7 5 7 5 5 7 5 5 7 5 5 7 5 5 7 s o t m c 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 i s s t g . . . . . . . . . . . . . . . . . t a n l s R e n i 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 i a u i t t r o r s u d t P e n n c p o a a o f r C n u P i c s o s n i l ’ l t u a t a i a g s 5 0 0 0 5 5 0 0 0 0 5 5 0 0 0 0 i u P 5 d m r n d a 0 1 4 2 4 0 1 4 2 2 4 0 1 4 2 2 4 l n l e E u o G 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 t o o a a c i Y M M r d c e r e M e P t m n n m o 4 i i o t s . ) - c a 5 1 5 0 7 0 1 0 3 0 3 6 1 0 3 7 8 1 r m s g 2 % < 1 1 2 < 1 1 1 2 2 < 1 1 1 2 e a d n i n m o e n l ( . h E d t u s e e n d i s i t e r r u d h ) e l t e t e p d e g a i % n l n 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 b y i o r i P 0 e e 2 2 9 1 2 7 6 8 1 7 2 8 3 7 1 7 4 1 s d ; . 2 2 3 1 1 2 2 3 1 1 1 2 2 3 1 1 2 P l r ) s Y t 0 M . u 2 ( d e n S l o r i c e e a s g m n d s a i e n n p c T a e o i t e h t p t t i e s s e g a a d 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 s t s n n ( s i 8 7 7 3 0 9 8 8 0 9 8 1 8 4 8 9 m e P 7 i o i 2 3 4 2 3 3 3 4 2 3 3 2 4 4 2 2 3 h t r e M l t c s t t U S r p d f e o . h 0 e r t n s o 1 a o e i , t . s n p e n a i r n a o t . o m 4 i . ) p o g p a s i n u t t n r e 5 d o y . i 5 0 5 8 7 5 8 0 5 8 5 2 5 a l o n u m % 0 3 6 2 u r m a 2 t g l i 1 1 1 1 1 1 g e o p o a n n t s a n m n e t i i i g v o a e e A ( o m a a n r l M l h s h a h E o e i i o t u i g t t l e b n n n g e d u e r a w o l o o t n l . t o a A o m e m l a e l f e n s r t r m m V h e , e . e e t , m d h h m . n s o a t m a h r a h g g m t e g g n e m f o i i t d { { { { { { { { { { { { { { { g r u m n n o g u d h g i d h u i n u i i d t e t e l n , e m t r e t e t h y , c e p t o i r m m i U a v t a t h h n S a t r i r t a i v r s i o r P g n c e g d c s i l s e M m t n % o n e o d M a b d e e i m h s s s e o u r 0 t r t s t g i r a u t t s i o D i 0 d s m l n a n 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 G d H d r 1 s a i t a e r e 7 4 6 8 0 1 3 6 4 9 2 7 3 6 4 0 5 . n . n e n r p e s n i o i d g e 1 2 2 1 2 2 2 1 1 1 2 2 1 1 1 i n o t s d i d w i e e i M Y N y r w e e e r t C t m p r o C y C o C i ° L ° y ° L e e — ° o o n 0 0 0 l l r a p l 5 l 9 . 5 . 0 d r D o a 1 a 2 n 1 n 9 i a s / r o 1 o 2 o p r n 1 1 p 5 5 8 0 3 8 5 3 8 n n e N b 1 v l i o b t t t l 2 3 3 3 3 3 0 2 3 3 0 e e r b 2 5 - - - 2 3 8 - - - 2 5 2 g a g a a a r t a g t a a i e 1 1 1 1 1 2 a n — a r 1 2 2 1 2 2 1 2 2 a m i c - - - - r o d r o d c d c t o s u i 1 e n d N N N L L N N N H L L N N N H L L t t t d o i r e i r e w r e w e d s n n g 3 3 3 3 3 4 4 4 4 4 4 6 6 6 6 6 6 i E a a C o t 0 0 0 0 0 0 0 0 0 0 0 1 1 1 1 1 1 N t T e N t e L e o r x h e e c i M s e l e 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 f O L c t o f — n — n n o i — D n o r u e 2 i — N S S S S S S S S S S S S S S S S S 1 i i S S S S S S S S S S S S S S S S S N S * N S * H S * L S C P * S M 3
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- e e t i r h s s u g s t D / D / D / D / D n n p 3 r 1 / B p a e s r e r 0 1 N N N N N u t e T v R S 1 u l a V l d y t y a e p c g c - h 5 i r f . n c r l p a a p e b 5 0 5 5 • 2 0 y U t t h n 5 2 8 1 6 f m T o n C I E 3
. n o i t i d n o c . d s n e i o t a t i e d r n t s ’ - o t n i o a c 5 7 7 7 7 7 s o t t e 2 2 2 2 2 2 s s g . . . . . . a n i h i e t n 0 0 0 0 0 0 i a s t o R e r r s u h t P e t n c p o n a o i f r C e u P i c s i t s l ’ l u s 0 0 0 0 0 0 a n a a t s g i . . . . . . u p 8 m m r n d a i l 4 5 5 4 4 t e E u o 0 1 2 2 2 2 2 l l t o a u i a Y M 1 d c M n r a e M P n m n ) o m o . i i t t n i o c a i d 1 6 5 0 8 5 g 1 % < 1 2 1 . n r e l s n n o o ( i c d a l n i . u r d d s E e e t e e d r i a s t e e r t r u n e m h D i e t ) i t s e p d n d l g b s o - i % p D 6 5 0 5 0 e r i e n s s t 2 3 3 3 3 e d 2 a P l a r . 0 Y t 0 . s u e n e r d e S ( 1 l t o r i e h c t t a s m a n d s i i e e n n n c h T a e o d p r i t l e h t t i t i s s e s o a g d i p 5 8 0 0 0 0 t f s n y i 0 4 6 5 6 5 m n ; s i e o i 1 h t . e r e F 0 l t 1 c s t t m ° U r p S f d 0 a s e o e . h 0 r 5 e t n 3 s a o 1 p ; t h o e . i , i t s n r h a e l n ) a l y t ) a i o t . o . m r 2 g a s p e t g n i n e p t u n n r i e t d o m y a a 0 0 3 4 4 0 l e o i u u r m a t r g l i 1 % 1 1 1 t e o m i m p m e a n n t / s s a i n g o i x e v a e A t . h ( r ) N m a n M l o s s h T a h E r o o t u i i t t l i e e 5 H g b e d n h n ( p u e r a 9 l o o t n l e t g a e d p a o a A i 8 f . m s m r t C r m t m V h e e H e . 6 e r , m h m e s t t . d o ( . r a a a n m g a e g m n d 0 { { { { { h t a i e e m f a u u r n e n o 9 h g d d g m t h i t i i d t u i P e t u n t m e e . m i t t r s , c p a l e t t e t J m r e v a g n S r a h a o i M U p i r t a r i i i t e n v o t e n r e g d 6 c c s i r s m h l e M m t t 5 t n e o o 5 0 b a d e a r s m 9 h i s s e s m 3 u 1 t a r e o . g t 8 s s u r a f l i i t e i . 4 1 D t m d n l s a n h i i d d s { 0 8 4 8 4 H 6 t . a r , e s e r e n r p e i 2 2 2 2 2 o 5 i . = d e s n n g e = 2 u n d i e n o d i t e M Y N y t r t i f w i e e e r a a t F F t s r r p r = y o i b — F ° ° m e e g e p . l o 0 L ° n 0 a r p e t l • l t D . 0 r s o p a n f 5 n c 0 3 d i i a 5 / i a 3 t 1 r m i 0 m i 2 p r o n o 3 T 8 8 n 2 t e l e p t 1 1 1 N v s l i o t b n t b l H 0 2 4 2 4 e r 2 g u a t a t a a a i g e i g d e 0 2 — 2 — 3 — 4 — r a d m i c i - 2 2 - 2 2 - r o d a o t n n c a t r d n 9 1 e n o s u L N L N L t t r d a n e w e d r e s n a e a g 0 0 0 0 4 4 i E E E E a i r C 1 1 3 3 3 3 N t T T T T e o r e e x h p d e M t c i M s e l e 4 4 4 4 4 4 f O O O O L c l t — — n o n o i i r f e D n u e m N N N N e i S S S S S S 2 S — i o T S P S S S S S S N * L S C H * * S M T Y 6
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